CN1056858C - 聚氨酯基塑料透镜及其制备方法 - Google Patents
聚氨酯基塑料透镜及其制备方法 Download PDFInfo
- Publication number
- CN1056858C CN1056858C CN95102316A CN95102316A CN1056858C CN 1056858 C CN1056858 C CN 1056858C CN 95102316 A CN95102316 A CN 95102316A CN 95102316 A CN95102316 A CN 95102316A CN 1056858 C CN1056858 C CN 1056858C
- Authority
- CN
- China
- Prior art keywords
- composition
- plastic lens
- heating
- dbc
- lens
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
- C08G18/3865—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms
- C08G18/3868—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP070347/1994 | 1994-04-08 | ||
| JP7034794 | 1994-04-08 | ||
| JP070347/94 | 1994-04-08 | ||
| JP204969/94 | 1994-08-30 | ||
| JP20496994 | 1994-08-30 | ||
| JP204969/1994 | 1994-08-30 | ||
| JP300611/1994 | 1994-12-05 | ||
| JP30061294 | 1994-12-05 | ||
| JP30061194 | 1994-12-05 | ||
| JP300612/1994 | 1994-12-05 | ||
| JP300612/94 | 1994-12-05 | ||
| JP300611/94 | 1994-12-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1119195A CN1119195A (zh) | 1996-03-27 |
| CN1056858C true CN1056858C (zh) | 2000-09-27 |
Family
ID=27465231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95102316A Expired - Lifetime CN1056858C (zh) | 1994-04-08 | 1995-04-08 | 聚氨酯基塑料透镜及其制备方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5693738A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0676429B1 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100191067B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1056858C (cg-RX-API-DMAC7.html) |
| DE (1) | DE69519696T2 (cg-RX-API-DMAC7.html) |
| TW (1) | TW281679B (cg-RX-API-DMAC7.html) |
Families Citing this family (87)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US5718817A (en) * | 1993-07-28 | 1998-02-17 | Elf Atochem North America, Inc. | Catalyst for low temperature cure of blocked isocyanates |
| MXPA99000662A (es) * | 1996-07-17 | 2004-11-22 | Essilor Int | Composiciones de liberacion de molde interna que contiene esteres de fosfato. |
| US5942158A (en) * | 1998-03-09 | 1999-08-24 | Ppg Industries Ohio, Inc. | One-component optical resin composition |
| US5932681A (en) * | 1998-03-09 | 1999-08-03 | Ppg Industries Ohio, Inc. | Method of preparing an optical polymerizate |
| CA2331749C (en) * | 1998-05-15 | 2005-10-18 | Akzo Nobel Nv | Ophthalmic lenses |
| EP1124873B1 (en) * | 1998-10-29 | 2003-11-05 | Essilor International Compagnie Generale D'optique | Polymerizable compositions for making thio containing resins including a salt catalyst and process for making thio containing resin articles |
| US6068797A (en) * | 1998-12-11 | 2000-05-30 | Ppg Industries Ohio, Inc. | Method of preparing a shaped article having a photochromic coating thereon |
| US7087698B1 (en) | 1999-11-18 | 2006-08-08 | Ppg Industries Ohio, Inc. | Method of preparing an optical polymerizate |
| US7473754B1 (en) | 2000-10-17 | 2009-01-06 | Ppg Industries Ohio, Inc. | Optical resin composition |
| US7098290B1 (en) | 1999-11-18 | 2006-08-29 | Ppg Industries Ohio, Inc. | Method of preparing an optical polymerizate |
| DE60110967T2 (de) * | 2000-03-27 | 2005-10-27 | Mitsui Chemicals, Inc. | Polythiol, polymerisierbare Zusammensetzung, Harz und Linse und Verfahren zur Herstellung der Thiolverbindung |
