CN105734963A - Knitted fabric containing cotton and having silky luster, handfeel and cool feeling and manufacturing method thereof - Google Patents

Knitted fabric containing cotton and having silky luster, handfeel and cool feeling and manufacturing method thereof Download PDF

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Publication number
CN105734963A
CN105734963A CN201610270347.7A CN201610270347A CN105734963A CN 105734963 A CN105734963 A CN 105734963A CN 201610270347 A CN201610270347 A CN 201610270347A CN 105734963 A CN105734963 A CN 105734963A
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Prior art keywords
yarn
grey cloth
pin
cotton
knitting machine
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CN105734963B (en
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李桦
徐春川
周立明
张玉高
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Guangdong Esquel Textiles Co Ltd
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Guangdong Esquel Textiles Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/10Patterned fabrics or articles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C15/00Calendering, pressing, ironing, glossing or glazing textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • D06M13/17Polyoxyalkyleneglycol ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/062Load-responsive characteristics stiff, shape retention
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/20Physical properties optical

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides knitted fabric containing cotton and having silky luster, handfeel and cool feeling and a manufacturing method thereof.The method includes the following steps that yarn is woven into gray fabric with a circular knitting machine, wherein the needle number of the circular knitting machine is 18-40, the yarn count is 20-80 S/1, length 50 C of the yarn is 90-200 mm, and the gram weight of the gray fabric is 60-240 g/m<2>.The tissue structure of the gray fabric includes tabby, half cardigan, knitted cotton, rib, looped pile and ball wool or jacquard weave; open width alkali mercerizing, boiling-off, enzyme washing, dyeing, drying, soft stabilized finishing and preshrinking are conducted to finally obtain the knitted fabric containing cotton and having silky luster, handfeel and cool feeling.The knitted fabric containing cotton and having silky luster, handfeel and cool feeling has the advantages of being smooth, stiff, good in drapability, resistant to crease and small in shrinking amount and integrates smoothness, stiffness and crease resistance.

Description

Have gloss as silk, feel and cool feeling containing cotton knitted fabric and preparation method thereof
Technical field
The present invention relates to a kind of preparation method containing cotton knitted fabric, particularly to one, there is gloss as silk, feel With cool feeling containing cotton knitted fabric and preparation method thereof.
Background technology
Cotton fiber, because of its natural, soft, comfortable advantage, is well received by consumers always.Recently as weaving dye The development of whole field process technology, exploitation has high added value, the cotton product of particular appearance feel class is trend of the times. Wherein, bafta being accomplished, similar gloss as silk, smooth fabric are exactly one of product of the most great market focus.
In order to make cotton fabrics obtain smooth, gloss, the pendency effect as similar silk, in industry common practice be by Pure-cotton fabric is washed through mercerising, enzyme, soft heat treatment.Wherein: mercerising be by concentrated base effect be bafta occur irreversible Swelling, as providing cotton fabric silk gloss, increases the stiffness of fabric simultaneously;The effect that enzyme is washed is to utilize cellulase to cotton Cellulosic molecule carries out catalytic decomposition, is degraded to glucose, it is therefore an objective to remove the unnecessary filoplume of surface of cotton fabric, improves fabric table The cleanliness factor in face and gloss inverse degree, make bafta look the cleanest, bright;The effect of soft sizing is to utilize macromole Bafta is arranged by silicone oil softening agent at fixating shape step, improves emphatically the pliability of bafta and smooth degree, and lifting is knitted The sense of touch of thing.
CN102505404A " a kind of trimming process of double-mercerized cotton knitted silk-like fabric " discloses mercerized cotton looped fabric warp Cross singe, mercerising, boil drift, ferment treatment, pre-softness, Final finishing after, obtain the mercerized cotton looped fabric of silk like fabric effect.The method is tied Close singeing, double mercerization, cellulase treatment and postfinishing process, but do not ground in terms of knitting face weave Studying carefully, if the fabric that employing is the most thick and heavy or result is loosened very much, the effect worked it out will not be highly desirable.Additionally, mariages light also increases Production process and production cost.
