JP7460612B2 - リチウムイオン電池用電解質添加剤 - Google Patents
リチウムイオン電池用電解質添加剤 Download PDFInfo
- Publication number
- JP7460612B2 JP7460612B2 JP2021516923A JP2021516923A JP7460612B2 JP 7460612 B2 JP7460612 B2 JP 7460612B2 JP 2021516923 A JP2021516923 A JP 2021516923A JP 2021516923 A JP2021516923 A JP 2021516923A JP 7460612 B2 JP7460612 B2 JP 7460612B2
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- JP
- Japan
- Prior art keywords
- compound
- battery
- group
- electrolyte
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
- C07C255/37—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by etherified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
- C07C255/35—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms, or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/50—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/50—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
- C07C255/51—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings containing at least two cyano groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/55—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and esterified hydroxy groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/57—Nitriles
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2023200825A JP2024026195A (ja) | 2018-10-04 | 2023-11-28 | リチウムイオン電池用電解質添加剤 |
| JP2025101544A JP2025131854A (ja) | 2018-10-04 | 2025-06-17 | リチウムイオン電池用電解質添加剤 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862741275P | 2018-10-04 | 2018-10-04 | |
| US62/741,275 | 2018-10-04 | ||
| PCT/CA2019/051415 WO2020069619A1 (en) | 2018-10-04 | 2019-10-03 | Additives for electrolytes in li-ion batteries |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023200825A Division JP2024026195A (ja) | 2018-10-04 | 2023-11-28 | リチウムイオン電池用電解質添加剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2022502817A JP2022502817A (ja) | 2022-01-11 |
| JP7460612B2 true JP7460612B2 (ja) | 2024-04-02 |
Family
ID=70054643
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021516923A Active JP7460612B2 (ja) | 2018-10-04 | 2019-10-03 | リチウムイオン電池用電解質添加剤 |
| JP2023200825A Pending JP2024026195A (ja) | 2018-10-04 | 2023-11-28 | リチウムイオン電池用電解質添加剤 |
| JP2025101544A Pending JP2025131854A (ja) | 2018-10-04 | 2025-06-17 | リチウムイオン電池用電解質添加剤 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023200825A Pending JP2024026195A (ja) | 2018-10-04 | 2023-11-28 | リチウムイオン電池用電解質添加剤 |
| JP2025101544A Pending JP2025131854A (ja) | 2018-10-04 | 2025-06-17 | リチウムイオン電池用電解質添加剤 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US12100807B2 (https=) |
| EP (1) | EP3860974A4 (https=) |
| JP (3) | JP7460612B2 (https=) |
| KR (4) | KR20250026888A (https=) |
| CN (4) | CN118099525A (https=) |
| CA (3) | CA3112350C (https=) |
| WO (1) | WO2020069619A1 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102940360B1 (ko) | 2021-01-07 | 2026-03-16 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수계 전해액 및 이를 포함하는 리튬 이차전지 |
| CN114805124A (zh) * | 2021-01-29 | 2022-07-29 | 石家庄圣泰化工有限公司 | 一种亚苄基丙二腈类化合物的合成方法 |
| CN114695963B (zh) * | 2022-04-19 | 2025-05-02 | 华南师范大学 | 电解液和锂离子电池 |
| CN115579522B (zh) * | 2022-11-10 | 2023-03-17 | 合肥国轩高科动力能源有限公司 | 电解液及锂离子电池 |
