JP2002173407A - Flying insect repellent - Google Patents
Flying insect repellentInfo
- Publication number
- JP2002173407A JP2002173407A JP2000369829A JP2000369829A JP2002173407A JP 2002173407 A JP2002173407 A JP 2002173407A JP 2000369829 A JP2000369829 A JP 2000369829A JP 2000369829 A JP2000369829 A JP 2000369829A JP 2002173407 A JP2002173407 A JP 2002173407A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- flying
- active ingredient
- insect repellent
- flying insect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本願発明は、天然精油を用いた飛
翔昆虫忌避剤に関するものであり、家畜小屋、犬小屋、
室内、また、身につけたり、設置することで開放空間や
室内の一部分の空間内における蚊やサシバエなどの吸血
性害虫の吸血行動や、ショウジョウバエ、チョウバエ、
イエバエ、ヒメイエバエ、メマトイなどの害虫の飛来行
動を抑制する飛翔昆虫忌避剤である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flying insect repellent using natural essential oils, and is used for livestock pens, dog kennels,
The blood-sucking behavior of blood-sucking pests, such as mosquitoes and sand flies, in open spaces and in parts of indoor spaces when worn or installed, as well as in Drosophila, Drosophila,
It is a flying insect repellent that suppresses the flying behavior of insect pests such as house flies, gypsophila and mematii.
【０００２】[0002]
【従来の技術とその問題点】従来の害虫の飛来及び吸血
性昆虫を駆除するものとして、殺虫剤を用いた線香、電
気蚊取りマット、電気蚊取り液、エアゾール式の害虫駆
除剤が上市されているが、いずれも殺虫、ノックダウン
を目的とし、比較的広範囲にわたってその効力を維持す
るために、かなり高濃度の薬剤を空気中に存在させる必
要があった。そのため、薬剤による人体に対する害がし
ばしば問題となっている。2. Description of the Related Art Incense sticks, electric mosquito-removing mats, electric mosquito-removing liquids, and aerosol-type pesticides using insecticides have been put on the market as conventional ones for controlling pest flying and blood-sucking insects. However, all of them are aimed at killing insects and knocking down, and in order to maintain their efficacy over a relatively wide range, it was necessary to have a considerably high concentration of the drug in the air. Therefore, harm to the human body due to drugs is often a problem.
【０００３】また、吸血性の害虫忌避剤として、ジエチ
ルトルアミド（ＤＥＥＴ）を有効成分とするエアゾール
式、ウエットテッシュ式、ゲル式のものが上市されてい
るが、いずれも人や動物類の体表面に直接塗布するもの
であることから、有効成分やその添加剤などによる影響
が懸念されている。さらに、ジエチルトルアミド（ＤＥ
ＥＴ）には空間での忌避効果は弱く、害虫との接触によ
る忌避効果のみであり、接触面以外からの害虫侵入を阻
止できないという問題がある。従って、一定空間内での
害虫忌避を有効、かつ確実に達成できる害虫忌避剤が強
く求められていた。[0003] As the blood-absorbing insect repellent, aerosol, wet-tissue, and gel-type products containing diethyltoluamide (DEET) as an active ingredient have been put on the market. Since it is applied directly to the surface, there is a concern that the effects of the active ingredient and its additives may be caused. Furthermore, diethyltoluamide (DE
ET) has a problem that the repelling effect in space is weak, only the repelling effect due to contact with the pests, and the infestation of pests from other than the contact surface cannot be prevented. Therefore, there has been a strong demand for a pest repellent that can effectively and reliably achieve pest repellency in a certain space.
【０００４】[0004]
【発明が解決しようとする課題】本願発明の目的は、従
来の駆除剤のようなノックダウンや殺虫ではなく、安全
性が高く、飛翔昆虫に対して高い空間忌避効果を有し、
低濃度でも害虫の飛来及び吸血行動を抑制させることが
できる飛翔昆虫忌避剤を提供することにある。An object of the present invention is not to knock down or kill insects as in the case of conventional pesticides, but to have high safety and a high space repellent effect against flying insects.
An object of the present invention is to provide a flying insect repellent which can suppress the pests from flying and sucking behavior even at a low concentration.
