CN1093138C - 由非水解方式形成的聚烷基铝氧烷组合物 - Google Patents

由非水解方式形成的聚烷基铝氧烷组合物 Download PDF

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Publication number
CN1093138C
CN1093138C CN96180050A CN96180050A CN1093138C CN 1093138 C CN1093138 C CN 1093138C CN 96180050 A CN96180050 A CN 96180050A CN 96180050 A CN96180050 A CN 96180050A CN 1093138 C CN1093138 C CN 1093138C
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prepared
aluminoxane
composition
polymethylaluminoxane
carbon
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Expired - Lifetime
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Chinese (zh)
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CN1209080A (zh
Inventor
G·M·史密斯
S·W·帕尔马卡
J·S·罗杰斯
D·B·马尔帕斯
D·J·蒙菲斯顿
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Akzo Nobel NV
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
CN96180050A 1995-12-22 1996-12-18 由非水解方式形成的聚烷基铝氧烷组合物 Expired - Lifetime CN1093138C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/576,892 US5831109A (en) 1995-12-22 1995-12-22 Polyalkylaluminoxane compositions formed by non-hydrolytic means
US08/576,892 1995-12-22

Publications (2)

Publication Number Publication Date
CN1209080A CN1209080A (zh) 1999-02-24
CN1093138C true CN1093138C (zh) 2002-10-23

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CN96180050A Expired - Lifetime CN1093138C (zh) 1995-12-22 1996-12-18 由非水解方式形成的聚烷基铝氧烷组合物

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Country Link
US (1) US5831109A (enExample)
EP (1) EP0966322B1 (enExample)
JP (1) JP4112005B2 (enExample)
KR (1) KR100417968B1 (enExample)
CN (1) CN1093138C (enExample)
AT (1) ATE289868T1 (enExample)
AU (1) AU1421097A (enExample)
DE (1) DE69634424T2 (enExample)
ES (1) ES2238701T3 (enExample)
TW (1) TW581768B (enExample)
WO (1) WO1997023288A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
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CN103182156A (zh) * 2011-12-28 2013-07-03 中国石油天然气股份有限公司 烷基铝生产过程中危险废弃物的回收处理方法

