CN104870664A - 水系冷却剂 - Google Patents
水系冷却剂 Download PDFInfo
- Publication number
- CN104870664A CN104870664A CN201380068332.7A CN201380068332A CN104870664A CN 104870664 A CN104870664 A CN 104870664A CN 201380068332 A CN201380068332 A CN 201380068332A CN 104870664 A CN104870664 A CN 104870664A
- Authority
- CN
- China
- Prior art keywords
- water system
- quality
- system refrigerant
- acid salt
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002826 coolant Substances 0.000 title abstract 4
- 238000005260 corrosion Methods 0.000 claims abstract description 25
- 230000007797 corrosion Effects 0.000 claims abstract description 25
- -1 inorganic acid salt Chemical class 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229940071207 sesquicarbonate Drugs 0.000 claims abstract description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003507 refrigerant Substances 0.000 claims description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- 150000001875 compounds Chemical class 0.000 claims description 28
- 150000002739 metals Chemical class 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000010791 quenching Methods 0.000 claims description 10
- 239000012964 benzotriazole Substances 0.000 claims description 9
- 230000000171 quenching effect Effects 0.000 claims description 9
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 8
- 150000003016 phosphoric acids Chemical class 0.000 claims description 7
- 229920000388 Polyphosphate Polymers 0.000 claims description 5
- 239000001205 polyphosphate Substances 0.000 claims description 5
- 235000011176 polyphosphates Nutrition 0.000 claims description 5
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- OBISXEJSEGNNKL-UHFFFAOYSA-N dinitrogen-n-sulfide Chemical compound [N-]=[N+]=S OBISXEJSEGNNKL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 238000003754 machining Methods 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 235000010755 mineral Nutrition 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 3
- 159000000007 calcium salts Chemical class 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 claims description 3
- 159000000003 magnesium salts Chemical class 0.000 claims description 3
- 125000005341 metaphosphate group Chemical group 0.000 claims description 3
- 238000001816 cooling Methods 0.000 abstract description 30
- 239000003921 oil Substances 0.000 abstract description 14
- 238000010438 heat treatment Methods 0.000 abstract description 12
