CN103548826B - Citrus fruit fly sex attraction agent and its preparation method and application - Google Patents
Citrus fruit fly sex attraction agent and its preparation method and application Download PDFInfo
- Publication number
- CN103548826B CN103548826B CN201310537373.8A CN201310537373A CN103548826B CN 103548826 B CN103548826 B CN 103548826B CN 201310537373 A CN201310537373 A CN 201310537373A CN 103548826 B CN103548826 B CN 103548826B
- Authority
- CN
- China
- Prior art keywords
- agent
- fruit fly
- citrus fruit
- sex attraction
- citrus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of citrus (tangerine) little trypetid sex attraction agent and its preparation method and application, comprise hesperetin, alcohols, ketone, methyl eugenol, ester class, vegetable oil, antioxidant, and add complementary composition and thickener, the sustained release agents etc. such as antioxidant, anti ultraviolet agent, antibacterial agent, obtain the agent of citrus fruit fly sex attraction, be placed in the dark container of lid and preserved; Sex attraction agent main component of the present invention, raw material all comes from natural plant extracts, environmentally friendly, to non-target organism safety; In conjunction with the integrated application of other solid slow-release materials, male imago female to citrus fruit fly has good trapping effect, effectively can reduce by generation the population radix using citrus fruit fly in region.Citrus fruit fly (or claiming citrus fruit fly) the sex attraction agent that the present invention obtains, synthesis technique is simple, with low cost, is adapted at citrus producing region and citrus fruit fly other extensive use of host crop producing region and popularizations, also effective to insects such as peach trypetid, melon trypetids.
Description
Technical field
The present invention relates to a kind of citrus fruit fly sex attraction agent and preparation method thereof, and in orchard using method.
Background technology
Citrus fruit fly, have another name called dacus dorsalis hendel of mandarin orange, orient fruit fly, yellow fly, fruit maggot etc., Classification system is Bactroceradorsalis Hendel, and English name is Oriental fruit fly.Citrus fruit fly belongs to diptera Tephritidae bactrocera oligochaeta and belongs to, and is commonly called as fruit maggot.Be distributed in the countries and regions such as the U.S., Australia, India, Pakistan, Japan, Philippine, Indonesia, Thailand, Vietnam abroad, domestic in Guangdong, all there is distribution in Guangxi, Fujian, Jiangsu, Zhejiang, Shanghai, Sichuan, Chongqing, Hunan, Hubei, the citrus producing region such as Taiwan mainly with larval feeding fruit flesh, form maggot mandarin orange, cause rotten, cause fruit early fallout, have a strong impact on seed output and quality.Time serious, loss greatly, once in the large generation in the ground such as Sichuan, Chongqing, causes citrus industry to suffer heavy losses in 2009.Except citrus, pomegranate, red bayberry, peach, carambola, loquat, banana, guava, pawpaw, carambola, pears, persimmon, apricot, capsicum, eggplant, tomato, fig, lichee, longan, avocado, jujube etc. more than 250 can be endangered and plant fruits and vegetables, with larva moth food fruit, fruit rot is caused to come off, be referred to as " number one killer " of fruit, China is classified as quarantine object.
For citrus fruit fly, orchard worker or vegetable grower adopt the means such as chemical control or physical control in the past usually.Chemical control: at de-Sheng phase and the adult eclosion Sheng phase ground spray 50% phoxim 600-1000 times of liquid of really burying of larva, mainly causing harm the phase, namely 5 ~ November, adult contained the phase of sending out, and taked tree crown to spray 80% DDT EC or 90% trichlorphon or 50% malathion missible oil 800-1000 times liquid.Also the mode that chemical pesticide combines with baits such as brown sugar can be adopted, as added 90% chlorophos, 600 times of liquid with 1% protein hydrolysate, or 90% trichlorphon, 1000 times of liquid add 3% brown sugar, or 20% go out sweep profit 1000 extraordinarily 3% brown sugar make poison bait, spraying orchard and around assorted tree tree crown.Spray in every 10 days 1 time, connects spray 3 ~ 4 times.Although chemical prevention and control method can reduce population number to a certain extent, increase product yield, cost of labor is higher, bring certain security implication also to the quality of fruit itself, cover spray difficulty is high in addition, also brings certain hidden danger to operator safety simultaneously.
