JP7042494B2 - Flying pest attractant - Google Patents
Flying pest attractant Download PDFInfo
- Publication number
- JP7042494B2 JP7042494B2 JP2018523552A JP2018523552A JP7042494B2 JP 7042494 B2 JP7042494 B2 JP 7042494B2 JP 2018523552 A JP2018523552 A JP 2018523552A JP 2018523552 A JP2018523552 A JP 2018523552A JP 7042494 B2 JP7042494 B2 JP 7042494B2
- Authority
- JP
- Japan
- Prior art keywords
- aliphatic
- flying pest
- pest attractant
- ester
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 241000607479 Yersinia pestis Species 0.000 title claims description 71
- 239000005667 attractant Substances 0.000 title claims description 60
- 230000031902 chemoattractant activity Effects 0.000 title claims description 57
- 239000002253 acid Substances 0.000 claims description 52
- 125000001931 aliphatic group Chemical group 0.000 claims description 49
- 125000004432 carbon atom Chemical group C* 0.000 claims description 47
- 150000002148 esters Chemical class 0.000 claims description 34
- -1 aliphatic alcohols Chemical class 0.000 claims description 32
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 150000002191 fatty alcohols Chemical class 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 241000256059 Culex pipiens Species 0.000 claims description 7
- 241000255581 Drosophila <fruit fly, genus> Species 0.000 claims description 7
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 7
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 6
- 241000255131 Psychodidae Species 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 4
- 241000251468 Actinopterygii Species 0.000 claims description 2
- 235000013334 alcoholic beverage Nutrition 0.000 claims description 2
- 235000013365 dairy product Nutrition 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 235000013569 fruit product Nutrition 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 235000013372 meat Nutrition 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 235000020991 processed meat Nutrition 0.000 claims description 2
- 235000014102 seafood Nutrition 0.000 claims description 2
- 235000015170 shellfish Nutrition 0.000 claims description 2
- 235000000346 sugar Nutrition 0.000 claims description 2
- 150000008163 sugars Chemical class 0.000 claims description 2
- 239000000126 substance Substances 0.000 description 52
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 32
- 230000000694 effects Effects 0.000 description 27
- 241000255925 Diptera Species 0.000 description 17
- 239000000306 component Substances 0.000 description 13
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 8
- 230000002195 synergetic effect Effects 0.000 description 8
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 6
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 125000004185 ester group Chemical group 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- HNVRRHSXBLFLIG-UHFFFAOYSA-N 3-hydroxy-3-methylbut-1-ene Chemical compound CC(C)(O)C=C HNVRRHSXBLFLIG-UHFFFAOYSA-N 0.000 description 4
- IWTBVKIGCDZRPL-UHFFFAOYSA-N 3-methylpentanol Chemical compound CCC(C)CCO IWTBVKIGCDZRPL-UHFFFAOYSA-N 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 235000019629 palatability Nutrition 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- ASUAYTHWZCLXAN-UHFFFAOYSA-N prenol Chemical compound CC(C)=CCO ASUAYTHWZCLXAN-UHFFFAOYSA-N 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000001618 (3R)-3-methylpentan-1-ol Substances 0.000 description 2
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 2
- BZAZNULYLRVMSW-UHFFFAOYSA-N 2-Methyl-2-buten-3-ol Natural products CC(C)=C(C)O BZAZNULYLRVMSW-UHFFFAOYSA-N 0.000 description 2
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 2
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 2
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- 241000256173 Aedes albopictus Species 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000012907 honey Nutrition 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 2
- VSMOENVRRABVKN-UHFFFAOYSA-N oct-1-en-3-ol Chemical compound CCCCCC(O)C=C VSMOENVRRABVKN-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- NIONDZDPPYHYKY-SNAWJCMRSA-N (2E)-hexenoic acid Chemical compound CCC\C=C\C(O)=O NIONDZDPPYHYKY-SNAWJCMRSA-N 0.000 description 1
- LKUWQWDAIWXHIY-CHNJZELVSA-N (z)-2-methylbut-2-enoic acid Chemical compound C\C=C(\C)C(O)=O.C\C=C(\C)C(O)=O LKUWQWDAIWXHIY-CHNJZELVSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- VSMOENVRRABVKN-MRVPVSSYSA-N 1-Octen-3-ol Natural products CCCCC[C@H](O)C=C VSMOENVRRABVKN-MRVPVSSYSA-N 0.000 description 1
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 description 1
- XRMVWAKMXZNZIL-UHFFFAOYSA-N 2,2-dimethyl-1-butanol Chemical compound CCC(C)(C)CO XRMVWAKMXZNZIL-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-BYPYZUCNSA-N 2-Methylbutanoic acid Natural products CC[C@H](C)C(O)=O WLAMNBDJUVNPJU-BYPYZUCNSA-N 0.000 description 1
- AFENDNXGAFYKQO-UHFFFAOYSA-N 2-hydroxybutyric acid Chemical compound CCC(O)C(O)=O AFENDNXGAFYKQO-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 1
- NSPPRYXGGYQMPY-UHFFFAOYSA-N 3-Methylbuten-2-ol-1 Natural products CC(C)C(O)=C NSPPRYXGGYQMPY-UHFFFAOYSA-N 0.000 description 1
- YDXQPTHHAPCTPP-UHFFFAOYSA-N 3-Octen-1-ol Natural products CCCCC=CCCO YDXQPTHHAPCTPP-UHFFFAOYSA-N 0.000 description 1
- KRVXMNNRSSQZJP-PHFHYRSDSA-N 5alpha-androst-16-en-3alpha-ol Chemical compound C1[C@H](O)CC[C@]2(C)[C@H]3CC[C@](C)(C=CC4)[C@@H]4[C@@H]3CC[C@H]21 KRVXMNNRSSQZJP-PHFHYRSDSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000255930 Chironomidae Species 0.000 description 1
- 241000255601 Drosophila melanogaster Species 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 241000256095 Sciaridae Species 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- NIONDZDPPYHYKY-UHFFFAOYSA-N Z-hexenoic acid Natural products CCCC=CC(O)=O NIONDZDPPYHYKY-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- KRVXMNNRSSQZJP-UHFFFAOYSA-N beta-androstenol Natural products C1C(O)CCC2(C)C3CCC(C)(C=CC4)C4C3CCC21 KRVXMNNRSSQZJP-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005428 food component Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- 125000004043 oxo group Chemical group O=* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は、飛翔害虫誘引剤に関し、更に詳しくは、特定の２種類の成分を組み合わせて用いることによって、誘引作用が大幅に改善された飛翔害虫誘引剤に関する。 The present invention relates to a flying pest attractant, and more particularly to a flying pest attracting agent whose attractive action is significantly improved by using a combination of two specific types of components.
ハエ、蚊、コバエ等の飛翔害虫（以下、単に「害虫」という場合がある。）は、家屋等に出現し衛生環境を悪化させたり、人間を刺したり、見た目の悪さにより人を不快な気分にさせたりと、様々な害を与える。 Flying pests such as flies, mosquitoes, and midges (hereinafter, may be simply referred to as "pests") appear in houses, etc., deteriorating the hygienic environment, stinging humans, and making people feel uncomfortable due to their unsightly appearance. It causes various harms.
これらの飛翔害虫による様々な害を防ぐための防除方法として、様々な薬剤を用いた方法が開発されている。
飛翔害虫の防除方法として、飛翔害虫が好む化学成分を揮散させることで飛翔害虫を誘引する防除方法がある。誘引された飛翔害虫は、粘着剤等により捕獲する、閉鎖空間に閉じ込める、殺虫成分により殺す、等の方法により、駆除される。As a control method for preventing various harms caused by these flying pests, methods using various chemicals have been developed.