- 239000007769 metal material Substances 0.000 abstract description 11
- 239000003112 inhibitor Substances 0.000 abstract description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000010730 cutting oil Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 19
- 239000000243 solution Substances 0.000 description 10
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000013556 antirust agent Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002500 ions Chemical group 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 2
- 229960002026 pyrithione Drugs 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- XNRNJIIJLOFJEK-UHFFFAOYSA-N sodium;1-oxidopyridine-2-thione Chemical compound [Na+].[O-]N1C=CC=CC1=S XNRNJIIJLOFJEK-UHFFFAOYSA-N 0.000 description 2
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical compound C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- DRLNNBXBGGRLDJ-UHFFFAOYSA-N decanedioic acid;potassium Chemical compound [K].OC(=O)CCCCCCCCC(O)=O DRLNNBXBGGRLDJ-UHFFFAOYSA-N 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical class OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003330 sebacic acids Chemical class 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 150000003441 suberic acid derivatives Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940066771 systemic antihistamines piperazine derivative Drugs 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
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- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/10—Metal oxides, hydroxides, carbonates or bicarbonates
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- C10M125/24—Compounds containing phosphorus, arsenic or antimony
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- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
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- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/40—Six-membered ring containing nitrogen and carbon only
- C10M133/42—Triazines
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/20—Thiols; Sulfides; Polysulfides
- C10M135/28—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to a carbon atom of a six-membered aromatic ring
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/32—Heterocyclic sulfur, selenium or tellurium compounds
- C10M135/36—Heterocyclic sulfur, selenium or tellurium compounds the ring containing sulfur and carbon with nitrogen or oxygen
