CN1044573C - 用于甲醇氧化脱氢制备甲醛的催化剂颗粒 - Google Patents

用于甲醇氧化脱氢制备甲醛的催化剂颗粒 Download PDF

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Publication number
CN1044573C
CN1044573C CN92115016A CN92115016A CN1044573C CN 1044573 C CN1044573 C CN 1044573C CN 92115016 A CN92115016 A CN 92115016A CN 92115016 A CN92115016 A CN 92115016A CN 1044573 C CN1044573 C CN 1044573C
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radius
ratio
catalyst
particle
cross
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Expired - Fee Related
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Chinese (zh)
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CN1085124A (zh
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A·怀奥拉
M·布鲁莎
B·麦里吉
G·古比托沙
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Montecatini Technologie SA
Montecatini Tecnologie SRL
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Montecatini Technologie SA
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30223—Cylinder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/3023—Triangle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
CN92115016A 1992-10-06 1992-12-16 用于甲醇氧化脱氢制备甲醛的催化剂颗粒 Expired - Fee Related CN1044573C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI922301A IT1256156B (it) 1992-10-06 1992-10-06 Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide
ITMI92A002301 1992-10-06

Publications (2)

Publication Number Publication Date
CN1085124A CN1085124A (zh) 1994-04-13
CN1044573C true CN1044573C (zh) 1999-08-11

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CN92115016A Expired - Fee Related CN1044573C (zh) 1992-10-06 1992-12-16 用于甲醇氧化脱氢制备甲醛的催化剂颗粒

Country Status (13)

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US (2) US5330958A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0591572B9 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP3382983B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN1044573C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AT (1) ATE153880T1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2084870C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69220225T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DK (1) DK0591572T4 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2103870T5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GR (1) GR3024108T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IT (1) IT1256156B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2086299C1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW231973B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

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IT1274033B (it) * 1994-04-05 1997-07-14 Montecatini Tecnologie Srl Catalizzatore in granuli per la sintesi di 1-2 dicloroetano e preprocedimento di ossiclorurazione a letto fisso dell'etilene che utilizza tale catalizzatore.
JP3314322B2 (ja) * 1995-01-06 2002-08-12 日立造船株式会社 二酸化硫黄酸化触媒構造物
RU2124399C1 (ru) * 1995-01-10 1999-01-10 Сергей Александрович Логинов Катализатор для гидрогенизации нефтепродуктов
IT1282267B1 (it) * 1995-03-14 1998-03-16 Montecatini Tecnologie Srl Catalizzatori e supporti per catalizzatori ottenuti per pastigliatura
IT1276155B1 (it) * 1995-11-21 1997-10-27 Montecatini Tecnologie Srl Catalizzatori per l'ossiclorurazione dell'etilene,procedimento per la loro preparazione e procedimento di ossiclorurazione impiegante gli
IT1283207B1 (it) * 1996-03-08 1998-04-16 Montecatini Tecnologie Srl Catalizzatori per la deidrogenazione di etilbenzene a stirene
DE19850141A1 (de) * 1998-10-30 2000-05-04 Basf Ag Formkörper
DE10048219A1 (de) * 2000-02-10 2002-04-11 Sued Chemie Ag Katalysator für die Hydrierung von ungesättigten Kohlenwasserstoffen
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ATE306986T1 (de) 2000-08-30 2005-11-15 Haldor Topsoe As Katalysatorpartikel zur hydrobehandlung
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ITMI20042456A1 (it) * 2004-12-22 2005-03-22 Sued Chemie Mt Srl Catalizzatori per l'ossidazione del metanolo a formaldeide
ITMI20042500A1 (it) * 2004-12-23 2005-03-23 Sued Chemie Mt Srl Processo per la preparazione di un catalizzatore per l'ossidazione del metanolo a formaldeide
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JP4724796B2 (ja) 2007-01-25 2011-07-13 住友化学株式会社 成形体およびその製造方法ならびに押出成形機
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GB0816709D0 (en) 2008-09-12 2008-10-22 Johnson Matthey Plc Shaped heterogeneneous catalysts
GB0816703D0 (en) 2008-09-12 2008-10-22 Johnson Matthey Plc Shaped heterogeneous catalysts
WO2013106771A2 (en) 2012-01-13 2013-07-18 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
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AU2013355038B2 (en) 2012-12-07 2017-11-02 Lummus Technology Llc Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
EP3074119B1 (en) 2013-11-27 2019-01-09 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA3123783A1 (en) 2014-01-08 2015-07-16 Lummus Technology Llc Ethylene-to-liquids systems and methods
CA3148421C (en) 2014-01-09 2024-02-13 Lummus Technology Llc Oxidative coupling of methane implementations for olefin production
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CN105457648B (zh) * 2014-09-09 2018-08-07 中国石油化工股份有限公司 铁钼法甲醛合成催化剂及其制备方法
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
DK3274086T3 (da) * 2015-03-27 2019-05-06 Basf Se Katalysatorstøbelegeme til katalytisk oxidation af so2 til so3
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
EP3325144A4 (en) 2015-07-22 2019-01-16 BASF Corporation HIGH GEOMETRIC SURFACE CATALYSTS FOR THE MANUFACTURE OF VINYL ACETATE MONOMER
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CA3019396A1 (en) 2016-04-13 2017-10-19 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
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US10836689B2 (en) 2017-07-07 2020-11-17 Lummus Technology Llc Systems and methods for the oxidative coupling of methane
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US20200398255A1 (en) 2018-03-07 2020-12-24 Basf Se Shaped catalyst body in the form of tetralobes having a central through-passage
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CN110893344B (zh) * 2018-09-13 2021-04-27 中国科学院大连化学物理研究所 一种甲醇氧化制甲醛铁钼催化剂及制备和应用
RU2695617C1 (ru) * 2019-05-24 2019-07-24 Акционерное общество "Техметалл-2002" Способ получения катализатора окисления метанола до формальдегида
US20240278222A1 (en) 2020-05-26 2024-08-22 Basf Se Shaped catalyst body with improved properties, its preparation and use
CN111545159B (zh) * 2020-05-29 2021-05-04 北京化工大学 一种高效传质分离散装填料结构
RU2753669C1 (ru) * 2020-11-17 2021-08-19 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для гетерогенных реакций с пониженным гидравлическим сопротивлением слоя
WO2022250568A1 (ru) * 2021-05-24 2022-12-01 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор окисления метанола до формальдегида и способ его получения
EP4396156A4 (en) 2021-08-31 2025-08-27 Lummus Technology Inc METHODS AND SYSTEMS FOR OXIDATIVE COUPLING OF METHANE

