CN1043034C - 对太阳辐射和紫外线的透射率低的玻璃 - Google Patents
对太阳辐射和紫外线的透射率低的玻璃 Download PDFInfo
- Publication number
- CN1043034C CN1043034C CN95119016A CN95119016A CN1043034C CN 1043034 C CN1043034 C CN 1043034C CN 95119016 A CN95119016 A CN 95119016A CN 95119016 A CN95119016 A CN 95119016A CN 1043034 C CN1043034 C CN 1043034C
- Authority
- CN
- China
- Prior art keywords
- weight
- glass
- calculates
- iron
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 title claims abstract description 68
- 230000005855 radiation Effects 0.000 title claims abstract description 19
- 230000005540 biological transmission Effects 0.000 title claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 114
- 229910052742 iron Inorganic materials 0.000 claims abstract description 36
- 238000002834 transmittance Methods 0.000 claims abstract description 18
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 11
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 15
- NCXOIRPOXSUZHL-UHFFFAOYSA-N [Si].[Ca].[Na] Chemical compound [Si].[Ca].[Na] NCXOIRPOXSUZHL-UHFFFAOYSA-N 0.000 claims description 9
- 239000005357 flat glass Substances 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 239000005340 laminated glass Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 230000003287 optical effect Effects 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 19
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 238000005352 clarification Methods 0.000 description 4
- 230000005284 excitation Effects 0.000 description 4
- 238000006253 efflorescence Methods 0.000 description 3
- 239000000146 host glass Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 206010037844 rash Diseases 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006066 glass batch Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- GHLITDDQOMIBFS-UHFFFAOYSA-H cerium(3+);tricarbonate Chemical compound [Ce+3].[Ce+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GHLITDDQOMIBFS-UHFFFAOYSA-H 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/085—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for ultraviolet absorbing glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/082—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for infrared absorbing glass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S501/00—Compositions: ceramic
- Y10S501/90—Optical glass, e.g. silent on refractive index and/or ABBE number
- Y10S501/905—Ultraviolet transmitting or absorbing
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
一种对太阳辐射和紫外线的透射率低的玻璃，它基本上由钠钙-硅系玻璃组成，该钠钙-硅系玻璃中按Fe2O3计算的铁的总重量为0.52-0.67%(重量)、TiO2含量为0.2-0.6%(重量)、按CeO2计算的总铈含量为0.9-2.0%(重量)，其中按Fe2O3计算的FeO的重量占按Fe2O3计算的铁的总重量中的28至38%，其可见光透射率(对A光源)至少为70%，紫外线透射率不大于15%，对波长为370mm的光的透射率不大于30%。
Description
本发明涉及具有低的太阳辐射和紫外线透射率的玻璃。
美国专利4,792,536揭示了一种具有低的太阳辐射透射率(见JIS R3106)和低的紫外线透射率(见ISO 9050)的车辆用玻璃，这种玻璃是钠钙-硅系玻璃，其中按Fe2O3计算的FeO的重量至少占按Fe2O3计算的铁的总重量的45％。这种玻璃带有蓝色。
对于该种玻璃，用作澄清剂的Glauber盐不能产生澄清作用，因为其中按Fe2O3计算的FeO的重量至少占按Fe2O3计算的铁的总重量的45％。因此，熔融的玻璃需要在减压下澄清，这就使玻璃熔融步骤很费事。
另外，含有至少0.51％(重量)Fe2O3的钠钙-硅系玻璃也是人们已知的。这种玻璃带有绿色。例如，美国专利5,077,133揭示了以下的该种玻璃。该种玻璃厚度为3mm，总铁含量为0.68-0.92％(重量)，CeO2含量为0.5-1.2％(重量)，TiO2为0.02-0.85％(重量)，铁总量中二价铁的含量为23-29％(重量)。另一个例子的厚度为4mm，总铁含量为0.61-0.86％(重量)，CeO2含量为0.3-0.75％(重量)，TiO2为0.02-0.45％(重量)，铁总量中二价铁的含量为23-29％(重量)。
公开号为56466/1994的日本未审查专利揭示了一种对太阳辐射和紫外线的透射率低的玻璃，它基本上由钠钙-硅系玻璃基质构成，按Fe2O3计算的铁的总重量为0.53-0.70％(重量)，TiO2含量为0.2-0.4％(重量)，按CeO2计算的总铈含量为0.4-0.8％(重量)，按Fe2O3计算的FeO的重量占按Fe2O3计算的铁的总重量中的30至40％。
近年来，对于对紫外线吸收功能有所提高的玻璃的需求日益增加，尤其是用于汽车上的。本发明就是为了满足这种需求。
本发明的目的是提供一种对可见光的透射率至少为70％，对太阳辐射的透射率低，而对紫外线的透射率，特别是在370nm的透射率大大降低了的玻璃。
本发明提供一种具有低的太阳辐射和紫外线透射率的玻璃，它包括按Fe2O3计算的铁的总重量为0.52-0.67％(重量)、TiO2含量为0.2-0.6％(重量)、按CeO2计算的总铈含量为0.9-2.0％(重量)的钠钙-硅系玻璃，其中按Fe2O3计算的FeO的重量占按Fe2O3计算的铁的总重量中的28至38％。
