CN108003260B - 在用于生产丙烯聚合物的齐格勒-纳塔催化剂体系中用作电子供体的环状有机硅化合物 - Google Patents

在用于生产丙烯聚合物的齐格勒-纳塔催化剂体系中用作电子供体的环状有机硅化合物 Download PDF

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CN108003260B
CN108003260B CN201711368376.8A CN201711368376A CN108003260B CN 108003260 B CN108003260 B CN 108003260B CN 201711368376 A CN201711368376 A CN 201711368376A CN 108003260 B CN108003260 B CN 108003260B
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ziegler
electron donor
organosilicon compounds
external electron
polymerization
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CN108003260A (zh
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张雷
方义群
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Formosa Plastics Corp USA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201711368376.8A 2011-10-28 2012-10-26 在用于生产丙烯聚合物的齐格勒-纳塔催化剂体系中用作电子供体的环状有机硅化合物 Active CN108003260B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/284,602 2011-10-28
US13/284,602 US10654947B2 (en) 2011-10-28 2011-10-28 Cyclic organosilicon compounds as electron donors in Zeigler-Natta catalyst systems for producing propylene polymer having high melt-flowability
CN201280051801.XA CN104114587A (zh) 2011-10-28 2012-10-26 在用于生产具有高熔体流动性的丙烯聚合物的齐格勒-纳塔催化剂体系中用作电子供体的环状有机硅化合物

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CN201280051801.XA Division CN104114587A (zh) 2011-10-28 2012-10-26 在用于生产具有高熔体流动性的丙烯聚合物的齐格勒-纳塔催化剂体系中用作电子供体的环状有机硅化合物

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CN108003260A CN108003260A (zh) 2018-05-08
CN108003260B true CN108003260B (zh) 2021-05-04

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CN201280051801.XA Pending CN104114587A (zh) 2011-10-28 2012-10-26 在用于生产具有高熔体流动性的丙烯聚合物的齐格勒-纳塔催化剂体系中用作电子供体的环状有机硅化合物

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US (3) US10654947B2 (enExample)
EP (1) EP2771374A2 (enExample)
JP (3) JP2014530956A (enExample)
CN (2) CN108003260B (enExample)
WO (1) WO2013063464A2 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6914348B2 (ja) * 2017-03-06 2021-08-04 ダブリュー・アール・グレース・アンド・カンパニー−コーンＷ Ｒ Ｇｒａｃｅ ＆ Ｃｏ−Ｃｏｎｎ オレフィン重合のためのチーグラー−ナッタ触媒調製用の電子供与体及び触媒系
US11117995B2 (en) 2018-08-23 2021-09-14 Formosa Plastics Corporation, U.S.A. Process for preparing high melt strength polypropylene
WO2026063967A1 (en) * 2024-09-19 2026-03-26 Formosa Plastics Corporation, Usa Olefin polymerization ziegler-natta catalyst components and process for the production of olefin polymers therewith

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0778294B1 (de) * 1995-12-06 1999-04-28 Basf Aktiengesellschaft Verbesserte Propylenpolymerisate
CN101245114A (zh) * 2003-12-05 2008-08-20 中国石化扬子石油化工有限公司 丙烯超临界聚合催化剂体系及聚丙烯组合物的制备方法
WO2010120331A1 (en) * 2009-04-13 2010-10-21 Formosa Plastics Corporation, U.S.A. Cyclic organosilicon compounds as electron donors for polyolefin catalysts