As a control method for flying pests, there is a control method for attracting flying pests by volatilizing chemical components preferred by flying pests. The attracted flying pests are exterminated by methods such as catching them with an adhesive, confining them in a closed space, and killing them with an insecticidal component.
上記のような誘引による防除方法に用いるための飛翔害虫誘引剤として、従来、様々な化学物質を使用したものが提案されている。 As a flying pest attractant for use in the above-mentioned attracting control method, those using various chemical substances have been conventionally proposed.
特許文献１には、１－オクテン－３－オール等の１－アルケン－３－オールの（Ｒ）－（－）異性体を用いる蚊を誘引するための方法が記載されている。
特許文献２には、リシン、イソ吉草酸、アラニン、アンドロステノール、皮脂のうち、１または２以上を含有することを特徴とする蚊誘引剤が記載されている。
特許文献３には、乳酸と乳酸メチルの混合物を有効成分として含有する蚊誘引剤が記載されている。Patent Document 1 describes a method for attracting mosquitoes using the (R)-(-) isomer of 1-alkene-3-ol such as 1-octen-3-ol.
Patent Document 2 describes a mosquito attractant characterized by containing one or more of lysine, isovaleric acid, alanine, androstenol, and sebum.
Patent Document 3 describes a mosquito attractant containing a mixture of lactic acid and methyl lactate as an active ingredient.
しかし、これらの誘引剤は、誘引効果が必ずしも十分ではない場合があった。特に、害虫の種類により好む誘引成分は異なり、飛翔害虫の種類によっては、これらの誘引剤は、効果を示さない場合があった。
このため、様々な飛翔害虫に対して十分な誘引効果を示す飛翔害虫誘引剤が望まれていた。However, these attractants may not always have a sufficient attracting effect. In particular, the preferred attractant component differs depending on the type of pest, and depending on the type of flying pest, these attractants may not show any effect.
Therefore, a flying pest attractant having a sufficient attracting effect on various flying pests has been desired.
本発明は上記背景技術に鑑みてなされたものであり、その課題は、従来の誘引剤よりも誘引効果が強く、様々な飛翔害虫に対して誘引効果を示す飛翔害虫誘引剤を提供することにある。 The present invention has been made in view of the above background technique, and an object thereof is to provide a flying pest attractant which has a stronger attracting effect than a conventional attracting agent and exhibits an attracting effect against various flying pests. be.
本発明者は、上記の課題を解決すべく鋭意検討を重ねた結果、特定の炭素数の脂肪族アルコールと、特定の炭素数の脂肪族酸エステルとを組み合わせて使用することにより、誘引効果が強い誘引剤となったり、様々な害虫に対して十分な誘引作用を示したりする誘引剤を製造できることを見出して、本発明を完成するに至った。 As a result of diligent studies to solve the above problems, the present inventor has an attractive effect by using a fatty alcohol having a specific carbon number in combination with an aliphatic acid ester having a specific carbon number. The present invention has been completed by finding that it is possible to produce an attractant that can be a strong attractant or exhibit a sufficient attracting action against various pests.
すなわち、本発明は、炭素数２以上６以下の脂肪族アルコール（Ａ）と、炭素数３以上８以下の脂肪族酸エステル（Ｅ）を含有することを特徴とする飛翔害虫誘引剤を提供するものである。 That is, the present invention provides a flying pest attractant comprising an aliphatic alcohol (A) having 2 or more and 6 or less carbon atoms and an aliphatic acid ester (E) having 3 or more and 8 or less carbon atoms. It is a thing.
また、本発明は、上記の飛翔害虫誘引剤を使用することを特徴とする飛翔害虫の駆除方法を提供するものである。 The present invention also provides a method for exterminating flying pests, which comprises using the above-mentioned flying pest attractant.
本発明によれば、従来の誘引剤よりも誘引効果が強く、様々な飛翔害虫に対して誘引効果を示す飛翔害虫誘引剤を提供することができる。 According to the present invention, it is possible to provide a flying pest attractant which has a stronger attracting effect than a conventional attracting agent and exhibits an attracting effect against various flying pests.
本発明の飛翔害虫誘引剤が含有する成分は、人体に対して安全な成分であるので、本発明の飛翔害虫誘引剤は、一般家庭等においても使用することができる。 Since the component contained in the flying pest attractant of the present invention is a component that is safe for the human body, the flying pest attractant of the present invention can also be used in general households and the like.
更に、本発明の飛翔害虫誘引剤において、炭素数２以上６以下の脂肪族アルコール（Ａ）及び／又は炭素数３以上８以下の脂肪族酸エステル（Ｅ）として、それぞれ複数の化合物の混合物を使用すると、様々な種類の害虫に対して誘引効果を発揮しやすくなる。 Further, in the flying pest attractant of the present invention, a mixture of a plurality of compounds is used as an aliphatic alcohol (A) having 2 or more and 6 or less carbon atoms and / or an aliphatic acid ester (E) having 3 or more and 8 or less carbon atoms. When used, it tends to exert an attractive effect against various types of pests.
以下、本発明について説明するが、本発明は以下の実施の形態に限定されるものではなく、任意に変形して実施することができる。 Hereinafter, the present invention will be described, but the present invention is not limited to the following embodiments, and can be arbitrarily modified and carried out.
本発明の飛翔害虫誘引剤は、炭素数２以上６以下の脂肪族アルコール（Ａ）と、炭素数３以上８以下の脂肪族酸エステル（Ｅ）を含有する。 The flying pest attractant of the present invention contains an aliphatic alcohol (A) having 2 or more and 6 or less carbon atoms and an aliphatic acid ester (E) having 3 or more and 8 or less carbon atoms.
脂肪族アルコール（Ａ）や脂肪族酸エステル（Ｅ）の中には、香料成分として知られているものがあり、害虫等の誘引剤の成分として使用されているものがある。しかし、これらの成分は、炭素数等によっては、害虫等を忌避する効果が強くなる。 Some of the aliphatic alcohols (A) and aliphatic acid esters (E) are known as fragrance components, and some are used as components of attractants for pests and the like. However, these components have a strong effect of repelling pests and the like depending on the number of carbon atoms and the like.
本発明において、「脂肪族アルコール（Ａ）」とは、脂肪族炭化水素基を有するアルコールをいう。
脂肪族アルコール（Ａ）の炭素数は、３以上５以下がより好ましく、４が特に好ましい。
脂肪族アルコール（Ａ）の脂肪族炭化水素基は、飽和であっても不飽和であってもよい。また、直鎖状であっても分岐を有していてもよい。In the present invention, the "aliphatic alcohol (A)" refers to an alcohol having an aliphatic hydrocarbon group.
The carbon number of the aliphatic alcohol (A) is more preferably 3 or more and 5 or less, and particularly preferably 4.
The aliphatic hydrocarbon group of the aliphatic alcohol (A) may be saturated or unsaturated. Further, it may be linear or may have a branch.