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US6127302A (en) * 1997-12-09 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US5962362A (en) * 1997-12-09 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6159889A (en) * 1997-12-09 2000-12-12 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
US6153550A (en) * 1997-12-18 2000-11-28 Mobile Oil Corporation Olefin polymerization catalyst based on metallocene complexes and perfluorinated oligoaryl derivatives of aluminates
US6013820A (en) * 1998-03-18 2000-01-11 Albemarle Corporation Alkylaluminoxane compositions and their preparation
US6936306B1 (en) 1998-03-30 2005-08-30 William Marsh Rice University Chemical control over ceramic porosity using carboxylate-alumoxanes
US6369183B1 (en) 1998-08-13 2002-04-09 Wm. Marsh Rice University Methods and materials for fabrication of alumoxane polymers
US7220804B1 (en) * 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6518445B1 (en) 2000-12-15 2003-02-11 Albemarle Corporation Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof
CA2473934C (en) 2002-01-24 2011-01-04 William Marsh Rice University Ferroxanes, membranes and ceramics made therefrom
EP1348722A1 (fr) * 2002-03-25 2003-10-01 SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) Procédé pour la polymérisation des alpha-oléfines
US7244498B2 (en) 2002-06-12 2007-07-17 Tda Research, Inc. Nanoparticles modified with multiple organic acids
US6933046B1 (en) 2002-06-12 2005-08-23 Tda Research, Inc. Releasable corrosion inhibitor compositions
US6887517B1 (en) 2002-06-12 2005-05-03 Tda Research Surface modified particles by multi-step Michael-type addition and process for the preparation thereof
US6986943B1 (en) 2002-06-12 2006-01-17 Tda Research, Inc. Surface modified particles by multi-step addition and process for the preparation thereof
US7193100B2 (en) * 2003-12-31 2007-03-20 Albemarle Corporation Haloaluminoxane compositions, their preparation, and their use in catalysis
JP4476657B2 (ja) * 2004-03-22 2010-06-09 東ソー・ファインケム株式会社 ポリメチルアルミノキサン調製物、その製造方法、重合触媒およびオレフィン類の重合方法
FR2917308B1 (fr) * 2007-06-18 2009-12-04 Centre Nat Rech Scient Systeme catalytique, procede de fabrication et utilisation
CN102239187B (zh) 2008-11-11 2014-04-30 东曹精细化工株式会社 固体状聚甲基铝氧烷组合物及其制造方法
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
KR101812365B1 (ko) 2010-05-11 2017-12-26 토소 화인켐 가부시키가이샤 고체 형태 담체-폴리메틸알루미녹산 복합체, 그 제조 방법, 올레핀류의 중합 촉매 및 폴리올레핀류의 제조 방법
CA2737713C (en) * 2011-04-20 2018-10-30 Nova Chemicals Corporation Activation for oligomerization
KR102009005B1 (ko) 2012-03-28 2019-10-23 토소 화인켐 가부시키가이샤 작은 입자 직경을 갖는 고체상 폴리메틸알루미녹산 조성물의 제조방법
CN109369830A (zh) * 2012-07-11 2019-02-22 亚培烯科技（杭州）有限公司 固体活化剂体系及其制备方法
CN104968668B (zh) * 2013-02-08 2017-11-17 三井化学株式会社 固体状聚铝氧烷组合物、烯烃聚合用催化剂、烯烃聚合物的制造方法及固体状聚铝氧烷组合物的制造方法
PL3063155T3 (pl) 2013-10-28 2018-02-28 Akzo Nobel Chemicals International B.V. Sposób wytwarzania aluminoksanów
WO2016170017A1 (en) 2015-04-24 2016-10-27 Akzo Nobel Chemicals International B.V. Process to prepare aluminoxanes
WO2017175766A1 (ja) * 2016-04-05 2017-10-12 東ソー・ファインケム株式会社 固体状ｐｍａｏ組成物およびその製造方法
JP6940939B2 (ja) * 2016-09-21 2021-09-29 大日本印刷株式会社 パターン形成方法及び凹凸構造体の製造方法
SG11202001743RA (en) * 2017-10-31 2020-05-28 Exxonmobil Chemical Patents Inc Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
JP7216958B2 (ja) * 2019-02-28 2023-02-02 国立大学法人広島大学 高純度固体アルミノキサン及びその製造方法
US20220275113A1 (en) * 2019-09-30 2022-09-01 Lg Chem, Ltd. Method for Purifying Polyalkylaluminoxane-Containing Solution Using Hydroxy Group-Containing Compound and Catalyst Composition Using the Same
CN111662398A (zh) * 2020-06-19 2020-09-15 上海东化环境工程有限公司 一种改性烷基铝氧烷、制备方法及用于聚烯烃聚合反应的催化剂
CN116670146A (zh) 2020-11-23 2023-08-29 埃克森美孚化学专利公司 使用不含芳族溶剂的载体制备的茂金属聚丙烯
CN116490510A (zh) 2020-11-23 2023-07-25 埃克森美孚化学专利公司 Smao和催化剂的非水解制备
WO2022108971A1 (en) 2020-11-23 2022-05-27 Exxonmobil Chemical Patents Inc. Toluene free supported methylalumoxane precursor
US20240018278A1 (en) 2020-11-23 2024-01-18 ExxonMobil Technology and Engineering Company-Chem Improved Process to Prepare Catalyst from In-Situ Formed Alumoxane

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DE3240383A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
WO1989002453A1 (en) * 1987-08-31 1989-03-23 Dow Chemical Co Preparation of polyhydrocarbylaluminoxanes
US5066631A (en) * 1990-10-16 1991-11-19 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds
US5235081A (en) * 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes

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Publication number Priority date Publication date Assignee Title
CN103182156A (zh) * 2011-12-28 2013-07-03 中国石油天然气股份有限公司 烷基铝生产过程中危险废弃物的回收处理方法

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DE69634424T2 (de) 2006-05-11
DE69634424D1 (de) 2005-04-07
AU1421097A (en) 1997-07-17
EP0966322B1 (en) 2005-03-02
JP4112005B2 (ja) 2008-07-02
US5831109A (en) 1998-11-03
WO1997023288A1 (en) 1997-07-03
HK1018419A1 (en) 1999-12-24
ES2238701T3 (es) 2005-09-01
KR100417968B1 (ko) 2004-03-19
EP0966322A1 (en) 1999-12-29
EP0966322A4 (en) 2000-06-28
TW581768B (en) 2004-04-01
ATE289868T1 (de) 2005-03-15
CN1209080A (zh) 1999-02-24
JP2000505785A (ja) 2000-05-16
KR19990076769A (ko) 1999-10-15

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