Nuclear radiation process trypetid pupa is taked to implement sterile control, namely at indoor amount reproduction dacus dorsalis pupa, with the process of 50Co gamma-radiation, let sterile male imago fly away, be discharged into orchard, compete spouse with normal male worm, the chance reducing natural world citrus fruit fly female adult pest success mating fertilization can be reduced, reach the object effectively reducing population density.But this kind of method input cost is high, large area is thrown in and is difficult to realize.In addition, before young fruit period, trypetid adult do not lay eggs, to fruit bagging, can effectively prevent Adult worms producting eggs from causing harm, there is certain reliability, but cost of labor be high, and affect the qualities such as the mouthfeel of fruit to a certain extent.
In recent years gyplure trapping citrus fruit fly adult is adopted both at home and abroad, Main Ingredients and Appearance is methyl eugenol (Methyl Eugenol, be abbreviated as ME), price costly, and can only trapping male adult, as the Scentry Methyl Eugenol Cone product (registration number: EPA Reg.No.36638-41. of Environmental Protection Agency (US EPA) approval registration in 2007, SCENTRYBIOLOGICALS, INC product), its main component is exactly methyl eugenol, account for 76.9%, all the other 23.1% are inert component.
In addition, the GF-120 bait formulation (U.S. Patent number: US2008/0118461A1) that The Dow Agrosciences, LLC. produces, also for trapping and killing citrus fruit fly male imago, its main component also comprises methyl eugenol, and by the pleocidin of actinomycetes thorniness saccharopolyspora strain (Saccharopolyspora spinosa) fermenting and producing, containing the mixture of spinosyn A ultimate constituent and spinosynD, add water, soya-bean oil, the compositions such as microwax and SPAN60 emulsifier, there is low toxicity, low-residual, to Natural Enemies of Insects safety, the features such as natural decomposition is fast, there is good field control effect, but due to price costly, peasant's more options traditional chemical agricultural chemicals or male worm gyplure.
The trypetid quarantine key lab of country of State Administration of Quality Supervision, Inspection and Quarantine being positioned at Guangzhou, Guangdong once obtained " attractant for juxiaoshi fly " of the interim registration card of Ministry of Agriculture's agricultural chemicals (LS20040755) in 2007, active ingredient is methyl eugenol, can only lure merely citrus fruit fly male imago.
Because citrus fruit fly is caused the oviposition behavior of the harm of the fruit such as citrus mainly due to female adult pest; therefore development can lure male imago can lure again " the sex attraction agent " of female adult pest; for the host plant of the citrus fruit flies such as fruit or vegetables such as protection citrus, there is even more important meaning.At present only minute quantity report shows that " sex attraction agent " lures male imago and female adult pest simultaneously; normally on the basis of methyl eugenol, add protein hydrolysate;, male imago female for trapping citrus fruit fly has good effect; but also there is obvious defect; preserve if reason is protein hydrolysate and uses inconvenience; usually need now-making-now-using, be difficult to large-scale production and form matured product in addition sales promotion, practicality is subject to larger restriction.
Nowadays, the attractant of trapping and killing citrus fruit fly is main still to lure male worm, although lure male worm still to keep away unavoidable a part of female worm be fertilized to lay eggs on fruits and vegetables, produce to fruits and vegetables and cause huge loss, moreover female worm is unfertilized also can lay eggs, but about luring the female worm of citrus fruit fly specially or have male and female the report of the lure kind of obvious attracting action less, mainly some albumen lures.
The host fruit tree area of citrus fruit fly harm is suitable for close to 8,000,000 hectares in China, namely the gross area surpasses hundred million mu, if lack effective preventions, citrus fruit fly will spread rapidly, cause serious harm and huge loss by the generation of the numerous fruit of China and Vegetable kind.
Summary of the invention
Goal of the invention: provide the attractant simultaneously luring both sexes citrus fruit fly.
