MX9303001A - Catalizador de oxido fosforo y vanadio de alta eficiencia y procedimiento para su preparacion. - Google Patents

Catalizador de oxido fosforo y vanadio de alta eficiencia y procedimiento para su preparacion.

Info

Publication number
MX9303001A
MX9303001A MX9303001A MX9303001A MX9303001A MX 9303001 A MX9303001 A MX 9303001A MX 9303001 A MX9303001 A MX 9303001A MX 9303001 A MX9303001 A MX 9303001A MX 9303001 A MX9303001 A MX 9303001A
Authority
MX
Mexico
Prior art keywords
catalyst
pore volume
vanadium
procedure
oxide catalyst
Prior art date
Application number
MX9303001A
Other languages
English (en)
Inventor
William Joseph Andre Felthouse
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of MX9303001A publication Critical patent/MX9303001A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

Un catalizador poroso, activado de óxido de fósforo/vanadio adaptado para la oxidación catalítica de un hidrocarburo para producir un anhídrido a ácido carboxílico el catalizador comprende cuerpos conformados que tienen un área de superficie B.E.T. de por lo menos aproximadamente 15 m2/g, un estado de oxidación promedio de vanadio de entre aproximadamente 4 y aproximadamente 4.5, un volumen total de poros de por lo menos aproximadamente 0.15 cc/g, una densidad de cuerpos conformados, aparente, normalizada, entre aproximadamente 1.25 y aproximadamente 2 g/cc, y una resistencia a la trituración de por lo menos aproximadamente 1.816 kg. Por lo menos aproximadamente el 5 por ciento del volumen de poros de catalizador está constituido de poros que tienen un diámetro de por lo menos aproximadamente 0.8 micras, y por lo menos aproximadamente 4 por ciento del volumen de poros esta constituidos de poros que tienen un diámetro de por lo menos aproximadamente 10 micras. El catalizador se prepara mezclando un precursor de óxido de fósforo/vanadio en partículas, con un agente modificador de poros para producir una composición precursora de catalizador modificada, transformando la composición precursora modificada a una configuración predeterminada, y removiendo el agente modificador de poros substancialmente a una temperatura menor que 300°C.
MX9303001A 1992-05-22 1993-05-21 Catalizador de oxido fosforo y vanadio de alta eficiencia y procedimiento para su preparacion. MX9303001A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/887,254 US5275996A (en) 1992-05-22 1992-05-22 Phosphorous/vanadium oxide catalyst and process of preparation thereof

Publications (1)

Publication Number Publication Date
MX9303001A true MX9303001A (es) 1993-11-01

Family

ID=25390769

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9303001A MX9303001A (es) 1992-05-22 1993-05-21 Catalizador de oxido fosforo y vanadio de alta eficiencia y procedimiento para su preparacion.

Country Status (11)

Country Link
US (1) US5275996A (es)
EP (1) EP0646045B1 (es)
JP (1) JP3733382B2 (es)
CN (1) CN1080212A (es)
AU (1) AU4027193A (es)
DE (1) DE69325514T2 (es)
IL (1) IL105762A0 (es)
MX (1) MX9303001A (es)
TW (1) TW279815B (es)
WO (1) WO1993024225A1 (es)
ZA (1) ZA933570B (es)