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- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/58—Oils
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/60—Aqueous agents
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/043—Sulfur; Selenenium; Tellurium
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/081—Inorganic acids or salts thereof containing halogen
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/09—Heterocyclic compounds containing no sulfur, selenium or tellurium compounds in the ring
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Abstract
水系冷却剂配合有选自碳酸盐、碳酸氢盐、倍半碳酸盐、磷酸盐、硼酸盐、钼酸盐、以及钨酸盐中的1种以上的无机酸盐与金属抗腐蚀剂。本发明的水系冷却剂具有高的冷却性能,且成为冷却对象的金属材料难以产生腐蚀。因此,本发明的水系冷却剂适合作为热处理油或切削油。
Description
技术领域
本发明涉及水系冷却剂,详细而言,涉及金属部件的淬火等中使用的水系冷却剂。
背景技术
金属部件的淬火中使用的冷却剂(热处理液)大致分为油系和水系(水溶液),广泛使用油系的热处理液。这是因为:油系的热处理液具有适度的冷却性能,淬火形变小、不用担心发生淬裂。
另一方面,尤其是在大的金属部件、淬火性差的金属部件的情况下,油系热处理液的冷却速度慢、冷却性能不足,因此可以使用水系的热处理液。然而,水系热处理液与油系热处理液相比冷却性能更高,因此容易产生冷却不均、有可能淬裂。
作为提高耐冷却不均性能的技术,一直以来已知有基于食盐水的淬火。食盐水没有蒸汽膜阶段,因此具有高的冷却性能且耐冷却不均性能高、淬裂少(参照非专利文献1)。但是,将食盐水用作热处理液时,在热处理后1小时以内这一极短的时间内生锈,对油槽等设备的腐蚀也显著,因此工业上基本无法使用。
因而,提出了通过含有甲酸或乙酸等有机酸、盐酸或硫酸等无机酸、或者它们的盐的水系热处理液来提高冷却速度(参照专利文献1、2)。
现有技术文献
专利文献
专利文献1:日本特开昭64-42521号公报
专利文献2:日本特开平1-259119号公报
非专利文献
非专利文献1:大和久重雄、“思考淬裂”、热处理、1967年6月、第7卷、第3号、p.140~144。
发明内容
发明要解决的问题
然而,专利文献1、2的水系热处理液中均有可能使成为冷却对象的金属材料产生腐蚀。
本发明的目的在于,提供具有高的冷却性能且成为冷却对象的金属材料难以腐蚀的水系冷却剂。
用于解决问题的手段
为了解决前述课题,本发明提供以下那样的水系冷却剂。
(1)水系冷却剂,其特征在于,其配合有选自碳酸盐、碳酸氢盐、倍半碳酸盐、磷酸盐、硼酸盐、钼酸盐、以及钨酸盐中的1种以上的无机酸盐与金属抗腐蚀剂。
(2)水系冷却剂,其特征在于,在上述水系冷却剂中,前述金属抗腐蚀剂为选自苯并三唑系化合物、苯并咪唑系化合物、苯并噻唑系化合物、以及苯并噻二唑系化合物中的1种以上的化合物。
(3)水系冷却剂,其特征在于,在上述水系冷却剂中,其还配合有杀菌剂。
(4)水系冷却剂,其特征在于,在上述水系冷却剂中,前述杀菌剂的配合量以该冷却剂总量基准计为0.001质量%以上且0.5质量%以下。
(5)水系冷却剂,其特征在于,在上述水系冷却剂中,前述无机酸盐的配合量以该冷却剂总量基准计为1质量%以上且20质量%以下。
(6)水系冷却剂,其特征在于,在上述水系冷却剂中,前述金属抗腐蚀剂的配合量以该冷却剂总量基准计为0.01质量%以上且1质量%以下。
(7)水系冷却剂,其特征在于,在上述水系冷却剂中,前述无机酸盐为无机酸的金属盐。
(8)水系冷却剂,其特征在于,在上述水系冷却剂中,前述无机酸盐为钠盐、钾盐、钙盐、以及镁盐中的至少任一者。
(9)水系冷却剂,其特征在于,在上述水系冷却剂中,前述磷酸盐为正磷酸盐、磷酸氢盐、磷酸二氢盐、多磷酸盐、以及偏磷酸盐中的至少任一者。
(10)水系冷却剂,其特征在于,上述水系冷却剂为淬火油或切削油。
根据本发明,能够提供具有极高冷却性能且成为冷却对象的金属材料难以产生腐蚀的水系冷却剂。
具体实施方式
本发明的水系冷却剂(以下,有时简称为“本冷却剂”。)是配合有特定无机酸盐与金属抗腐蚀剂的水溶液。以下详细说明。
作为本冷却剂中使用的无机酸盐,可列举出碳酸盐、碳酸氢盐、倍半碳酸盐、磷酸盐、硫酸盐、硼酸盐、钼酸盐、以及钨酸盐。它们可单独使用,也可以混合使用。
上述无机酸盐之中,从冷却效果的观点出发,优选为碳酸盐、碳酸氢盐、倍半碳酸盐、以及磷酸盐。另外,碳酸盐与碳酸氢盐从调节pH的观点出发优选混合而使用。
作为磷酸盐,可以为正磷酸盐、磷酸氢盐、磷酸二氢盐、多磷酸盐、以及偏磷酸盐中的任一者。作为多磷酸盐,可列举出二磷酸盐(焦磷酸盐)、三多磷酸盐等。这些之中,从冷却效果的观点出发,优选为焦磷酸盐。这些各磷酸盐可以单独使用,也可以混合使用。另外,它们也可以与前述无机盐混合使用。
作为这样的无机酸盐,优选为金属盐,具体而言,可列举出钠盐、钾盐、钙盐、以及镁盐等。这些之中,从冷却性的观点出发,优选为钠盐、钾盐。