本発明の飛翔害虫誘引剤が含有する脂肪族アルコール（Ａ）の具体例としては、エタノール、１－プロパノール、２－プロパノール、２－プロペン－１－オール、１－ブタノール、２－メチル－１－プロパノール、２－ブタノール、２－メチル－２－プロパノール、１－ペンタノール、２－ペンタノール、２－メチル－１－ブタノール、３－メチル－１－ブタノール、２－メチル－２－ブタノール、２－メチル－３－ブテン－２－オール、３－メチル－２－ブテン－１－オール、１－ヘキサノール、３－メチル－１－ペンタノール、４－メチル－２－ペンタノール、２，２－ジメチル－１－ブタノール等が挙げられ、これらは１種単独で用いてもよいし、２種以上を混合して用いてもよい。
害虫により、特に好まれる誘引成分は異なる。また、同じ化合物でも、ある濃度では嗜好性が高く（誘引されやすく）、濃度が高くなると忌避する場合がある。このため、脂肪族アルコール（Ａ）として、２種類以上の化合物を混合して用いると、嗜好性の高い濃度に調節しやすくなり、多くの害虫に対して効果を発揮しやすくなる。Specific examples of the aliphatic alcohol (A) contained in the flying pest attractant of the present invention include ethanol, 1-propanol, 2-propanol, 2-propen-1-ol, 1-butanol and 2-methyl-1-. Propanol, 2-butanol, 2-methyl-2-propanol, 1-pentanol, 2-pentanol, 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, 2- Methyl-3-buten-2-ol, 3-methyl-2-buten-1-ol, 1-hexanol, 3-methyl-1-pentanol, 4-methyl-2-pentanol, 2,2-dimethyl- Examples thereof include 1-butanol and the like, and these may be used alone or in combination of two or more.
Different pests have different attracting ingredients that are particularly preferred. In addition, even the same compound has high palatability (easily attracted) at a certain concentration, and may be repelled at a high concentration. Therefore, when two or more kinds of compounds are mixed and used as the aliphatic alcohol (A), it becomes easy to adjust the concentration to a highly palatable concentration, and it becomes easy to exert an effect against many pests.
本発明において、「脂肪族酸エステル（Ｅ）」とは、脂肪族酸（Ｅ１）とアルコール（Ｅ２）が脱水縮合した構造であるエステルをいうが、脂肪族酸（Ｅ１）とアルコール（Ｅ２）の脱水縮合により製造されたものには限られない。 In the present invention, the "aliphatic acid ester (E)" refers to an ester having a structure in which an aliphatic acid (E1) and an alcohol (E2) are dehydrated and condensed, but the aliphatic acid (E1) and the alcohol (E2) are used. It is not limited to those produced by dehydration condensation of.
「脂肪族酸（Ｅ１）」とは、脂肪酸（炭化水素の１価のカルボン酸）や、脂肪酸の一部の水素原子が置換された化合物をいう。
本発明における脂肪族酸（Ｅ１）は、飽和であっても不飽和であってもよい。また、直鎖状であっても分岐を有していてもよい。The "aliphatic acid (E1)" refers to a fatty acid (monovalent carboxylic acid of a hydrocarbon) or a compound in which some hydrogen atoms of the fatty acid are substituted.
The aliphatic acid (E1) in the present invention may be saturated or unsaturated. Further, it may be linear or may have a branch.
また、「脂肪酸の一部の水素原子が置換された化合物である脂肪族酸（Ｅ１）」において、水素原子の一部を置換した置換基の種類としては、ヒドロキシル基、オキソ基等が挙げられる。 Further, in "aliphatic acid (E1) which is a compound in which a part of hydrogen atom of fatty acid is substituted", examples of the type of substituent in which a part of hydrogen atom is substituted include a hydroxyl group and an oxo group. ..
脂肪族酸（Ｅ１）の炭素数は、２以上６以下が好ましく、３以上５以下がより好ましい。 The carbon number of the aliphatic acid (E1) is preferably 2 or more and 6 or less, and more preferably 3 or more and 5 or less.
脂肪族酸（Ｅ１）の具体例としては、酢酸、プロパン酸、２－ヒドロキシプロパン酸、２－オキソプロパン酸、ブタン酸、２－メチルプロパン酸、２－ヒドロキシブタン酸、３－ヒドロキシブタン酸、２－ブテン酸、ペンタン酸、２，２－ジメチルプロパン酸、２－メチルブタン酸、３－メチルブタン酸、（Ｚ）－２－メチルブタ－２－エン酸、（Ｅ）－２－メチルブタ－２－エン酸、４－オキソペンタン酸、ヘキサン酸、２－エチルブタン酸、２－ヘキセン酸等が挙げられる。 Specific examples of the aliphatic acid (E1) include acetic acid, propanoic acid, 2-hydroxypropanoic acid, 2-oxopropanoic acid, butanoic acid, 2-methylpropanoic acid, 2-hydroxybutanoic acid and 3-hydroxybutanoic acid. 2-butenoic acid, pentanoic acid, 2,2-dimethylpropanoic acid, 2-methylbutanoic acid, 3-methylbutanoic acid, (Z) -2-methylbut-2-enoic acid, (E) -2-methylbut-2-ene Examples thereof include acid, 4-oxopentanoic acid, hexane acid, 2-ethylbutanoic acid, 2-hexenoic acid and the like.
アルコール（Ｅ２）は、飽和であっても不飽和であってもよい。また、直鎖状であっても分岐を有していてもよい。
アルコール（Ｅ２）の炭素数は、１以上５以下が好ましく、２以上４以下がより好ましい。The alcohol (E2) may be saturated or unsaturated. Further, it may be linear or may have a branch.
The carbon number of the alcohol (E2) is preferably 1 or more and 5 or less, and more preferably 2 or more and 4 or less.
アルコール（Ｅ２）の具体例としては、メタノール、エタノール、１－プロパノール、２－プロパノール、２－プロペン－１－オール、１－ブタノール、２－メチル－１－プロパノール、２－ブタノール、２－メチル－２－プロパノール、１－ペンタノール、２－ペンタノール、２－メチル－１－ブタノール、３－メチル－１－ブタノール、２－メチル－２－ブタノール、２－メチル－３－ブテン－２－オール、３－メチル－２－ブテン－１－オール、１－ヘキサノール、３－メチル－１－ペンタノール、４－メチル－２－ペンタノール、２，２－ジメチル－１－ブタノール等が挙げられる。 Specific examples of the alcohol (E2) include methanol, ethanol, 1-propanol, 2-propanol, 2-propanol-1-ol, 1-butanol, 2-methyl-1-propanol, 2-butanol, 2-methyl-. 2-propanol, 1-pentanol, 2-pentanol, 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, 2-methyl-3-buten-2-ol, Examples thereof include 3-methyl-2-butene-1-ol, 1-hexanol, 3-methyl-1-pentanol, 4-methyl-2-pentanol, 2,2-dimethyl-1-butanol and the like.
本発明の脂肪族酸エステル（Ｅ）は、脂肪族酸（Ｅ１）とアルコール（Ｅ２）が脱水縮合した構造であるエステルであるが、脂肪族酸（Ｅ１）とアルコール（Ｅ２）の組み合わせとしては、炭素数２の脂肪族酸と炭素数１以上６以下のアルコールの組み合わせ、炭素数３の脂肪族酸と炭素数１以上５以下のアルコールの組み合わせ、炭素数４の脂肪族酸と炭素数１以上４以下のアルコールの組み合わせ、炭素数５の脂肪族酸と炭素数１以上３以下のアルコールの組み合わせ、炭素数６の脂肪族酸と炭素数１以上２以下のアルコールの組み合わせが挙げられる。 The aliphatic acid ester (E) of the present invention is an ester having a structure in which an aliphatic acid (E1) and an alcohol (E2) are dehydrated and condensed, but as a combination of the aliphatic acid (E1) and the alcohol (E2), , A combination of an aliphatic acid having 2 carbon atoms and an alcohol having 1 or more carbon atoms and 6 or less carbon atoms, a combination of an aliphatic acid having 3 carbon atoms and an alcohol having 1 or more carbon atoms and 5 or less carbon atoms, an aliphatic acid having 4 carbon atoms and 1 carbon atom. Examples thereof include a combination of alcohols having 4 or less carbon atoms, an aliphatic acid having 5 carbon atoms and an alcohol having 1 or more carbon atoms and 3 or less carbon atoms, and a combination of an aliphatic acid having 6 carbon atoms and alcohols having 1 or more carbon atoms and 2 or less carbon atoms.
