JPH11514575A - 触媒の活性化および再活性化方法 - Google Patents
触媒の活性化および再活性化方法Info
- Publication number
- JPH11514575A JPH11514575A JP9517861A JP51786197A JPH11514575A JP H11514575 A JPH11514575 A JP H11514575A JP 9517861 A JP9517861 A JP 9517861A JP 51786197 A JP51786197 A JP 51786197A JP H11514575 A JPH11514575 A JP H11514575A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- hydrogen
- hydrocarbon
- gas
- hydrocarbon synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 183
- 238000000034 method Methods 0.000 title claims abstract description 68
- 230000007420 reactivation Effects 0.000 title claims description 32
- 230000004913 activation Effects 0.000 title description 36
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 122
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 121
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 116
- 239000001257 hydrogen Substances 0.000 claims abstract description 116
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 116
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 111
- 239000007789 gas Substances 0.000 claims abstract description 92
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 70
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 70
- 239000007788 liquid Substances 0.000 claims abstract description 59
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 230000003213 activating effect Effects 0.000 claims abstract description 15
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 15
- 238000001308 synthesis method Methods 0.000 claims abstract description 5
- 230000008569 process Effects 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001869 cobalt compounds Chemical class 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000002002 slurry Substances 0.000 description 36
- 229910052751 metal Inorganic materials 0.000 description 19
- 239000002184 metal Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229910017052 cobalt Inorganic materials 0.000 description 13
- 239000010941 cobalt Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 description 12
- 238000004517 catalytic hydrocracking Methods 0.000 description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 12
- 238000006722 reduction reaction Methods 0.000 description 11
- 239000011261 inert gas Substances 0.000 description 10
- 230000009467 reduction Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 238000011065 in-situ storage Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000000571 coke Substances 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 208000036366 Sensation of pressure Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- -1 cobalt metal compound Chemical class 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
- B01J38/58—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids and gas addition thereto
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP95203040.1 | 1995-11-08 | ||
| EP95203040 | 1995-11-08 | ||
| PCT/EP1996/004879 WO1997017137A1 (en) | 1995-11-08 | 1996-11-06 | Catalyst activation and rejuvenation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11514575A true JPH11514575A (ja) | 1999-12-14 |
| JPH11514575A5 JPH11514575A5 (https=) | 2004-10-07 |
Family
ID=8220810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9517861A Ceased JPH11514575A (ja) | 1995-11-08 | 1996-11-06 | 触媒の活性化および再活性化方法 |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP0861122B1 (https=) |
| JP (1) | JPH11514575A (https=) |
| KR (1) | KR100447016B1 (https=) |
| CN (1) | CN1127376C (https=) |
| AU (1) | AU704027B2 (https=) |
| BR (1) | BR9611350A (https=) |
| CA (1) | CA2235679C (https=) |
| DE (1) | DE69631596T2 (https=) |
| DK (1) | DK0861122T3 (https=) |
| DZ (1) | DZ2120A1 (https=) |
| EA (1) | EA000665B1 (https=) |
| ES (1) | ES2211992T3 (https=) |
| MY (1) | MY118875A (https=) |
| NO (1) | NO315358B1 (https=) |
| NZ (1) | NZ322009A (https=) |
| PE (1) | PE31698A1 (https=) |
| WO (1) | WO1997017137A1 (https=) |
| ZA (1) | ZA969314B (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001524024A (ja) * | 1997-05-02 | 2001-11-27 | エクソン リサーチ アンド エンジニアリング カンパニー | 反応器テールガスを触媒再生に用いる炭化水素の合成方法 |
| JP2018505251A (ja) * | 2014-12-12 | 2018-02-22 | ビーピー ピー・エル・シー・ | 還元コバルト触媒を用いるフィッシャー−トロプシュ法 |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5811363A (en) * | 1997-05-02 | 1998-09-22 | Exxon Research And Engineering Company | Catalyst rejuvenation in hydrocarbon synthesis slurry with reduced slurry recontamination |
