CN1080212A - 高性能的钒磷氧(vpo)催化剂及其制备方法 - Google Patents

高性能的钒磷氧(vpo)催化剂及其制备方法 Download PDF

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Publication number
CN1080212A
CN1080212A CN93106019A CN93106019A CN1080212A CN 1080212 A CN1080212 A CN 1080212A CN 93106019 A CN93106019 A CN 93106019A CN 93106019 A CN93106019 A CN 93106019A CN 1080212 A CN1080212 A CN 1080212A
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China
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catalyst
pore
temperature
modifying agent
precursor
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Pending
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CN93106019A
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English (en)
Chinese (zh)
Inventor
W·J·安德鲁斯
J·R·艾纳
T·R·费尔特豪斯
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Monsanto Co
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Monsanto Co
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Publication of CN1080212A publication Critical patent/CN1080212A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN93106019A 1992-05-22 1993-05-21 高性能的钒磷氧(vpo)催化剂及其制备方法 Pending CN1080212A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US887,254 1992-05-22
US07/887,254 US5275996A (en) 1992-05-22 1992-05-22 Phosphorous/vanadium oxide catalyst and process of preparation thereof

Publications (1)

Publication Number Publication Date
CN1080212A true CN1080212A (zh) 1994-01-05

Family

ID=25390769

Family Applications (1)

Application Number Title Priority Date Filing Date
CN93106019A Pending CN1080212A (zh) 1992-05-22 1993-05-21 高性能的钒磷氧(vpo)催化剂及其制备方法

Country Status (11)

Country Link
US (1) US5275996A (enExample)
EP (1) EP0646045B1 (enExample)
JP (1) JP3733382B2 (enExample)
CN (1) CN1080212A (enExample)
AU (1) AU4027193A (enExample)
DE (1) DE69325514T2 (enExample)
IL (1) IL105762A0 (enExample)
MX (1) MX9303001A (enExample)
TW (1) TW279815B (enExample)
WO (1) WO1993024225A1 (enExample)
ZA (1) ZA933570B (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1087974C (zh) * 1996-03-08 2002-07-24 株式会社日本触媒 新型经过金属离子交换的磷钒化合物和采用这种化合物的固体酸性催化剂
CN112090437A (zh) * 2019-06-18 2020-12-18 中国石油化工股份有限公司 正丁烷氧化制顺酐的钒磷氧催化剂及其制备方法和应用
CN114433151A (zh) * 2020-10-31 2022-05-06 中国石油化工股份有限公司 一种钒磷氧催化剂及其制备方法和应用

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US5641722A (en) * 1994-09-15 1997-06-24 Huntsman Petrochemical Corporation High performance VPO catalyst and process of preparation thereof
US5945368A (en) * 1995-10-02 1999-08-31 Huntsman Petrochemical Corporation Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride
US6495486B1 (en) * 1999-11-10 2002-12-17 Tonen Chemical Corporation Intercalation compound and a vanadium phosphorus mixed oxide and a process for the preparation thereof
DE10011309A1 (de) * 2000-03-10 2001-09-13 Basf Ag Verfahren zur Herstellung von Maleinsäreanhydrid
DE10011307A1 (de) * 2000-03-10 2001-09-13 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE10211449A1 (de) * 2002-03-15 2003-09-25 Basf Ag Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid und Verfahren zu dessen Herstellung
DE10211446A1 (de) * 2002-03-15 2003-10-02 Basf Ag Verfahren zur Herstellung eines Vanadium, Phosphor und Sauerstoff enthaltenden Katalysators
DE10235355A1 (de) * 2002-08-02 2004-02-19 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
DE10334582A1 (de) * 2003-07-28 2005-02-24 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
US20070270597A1 (en) * 2006-05-18 2007-11-22 Basf Aktiengesellschaft Process for preparing maleic anhydride in a microchannel reactor
WO2008030714A1 (en) * 2006-09-05 2008-03-13 Huntsman Petrochemical Corporation Improved maleic anhydride catalyst and method for its preparation
EP2205353B1 (en) 2007-10-22 2019-12-18 Huntsman Petrochemical LLC Improved oxidation catalyst for maleic anhydride production
TWI468223B (zh) * 2008-10-20 2015-01-11 Huntsman Petrochemical Llc 經改良之三瓣形馬來酸酐觸媒及製造馬來酸酐的方法
US8728972B2 (en) 2008-10-21 2014-05-20 Huntsman Petrochemical Llc High pore volume VPO catalyst for maleic anhydride production
EP2379223A2 (de) 2008-12-22 2011-10-26 Basf Se Katalysatorformkörper und verfahren zur herstellung von maleinsäureanhydrid
US9138729B2 (en) 2008-12-22 2015-09-22 Basf Se Catalyst and method for producing maleic anhydride
WO2011023646A1 (de) * 2009-08-26 2011-03-03 Basf Se Katalysator-precursor für die herstellung von maleinsäureanhydrid und verfahren zu dessen herstellung
WO2011057911A2 (de) 2009-11-10 2011-05-19 Basf Se Rohrbündelreaktor zur herstellung von maleinsäureanhydrid
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
US8785344B2 (en) 2012-02-20 2014-07-22 Basf Se Gas phase oxidation catalyst with low charge transport activation energy
EP2781262B1 (en) * 2013-03-22 2020-05-27 Clariant International Ltd Removable protective coating for the receipt of a dust free catalyst
DE102013008207A1 (de) 2013-05-14 2014-11-20 Basf Se Verfahren zur Herstellung von Acrylsäure mit hoher Raum-Zeit-Ausbeute
US9073846B2 (en) 2013-06-05 2015-07-07 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
DE102014004786B4 (de) * 2014-04-02 2021-09-30 Clariant International Ltd. Alkalimetall-modifizierter Vanadium-Phosphor-Oxid (VPO)-Katalysator
CN108355690B (zh) * 2018-02-09 2021-01-26 中国科学院过程工程研究所 一种磷酸氧钒催化剂、其制备方法及用途
CN116550351B (zh) * 2022-01-29 2025-12-02 中国石油化工股份有限公司 一种高堆比钒磷氧催化剂前驱体及催化剂
WO2025032125A1 (en) * 2023-08-07 2025-02-13 Basf Se Quality-optimized process for preparing a vanadium/phosphorous mixed oxide catalyst

