CN1127376C - 催化剂活化和再生方法 - Google Patents

催化剂活化和再生方法 Download PDF

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Publication number
CN1127376C
CN1127376C CN96198191A CN96198191A CN1127376C CN 1127376 C CN1127376 C CN 1127376C CN 96198191 A CN96198191 A CN 96198191A CN 96198191 A CN96198191 A CN 96198191A CN 1127376 C CN1127376 C CN 1127376C
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CN
China
Prior art keywords
catalyst
hydrogen
hydrocarbon
gas
synthesis
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Expired - Fee Related
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CN96198191A
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English (en)
Chinese (zh)
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CN1202119A (zh
Inventor
A·霍克
J·H·穆斯
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Shell Internationale Research Maatschappij BV
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Shell Internationale Research Maatschappij BV
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Publication of CN1202119A publication Critical patent/CN1202119A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/58—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids and gas addition thereto
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN96198191A 1995-11-08 1996-11-06 催化剂活化和再生方法 Expired - Fee Related CN1127376C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP95203040.1 1995-11-08
EP95203040 1995-11-08

Publications (2)

Publication Number Publication Date
CN1202119A CN1202119A (zh) 1998-12-16
CN1127376C true CN1127376C (zh) 2003-11-12

Family

ID=8220810

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96198191A Expired - Fee Related CN1127376C (zh) 1995-11-08 1996-11-06 催化剂活化和再生方法

Country Status (18)

Country Link
EP (1) EP0861122B1 (https=)
JP (1) JPH11514575A (https=)
KR (1) KR100447016B1 (https=)
CN (1) CN1127376C (https=)
AU (1) AU704027B2 (https=)
BR (1) BR9611350A (https=)
CA (1) CA2235679C (https=)
DE (1) DE69631596T2 (https=)
DK (1) DK0861122T3 (https=)
DZ (1) DZ2120A1 (https=)
EA (1) EA000665B1 (https=)
ES (1) ES2211992T3 (https=)
MY (1) MY118875A (https=)
NO (1) NO315358B1 (https=)
NZ (1) NZ322009A (https=)
PE (1) PE31698A1 (https=)
WO (1) WO1997017137A1 (https=)
ZA (1) ZA969314B (https=)

Cited By (1)

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CN107405607A (zh) * 2014-12-12 2017-11-28 英国石油有限公司 使用还原钴催化剂的费‑托方法