| KR102905187B1 (ko) * | 2022-11-14 | 2025-12-26 | 삼성에스디아이 주식회사 | 리튬이차전지용 전해질 및 이를 포함하는 리튬이차전지 |
| CN116470127A (zh) * | 2023-03-29 | 2023-07-21 | 中国科学院青岛生物能源与过程研究所 | 一种适用于碱金属电池的电解质和应用 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002302649A (ja) | 2001-02-02 | 2002-10-18 | Daikin Ind Ltd | 電極表面被膜形成剤 |
| JP2004165050A (ja) | 2002-11-14 | 2004-06-10 | Nippon Shokubai Co Ltd | イオン伝導性材料 |
| WO2008056776A1 (fr) | 2006-11-10 | 2008-05-15 | Nagoya Industrial Science Research Institute | Composé mésoionique, liquide ionique constitué du composé mésoionique et procédé de production du composé mésoionique |
| JP2011119097A (ja) | 2009-12-02 | 2011-06-16 | Sony Corp | 非水電解質電池 |
| JP2012227068A (ja) | 2011-04-22 | 2012-11-15 | Hitachi Ltd | リチウムイオン二次電池及び組電池システム |
| WO2017113820A1 (zh) | 2015-12-31 | 2017-07-06 | 石家庄圣泰化工有限公司 | 高电压宽温锂离子电池电解液及其制备方法及应用 |
| JP2018508112A (ja) | 2015-03-16 | 2018-03-22 | アルケマ フランス | リチウムイオン電池のための電解質配合組成物 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1517178A (fr) * | 1966-03-21 | 1968-03-15 | Ciba Geigy | Nouveaux agents pesticides |
| AU632992B2 (en) * | 1987-12-24 | 1993-01-21 | Yissum Research Development Company Of The Hebrew University Of Jerusalem | Pharmaceutical compositions comprising benzylidene- and cinnamylidene-malononitrile derivatives for the inhibition of proliferative processes in mammalian cells, certain such novel compounds and their preparation |
| JPH03236168A (ja) * | 1990-02-13 | 1991-10-22 | Nippon Telegr & Teleph Corp <Ntt> | 化学電池 |
| JP2002023394A (ja) * | 2000-07-04 | 2002-01-23 | Konica Corp | 電子写真感光体とそれを用いたプロセスカートリッジ及び画像形成装置 |
| JP5589984B2 (ja) * | 2001-02-02 | 2014-09-17 | ダイキン工業株式会社 | 電極表面被膜形成剤 |
| KR101111365B1 (ko) | 2002-07-15 | 2012-03-09 | 우베 고산 가부시키가이샤 | 비수성 전해액 및 리튬 전지 |
| DE102005048802A1 (de) * | 2005-10-10 | 2007-04-12 | Solvay Fluor Gmbh | Fluorierte Additive für Lithiumionenbatterien |
| KR101309157B1 (ko) | 2011-02-16 | 2013-09-17 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 전해액 및 이를 포함하는 리튬 이차 전지 |
| JP2014096213A (ja) * | 2012-11-07 | 2014-05-22 | Yokohama National Univ | アルカリ金属−空気二次電池 |
| US9437371B2 (en) | 2013-06-04 | 2016-09-06 | Silatronix, Inc. | Nitrile-substituted silanes and electrolyte compositions and electrochemical devices containing them |
| CN104051786B (zh) | 2014-06-24 | 2016-06-15 | 东莞市凯欣电池材料有限公司 | 一种电解液及其制备方法以及一种高电压锂离子电池 |
| CA3005799C (en) | 2015-12-14 | 2023-10-17 | NOHMs Technologies, Inc. | Silane functionalized ionic liquids |
| CN105591156A (zh) * | 2016-01-04 | 2016-05-18 | 东莞市凯欣电池材料有限公司 | 一种含有苯三腈的电解液及含有该电解液的锂离子二次电池 |
| KR102049220B1 (ko) * | 2016-01-22 | 2019-11-28 | 아사히 가세이 가부시키가이샤 | 비수계 리튬 축전 소자 |
| KR102047291B1 (ko) | 2016-09-23 | 2019-11-21 | 주식회사 엘지화학 | 접착제 조성물 |
| JP6899312B2 (ja) * | 2016-12-19 | 2021-07-07 | 株式会社Gsユアサ | 非水電解質、及び非水電解質蓄電素子 |
| JP2018120848A (ja) * | 2017-01-26 | 2018-08-02 | 本田技研工業株式会社 | リチウムイオン二次電池 |
| CN107403959B (zh) * | 2017-08-04 | 2019-05-03 | 广州天赐高新材料股份有限公司 | 一种锂二次电池电解液及锂二次电池 |
| CN107785610B (zh) * | 2017-10-24 | 2020-06-23 | 广州天赐高新材料股份有限公司 | 锂二次电池电解液及其锂二次电池 |
| CN108054430B (zh) * | 2017-12-26 | 2020-01-24 | 欣旺达电子股份有限公司 | 锂离子电池电解液及锂离子电池 |
