CN109364983A - 用于丙烯生产的双重催化剂体系 - Google Patents

用于丙烯生产的双重催化剂体系 Download PDF

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CN109364983A
CN109364983A CN201811179717.1A CN201811179717A CN109364983A CN 109364983 A CN109364983 A CN 109364983A CN 201811179717 A CN201811179717 A CN 201811179717A CN 109364983 A CN109364983 A CN 109364983A
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Prior art keywords
catalyst
dual
mfi
catalyst system
metathesis
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CN201811179717.1A
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Chinese (zh)
Inventor
阿鲁德拉·帕拉尼
塔兹·伊斯兰·布延
索赫尔·谢赫
穆罕默德·纳西姆·阿赫塔尔
阿布杜拉·M·埃塔尼
苏莱曼·萨利赫·阿尔-哈塔夫
穆罕默德·A·阿尔-雅美
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Saudi Arabian Oil Co
King Fahd University of Petroleum and Minerals
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Saudi Arabian Oil Co
King Fahd University of Petroleum and Minerals
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Publication of CN109364983A publication Critical patent/CN109364983A/zh
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Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3317014B1 (en) 2015-07-02 2022-03-02 Saudi Arabian Oil Company Propylene production using a mesoporous silica foam metathesis catalyst
SG10201913486WA (en) 2015-07-02 2020-02-27 Saudi Arabian Oil Co Systems and methods for producing propylene
CN109364983A (zh) 2015-07-02 2019-02-22 沙特阿拉伯石油公司 用于丙烯生产的双重催化剂体系
KR102387487B1 (ko) 2015-07-02 2022-04-18 사우디 아라비안 오일 컴퍼니 프로필렌을 제조하기 위한 시스템 및 방법
US10329225B2 (en) * 2017-01-20 2019-06-25 Saudi Arabian Oil Company Dual catalyst processes and systems for propylene production
US10550048B2 (en) * 2017-01-20 2020-02-04 Saudi Arabian Oil Company Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking
US10934231B2 (en) * 2017-01-20 2021-03-02 Saudi Arabian Oil Company Multiple-stage catalyst systems and processes for propene production
FR3068967B1 (fr) * 2017-07-13 2019-06-28 IFP Energies Nouvelles Methode et procede pour convertir l'ethylene present dans l'effluent de tete d'un fcc de maniere a augmenter la production de propylene
US11369950B2 (en) * 2018-02-21 2022-06-28 Saudi Arabian Oil Company Multi-functional composite catalyst materials and methods of synthesizing the catalyst materials
US10961171B2 (en) 2018-10-10 2021-03-30 Saudi Arabian Oil Company Catalysts systems that include metal co-catalysts for the production of propylene
US11242299B2 (en) 2018-10-10 2022-02-08 Saudi Arabian Oil Company Catalyst systems that include metal oxide co-catalysts for the production of propylene
CN111085207A (zh) * 2018-10-24 2020-05-01 中国石油化工股份有限公司 载体为球形三介孔复合材料的非贵金属系低碳烷烃脱氢催化剂及其制法和应用
US10975004B2 (en) 2019-01-03 2021-04-13 Saudi Arabian Oil Company Integrated process for production of ethylene from propylene
EP3941621A1 (en) * 2019-03-18 2022-01-26 ExxonMobil Research and Engineering Company Mesoporous catalyst compounds and uses thereof
CN112387302B (zh) * 2019-08-13 2023-05-30 中国石油化工股份有限公司 催化裂化助剂及其制备方法和应用及烃油催化裂化的方法
US11185850B2 (en) * 2019-12-02 2021-11-30 Saudi Arabian Oil Company Dual functional composite catalyst for olefin metathesis and cracking
US11311869B2 (en) 2019-12-03 2022-04-26 Saudi Arabian Oil Company Methods of producing isomerization catalysts
US11517892B2 (en) 2019-12-03 2022-12-06 Saudi Arabian Oil Company Methods of producing isomerization catalysts
US11339332B2 (en) 2020-01-29 2022-05-24 Saudi Arabian Oil Company Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins
CN113304786B (zh) * 2020-02-27 2023-05-30 中国石油化工股份有限公司 含有二氯二甲基硅烷改性全硅介孔材料的催化裂化助剂及其制备方法和应用
US11572516B2 (en) 2020-03-26 2023-02-07 Saudi Arabian Oil Company Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins
CN115427378A (zh) * 2020-04-22 2022-12-02 利安德化学技术有限公司 由丁烯生产专用丙烯
CN116075493A (zh) 2020-09-15 2023-05-05 利安德化学技术有限公司 用于将萃余液丁烯转化为丙烯的方法
US11679378B2 (en) 2021-02-25 2023-06-20 Saudi Arabian Oil Company Methods of producing isomerization catalysts
US11845705B2 (en) 2021-08-17 2023-12-19 Saudi Arabian Oil Company Processes integrating hydrocarbon cracking with metathesis for producing propene
US20250018381A1 (en) * 2022-04-07 2025-01-16 Ptt Global Chemical Public Company Limited A catalyst for light olefins production and a process of light olefins production by using a catalyst thereof
USD1040950S1 (en) * 2022-11-07 2024-09-03 Wolf Fitness, LLC Barbell jack

