TW581768B - Polyalkylaluminoxane compositions formed by non-hydrolytic means - Google Patents

Polyalkylaluminoxane compositions formed by non-hydrolytic means Download PDF

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Publication number
TW581768B
TW581768B TW086106014A TW86106014A TW581768B TW 581768 B TW581768 B TW 581768B TW 086106014 A TW086106014 A TW 086106014A TW 86106014 A TW86106014 A TW 86106014A TW 581768 B TW581768 B TW 581768B
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TW
Taiwan
Prior art keywords
patent application
oxygen
composition
catalyst
aluminum
Prior art date
Application number
TW086106014A
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English (en)
Chinese (zh)
Inventor
Gregory M Smith
Stanley W Palmaka
Johnathan S Rogers
Dennis B Malpass
Daniel J Monfiston
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Akzo Nobel Nv
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Publication of TW581768B publication Critical patent/TW581768B/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
TW086106014A 1995-12-22 1997-05-06 Polyalkylaluminoxane compositions formed by non-hydrolytic means TW581768B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/576,892 US5831109A (en) 1995-12-22 1995-12-22 Polyalkylaluminoxane compositions formed by non-hydrolytic means

Publications (1)

Publication Number Publication Date
TW581768B true TW581768B (en) 2004-04-01

Family

ID=24306444

Family Applications (1)

Application Number Title Priority Date Filing Date
TW086106014A TW581768B (en) 1995-12-22 1997-05-06 Polyalkylaluminoxane compositions formed by non-hydrolytic means

Country Status (11)

Country Link
US (1) US5831109A (enExample)
EP (1) EP0966322B1 (enExample)
JP (1) JP4112005B2 (enExample)
KR (1) KR100417968B1 (enExample)
CN (1) CN1093138C (enExample)
AT (1) ATE289868T1 (enExample)
AU (1) AU1421097A (enExample)
DE (1) DE69634424T2 (enExample)
ES (1) ES2238701T3 (enExample)
TW (1) TW581768B (enExample)
WO (1) WO1997023288A1 (enExample)