Technical scheme; The agent of a kind of citrus fruit fly sex attraction, comprises hesperetin, alcohols, ketone, methyl eugenol, ester class, vegetable oil, antioxidant.
The step of its preparation method comprises:
Step 1, provides hesperetin (Tangeretin, C
20h
20o
7) or citrus essential oil, be dissolved in alcohols, add acetone respectively, methyl eugenol, ester class, fully shakes up.
Step 2, adds vegetable oil in above-mentioned solution, then adds antioxidant l, fully shakes up.
Step 3, for preventing part active ingredient fast decoupled under solar light irradiation, or by microbial destruction, can add anti ultraviolet agent in right amount, and antibacterial agent, and protection active ingredient is from destruction.Be placed with in the dark container of lid after abundant mixing, preserve at shady and cool dry place.
Step 4, be distributed into lure core or make a small amount of single use packaging time, the thickeners such as glycerine, microwax, paraffin can be added to improve sustained release performance, carry out after should fully mixing machine automatization filling and seal.Lure core if made, should note luring the protection of core and the convenience of use and safety.Also can be made into the formulations such as paste to use.Note in process ventilating and fire prevention.Every security measures such as prevention device electricity cremate generation and prevention detonation should be carried out, ensure production safety.
Wherein, described hesperetin molecular formula is C
20h
20o
7english name is Tangeretin, for tissue extract or Prof. Du Yucang materials such as Rutaceae river tangerine Citrusnobilis Lour. pericarp, bitter orange Citrus aurantium L. pericarp, oranges and tangerines Citrus reticulata Blanco leaf or stems, its English language Chemical name is called: 5,6,7,8-tetramethoxy-2-(4-methoxyphenyl) chromen-4-one, No. CAS is 481-53-8, another name is 5,6,7,8,4 '-pentamethoxyl flavones, tangeretin, molecular weight is 372.38, be white crystal under normal temperature, belong to flavonoids.
Wherein, described methyl eugenol molecular formula is C
11h
14o, English name: Methyl Eugenol, can by following plant extract: canella bay Laurus nobilis L. fruit, aristolochiaceae plant root of Chinese wild ginger Asarum heterotropoidesFr.Schmidt var.mandshuricum (Maxim.) Kitag. root, Ma Xin (wild ginger) Asarum forbesii Maxim. herb essential oil, labiate Ji Limonene Mosla grosseserrata Maxim. herb essential oil, the volatile oil of aroid calamus Acoruscalamus L. rhizome, gramineous plants is wriggled lemongrass Cymbopogon flexuosus Nees ex Steud. wet goods, or adopt artificial synthesis to produce.English language Chemical title Benzene, 1,2-dimethoxy-4-(2-propenyl)-, No. CAS is 93-15-2, and Chinese another name lures fly ether, methyleugenol, methyleugenol, and molecular weight is 178.22, and under normal temperature, outward appearance is light yellow liquid.
Wherein, ethyl butyrate molecular formula is C
6h
12o
2, English name: Ethyl butyrate, English another name: Butyric acidethyl ester, Ethyl butyrate, Ethyl butanoate, Natural ethyl butyrate, No. CAS is 105-54-4, the natural ethyl butyrate of Chinese another name, molecular weight is 116.1583, colourless liquid, has strong hesperidium fragrant, there are pineapple, banana, apple breath, easily spread.Be dissolved in 3 volume 60% ethanol, can dissolve each other with oils, be dissolved in propane diols, water insoluble, glycerine.Unstable in alkaline medium.Hesperetin is purity is more than 95% product, and citrus essential oil is citrus peel extract, and methyl eugenol is high-purity extract.
Wherein, described vegetable oil, comprises the conventional edible oils such as soybean oil, peanut oil, rape seed, but is not limited only to above-mentioned substance.
Wherein, described citrus fruit fly sex attraction agent, comprises the above component and proportioning, can add other complementary chemical substances, combines full performance for the attracting ability and product strengthening sex attraction agent.
