CN105129870A - 无机化合物 - Google Patents
无机化合物 Download PDFInfo
- Publication number
- CN105129870A CN105129870A CN201510386454.1A CN201510386454A CN105129870A CN 105129870 A CN105129870 A CN 105129870A CN 201510386454 A CN201510386454 A CN 201510386454A CN 105129870 A CN105129870 A CN 105129870A
- Authority
- CN
- China
- Prior art keywords
- mixed metal
- lithium
- compound according
- hydroxide
- metal hydroxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000002484 inorganic compounds Chemical class 0.000 title description 2
- 229910010272 inorganic material Inorganic materials 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 52
- 239000002243 precursor Substances 0.000 claims abstract description 36
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 35
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 18
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 5
- 239000010406 cathode material Substances 0.000 claims abstract description 4
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 55
- 150000004692 metal hydroxides Chemical class 0.000 claims description 55
- 229910052751 metal Inorganic materials 0.000 claims description 40
- 239000002184 metal Substances 0.000 claims description 40
- 230000003647 oxidation Effects 0.000 claims description 35
- 238000007254 oxidation reaction Methods 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 23
- 239000000725 suspension Substances 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 11
- 238000007873 sieving Methods 0.000 claims description 11
- 239000011149 active material Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 238000001354 calcination Methods 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000012266 salt solution Substances 0.000 claims description 7
- 238000000975 co-precipitation Methods 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 239000011163 secondary particle Substances 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 230000009466 transformation Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 56
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- 239000000243 solution Substances 0.000 description 29
- 239000011572 manganese Substances 0.000 description 21
- 239000000047 product Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- 239000012071 phase Substances 0.000 description 16
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 15
- 229910017052 cobalt Inorganic materials 0.000 description 14
- 239000010941 cobalt Substances 0.000 description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 14
- 238000001556 precipitation Methods 0.000 description 14
- 239000012467 final product Substances 0.000 description 13
- 150000004679 hydroxides Chemical class 0.000 description 13
- 239000012535 impurity Substances 0.000 description 13
- 229910052759 nickel Inorganic materials 0.000 description 13
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 6
- 229910052808 lithium carbonate Inorganic materials 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- 239000012798 spherical particle Substances 0.000 description 5
- 241000080590 Niso Species 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000012527 feed solution Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- SEVNKUSLDMZOTL-UHFFFAOYSA-H cobalt(2+);manganese(2+);nickel(2+);hexahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mn+2].[Co+2].[Ni+2] SEVNKUSLDMZOTL-UHFFFAOYSA-H 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 description 3
- 239000012086 standard solution Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 239000000320 mechanical mixture Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910003160 β-NiOOH Inorganic materials 0.000 description 2
- 229910006279 γ-NiOOH Inorganic materials 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910020632 Co Mn Inorganic materials 0.000 description 1