| US6477926B1 (en) | 2000-09-15 | 2002-11-12 | Ppg Industries Ohio, Inc. | Polishing pad |
| US6998072B2 (en) * | 2001-11-01 | 2006-02-14 | Transitions Optical, Inc. | Photochromic polymerizable compositions |
| US20030149217A1 (en) * | 2001-11-16 | 2003-08-07 | Bojkova Nina V. | High impact poly (urethane urea) polysulfides |
| US7144969B2 (en) * | 2001-11-16 | 2006-12-05 | Ppg Industries Ohio, Inc. | Impact resistant polyureaurethane and polyureaurethane prepolymer having low NCO/OH ratio |
| US20040138401A1 (en) | 2002-11-05 | 2004-07-15 | Nina Bojkova | High impact poly (urethane urea) polysulfides |
| US20060241273A1 (en) | 2001-11-16 | 2006-10-26 | Bojkova Nina V | High impact poly (urethane urea) polysulfides |
| US8017720B2 (en) | 2005-12-16 | 2011-09-13 | Ppg Industries Ohio, Inc. | Sulfur-containing oligomers and high index polyurethanes prepared therefrom |
| US20070142606A1 (en) * | 2005-12-16 | 2007-06-21 | Bojkova Nina V | Polyurethane (ureas) and sulfur-containing polyurethane (ureas) methods of preparation |
| US20050282991A1 (en) * | 2001-11-16 | 2005-12-22 | Bojkova Nina V | High impact poly (urethane urea) polysulfides |
| US7097549B2 (en) * | 2001-12-20 | 2006-08-29 | Ppg Industries Ohio, Inc. | Polishing pad |
| CN100519612C (zh) | 2002-12-20 | 2009-07-29 | Ppg工业俄亥俄公司 | 高冲击强度聚(氨酯-脲)聚硫化物 |
| US7009032B2 (en) | 2002-12-20 | 2006-03-07 | Ppg Industries Ohio, Inc. | Sulfide-containing polythiols |
| EP1650275B1 (en) * | 2003-07-24 | 2013-06-26 | Mitsubishi Gas Chemical Company, Inc. | Coating composition, coating film made of same, and optical article |
| KR101136478B1 (ko) * | 2004-04-19 | 2012-04-20 | 썬룩스 컴퍼니 리미티드 | 편광 플라스틱 광학 소자 및 그의 제조 방법 |
| US20070148471A1 (en) * | 2004-09-01 | 2007-06-28 | Rukavina Thomas G | Impact resistant polyurethane and poly(ureaurethane) articles and methods of making the same |
| US8889815B2 (en) * | 2004-09-01 | 2014-11-18 | Ppg Industries Ohio, Inc. | Reinforced polyurethanes and poly(ureaurethane)s, methods of making the same and articles prepared therefrom |
| US8399559B2 (en) * | 2004-09-01 | 2013-03-19 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US11591436B2 (en) | 2004-09-01 | 2023-02-28 | Ppg Industries Ohio, Inc. | Polyurethane article and methods of making the same |
| US9598527B2 (en) * | 2004-09-01 | 2017-03-21 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US8927675B2 (en) * | 2004-09-01 | 2015-01-06 | Ppg Industries Ohio, Inc. | Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same |
| US9464169B2 (en) | 2004-09-01 | 2016-10-11 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US11149107B2 (en) | 2004-09-01 | 2021-10-19 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US11008418B2 (en) | 2004-09-01 | 2021-05-18 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US8859680B2 (en) * | 2004-09-01 | 2014-10-14 | Ppg Industries Ohio, Inc | Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same |
| US8734951B2 (en) * | 2004-09-01 | 2014-05-27 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US8399094B2 (en) * | 2004-09-01 | 2013-03-19 | Ppg Industries Ohio, Inc. | Multilayer laminated articles including polyurethane and/or poly(ureaurethane) layers and methods of making the same |
| US8653220B2 (en) * | 2004-09-01 | 2014-02-18 | Ppg Industries Ohio, Inc. | Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same |