Wherein, described citrus fruit fly sex attraction agent, can trap and kill female adult pest and the male imago of citrus fruit fly.Also to other Partial Species fruit flies, there is certain attracting action.Citrus fruit fly described herein, also citrus fruit fly by name, dacus dorsalis hendel of mandarin orange, orient fruit fly, yellow fly, fruit maggot etc., Classification system is Bactrocera dorsalis Hendel (Diptera:Tephritidae), and English name is Oriental Fruit Fly.
Wherein, the application of described citrus fruit fly sex attraction agent and preparation method thereof, the agent of described citrus fruit fly sex attraction can be used for preparing attractant, bait formulation, agricultural chemicals, lure core, lure bottle, lure paper, lure device, killing trapping device construct etc. any one or a few, or be not limited only to such use.Those skilled in the art it is understood that, the application of described citrus fruit fly sex attraction agent and preparation method thereof, in the structure active ingredient described at this patent and the framework such as using method, or any equivalent modifications that the present invention is carried out and substituting also all among category of the present invention.Therefore, equalization conversion done without departing from the spirit and scope of the invention and amendment, all should contain within the scope of the invention.
Described citrus fruit fly sex attraction agent, for citrus, pomegranate, red bayberry, peach, loquat, banana, guava, pawpaw, carambola, pears, persimmon, capsicum, eggplant, tomato, fig, lichee, longan, apricot, avocado, fruits and vegetables garden planted by jujubes etc. more than 250, and be not limited in and be applied to the above-mentioned trapping listed to citrus fruit fly female adult pest and male imago in the crop of classification, comprise and other chemical pesticides, biopesticide is (as Avermectin, pleocidin, methyl Avermectin sodium salt, ethyl pleocidin etc.), protein hydrolysate class bait formulation, the materials such as carbohydrate or light trap, the combined trapping facility that solar insect-killing device etc. are formed.
In foregoing, described ketone preferable range comprises and is not limited only to: acetone, butanone, pentanone etc., override acetone.
In foregoing, described alcohol preferable range comprises and is not limited only to: methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, most preferably be ethanol.
In foregoing, the described preferred object of ester class extracted by natural plants etc. comprises ethyl butyrate, ethyl acetate etc., but is not limited only to this, most preferably is ethyl butyrate.
In foregoing, use hesperetin to lure one of composition as citrus fruit fly, but be not limited only to this composition, also comprise the volatile materials that other host crops extract, as tangertin wet goods.
Beneficial effect:
1) the citrus fruit fly sex attraction agent that obtains of the present invention, with low cost, can lure that citrus fruit fly is female, male imago simultaneously, not containing materials such as hydrolyzed proteins, safety and environmental protection.
2) in the present invention main component all come from natural world exist natural materials or plant host in extractible material, product is Biodegradable material, environmentally friendly, building-up process green non-pollution, does not produce three industrial wastes, the Product Green environmental protection of gained, directly do not spray in crop surface, very safe to non-target organisms such as natural enemies, all very safe to environment, user and fruit, non-target organism etc. in use procedure, be suitable for long-term preservation and use.Can be applicable to the production of organic, green non-pollution fruit, vegetables, fruit, victual quality safety that effective guarantee is produced are reliable.
3) citrus fruit fly sex attraction provided by the invention agent, is easy to processing, and fully optimizes the performances such as the slowly-releasing of product self, anti-oxidant, uvioresistant and Resistance to microbes.
(4) can be used for inspection and quarantining for import/export department of China to use in the quarantine of import and export animals and plants product, again can large-area applications in the production of fruit, vegetables etc., there is huge economic benefit, ecological benefits and social benefit.
4) and, this product can organically combine with other environment-friendlybiological biological pesticide, comprehensive preventive health measuress etc. and use, compatible high.
Embodiment
Below in conjunction with concrete embodiment, the present invention is further illustrated.
Embodiment 1
The preparation of citrus fruit fly sex attraction agent prescription I:
Configure hesperetin or 2-5 gram of Panongchus citri that 2-5 gram of purity is more than 95%, be dissolved in 180 milliliters of absolute ethyl alcohols, add 30 milliliters of acetone, and 60 milliliters of methyl eugenols, 5 milliliters of ethyl butyrates, 30 milliliters of vegetable oil are added after abundant dissolving mixing, add antioxidant 3-8 milliliter, fully mix, add anti ultraviolet agent, antibacterial agent, be placed with in the dark container of lid after abundant mixing, preserve at shady and cool dry place.Add thickener or sustained release agent, fully adopt machine automatization packing to be packaged into the disposable sex attractant product of 2-10 milliliter or to be directly encapsulated as after mixing and lure core product.