脂肪族酸エステル（Ｅ）の具体例としては、酢酸１－プロパノールエステル、酢酸１－ペンタノールエステル、プロパン酸２－プロペン－１－オールエステル、プロパン酸１－ブタノールエステル、２－ヒドロキシプロパン酸１－ブタノールエステル、２－オキソプロパン酸エタノールエステル、ブタン酸１－プロパノールエステル、ブタン酸２－プロパノールエステル、ブタン酸エタノールエステル、２－メチルプロパン酸２－プロパノールエステル、２－ヒドロキシブタン酸エタノールエステル、３－ヒドロキシブタン酸エタノールエステル、２－ブテン酸２－メチルプロパン－１－オールエステル、ペンタン酸メタノールエステル、２，２－ジメチルプロパン酸メタノールエステル、２－メチルブタン酸エタノールエステル、３－メチルブタン酸エタノールエステル、３－メチルブタン酸メタノールエステル、（Ｅ）－２－メチルブタ－２－エン酸エタノールエステル、４－オキソペンタン酸メタノールエステル、２－エチルブタン酸メタノールエステル、２－エチルブタン酸エタノールエステル、２－ヘキセン酸エタノールエステル等が挙げられ、これらは１種単独で用いてもよいし、２種以上を混合して用いてもよい。
害虫により、特に好まれる誘引成分は異なる。また、同じ化合物でも、ある濃度では嗜好性が高く（誘引されやすく）、濃度が高くなると忌避する場合がある。このため、脂肪族酸エステル（Ｅ）として、２種類以上の化合物を混合して用いると、嗜好性の高い濃度に調節しやすくなり、多くの害虫に対して効果を発揮しやすくなる。Specific examples of the aliphatic acid ester (E) include acetic acid 1-propanol ester, acetic acid 1-pentanol ester, propanoic acid 2-propen-1-all ester, propanoic acid 1-butanol ester, and 2-hydroxypropanoic acid 1. -Butanol ester, 2-oxopropanoic acid ethanol ester, butanoic acid 1-propanol ester, butanoic acid 2-propanol ester, butanoic acid ethanol ester, 2-methylpropanoic acid 2-propanol ester, 2-hydroxybutanoic acid ethanol ester, 3 -Hydroxybutanoic acid ethanol ester, 2-butenoic acid 2-methylpropane-1-all ester, pentanoic acid methanol ester, 2,2-dimethylpropanoic acid methanol ester, 2-methylbutanoic acid ethanol ester, 3-methylbutanoic acid ethanol ester, 3-Methylbutanoic acid methanol ester, (E) -2-Methylbuta-2-enoic acid ethanol ester, 4-oxopentanoic acid methanol ester, 2-ethylbutanoic acid methanol ester, 2-ethylbutanoic acid ethanol ester, 2-hexenoic acid ethanol ester These may be used alone or in combination of two or more.
Different pests have different attracting ingredients that are particularly preferred. In addition, even the same compound has high palatability (easily attracted) at a certain concentration, and may be repelled at a high concentration. Therefore, when two or more kinds of compounds are mixed and used as the aliphatic acid ester (E), it becomes easy to adjust the concentration to a high palatability, and it becomes easy to exert an effect against many pests.
本発明の飛翔害虫誘引剤は、炭素数２以上６以下の脂肪族アルコール（Ａ）と、炭素数３以上８以下の脂肪族酸エステル（Ｅ）を有効成分として共に含有するものであるが、該脂肪族アルコール（Ａ）と該脂肪族酸エステル（Ｅ）の含有比率（質量基準）は、０．０５≦（Ａ）／［（Ａ）＋（Ｅ）］≦０．９５が好ましく、０．１０≦（Ａ）／［（Ａ）＋（Ｅ）］≦０．９０がより好ましく、０．２０≦（Ａ）／［（Ａ）＋（Ｅ）］≦０．８０が特に好ましい。
上記範囲内であると、様々な害虫に対して十分な誘引効果を発揮しやすい。The flying pest attractant of the present invention contains both an aliphatic alcohol (A) having 2 or more and 6 or less carbon atoms and an aliphatic acid ester (E) having 3 or more and 8 or less carbon atoms as active ingredients. The content ratio (mass basis) of the fatty alcohol (A) and the aliphatic acid ester (E) is preferably 0.05 ≦ (A) / [(A) + (E)] ≦ 0.95, and is 0. .10 ≦ (A) / [(A) + (E)] ≦ 0.90 is more preferable, and 0.20 ≦ (A) / [(A) + (E)] ≦ 0.80 is particularly preferable.
Within the above range, it is easy to exert a sufficient attracting effect against various pests.
本発明の飛翔害虫誘引剤中における有効成分である炭素数２以上６以下の脂肪族アルコール（Ａ）と炭素数３以上８以下の脂肪族酸エステル（Ｅ）の含有割合は、飛翔害虫誘引剤全体に対して、（Ａ）と（Ｅ）の和で、０．１質量％以上２０質量％以下であることが好ましく、０．５質量％以上１０質量％以下であることがより好ましく、１質量％以上５質量％以下であることが特に好ましい。
上記下限以上であると、十分な誘引効果を発揮することができる。また、上記上限以下であると、適度な揮散速度となり、効果の持続時間が十分長くなる。The content ratio of the fatty alcohol (A) having 2 or more and 6 or less carbon atoms and the aliphatic acid ester (E) having 3 or more and 8 or less carbon atoms, which are the active ingredients in the flying pest attractant of the present invention, is the flying pest attractant. The sum of (A) and (E) is preferably 0.1% by mass or more and 20% by mass or less, and more preferably 0.5% by mass or more and 10% by mass or less. It is particularly preferable that it is by mass% or more and 5% by mass or less.
When it is at least the above lower limit, a sufficient attraction effect can be exhibited. Further, when it is not more than the above upper limit, the volatilization rate becomes appropriate and the duration of the effect becomes sufficiently long.
本発明の飛翔害虫誘引剤は、有効成分である炭素数２以上６以下の脂肪族アルコール（Ａ）、炭素数３以上８以下の脂肪族酸エステル（Ｅ）の他に、本発明の効果を妨げない範囲において、溶剤；香料、精油等の他の誘引成分；誘引した害虫を殺すための殺虫成分；乳化剤、分散剤、保留剤、防腐剤等の添加剤；等を含有することができる。 The flying pest attractant of the present invention has the effects of the present invention in addition to the active ingredient, an aliphatic alcohol (A) having 2 or more and 6 or less carbon atoms and an aliphatic acid ester (E) having 3 or more and 8 or less carbon atoms. To the extent that it does not interfere, it can contain solvents; other attracting components such as fragrances and essential oils; insecticidal components for killing attracted pests; additives such as emulsifiers, dispersants, retaining agents and preservatives; and the like.