" silk like fabric of knitting mercerized cotton arranges " discloses employing cellulase pre-treatment and silicone oil postfinishing process, to enzyme Process time, temperature, silicon oil dosage, bake the time, baking temperature is optimized, it is thus achieved that optimal knitting mercerized cotton imitative Silk technique, after arrangement, to have the softness of similar silk broadcloth smooth for fabric, but does not has mercerization finish in flow process, its gloss and real silk Still have a long way to go;And housekeeping liquid is not improved during silicone oil Final finishing, but use single silicone oil Process so that the drapability of fabric and smooth degree and real silk also have certain gap.
The product that above-mentioned prior art can obtain with there is gloss as silk, smooth cotton fabrics has certain phase Like degree, but closer effect cannot be obtained all the time in terms of drapability, feel, gloss, cool feeling.
Summary of the invention
For solving above-mentioned technical problem, it is an object of the invention to provide one and there is gloss as silk, feel and cool feeling Containing cotton knitted fabric, this fabric possesses the gloss as silk, feel and cool feeling.
For reaching above-mentioned purpose, the invention provides a kind of have gloss as silk, feel and cool feeling containing cotton knitted side The preparation method of material, it comprises the following steps:
Yarn is made into grey cloth by step one, utilization circular knitting machine;Wherein, the pin number of described circular knitting machine is 18-40, described yarn Yarn count be 20S/1-80S/1, a length of 50C=90mm-200mm of yarn of described yarn, the grammes per square metre of described grey cloth is 60-240g/ m2, the organizational structure of described grey cloth includes plain weave, pearl ground, cotton wool, rib-loop, looped pile, ball woll or jacquard weave;
Step 2, the open width that carries out grey cloth are alkali mercerized, kiering;
Step 3, use cellulase that the grey cloth after alkali mercerized is carried out enzyme to wash;
Step 4, enzyme is washed after grey cloth dye, dry, the cloth specimen after being dried;
Step 5, the softness that carries out the cloth specimen after drying are shaped and are arranged;Wherein, the raw material group of described soft sizing dressing liquid Become to include resin, amido silicon oil and modified silicon oil;
Step 6, softness sizing is arranged after cloth specimen carry out preshrunk process, obtain having gloss as silk, feel and cool Sense containing cotton knitted fabric.
The present invention studies the suitable knitting of discovery and design of plus material is most important to the sense of touch effect of finished product fabric: suitable Closing and make that to have the fabric yarn count of silky handle and gloss be 20S/1-80S/1, pin number the lowest (less than 18 pins), yarn length are the biggest (50C > 200mm), loop construction loosens, and the grey cloth being made into is the most soft, is unfavorable for forming preferable well-pressed degree;Pin number is the highest (more than 40 pins), yarn length the least (50C < 90mm), coil too closely, easily forms knitting broken hole fault, affects production efficiency, Additionally, the organizational structure of grey cloth is the most critically important, the organizational structure that the present invention provides is beneficial to obtain the grey cloth that cloth cover is smooth, makes final Fabric obtain preferable effect;The grey cloth that pin number, yarn count, yarn length and the fabric organizational structure using the present invention to provide obtains, Close structure, cloth cover is excellent without fault and well-pressed degree;Meanwhile, the technical scheme that the present invention provides is in actual production process Disclosure satisfy that loom efficiency, possess producing feasibility.
In the above-mentioned methods, it is preferable that in step one, when the organizational structure of described grey cloth is plain weave, described circular knitting machine Pin number be 20-40 pin, the yarn count of described yarn is 20S/1-80S/1, a length of 50C=90mm-200mm of yarn, described grey cloth Grammes per square metre is 60-200g/m2;It is highly preferred that the pin number of described circular knitting machine is 28-36 pin, the yarn count of described yarn is 30S/1- 60S/1, more preferably 30S/1-50S/1, a length of 50C=100mm-130mm of yarn, the grammes per square metre of described grey cloth is 110- 160g/m2
In the above-mentioned methods, it is preferable that in step one, when the organizational structure of described grey cloth is jacquard weave, described circular knitting machine Pin number be 28-36 pin, the yarn count of described yarn is 30S/1-50S/1, a length of 50C=100mm-130mm of yarn, described grey cloth Grammes per square metre is 110-160g/m2
In the above-mentioned methods, it is preferable that in step one, when the organizational structure of described grey cloth is pearl ground, described circular knitting machine Pin number be 18-28 pin, the yarn count of described yarn is 20S/1-50S/1, a length of 50C=100mm-170mm of yarn, described grey cloth Grammes per square metre is 90-200g/m2;It is highly preferred that the pin number of described circular knitting machine is 24-28 pin, the yarn count of described yarn is 30S/1- 40S/1, a length of 50C=110mm-130mm of yarn, the grammes per square metre of described grey cloth is 120-170g/m2
In the above-mentioned methods, it is preferable that in step one, when the organizational structure of described grey cloth is cotton wool, described circular knitting machine Pin number be 18-40 pin, the yarn count of described yarn is 30S/1-80S/1, a length of 50C=105mm-200mm of yarn, described grey cloth Grammes per square metre is 90-240g/m2;Preferably, the pin number of described circular knitting machine is 24-36 pin, and the yarn count of described yarn is 40S/1-70S/ 1, a length of 50C=105mm-140mm of yarn, the grammes per square metre of described grey cloth is 130-190g/m2
In the above-mentioned methods, it is preferable that in step one, the organizational structure of described grey cloth is plain weave, uses this knot of tissue The well-pressed effect of grey cloth cloth cover that structure is made into is best, the especially best results of plain weave single jersey.