- 229910020678 Co—Mn Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910032387 LiCoO2 Inorganic materials 0.000 description 1
- 229910015915 LiNi0.8Co0.2O2 Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- -1 Na + Chemical class 0.000 description 1
- 229910018060 Ni-Co-Mn Inorganic materials 0.000 description 1
- 229910006025 NiCoMn Inorganic materials 0.000 description 1
- 229910018209 Ni—Co—Mn Inorganic materials 0.000 description 1
- IQNRLBUERLDDJA-UHFFFAOYSA-N O(O)O.[Co].[Mn].[Ni] Chemical compound O(O)O.[Co].[Mn].[Ni] IQNRLBUERLDDJA-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000003834 hydroxide co-precipitation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 238000013386 optimize process Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000003260 vortexing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/80—Compounds containing cobalt, with or without oxygen or hydrogen, and containing one or more other elements
- C01G51/82—Compounds containing cobalt, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Compounds Of Iron (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005038158 | 2005-08-12 | ||
| DE102005038158.8 | 2005-08-12 | ||
| CNA2006800336317A CN101282911A (zh) | 2005-08-12 | 2006-08-08 | 无机化合物 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006800336317A Division CN101282911A (zh) | 2005-08-12 | 2006-08-08 | 无机化合物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105129870A true CN105129870A (zh) | 2015-12-09 |
Family
ID=37106922
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510386454.1A Pending CN105129870A (zh) | 2005-08-12 | 2006-08-08 | 无机化合物 |
| CNA2006800336317A Pending CN101282911A (zh) | 2005-08-12 | 2006-08-08 | 无机化合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006800336317A Pending CN101282911A (zh) | 2005-08-12 | 2006-08-08 | 无机化合物 |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US20090302267A1 (https=) |
| EP (1) | EP1912899B1 (https=) |
| JP (2) | JP5353239B2 (https=) |
| KR (1) | KR101306532B1 (https=) |
| CN (2) | CN105129870A (https=) |
| CA (1) | CA2618780C (https=) |
| TW (1) | TW200718651A (https=) |
| WO (1) | WO2007019986A1 (https=) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4846309B2 (ja) * | 2005-09-09 | 2011-12-28 | 株式会社田中化学研究所 | ニッケルマンガンコバルト複合酸化物の製造方法 |
| JP5109423B2 (ja) * | 2007-03-19 | 2012-12-26 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質およびその製造方法 |
| DE102007039471A1 (de) * | 2007-08-21 | 2009-02-26 | H.C. Starck Gmbh | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien |
| DE102007049108A1 (de) * | 2007-10-12 | 2009-04-16 | H.C. Starck Gmbh | Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien |
| HUE060257T2 (hu) * | 2008-04-03 | 2023-02-28 | Lg Energy Solution Ltd | Új prekurzor lítium kompozit átmenetifém-oxid elõállítására |
| CN106395918A (zh) * | 2009-10-22 | 2017-02-15 | 户田工业株式会社 | 镍-钴-锰类化合物颗粒粉末和锂复合氧化物颗粒粉末及其制造方法和非水电解质二次电池 |
| CN102612495A (zh) * | 2009-11-20 | 2012-07-25 | 住友化学株式会社 | 过渡金属复合氢氧化物和锂复合金属氧化物 |
| PL2605312T3 (pl) | 2010-08-09 | 2018-11-30 | Zeon Corporation | Porowata membrana do baterii akumulatorowej, sposób jej produkcji i jej zastosowanie |
| JP5842478B2 (ja) * | 2010-09-06 | 2016-01-13 | 住友化学株式会社 | リチウム複合金属酸化物およびその製造方法 |
| HRP20160974T1 (hr) * | 2010-09-22 | 2016-10-07 | Freeport Cobalt Oy | Mješavina oksidiranog hidroksid metala i postupak za proizvodnju |
| KR101432628B1 (ko) * | 2010-09-30 | 2014-08-22 | 에스케이이노베이션 주식회사 | 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지 |
| US10128501B2 (en) | 2011-06-07 | 2018-11-13 | Sumitomo Metal Mining Co., Ltd. | Nickel composite hydroxide and manufacturing method thereof, cathode active material for nonaqueous-electrolyte secondary battery and manufacturing method thereof, and nonaqueous-electrolyte secondary battery |
| BR112014031358B8 (pt) * | 2012-07-09 | 2023-01-17 | Lg Chemical Ltd | Método para preparar um composto de metal de transição compósito de um precursor de metal de transição |