| US20070167601A1 (en) * | 2004-09-01 | 2007-07-19 | Rukavina Thomas G | Polyurethanes prepared from polycarbonate polyols, articles and coatings prepared therefrom and methods of making the same |
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| US20070173601A1 (en) * | 2004-09-01 | 2007-07-26 | Rukavina Thomas G | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US8349986B2 (en) * | 2004-09-01 | 2013-01-08 | Ppg Industries Ohio, Inc. | Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same |
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| US20070225468A1 (en) * | 2004-09-01 | 2007-09-27 | Rukavina Thomas G | Polyurethanes prepared from polyester polyols and/or polycaprolactone polyols, articles and coatings prepared therefrom and methods of making the same |
| US20060089095A1 (en) * | 2004-10-27 | 2006-04-27 | Swisher Robert G | Polyurethane urea polishing pad |
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| JP5230442B2 (ja) | 2005-12-16 | 2013-07-10 | ピーピージー・インダストリーズ・オハイオ・インコーポレイテッド | ポリウレタン、ポリウレタン(ウレア)、硫黄含有ポリウレタンおよび硫黄含有ポリウレタン(ウレア)ならびに調製方法 |
| US7553925B2 (en) | 2006-05-05 | 2009-06-30 | Ppg Industries Ohio, Inc. | Thioether functional oligomeric polythiols and articles prepared therefrom |
| US20080071016A1 (en) * | 2006-09-14 | 2008-03-20 | Ppg Industries Ohio, Inc. | Polyureaurethane composition having improved color stability |
| JP5175732B2 (ja) * | 2006-09-21 | 2013-04-03 | 三井化学株式会社 | ポリチオウレタン系光学材料用重合触媒、それを含む重合性組成物、それより得られる成形体、及びポリチオウレタン樹脂の製造方法 |
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| AU2011286681B2 (en) | 2010-08-06 | 2014-01-16 | Tokuyama Corporation | Photochromic composition |
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| US20120286435A1 (en) | 2011-03-04 | 2012-11-15 | Ppg Industries Ohio, Inc. | Process for preparing molded optical articles |
| US20130119585A1 (en) | 2011-11-01 | 2013-05-16 | Marvin J. Graham | Method for preparing polymeric sheets derived from polyisocyanates |
| ITMI20112102A1 (it) * | 2011-11-18 | 2013-05-19 | Acomon Ag | Composizione polimerizzabile, articolo ottico ottenuto dalla stessa e metodo per la produzione di detto articolo ottico |
| WO2013146481A1 (ja) * | 2012-03-27 | 2013-10-03 | Hoya株式会社 | プラスチックレンズの製造方法 |
| US9353209B2 (en) * | 2012-04-23 | 2016-05-31 | Covestro Deutschland Ag | Lightfast polyurethane compositions |
| US9778396B2 (en) * | 2012-06-26 | 2017-10-03 | Mitsui Chemicals, Inc. | Polymerizable composition for optical material, optical material obtained from same composition, and plastic lens |
| CN104755520B (zh) * | 2012-11-16 | 2018-10-09 | 三井化学株式会社 | 聚合性组合物、光学材料及其制造方法 |
| EP2924056B1 (en) * | 2012-11-21 | 2017-06-21 | Mitsui Chemicals, Inc. | Polyurethane resin production method |
| US9568643B2 (en) | 2012-12-13 | 2017-02-14 | Ppg Industries Ohio, Inc. | Polyurethane urea-containing compositions and optical articles and methods for preparing them |
| EP2801586B1 (de) | 2013-05-07 | 2016-04-13 | Bruno Bock Chemische Fabrik GmbH & Co. KG | Gießharz auf Polythiourethanbasis mit hoher Bruchfestigkeit und niedrigem spezifischen Gewicht |
| CN103289054A (zh) * | 2013-05-30 | 2013-09-11 | 长春工业大学 | 一种木糖醇芳香型聚氨酯 |
| KR101930604B1 (ko) * | 2013-12-10 | 2018-12-18 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 폴리우레탄 우레아-함유 조성물 및 광학 물품 및 이의 제조 방법 |