In the above-mentioned methods, it is preferable that in step 2, the concentration of described alkali is 20-32Be, the concentration of silkete penetrating agent For 1-5g/L, the speed of open width mercerizing range is 5-20m/min;It is highly preferred that the concentration of described alkali is 24-32Be, mercerising permeates The concentration of agent is 3-5g/L, and the speed of open width mercerizing range is 10-15m/min.
The present invention studies and finds that in mercerization, the concentration of alkali has vital shadow to the luster effect of finished product fabric Ringing, more preferably, the alkali of employing present invention offer is dense can make finished product fabric obtain this to the luster effect of the high-alkali dense dense acquisition of relatively low alkali Invent the gloss and well-pressed degree wanted.The present invention further study show that simultaneously, when the concentration of alkali is respectively 24Be and 30Be, Gloss, well-pressed degree that both produce have significant difference, on the premise of abundant mercerising, can make cotton when the concentration of alkali is 30Be Fiber is the most swelling, obtain optimal gloss and well-pressed degree, and when the concentration of alkali is more than 30Be, gloss and well-pressed degree will not be again Substantially increase.
In the above-mentioned methods, it is preferable that in step 3, described enzyme is washed and is comprised the following steps: be placed in by grey cloth containing fine In the working solution of dimension element enzyme, control bath raio is 1:(5-15), process 50-100min in 50-70 DEG C, then grey cloth is placed in 80 DEG C Water-bath processes 10min;Wherein, the pH value of described working solution is 5-7, and the concentration of described cellulase is 0.5-3.0g/L;More Preferably, the pH value of described working solution is 5-6;It is further preferred that described working solution cellulase concentration is 2.0-3.0g/ L;It is further preferred that described bath raio is 1:(10-15).Enzyme washes the quality of effect and the clean journey of final finished fabric cloth cover Degree is directly proportional, and directly affects the sense of touch effect of finished product fabric cloth cover;The enzyme using the present invention to provide washes technique can make finished product Fabric cloth cover obtains clean, smooth, well-pressed effect.
In the above-mentioned methods, it is preferable that after step 4 terminates, before step (5) starts, the method also includes the step of calendering Suddenly, described calen-dering process is: calendering face is the front of cloth specimen, and temperature is 60 DEG C-120 DEG C, and pressure is 6MPa-16MPa, and speed is 10-30m/min;Preferably, temperature is 80 DEG C-100 DEG C, and pressure is 8MPa-12MPa, and speed is 15-25m/min;The mesh of calendering Be further lifting cloth cover gloss.
In the above-mentioned methods, it is preferable that in step 5, described soft finish comprises the following steps: the cloth after drying Sample pads soft sizing dressing liquid, then in 130-170 DEG C of drying;It is highly preferred that with the stereometer of softness sizing dressing liquid, institute The raw material composition stating soft sizing dressing liquid includes 10-100g/L resin, 50-300g/L amido silicon oil, 10-100g/L modified silicon Oil, 1-5g/L penetrating agent, 5-30g/L anti-pin hole agent and 5-15g/L catalyst;It is further preferred that with softness sizing dressing liquid Stereometer, the raw material composition of described dressing liquid includes that 30-60g/L resin, 100-200g/L amido silicon oil, 30-60g/L are modified Silicone oil, 1-3g/L penetrating agent, 5-10g/L anti-pin hole agent and 6-12g/L catalyst.
