MX169846B - Catalizadores de niquel silice y su preparacion - Google Patents

Catalizadores de niquel silice y su preparacion

Info

Publication number
MX169846B
MX169846B MX014282A MX1428288A MX169846B MX 169846 B MX169846 B MX 169846B MX 014282 A MX014282 A MX 014282A MX 1428288 A MX1428288 A MX 1428288A MX 169846 B MX169846 B MX 169846B
Authority
MX
Mexico
Prior art keywords
nickel
silice
catalysts
preparation
catalyst
Prior art date
Application number
MX014282A
Other languages
English (en)
Inventor
Dirk Verzijl
Martha Johanna Philomen Botman
Peter Nootenboom
Johannes Cornelis Oudejans
Original Assignee
Unilever Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Nv filed Critical Unilever Nv
Publication of MX169846B publication Critical patent/MX169846B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un catalizador de n íquel/sílice que opcionalmente tambien contiene cationes de un metal (X) del Grupo II inferior, caracterizado en que el catalizador reducido satisface la siguiente combinación de características: 1) una razón molar de SiO2/Ni 0.15 - 0.35; 2) una razón molar de X / Ni 0 - 0.15; 3) un área de uperficie activa de níquel por arriba de 120 m cuadrado/g; 4) un área de superficie BET de la cual, cuando menos 40 por ciento se encuentra con poros con un radio por arriba de 2.5 nm, también el catalizador contiene cuando menos 50 por ciento de níquel.
MX014282A 1987-12-21 1988-12-21 Catalizadores de niquel silice y su preparacion MX169846B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP87202585 1987-12-21

Publications (1)

Publication Number Publication Date
MX169846B true MX169846B (es) 1993-07-28

Family

ID=8197725

Family Applications (1)

Application Number Title Priority Date Filing Date
MX014282A MX169846B (es) 1987-12-21 1988-12-21 Catalizadores de niquel silice y su preparacion

Country Status (12)

Country Link
US (1) US5087599A (es)
EP (1) EP0322049B1 (es)
JP (1) JPH06205B2 (es)
KR (1) KR920006866B1 (es)
AT (1) ATE87845T1 (es)
AU (1) AU604392B2 (es)
BR (1) BR8806741A (es)
DE (1) DE3880113T2 (es)
DK (1) DK710288A (es)
MX (1) MX169846B (es)
NO (1) NO885626L (es)
ZA (1) ZA889530B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD299623A5 (de) * 1989-05-16 1992-04-30 ��������@��@�@�����@�������@��@������������@�}����������@�k�� Nickel/silizium katalysator und verfahren und herstellung davon
DE4025525A1 (de) * 1990-08-11 1992-02-20 Hoechst Ag Traegerkatalysatoren und ein verfahren zu ihrer herstellung
DE4141771A1 (de) * 1991-12-18 1993-06-24 Hoechst Ag Verfahren zur herstellung von aminen durch katalytische hydrierung von nitrilen
US5258346A (en) * 1992-07-13 1993-11-02 United Catalysts Inc. Nickel hydrogenation catalyst
ATE136814T1 (de) * 1992-09-21 1996-05-15 Unichema Chemie Bv Nickel-silica katalysator für die wasserstoffbehandlung von organischen ungesättigten verbindungen
DE4310053A1 (de) * 1993-03-27 1994-09-29 Hoechst Ag Hydrierkatalysator, ein Verfahren zur Herstellung und Verwendung
IT1268868B1 (it) * 1993-06-16 1997-03-13 Mini Ricerca Scient Tecnolog Procedimento per la preparazione di un catalizzatore metallico con supporto generato in situ per l'idrogenazione di composti organici e
US7585990B2 (en) * 2003-07-31 2009-09-08 Cargill, Incorporated Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
BRPI0413177A (pt) * 2003-07-31 2006-10-03 Cargill Inc composições gordurosas com teor baixo de ácido trans-graxo; hidrogenação em temperatura baixa, por exemplo, de óleos comestìveis
JPWO2006101079A1 (ja) * 2005-03-24 2008-09-04 出光興産株式会社 脱硫剤及びこれを用いた脱硫方法
JP5179107B2 (ja) * 2007-07-24 2013-04-10 花王株式会社 水素添加用触媒
EP2512673B1 (en) 2009-12-18 2016-09-28 Invista Technologies S.à.r.l. Nickel metal compositions and nickel complexes derived from basic nickel carbonates
EP2371937A1 (en) * 2010-03-26 2011-10-05 BASF Corporation Process for the hydrogenation of fatty acids using a promoted supported nickel catalyst
WO2012033555A1 (en) 2010-09-07 2012-03-15 Invista Technologies S.A.R.L. Nickel compositions for preparing nickel metal and nickel complexes
KR20140039268A (ko) 2011-06-10 2014-04-01 인비스타 테크놀러지스 에스.에이 알.엘. 유동층 반응기를 포함하는 하소 및 환원 방법
TWI704132B (zh) * 2019-02-13 2020-09-11 台灣中油股份有限公司 苯多羧酸酯氫化反應形成脂環族多羧酸酯之氫化方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7316234A (nl) * 1973-11-28 1975-05-30 Stamicarbon Nikkelkatalysator.
DE2952683A1 (de) * 1979-12-29 1981-07-02 Ruhrchemie Ag, 4200 Oberhausen Methanisierungskatalysator und verfahren zu seiner herstellung
FR2502142B1 (es) * 1981-03-17 1983-12-02 Inst Francais Du Petrole
DE3221076A1 (de) * 1982-06-04 1983-12-08 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von medizinischen weissoelen durch katalytische hydrierung und katalysatoren hierfuer
AU572108B2 (en) * 1983-01-19 1988-05-05 Genentech Inc. Human tpa production using vectors coding for dhfr protein
NL191511C (nl) * 1983-01-20 1995-08-21 Unilever Nv Werkwijze voor de bereiding van een nikkel-bevattende katalysator.
NL190602C (nl) * 1983-12-06 1994-05-16 Unilever Nv Werkwijze ter bereiding van een nikkel/nikkelsilicaat katalysator en werkwijze voor het hydrogeneren van organische verbindingen daarmee.
NL190750C (nl) * 1984-06-21 1994-08-01 Unilever Nv Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee.

Also Published As

Publication number Publication date
ATE87845T1 (de) 1993-04-15
DK710288A (da) 1989-06-22
EP0322049B1 (en) 1993-04-07
NO885626L (no) 1989-06-22
EP0322049A1 (en) 1989-06-28
JPH06205B2 (ja) 1994-01-05
DE3880113T2 (de) 1993-07-15
DK710288D0 (da) 1988-12-20
KR890009462A (ko) 1989-08-02
NO885626D0 (no) 1988-12-19
US5087599A (en) 1992-02-11
KR920006866B1 (ko) 1992-08-21
AU2742588A (en) 1989-06-22
AU604392B2 (en) 1990-12-13
BR8806741A (pt) 1989-08-29
JPH02184341A (ja) 1990-07-18
ZA889530B (en) 1990-08-29
DE3880113D1 (de) 1993-05-13

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