Embodiment 2
The preparation of citrus fruit fly sex attraction agent prescription II:
Configure hesperetin or 2-8 gram of citrus volatile oil that 1-5 gram of purity is more than 95%, be dissolved in 160-200 milliliter absolute ethyl alcohol, add 20-40 milliliter acetone, and 80-120 milliliter methyl eugenol, 30-40 milliliter ethyl butyrate, 30-50 milliliter vegetable oil is added after abundant dissolving mixing, add antioxidant 5-10 milliliter, fully mix, add anti ultraviolet agent, antibacterial agent, be placed with in the dark container of lid after abundant mixing, preserve at shady and cool dry place.Or add thickener or sustained release agent, fully adopt machine automatization packing to be packaged into the disposable sex attractant product of 4-10 milliliter or to be directly encapsulated as after mixing and lure core product.Packaged inner wrapping product (lure or lure core) is stored in dry shady and cool lucifuge place with carton.
Embodiment 3
The use of citrus fruit fly sex attraction agent:
Open citrus fruit fly trapper, install slow-release material block/bar-shaped, inject appropriate suds in trapper or add water or the vegetable oil of washing powder, or add the biopesticides such as a small amount of chemical pesticide or Avermectin in a liquid.Unlatching attractant is packed, and is filled into slow-release material, and after all sucking, screw on trapper lid, trapper is with being fixed on tangerine Gan Shu or other host fruit trees about 1.5 meters At The Heights.Every mu can be hung 3-5 trapper, and every 7-15 days inspection once, removes the dead adult of traping in bottle, buried or burning.
Embodiment 4
Citrus fruit fly sex attraction agent or lure the replacing of core:
Take off citrus fruit fly trapper, to outward winding citrus fruit fly trapper lid, attractant is supplemented to slow-release material block/rod, or change and lure core, remove dead adult in trapper, in trapper, supplement appropriate suds (washing powder water or vegetable oil), in the liquid of below, add a small amount of chemical pesticide or the biopesticide such as Avermectin, pleocidin.Screw on citrus fruit fly trapper lid, trapper rope or hook are fixed on tangerine Gan Shu or other host fruit trees more than 1.5 meters eminences are advisable.Once, the dead adult of traping in bottle will carry out buried or burn in every 7-15 days inspection.
Product effect application testing
Measured by Electroantennogram (EAG) and test with olfaction reaction, " citrus fruit fly male imago attractant " and methyl eugenol+" agent of citrus fruit fly sex attraction " of other active ingredient composition that methyl eugenol is main component has been carried out Comprehensive Correlation and tested and field trial, on this basis adjustment and optimisation is carried out to the formula of " agent of citrus fruit fly sex attraction ", finally determine the formula of " agent of citrus fruit fly sex attraction ", and for peasant household's medication demand and custom, the citrus fruit fly trapper that development applicable orchard worker field trapping uses and spacetabs type lure core.
Indoor tentaculum electric potential (EAG) determination test result (2006,2007, Nanjing) of table 1. attractant
* adopted medicament uses after being dilution 10 times, and in experiment, methyl eugenol system is from imported from America.
Table 1 is measured by tentaculum electric potential (EAG), test two kinds of citrus fruit fly sex attractions agent and the citrus fruit fly of methyl eugenol to different age in week is female, male imago attracting ability, wherein:
Only there is the proportioning difference in active ingredient in formula I and the agent of formula I I two kinds of citrus fruit fly sex attractions, all have attracting action, and methyl eugenol only has attracting action to male imago, do not have attractant effect to female adult pest to female, male imago.
Methyl eugenol is slightly better than formula I to 1-5 male imago attractant effect in age in week, coordinates the effect or close of II, is slightly weaker than formula I or close to the attractant effect of male imago after 5 week age.Formula I to 1-3 week age male imago attractant effect a little less than formula I I, but to 7-11 week age male imago attractant effect be better than formula I I.