另外,作为本冷却剂中的pH,从防腐败的观点出发,优选为7以上。
本冷却剂中的无机酸盐的优选配合量以该冷却剂总量基准计为1质量%以上且20质量%以下,进一步优选的配合量为3质量%以上且15质量%。无机酸盐的配合量不足1质量%时,冷却效果有可能不充分。另一方面,无机酸盐的配合量即使超过20质量%,也无法期待相应的冷却效果的提高。
本冷却剂中配合有金属抗腐蚀剂。作为金属抗腐蚀剂,适合为苯并三唑系化合物、苯并咪唑系化合物、苯并噻唑系化合物、以及苯并噻二唑系化合物等。它们可单独使用,也可以混合使用。
此处,苯并三唑系化合物是指苯并三唑本身、其衍生物。针对苯并咪唑系化合物、苯并噻唑系化合物、以及苯并噻二唑系化合物也是相同的。
例如,作为苯并三唑系化合物,可列举出苯环上取代有烷基的烷基苯并三唑、以及氨基氢被烷基取代而成的(烷基)氨基烷基苯并三唑等。
作为这样的金属抗腐蚀剂的配合量,以本冷却剂总量基准计优选为0.01质量%以上且1质量%以下、更优选为0.1质量%以上且0.7质量%以下。金属抗腐蚀剂的配合量不足0.01质量%时,金属抗腐蚀效果有可能不充分。另一方面,金属抗腐蚀剂的配合量即使超过1质量%,也无法期待相应的金属抗腐蚀效果的提高。
本冷却剂根据需要还可以配合杀菌剂。作为杀菌剂,可列举出苯并异噻唑啉系化合物、异噻唑啉系化合物、三嗪系化合物、以及吡啶硫酮系化合物等。苯并异噻唑啉系化合物是指苯并异噻唑啉本身、其衍生物。其它化合物也是同样的。
具体而言,作为苯并异噻唑啉系化合物,可列举出苯并异噻唑啉、1,2-苯并异噻唑啉-3-酮、2-甲基异噻唑啉-3-酮、以及5-氯-2-甲基-4-异噻唑啉-3-酮等。作为三嗪系化合物,可列举出六氢-1,3,5-三-(2-羟基乙基)三嗪等。作为吡啶硫酮系化合物,可列举出吡啶硫酮钠等。
作为这种杀菌剂的配合量,以本冷却剂总量基准计优选为0.001质量%以上且0.5质量%以下、更优选为0.01质量%以上且0.4质量%以下。杀菌剂的配合量不足0.001质量%时,杀菌效果有可能不充分。另一方面,杀菌剂的配合量即使超过0.5质量%,也无法期待相应的杀菌效果的提高。
本冷却剂中根据需要还可以配合水溶性防锈剂。水溶性防锈剂的配合量从防锈性能的提高和经济性的平衡等方面出发以本冷却剂总量基准计优选为0.01质量%以上且5质量%以下、更优选为0.03质量%以上且1质量%以下。作为这种水溶性防锈剂,可列举出辛酸盐等脂肪族单羧酸盐、辛烷二酸(辛二酸)盐、癸烷二酸(癸二酸)盐等脂肪族二羧酸盐,可适合地使用例如癸二酸钾等。需要说明的是,作为水溶性防锈剂,也可以为芳香族羧酸盐。另外,作为水溶性防锈剂,也可以适合地使用单羟基单乙基哌嗪等哌嗪衍生物等。
本冷却剂中还可以配合通用的添加剂、例如抗氧化剂和清洗分散剂等。
本发明的水系冷却剂基本没有蒸汽膜阶段,因此具备高的冷却性能。进而,成为冷却对象的金属材料难以产生腐蚀,因此适合作为金属材料的淬火油、切削油。
实施例
接着,通过实施例、比较例来更详细地说明本发明,但本发明不受这些例子的任何限定。
[实施例1~16、比较例1~5]
(试样液的制备)
向离子交换水中配合以下添加剂而制成试样液。需要说明的是,将各试样液的pH也合并记载于表1。参考例仅使用完全未配合添加剂的离子交换水。
无机酸盐等(参照表1):以试样液基准计为10质量%
金属抗腐蚀剂(苯并三唑):以试样液基准计为0.5质量%
杀菌剂:
实施例1~3、9~16、比较例1~5:苯并异噻唑啉(有效成分量为7质量%)以试样液基准计为0.05质量%(试样液中的浓度:0.0035质量%)
实施例4:苯并异噻唑啉以试样液基准计为0.15质量%(试样液中的浓度为0.0108质量%)
实施例5:六氢-1,3,5-三-(2-羟基乙基)三嗪以试样液基准计为0.1质量%(试样液中的浓度为0.080质量%)
实施例6:5-氯-2-甲基-4-异噻唑啉-3-酮以试样液基准计为0.3质量%(试样液中的浓度为0.0060质量%)
实施例7:5-氯-2-甲基-4-异噻唑啉-3-酮以试样液基准计为0.05质量%(试样液中的浓度为0.0010质量%)
实施例8:吡啶硫酮钠以试样液基准计为0.05质量%(试样液中的浓度为0.020质量%)
需要说明的是,实施例15和16是相对于实施例13分别进一步添加1.0质量%、3.0质量%的碳酸氢钠而成的,参考例仅使用完全未配合添加剂的离子交换水。
(冷却试验)
将各试样液保持于50℃,基于JIS K2242B法进行冷却试验,测定特性秒数。具体而言,测定冷却曲线中的达到蒸汽膜阶段结束的温度(特性温度)为止的时间(秒数)。将结果示于表1。
(金属腐蚀试验)
使用金属材料(S45C),以30℃进行3天半的浸渍试验,以如下基准评价腐蚀的程度。将结果示于表1。
A:不存在锈和变色
B:存在锈和变色中的任一者
(腐败试验)
相对于试样液100mL投入细菌5.5mL(大肠杆菌和枯草菌等细菌数:108),以30℃进行一周静置培养,计算细菌数。将结果示于表1。
[评价结果]
由表1的结果可知:本发明的水系冷却液为规定的无机酸盐的水溶液,因此特性秒数均非常短、冷却性能极高。而且,由于配合有金属抗腐蚀剂,难以使金属材料产生腐蚀。因此,可理解为对于金属材料的淬火、切削是极其有效的。
另外,本发明的水系冷却剂的基于杀菌剂的杀菌效果均优异,但比较例的水系冷却剂即使使用相同的杀菌剂,有时也不会发挥出其效果。
通常,水的液体温度达到30℃以上时,冷却性急剧降低、不会淬火。本发明的水系冷却剂即使在50℃的液体温度下也会发挥出优异的冷却性能,是应该特别说明的。
需要说明的是,完全未添加本发明规定的无机酸盐的参考例的离子交换水不会充分表现出冷却性能。另外,即使是无机酸的盐,即使添加与本发明的无机酸盐不同的盐、有机酸的盐,也无法提高冷却性能。
产业利用性