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EP0461431A1 (de) * 1990-06-09 1991-12-18 Degussa Aktiengesellschaft Zylindrisch geformter Katalysator und dessen Verwendung bei der Oxichlorierung von Ethylen
EP0464633A1 (en) * 1990-07-03 1992-01-08 Kuraray Co., Ltd. Catalyst and process for producing unsaturated ester
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EP0461431A1 (de) * 1990-06-09 1991-12-18 Degussa Aktiengesellschaft Zylindrisch geformter Katalysator und dessen Verwendung bei der Oxichlorierung von Ethylen
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Also Published As

Publication number Publication date
CA2084870A1 (en) 1994-04-07
DK0591572T4 (da) 2006-08-21
DK0591572T3 (da) 1997-12-29
ATE153880T1 (de) 1997-06-15
EP0591572B1 (en) 1997-06-04
DE69220225D1 (de) 1997-07-10
CN1085124A (zh) 1994-04-13
ITMI922301A1 (it) 1994-04-06
EP0591572B2 (en) 2006-04-19
EP0591572B9 (en) 2006-08-23
US5330958A (en) 1994-07-19
DE69220225T3 (de) 2006-10-05
JP3382983B2 (ja) 2003-03-04
US5326915A (en) 1994-07-05
GR3024108T3 (en) 1997-10-31
TW231973B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1994-10-11
IT1256156B (it) 1995-11-29
CA2084870C (en) 2003-07-08
ES2103870T5 (es) 2006-11-16
EP0591572A1 (en) 1994-04-13
ES2103870T3 (es) 1997-10-01
ITMI922301A0 (it) 1992-10-06
RU2086299C1 (ru) 1997-08-10
JPH06134318A (ja) 1994-05-17
DE69220225T2 (de) 1998-02-19

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Granted publication date: 19990811

Termination date: 20111216