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1209255B (it) 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
US4342856A (en) * 1980-11-14 1982-08-03 El Paso Polyolefins Company Propylene polymerization process and product
IT1190682B (it) 1982-02-12 1988-02-24 Montedison Spa Catalizzatori per la polimerizzazione di olefine
IT1190681B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4560671A (en) 1983-07-01 1985-12-24 Union Carbide Corporation Olefin polymerization catalysts adapted for gas phase processes
US4657882A (en) 1984-11-26 1987-04-14 Amoco Corporation Supported olefin polymerization catalyst produced from a magnesium alkyl/organophosphoryl complex
US4581342A (en) 1984-11-26 1986-04-08 Standard Oil Company (Indiana) Supported olefin polymerization catalyst
JP2566420B2 (ja) 1987-08-08 1996-12-25 清水建設株式会社 軽量盛土構造およびその構築方法
IT1241062B (it) 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
JPH0486298A (ja) 1990-07-31 1992-03-18 Mimaki Eng:Kk プロッタ
JP2879391B2 (ja) 1992-04-14 1999-04-05 昭和電工株式会社 オレフィン重合用触媒およびオレフィン重合体の製造法
US5684173A (en) 1994-04-28 1997-11-04 Toho Titanium Co., Ltd. Organosilicon compound and ziegler-natta catalyst containing the same
JP3443990B2 (ja) 1994-11-22 2003-09-08 宇部興産株式会社 α−オレフィンの重合方法
FR2738826B1 (fr) * 1995-09-20 1997-10-17 Atochem Elf Sa Alcoxysilacycloalcanes, leur procede de preparation et leur utilisation pour la polymerisation des olefines
JP3766505B2 (ja) * 1997-03-26 2006-04-12 三井化学株式会社 オレフィン重合用触媒成分、これを含むオレフィン重合用触媒、予備重合触媒、オレフィンの重合方法
JP3280920B2 (ja) * 1998-09-28 2002-05-13 松下電器産業株式会社 車載用音響再生方法および装置
JP2000109514A (ja) * 1998-10-05 2000-04-18 Tokuyama Corp オレフィン重合用触媒及びこれを用いるオレフィンの重合方法
SG80673A1 (en) 1999-02-25 2001-05-22 Sumitomo Chemical Co Catalyst component, catalyst for olefin polymerization, process for producing olefin polymer and use of organosilicon compound
JP2000336112A (ja) 1999-06-01 2000-12-05 Idemitsu Petrochem Co Ltd 有機ケイ素化合物、オレフィン重合体製造用触媒およびオレフィン重合体の製造方法
ATE280188T1 (de) 1999-12-22 2004-11-15 Basell Poliolefine Spa Alpha-olefin enthaltendes polymerisationskatalysatorsystem, das ein aromatisches silan enthält
KR20020021381A (ko) 2000-04-24 2002-03-20 가즈토 도미나가 벌크 중합용 촉매, 기상 중합용 촉매, 이를 이용한 중합방법 및 이를 이용하여 수득된 올레핀 중합체
US6657025B2 (en) * 2001-01-12 2003-12-02 Fina Technology, Inc. Production of ultra high melt flow polypropylene resins
JP2002265477A (ja) * 2001-03-07 2002-09-18 Japan Science & Technology Corp カチオン性ケイ素化合物とその製造方法、及び重合開始剤としての用途
US20030069372A1 (en) 2001-10-09 2003-04-10 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst and process for preparing polyolefins with said catalyst
JP2005519118A (ja) 2002-03-01 2005-06-30 ザ トラスティーズ オブ コロンビア ユニヴァーシティ イン ザ シティ オブ ニューヨーク 不斉アリル化、アルドール、およびタンデムアルドールおよびアリル化反応のための試薬
AU2003281627A1 (en) 2002-07-22 2004-02-09 Jsr Corporation Process for producing crystalline 1,2-polybutadiene
AU2003257555A1 (en) 2002-08-19 2004-03-03 Ube Industries, Ltd. CATALYSTS FOR POLYMERIZATION OR COPOLYMERIZATION OF Alpha-OLEFINS, CATALYST COMPONENTS THEREOF, AND PROCESSES FOR POLYMERIZATION OF Alpha-OLEFINS WITH THE CATALYSTS
US7211534B2 (en) 2003-02-12 2007-05-01 Formosa Plastics Corporation, U.S.A. Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same
US6992034B2 (en) 2003-07-10 2006-01-31 Formosa Plastics Corporation, U.S.A. Catalyst component for olefin polymerization
US6956003B2 (en) 2003-12-03 2005-10-18 Formosa Plastics Corporation, U.S.A. Catalyst system for ethylene (co)-polymerization
US7307036B2 (en) 2004-07-22 2007-12-11 Formosa Plastics Corporation U.S.A. Highly active alpha-olefin polymerization catalyst
WO2006062901A2 (en) * 2004-12-07 2006-06-15 The Trustees Of Columbia University In The City Of New York Silacycle compounds and methods of use thereof
US7399812B2 (en) 2005-02-16 2008-07-15 China Petroleum & Chemical Corporation Silicon ether compounds and a method for the preparation thereof
KR100523474B1 (ko) 2005-03-29 2005-10-24 삼성토탈 주식회사 매우 높은 용융흐름성을 갖는 프로필렌 중합체의 제조방법
US7618913B2 (en) 2006-08-31 2009-11-17 Formosa Plastics Corporation, U.S.A. Highly active alpha-olefin copolymerization catalyst system
US7718713B2 (en) 2006-10-02 2010-05-18 Formosa Plastics Corporation Method of manufacturing the super-absorbent polymer (SAP) which is powdery, insoluble in water, and able to absorb water, blood and urine and has slight soluble things
JP2008094764A (ja) * 2006-10-12 2008-04-24 Ube Ind Ltd 環状アミノシラン、重合用触媒及び重合方法
US7651969B2 (en) 2006-12-05 2010-01-26 Formosa Plastics Corporation, U.S.A. Catalyst system for producing ethylene (co) polymer with improved branch distribution
US7582712B1 (en) 2008-05-09 2009-09-01 Formosa Plastics Corporation, U.S.A. Alpha-olefins polymerization catalyst
US7790819B1 (en) * 2009-04-13 2010-09-07 Formosa Plastics Corporation, U.S.A. Bicyclic organosilicon compounds as electron donors for polyolefin catalysts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0778294B1 (de) * 1995-12-06 1999-04-28 Basf Aktiengesellschaft Verbesserte Propylenpolymerisate
CN101245114A (zh) * 2003-12-05 2008-08-20 中国石化扬子石油化工有限公司 丙烯超临界聚合催化剂体系及聚丙烯组合物的制备方法
WO2010120331A1 (en) * 2009-04-13 2010-10-21 Formosa Plastics Corporation, U.S.A. Cyclic organosilicon compounds as electron donors for polyolefin catalysts

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JP6612212B2 (ja) 2019-11-27
CN108003260A (zh) 2018-05-08
JP2015227469A (ja) 2015-12-17
CN104114587A (zh) 2014-10-22
US20230088145A1 (en) 2023-03-23
JP2014530956A (ja) 2014-11-20
EP2771374A2 (en) 2014-09-03
US20200277414A1 (en) 2020-09-03
US10654947B2 (en) 2020-05-19
JP2017057418A (ja) 2017-03-23
US11572425B2 (en) 2023-02-07
WO2013063464A2 (en) 2013-05-02
WO2013063464A3 (en) 2013-06-20
US20130109820A1 (en) 2013-05-02

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