本发明的冷却剂具备高的冷却性能、成为冷却对象的金属材料难以产生腐蚀,因此可用作金属材料的热处理油(淬火油)、切削油。
Claims (10)
1.水系冷却剂,其特征在于,其配合有选自碳酸盐、碳酸氢盐、倍半碳酸盐、磷酸盐、硼酸盐、钼酸盐、以及钨酸盐中的1种的以上无机酸盐与金属抗腐蚀剂。
2.权利要求1所述的水系冷却剂,其特征在于,所述金属抗腐蚀剂为选自苯并三唑系化合物、苯并咪唑系化合物、苯并噻唑系化合物、以及苯并噻二唑系化合物中的1种以上的化合物。
3.权利要求1或权利要求2所述的水系冷却剂,其特征在于,其还配合有杀菌剂。
4.权利要求3所述的水系冷却剂,其特征在于,所述杀菌剂的配合量以该冷却剂总量基准计为0.001质量%以上且0.5质量%以下。
5.权利要求1~权利要求4中任一项所述的水系冷却剂,其特征在于,所述无机酸盐的配合量以该冷却剂总量基准计为1质量%以上且20质量%以下。
6.权利要求1~权利要求5中任一项所述的水系冷却剂,其特征在于,所述金属抗腐蚀剂的配合量以该冷却剂总量基准计为0.01质量%以上且1质量%以下。
7.权利要求1~权利要求6中任一项所述的水系冷却剂,其特征在于,所述无机酸盐为无机酸的金属盐。
8.权利要求7所述的水系冷却剂,其特征在于,所述无机酸盐为钠盐、钾盐、钙盐、以及镁盐中的至少任一者。
9.权利要求1~权利要求8中任一项所述的水系冷却剂,其特征在于,所述磷酸盐为正磷酸盐、磷酸氢盐、磷酸二氢盐、多磷酸盐、以及偏磷酸盐中的至少任一者。
10.权利要求1~权利要求9中任一项所述的水系冷却剂,其特征在于,该水系冷却剂为淬火油或切削油。
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JP2012286247A JP6227248B2 (ja) | 2012-12-27 | 2012-12-27 | 水系冷却剤 |
PCT/JP2013/083055 WO2014103697A1 (ja) | 2012-12-27 | 2013-12-10 | 水系冷却剤 |
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EP (1) | EP2940157A4 (zh) |
JP (1) | JP6227248B2 (zh) |
KR (1) | KR20150099740A (zh) |
CN (1) | CN104870664B (zh) |
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Cited By (5)
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CN106755816A (zh) * | 2016-12-29 | 2017-05-31 | 铜陵市金利电子有限公司 | 一种用于大型金属部件淬火的冷却剂 |
CN107058695A (zh) * | 2016-12-29 | 2017-08-18 | 铜陵市金利电子有限公司 | 一种高效水溶性淬冷剂 |
CN108342245A (zh) * | 2017-12-29 | 2018-07-31 | 江苏乐彩印刷材料有限公司 | 一种版材切割冷却剂 |
CN108684687A (zh) * | 2018-06-25 | 2018-10-23 | 杨飞 | 一种非氧化性杀菌灭藻剂及其制备方法 |
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Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4208344A (en) * | 1976-12-24 | 1980-06-17 | Ciba-Geigy Corporation | Phosphonoadipic acid additives to aqueous systems |
JPS59229496A (ja) * | 1983-05-14 | 1984-12-22 | Honda Motor Co Ltd | 鋼材の塗装前処理剤及び塗装前処理方法 |
CN1196079A (zh) * | 1995-07-20 | 1998-10-14 | 孟山都公司 | 改进的水溶性金属加工液 |
CN1362502A (zh) * | 2001-01-05 | 2002-08-07 | 中国石油化工股份有限公司 | 一种磨削-防锈两用油组合物 |
CN1995299A (zh) * | 2006-12-08 | 2007-07-11 | 中国石油化工股份有限公司 | 切削液组合物 |
JP2008189806A (ja) * | 2007-02-05 | 2008-08-21 | Showa Co Ltd | 冷却液組成物 |
CN102115807A (zh) * | 2009-12-30 | 2011-07-06 | 张家口天龙科技发展有限公司 | 螺纹钢淬火阻锈剂 |
JP2011168860A (ja) * | 2010-02-22 | 2011-09-01 | Idemitsu Kosan Co Ltd | 水系熱処理液組成物 |
CN102703194A (zh) * | 2012-05-28 | 2012-10-03 | 上海福岛化工科技发展有限公司 | 铝镁合金切削液 |
CN102822324A (zh) * | 2010-03-26 | 2012-12-12 | 株式会社Adeka | 润滑油组合物 |