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US5641722A (en) * 1994-09-15 1997-06-24 Huntsman Petrochemical Corporation High performance VPO catalyst and process of preparation thereof
US5945368A (en) * 1995-10-02 1999-08-31 Huntsman Petrochemical Corporation Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride
MY121280A (en) * 1996-03-08 2006-01-28 Nippon Catalytic Chem Ind Novel metal ion-exchanged phosphorus-vanadium compound and solid acid catalyst using the compound
US6495486B1 (en) * 1999-11-10 2002-12-17 Tonen Chemical Corporation Intercalation compound and a vanadium phosphorus mixed oxide and a process for the preparation thereof
DE10011307A1 (de) * 2000-03-10 2001-09-13 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE10011309A1 (de) * 2000-03-10 2001-09-13 Basf Ag Verfahren zur Herstellung von Maleinsäreanhydrid
DE10211449A1 (de) * 2002-03-15 2003-09-25 Basf Ag Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid und Verfahren zu dessen Herstellung
DE10211446A1 (de) * 2002-03-15 2003-10-02 Basf Ag Verfahren zur Herstellung eines Vanadium, Phosphor und Sauerstoff enthaltenden Katalysators
DE10235355A1 (de) * 2002-08-02 2004-02-19 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
DE10334582A1 (de) * 2003-07-28 2005-02-24 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
US20070270597A1 (en) * 2006-05-18 2007-11-22 Basf Aktiengesellschaft Process for preparing maleic anhydride in a microchannel reactor
US8143461B2 (en) * 2006-09-05 2012-03-27 Huntsman Petrochemical Llc Maleic anhydride catalyst and method for its preparation
US8404614B2 (en) 2007-10-22 2013-03-26 Huntsman Petrochemical Llc Oxidation catalyst for maleic anhydride production
TWI468223B (zh) 2008-10-20 2015-01-11 Huntsman Petrochemical Llc 經改良之三瓣形馬來酸酐觸媒及製造馬來酸酐的方法
WO2010047957A1 (en) 2008-10-21 2010-04-29 Huntsman Petrochemical Llc High pore volume vpo catalyst for maleic anhydride production
EP2379222B1 (de) 2008-12-22 2018-09-05 Basf Se Katalysator und verfahren zur herstellung von maleinsäureanhydrid
CN102325593A (zh) 2008-12-22 2012-01-18 巴斯夫欧洲公司 用于生产马来酸酐的催化剂成型体及方法
WO2011023646A1 (de) * 2009-08-26 2011-03-03 Basf Se Katalysator-precursor für die herstellung von maleinsäureanhydrid und verfahren zu dessen herstellung
RU2566749C2 (ru) * 2009-11-10 2015-10-27 Басф Се Кожухотрубный реактор для получения ангидрида малеиновой кислоты
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
US8785344B2 (en) 2012-02-20 2014-07-22 Basf Se Gas phase oxidation catalyst with low charge transport activation energy
EP2781262B1 (en) * 2013-03-22 2020-05-27 Clariant International Ltd Removable protective coating for the receipt of a dust free catalyst
DE102013008207A1 (de) 2013-05-14 2014-11-20 Basf Se Verfahren zur Herstellung von Acrylsäure mit hoher Raum-Zeit-Ausbeute
US9073846B2 (en) 2013-06-05 2015-07-07 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
DE102014004786B4 (de) 2014-04-02 2021-09-30 Clariant International Ltd. Alkalimetall-modifizierter Vanadium-Phosphor-Oxid (VPO)-Katalysator
CN108355690B (zh) * 2018-02-09 2021-01-26 中国科学院过程工程研究所 一种磷酸氧钒催化剂、其制备方法及用途
CN112090437A (zh) * 2019-06-18 2020-12-18 中国石油化工股份有限公司 正丁烷氧化制顺酐的钒磷氧催化剂及其制备方法和应用
CN114433151B (zh) * 2020-10-31 2024-02-13 中国石油化工股份有限公司 一种钒磷氧催化剂及其制备方法和应用

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US3864280A (en) * 1972-06-19 1975-02-04 Chevron Res Catalyst for a n-butane oxidation to maleic anhydride
US4187235A (en) * 1972-09-18 1980-02-05 Chevron Research Company Method for preparing maleic anhydride
JPS6034510B2 (ja) * 1976-06-10 1985-08-09 日本碍子株式会社 セラミツクハニカム構造体の押出製造法
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Also Published As

Publication number Publication date
IL105762A0 (en) 1993-09-22
TW279815B (es) 1996-07-01
JPH08501486A (ja) 1996-02-20
WO1993024225A1 (en) 1993-12-09
DE69325514T2 (de) 2000-02-03
EP0646045A1 (en) 1995-04-05
ZA933570B (en) 1994-02-14
EP0646045B1 (en) 1999-06-30
DE69325514D1 (de) 1999-08-05
AU4027193A (en) 1993-12-30
CN1080212A (zh) 1994-01-05
US5275996A (en) 1994-01-04
JP3733382B2 (ja) 2006-01-11

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