| WO2015125817A1 (ja) * | 2014-02-20 | 2015-08-27 | 三井化学株式会社 | 光学材料の製造方法 |
| US20170052284A1 (en) * | 2015-08-21 | 2017-02-23 | Ppg Industries Ohio, Inc. | Batch Process for Preparing Molded Optical Articles |
| JP6698170B2 (ja) * | 2016-10-31 | 2020-05-27 | 三井化学株式会社 | 光学材料用重合性組成物、光学材料およびその製造方法 |
| KR101831889B1 (ko) * | 2017-02-03 | 2018-02-26 | 에스케이씨 주식회사 | 플라스틱 렌즈용 폴리티올 조성물 |
| KR20190042190A (ko) | 2017-10-16 | 2019-04-24 | 에스케이씨 주식회사 | 공정성이 개선된 폴리티오우레탄계 화합물의 제조방법 |
| EP3743453A4 (en) * | 2018-01-25 | 2021-10-20 | Novol, Inc. | SORBITOL-BASED CROSS-LINKED OPTICAL POLYMERS |
| CN112500549B (zh) * | 2019-09-16 | 2021-12-28 | 西安交通大学 | 一种可回收形状记忆热固性树脂的合成及回收再加工方法 |
| CN110563908A (zh) * | 2019-09-23 | 2019-12-13 | 西北工业大学 | 一种可再加工、自修复硫代聚氨酯材料及制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2636636B1 (fr) * | 1988-09-16 | 1992-09-04 | Alsthom Gec | Melanges stables a temperature ambiante de resines reactives thermodurcissables, complexes catalyseurs latents de durcissement de ces melanges, leurs procedes de fabrication et resines thermodurcies obtenues a partir de ces melanges |
| JP2950862B2 (ja) * | 1989-08-29 | 1999-09-20 | 三井化学株式会社 | チオカルバミン酸s―アルキルエステル系レンズおよびその製造方法 |
| CA2047301A1 (en) * | 1990-07-30 | 1992-01-31 | Takeyoshi Yamada | Plural liquid pack type, heat-curable polyisocyanate-polyol-polyepoxy resin composition and process for producing a shaped resin article therefrom |
-
1995
- 1995-03-29 US US08/413,113 patent/US5693738A/en not_active Expired - Lifetime
- 1995-04-07 EP EP95302322A patent/EP0676429B1/en not_active Expired - Lifetime
- 1995-04-07 DE DE69519696T patent/DE69519696T2/de not_active Expired - Lifetime
- 1995-04-07 TW TW084103455A patent/TW281679B/zh not_active IP Right Cessation
- 1995-04-08 KR KR1019950008184A patent/KR100191067B1/ko not_active Expired - Lifetime
- 1995-04-08 CN CN95102316A patent/CN1056858C/zh not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3661885A (en) * | 1967-05-01 | 1972-05-09 | Nuodex Ltd | Polyurethane catalyst |
| US4327204A (en) * | 1979-04-11 | 1982-04-27 | Ihara Chemical Industry Co., Ltd. | Process for producing polyurethane elastomer by mixing a hardener composition with an isocyanate composition |
| US4975328A (en) * | 1987-09-22 | 1990-12-04 | Hoya Corporation | Process for producing polyurethane lens |
| US5223598A (en) * | 1990-07-30 | 1993-06-29 | Teijin Limited | Plural liquid pack type, heat-curable polyisocyanate-polyol-polyepoxy resin composition and process for producing a shaped resin article therefrom |
| EP0562966A2 (en) * | 1992-03-24 | 1993-09-29 | Daiso Co., Ltd. | A cyclic sulfide compound, polymerizable compositions for optical products and optical products formed thereof |
| JP3084021B1 (ja) * | 1999-05-18 | 2000-09-04 | 日本レック株式会社 | 電子部品の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW281679B (cg-RX-API-DMAC7.html) | 1996-07-21 |
| EP0676429A2 (en) | 1995-10-11 |
| DE69519696D1 (de) | 2001-02-01 |
| US5693738A (en) | 1997-12-02 |
| EP0676429A3 (en) | 1996-06-26 |
| KR950029290A (ko) | 1995-11-22 |
| KR100191067B1 (ko) | 1999-06-15 |
| CN1119195A (zh) | 1996-03-27 |
| EP0676429B1 (en) | 2000-12-27 |
| DE69519696T2 (de) | 2001-06-13 |
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