| CA2888419A1 (en) | 2012-10-17 | 2014-04-24 | Toda Kogyo Corp. | Li-ni composite oxide particles and process for producing the same, and non-aqueous electrolyte secondary battery |
| WO2014061654A1 (ja) * | 2012-10-17 | 2014-04-24 | 戸田工業株式会社 | Ｌｉ－Ｎｉ複合酸化物粒子粉末並びに非水電解質二次電池 |
| JP2014139119A (ja) * | 2012-12-20 | 2014-07-31 | Tosoh Corp | ニッケル−コバルト−マンガン系複合酸化物及びその製造方法、並びにその用途 |
| CN103178263A (zh) * | 2013-02-21 | 2013-06-26 | 湖南桑顿新能源有限公司 | 一种镍钴铝酸锂正极材料的制备方法 |
| JP6136604B2 (ja) * | 2013-06-10 | 2017-05-31 | 住友金属鉱山株式会社 | ニッケルコバルト複合水酸化物粒子の製造方法 |
| JP6186919B2 (ja) * | 2013-06-17 | 2017-08-30 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6044463B2 (ja) * | 2013-06-19 | 2016-12-14 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6357928B2 (ja) * | 2013-07-18 | 2018-07-18 | 東ソー株式会社 | ニッケル−マンガン系複合オキシ水酸化物及びその製造方法、並びにその用途 |
| TWI636613B (zh) * | 2013-07-18 | 2018-09-21 | 日商東曹股份有限公司 | 鎳－錳系複合氧氫氧化物及其製造方法、以及其用途 |
| WO2016013674A1 (ja) * | 2014-07-25 | 2016-01-28 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物粒子およびその製造方法 |
| KR20160083616A (ko) * | 2014-12-31 | 2016-07-12 | 삼성에스디아이 주식회사 | 리튬이차전지용 양극 활물질의 전구체, 그 제조방법, 리튬이차전지용 양극 활물질, 그 제조방법, 및 상기 양극 활물질을 포함하는 리튬이차전지 |
| JP5967264B2 (ja) * | 2015-05-22 | 2016-08-10 | 住友金属鉱山株式会社 | 非水系電解質二次電池の正極活物質の製造方法 |
| KR101768374B1 (ko) | 2016-04-29 | 2017-08-14 | 주식회사 엘지화학 | 복합 전이금속산화물계 전구체 및 이의 제조방법, 상기 전구체를 이용한 양극활물질 |
| PL3281915T3 (pl) * | 2016-08-10 | 2019-09-30 | Umicore | Prekursory materiałów katody zawierających tlenek metalu przejściowego litu do baterii wielokrotnego ładowania |
| KR102322728B1 (ko) | 2017-03-14 | 2021-11-05 | 유미코아 | 개선된 이차 전지 성능을 갖는 캐소드 물질을 위한 전구체 및 그 전구체의 제조 방법 |
| WO2019117027A1 (ja) * | 2017-12-13 | 2019-06-20 | 住友金属鉱山株式会社 | ニッケル含有水酸化物およびその製造方法 |
| WO2019172637A2 (ko) | 2018-03-09 | 2019-09-12 | 주식회사 엘지화학 | 리튬 이차전지 |
| KR20190106638A (ko) | 2018-03-09 | 2019-09-18 | 주식회사 엘지화학 | 리튬 이차전지 |
| JP7262230B2 (ja) * | 2019-01-22 | 2023-04-21 | 株式会社田中化学研究所 | 非水電解質二次電池用複合水酸化物小粒子 |
| EP4012806A4 (en) * | 2019-08-06 | 2023-09-06 | Tanaka Chemical Corporation | Nickel composite hydroxide particles, positive electrode active material having nickel composite hydroxide particles as precursors, and method for producing positive electrode active material |
| US20230212028A1 (en) * | 2020-06-04 | 2023-07-06 | Basf Se | Process for making a particulate (oxy) hydroxide |
| WO2023038472A1 (ko) * | 2021-09-10 | 2023-03-16 | 주식회사 엘지에너지솔루션 | 리튬 이차 전지용 양극 활물질 분말, 이의 제조 방법, 리튬 이차 전지용 양극, 및 리튬 이차 전지 |
| US20240400411A1 (en) * | 2023-05-31 | 2024-12-05 | Sylvatex, Inc. | Method for the Manufacture of Cathode Materials |
| KR102941786B1 (ko) * | 2023-10-13 | 2026-03-19 | (주)에코프로머티리얼즈 | 리튬 이차 전지용 양극 활물질 전구체 및 이의 제조 방법 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2803104B1 (fr) * | 1999-12-23 | 2002-03-15 | Cit Alcatel | Electrode au nickel non frittee pour generateur electrochimique secondaire a electrolyte alcalin |
| US6350543B2 (en) * | 1999-12-29 | 2002-02-26 | Kimberly-Clark Worldwide, Inc. | Manganese-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries |
| JP3976482B2 (ja) * | 2000-08-08 | 2007-09-19 | 三洋電機株式会社 | アルカリ蓄電池用正極活物質の製造方法およびこの正極活物質を用いたニッケル電極ならびにこのニッケル電極を用いたアルカリ蓄電池 |
| JP2002201028A (ja) * | 2000-11-06 | 2002-07-16 | Tanaka Chemical Corp | 高密度コバルトマンガン共沈水酸化ニッケル及びその製造法 |
| US20020053663A1 (en) * | 2000-11-06 | 2002-05-09 | Tanaka Chemical Corporation | High density cobalt-manganese coprecipitated nickel hydroxide and process for its production |
| EP1424741A4 (en) * | 2001-09-03 | 2006-10-04 | Yuasa Battery Co Ltd | MATERIAL FOR NICKEL ELECTRODE AND PROCESS FOR PRODUCING THE SAME, NICKEL ELECTRODE AND ALKALINE BATTERY |
| JP2003346795A (ja) * | 2002-03-19 | 2003-12-05 | Tanaka Chemical Corp | 電解酸化によるオキシ水酸化ニッケルの製造方法 |
| NZ520452A (en) | 2002-10-31 | 2005-03-24 | Lg Chemical Ltd | Anion containing mixed hydroxide and lithium transition metal oxide with gradient of metal composition |