| CN108428939A (zh) * | 2018-03-20 | 2018-08-21 | 成都新柯力化工科技有限公司 | 一种循环稳定的高镍三元锂电池电解液 |
| WO2019183351A1 (en) * | 2018-03-23 | 2019-09-26 | Maxwell Technologies, Inc. | Electrolyte additives and formulations for energy storage devices |
-
2019
- 2019-10-03 CN CN202410235009.4A patent/CN118099525A/zh active Pending
- 2019-10-03 JP JP2021516923A patent/JP7460612B2/ja active Active
- 2019-10-03 US US17/281,120 patent/US12100807B2/en active Active
- 2019-10-03 KR KR1020257005078A patent/KR20250026888A/ko active Pending
- 2019-10-03 WO PCT/CA2019/051415 patent/WO2020069619A1/en not_active Ceased
- 2019-10-03 CN CN201980062375.1A patent/CN112771022B/zh active Active
- 2019-10-03 EP EP19868859.0A patent/EP3860974A4/en active Pending
- 2019-10-03 KR KR1020257041542A patent/KR20260006044A/ko active Pending
- 2019-10-03 CA CA3112350A patent/CA3112350C/en active Active
- 2019-10-03 CN CN202410234961.2A patent/CN118117168A/zh active Pending
- 2019-10-03 CA CA3226004A patent/CA3226004A1/en active Pending
- 2019-10-03 KR KR1020257005075A patent/KR20250026887A/ko active Pending
- 2019-10-03 CA CA3226009A patent/CA3226009A1/en active Pending
- 2019-10-03 CN CN202410234917.1A patent/CN118099524A/zh active Pending
- 2019-10-03 KR KR1020217008795A patent/KR102925738B1/ko active Active
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2023
- 2023-11-28 JP JP2023200825A patent/JP2024026195A/ja active Pending
-
2025
- 2025-06-17 JP JP2025101544A patent/JP2025131854A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002302649A (ja) | 2001-02-02 | 2002-10-18 | Daikin Ind Ltd | 電極表面被膜形成剤 |
| JP2004165050A (ja) | 2002-11-14 | 2004-06-10 | Nippon Shokubai Co Ltd | イオン伝導性材料 |
| WO2008056776A1 (fr) | 2006-11-10 | 2008-05-15 | Nagoya Industrial Science Research Institute | Composé mésoionique, liquide ionique constitué du composé mésoionique et procédé de production du composé mésoionique |
| JP2011119097A (ja) | 2009-12-02 | 2011-06-16 | Sony Corp | 非水電解質電池 |
| JP2012227068A (ja) | 2011-04-22 | 2012-11-15 | Hitachi Ltd | リチウムイオン二次電池及び組電池システム |
| JP2018508112A (ja) | 2015-03-16 | 2018-03-22 | アルケマ フランス | リチウムイオン電池のための電解質配合組成物 |
| WO2017113820A1 (zh) | 2015-12-31 | 2017-07-06 | 石家庄圣泰化工有限公司 | 高电压宽温锂离子电池电解液及其制备方法及应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| US12100807B2 (en) | 2024-09-24 |
| KR20210061353A (ko) | 2021-05-27 |
| US20210376381A1 (en) | 2021-12-02 |
| CN112771022A (zh) | 2021-05-07 |
| JP2025131854A (ja) | 2025-09-09 |
| US20250023099A1 (en) | 2025-01-16 |
| EP3860974A4 (en) | 2022-08-17 |
| CA3112350C (en) | 2026-01-06 |
| CN112771022B (zh) | 2024-03-19 |
| KR102925738B1 (ko) | 2026-02-10 |
| CA3226004A1 (en) | 2020-04-09 |
| CA3226009A1 (en) | 2020-04-09 |
| EP3860974A1 (en) | 2021-08-11 |
| CN118117168A (zh) | 2024-05-31 |
| JP2024026195A (ja) | 2024-02-28 |
| KR20250026888A (ko) | 2025-02-25 |
| CN118099525A (zh) | 2024-05-28 |
| WO2020069619A1 (en) | 2020-04-09 |
| JP2022502817A (ja) | 2022-01-11 |
| CA3112350A1 (en) | 2020-04-09 |
| KR20250026887A (ko) | 2025-02-25 |
| KR20260006044A (ko) | 2026-01-12 |
| CN118099524A (zh) | 2024-05-28 |
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