溶剤としては、水；メタノール、エタノール、プロパノール、イソプロパノール、ブタノ－ル等の１価アルコール；エチレングリコール、プロピレングリコール等の多価アルコール；アセトン、メチルエチルケトン等のケトン；テトラヒドロフラン、ジオキサン、ジエチルエーテル等のエーテル；ヘキサン、ケロシン、パラフィン等の脂肪族炭化水素；ベンゼン、トルエン等の芳香族炭化水素；クロロホルム、ジクロロエタン等のハロゲン化炭化水素；酢酸エチル、酢酸ブチル等のエステル；等が挙げられ、これらは、１種単独で用いてもよいし、２種以上を混合して用いてもよい。
本発明の飛翔害虫誘引剤は、一般家庭等でも使用されうるものであり、溶剤には、安全性が要求されるので、水、１価アルコール、多価アルコールや、これらの組み合わせが好ましい。特に好ましくは、水、エタノール、プロピレングリコールや、これらの組み合わせである。
害虫の種類により、有効成分（炭素数２以上６以下の脂肪族アルコール（Ａ）及び炭素数３以上８以下の脂肪族酸エステル（Ｅ））の最適な濃度は異なる場合があるが、本発明の飛翔害虫誘引剤を上記溶剤で適宜希釈することにより、様々な害虫に対して、誘引効果を発揮する。Examples of the solvent include water; monohydric alcohols such as methanol, ethanol, propanol, isopropanol and butanol; polyhydric alcohols such as ethylene glycol and propylene glycol; ketones such as acetone and methyl ethyl ketone; ethers such as tetrahydrofuran, dioxane and diethyl ether. Fat group hydrocarbons such as hexane, kerosine and paraffin; aromatic hydrocarbons such as benzene and toluene; halogenated hydrocarbons such as chloroform and dichloroethane; esters such as ethyl acetate and butyl acetate; One type may be used alone, or two or more types may be mixed and used.
The flying pest attractant of the present invention can be used in ordinary households and the like, and since safety is required for the solvent, water, monohydric alcohol, polyhydric alcohol, or a combination thereof is preferable. Particularly preferred are water, ethanol, propylene glycol and combinations thereof.
The optimum concentration of the active ingredient (fatty alcohol (A) having 2 or more and 6 or less carbon atoms and the aliphatic acid ester (E) having 3 or more carbon atoms and 8 or less carbon atoms) may differ depending on the type of pest. By appropriately diluting the flying pest attractant with the above solvent, it exerts an attracting effect on various pests.
本発明の飛翔害虫誘引剤の形態としては特に制限はなく、例えば、液状、ゲル状、顆粒状、粉末状等の形態で用いることができ、更には噴霧して用いてもよい。 The form of the flying pest attractant of the present invention is not particularly limited, and for example, it can be used in the form of liquid, gel, granule, powder, etc., and may be further sprayed and used.
本発明は、前記飛翔害虫誘引剤を使用することを特徴とする飛翔害虫の駆除方法でもある。
駆除方法に特に限定はなく、飛翔害虫誘引剤に殺虫成分を添加し、誘引した害虫を殺虫成分の作用によって死滅させてもよいし、後述の実施例で示すように、粘着剤等を使用したトラップを使用して誘引した害虫を捕獲することで駆除してもよい。The present invention is also a method for exterminating flying pests, which comprises using the flying pest attractant.
The extermination method is not particularly limited, and an insecticidal component may be added to the flying pest attractant to kill the attracted pest by the action of the insecticidal component, or an adhesive or the like is used as shown in Examples described later. You may use a trap to catch the attracted pests and get rid of them.
害虫は、糖類、果実、果実加工品、乳製品、魚介類加工品、魚介類抽出物、食肉加工品、食肉抽出物、酒類、酒粕、穀類等の食物を好む傾向にあるので、これらの食物を併用することで、誘引効果を高めることができる場合がある。
上記食物は、１種単独で用いてもよいし、２種以上を混合して用いてもよい。
また、上記食物成分は、本発明の飛翔害虫誘引剤に含有させてもよいし、本発明の飛翔害虫誘引剤を塗布・設置等した場所の付近に別途設置してもよい。Pests tend to prefer foods such as sugars, fruits, processed fruit products, dairy products, processed seafood products, fish and shellfish extracts, processed meat products, meat extracts, alcoholic beverages, lees, grains, etc. In some cases, the attraction effect can be enhanced by using in combination with.
The above-mentioned foods may be used alone or in combination of two or more.
Further, the above-mentioned food component may be contained in the flying pest attractant of the present invention, or may be separately installed in the vicinity of a place where the flying pest attractant of the present invention is applied or installed.
本発明の飛翔害虫誘引剤は、特に、ハエ類、蚊類、コバエ類等の飛翔害虫に対して誘引作用を発揮する。具体的には、イエバエ、ヒメイエバエ等のハエ類；アカイエカ、ヒトスジシマカ等の蚊類；ショウジョウバエ、ノミバエ、クロバネキノコバエ、キノコバエ、チョウバエ等のコバエ類に対して誘引作用を発揮する。 The flying pest attractant of the present invention exerts an attracting action particularly against flying pests such as flies, mosquitoes and flies. Specifically, it exerts an attractive action against flies such as houseflies and Aedes albopictus; mosquitoes such as Culex pipiens and Aedes albopictus; and flies such as Drosophila, flies, Sciaridae, mushroom flies, and butterfly flies.
以下に、実施例を挙げて本発明を更に具体的に説明するが、本発明は、その要旨を超えない限りこれらの実施例及び比較例に限定されるものではない。
以下、単に「％」というときは、「質量％」を意味する。Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples and comparative examples as long as the gist thereof is not exceeded.
Hereinafter, the term "%" simply means "mass%".
表１に、実施例等で使用した脂肪族アルコール（Ａ）を示す。表２に実施例等で使用した脂肪族酸エステル（Ｅ）を示す。 Table 1 shows the aliphatic alcohol (A) used in Examples and the like. Table 2 shows the aliphatic acid ester (E) used in Examples and the like.
試験例１（ショウジョウバエの誘引試験）
ハチミツ水（４０％）に、表３に示す試験物質Ａ（脂肪族アルコール（Ａ））、試験物質Ｅ（脂肪族酸エステル（Ｅ））、試験物質Ａ＋Ｅ（脂肪族アルコール（Ａ）と脂肪族酸エステル（Ｅ）の混合物）を、それぞれ２．０％となるように添加し、各試験液を調製した。Test Example 1 (Drosophila attraction test)
Test substance A (fatty alcohol (A)), test substance E (fatty acid ester (E)), test substance A + E (fatty alcohol (A) and fatty alcohol) shown in Table 3 in honey water (40%). A mixture of acid ester (E)) was added so as to be 2.0% each, and each test solution was prepared.
調製した各試験液を、１４ｍｍ（縦）×２４ｍｍ（横）×２ｍｍ（厚み）のパルプにそれぞれ１．０ｇずつ含浸したものを約１時間風乾し、各試験物質がパルプに染み込んだ誘引剤を作製した。 Each of the prepared test solutions was impregnated with 1.0 g of each 14 mm (length) x 24 mm (horizontal) x 2 mm (thickness) pulp and air-dried for about 1 hour to obtain an attractant in which each test substance soaked into the pulp. Made.
