CN106414510B - 采用聚环氧烷在含氟单体的水相聚合中成核 - Google Patents

采用聚环氧烷在含氟单体的水相聚合中成核 Download PDF

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CN106414510B
CN106414510B CN201480064604.0A CN201480064604A CN106414510B CN 106414510 B CN106414510 B CN 106414510B CN 201480064604 A CN201480064604 A CN 201480064604A CN 106414510 B CN106414510 B CN 106414510B
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aqueous medium
surfactant
reactor
dispersion
polymerization
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CN106414510A (zh
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P.D.布罗瑟斯
S.V.甘加尔
D.D.哈斯尼斯
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201480064604.0A 2013-11-26 2014-11-25 采用聚环氧烷在含氟单体的水相聚合中成核 Active CN106414510B (zh)

Applications Claiming Priority (3)

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US201361908768P 2013-11-26 2013-11-26
US61/908768 2013-11-26
PCT/US2014/067268 WO2015081055A1 (en) 2013-11-26 2014-11-25 Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer

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CN106414510A CN106414510A (zh) 2017-02-15
CN106414510B true CN106414510B (zh) 2018-11-30

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US (1) US9676929B2 (enExample)
EP (1) EP3074430B1 (enExample)
JP (1) JP6622209B2 (enExample)
CN (1) CN106414510B (enExample)
WO (1) WO2015081055A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102566701B1 (ko) * 2016-12-22 2023-08-14 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 비닐리덴 플루오라이드 중합체
CN113717300B (zh) 2017-03-31 2023-11-17 大金工业株式会社 含氟聚合物的制造方法、聚合用表面活性剂和表面活性剂的使用
WO2019208707A1 (ja) 2018-04-27 2019-10-31 Ａｇｃ株式会社 変性ポリテトラフルオロエチレンの製造方法、変性ポリテトラフルオロエチレン粉末の製造方法、延伸多孔体の製造方法
JP7277799B2 (ja) * 2018-10-03 2023-05-19 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法
CN113227167A (zh) 2018-11-12 2021-08-06 阿科玛股份有限公司 用于制造含氟聚合物分散体的方法
JP7564452B2 (ja) * 2019-04-26 2024-10-09 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法
WO2021039861A1 (ja) 2019-08-26 2021-03-04 ダイキン工業株式会社 射出成形方法
JP6974776B2 (ja) 2019-08-26 2021-12-01 ダイキン工業株式会社 非水電解液電池用部材
JP7586090B2 (ja) 2019-10-29 2024-11-19 Ａｇｃ株式会社 ポリテトラフルオロエチレン水性分散液の製造方法
ES3039143T3 (en) 2020-10-01 2025-10-17 Chemours Co Fc Llc Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers
JPWO2022181662A1 (enExample) 2021-02-24 2022-09-01
KR102867567B1 (ko) 2021-02-26 2025-10-14 다이킨 고교 가부시키가이샤 관 조인트 및 관 조인트의 제조 방법
JP7174306B2 (ja) 2021-02-26 2022-11-17 ダイキン工業株式会社 射出成形体およびその製造方法
WO2022181244A1 (ja) 2021-02-26 2022-09-01 ダイキン工業株式会社 射出成形体およびその製造方法
WO2022181243A1 (ja) 2021-02-26 2022-09-01 ダイキン工業株式会社 射出成形体およびその製造方法
JP7174307B2 (ja) 2021-02-26 2022-11-17 ダイキン工業株式会社 射出成形体およびその製造方法
JP7364982B1 (ja) 2022-03-30 2023-10-19 ダイキン工業株式会社 共重合体、成形体および射出成形体
WO2025089223A1 (ja) 2023-10-23 2025-05-01 Ａｇｃ株式会社 含フッ素重合体の製造方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101535352A (zh) * 2006-11-09 2009-09-16 纳幕尔杜邦公司 使用包含氟聚醚酸或盐以及短链含氟表面活性剂的聚合剂进行的氟化单体的含水聚合反应
CN101547966A (zh) * 2006-12-08 2009-09-30 阿科玛股份有限公司 用于制造一种稳定的氟聚合物分散体的水性方法
CN101553528A (zh) * 2006-12-08 2009-10-07 阿科玛股份有限公司 用于制造氟聚合物的水性方法
CN103201300A (zh) * 2010-11-09 2013-07-10 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
CN103201301A (zh) * 2010-11-09 2013-07-10 纳幕尔杜邦公司 含氟单体的含水聚合反应中的成核作用
JP2013212438A (ja) * 2012-03-30 2013-10-17 Daikin Industries Ltd 非イオン性界面活性剤組成物、及び、フルオロポリマー水性分散液