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US5811363A (en) * 1997-05-02 1998-09-22 Exxon Research And Engineering Company Catalyst rejuvenation in hydrocarbon synthesis slurry with reduced slurry recontamination
US5817701A (en) * 1997-05-02 1998-10-06 Exxon Research And Engineering Company Slurry hydrocarbon synthesis with cyclic CO purge and catalyst rejuvenation
US5844005A (en) * 1997-05-02 1998-12-01 Exxon Research And Engineering Company Hydrocarbon synthesis using reactor tail gas for catalyst rejuvenation
US5817702A (en) * 1997-05-02 1998-10-06 Exxon Research And Engineering Company Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement
NZ504988A (en) * 1997-12-30 2001-08-31 Shell Int Research Cobalt and titania based fisher-tropsch catalyst
US5929126A (en) * 1998-01-30 1999-07-27 Exxon Research And Engineering Co. Gas conversion with rejuvenation ammonia removal
US6080301A (en) 1998-09-04 2000-06-27 Exxonmobil Research And Engineering Company Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins
US6475960B1 (en) 1998-09-04 2002-11-05 Exxonmobil Research And Engineering Co. Premium synthetic lubricants
DE19933348B4 (de) * 1999-07-16 2005-11-17 Oxeno Olefinchemie Gmbh Verfahren zur Reduzierung oxidischer Hydrierkontakte
US6486220B1 (en) 1999-11-17 2002-11-26 Conoco Inc. Regeneration procedure for Fischer-Tropsch catalyst
US6869978B2 (en) 1999-11-17 2005-03-22 Conocophillips Company Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst
FR2801228B1 (fr) * 1999-11-22 2001-12-28 Inst Francais Du Petrole Procede d'activation d'un catalyseur de synthese fischer tropsch
ATE299399T1 (de) * 2000-04-11 2005-07-15 Albemarle Netherlands Bv Verfahren zum aktivieren eines katalysators der ein schwefelenthaltendes additiv enthält
US6872678B2 (en) 2000-04-11 2005-03-29 Akzo Nobel N.V. Process for activating a catalyst containing an S-containing additive
GC0000360A (en) 2000-05-04 2007-03-31 Shell Int Research A catalyst support and a supported metal catalyst, a process for their preparation, and the use of the catalyst
US6696502B1 (en) * 2000-06-02 2004-02-24 Exxonmobil Research And Engineering Company Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production
US6323248B1 (en) * 2000-06-02 2001-11-27 Exxonmobil Research And Engineering Company Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production
MY122994A (en) 2000-07-03 2006-05-31 Shell Int Research Catalyst and process fo rthe preparation of hydrocarbons
EP1303351B1 (en) 2000-07-24 2004-03-03 Shell Internationale Researchmaatschappij B.V. A shell metal catalyst and a precursor thereof, a process for their preparation and the use of the catalyst
GB0109555D0 (en) * 2001-04-18 2001-06-06 Kvaerner Process Tech Ltd Process
WO2002092227A1 (en) * 2001-05-17 2002-11-21 Conocophillips Company Pressure swing catalyst regeneration procedure for fischer-tropsch catalyst
ATE298630T1 (de) 2001-10-25 2005-07-15 Sasol Tech Pty Ltd Verfahren zur aktivierung von cobaltkatalysatoren
US6900151B2 (en) * 2001-11-13 2005-05-31 Exxonmobil Research And Engineering Company In situ catalyst regeneration/activation process
US6949488B2 (en) * 2002-09-20 2005-09-27 Conocophillips Company Fischer-Tropsch catalyst regeneration
US6878655B2 (en) * 2002-09-20 2005-04-12 Conocophillips Company Method and apparatus for the regeneration of hydrocarbon synthesis catalysts
US7045554B2 (en) 2003-09-03 2006-05-16 Conocophillips Company Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion
ITMI20031777A1 (it) * 2003-09-18 2005-03-19 Enitecnologie Spa Procedimento per la gestione di un reattore adatto a reazioni eterogenee in combinazioni con reazioni che si realizzano in sistemi trifasici
DE102005050526A1 (de) * 2005-10-21 2007-04-26 Choren Industries Gmbh Verfahren zum Haltebetrieb einer Fischer-Tropsch-Synthese
CN101326145B (zh) 2005-12-09 2013-09-18 国际壳牌研究有限公司 由合成气制烃工艺的起动方法
CN101351528B (zh) * 2005-12-09 2015-11-25 国际壳牌研究有限公司 起动由合成气制备烃的工艺的方法
MY145837A (en) 2005-12-09 2012-04-30 Shell Int Research Method to start a process for producing hydrocarbons from synthesis gas
EA018794B1 (ru) * 2008-12-23 2013-10-30 Рентек, Инк. Способ активации катализатора в процессах фишера-тропша
JP5676120B2 (ja) * 2010-02-26 2015-02-25 Ｊｘ日鉱日石エネルギー株式会社 活性化フィッシャー・トロプシュ合成触媒の製造方法及び炭化水素の製造方法
GB201207716D0 (en) * 2012-05-02 2012-06-13 Compactgtl Plc Catalyst treatment process
RU2530890C1 (ru) * 2013-07-02 2014-10-20 Открытое акционерное общество "Электростальское научно-производственное объединение "Неорганика" (ОАО "ЭНПО "Неорганика") Способ получения катализатора окисления оксида углерода
CN105080570B (zh) * 2014-05-14 2017-10-27 中国石油化工股份有限公司 流化床合成气直接制备低碳烯烃铁基催化剂的再生方法
CN106190592B (zh) * 2015-04-29 2022-03-11 中国石油化工股份有限公司 一种生物柴油催化加氢制备生物润滑油的方法
AU2019239566A1 (en) * 2018-03-20 2020-09-24 Shell Internationale Research Maatschappij B.V. Preparation of a cobalt-containing catalyst
CN113181976B (zh) * 2021-03-30 2023-06-20 福建申远新材料有限公司 一种钯系催化剂活化方法

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107405607A (zh) * 2014-12-12 2017-11-28 英国石油有限公司 使用还原钴催化剂的费‑托方法
CN107405607B (zh) * 2014-12-12 2020-12-08 英国石油有限公司 使用还原钴催化剂的费-托方法

Also Published As

Publication number Publication date
EP0861122B1 (en) 2004-02-18
PE31698A1 (es) 1998-06-15
DE69631596D1 (de) 2004-03-25
ZA969314B (en) 1997-05-08
NO982086D0 (no) 1998-05-07
DK0861122T3 (da) 2004-05-03
BR9611350A (pt) 1999-04-06
ES2211992T3 (es) 2004-07-16
NZ322009A (en) 1999-09-29
CN1202119A (zh) 1998-12-16
MY118875A (en) 2005-02-28
KR19990067388A (ko) 1999-08-16
WO1997017137A1 (en) 1997-05-15
AU704027B2 (en) 1999-04-15
NO315358B1 (no) 2003-08-25
AU7567496A (en) 1997-05-29
MX9803451A (es) 1998-09-30
EA000665B1 (ru) 2000-02-28
CA2235679C (en) 2005-07-12
EA199800432A1 (ru) 1998-10-29
EP0861122A1 (en) 1998-09-02
JPH11514575A (ja) 1999-12-14
NO982086L (no) 1998-05-07
DZ2120A1 (fr) 2002-07-22
KR100447016B1 (ko) 2004-10-15
CA2235679A1 (en) 1997-05-15
DE69631596T2 (de) 2004-08-05

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