試験箱として、５８２ｍｍ（縦）×９００ｍｍ（横）×６００ｍｍ（高さ）（０．３１ｍ３）のベニヤ板製コンテナを用いた。コンテナ側面の２面は金網を張り、上部には観察が容易になるように透明なプラスチック板を設置した。As a test box, a plywood container of 582 mm (length) × 900 mm (width) × 600 mm (height) (0.31 m 3 ) was used. Wire mesh was placed on the two sides of the container, and a transparent plastic plate was installed on the top for easy observation.
１００×８０ｍｍの接着シートをトラップとして４個用意し、そのうち２個のシートの中央部に試験物質Ａ（又は試験物質Ｅ）が染み込んだ誘引剤を設置した。他の２個のシートの中央部に試験物質Ａ＋Ｅが染み込んだ誘引剤を設置した。 Four 100 × 80 mm adhesive sheets were prepared as traps, and an attractant impregnated with the test substance A (or the test substance E) was installed in the center of the two sheets. An attractant impregnated with the test substance A + E was installed in the center of the other two sheets.
試験箱内に、誘引剤を設置したシート（トラップ）４個を、２００ｍｍ間隔となるように、交差するように設置した。すなわち、試験箱を上から見た場合に、左上（場所＜１＞）と右下（場所＜４＞）には試験物質Ａ（又は試験物質Ｅ）が染み込んだ誘引剤を設置したシート（トラップ）を、右上（場所＜２＞）と左下（場所＜３＞）には試験物質Ａ＋Ｅが染み込んだ誘引剤を設置したシート（トラップ）を、それぞれ設置した。 In the test box, four sheets (traps) in which the attractant was installed were installed so as to intersect each other at intervals of 200 mm. That is, when the test box is viewed from above, a sheet (trap) in which an attractant impregnated with test substance A (or test substance E) is installed in the upper left (place <1>) and lower right (place <4>). ), And a sheet (trap) in which an attractant impregnated with the test substance A + E was placed in the upper right (place <2>) and lower left (place <3>), respectively.
約１００頭のキイロショウジョウバエを試験箱内に放飼した。放飼してから、約２４時間後に接着シートで捕獲されたハエの数（捕虫数）を調べた。 About 100 Drosophila melanogaster were released in the test box. Approximately 24 hours after release, the number of flies captured on the adhesive sheet (number of insects caught) was examined.
また、試験箱内の場所による害虫の集まりやすさによる影響（詳細な理由は不明だが、光の当たり方等に起因すると考えられる）をなくすため、試験物質Ａ（又は試験物質Ｅ）が染み込んだ誘引剤を設置したシート（トラップ）と、試験物質Ａ＋Ｅが染み込んだ誘引剤を設置したシート（トラップ）の位置関係を逆にして同じことを行い、接着シートで捕獲されたハエの数を調べた。 In addition, test substance A (or test substance E) was infiltrated in order to eliminate the effect of the ease of gathering of pests depending on the location inside the test box (the detailed reason is unknown, but it is thought to be due to the way the light hits, etc.). The same thing was done by reversing the positional relationship between the sheet (trap) on which the attractant was installed and the sheet (trap) on which the attractant soaked with the test substance A + E was installed, and the number of flies captured by the adhesive sheet was investigated. ..
シート（トラップ）の位置関係を２通りにして実施した試験で、各シート（トラップ）設置場所の捕虫数を積算し、試験物質Ａ＋Ｅを使用した時の捕虫数を、試験物質Ａ又は試験物質Ｅを使用した時の捕虫数で除した値である増強率を算出した。 In the test conducted with the positional relationship of the sheets (traps) in two ways, the number of insects caught at each sheet (trap) installation location was integrated, and the number of insects caught when the test substance A + E was used was determined by the test substance A or the test substance E. Was calculated by dividing by the number of insects caught when using.
表３のＮｏ．１の試験物質の組み合わせを使用した場合の試験結果を表４及び表５に示す。 No. in Table 3 The test results when the combination of the test substances of 1 is used are shown in Tables 4 and 5.
表４及び表５から、エタノールと２－ヒドロキシプロパン酸１－ブタノールエステルを混合した場合は、ショウジョウバエに対して、エタノールや２－ヒドロキシプロパン酸１－ブタノールエステルを単独で使用した場合より、相乗誘引効果が認められた。 From Tables 4 and 5, when ethanol and 2-hydroxypropanoic acid 1-butanol ester are mixed, synergistic attraction is performed with respect to Drosophila as compared with the case where ethanol or 2-hydroxypropanoic acid 1-butanol ester is used alone. The effect was recognized.
また、表３に示す他の試験物質の組み合わせを使用した場合の試験結果を表６に示す。 Table 6 shows the test results when the combinations of other test substances shown in Table 3 are used.
表６から、炭素数２以上６以下の脂肪族アルコールと炭素数３以上８以下の脂肪族酸エステルを混合した場合は、ショウジョウバエに対して、脂肪族アルコールや脂肪族酸エステルを単独で使用した場合より、相乗誘引効果が認められた。 From Table 6, when an aliphatic alcohol having 2 or more and 6 or less carbon atoms and an aliphatic acid ester having 3 or more and 8 or less carbon atoms were mixed, the aliphatic alcohol or the aliphatic acid ester was used alone for the Drosophila. In some cases, a synergistic attraction effect was observed.
次に、試験物質Ａと試験物質Ｅの少なくとも一方を、２種類以上の化合物の混合物としてショウジョウバエの誘引試験をした。
表７に示す試験物質の組み合わせを使用した場合の試験結果を表８に示す。Next, an attraction test for Drosophila was carried out using at least one of the test substance A and the test substance E as a mixture of two or more kinds of compounds.
Table 8 shows the test results when the combination of test substances shown in Table 7 was used.
表８から、試験物質Ａや試験物質Ｅとして、２種類以上の化合物の混合物を使用した場合も、炭素数２以上６以下の脂肪族アルコール群と炭素数３以上８以下の脂肪族酸エステル群を混合した場合は、ショウジョウバエに対して、脂肪族アルコール群や脂肪族酸エステル群をそれぞれ単独で使用した場合より、相乗誘引効果が認められた。 From Table 8, even when a mixture of two or more compounds is used as the test substance A or the test substance E, the aliphatic alcohol group having 2 or more and 6 or less carbon atoms and the aliphatic acid ester group having 3 or more carbon atoms and 8 or less carbon atoms are used. When the above was mixed, a synergistic attracting effect was observed with respect to Drosophila as compared with the case where the aliphatic alcohol group and the aliphatic acid ester group were used alone.
試験例２（チョウバエの誘引試験）
５８２ｍｍ（縦）×９００ｍｍ（横）×６００ｍｍ（高さ）（０．３１ｍ３）のベニヤ板製コンテナを用いて、供試虫としてオオチョウバエを使って、試験例１と同様の試験を行った。Test Example 2 (Psychodidae attraction test)
The same test as in Test Example 1 was carried out using a plywood container of 582 mm (length) × 900 mm (width) × 600 mm (height) (0.31 m 3 ) and Psychodidae as a test insect.
試験物質Ａ及び試験物質Ｅとして、それぞれ１種類の化合物を使用した場合（表９に示す試験物質の組み合わせを使用した場合）の試験結果を表１０に示す。 Table 10 shows the test results when one kind of compound is used as the test substance A and the test substance E (when the combination of the test substances shown in Table 9 is used).