Family Cites Families (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA878571A (en) 1971-08-17 H. Porter Verleon Dispersion polymerization of tetrafluoroethylene
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
BE563881A (enExample) 1957-01-11
US3037953A (en) 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3271341A (en) 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3391099A (en) 1966-04-25 1968-07-02 Du Pont Polymerization process
FR2042250A5 (enExample) 1969-04-01 1971-02-05 Du Pont
DE2037028C2 (de) 1970-07-25 1982-07-08 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung fluorhaltiger Copolymerisate
US4036802A (en) 1975-09-24 1977-07-19 E. I. Du Pont De Nemours And Company Tetrafluoroethylene copolymer fine powder resin
US4098978A (en) 1975-11-12 1978-07-04 The B. F. Goodrich Company Process for emulsion polymerization of vinylidene halides and product thereof
US4342675A (en) 1978-06-16 1982-08-03 E. I. Du Pont De Nemours And Company Process for preparing aqueous dispersion of polytetrafluoroethylene
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4463144A (en) 1980-09-10 1984-07-31 Asahi Glass Company Ltd. Process for producing propylene-tetrafluoroethylene copolymer
US4380618A (en) 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
JP3172983B2 (ja) 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
DE4335705A1 (de) 1993-10-20 1995-04-27 Hoechst Ag Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung
IT1270703B (it) 1994-11-17 1997-05-07 Ausimont Spa Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati
US5637748A (en) 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
US5703185A (en) 1995-08-17 1997-12-30 E. I. Du Pont De Nemours And Company Fluoropolymer extrusion process
US5763552A (en) 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5969067A (en) 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
US5866711A (en) 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
US6395848B1 (en) 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6512063B2 (en) 2000-10-04 2003-01-28 Dupont Dow Elastomers L.L.C. Process for producing fluoroelastomers
CA2445998A1 (en) 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
JP2006504844A (ja) 2002-10-31 2006-02-09 スリーエム イノベイティブ プロパティズ カンパニー フッ化オレフィンと炭化水素オレフィンとのコポリマーを製造するための、乳化剤非含有水性乳化重合
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
US6869997B2 (en) 2003-05-06 2005-03-22 Arkema, Inc. Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005003075A1 (ja) 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
US20050090613A1 (en) 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
EP1726599B1 (en) 2003-12-25 2013-07-24 Daikin Industries, Ltd. Process for producing fluoropolymer
US7122610B2 (en) 2004-04-27 2006-10-17 Arkema Inc. Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
US20060281845A1 (en) 2005-06-10 2006-12-14 Ramin Amin-Sanayei Aqueous process for making fluoropolymers
US8765890B2 (en) 2005-06-10 2014-07-01 Arkema Inc. Aqueous process for making fluoropolymers
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US20070015937A1 (en) 2005-07-15 2007-01-18 3M Innovative Properties Company Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas
US8124699B2 (en) 2005-08-08 2012-02-28 Arkema Inc. Polymerization of fluoropolymers using alkyl phosphonate surfactants
JP5106396B2 (ja) 2005-08-08 2012-12-26 アーケマ・インコーポレイテッド 非フッ素化界面活性剤を用いたフルオロポリマーの重合
WO2007046345A1 (ja) 2005-10-17 2007-04-26 Asahi Glass Company, Limited ポリテトラフルオロエチレン水性乳化液、それから得られるポリテトラフルオロエチレンファインパウダーおよび多孔体
EP1939223B1 (en) 2005-10-20 2011-07-13 Asahi Glass Company, Limited Method for producing melt-moldable fluororesin
JP5141256B2 (ja) 2005-10-20 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性分散液およびその製品
JP5343355B2 (ja) 2005-10-26 2013-11-13 旭硝子株式会社 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法
JP5232653B2 (ja) 2005-11-18 2013-07-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー コア／シェルポリマー
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US7754287B2 (en) 2006-05-31 2010-07-13 E. I. Du Pont De Nemours And Company Process for forming filled bearings from fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents
EP2049578A1 (en) 2006-08-11 2009-04-22 The University of North Carolina At Chapel Hill Process of fluoromonomer polymerization
JP5593071B2 (ja) 2006-11-09 2014-09-17 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロポリエーテル酸または塩およびシロキサン界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
WO2008060463A1 (en) 2006-11-09 2008-05-22 E. I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant
US7521513B2 (en) 2006-11-29 2009-04-21 Dupont Performance Elastomers Llc Semi-batch process for producing fluoroelastomers
US20080146757A1 (en) 2006-12-19 2008-06-19 Lyons Donald F Process for producing fluoroelastomers
US20080262177A1 (en) 2006-12-19 2008-10-23 Lyons Donald F Process for producing fluoroelastomers
WO2009013214A1 (en) 2007-07-20 2009-01-29 Solvay Solexis S.P.A. Process for polymer dispersions
WO2009126504A2 (en) 2008-04-07 2009-10-15 Arkema Inc. Polymerization of fluoropolymers using polycaprolactone
US8153738B2 (en) 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
JP5673541B2 (ja) 2009-08-28 2015-02-18 ダイキン工業株式会社 含フッ素重合体の製造方法
US9434837B2 (en) 2010-09-01 2016-09-06 Arkema Inc. Method of producing fluoropolymers using acid-functionalized monomers
US20120157656A1 (en) 2010-12-17 2012-06-21 Nippon Shokubai Co, Ltd Polyalkylene glycol-based polymer and process for producing the same
US8809471B2 (en) 2011-03-16 2014-08-19 Arkema Inc. Synthesis of making 2,3,3,3-tetrafluoropropene containing fluoropolymers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101535352A (zh) * 2006-11-09 2009-09-16 纳幕尔杜邦公司 使用包含氟聚醚酸或盐以及短链含氟表面活性剂的聚合剂进行的氟化单体的含水聚合反应
CN101547966A (zh) * 2006-12-08 2009-09-30 阿科玛股份有限公司 用于制造一种稳定的氟聚合物分散体的水性方法
CN101553528A (zh) * 2006-12-08 2009-10-07 阿科玛股份有限公司 用于制造氟聚合物的水性方法
CN103201300A (zh) * 2010-11-09 2013-07-10 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
CN103201301A (zh) * 2010-11-09 2013-07-10 纳幕尔杜邦公司 含氟单体的含水聚合反应中的成核作用
JP2013212438A (ja) * 2012-03-30 2013-10-17 Daikin Industries Ltd 非イオン性界面活性剤組成物、及び、フルオロポリマー水性分散液

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WO2015081055A1 (en) 2015-06-04
EP3074430A1 (en) 2016-10-05
JP2016537499A (ja) 2016-12-01
JP6622209B2 (ja) 2019-12-18
EP3074430B1 (en) 2019-02-20
US20150148481A1 (en) 2015-05-28
US9676929B2 (en) 2017-06-13
CN106414510A (zh) 2017-02-15

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