如果按Fe2O3计算的总铁含量太低，则太阳辐射透射率和紫外线透射率会太高；如果总铁含量太高，对可见光的透射率又会太小。总铁含量以不大于0.64％(重量)为宜，最好不大于0.63％.如果总铁含量中二价铁的含量太低，则太阳辐射透射率会太高；如果太高，则玻璃的熔融步骤会很费事，而且玻璃会带有蓝色。
如果CeO2的含量太多，原材料的成本会太高，而且在生产玻璃时需要很长时间来使成分改变，因而生产率低。此外，玻璃会带有黄色。
如果TiO2的含量太低，紫外线透射率就会太高；如果含量太高，则可见光透射率会太低，而且玻璃会带有黄色。
为了使紫外线透射率保持在低的数值，本发明的第二个种实施方式中，CeO2+TiO2最好为1.2-2.3％(重量)。
CoO并不是基本组分，但掺入极少量的CoO，可使因CeO2和TiO2而呈黄色的玻璃调节成绿色。其含量最好在0.0002％(重量)以上。但如果含量太高，则可见光透射率会太低。
在各种组分中，铁总量和CeO2的含量最好按以下方法根据玻璃的厚度进行调节。即，当厚度为1.7-4.3mm时，按Fe2O3计算的总铁含量最好为0.59-0.64％(重量)，同时，CeO2的含量最好为1.2-2.0％(重量)。当厚度为1.7-4.4mm时，按Fe2O3计算的总铁含量为0.60-0.64％(重量)，TiO2的含量为0.3-0.5％(重量)，按CeO2计算的总铈含量为1.4-1.7％(重量)，而按Fe2O3计算的FeO的重量为按Fe2O3计算的铁的总重量的30-35％(重量)。类似地，当厚度为4.4-5.5mm时，按Fe2O3计算的铁的总含量最好为0.52-0.63％(重量)，同时，CeO2含量最好为0.9-1.2％(重量)。另外，当厚度为4.4-7.0mm时，
按Fe2O3计算的总铁含量为0.57-0.62％(重量)，TiO2的含量为0.2-0.4％(重量)，按CeO2计算的总铈含量为0.9-1.4％(重量)，而按Fe2O3计算的FeO的重量为按Fe2O3计算的铁的总重量的30-35％(重量)。
该种钠钙-硅系玻璃可普遍用于车辆和建筑用途。于是，本发明的一种较佳的玻璃组分为：
SiO2 68-74％(重量)
Al2O3 0.5-3％(重量)
MgO 3-6％(重量)
CaO 6-10％(重量)
Na2O+K2O 10-16％(重量)
SO3 0.05-1％(重量)
按Fe2O3计算的铁总量 0.52-0.67％(重量)
Fe2O3 0.35-0.50％(重量)
FeO 0.16-0.24％(重量)
TiO2 0.2-0.6％(重量)
按CeO2计算的铈总量 0.9-2％(重量)
如果SiO2的含量低，则抗风化性低；如果含量太高，则可能导致析晶。如果Al2O3含量太低，则抗水性会较差；如果含量太高，则可熔性会较低。
Na2O和K2O是用以促进原材料熔化的组分。如果它们的总量太低，这种作用就太小；如果太高，抗风化性就较差。
CaO和MgO是用以提高原材料可熔性和改善抗风化性的组分。如果其含量太低，这种作用就太小；如果其含量太高，则可能发生析晶。
如果SO3的含量太低，则澄清作用太小。
本发明中，玻璃的比重调节至2.49-2.53，更好是2.51-2.52，与普通的钠钙-硅系玻璃一致，目的是提高成分改变的效率。
比重可按第一种实施方式那样，通过控制基质玻璃的组分来调节。具体地说，SiO2/(MgO+CaO)的重量比可调节到5.0-7.0，较好是5.4-6.6，更好是6.0-6.6，最好是6.2-6.6。
本发明的玻璃的透射主波长是500-540nm，尤其是515-535nm，通常使用的厚度为1.7-7mm。其特征性能是：太阳辐射透射率为45-52％，可见光透射率(对A光源)至少为70％，紫外线透射率不大于15％，特别是不大于10％，对波长为370nm的光的透射率不大于30％，激发纯度(excitation purity)为2-3％。
本发明的对太阳辐射和紫外线的透射率低的玻璃，可用作单层玻璃、层叠玻璃或双层玻璃窗玻璃。当用于层叠玻璃或双层玻璃窗时，本发明的玻璃可用于层叠玻璃或双层玻璃窗的两个表面。另外，本发明的玻璃也可与其它种类的玻璃组合起来构成层叠玻璃或双层玻璃窗。
本发明的对太阳辐射和紫外线的透射率低的玻璃，例如，可按以下方法制备。即，先按所需玻璃的组分混合各种原料。关于所用的原料，铁粉或红色氧化铁，例如，可用作FeO和Fe2O3的源；氧化铈、碳酸铈或氢氧化铈可用作铈源；而氧化钛可用作钛源。基质玻璃的原料可用那些常用的材料。另外，在原料中最好加入如碳之类的还原剂，以使熔融玻璃中的铁不被氧化为Fe2O3，从而得到预定数量的FeO。
将这样调节好的玻璃批料连续供入熔炉，例如，用重油加热至1500℃使之熔融和玻化。然后，使这熔融玻璃澄清，并例如用浮法将它制成具有预定厚度的平板玻璃。再将平板玻璃切裁成预定的形状，就得到本发明的对太阳辐射和紫外线的透射率低的玻璃。进一步，裁割好的玻璃可进行钢化、层叠或组装成双层玻璃窗。
以下，将参照实施例进一步详细说明本发明。但应理解，本发明绝不仅限于这些具体实施例。
实施例1-9
制备了掺有改进光学性能的组分的钠钙-硅系玻璃，其基质玻璃含有71份(重量，下同)SiO2,1.7份Al2O3,12.3份Na2O,0.5份K2O,8份CaO,3.5份MgO，和0.6份SO3，掺入的按Fe2O3计算的铁总量、CeO2、TiO2、和CoO的数量如表1上部所示。二价铁(在表1中简单表示为FeⅡ)与铁总量之比也在同一部分示出。
制备该种玻璃时，将预先配好的玻璃批料放入一个300立方厘米的白金坩埚中，在电炉中加热熔融使之玻化。然后将熔融的玻璃浇铸在不锈钢板上，再把制成的玻璃板的两面抛光，得到厚度为3.5mm的平板玻璃(实施例6、7和9中，厚度为5.0mm)。测得这些平板的太阳辐射透射率Te，可见光透射率TVa(对A光源)，紫外线透射率TUV，对波长为370nm的光的透射率T370，透射主波长DW以及激发纯度PE，结果如表1下部所示。对比例(例8)中玻璃的这些性能也同样测得，也列在表1中。
表1
| 实施例 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 |
| Fe2O3份 | 0.62 | 0.59 | 0.62 | 0.61 | 0.61 | 0.53 | 0.54 | 0.64 | 0.60 |
| FeⅡwt％ | 31 | 34 | 32 | 33 | 32 | 33 | 32 | 35 | 35 |
| CeO2份 | 1.27 | 1.5 | 1.55 | 1.3 | 1.4 | 1.20 | 0.90 | 0.54 | 1.23 |
| TiO2份 | 0.4 | 0.45 | 0.35 | 0.4 | 0.4 | .40 | 0.40 | 0.32 | 0.31 |
| CoO份 | 0.0009 | 0.0015 | 0.0017 | - | 0.0012 | - | - | - | - |
| Te％ | 48.2 | 46.8 | 47.2 | 47.8 | 47.9 | 42.1 | 43.4 | 46.7 | 45.5 |
| TVa％ | 73.0 | 72.0 | 73.3 | 74.4 | 73.4 | 71.4 | 72.9 | 73.8 | 72.8 |
| Tuv％ | 9.8 | 8.1 | 7.9 | 9.8 | 9.0 | 7.2 | 8.8 | 16.3 | 7.9 |
| T370％ | 28.2 | 24.5 | 24.3 | 28.1 | 26.4 | 21.5 | 26.4 | 41.5 | 24.0 |
| Dwnm | 521 | 519 | 525 | 528 | 525 | 519 | 519 | 506 | 519 |
| Pe％ | 2.3 | 2.3 | 2.4 | 2.6 | 2.4 | 2.8 | 2.7 | 2.6 | 2.4 |
太阳辐射透射率和可见光透射率是按JIS R3106测定，紫外线透射率是按ISO 9050测定，而透射的主波长和激发纯度是按JISZ8722测定。
从表1可明显看到，本发明的玻璃具有绿的颜色，高的可见光透射率，低的太阳辐射透射率，和特别低的紫外线透射率。
根据本发明，得到了绿色的、具有高的可见光透射率，低的紫外线透射率，和特别低的对波长为370nm的光的透射率的玻璃。这种玻璃特别适合用作汽车挡风玻璃。
Claims (11)
1．一种对太阳辐射和紫外线的透射率低、其透射主波长为500-540nm的玻璃，它基本上由钠钙-硅系玻璃组成，该钠钙-硅系玻璃中按Fe2O3计算的铁的总重量为0.52-0.67％(重量)、TiO2含量为0.2-0.6％(重量)、按CeO2计算的总铈含量为0.9-2.0％(重量)，其中按Fe2O3计算的FeO的重量占按Fe2O3计算的铁的总重量的28至38％，其可见光透射率(对A光源)至少为70％，紫外线透射率不大于15％，对波长为370nm的光的透射率不大于30％。
2．如权利要求1所述的玻璃，其特征在于其基本组成为：
SiO2 68-74％(重量)
Al2O3 0.5-3％(重量)