Table 1 result shows, except to 3 week age female adult pest attractant effect a little less than except formula I I, the attractant effect of formula I to female adult pest in other is slightly better than formula I I in each all age.
In actual applications, have employed the materials such as semi-artificial synthesis macromolecule or macromolecular material, cotton fiber, carbon nano-fiber, vegetable oil, sodium carboxymethylcellulose, Sodium Polyacrylate and carry out comparative trial as slow-release material, for different field conditions and application requirement, choose suitable material and sex attraction agent active ingredient forms slow release formulation, paste or lures core etc., and can combinationally use with low toxicity biopesticide, biochemical pesticides, low toxicity chemical pesticide, protein hydrolysate etc., form the compound trapping facility to citrus fruit fly.The present invention also has attracting action to part Fruit flies such as peach trypetid, melon trypetid and invasive fruit flies.
Above content of the present invention and preparation method, application are described, but just as example, the present invention is not restricted to particular content described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and substituting also all among category of the present invention.Therefore, equalization conversion done without departing from the spirit and scope of the invention and amendment, all should contain within the scope of the invention.
Claims (10)
1. the agent of citrus fruit fly sex attraction, is characterized in that, comprises hesperetin, alcohols, ketone, methyl eugenol, ester class, vegetable oil, antioxidant.
2. citrus fruit fly sex attraction according to claim 1 agent, is characterized in that, also comprises anti ultraviolet agent and antibacterial agent.
3. citrus fruit fly sex attraction according to claim 1 and 2 agent, is characterized in that, described antioxidant comprises vitamin E, butylhydroxy anisole, BHT.
4. citrus fruit fly sex attraction according to claim 2 agent, is characterized in that, described antibacterial agent comprises potassium sorbate, nitrite, propylene oxide.
5. citrus fruit fly sex attraction according to claim 1 and 2 agent, is characterized in that, described vegetable oil comprises soybean oil, peanut oil, rapeseed oil.
6. citrus fruit fly sex attraction according to claim 1 and 2 agent, is characterized in that, described ketone comprises: acetone, butanone, pentanone.
7. citrus fruit fly sex attraction according to claim 1 and 2 agent, is characterized in that, described alcohols comprises: methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols.
8. citrus fruit fly sex attraction according to claim 1 and 2 agent, is characterized in that, described ester class comprises: ethyl butyrate, ethyl acetate.
9. prepare the citrus fruit fly sex attraction agent method described in any one of claim 2 to 8, it is characterized in that
Step 1, provides hesperetin, is dissolved in alcohols, adds ketone, and methyl eugenol, and ester class, fully mixes;
Step 2, adds vegetable oil in above-mentioned solution, then adds antioxidant, fully mix;
Step 3, adds anti ultraviolet agent, and antibacterial agent.