| US5817701A (en) * | 1997-05-02 | 1998-10-06 | Exxon Research And Engineering Company | Slurry hydrocarbon synthesis with cyclic CO purge and catalyst rejuvenation |
| US5817702A (en) * | 1997-05-02 | 1998-10-06 | Exxon Research And Engineering Company | Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement |
| NZ504988A (en) * | 1997-12-30 | 2001-08-31 | Shell Int Research | Cobalt and titania based fisher-tropsch catalyst |
| US5929126A (en) * | 1998-01-30 | 1999-07-27 | Exxon Research And Engineering Co. | Gas conversion with rejuvenation ammonia removal |
| US6080301A (en) | 1998-09-04 | 2000-06-27 | Exxonmobil Research And Engineering Company | Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins |
| US6475960B1 (en) | 1998-09-04 | 2002-11-05 | Exxonmobil Research And Engineering Co. | Premium synthetic lubricants |
| DE19933348B4 (de) * | 1999-07-16 | 2005-11-17 | Oxeno Olefinchemie Gmbh | Verfahren zur Reduzierung oxidischer Hydrierkontakte |
| US6486220B1 (en) | 1999-11-17 | 2002-11-26 | Conoco Inc. | Regeneration procedure for Fischer-Tropsch catalyst |
| US6869978B2 (en) | 1999-11-17 | 2005-03-22 | Conocophillips Company | Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst |
| FR2801228B1 (fr) * | 1999-11-22 | 2001-12-28 | Inst Francais Du Petrole | Procede d'activation d'un catalyseur de synthese fischer tropsch |
| ATE299399T1 (de) * | 2000-04-11 | 2005-07-15 | Albemarle Netherlands Bv | Verfahren zum aktivieren eines katalysators der ein schwefelenthaltendes additiv enthält |
| US6872678B2 (en) | 2000-04-11 | 2005-03-29 | Akzo Nobel N.V. | Process for activating a catalyst containing an S-containing additive |
| GC0000360A (en) | 2000-05-04 | 2007-03-31 | Shell Int Research | A catalyst support and a supported metal catalyst, a process for their preparation, and the use of the catalyst |
| US6696502B1 (en) * | 2000-06-02 | 2004-02-24 | Exxonmobil Research And Engineering Company | Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production |
| US6323248B1 (en) * | 2000-06-02 | 2001-11-27 | Exxonmobil Research And Engineering Company | Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production |
| MY122994A (en) | 2000-07-03 | 2006-05-31 | Shell Int Research | Catalyst and process fo rthe preparation of hydrocarbons |
| EP1303351B1 (en) | 2000-07-24 | 2004-03-03 | Shell Internationale Researchmaatschappij B.V. | A shell metal catalyst and a precursor thereof, a process for their preparation and the use of the catalyst |
| GB0109555D0 (en) * | 2001-04-18 | 2001-06-06 | Kvaerner Process Tech Ltd | Process |
| WO2002092227A1 (en) * | 2001-05-17 | 2002-11-21 | Conocophillips Company | Pressure swing catalyst regeneration procedure for fischer-tropsch catalyst |
| ATE298630T1 (de) | 2001-10-25 | 2005-07-15 | Sasol Tech Pty Ltd | Verfahren zur aktivierung von cobaltkatalysatoren |
| US6900151B2 (en) * | 2001-11-13 | 2005-05-31 | Exxonmobil Research And Engineering Company | In situ catalyst regeneration/activation process |
| US6949488B2 (en) * | 2002-09-20 | 2005-09-27 | Conocophillips Company | Fischer-Tropsch catalyst regeneration |
| US6878655B2 (en) * | 2002-09-20 | 2005-04-12 | Conocophillips Company | Method and apparatus for the regeneration of hydrocarbon synthesis catalysts |
| US7045554B2 (en) | 2003-09-03 | 2006-05-16 | Conocophillips Company | Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion |
| ITMI20031777A1 (it) * | 2003-09-18 | 2005-03-19 | Enitecnologie Spa | Procedimento per la gestione di un reattore adatto a reazioni eterogenee in combinazioni con reazioni che si realizzano in sistemi trifasici |
| DE102005050526A1 (de) * | 2005-10-21 | 2007-04-26 | Choren Industries Gmbh | Verfahren zum Haltebetrieb einer Fischer-Tropsch-Synthese |
| CN101326145B (zh) | 2005-12-09 | 2013-09-18 | 国际壳牌研究有限公司 | 由合成气制烃工艺的起动方法 |
| CN101351528B (zh) * | 2005-12-09 | 2015-11-25 | 国际壳牌研究有限公司 | 起动由合成气制备烃的工艺的方法 |
| MY145837A (en) | 2005-12-09 | 2012-04-30 | Shell Int Research | Method to start a process for producing hydrocarbons from synthesis gas |
| EA018794B1 (ru) * | 2008-12-23 | 2013-10-30 | Рентек, Инк. | Способ активации катализатора в процессах фишера-тропша |