MgO 3-6％(重量)
CaO 6-10％(重量)
Na2O+K2O 10-16％(重量)
SO3 0.05-1％(重量)
按Fe2O3计算的铁总量 0.52-0.67％(重量)
Fe2O3 0.35-0.50％(重量)
FeO 0.16-0.24％(重量)
TiO2 0.2-0.6％(重量)
按CeO2计算的铈总量 0.9-2％(重量)
3．如权利要求1所述的玻璃，其特征在于其透射的主波长为515-535nm。
4．如权利要求1所述的玻璃，其特征在于其比重为2.49-2.53。
5．如权利要求1所述的玻璃，其特征在于其比重为2.51-2.52。
6．如权利要求1所述的玻璃，其特征在于其厚度为1.7-4.3mm，且该玻璃中按Fe2O3计算的铁总量为0.59-0.64％(重量)，CeO2的数量为1.2-2.0％(重量)。
7．如权利要求1所述的玻璃，其特征在于其厚度为4.4-5.5mm，且该玻璃中按Fe2O3计算的铁总量为0.52-0.63％(重量)，CeO2的数量为0.9-1.2％(重量)。
8．如权利要求1所述的玻璃，其特征在于其厚度为1.7-4.4mm，且该玻璃中按Fe2O3计算的铁总量为0.60-0.64％(重量)，TiO2的数量为0.3-0.5％(重量)，按CeO2计算的总铈含量为1.4-1.7％(重量)，而按Fe2O3计算的FeO的重量占按Fe2O3计算的铁的总重量的30至35％。
9．如权利要求1所述的玻璃，其特征在于其厚度为4.4-7.0mm，且该玻璃中按Fe2O3计算的铁总量为0.57-0.62％(重量)，TiO2的数量为0.2-0.4％(重量)，按CeO2计算的总铈含量为0.9-1.4％(重量)，而按Fe2O3计算的FeO的重量占按Fe2O3计算的铁的总重量的30至35％。
10．一种玻璃板，其特征在于它是用权利要求1-8中任一项所述的玻璃制成的。
11．用于层叠玻璃的一对玻璃板，其特征在于它们是用权利要求1-8中任一项所述的玻璃制备的。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26286694 | 1994-10-26 | ||
| JP262866/94 | 1994-10-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1128737A CN1128737A (zh) | 1996-08-14 |
| CN1043034C true CN1043034C (zh) | 1999-04-21 |
Family
ID=17381722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95119016A Expired - Fee Related CN1043034C (zh) | 1994-10-26 | 1995-10-26 | 对太阳辐射和紫外线的透射率低的玻璃 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5723390A (zh) |
| EP (1) | EP0709344B1 (zh) |
| JP (1) | JP3190965B2 (zh) |
| CN (1) | CN1043034C (zh) |
| AU (1) | AU696443B2 (zh) |
| CA (1) | CA2161379C (zh) |
| DE (1) | DE69507421T2 (zh) |
| MY (1) | MY115988A (zh) |
| ZA (1) | ZA959079B (zh) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY115988A (en) * | 1994-10-26 | 2003-10-31 | Asahi Glass Co Ltd | Glass having low solar radiation and ultraviolet ray transmittance |
| EP0745566B1 (en) * | 1995-06-02 | 1998-08-19 | Nippon Sheet Glass Co. Ltd. | Ultraviolet and infrared radiation absorbing glass |
| JP3899531B2 (ja) * | 1995-06-16 | 2007-03-28 | 日本板硝子株式会社 | 紫外線赤外線吸収ガラス |
| US5830812A (en) * | 1996-04-01 | 1998-11-03 | Ppg Industries, Inc. | Infrared and ultraviolet radiation absorbing green glass composition |
| US5908702A (en) * | 1996-04-02 | 1999-06-01 | Asahi Glass Company Ltd. | Ultraviolet ray absorbing colored glass |
| JPH1045425A (ja) * | 1996-05-28 | 1998-02-17 | Nippon Sheet Glass Co Ltd | 紫外線赤外線吸収ガラス |
| JPH09328332A (ja) * | 1996-06-07 | 1997-12-22 | Nippon Sheet Glass Co Ltd | 赤外線吸収ガラス |
| US6612133B2 (en) | 1996-06-07 | 2003-09-02 | Nippon Sheet Glass Co., Ltd. | Method for shifting absorption peak wavelength of infrared radiation absorbing glass |
| ATE199369T1 (de) * | 1996-07-02 | 2001-03-15 | Ppg Ind Ohio Inc | Grünes vertraulichkeitsglas |
| JPH10101368A (ja) * | 1996-10-01 | 1998-04-21 | Nippon Sheet Glass Co Ltd | 紫外線赤外線吸収ガラス |
| JPH10265239A (ja) * | 1997-03-26 | 1998-10-06 | Nippon Sheet Glass Co Ltd | 紫外線赤外線吸収ガラス |
| ATE292607T1 (de) * | 1997-10-20 | 2005-04-15 | Ppg Ind Ohio Inc | Infrarote und ultraviolette strahlung absorbierende blauglaszusammensetzung |
| EP1029827A4 (en) * | 1997-11-13 | 2003-07-09 | Nippon Sheet Glass Co Ltd | ULTRAVIOLET / INFRARED ABSORBENT GLASS, ULTRAVIOLET / INFRARED ABSORBENT GLASS PANEL, ULTRAVIOLET / INFRARED ABSORBENT GLASS PANEL COATED WITH A COLORED FILM, AND VEHICLE GLAZING |
| US6929862B2 (en) * | 1999-06-08 | 2005-08-16 | Libbey-Owens-Ford Co. | Coated substrates |
| JP5433123B2 (ja) * | 2000-09-14 | 2014-03-05 | 旭硝子株式会社 | 合わせガラス |
| EP1671783A1 (en) * | 2000-09-14 | 2006-06-21 | Asahi Glass Company, Limited | Laminated glass |
| US6596660B1 (en) | 2001-10-26 | 2003-07-22 | Visteon Global Technologies, Inc. | Amber-free reduced blue glass composition |
| EP1453766A1 (en) * | 2001-12-14 | 2004-09-08 | Glaverbel | Coloured soda-lime glass |
| BE1014542A3 (fr) * | 2001-12-14 | 2003-12-02 | Glaverbel | Verre sodo-calcique colore. |