In the above-mentioned methods, it is preferable that described resin is modified 2D resin.
In the above-mentioned methods, it is preferable that described amido silicon oil includes the SILYOUINV0161 of Jiahe, Dongguan Chemical Manufacture And/or the OFX-8040A that Dow Corning Corporation produces, but it is not limited to this.
In the above-mentioned methods, it is preferable that described modified silicon oil includes what Dongguan, Guangdong Pacific Ocean Chemical Co., Ltd. produced KDM-C18A and/or the 8221 of the production of east Qi Chemical Co., Ltd., but it is not limited to this, the modified silicon oil that the present invention provides is for containing The emulsion of high response functional group.
In the above-mentioned methods, it is preferable that described penetrating agent is polyethenoxy ether class, described anti-pin hole agent is polyethylene or stone Wax, described catalyst is magnesium chloride.
The modified 2D resin that the present invention provides can improve the shrink problem of fabric, improves the ironing-free performance of fabric and then carries The appearance after laundering of high cloth cover;Amido silicon oil can be formed at cloth cover and align, and uniform fold fiber surface makes fabric obtain Lubrication well, soft effect;Modified silicon oil can help amido silicon oil and cellulose hydroxyl group to form the crosslinking of certain density, is to knit Thing reaches well-pressed and bony finishing effect, and is resistant to repeatedly family's wash water;Described penetrating agent can promote cellulose fibre pair The absorption of soft sizing dressing liquid;Anti-pin hole agent can improve the smoothness of fabric, reduces the risk that pin hole produces.
Traditional handicraft, when carrying out soft sizing and arranging, uses single consistent lubricant or simply consistent lubricant is carried out simple group Close, it is impossible to realize smooth, well-pressed, the unification of wrinkle resistance;And the soft sizing dressing liquid that the present invention provides is by resin, amino silicone Oil, modified silicon oil are compounding to be used, and can not only ensure that final fabric is the most smooth, well-pressed, drapability is good, and can also make Whole fabric has crease-resistant, little advantage of shrinking.
In the above-mentioned methods, it is preferable that in step 6, described preshrunk processes and uses close blanket preshrinking machine, described pre- The temperature that contracting processes is 80-100 DEG C, more preferably 90-100 DEG C;The time that described preshrunk processes is 1-3min, more preferably 1.5-2min.Use preshrunk to process and can improve the pliability of fabric and smooth degree further, improve the contracting of knitting fabric simultaneously Water problems.
In the above-mentioned methods, it is preferable that in step one, described grey cloth is to be made into by the cotton content yarn more than 50% 's;It is highly preferred that described grey cloth is that (cotton is mixed with silk by Quality Pure Cotton Yarn Production, polyester (terylene and cotton scribbled) or cotton-silk yarn Yarn) be made into.
Beneficial effects of the present invention:
1) present invention studies the suitable knitting of discovery and design of plus material is most important to the sense of touch effect of finished product fabric, By to including that yarn count, pin number, yarn length, the organizational structure of fabric are designed, the grey cloth being made into is the tightst, well-pressed, is holding concurrently While turning round and look at actual production feasibility, it can be ensured that fabric is finally obtained in that the feel as silk, gloss and cool feeling effect, Whole actual effect is close to ideal effect;
2) the raw material composition of softness sizing dressing liquid is improved by the technical scheme that the present invention provides, and uses this softness After sizing dressing liquid carries out soft sizing arrangement, fabric is the most smooth, well-pressed, drapability is good, but also has crease-resistant, contracting The advantage that water is little, has accomplished smooth, well-pressed, crease-resistant comprehensive unification;
3) with tradition similar products, the present invention is to the design of fabric and weaving, and the finisher such as mercerising, cellulase treatment Skill is studied and has been improved, and especially uses circular knitting machine to use high pin count to coordinate suitable yarns length closely to knit base, at shaping process Middle employing softness sizing dressing liquid processes, and not only increases well-pressed effect and the glossiness of fabric, adds the cunning of fabric Refreshing, ice-cold sense of touch style, but also be that fabric has preferable dimensional stability, wrinkle resistance and washes rear feel, finally obtain Fabric there is the style characteristic as silk.