CN102834493A (zh) * | 2010-03-26 | 2012-12-19 | 株式会社Adeka | 润滑油添加剂及含有其的润滑油组合物 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3618707A (en) * | 1970-06-16 | 1971-11-09 | Metal Chemicals Inc | Method of lubricating machine tools |
JPS5293635A (en) * | 1976-02-03 | 1977-08-06 | Nippon Steel Corp | Method of fabricating hot rolled steel strip*band*excellent in property to be pickled |
US4719035A (en) * | 1984-01-27 | 1988-01-12 | The United States Of America As Represented By The Secretary Of The Air Force | Corrosion inhibitor formulation for molybdenum tungsten and other metals |
JPS6442521A (en) | 1987-08-07 | 1989-02-14 | Sumitomo Metal Ind | Method for cooling metal |
FR2624875B1 (fr) * | 1987-12-17 | 1992-06-26 | Servimetal | Procede de modification du pouvoir refroidissant de milieux aqueux destines a la trempe d'alliages metalliques |
JPH02157088A (ja) | 1988-12-09 | 1990-06-15 | Nippon Steel Corp | 塩素系殺菌剤注入装置 |
JP3430462B2 (ja) | 1993-05-31 | 2003-07-28 | 出光興産株式会社 | 水系熱処理液 |
JP4460076B2 (ja) * | 1996-02-21 | 2010-05-12 | 出光興産株式会社 | 水溶性焼入れ液 |
JPH1150212A (ja) * | 1997-07-31 | 1999-02-23 | Mazda Motor Corp | 軽合金鋳物の熱処理方法 |
WO2000052230A1 (en) * | 1999-03-02 | 2000-09-08 | Chemax, Inc. | Corrosion inhibitor and process |
JP2002066871A (ja) | 2000-09-04 | 2002-03-05 | Enshu Ltd | 加工方法と極微小ミスト生成装置、ワークの冷却方法、主軸の冷却方法 |
JP4997581B2 (ja) * | 2001-03-07 | 2012-08-08 | 大同化学工業株式会社 | 水溶性熱処理液 |
US6572789B1 (en) * | 2001-04-02 | 2003-06-03 | Ondeo Nalco Company | Corrosion inhibitors for aqueous systems |
JP2003201580A (ja) | 2002-01-08 | 2003-07-18 | Sumitomo Precision Prod Co Ltd | チタン材仕上げ加工方法 |
JP4261884B2 (ja) | 2002-11-26 | 2009-04-30 | 株式会社ネオス | 水溶性金属加工油剤組成物 |
JPWO2006046275A1 (ja) * | 2004-10-25 | 2008-05-22 | シーシーアイ株式会社 | 不凍液/冷却液組成物 |
JP4876517B2 (ja) | 2005-10-05 | 2012-02-15 | 旭硝子株式会社 | 熱処理油組成物 |
US20070203323A1 (en) * | 2006-02-10 | 2007-08-30 | Gyorgyi Fenyvesi | Food compositions comprising biologically-based biodegradable 1,3-propanediol esters |
JP2008239917A (ja) | 2007-03-29 | 2008-10-09 | Nippon Fine Chem Co Ltd | 水系・水溶性潤滑組成物 |
JP2010270256A (ja) | 2009-05-22 | 2010-12-02 | Toyota Motor Corp | 高冷却性能冷却液 |
JP5571795B2 (ja) * | 2009-10-16 | 2014-08-13 | ダウ グローバル テクノロジーズ エルエルシー | ダイヤモンドワイヤーソーと共に使用する水性切削液 |
KR20140131941A (ko) | 2012-03-02 | 2014-11-14 | 이데미쓰 고산 가부시키가이샤 | 수계 냉각제 |
-
2012
- 2012-12-27 JP JP2012286247A patent/JP6227248B2/ja active Active
-
2013
- 2013-12-10 KR KR1020157015625A patent/KR20150099740A/ko not_active Application Discontinuation
- 2013-12-10 WO PCT/JP2013/083055 patent/WO2014103697A1/ja active Application Filing