Family Cites Families (17)

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US3864280A (en) * 1972-06-19 1975-02-04 Chevron Res Catalyst for a n-butane oxidation to maleic anhydride
US4187235A (en) * 1972-09-18 1980-02-05 Chevron Research Company Method for preparing maleic anhydride
JPS6034510B2 (ja) * 1976-06-10 1985-08-09 日本碍子株式会社 セラミツクハニカム構造体の押出製造法
US4092269A (en) * 1976-10-15 1978-05-30 Monsanto Company Phosphorus-vanadium-oxygen catalysts having a specific pore volume
EP0003431B1 (en) * 1978-01-30 1984-04-11 Imperial Chemical Industries Plc Production of carboxylic acid anhydrides and catalysts therefor
US4251390A (en) * 1979-06-11 1981-02-17 Denka Chemical Corporation Partial oxidation catalyst
US4333853A (en) * 1980-05-05 1982-06-08 The Standard Oil Company Mixed vanadium phosphorus oxide catalysts and preparation thereof
US4328162A (en) * 1980-09-05 1982-05-04 Eastman Kodak Company Process for preparing 9,11-unsaturated steroidal compound from the corresponding saturated steroidal compound
US4315864A (en) * 1980-10-22 1982-02-16 Standard Oil Company (Ohio) Preparation of maleic anhydride
DE3130343A1 (de) * 1981-07-31 1983-02-17 Bayer Ag, 5090 Leverkusen Vanadium/phosphor-mischoxid-katalysator, verfahren zu dessen herstellung sowie dessen verwendung
US4386215A (en) * 1981-11-27 1983-05-31 Monsanto Company Maleic anhydride production with high crush strength catalysts
CA1227784A (en) * 1983-12-28 1987-10-06 James T. Wrobleski Phosphorus-vanadium-mixed oxide oxidation catalysts and processes for the preparation and use thereof
US4567158A (en) * 1983-12-28 1986-01-28 Monsanto Company Process for preparing phosphorus-vanadium mixed oxide oxidation catalysts
US4632916A (en) * 1985-07-15 1986-12-30 E. I. Du Pont De Nemours And Company Fumed silica modified catalyst
US4699985A (en) * 1985-07-15 1987-10-13 E. I. Du Pont De Nemours And Company Process for oxidation of N-butane to maleic anhydride
US4632915A (en) * 1985-10-28 1986-12-30 Monsanto Company Iron/lithium--promoted catalysts for the production of maleic anhydride
JP2895142B2 (ja) * 1989-02-23 1999-05-24 三井化学株式会社 触媒先駆体および対応する触媒の製造法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1087974C (zh) * 1996-03-08 2002-07-24 株式会社日本触媒 新型经过金属离子交换的磷钒化合物和采用这种化合物的固体酸性催化剂
CN112090437A (zh) * 2019-06-18 2020-12-18 中国石油化工股份有限公司 正丁烷氧化制顺酐的钒磷氧催化剂及其制备方法和应用
CN114433151A (zh) * 2020-10-31 2022-05-06 中国石油化工股份有限公司 一种钒磷氧催化剂及其制备方法和应用
CN114433151B (zh) * 2020-10-31 2024-02-13 中国石油化工股份有限公司 一种钒磷氧催化剂及其制备方法和应用

Also Published As

Publication number Publication date
EP0646045B1 (en) 1999-06-30
IL105762A0 (en) 1993-09-22
JP3733382B2 (ja) 2006-01-11
ZA933570B (en) 1994-02-14
DE69325514T2 (de) 2000-02-03
US5275996A (en) 1994-01-04
DE69325514D1 (de) 1999-08-05
JPH08501486A (ja) 1996-02-20
MX9303001A (es) 1993-11-01
WO1993024225A1 (en) 1993-12-09
EP0646045A1 (en) 1995-04-05
TW279815B (enExample) 1996-07-01
AU4027193A (en) 1993-12-30

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