Detailed description of the invention
In order to the technical characteristic of the present invention, purpose and beneficial effect are more clearly understood from, the existing skill to the present invention Art scheme carries out described further below, but it is not intended that to the present invention can the restriction of practical range.
Embodiment 1
Present embodiments provide a kind of have gloss as silk, feel and cool feeling containing cotton knitted fabric, the system of this fabric Preparation Method is as described below:
1) use circular knitting machine that yarn is made into two kinds of different grey cloths (being respectively labeled as grey cloth 1 and grey cloth 2) respectively: two kinds The yarn that different grey cloths is used is 100% cotton yarn, and the organizational structure of grey cloth is also plain weave, and grey cloth designs and knits base Parameter is as shown in table 1.
Table 1 grey cloth designs and knits base parameter
Numbering Yarn count The long 50C of yarn Pin number Door width Grammes per square metre
Grey cloth 1 40S/1 115mm 32 56 inches 135g/m2
Grey cloth 2 40S/1 120mm 24 54 inches 120g/m2
2) mercerising: use open width mercerizing range that above two grey cloth carries out mercerising, speed: 15m/min, temperature: room respectively Temperature 20 DEG C, the composition of mercerising working solution is as shown in table 2.
3) kiering: use common process to carry out kiering.
The composition of table 2 mercerising working solution
Component Consumption Manufacturer
Alkali NaOH 30Be Build flood (Hengyang) Industrial Co., Ltd.
Silkete penetrating agent Floranit 4028-A 5g/L Ke Kai Fine Chemical Co., Ltd
4) enzyme is washed: grey cloth being placed in enzyme and washes in working solution (pH value is 5-7), control bath raio is 1:15,55 DEG C of process 60min, is then placed in grey cloth in 80 DEG C of water-baths process 10min and kills enzyme;The composition that enzyme washes working solution is as shown in table 3.
Table 3 enzyme washes the composition of working solution
Component Consumption Manufacturer
HAC 0.3g/L Jinan Lu Yuan Chemical Co., Ltd.
NaAC 0.5g/L Taizhou City Xinghua Chemical Company
Cellulase Super GX plus 2g/L Bio tech ltd of Jie Neng section
5) dye, dry as common process.
6) cloth specimen after drying carrying out on forming machine soft sizing to arrange, treatment temperature is 150 DEG C, and the time is 2min, the composition of soft sizing dressing liquid is as shown in table 4.
7) preshrunk: using close blanket preshrinking machine to carry out preshrunk process, preshrunk number of times is once, and temperature is 100 DEG C, the time is 1min, finally gives the finished product fabric of 40S/1, wherein grey cloth 1 correspondence for finished product fabric 1, grey cloth 2 correspondence for finished product fabric 2, both fabrics are respectively provided with the gloss as silk and feel.
The composition of table 4 soft sizing dressing liquid
Component Consumption Manufacturer
Amido silicon oil OFX-8040A 150g/L Dow Corning Corporation
Modified silicon oil KDM-C18A 50g/L Dongguan City, Guangdong Province Tai Yang Chemical Co., Ltd.
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.
Catalyst MgCl2 5g/L Guangzhou good fortune million trade Co., Ltd
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
Finished product fabric 1 and finished product fabric 2 are carried out performance test respectively, and test result is as shown in table 5.
Table 5 test result
Note: 1, stiffening (Stiffness), smooth (Smoothness), soft (Softness) value are by Nu Cybertek, The product that Inc company producesSystem (Chinese is translated into " magic weapon instrument " or " magic weapon system ") records, these three The absolute value of parameter is the biggest, represents the most stiffening, the most smooth, the most soft respectively;2, the result of cool feeling test is by Boken test public affairs Department provides, and wherein, the biggest expression of Q-MAX value feels the most nice and cool;3, shrink test is according to AATCC135 III A, washes 1 time-baking 1 time Calculate a circulation, carry out altogether three circulations.