| NZ538480A (en) * | 2003-04-17 | 2007-12-21 | Seimi Chem Kk | Lithium-nickel-cobalt-manganese containing composite oxide, material for positive electrode active material for lithium secondary battery, and methods for producing these |
| JP4412936B2 (ja) * | 2003-07-31 | 2010-02-10 | パナソニック株式会社 | オキシ水酸化コバルトおよびその製造方法ならびにそれを用いたアルカリ蓄電池 |
-
2006
- 2006-08-08 CA CA2618780A patent/CA2618780C/en active Active
- 2006-08-08 JP JP2008525463A patent/JP5353239B2/ja active Active
- 2006-08-08 CN CN201510386454.1A patent/CN105129870A/zh active Pending
- 2006-08-08 KR KR1020087005942A patent/KR101306532B1/ko active Active
- 2006-08-08 WO PCT/EP2006/007816 patent/WO2007019986A1/de not_active Ceased
- 2006-08-08 US US11/990,273 patent/US20090302267A1/en not_active Abandoned
- 2006-08-08 CN CNA2006800336317A patent/CN101282911A/zh active Pending
- 2006-08-08 EP EP06776660A patent/EP1912899B1/de active Active
- 2006-08-10 TW TW095129295A patent/TW200718651A/zh unknown
-
2012
- 2012-06-04 US US13/487,477 patent/US20120305861A1/en not_active Abandoned
- 2012-11-01 JP JP2012241931A patent/JP5716001B2/ja active Active
-
2016
- 2016-09-16 US US15/267,167 patent/US10326133B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2618780C (en) | 2015-10-20 |
| US10326133B2 (en) | 2019-06-18 |
| CN101282911A (zh) | 2008-10-08 |
| US20170033358A1 (en) | 2017-02-02 |
| JP5353239B2 (ja) | 2013-11-27 |
| EP1912899A1 (de) | 2008-04-23 |
| CA2618780A1 (en) | 2007-02-22 |
| US20120305861A1 (en) | 2012-12-06 |
| JP2009515799A (ja) | 2009-04-16 |
| US20090302267A1 (en) | 2009-12-10 |
| KR101306532B1 (ko) | 2013-09-09 |
| EP1912899B1 (de) | 2012-10-10 |
| KR20080043347A (ko) | 2008-05-16 |
| TW200718651A (en) | 2007-05-16 |
| JP2013056827A (ja) | 2013-03-28 |
| JP5716001B2 (ja) | 2015-05-13 |
| WO2007019986A1 (de) | 2007-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10326133B2 (en) | Methods of making inorganic compounds | |
| EP3012889B1 (en) | Nickel-cobalt-manganese composite hydroxide, and production method therefor | |
| CN103563137B (zh) | 过渡金属复合氢氧化物及其制法、正极活性物质的制法 | |
| JP5638232B2 (ja) | 非水系電解質二次電池正極活物質用ニッケルコバルトマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 | |
| TWI753429B (zh) | 改善電池性能的穩定化高鎳nmc陰極材料 | |
| CN103534846B (zh) | 锂离子电池用正极活性物质及其制造方法 | |
| TWI622212B (zh) | 用於鋰離子電池的陰極組成物 | |
| CN103904323B (zh) | 一种球形羟基氧化钴的制备方法 | |
| JP6985406B2 (ja) | 改善された二次電池性能を有するカソード材料の前駆体及び前駆体を調製する方法 | |
| CN111129463A (zh) | 一种mof包覆的单晶三元正极材料及其前驱体的制备方法 | |
| KR20130097779A (ko) | 혼합 금속 산화 수산화물 및 그 제조 방법 | |
| JP2011116580A5 (https=) | ||
| JP2014520359A (ja) | サイズ依存性の組成を有する正極材料 | |
| US8956759B2 (en) | 3V class spinel complex oxides as cathode active materials for lithium secondary batteries, method for preparing the same by carbonate coprecipitation, and lithium secondary batteries using the same | |
| CN108878860A (zh) | 镍基正极材料、其前驱体及该材料和前驱体的制备方法 | |
| JP7064685B2 (ja) | ニッケルマンガン複合水酸化物の製造方法、および非水系電解質二次電池用正極活物質の製造方法 | |
| WO2023013494A1 (ja) | リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池 | |
| JP7338133B2 (ja) | 非水系電解質二次電池用正極活物質前駆体、非水系電解質二次電池用正極活物質前駆体の製造方法、非水系電解質二次電池用正極活物質の製造方法 | |
| JP7273260B2 (ja) | リチウムイオン二次電池用正極活物質とその製造方法およびリチウムイオン二次電池 | |
| JP2025511658A (ja) | リチウム酸化物含有正極材料前駆体とリチウム酸化物含有正極材料及びその調製方法と使用、正極シート及びその使用 | |
| JP2002338246A (ja) | リチウム・マンガン複合酸化物の製造方法及び該リチウム・マンガン複合酸化物を用いてなるリチウム電池 | |
| KR100668050B1 (ko) | 망간복합산화물, 이를 이용한 리튬이차전지 스피넬형양극활물질 및 그 제조방법 | |
| CN110997573A (zh) | 将钛均匀地引入固体材料 | |
| CN104203829B (zh) | 四氧化三锰及其制造方法 | |
| JP7417675B1 (ja) | 金属複合水酸化物粒子、金属複合化合物の製造方法、及びリチウム二次電池用正極活物質の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160425 Address after: Hiroshima County Applicant after: Toda Kogyo Corp. Address before: Dusseldorf Applicant before: Toda Kogyo Europ GmbH |
|
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151209 |
|
| RJ01 | Rejection of invention patent application after publication |