- 2013-12-10 SG SG11201504501WA patent/SG11201504501WA/en unknown
- 2013-12-10 EP EP13867576.4A patent/EP2940157A4/en not_active Withdrawn
- 2013-12-10 US US14/651,410 patent/US20150315512A1/en not_active Abandoned
- 2013-12-10 CN CN201380068332.7A patent/CN104870664B/zh active Active
- 2013-12-18 TW TW102146935A patent/TWI623613B/zh active
-
2017
- 2017-05-12 US US15/594,171 patent/US10421924B2/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4208344A (en) * | 1976-12-24 | 1980-06-17 | Ciba-Geigy Corporation | Phosphonoadipic acid additives to aqueous systems |
JPS59229496A (ja) * | 1983-05-14 | 1984-12-22 | Honda Motor Co Ltd | 鋼材の塗装前処理剤及び塗装前処理方法 |
CN1196079A (zh) * | 1995-07-20 | 1998-10-14 | 孟山都公司 | 改进的水溶性金属加工液 |
CN1362502A (zh) * | 2001-01-05 | 2002-08-07 | 中国石油化工股份有限公司 | 一种磨削-防锈两用油组合物 |
CN1995299A (zh) * | 2006-12-08 | 2007-07-11 | 中国石油化工股份有限公司 | 切削液组合物 |
JP2008189806A (ja) * | 2007-02-05 | 2008-08-21 | Showa Co Ltd | 冷却液組成物 |
CN102115807A (zh) * | 2009-12-30 | 2011-07-06 | 张家口天龙科技发展有限公司 | 螺纹钢淬火阻锈剂 |
JP2011168860A (ja) * | 2010-02-22 | 2011-09-01 | Idemitsu Kosan Co Ltd | 水系熱処理液組成物 |
CN102822324A (zh) * | 2010-03-26 | 2012-12-12 | 株式会社Adeka | 润滑油组合物 |
CN102834493A (zh) * | 2010-03-26 | 2012-12-19 | 株式会社Adeka | 润滑油添加剂及含有其的润滑油组合物 |
CN102703194A (zh) * | 2012-05-28 | 2012-10-03 | 上海福岛化工科技发展有限公司 | 铝镁合金切削液 |
Non-Patent Citations (2)
Title |
---|
杰里•P•拜尔斯: "《金属加工液原著第二版》", 30 September 2011 * |
欧风: "《石油产品应用技术手册》", 30 June 1998 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106755816A (zh) * | 2016-12-29 | 2017-05-31 | 铜陵市金利电子有限公司 | 一种用于大型金属部件淬火的冷却剂 |
CN107058695A (zh) * | 2016-12-29 | 2017-08-18 | 铜陵市金利电子有限公司 | 一种高效水溶性淬冷剂 |
CN111247257A (zh) * | 2017-10-23 | 2020-06-05 | 诺维尔里斯公司 | 反应性淬火溶液及使用方法 |
CN108342245A (zh) * | 2017-12-29 | 2018-07-31 | 江苏乐彩印刷材料有限公司 | 一种版材切割冷却剂 |
CN108684687A (zh) * | 2018-06-25 | 2018-10-23 | 杨飞 | 一种非氧化性杀菌灭藻剂及其制备方法 |
Also Published As
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JP2014125680A (ja) | 2014-07-07 |
KR20150099740A (ko) | 2015-09-01 |
US10421924B2 (en) | 2019-09-24 |
SG11201504501WA (en) | 2015-07-30 |
EP2940157A4 (en) | 2016-08-24 |
US20170247633A1 (en) | 2017-08-31 |
US20150315512A1 (en) | 2015-11-05 |
WO2014103697A1 (ja) | 2014-07-03 |
EP2940157A1 (en) | 2015-11-04 |
JP6227248B2 (ja) | 2017-11-08 |
TWI623613B (zh) | 2018-05-11 |
TW201435074A (zh) | 2014-09-16 |
CN104870664B (zh) | 2018-05-04 |
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