As can be seen from Table 5, both fabrics that the present invention provides are respectively provided with the gloss as silk, feel and cool feeling;Phase For compare, stiffening (Stiffness) of finished product fabric 1, smooth (Smoothness) absolute value relatively big, and cool feeling test result Q-MAX value is relatively big, illustrates that the final style of finished product fabric 1 is better compared with finished product fabric 2, owing to fabric is the tightst, so The shrink performance of fabric 1 is also better compared with fabric 2.Organizational structure one timing when yarn count and fabric is described, pin number is the highest, and yarn is long The least, the final finished product fabric obtained is more well-pressed, smooth, skeleton sense is higher, and cool feeling effect is also more preferable, shrinks less.
Embodiment 2
Present embodiments provide a kind of have gloss as silk, feel and cool feeling containing cotton knitted fabric, the system of this fabric Preparation Method is as described below:
1) use circular knitting machine that yarn is made into grey cloth: the yarn of employing is 100% cotton yarn, and the organizational structure of grey cloth is Interlock fabric, grey cloth design is with to knit base parameter as shown in table 6.
Table 6 grey cloth designs and knits base parameter
Yarn count The long 50C of yarn Pin number Door width Grammes per square metre
60S/1 130mm 32 60 inches 170g/m2
2) mercerising: use open width mercerizing range that grey cloth is carried out mercerising, speed: 15m/min, temperature: room temperature 20 DEG C, mercerizer The composition making liquid is as shown in table 7.
3) kiering: use common process to carry out kiering.
The composition of table 7 mercerising working solution
Component Consumption Manufacturer
Alkali NaOH 30Be Build flood (Hengyang) Industrial Co., Ltd.
Silkete penetrating agent Floranit 4028-A 5g/L Ke Kai Fine Chemical Co., Ltd
4) enzyme is washed: grey cloth being placed in enzyme and washes in working solution (pH value is 5-7), control bath raio is 1:15,55 DEG C of process 60min, is then placed in grey cloth in 80 DEG C of water-baths process 10min and kills enzyme;The composition that enzyme washes working solution is as shown in table 8.
Table 8 enzyme washes the composition of working solution
Component Consumption Manufacturer
HAC 0.3g/L Jinan Lu Yuan Chemical Co., Ltd.
NaAC 0.5g/L Taizhou City Xinghua Chemical Company
Cellulase Super GX plus 2g/L Bio tech ltd of Jie Neng section
5) kiering, dye, dry as common process.
6) cloth specimen after drying carrying out on forming machine soft sizing to arrange, treatment temperature is 150 DEG C, and the time is 2min, the composition of soft sizing dressing liquid is as shown in table 9.
7) preshrunk: using close blanket preshrinking machine to carry out preshrunk process, preshrunk number of times is once, and temperature is 100 DEG C, the time is 1min, finally gives 60S/1 and has the textile cotton wool fabric finished product of gloss as silk, feel and cool feeling.
The composition of table 9 soft sizing dressing liquid
Component Consumption Manufacturer
Amido silicon oil OFX-8040A 150g/L Dow Corning Corporation
Modified silicon oil KDM-C18A 50g/L Dongguan City, Guangdong Province Tai Yang Chemical Co., Ltd.
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.
Catalyst MgCl2 5g/L Guangzhou good fortune million trade Co., Ltd
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
Embodiment 3
1) use circular knitting machine that yarn is made into grey cloth: the yarn of employing is 100% cotton yarn, and the organizational structure of grey cloth is Pearl ground cloth, grey cloth design is with to knit base parameter as shown in table 10.
Table 10 grey cloth designs and knits base parameter
Yarn count The long 50C of yarn Pin number Door width Grammes per square metre
36S/1 120mm 24 60 inches 150g/m2
2) mercerising: use open width mercerizing range that grey cloth is carried out mercerising, speed: 15m/min, temperature: room temperature 20 DEG C, mercerizer The composition making liquid is as shown in table 11.
3) kiering: use common process to carry out kiering.
The composition of table 11 mercerising working solution
Component Consumption Manufacturer
Alkali NaOH 30Be Build flood (Hengyang) Industrial Co., Ltd.
Silkete penetrating agent Floranit 4028-A 5g/L Ke Kai Fine Chemical Co., Ltd
4) grey cloth being placed in enzyme wash in working solution (pH value is 5-7), control bath raio is 1:15, and 55 DEG C process 60min, then Grey cloth is placed in 80 DEG C of water-baths process 10min and kills enzyme;The composition that enzyme washes working solution is as shown in table 12.