| US7094716B2 (en) * | 2002-10-04 | 2006-08-22 | Automotive Components Holdings, Llc | Green glass composition |
| US6995102B2 (en) * | 2003-07-16 | 2006-02-07 | Visteon Global Technologies, Inc. | Infrared absorbing blue glass composition |
| WO2005063643A1 (ja) * | 2003-12-26 | 2005-07-14 | Nippon Sheet Glass Company, Limited | 近赤外線吸収グリーンガラス組成物、およびこれを用いた合わせガラス |
| FR2881739B1 (fr) * | 2005-02-08 | 2007-03-30 | Saint Gobain | Composition de verre destinee a la fabrication de vitrages absorbant les radiations ultraviolettes et infrarouges. |
| JP5000097B2 (ja) * | 2005-03-22 | 2012-08-15 | 日本板硝子株式会社 | 赤外線吸収グリーンガラス組成物 |
| IES20050313A2 (en) * | 2005-05-13 | 2006-11-15 | Heye Res And Dev Ltd | Soda lime glass compositions and process for manafacturing containers made from said compositions |
| US7678722B2 (en) * | 2005-07-29 | 2010-03-16 | Ppg Industries Ohio, Inc. | Green glass composition |
| US7666806B2 (en) | 2005-11-02 | 2010-02-23 | Ppg Industries Ohio, Inc. | Gray glass composition |
| US7585801B2 (en) | 2005-11-02 | 2009-09-08 | Ppg Industries Ohio, Inc. | Gray glass composition |
| JP2007290923A (ja) * | 2006-04-26 | 2007-11-08 | Nippon Sheet Glass Co Ltd | 合わせガラス |
| US8304358B2 (en) * | 2008-11-21 | 2012-11-06 | Ppg Industries Ohio, Inc. | Method of reducing redox ratio of molten glass and the glass made thereby |
| CN102167511B (zh) * | 2011-01-07 | 2012-10-24 | 李锋 | 低能辐射防护玻璃的制造方法 |
| JP5999110B2 (ja) | 2012-01-27 | 2016-09-28 | 旭硝子株式会社 | 着色ガラス板およびその製造方法 |
| WO2013111882A1 (ja) * | 2012-01-27 | 2013-08-01 | 旭硝子株式会社 | 着色ガラス板およびその製造方法 |
| JP5999111B2 (ja) | 2012-01-27 | 2016-09-28 | 旭硝子株式会社 | 着色ガラス板およびその製造方法 |
| US11261122B2 (en) | 2013-04-15 | 2022-03-01 | Vitro Flat Glass Llc | Low iron, high redox ratio, and high iron, high redox ratio, soda-lime-silica glasses and methods of making same |
| US20140309099A1 (en) | 2013-04-15 | 2014-10-16 | Ppg Industries Ohio, Inc. | Low iron, high redox ratio, and high iron, high redox ratio, soda-lime-silica glasses and methods of making same |
| CN103508669B (zh) * | 2013-05-14 | 2015-10-28 | 河源旗滨硅业有限公司 | 一种抗紫外线超白光伏玻璃及其应用 |
| JP6373852B2 (ja) * | 2013-09-09 | 2018-08-15 | 日本板硝子株式会社 | ガラス組成物及び強化ガラス板 |
| KR101969627B1 (ko) | 2016-06-23 | 2019-04-16 | 주식회사 케이씨씨 | 녹색 유리 조성물 |
| CN106396364A (zh) * | 2016-08-31 | 2017-02-15 | 中山火炬职业技术学院 | 一种低紫外辐射灯具玻壳的制备方法 |
| US11690645B2 (en) | 2017-05-03 | 2023-07-04 | Medtronic Vascular, Inc. | Tissue-removing catheter |
| CN110582242B (zh) | 2017-05-03 | 2023-03-10 | 美敦力瓦斯科尔勒公司 | 组织移除导管 |
| CN107117811B (zh) * | 2017-06-16 | 2018-04-06 | 南京安达玻璃技术有限公司 | 一种低透光的隐私节能浮法玻璃组合物及其制备方法 |
| US11299018B2 (en) * | 2017-07-28 | 2022-04-12 | Pilkington Group Limited | Window assembly |
| CN109485253A (zh) * | 2019-01-15 | 2019-03-19 | 海南中航特玻科技有限公司 | 具有吸收紫外红外线防眩光功能玻璃的制备方法 |
| US11819236B2 (en) | 2019-05-17 | 2023-11-21 | Medtronic Vascular, Inc. | Tissue-removing catheter |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US536289A (en) * | 1895-03-26 | Combined pencil and sharpener | ||
| CN1052647A (zh) * | 1989-11-16 | 1991-07-03 | 利比-欧文斯-福特公司 | 吸收红外和紫外辐射的绿色玻璃组合物 |
| JPH0558670A (ja) * | 1991-02-08 | 1993-03-09 | Nippon Sheet Glass Co Ltd | 車両用ガラス |
| US5318931A (en) * | 1991-02-08 | 1994-06-07 | Nippon Sheet Glass Co., Ltd. | Glass panes for vehicles |
Family Cites Families (103)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US34760A (en) * | 1862-03-25 | Improvement in harvesters | ||
| DE220592C (zh) * | ||||
| US34639A (en) * | 1862-03-11 | Improved clothes-wringer | ||
| LU46426A1 (zh) * | 1964-06-29 | 1972-01-01 | ||
| US3858964A (en) * | 1969-01-22 | 1975-01-07 | Philips Corp | Light-absorbing silicate glass for fibre-optical elements |
| US3652303A (en) * | 1970-01-26 | 1972-03-28 | Ppg Industries Inc | Heat absorbing blue soda-lime-silica glass |