表１０から、炭素数２以上６以下の脂肪族アルコールと炭素数３以上８以下の脂肪族酸エステルを混合した場合は、オオチョウバエに対して、脂肪族アルコールや脂肪族酸エステルを単独で使用した場合より、相乗誘引効果が認められた。 From Table 10, when an aliphatic alcohol having 2 or more and 6 or less carbon atoms and an aliphatic acid ester having 3 or more and 8 or less carbon atoms are mixed, the aliphatic alcohol or the aliphatic acid ester is used alone for the butterfly fly. A synergistic attraction effect was observed.
次に、試験物質Ａと試験物質Ｅの少なくとも一方を、２種類以上の化合物の混合物としてオオチョウバエの誘引試験をした。
表１１に示す試験物質の組み合わせを使用した場合の試験結果を表１２に示す。Next, at least one of the test substance A and the test substance E was subjected to an attraction test for Psychodidae as a mixture of two or more kinds of compounds.
Table 12 shows the test results when the combination of the test substances shown in Table 11 was used.
表１２から、試験物質Ａや試験物質Ｅとして、２種類以上の化合物の混合物を使用した場合も、炭素数２以上６以下の脂肪族アルコール群と炭素数３以上８以下の脂肪族酸エステル群を混合した場合は、オオチョウバエに対して、脂肪族アルコール群や脂肪族酸エステル群をそれぞれ単独で使用した場合より、相乗誘引効果が認められた。 From Table 12, even when a mixture of two or more compounds is used as the test substance A or the test substance E, the aliphatic alcohol group having 2 or more and 6 or less carbon atoms and the aliphatic acid ester group having 3 or more carbon atoms and 8 or less carbon atoms are used. In the case of mixing, a synergistic attracting effect was observed for the fatty alcohol flies as compared with the case where the aliphatic alcohol group and the aliphatic acid ester group were used alone.
試験例３（アカイエカの誘引試験）
甘蔗黒蜜に、表１３に示す試験物質Ａ（脂肪族アルコール（Ａ））、試験物質Ｅ（脂肪族酸エステル（Ｅ））、試験物質Ａ＋Ｅ（脂肪族アルコール（Ａ）と脂肪族酸エステル（Ｅ）の混合物）を、それぞれ２．０％となるように混合し、液状誘引剤を調製した。
調製した液状誘引剤を、６０ｍｍ（内径）×４５ｍｍ（高さ）の丸型容器に１０．０ｇずつ入れた。Test Example 3 (Culex pipiens attraction test)
Test substance A (fatty alcohol (A)), test substance E (fatty acid ester (E)), test substance A + E (fatty alcohol (A) and aliphatic acid ester) shown in Table 13 are added to sweet potato black honey. The mixture of E)) was mixed so as to be 2.0% each to prepare a liquid attractant.
The prepared liquid attractant was placed in a round container of 60 mm (inner diameter) × 45 mm (height) in an amount of 10.0 g each.
試験箱として、８５０ｍｍ（縦）×１５００ｍｍ（横）×８２０ｍｍ（高さ）（１．０４ｍ３）のベニヤ板製コンテナを用いた。コンテナ側面の２面は金網を張り、上部は観察が容易になるように透明なプラスチック板を設置した。As a test box, a plywood container of 850 mm (length) × 1500 mm (width) × 820 mm (height) (1.04 m 3 ) was used. Wire mesh was placed on the two sides of the container, and a transparent plastic plate was installed on the upper part for easy observation.
１００×８０ｍｍの接着シート（直径５ｍｍの穴を４個開けた）を４個用意し、そのうち２個を、試験物質Ａを添加した液状誘引剤の入った丸型容器の上に設置し、トラップを作製した。他の２個を、試験物質Ａ＋Ｅを添加した液状誘引剤の入った丸型容器の上に設置し、トラップを作製した。 Prepare four 100 x 80 mm adhesive sheets (with four holes with a diameter of 5 mm), and place two of them on a round container containing a liquid attractant containing test substance A and trap them. Was produced. The other two were placed on a round container containing a liquid attractant to which the test substance A + E was added to prepare a trap.
試験箱内に、トラップ４個を、３００ｍｍ間隔となるように、交差するように設置した。すなわち、試験箱を上から見た場合に、左上（場所＜１＞）と右下（場所＜４＞）には試験物質Ａ（又は試験物質Ｅ）を添加した液状誘引剤を使用したトラップを、右上（場所＜２＞）と左下（場所＜３＞）には試験物質Ａ＋Ｅを添加した液状誘引剤を使用したトラップを、それぞれ設置した。 Four traps were installed in the test box so as to intersect each other at intervals of 300 mm. That is, when the test box is viewed from above, a trap using a liquid attractant to which test substance A (or test substance E) is added is placed in the upper left (place <1>) and lower right (place <4>). , Traps using a liquid attractant to which the test substance A + E was added were installed in the upper right (place <2>) and lower left (place <3>), respectively.
約１００頭のアカイエカを試験箱内に放飼した。放飼してから、約２４時間後に接着シートで捕獲されたアカイエカの数を調べた。 About 100 Culex pipiens were released in the test box. Approximately 24 hours after release, the number of Culex pipiens captured on the adhesive sheet was examined.
また、試験物質Ａ（又は試験物質Ｅ）を添加した液状誘引剤を使用したトラップと、試験物質Ａ＋Ｅを添加した液状誘引剤を使用したトラップの位置関係を逆にして同じことを行い、接着シートで捕獲されたアカイエカの数を調べた。 Further, the same thing is done by reversing the positional relationship between the trap using the liquid attractant to which the test substance A (or the test substance E) is added and the trap using the liquid attractant to which the test substance A + E is added, and the adhesive sheet. The number of Culex pipiens captured in.
表１３のＮｏ．４１の試験物質の組み合わせを使用した場合の試験結果を表１４及び表１５に示す。 No. in Table 13 The test results when the combination of 41 test substances is used are shown in Tables 14 and 15.
表１４及び表１５から、２－ブタノールと（Ｅ）－２－メチルブタ－２－エン酸エタノールエステルを混合した場合は、アカイエカに対して、２－ブタノールや（Ｅ）－２－メチルブタ－２－エン酸エタノールエステルを単独で使用した場合より、相乗誘引効果が認められた。 From Tables 14 and 15, when 2-butanol and (E) -2-methylbuta-2-enoic acid ethanol ester were mixed, 2-butanol and (E) -2-methylbuta-2- A synergistic attracting effect was observed as compared with the case where the enoic acid ethanol ester was used alone.
また、表１３に示す他の試験物質の組み合わせを使用した場合の試験結果を表１６に示す。 Table 16 shows the test results when the combinations of other test substances shown in Table 13 were used.
表１６から、炭素数２以上６以下の脂肪族アルコールと炭素数３以上８以下の脂肪族酸エステルを混合した場合は、アカイエカに対して、脂肪族アルコールや脂肪族酸エステルを単独で使用した場合より、相乗誘引効果が認められた。 From Table 16, when an aliphatic alcohol having 2 or more and 6 or less carbon atoms and an aliphatic acid ester having 3 or more and 8 or less carbon atoms were mixed, the aliphatic alcohol or the aliphatic acid ester was used alone with respect to Akai Eka. In some cases, a synergistic attraction effect was observed.
次に、試験物質Ａと試験物質Ｅの少なくとも一方を、２種類以上の化合物の混合物としてアカイエカの誘引試験をした。
表１７に示す試験物質の組み合わせを使用した場合の試験結果を表１８に示す。Next, at least one of the test substance A and the test substance E was subjected to an attraction test of Culex pipiens as a mixture of two or more kinds of compounds.
Table 18 shows the test results when the combination of test substances shown in Table 17 was used.