Table 12 enzyme washes the composition of working solution
Component Consumption Manufacturer
HAC 0.3g/L Jinan Lu Yuan Chemical Co., Ltd.
NaAC 0.5g/L Taizhou City Xinghua Chemical Company
Cellulase Super GX plus 2g/L Bio tech ltd of Jie Neng section
5) kiering, dye, dry as common process.
6) cloth specimen after drying carrying out on forming machine soft sizing to arrange, treatment temperature is 150 DEG C, and the time is 2min, the composition of soft sizing dressing liquid is as shown in table 13.
The composition of the soft qualitative dressing liquid of table 13
Component Consumption Manufacturer
Amido silicon oil OFX-8040A 150g/L Dow Corning Corporation
Modified silicon oil KDM-C18A 50g/L Dongguan City, Guangdong Province Tai Yang Chemical Co., Ltd.
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.
Catalyst MgCl2 5g/L Guangzhou good fortune million trade Co., Ltd
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
7) preshrunk: using close blanket preshrinking machine to carry out preshrunk process, preshrunk number of times is once, and temperature is 100 DEG C, the time is 1min, finally gives 36S/1 and has the cotton pearl ground cloth finished product of gloss as silk, feel and cool feeling.
Comparative example 1
With reference to the production procedure of finished product fabric 1 in embodiment 1, this comparative example is only to the softness in softness sizing finishing technique Sizing dressing liquid adjusted, the most as shown in table 14, remaining production procedure all with the production of finished product fabric 1 in embodiment 1 Flow process is identical, finally gives contrast fabric 1.
The raw material ancestral composition of table 14 soft sizing dressing liquid
Component Consumption Manufacturer
Softening agent JSS 200g/L Step figure chemical industry
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.
Catalyst MgCl2 5g/L Guangzhou good fortune million trade Co., Ltd
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
Table 15 comparing result
The contrast fabric 1 that the finished product fabric 1 providing embodiment 1 and comparative example 1 provide carries out performance test, after test Comparing result is as shown in Table 15.
As can be seen from Table 15: the absolute value of stiffening (Stiffness) of finished product fabric 1 is relatively big, smooth (smoothness) absolute value is relatively big, and the absolute value of soft (Softness) is less, and cool feeling test result is more preferable;Explanation Compared with the dressing liquid that softening agent single in comparative example 1 prepares, after the soft sizing dressing liquid using the present invention to provide processes Fabric is more well-pressed, smooth, skeleton sense is higher, cool feeling is better.

Claims (10)

1. having the preparation method containing cotton knitted fabric of gloss as silk, feel and cool feeling, it comprises the following steps:
Yarn is made into grey cloth by step one, utilization circular knitting machine;Wherein, the pin number of described circular knitting machine is 18-40, the yarn of described yarn Propping up is 20S/1-80S/1, a length of 50C=90mm-200mm of yarn of described yarn, and the grammes per square metre of described grey cloth is 60-240g/m2, institute The organizational structure stating grey cloth includes plain weave, pearl ground, cotton wool, rib-loop, looped pile, ball woll or jacquard weave;
Step 2, the open width that carries out grey cloth are alkali mercerized, kiering;
Step 3, use cellulase that the grey cloth after alkali mercerized is carried out enzyme to wash;
Step 4, enzyme is washed after grey cloth dye, dry, the cloth specimen after being dried;
Step 5, the softness that carries out the cloth specimen after drying are shaped and are arranged;Wherein, the raw material composition bag of described soft sizing dressing liquid Include resin, amido silicon oil and modified silicon oil;
Step 6, the cloth specimen after arranging of shaping softness carry out preshrunk process, obtain having gloss as silk, feel and cool feeling Containing cotton knitted fabric.