| US4104076A (en) * | 1970-03-17 | 1978-08-01 | Saint-Gobain Industries | Manufacture of novel grey and bronze glasses |
| SU449890A1 (ru) * | 1972-07-21 | 1974-11-15 | Тбилисский Научно-Исследовательский Институт Стройматериалов | Стекло |
| SU528271A1 (ru) * | 1972-12-25 | 1976-09-15 | Институт Химии Ан Узбекской Сср | Стекло |
| SU443004A1 (ru) * | 1973-01-09 | 1974-09-15 | Салаватский завод технического стекла | Стекло |
| SU579239A1 (ru) * | 1973-03-26 | 1977-11-05 | Предприятие П/Я Х-5382 | Стекло дл изготовлени магнитоуправл емых контактов |
| SU459437A1 (ru) * | 1973-05-03 | 1975-02-05 | Государственный научно-исследовательский институт стекла | Декоративное стекло |
| SU471315A1 (ru) * | 1973-05-28 | 1975-05-25 | Ордена Трудового Красного Знамени Грузинский Политехнический Институт Им.В.И.Ленина | Стекло |
| DD112692A1 (zh) * | 1974-05-07 | 1975-04-20 | ||
| SU536132A1 (ru) * | 1974-05-17 | 1976-11-25 | Государственный научно-исследовательский институт стекла | Стекло |
| SU504715A1 (ru) * | 1974-07-16 | 1976-02-28 | Уральский ордена Трудового Красного Знамени политехнический институт им.С.М.Кирова | Стекло |
| SU511301A1 (ru) * | 1974-11-11 | 1976-04-25 | Боржомский Стекольный Завод Им. М.И.Калинина | Стекло |
| SU547399A1 (ru) * | 1975-07-18 | 1977-02-25 | Государственный научно-исследовательский институт стекла | Стекло |
| SU557060A1 (ru) * | 1975-10-14 | 1977-05-05 | Научно-Техническое Объединение Грузниистром | Стекло |
| SU594065A1 (ru) * | 1975-11-21 | 1978-02-25 | Государственный научно-исследовательский институт стекла | Секло |
| SU632661A1 (ru) * | 1975-11-21 | 1978-11-15 | Государственный научно-исследовательский институт стекла | Стекло |
| SU579240A1 (ru) * | 1976-06-01 | 1977-11-05 | Константиновский Ордена Трудового Красного Знамени Завод "Автостекло" | Черное стекло |
| JPS539805A (en) * | 1976-07-15 | 1978-01-28 | Kogyo Gijutsuin | Composite of alkaliiproof glass |
| SU612905A1 (ru) * | 1976-08-01 | 1978-06-30 | Специальное конструкторско-технологическое бюро по изоляторам и арматуре Треста "Электросетьизоляция" | Стекло дл высоковольтных изол торов |
| JPS5345315A (en) * | 1976-10-06 | 1978-04-24 | Ishizuka Glass | Method of manufacturing greenish brown glass |
| SU614037A1 (ru) * | 1976-12-07 | 1978-07-05 | Уральский ордена Трудового Красного Знамени политехнический институт им.С.М.Кирова | Стекло |
| SU631473A1 (ru) * | 1976-12-08 | 1978-11-05 | Научно-Техническое Объединение "Грузниистром" | Каменное литье |
| FR2390390A1 (fr) * | 1977-05-10 | 1978-12-08 | Santt Rene | Materiaux vitrifies et procedes les rendant aptes a capter l'energie solaire et a accumuler la chaleur |
| SU753802A1 (ru) | 1978-03-22 | 1980-08-07 | Государственный научно-исследовательский институт стекла | Стекло дл регулировани световых потоков |
| US4192689A (en) * | 1978-05-30 | 1980-03-11 | Ppg Industries, Inc. | Ion exchange strengthening of soda-lime-silica glass |
| SU709575A1 (ru) * | 1978-07-14 | 1980-01-15 | Предприятие П/Я А-7840 | Стекло |
| DE2911510A1 (de) * | 1978-12-08 | 1980-06-19 | Saint Gobain | Verfahren, vorrichtung und glaeser zum herstellen von glasfasern und damit hergestellte glasfasern |
| SU821426A1 (ru) | 1979-02-19 | 1981-04-15 | Чернятинский Стекольный Заводпроизводственного Объединения "Брян-Скстекло" | Стекло |
| FR2463108A2 (fr) * | 1979-05-21 | 1981-02-20 | Santt Rene | Materiaux resistant au choc thermique et procedes pour les produire |
| SU895943A1 (ru) | 1979-07-16 | 1982-01-07 | Гусевской Филиал Государственного Научно-Исследовательского Института Стекла | Стекло |
| US4270945A (en) * | 1979-12-03 | 1981-06-02 | Ppg Industries, Inc. | Method of melting flat glass using nitrates to suppress sulfurous emissions |