10. the purposes of the citrus fruit fly sex attraction agent described in any one of claim 1 to 8, is characterized in that, for the preparation of agricultural chemicals or lure core or lure paper or lure device, or combinationally uses with protein hydrolysate, biopesticide or low toxicity chemical pesticide, strengthens trapping ability.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310537373.8A CN103548826B (en) | 2013-11-04 | 2013-11-04 | Citrus fruit fly sex attraction agent and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310537373.8A CN103548826B (en) | 2013-11-04 | 2013-11-04 | Citrus fruit fly sex attraction agent and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103548826A CN103548826A (en) | 2014-02-05 |
| CN103548826B true CN103548826B (en) | 2015-10-14 |
Family
ID=50003343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310537373.8A Expired - Fee Related CN103548826B (en) | 2013-11-04 | 2013-11-04 | Citrus fruit fly sex attraction agent and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103548826B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105010440A (en) * | 2015-08-20 | 2015-11-04 | 四川新致高生物科技有限公司 | Tephritidae insect pheromone attractant and trap-killing agent adopting attractant |
| CN105613528A (en) * | 2016-02-05 | 2016-06-01 | 烟台顺隆化工科技有限公司 | Pesticide for controlling Euaresta aequalis |
| JP7042494B2 (en) * | 2016-06-20 | 2022-03-28 | 理研香料ホールディングス株式会社 | Flying pest attractant |
| CN106818923A (en) * | 2017-01-24 | 2017-06-13 | 福建农林大学 | A kind of micro-capsule suspension for trapping and killing citrus fruit fly |
| CN106900700A (en) * | 2017-03-15 | 2017-06-30 | 全国农业技术推广服务中心 | A kind of attractant for juxiaoshi fly |
| CN108184840A (en) * | 2018-01-26 | 2018-06-22 | 程骏 | A kind of fruit fly attractant |
| CN108323532A (en) * | 2018-02-13 | 2018-07-27 | 四川省农业科学院植物保护研究所 | A kind of slow-release citrus fruit fly attractant and production method |
| CN109452325A (en) * | 2018-12-06 | 2019-03-12 | 葛诚 | A kind of dacus dorsalis male and female are double to lure attractant |
| CN111084198A (en) * | 2019-12-11 | 2020-05-01 | 广州大学 | Citrus fruit fly attractant and preparation method thereof |
| CN116439235A (en) * | 2022-12-29 | 2023-07-18 | 广西百盛源农业科技有限公司 | Fruit fly food attractant and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100393207C (en) * | 2006-09-05 | 2008-06-11 | 广东省昆虫研究所 | Oriental fruit fly attractant |
-
2013
- 2013-11-04 CN CN201310537373.8A patent/CN103548826B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103548826A (en) | 2014-02-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103548826B (en) | Citrus fruit fly sex attraction agent and its preparation method and application | |
| CN103636660B (en) | A kind of for preventing and treating the Environmental-protection particle agent of Sugarcane Pests | |
| CN103548895B (en) | Botanical vegetable insecticide | |
| CN103535389B (en) | Plant source fruit tree insecticide | |
| CN103875720B (en) | A kind of plant protecting liquid | |
| CN102283258A (en) | Plant protecting agent for plant source and preparation method thereof | |
| CN103141488A (en) | Pesticide compounded by azadirachtin and cnidium lactone and preparation method thereof | |
| KR20130114537A (en) | Due to the complex at the plant pest control for natural composition and manufacturing method | |
| CN107996628A (en) | Environment-friendly pesticide and preparation method thereof | |
| AU2020102672A4 (en) | Plant attractant composition for tephritidae pests and preparation method thereof | |
| CN102067878B (en) | Ultra-low-volume liquid preparation containing carbosulfan | |
| CN106922665A (en) | A kind of method lured the jelly composition and spray and adhesive tape of insect and reduce insect infestations | |
| CN103271103B (en) | Botanical complex insecticide containing matrine and aconitum flavum hand alkaloid and preparation method of botanical complex insecticide | |
| CN105379696B (en) | A kind of ditch socket of the eye is as food source attractant and its methods for making and using same | |
| CN103340216A (en) | Pollution-free pesticide microcapsule suspending preparation and preparation method thereof | |
| CN101637181A (en) | Pesticide mixture agent for preventing ostrinia nubilalis and application thereof | |
| CN109527000A (en) | A kind of Frankliniella occidentalis plant-originated repellent and preparation method thereof | |
| CN108684699A (en) | A kind of food-grade mosquito eradication children's preparation and its preparation method and application | |
| Nwaehujor et al. | Orange peel powder and its extracts as preservative against Callosobruchus maculates (Coleoptera: Bruchidae) attack in cowpea | |
| CN103039533B (en) | Slow-release attractant for fruit piercing moth | |
| CN105410052A (en) | Dichocrocis punctiferalis attractive toxicant | |
| CN102498984B (en) | Method for preventing and treating plutella xylostella by applying lemongrass essential oil | |
| CN105685110A (en) | Plant source composite for preventing cutworms and plant source insecticide and application thereof | |
| CN105028536A (en) | Compound botanical insecticide for mosquito larvae control, preparation method therefor and applications thereof | |
| CN105660686B (en) | A kind of leek maggot attractant and preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151014 Termination date: 20181104 |