Method the most according to claim 1, wherein, in step one, when the organizational structure of described grey cloth is plain weave, described The pin number of circular knitting machine is 20-40 pin, and the yarn count of described yarn is 20S/1-80S/1, and a length of 50C=90mm-200mm of yarn is described The grammes per square metre of grey cloth is 60-200g/m2
Preferably, the pin number of described circular knitting machine is 28-36 pin, and the yarn count of described yarn is 30S/1-50S/1, a length of 50C=of yarn 100mm-130mm, the grammes per square metre of described grey cloth is 110-160g/m2
Method the most according to claim 1, wherein, in step one, when the organizational structure of described grey cloth is jacquard weave, described The pin number of circular knitting machine is 28-36 pin, and the yarn count of described yarn is 30S/1-50S/1, and a length of 50C=100mm-130mm of yarn is described The grammes per square metre of grey cloth is 110-160g/m2
Method the most according to claim 1, wherein, in step one, when the organizational structure of described grey cloth is pearl ground, described The pin number of circular knitting machine is 18-28 pin, and the yarn count of described yarn is 20S/1-50S/1, and a length of 50C=100mm-170mm of yarn is described The grammes per square metre of grey cloth is 90-200g/m2
Preferably, the pin number of described circular knitting machine is 24-28 pin, and the yarn count of described yarn is 30S/1-40S/1, a length of 50C=of yarn 110mm-130mm, the grammes per square metre of described grey cloth is 120-170g/m2
Method the most according to claim 1, wherein, in step one, when the organizational structure of described grey cloth is cotton wool, described The pin number of circular knitting machine is 18-40 pin, and the yarn count of described yarn is 30S/1-80S/1, and a length of 50C=105mm-200mm of yarn is described The grammes per square metre of grey cloth is 90-240g/m2
Preferably, the pin number of described circular knitting machine is 24-36 pin, and the yarn count of described yarn is 40S/1-70S/1, a length of 50C=of yarn 105mm-140mm, the grammes per square metre of described grey cloth is 130-190g/m2
Method the most according to claim 1, wherein, in step 2, the concentration of described alkali is 20-32Be, and mercerising permeates The concentration of agent is 1-5g/L, and the speed of open width mercerizing range is 5-20m/min;
Preferably, the concentration of described alkali is 24-32Be, and the concentration of silkete penetrating agent is 3-5g/L, and the speed of open width mercerizing range is 10-15m/min。
Method the most according to claim 1, wherein, in step 3, described enzyme is washed and is comprised the following steps:
Being placed in the working solution containing cellulase by grey cloth, control bath raio is 1:(5-15), process 50-in 50-70 DEG C 100min, is then placed in 80 DEG C of water-baths process 10min by grey cloth;Wherein, the pH value of described working solution is 5-7, described fiber The concentration of element enzyme is 0.5-3.0g/L;
Preferably, the pH value of described working solution is 5-6;
It is highly preferred that described working solution cellulase concentration is 2.0-3.0g/L;
It is further preferred that described bath raio is 1:(10-15).
Method the most according to claim 1, wherein, in step 5, described soft finish comprises the following steps:
Cloth specimen after drying pads soft sizing dressing liquid, then in 130-170 DEG C of drying;
Preferably, with the stereometer of softness sizing dressing liquid, the raw material composition of described soft sizing dressing liquid includes 10-100g/L Resin, 50-300g/L amido silicon oil, 10-100g/L modified silicon oil, 1-5g/L penetrating agent, 5-30g/L anti-pin hole agent and 5-15g/ L catalyst;
It is highly preferred that with softness sizing dressing liquid stereometer, described dressing liquid raw material composition include 30-60g/L resin, 100-200g/L amido silicon oil, 30-60g/L modified silicon oil, 1-3g/L penetrating agent, 5-10g/L anti-pin hole agent and 6-12g/L catalysis Agent;
It is further preferred that described resin is modified 2D resin;
It is further preferred that described amido silicon oil includes SILYOUINV0161 and/or the DOW CORNING of Jiahe, Dongguan Chemical Manufacture The OFX-8040A that company produces;Described modified silicon oil includes the KDM-C18A that Dongguan, Guangdong Pacific Ocean Chemical Co., Ltd. produces And/or the 8221 of the production of east Qi Chemical Co., Ltd.;
The most preferably, described penetrating agent is polyethenoxy ether class, and described anti-pin hole agent is polyethylene or paraffin class material, Described catalyst is magnesium chloride.
Method the most according to claim 1, wherein, in step one, described grey cloth is the yarn being more than 50% by cotton content Line is made into;
Preferably, described grey cloth is made into by Quality Pure Cotton Yarn Production, polyester or cotton-silk yarn.
10. have gloss as silk, feel and cool feeling containing a cotton knitted fabric, it is by any one of claim 1-9 institute The method stated prepares.
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