| LU83164A1 (fr) * | 1980-03-04 | 1981-06-05 | Bfg Glassgroup | Verre colore et son procede de fabrication |
| US4366252A (en) * | 1980-03-13 | 1982-12-28 | Owens-Illinois, Inc. | Fluorine-free, zirconia-free, X-ray absorbing silica based glass, containing oxides of lead, barium and strontium plus oxides of calcium, magnesium, sodium, potassium, cerium, titanium, arsenic and antimony |
| JPS575251A (en) * | 1980-06-12 | 1982-01-12 | Nippon Electric Glass Co Ltd | Cathode ray tube glass |
| US4312953A (en) * | 1981-01-29 | 1982-01-26 | Owens-Illinois, Inc. | Olive-green glass compositions |
| US4396722A (en) * | 1982-04-05 | 1983-08-02 | Owens-Corning Fiberglas Corporation | Wool glass composition |
| DE3220072C2 (de) * | 1982-05-27 | 1986-09-04 | Deutsche Spezialglas Ag, 3223 Delligsen | Dunkelblau gefärbtes Ofenschauglas mit hoher Infrarotabsorption |
| DE3322799A1 (de) * | 1983-06-24 | 1985-01-03 | VEGLA Vereinigte Glaswerke GmbH, 5100 Aachen | Glasscheibe fuer kraftfahrzeuge und verfahren zu ihrer herstellung |
| JPS60215546A (ja) * | 1984-04-06 | 1985-10-28 | Nippon Sheet Glass Co Ltd | 赤外線吸収ガラス |
| JPS61136936A (ja) * | 1984-12-04 | 1986-06-24 | Asahi Glass Co Ltd | ガラス組成物 |
| USRE34639E (en) | 1985-02-19 | 1994-06-14 | Ford Motor Company | Nickel ion-free blue glass composition |
| US4866010A (en) * | 1985-02-19 | 1989-09-12 | Ford Motor Company | Nickel ion-free blue glass composition |
| US4738938A (en) * | 1986-01-02 | 1988-04-19 | Ppg Industries, Inc. | Melting and vacuum refining of glass or the like and composition of sheet |
| US4713359A (en) * | 1986-04-14 | 1987-12-15 | Libbey-Owens-Ford Co. | Infrared absorbing glass compositions |
| US4701425A (en) * | 1986-05-19 | 1987-10-20 | Libbey-Owens-Ford Co. | Infrared and ultraviolet absorbing glass compositions |
| US5296294A (en) * | 1987-02-03 | 1994-03-22 | Nippon Sheet Glass Co., Ltd. | Glass panel resistant to coloring when irradiated with electron rays |
| US4792536A (en) | 1987-06-29 | 1988-12-20 | Ppg Industries, Inc. | Transparent infrared absorbing glass and method of making |
| DE3729036A1 (de) * | 1987-08-31 | 1989-03-09 | Ver Glaswerke Gmbh | Isolierglasscheibe fuer kraftfahrzeuge |
| JPH0725570B2 (ja) * | 1988-05-31 | 1995-03-22 | 日本特殊陶業株式会社 | 着色結晶化ガラス体とその製造法 |
| US4873206A (en) * | 1988-07-05 | 1989-10-10 | Ppg Industries, Inc. | Dark, neutral, gray, nickel-free glass composition |
| US4998784A (en) * | 1988-08-31 | 1991-03-12 | Ppg Industries, Inc. | Automotive windshield for a head up display system |
| JPH039805A (ja) * | 1989-06-07 | 1991-01-17 | Chugoku Kogyo Kk | セラミック又は金属と繊維強化プラスチック（ｆｒｐ）の複合材の製造方法 |
| US5213828A (en) * | 1989-07-03 | 1993-05-25 | Ppg Industries, Inc. | Heatable windshield |
| US5071796A (en) * | 1989-08-14 | 1991-12-10 | Ppg Industries, Inc. | Flat glass composition with improved melting and tempering properties |
| US5013487A (en) * | 1989-08-18 | 1991-05-07 | Libbey-Owens-Ford Co. | Infrared radiation absorbing glue glass composition |
| US5069826A (en) * | 1989-08-18 | 1991-12-03 | Libbey-Owens-Ford Co. | Infrared radiation absorbing blue glass composition |
| FR2652078B1 (fr) * | 1989-09-18 | 1992-05-22 | Saint Gobain Rech | Procede d'elaboration d'un verre destine a etre transforme en fibres continues ou discontinues. |
| US5023210A (en) * | 1989-11-03 | 1991-06-11 | Ppg Industries, Inc. | Neutral gray, low transmittance, nickel-free glass |
| US5077133A (en) | 1990-06-21 | 1991-12-31 | Libbey-Owens-Ford Co. | Infrared and ultraviolet radiation absorbing green glass composition |
| HU912379D0 (en) * | 1989-11-16 | 1991-12-30 | Libbey Owens Ford Co | Green glass composition extincting infrared and ultraviolet rays |
| US5077240A (en) * | 1990-01-11 | 1991-12-31 | Schott Glass Technologies, Inc. | Strengthenable, high neodymium-containing glasses |
| US5112778A (en) * | 1990-01-30 | 1992-05-12 | Libbey-Owens-Ford Co. | Batch composition for making infrared and ultraviolet radiation absorbing green glass |
| US5328768A (en) * | 1990-04-03 | 1994-07-12 | Ppg Industries, Inc. | Durable water repellant glass surface |
| FR2660921B1 (fr) * | 1990-04-13 | 1993-11-26 | Saint Gobain Vitrage Internal | Vitrage en verre teinte notamment pour toit de vehicules automobiles. |
| DE4015264C1 (zh) * | 1990-05-12 | 1991-07-18 | Schott Glaswerke | |
| US5593929A (en) * | 1990-07-30 | 1997-01-14 | Ppg Industries, Inc. | Ultraviolet absorbing green tinted glass |
| US5240886A (en) * | 1990-07-30 | 1993-08-31 | Ppg Industries, Inc. | Ultraviolet absorbing, green tinted glass |
| US5393593A (en) * | 1990-10-25 | 1995-02-28 | Ppg Industries, Inc. | Dark gray, infrared absorbing glass composition and coated glass for privacy glazing |
| DE69120509T2 (de) * | 1990-11-26 | 1996-10-31 | Central Glass Co Ltd | Infrarote und Ultraviolette Strahlung absorbierendes Glas |
| US5070048A (en) | 1990-12-12 | 1991-12-03 | Ford Motor Company | Blue glass compositions |
| JPH04310539A (ja) * | 1991-04-05 | 1992-11-02 | Asahi Glass Co Ltd | 赤外線・紫外線吸収ガラス |
| US5215944A (en) * | 1991-07-29 | 1993-06-01 | Ppg Industries, Inc. | X-ray absorbing glass compositions |
| JP2544035B2 (ja) * | 1991-08-14 | 1996-10-16 | セントラル硝子株式会社 | 高含鉄分・高還元率フリットガラス及びそれを用いた青色系熱線吸収ガラス |
| DE4129052A1 (de) * | 1991-09-02 | 1993-03-04 | Ver Glaswerke Gmbh | Fahrzeugfenster |
| JPH0597469A (ja) * | 1991-10-11 | 1993-04-20 | Nippon Sheet Glass Co Ltd | 車両用ガラス |
| US5316854A (en) * | 1991-12-06 | 1994-05-31 | Ppg Industries, Inc. | Glass or quartz articles having high temperature UV absorbing coatings containing ceria |
| JP2528579B2 (ja) * | 1991-12-27 | 1996-08-28 | セントラル硝子株式会社 | 含鉄分・高還元率フリットガラスおよびこれを用いた紫外・赤外線吸収緑色ガラス |
| EP0561337A1 (en) * | 1992-03-18 | 1993-09-22 | Central Glass Company, Limited | Bronze-colored infrared and ultraviolet radiation absorbing glass |
| DE69311197T2 (de) * | 1992-03-19 | 1997-09-18 | Central Glass Co Ltd | Infrarote und ultraviolette Strahlung absorbierendes, neutral grau gefärbtes Glas |
| US5214008A (en) * | 1992-04-17 | 1993-05-25 | Guardian Industries Corp. | High visible, low UV and low IR transmittance green glass composition |
| KR100206628B1 (ko) * | 1992-04-22 | 1999-07-01 | 마쯔무라 미노루 | 차량용 창유리 |
| TW213438B (en) * | 1992-05-11 | 1993-09-21 | Nippon Electric Glass Co | Marble-like glass ceramic |
| US5278108A (en) * | 1992-07-02 | 1994-01-11 | Libbey-Owens-Ford Co. | Neutral gray glass composition |
| US5250098A (en) * | 1992-07-27 | 1993-10-05 | Ford Motor Company | Thermally durable anti-reflective glass |
| JPH0656466A (ja) * | 1992-08-05 | 1994-03-01 | Asahi Glass Co Ltd | 日射透過率及び紫外線透過率の小さいガラス |
| US5278805A (en) * | 1992-10-26 | 1994-01-11 | Schlumberger Technology Corporation | Sonic well logging methods and apparatus utilizing dispersive wave processing |
| US5268335A (en) * | 1992-11-27 | 1993-12-07 | Corning Incorporated | Fast strengthening glass lenses |
| US5256607A (en) * | 1992-11-27 | 1993-10-26 | Corning Incorporated | Neutral, ultraviolet absoring, fixed tint lenses |
| FR2699527B1 (fr) * | 1992-12-23 | 1995-02-03 | Saint Gobain Vitrage Int | Compositions de verre destinées à la fabrication de vitrage. |
| US5308805A (en) * | 1993-05-05 | 1994-05-03 | Libbey-Owens-Ford Co. | Neutral, low transmittance glass |
| US5346867A (en) * | 1993-12-17 | 1994-09-13 | Ford Motor Company | Neutral gray absorbing glass comprising manganese oxide for selenium retention during processing |
| US5411922A (en) * | 1993-12-27 | 1995-05-02 | Ford Motor Company | Neutral gray-green low transmittance heat absorbing glass |
| US5366940A (en) * | 1994-01-28 | 1994-11-22 | Bausch & Lomb Incorporated | Transparent, fixed tint glass lenses |