表１８から、試験物質Ａや試験物質Ｅとして、２種類以上の化合物の混合物を使用した場合も、炭素数２以上６以下の脂肪族アルコール群と炭素数３以上８以下の脂肪族酸エステル群を混合した場合は、アカイエカに対して、脂肪族アルコール群や脂肪族酸エステル群をそれぞれ単独で使用した場合より、相乗誘引効果が認められた。 From Table 18, even when a mixture of two or more compounds is used as the test substance A or the test substance E, the aliphatic alcohol group having 2 or more and 6 or less carbon atoms and the aliphatic acid ester group having 3 or more carbon atoms and 8 or less carbon atoms are used. When the above was mixed, a synergistic inducing effect was observed with respect to Akai Eka as compared with the case where the aliphatic alcohol group and the aliphatic acid ester group were used alone.
本発明の飛翔害虫誘引剤は、様々な飛翔害虫に対して誘引効果を示すため、一般家庭用、工業用等の誘引剤として広く利用されるものである。 The flying pest attractant of the present invention is widely used as an attracting agent for general household use, industrial use, etc. because it exhibits an attracting effect on various flying pests.
Claims (8)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016121380 | 2016-06-20 | ||
| JP2016121380 | 2016-06-20 | ||
| PCT/JP2017/016191 WO2017221539A1 (en) | 2016-06-20 | 2017-04-24 | Flying pest attracting agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2017221539A1 JPWO2017221539A1 (en) | 2019-04-11 |
| JP7042494B2 true JP7042494B2 (en) | 2022-03-28 |
Family
ID=60784418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018523552A Active JP7042494B2 (en) | 2016-06-20 | 2017-04-24 | Flying pest attractant |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP7042494B2 (en) |
| CN (1) | CN109310085A (en) |
| WO (1) | WO2017221539A1 (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080305072A1 (en) | 2005-05-09 | 2008-12-11 | Edi Malo Alvaro Rivera | Attractant for the Anastrepha Obliqua Fruit Fly |
| CN102599193A (en) | 2012-03-01 | 2012-07-25 | 西南大学 | Food attractant of Bactrocera minax |
| JP2013151470A (en) | 2011-12-28 | 2013-08-08 | Dainippon Jochugiku Co Ltd | Flying insect pest attracting agent |
| WO2013156492A2 (en) | 2012-04-16 | 2013-10-24 | Biobest N.V. | Compositions for attracting drosophila |
| CN103548826A (en) | 2013-11-04 | 2014-02-05 | 吴小毅 | Bactrocera dorsalis amphoteric attractant as well as preparation method and application thereof |
| WO2014053016A1 (en) | 2012-10-03 | 2014-04-10 | Griffith University | Fruit fly olfactory attractant composition and use thereof |
| JP2015013831A (en) | 2013-07-05 | 2015-01-22 | アース製薬株式会社 | Method of enhancing pest attracting effect |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101268786B (en) * | 2008-04-18 | 2011-03-30 | 浙江大学 | Winged insect attractant |
| TW201127297A (en) * | 2009-11-13 | 2011-08-16 | Univ Okayama Nat Univ Corp | Repellent method using volatile calling pheromone of termite eggs and queen phoromone |
| JP6254371B2 (en) * | 2012-06-29 | 2017-12-27 | 大日本除蟲菊株式会社 | Aqueous gel bead type flying insect repellent |
| CN103155919B (en) * | 2013-03-26 | 2014-09-24 | 德清科中杰生物科技有限公司 | Culex attractant |
| CN105325410B (en) * | 2015-12-01 | 2017-07-07 | 河北大学 | A kind of sea-buckthorn is around trypetid attractant |
-
2017
- 2017-04-24 JP JP2018523552A patent/JP7042494B2/en active Active
- 2017-04-24 WO PCT/JP2017/016191 patent/WO2017221539A1/en active Application Filing
- 2017-04-24 CN CN201780035175.8A patent/CN109310085A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080305072A1 (en) | 2005-05-09 | 2008-12-11 | Edi Malo Alvaro Rivera | Attractant for the Anastrepha Obliqua Fruit Fly |
| JP2013151470A (en) | 2011-12-28 | 2013-08-08 | Dainippon Jochugiku Co Ltd | Flying insect pest attracting agent |
| CN102599193A (en) | 2012-03-01 | 2012-07-25 | 西南大学 | Food attractant of Bactrocera minax |
| WO2013156492A2 (en) | 2012-04-16 | 2013-10-24 | Biobest N.V. | Compositions for attracting drosophila |
| WO2014053016A1 (en) | 2012-10-03 | 2014-04-10 | Griffith University | Fruit fly olfactory attractant composition and use thereof |
| JP2015013831A (en) | 2013-07-05 | 2015-01-22 | アース製薬株式会社 | Method of enhancing pest attracting effect |
| CN103548826A (en) | 2013-11-04 | 2014-02-05 | 吴小毅 | Bactrocera dorsalis amphoteric attractant as well as preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017221539A1 (en) | 2017-12-28 |
| CN109310085A (en) | 2019-02-05 |
| JPWO2017221539A1 (en) | 2019-04-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5814325A (en) | Process for repelling and killing insects and compositions to effect the same comprising a monoterpene | |
| DE69432143T2 (en) | NON-HAZARDOUS PEST CONTROL | |
| JP5561663B2 (en) | 匍匐 Pest repellent and repellant method | |
| JP6663228B2 (en) | Volatile enclosed space pesticide | |
| JP2002173407A (en) | Flying insect repellent | |
| JP6576643B2 (en) | Volatile closed space insecticide | |
| TW200948273A (en) | Pesticidal compositions | |
| JP2010126486A (en) | New insect pest repellent | |
| WO2001013727A1 (en) | Plant protection | |
| GB2496741A (en) | Rodent and insect repellent comprising essential oils | |
| WO2018039376A1 (en) | Insect repellent compounds and compositions, and methods thereof | |
| JP2010184919A (en) | Method for preventing migration of smell of crawling vermin repelling component | |
| KR101181454B1 (en) | Liquid type composition for repelling animal and birds | |
| JP2013177342A (en) | Insect-controlling agent | |
| JP7042494B2 (en) | Flying pest attractant | |
| JP7093558B2 (en) | Flying pest attractant | |
| Adanan et al. | Efficacy and sublethal effects of mosquito mats on Aedes aegypti and Culex quinquefasciatus (Diptera: Culicidae). | |
| CN103621516B (en) | A kind of active component of luring Groton bug and preparation method thereof | |
| AU2020303404A1 (en) | Bed bug control composition and process of preparing the same | |
| KR101591090B1 (en) | Method for preventing odor-spread of creeping pest repelling compound | |
| JP2024094990A (en) | Attractant for mosquitoes and attractant composition for mosquitoes | |
| KR100468022B1 (en) | Essential oil composition for repelling insect | |
| JP4114114B2 (en) | Spatial repellent and extermination methods for pests | |
| JP2023055682A (en) | Mosquito attractant and mosquito attraction method | |
| JPH0768097B2 (en) | Pest repellent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200221 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210126 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210322 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20210831 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20211129 |
|
| C60 | Trial request (containing other claim documents, opposition documents) |
Free format text: JAPANESE INTERMEDIATE CODE: C60 Effective date: 20211129 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20211206 |
|
| C21 | Notice of transfer of a case for reconsideration by examiners before appeal proceedings |
Free format text: JAPANESE INTERMEDIATE CODE: C21 Effective date: 20211207 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20220208 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20220308 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7042494 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |