CN107922325B - 制备二芳基砜的改进方法 - Google Patents

制备二芳基砜的改进方法 Download PDF

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Publication number
CN107922325B
CN107922325B CN201680047207.1A CN201680047207A CN107922325B CN 107922325 B CN107922325 B CN 107922325B CN 201680047207 A CN201680047207 A CN 201680047207A CN 107922325 B CN107922325 B CN 107922325B
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aryl
coupling step
sulfone
alkyl
radical
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Chinese (zh)
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CN107922325A (zh
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R.穆鲁根
D.A.海
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Vertellus Specialties Inc
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Vertellus Specialties Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/04—Preparation of sulfones; Preparation of sulfoxides by reactions not involving the formation of sulfone or sulfoxide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/06—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201680047207.1A 2015-06-09 2016-06-09 制备二芳基砜的改进方法 Active CN107922325B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562173283P 2015-06-09 2015-06-09
US62/173,283 2015-06-09
PCT/US2016/036587 WO2016201039A1 (en) 2015-06-09 2016-06-09 Improved process for making diaryl sulfones

Publications (2)

Publication Number Publication Date
CN107922325A CN107922325A (zh) 2018-04-17
CN107922325B true CN107922325B (zh) 2021-09-07

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US (2) US10745348B2 (enExample)
EP (2) EP3307710B1 (enExample)
JP (2) JP2018516952A (enExample)
KR (1) KR102629634B1 (enExample)
CN (1) CN107922325B (enExample)
WO (1) WO2016201039A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3020328A1 (en) * 2016-04-06 2017-10-12 Emerge Print Management, Llc Apparatus and method for metering and monitoring printer related data on non-networked printers
EP3441393B1 (en) * 2017-08-07 2020-03-18 Rhodia Operations New cycloadduct precursors of dihalodiphenylsulfones and preparations thereof
WO2021037797A1 (en) * 2019-08-27 2021-03-04 Basf Se (c)crystal composition (cc) comprising 4,4'-dichlorodiphenylsulfone crystals (c)
JP2023503250A (ja) 2019-11-13 2023-01-27 ビーエーエスエフ ソシエタス・ヨーロピア 不純物として４，４’－ジクロロジフェニルスルホキシドおよび／または４，４’－ジクロロジフェニルスルホンを含有する水を処理する方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4778932A (en) * 1986-07-16 1988-10-18 New Japan Chemical Co., Ltd. Process for preparing diarylsulfones
US4937387A (en) * 1986-09-05 1990-06-26 Amoco Corporation Processes for preparing diaryl sulfones

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GB895464A (en) * 1958-07-05 1962-05-02 U C L A F Improvements in or relating to sulphones
US2971985A (en) 1958-07-05 1961-02-14 Roussel Uclaf Process for the preparation of 4, 4'-dichlorodiphenylsulfone
US3309409A (en) 1964-04-10 1967-03-14 Stauffer Chemical Co Purification of acidic chlorophenylsulfones
US3355497A (en) 1965-02-01 1967-11-28 Plains Chemical Dev Co Manufacture of 4, 4'-dichlorodiphenyl sulfone
CH497396A (de) 1968-11-06 1970-10-15 Inventa Ag Verfahren zum Reinigen von Halogendiphenylsulfonen
US3855312A (en) 1970-02-06 1974-12-17 Ici Ltd Production of di-4-chlorophenyl sulphone
JPS5182237A (en) 1975-01-16 1976-07-19 Nippon Soda Co 4*4** jikurofuenirusurupponnoseizojiniokeru jimechiruryusannokaishuhoho
JPS5188938A (en) 1975-01-31 1976-08-04 Kojundo 4*4** jikurorujifuenirusurupponnobunrihoho
JPS5785363A (en) * 1980-11-18 1982-05-28 Mitsui Toatsu Chem Inc Preparation of diaryl sulfone
JPS6368556A (ja) * 1986-09-09 1988-03-28 New Japan Chem Co Ltd ジアリ−ルスルホン類の製造方法
DE3704932A1 (de) 1987-02-17 1988-09-01 Basf Ag Verfahren zur herstellung von 4,4'-dichlordiphenylsulfon
US4822916A (en) * 1987-09-21 1989-04-18 Akzo America Inc. Preparation of diaryl sulfones
US4876390A (en) 1988-08-19 1989-10-24 Uop Process for separating dichlorodiphenylsulfone isomers
DE3835562A1 (de) * 1988-10-19 1990-05-03 Basf Ag Verfahren zur herstellung von bis-(4-chlorphenyl)-sulfon
DE3902894A1 (de) 1989-02-01 1990-08-02 Basf Ag Verfahren zur herstellung von bis-(4-chlorphenyl)-sulfon
DE3902890A1 (de) 1989-02-01 1990-08-02 Basf Ag Verfahren zur herstellung von bis-(4-chlorphenyl)-sulfon
GB9007577D0 (en) 1990-04-04 1990-05-30 Ici Plc Preparation of aromatic compounds
JPH06116231A (ja) * 1992-10-06 1994-04-26 Ube Ind Ltd ４，４’−ジクロロジフェニルスルホンの精製法
JPH09143150A (ja) 1995-11-28 1997-06-03 Tokuyama Corp 芳香族スルホンの製造方法
JPH09157246A (ja) 1995-12-13 1997-06-17 Tokuyama Corp ４，４’−ジクロロジフェニルスルホンの単離方法
JPH09165366A (ja) 1995-12-15 1997-06-24 Tokuyama Corp 芳香族スルホンの製造方法
JP3188173B2 (ja) 1996-01-10 2001-07-16 株式会社トクヤマ 芳香族スルホンの製造方法
JPH1017542A (ja) * 1996-06-28 1998-01-20 New Japan Chem Co Ltd ジアリールスルホン類の製造方法
RO113981B1 (ro) 1998-01-30 1998-12-30 Inst Cercetari Chim Procedeu de obținere a 4,4' -diclor
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GB0921069D0 (en) 2009-12-01 2010-01-13 Bandodkar Hemant R Process for the production of a sulfone polymer
WO2011107465A1 (de) 2010-03-05 2011-09-09 Basf Se Verfahren zur herstellung von 4-chlorbenzolsulfonsäure und 4,4'-dichlordiphenylsulfon
EP2383256A1 (de) 2010-04-22 2011-11-02 Basf Se Verfahren zur Herstellung von 4,4'-Dichlordiphenylsulfon
US20110263902A1 (en) 2010-04-22 2011-10-27 Basf Se Process for preparing 4,4'-dichlorodiphenyl sulfone
EP2383257A1 (de) 2010-04-22 2011-11-02 Basf Se Verfahren zur Herstellung von 4,4'-Dichlordiphenylsulfon
US20110263903A1 (en) 2010-04-22 2011-10-27 Basf Se Process for preparing 4,4'-dichlorodiphenyl sulfone
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US4937387A (en) * 1986-09-05 1990-06-26 Amoco Corporation Processes for preparing diaryl sulfones

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Publication number Publication date
KR102629634B1 (ko) 2024-01-25
EP3307710B1 (en) 2020-09-30
US20210171457A1 (en) 2021-06-10
EP3805202A1 (en) 2021-04-14
US10745348B2 (en) 2020-08-18
US20180179153A1 (en) 2018-06-28
WO2016201039A1 (en) 2016-12-15
EP3307710A1 (en) 2018-04-18
JP2021042221A (ja) 2021-03-18
CN107922325A (zh) 2018-04-17
KR20180016425A (ko) 2018-02-14
EP3307710A4 (en) 2018-12-19
JP2018516952A (ja) 2018-06-28
JP7027509B2 (ja) 2022-03-01

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