| US5405811A (en) * | 1994-02-28 | 1995-04-11 | Corning Incorporated | Ultraviolet absorbing, fixed tint green sunglass |
| US5403789A (en) * | 1994-02-28 | 1995-04-04 | Corning Incorporated | Ultraviolet absorbing, fixed tint brown sunglass |
| US5446007A (en) * | 1994-05-10 | 1995-08-29 | Schott Glass Technologies, Inc. | Brown contrast enhancement glass |
| JP3009805U (ja) | 1994-10-03 | 1995-04-11 | 富士電気化学株式会社 | Ｅｍｉノイズ防止用のインピーダンス素子 |
| MY115988A (en) * | 1994-10-26 | 2003-10-31 | Asahi Glass Co Ltd | Glass having low solar radiation and ultraviolet ray transmittance |
-
1995
- 1995-10-24 MY MYPI9503184 patent/MY115988A/en unknown
- 1995-10-24 AU AU34415/95A patent/AU696443B2/en not_active Ceased
- 1995-10-25 CA CA002161379A patent/CA2161379C/en not_active Expired - Fee Related
- 1995-10-26 CN CN95119016A patent/CN1043034C/zh not_active Expired - Fee Related
- 1995-10-26 JP JP27931195A patent/JP3190965B2/ja not_active Expired - Fee Related
- 1995-10-26 ZA ZA959079A patent/ZA959079B/xx unknown
- 1995-10-26 EP EP95116904A patent/EP0709344B1/en not_active Expired - Lifetime
- 1995-10-26 DE DE69507421T patent/DE69507421T2/de not_active Expired - Lifetime
-
1996
- 1996-02-12 US US08/600,028 patent/US5723390A/en not_active Expired - Lifetime
-
1997
- 1997-04-21 US US08/845,034 patent/US5897956A/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US536289A (en) * | 1895-03-26 | Combined pencil and sharpener | ||
| CN1052647A (zh) * | 1989-11-16 | 1991-07-03 | 利比-欧文斯-福特公司 | 吸收红外和紫外辐射的绿色玻璃组合物 |
| JPH0558670A (ja) * | 1991-02-08 | 1993-03-09 | Nippon Sheet Glass Co Ltd | 車両用ガラス |
| US5318931A (en) * | 1991-02-08 | 1994-06-07 | Nippon Sheet Glass Co., Ltd. | Glass panes for vehicles |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69507421T2 (de) | 2009-09-17 |
| US5897956A (en) | 1999-04-27 |
| CN1128737A (zh) | 1996-08-14 |
| MY115988A (en) | 2003-10-31 |
| AU3441595A (en) | 1996-05-09 |
| DE69507421D1 (de) | 1999-03-04 |
| CA2161379C (en) | 2004-01-13 |
| JPH08208266A (ja) | 1996-08-13 |
| US5723390A (en) | 1998-03-03 |
| ZA959079B (en) | 1996-05-22 |
| EP0709344B1 (en) | 1999-01-20 |
| AU696443B2 (en) | 1998-09-10 |
| CA2161379A1 (en) | 1996-04-27 |
| EP0709344A1 (en) | 1996-05-01 |
| JP3190965B2 (ja) | 2001-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1043034C (zh) | 对太阳辐射和紫外线的透射率低的玻璃 | |
| JP3280266B2 (ja) | 赤外線及び紫外線吸収性緑色ガラス組成物 | |
| JP4447658B2 (ja) | 窓ガラスを製造するためのガラス組成物 | |
| AU629086B2 (en) | Infrared and ultraviolet radiation absorbing green glass composition | |
| EP0565882B1 (en) | Neutral gray-colored infrared and ultraviolet radiation absorbing glass | |
| JP3451350B2 (ja) | 紫外線吸収無色透明ソーダライムシリカ系ガラス | |
| JP3965461B2 (ja) | 窓ガラス製造用のガラス板 | |
| JP5069567B2 (ja) | 紫外線および赤外線を吸収する窓ガラスを製造するためのガラス組成物 | |
| US9193621B2 (en) | Heat-absorbing glass plate and process for its production | |
| EP2492248B1 (en) | Heat-ray-absorbing glass plate | |
| JPH0656466A (ja) | 日射透過率及び紫外線透過率の小さいガラス | |
| US7601660B2 (en) | Clear glass composition | |
| EP0798271A1 (en) | Dark gray colored glass | |
| US9206072B2 (en) | Colored glass plate and method for its production | |
| US6133179A (en) | Glass compositions of the silica-soda-lime type | |
| JP3900550B2 (ja) | 紫外線吸収グリーンガラス | |
| JP2000103639A (ja) | 紫外線吸収ガラス | |
| EP0864545B1 (en) | Method for the production of glass sheets and their use | |
| CN104080750A (zh) | 着色玻璃板及其制造方法 | |
| CN104080751A (zh) | 着色玻璃板及其制造方法 | |
| KR20000075862A (ko) | 창유리 제작을 위한 유리 조성물 | |
| CN118561516A (zh) | 玻璃组合物及其制备方法和汽车玻璃 | |
| JPH08220342A (ja) | 紫外線赤外線吸収ガラス | |
| JPH0948635A (ja) | 紫外線赤外線吸収ガラス | |
| KR20020004753A (ko) | 자외선 및 적외선 흡수유리 제조용 뱃지조성물 및유리조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 19990421 Termination date: 20131026 |