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102177223A (zh) * 2008-08-12 2011-09-07 鲁姆斯科技公司 结合的丙烯生产

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3442821A (en) 1966-09-29 1969-05-06 Universal Oil Prod Co Manufacture of spheroidal silica-alumina particles
NL135562C (https=) 1967-04-03
US3546313A (en) 1967-04-03 1970-12-08 Phillips Petroleum Co Conversion of olefins
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
GB1489300A (en) 1974-08-26 1977-10-19 Agency Ind Science Techn Process for the selective disproportionation reaction of olefins
US4071471A (en) 1974-12-23 1978-01-31 Phillips Petroleum Company Catalysts for conversion of olefins
EP0304515B1 (en) 1983-03-10 1991-12-04 The Dow Chemical Company A process for the disproportionation of alkenes
US4609769A (en) * 1984-02-15 1986-09-02 Phillips Petroleum Company Olefin conversion
US4575575A (en) 1984-04-05 1986-03-11 Phillips Petroleum Company Catalysts and process for olefin conversion
US5191131A (en) 1988-12-05 1993-03-02 Research Association For Utilization Of Light Oil Process for preparation of lower aliphatic hydrocarbons
US5026935A (en) 1989-10-02 1991-06-25 Arco Chemical Technology, Inc. Enhanced production of ethylene from higher hydrocarbons
US5026936A (en) 1989-10-02 1991-06-25 Arco Chemical Technology, Inc. Enhanced production of propylene from higher hydrocarbons
FR2733986B1 (fr) * 1995-05-11 1997-06-13 Inst Francais Du Petrole Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene
DE19746040A1 (de) 1997-10-17 1999-04-22 Basf Ag Verfahren zur Herstellung von Propen
EP0921181A1 (en) * 1997-12-05 1999-06-09 Fina Research S.A. Production of propylene
EP0920911A1 (en) * 1997-12-05 1999-06-09 Fina Research S.A. Production of catalysts for olefin conversion
US6586649B1 (en) 1998-09-04 2003-07-01 Sasol Technology (Proprietary) Limited Production of propylene
DK1194236T4 (da) 1999-05-20 2008-11-24 Exxonmobil Chem Patents Inc Metalholdige makrostrukturer af poröst uorganisk oxid, fremstilling deraf og anvendelse
DE19932060A1 (de) 1999-07-12 2001-01-18 Basf Ag Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen
DE10013253A1 (de) 2000-03-17 2001-09-20 Basf Ag Verfahren zur flexiblen Herstellung von Propen und Hexen
EP1434752A2 (de) 2001-10-01 2004-07-07 Basf Aktiengesellschaft Verfahren zur herstellung von alkylarylverbindungen und sulfonaten davon
US6777582B2 (en) 2002-03-07 2004-08-17 Abb Lummus Global Inc. Process for producing propylene and hexene from C4 olefin streams
CN100402148C (zh) 2002-08-16 2008-07-16 Sasol技术股份有限公司 复分解催化剂及方法
DE10319439A1 (de) 2003-04-30 2004-11-18 Basf Ag Aktivierte Metathesekatalysatoren
US7214841B2 (en) 2003-07-15 2007-05-08 Abb Lummus Global Inc. Processing C4 olefin streams for the maximum production of propylene
ITMI20040855A1 (it) 2004-04-29 2004-07-29 Polimeri Europa Spa Catalizzatore di renio supportato su allimuna modificata e suo impiego nella reazione di metatesi delle olefine
KR100881042B1 (ko) 2004-07-16 2009-02-05 아사히 가세이 케미칼즈 가부시키가이샤 에틸렌 및 프로필렌 제조 방법
DE102005009596A1 (de) 2005-02-28 2006-08-31 Basf Ag Verfahren zur Metathese umfassend die Reinigung der Ausgangsstoffe
KR100912882B1 (ko) 2005-03-03 2009-08-20 미쓰이 가가쿠 가부시키가이샤 올레핀류의 제조 방법
US7692057B2 (en) * 2005-08-15 2010-04-06 China Petroleum & Chemical Corporation Process for producing lower olefins by using multiple reaction zones
EP2010318B1 (en) 2006-04-11 2014-04-02 Agency for Science, Technology and Research Catalysts for ring closing metathesis