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US6127302A (en) * 1997-12-09 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US5962362A (en) * 1997-12-09 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6159889A (en) * 1997-12-09 2000-12-12 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6153550A (en) * 1997-12-18 2000-11-28 Mobile Oil Corporation Olefin polymerization catalyst based on metallocene complexes and perfluorinated oligoaryl derivatives of aluminates
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
US6013820A (en) * 1998-03-18 2000-01-11 Albemarle Corporation Alkylaluminoxane compositions and their preparation
US6936306B1 (en) 1998-03-30 2005-08-30 William Marsh Rice University Chemical control over ceramic porosity using carboxylate-alumoxanes
US6369183B1 (en) 1998-08-13 2002-04-09 Wm. Marsh Rice University Methods and materials for fabrication of alumoxane polymers
US7220804B1 (en) * 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6518445B1 (en) 2000-12-15 2003-02-11 Albemarle Corporation Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof
WO2003062140A2 (en) 2002-01-24 2003-07-31 William Marsh Rice University Organic acid-feooh (ferroxane) particles and ferroxane-derived ceramics and ceramic membranes
EP1348722A1 (fr) * 2002-03-25 2003-10-01 SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) Procédé pour la polymérisation des alpha-oléfines
US6887517B1 (en) 2002-06-12 2005-05-03 Tda Research Surface modified particles by multi-step Michael-type addition and process for the preparation thereof
US7244498B2 (en) 2002-06-12 2007-07-17 Tda Research, Inc. Nanoparticles modified with multiple organic acids
US6986943B1 (en) 2002-06-12 2006-01-17 Tda Research, Inc. Surface modified particles by multi-step addition and process for the preparation thereof
US6933046B1 (en) 2002-06-12 2005-08-23 Tda Research, Inc. Releasable corrosion inhibitor compositions
US7193100B2 (en) * 2003-12-31 2007-03-20 Albemarle Corporation Haloaluminoxane compositions, their preparation, and their use in catalysis
JP4476657B2 (ja) * 2004-03-22 2010-06-09 東ソー・ファインケム株式会社 ポリメチルアルミノキサン調製物、その製造方法、重合触媒およびオレフィン類の重合方法
FR2917308B1 (fr) * 2007-06-18 2009-12-04 Centre Nat Rech Scient Systeme catalytique, procede de fabrication et utilisation
US8404880B2 (en) 2008-11-11 2013-03-26 Tosoh Finechem Corporation Solid polymethylaluminoxane composition and method for manufacturing same
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
US8975209B2 (en) 2010-05-11 2015-03-10 Tosoh Finechem Corporation Solid support-polymethylaluminoxane complex, method for producing same, olefin polymerization catalyst, and method for producing polyolefin
CA2737713C (en) * 2011-04-20 2018-10-30 Nova Chemicals Corporation Activation for oligomerization
CN103182156B (zh) * 2011-12-28 2016-04-06 中国石油天然气股份有限公司 烷基铝生产过程中危险废弃物的回收处理方法
EP2862889B1 (en) 2012-03-28 2017-01-04 Tosoh Finechem Corporation Method for producing solid polymethylaluminoxane composition having small particle diameter
CN109369830A (zh) * 2012-07-11 2019-02-22 亚培烯科技（杭州）有限公司 固体活化剂体系及其制备方法
CN104968668B (zh) * 2013-02-08 2017-11-17 三井化学株式会社 固体状聚铝氧烷组合物、烯烃聚合用催化剂、烯烃聚合物的制造方法及固体状聚铝氧烷组合物的制造方法
JP6149157B2 (ja) 2013-10-28 2017-06-14 アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． アリル型アルコールを用いるアルキルアルミニウムの加水分解によりアルミノキサンを調製するプロセス
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WO2017175766A1 (ja) * 2016-04-05 2017-10-12 東ソー・ファインケム株式会社 固体状ｐｍａｏ組成物およびその製造方法
JP6940939B2 (ja) * 2016-09-21 2021-09-29 大日本印刷株式会社 パターン形成方法及び凹凸構造体の製造方法
US11021552B2 (en) * 2017-10-31 2021-06-01 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
JP7216958B2 (ja) * 2019-02-28 2023-02-02 国立大学法人広島大学 高純度固体アルミノキサン及びその製造方法
CN114269795B (zh) 2019-09-30 2024-06-21 株式会社Lg化学 使用含羟基化合物纯化含聚烷基铝氧烷溶液的方法和使用该方法的催化剂组合物
CN111662398A (zh) * 2020-06-19 2020-09-15 上海东化环境工程有限公司 一种改性烷基铝氧烷、制备方法及用于聚烯烃聚合反应的催化剂
US20240010660A1 (en) 2020-11-23 2024-01-11 Exxonmobil Chemical Patents Inc. Toluene Free Supported Methylalumoxane Precursor
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CN116601160A (zh) 2020-11-23 2023-08-15 埃克森美孚化学专利公司 由原位形成的铝氧烷制备催化剂的改进方法
EP4247825A1 (en) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports

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Also Published As

Publication number Publication date
KR100417968B1 (ko) 2004-03-19
EP0966322B1 (en) 2005-03-02
ATE289868T1 (de) 2005-03-15
JP4112005B2 (ja) 2008-07-02
HK1018419A1 (en) 1999-12-24
KR19990076769A (ko) 1999-10-15
EP0966322A1 (en) 1999-12-29
CN1093138C (zh) 2002-10-23
WO1997023288A1 (en) 1997-07-03
JP2000505785A (ja) 2000-05-16
CN1209080A (zh) 1999-02-24
DE69634424T2 (de) 2006-05-11
DE69634424D1 (de) 2005-04-07
ES2238701T3 (es) 2005-09-01
US5831109A (en) 1998-11-03
AU1421097A (en) 1997-07-17
EP0966322A4 (en) 2000-06-28

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