| JP5676120B2 (ja) * | 2010-02-26 | 2015-02-25 | Ｊｘ日鉱日石エネルギー株式会社 | 活性化フィッシャー・トロプシュ合成触媒の製造方法及び炭化水素の製造方法 |
| GB201207716D0 (en) * | 2012-05-02 | 2012-06-13 | Compactgtl Plc | Catalyst treatment process |
| RU2530890C1 (ru) * | 2013-07-02 | 2014-10-20 | Открытое акционерное общество "Электростальское научно-производственное объединение "Неорганика" (ОАО "ЭНПО "Неорганика") | Способ получения катализатора окисления оксида углерода |
| CN105080570B (zh) * | 2014-05-14 | 2017-10-27 | 中国石油化工股份有限公司 | 流化床合成气直接制备低碳烯烃铁基催化剂的再生方法 |
| CN106190592B (zh) * | 2015-04-29 | 2022-03-11 | 中国石油化工股份有限公司 | 一种生物柴油催化加氢制备生物润滑油的方法 |
| AU2019239566A1 (en) * | 2018-03-20 | 2020-09-24 | Shell Internationale Research Maatschappij B.V. | Preparation of a cobalt-containing catalyst |
| CN113181976B (zh) * | 2021-03-30 | 2023-06-20 | 福建申远新材料有限公司 | 一种钯系催化剂活化方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4331544A (en) * | 1980-02-01 | 1982-05-25 | Director-General Of The Agency Of Industrial Science And Technology | Catalyst for methanation and method for the preparation thereof |
| JPS61162956A (ja) * | 1985-01-11 | 1986-07-23 | 東レ株式会社 | リ−クバル−ンカテ−テル |
| DE3524330A1 (de) * | 1985-07-08 | 1987-01-08 | Basf Ag | Verfahren zur herstellung von katalysatoren und ihre verwendung bei hydrier- und aminierreaktionen |
| US5283216A (en) * | 1992-09-24 | 1994-02-01 | Exxon Research And Engineering Company | Rejuvenation of hydrocarbon synthesis catalyst |
| US5292705A (en) * | 1992-09-24 | 1994-03-08 | Exxon Research & Engineering Co. | Activation of hydrocarbon synthesis catalyst |
| US5268344A (en) * | 1992-12-18 | 1993-12-07 | Exxon Research & Engineering Company | Draft tube for catalyst rejuvenation and distribution |
-
1996
- 1996-11-05 PE PE1996000769A patent/PE31698A1/es not_active Application Discontinuation
- 1996-11-06 AU AU75674/96A patent/AU704027B2/en not_active Ceased
- 1996-11-06 CN CN96198191A patent/CN1127376C/zh not_active Expired - Fee Related
- 1996-11-06 EP EP96938142A patent/EP0861122B1/en not_active Revoked
- 1996-11-06 WO PCT/EP1996/004879 patent/WO1997017137A1/en not_active Ceased
- 1996-11-06 EA EA199800432A patent/EA000665B1/ru not_active IP Right Cessation
- 1996-11-06 ZA ZA969314A patent/ZA969314B/xx unknown
- 1996-11-06 DZ DZ960164A patent/DZ2120A1/fr active
- 1996-11-06 ES ES96938142T patent/ES2211992T3/es not_active Expired - Lifetime
- 1996-11-06 CA CA002235679A patent/CA2235679C/en not_active Expired - Fee Related
- 1996-11-06 DE DE69631596T patent/DE69631596T2/de not_active Expired - Lifetime
- 1996-11-06 KR KR10-1998-0703398A patent/KR100447016B1/ko not_active Expired - Fee Related
- 1996-11-06 JP JP9517861A patent/JPH11514575A/ja not_active Ceased
- 1996-11-06 MY MYPI96004613A patent/MY118875A/en unknown
- 1996-11-06 BR BR9611350A patent/BR9611350A/pt not_active Application Discontinuation
- 1996-11-06 DK DK96938142T patent/DK0861122T3/da active
- 1996-11-06 NZ NZ322009A patent/NZ322009A/en unknown
-
1998
- 1998-05-07 NO NO19982086A patent/NO315358B1/no not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001524024A (ja) * | 1997-05-02 | 2001-11-27 | エクソン リサーチ アンド エンジニアリング カンパニー | 反応器テールガスを触媒再生に用いる炭化水素の合成方法 |
| JP2018505251A (ja) * | 2014-12-12 | 2018-02-22 | ビーピー ピー・エル・シー・ | 還元コバルト触媒を用いるフィッシャー−トロプシュ法 |
| JP2021006637A (ja) * | 2014-12-12 | 2021-01-21 | ビーピー ピー・エル・シー・ | 還元コバルト触媒を用いるフィッシャー−トロプシュ法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0861122B1 (en) | 2004-02-18 |
| PE31698A1 (es) | 1998-06-15 |
| DE69631596D1 (de) | 2004-03-25 |
| ZA969314B (en) | 1997-05-08 |
| NO982086D0 (no) | 1998-05-07 |
| DK0861122T3 (da) | 2004-05-03 |
| BR9611350A (pt) | 1999-04-06 |
| ES2211992T3 (es) | 2004-07-16 |
| NZ322009A (en) | 1999-09-29 |
| CN1202119A (zh) | 1998-12-16 |
| MY118875A (en) | 2005-02-28 |
| KR19990067388A (ko) | 1999-08-16 |
| WO1997017137A1 (en) | 1997-05-15 |
| CN1127376C (zh) | 2003-11-12 |
| AU704027B2 (en) | 1999-04-15 |
| NO315358B1 (no) | 2003-08-25 |
| AU7567496A (en) | 1997-05-29 |
| MX9803451A (es) | 1998-09-30 |
| EA000665B1 (ru) | 2000-02-28 |
| CA2235679C (en) | 2005-07-12 |
| EA199800432A1 (ru) | 1998-10-29 |
| EP0861122A1 (en) | 1998-09-02 |
| NO982086L (no) | 1998-05-07 |
| DZ2120A1 (fr) | 2002-07-22 |
| KR100447016B1 (ko) | 2004-10-15 |
| CA2235679A1 (en) | 1997-05-15 |
| DE69631596T2 (de) | 2004-08-05 |
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