EP2029638A1 (de) 2006-06-06 2009-03-04 Basf Se Herstellung reaktiver, im wesentlichen halogenfreier polyisobutene aus isobuten-armen c4-kohlenwasserstoff-gemischen
EP2097167A2 (en) 2006-12-12 2009-09-09 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
MY146409A (en) * 2007-04-27 2012-08-15 Mitsui Chemicals Inc Process for producing olefins
CN101531558B (zh) 2008-03-13 2013-04-24 中国石油化工股份有限公司 一种制取丙烯和芳烃的催化转化方法
US20090240010A1 (en) 2008-03-20 2009-09-24 Mcdaniel Max P Alumina-silica activator-supports for metallocene catalyst compositions
CN102131752A (zh) 2008-08-28 2011-07-20 三井化学株式会社 烯烃制造方法
KR101272392B1 (ko) 2008-09-04 2013-06-07 바스프 코포레이션 올레핀 이성질화 및 복분해 촉매
US8119849B2 (en) 2008-12-29 2012-02-21 Lyondell Chemical Technology, L.P. Propylene production
US8586813B2 (en) 2009-07-21 2013-11-19 Lummus Technology Inc. Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization
US8895795B2 (en) 2010-02-05 2014-11-25 Uop Llc Acid washed silica supported catalysts and their use in olefin metathesis
US8324440B2 (en) 2010-02-05 2012-12-04 Uop Llc Support properties of silica supported catalysts and their use in olefin metathesis
AR080682A1 (es) 2010-03-15 2012-05-02 Total Petrochemicals Res Feluy Produccion de propileno por deshidratacion e isomerizacion esqueletica simultaneas de isobutanol en catalizadores acidos seguido por metatesis
US8722950B2 (en) 2010-04-26 2014-05-13 Saudi Basic Industries Corporation Process for producing propylene and aromatics from butenes by metathesis and aromatization
US9079159B2 (en) 2011-04-14 2015-07-14 Uop Llc Olefin metathesis process using a treated tungsten oxide catalyst
US20120289617A1 (en) 2011-05-10 2012-11-15 Saudi Arabian Oil Company Hybrid Catalyst for Olefin Metathesis
KR101262549B1 (ko) * 2011-09-29 2013-05-09 롯데케미칼 주식회사 중형기공성 zsm-5 촉매 제조방법 및 그 촉매를 이용한 경질 올레핀 제조방법
KR101279691B1 (ko) * 2011-11-29 2013-06-28 롯데케미칼 주식회사 미세 및 중형기공성 zsm-5 촉매, 이의 제조방법 및 그 촉매를 이용한 탄화수소 혼합물의 촉매 접촉분해를 통한 경질 올레핀 제조방법
US20130085311A1 (en) * 2011-09-29 2013-04-04 Honam Petrochemical Corporation Zsm-5 catalyst with micropores and mesopores, preparation method thereof and production method of light olefins through catalytic cracking of hydrocarbons using the catalyst
US8575406B2 (en) 2011-12-22 2013-11-05 Celanese International Corporation Catalysts having promoter metals and process for producing ethanol
EP2862629A1 (en) 2013-10-15 2015-04-22 Borealis AG Catalyst and process for olefin metathesis reaction
WO2015077338A1 (en) 2013-11-20 2015-05-28 Lummus Technology Inc. Olefin conversion process
CN104370676B (zh) 2014-11-11 2016-06-08 中国石油天然气集团公司 一种以碳四烯烃为原料生产丙烯副产乙烯的方法
EP3317014B1 (en) 2015-07-02 2022-03-02 Saudi Arabian Oil Company Propylene production using a mesoporous silica foam metathesis catalyst
KR102387487B1 (ko) 2015-07-02 2022-04-18 사우디 아라비안 오일 컴퍼니 프로필렌을 제조하기 위한 시스템 및 방법
SG10201913486WA (en) 2015-07-02 2020-02-27 Saudi Arabian Oil Co Systems and methods for producing propylene
CN109364983A (zh) 2015-07-02 2019-02-22 沙特阿拉伯石油公司 用于丙烯生产的双重催化剂体系

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102177223A (zh) * 2008-08-12 2011-09-07 鲁姆斯科技公司 结合的丙烯生产

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BIN HU, ET AL.: "Highly active doped mesoporous KIT-6 catalysts for metathesis of 1-butene and ethene to propene: The influence of neighboring environment of W species", 《J. PHYS. CHEM. C》 *

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