CN112771022B - 用于Li离子电池中的电解质的添加剂 - Google Patents

用于Li离子电池中的电解质的添加剂 Download PDF

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Publication number
CN112771022B
CN112771022B CN201980062375.1A CN201980062375A CN112771022B CN 112771022 B CN112771022 B CN 112771022B CN 201980062375 A CN201980062375 A CN 201980062375A CN 112771022 B CN112771022 B CN 112771022B
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battery
electrolyte
compound
performance
ion battery
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CN112771022A (zh
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C·马莱
S·罗尚
K·扎吉布
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Hydro Quebec
Murata Manufacturing Co Ltd
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Hydro Quebec
Murata Manufacturing Co Ltd
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Priority to CN202410235009.4A priority Critical patent/CN118099525A/zh
Priority to CN202410234917.1A priority patent/CN118099524A/zh
Priority to CN202410234961.2A priority patent/CN118117168A/zh
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/37Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by etherified hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/35Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms, or by nitro or nitroso groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/50Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/50Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
    • C07C255/51Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings containing at least two cyano groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/49Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/55Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and esterified hydroxy groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/54Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/57Nitriles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0567Liquid materials characterised by the additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0025Organic electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
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  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CN201980062375.1A 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂 Active CN112771022B (zh)

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Application Number Priority Date Filing Date Title
CN202410235009.4A CN118099525A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410234917.1A CN118099524A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410234961.2A CN118117168A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂

Applications Claiming Priority (3)

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US201862741275P 2018-10-04 2018-10-04
US62/741,275 2018-10-04
PCT/CA2019/051415 WO2020069619A1 (en) 2018-10-04 2019-10-03 Additives for electrolytes in li-ion batteries

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CN202410234917.1A Division CN118099524A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410234961.2A Division CN118117168A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410235009.4A Division CN118099525A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂

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CN112771022B true CN112771022B (zh) 2024-03-19

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CN202410234917.1A Pending CN118099524A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410235009.4A Pending CN118099525A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410234961.2A Pending CN118117168A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂

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CN202410235009.4A Pending CN118099525A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂
CN202410234961.2A Pending CN118117168A (zh) 2018-10-04 2019-10-03 用于Li离子电池中的电解质的添加剂

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US (2) US12100807B2 (https=)
EP (1) EP3860974A4 (https=)
JP (3) JP7460612B2 (https=)
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CN (4) CN112771022B (https=)
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WO (1) WO2020069619A1 (https=)

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KR102940360B1 (ko) 2021-01-07 2026-03-16 주식회사 엘지에너지솔루션 리튬 이차전지용 비수계 전해액 및 이를 포함하는 리튬 이차전지
CN114805124A (zh) * 2021-01-29 2022-07-29 石家庄圣泰化工有限公司 一种亚苄基丙二腈类化合物的合成方法
CN114695963B (zh) * 2022-04-19 2025-05-02 华南师范大学 电解液和锂离子电池
CN115579522B (zh) * 2022-11-10 2023-03-17 合肥国轩高科动力能源有限公司 电解液及锂离子电池
KR102905187B1 (ko) * 2022-11-14 2025-12-26 삼성에스디아이 주식회사 리튬이차전지용 전해질 및 이를 포함하는 리튬이차전지
CN116470127A (zh) * 2023-03-29 2023-07-21 中国科学院青岛生物能源与过程研究所 一种适用于碱金属电池的电解质和应用

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FR1517178A (fr) * 1966-03-21 1968-03-15 Ciba Geigy Nouveaux agents pesticides
EP0322738A2 (en) * 1987-12-24 1989-07-05 Yissum Research Development Company Of The Hebrew University Of Jerusalem Benzylidene-malononitrile derivatives for the inhibition of proliferative processes in mammalian cells
JPH03236168A (ja) * 1990-02-13 1991-10-22 Nippon Telegr & Teleph Corp <Ntt> 化学電池
JP2002023394A (ja) * 2000-07-04 2002-01-23 Konica Corp 電子写真感光体とそれを用いたプロセスカートリッジ及び画像形成装置
CN1487621A (zh) * 2002-07-15 2004-04-07 ��˲���ʽ���� 非水电解液和锂电池
CN101283466A (zh) * 2005-10-10 2008-10-08 苏威氟有限公司 用于锂离子电池的氟化添加剂
CN102088111A (zh) * 2009-12-02 2011-06-08 索尼公司 非水电解质电池
CN102646846A (zh) * 2011-02-16 2012-08-22 三星Sdi株式会社 可再充电锂电池用电解液和含该电解液的可再充电锂电池
CN102751532A (zh) * 2011-04-22 2012-10-24 株式会社日立制作所 锂离子二次电池及电池组系统
JP2014096213A (ja) * 2012-11-07 2014-05-22 Yokohama National Univ アルカリ金属−空気二次電池
CN104837850A (zh) * 2013-06-04 2015-08-12 塞勒创尼克斯公司 腈-取代的硅烷和电解质组合物和包含它们的电化学装置
CN104051786A (zh) * 2014-06-24 2014-09-17 东莞市凯欣电池材料有限公司 一种电解液及其制备方法以及一种高电压锂离子电池
CN107408727A (zh) * 2015-03-16 2017-11-28 阿科玛法国公司 用于锂离子电池的电解质配制物
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