【０００５】[0005]
【課題を解決するための手段】前記目的を達成するため
に、請求項１に係る発明は、天然精油であるオレンジ
油、カシア油、グレープフルーツ油、クローブ油、シダ
ーウッド油、シトロネラ油、シナモン油、シナモンリー
フ油、ゼラニウム油、タイムホワイト油、ハッカ油、ヒ
バ油、ピメント油、フェンネル油、ペニーローヤル油、
ペパーミント油、ベルガモット油、ラベンダー油、ルー
油、レモングラス油から選ばれた１種又は２種以上を有
効成分として含有する飛翔昆虫忌避剤である。In order to achieve the above object, the invention according to claim 1 is characterized in that the essential oils are orange oil, cassia oil, grapefruit oil, clove oil, cedarwood oil, citronella oil, cinnamon oil, Cinnamon leaf oil, geranium oil, thyme oil, peppermint oil, hiba oil, pimento oil, fennel oil, penny royal oil,
A flying insect repellent containing one or more selected from peppermint oil, bergamot oil, lavender oil, roux oil, and lemongrass oil as active ingredients.
【０００６】前記目的を達成するために、請求項２に係
る発明は、前記有効成分を担体に保持させ、閉鎖空間に
有効成分量として３０ｍｇ／ｍ３〜１０００ｍｇ／ｍ３
設置し、常温蒸散させることにより害虫の飛来及び吸血
行動を抑制させる飛翔昆虫忌避剤である。[0006] To achieve the above object, the invention according to claim 2, wherein the active ingredient is held by the carrier, 30mg / m 3 ~1000mg / m 3 as an active ingredient amount in the closed space
It is a flying insect repellent that is installed and evaporates at room temperature to suppress pests from flying and sucking blood.
【０００７】前記目的を達成するために、請求項３に係
る発明は、前記有効成分を担体に保持又は溶剤に溶解さ
せ、加熱蒸散及び送風蒸散のうち少なくとも１つ以上の
蒸散により閉鎖空間に０．１ｍｇ／ｈｒ／ｍ３〜１０ｍ
ｇ／ｈｒ／ｍ３蒸散させることにより害虫の飛来及び吸
血行動を抑制させる飛翔昆虫忌避剤である。In order to achieve the above object, the invention according to claim 3 is characterized in that the active ingredient is retained in a carrier or dissolved in a solvent, and the active ingredient is contained in a closed space by at least one of heat evaporation and air evaporation. .1mg / hr / m 3 ~10m
a flying insect repellents to suppress flying and blood-sucking behavior pests by causing g / hr / m 3 transpiration.
【０００８】前記目的を達成するために、請求項４に係
る発明は、前記有効成分として含有する天然精油に加え
て、ピレスロイド系殺虫剤の１種又は２種以上を有効成
分として含有する飛翔昆虫忌避剤である。In order to achieve the above object, a fourth aspect of the present invention is a flying insect comprising, as an active ingredient, one or more pyrethroid insecticides in addition to the natural essential oil contained as the active ingredient. It is a repellent.
【０００９】[0009]
【発明の実施の形態】本願発明者らは、前記課題を解決
すべく、安全性が高く、一定空間内での害虫忌避を有
効、かつ、確実に達成できる害虫忌避剤を鋭意検討した
結果、天然精油であるオレンジ油、カシア油、グレープ
フルーツ油、クローブ油、シダーウッド油、シトロネラ
油、シナモン油、シナモンリーフ油、ゼラニウム油、タ
イムホワイト油、ハッカ油、ヒバ油、ピメント油、フェ
ンネル油、ペニーローヤル油、ペパーミント油、ベルガ
モット油、ラベンダー油、ルー油、レモングラス油が飛
翔昆虫に対して優れた忌避効果を有することを見出し
た。BEST MODE FOR CARRYING OUT THE INVENTION The present inventors have conducted intensive studies on pest repellents which are high in safety, effective in repelling pests in a certain space, and which can surely be achieved, in order to solve the above problems. Natural essential oils such as orange oil, cassia oil, grapefruit oil, clove oil, cedarwood oil, citronella oil, cinnamon oil, cinnamon leaf oil, geranium oil, thyme white oil, peppermint oil, hiba oil, pimento oil, fennel oil, and penny royal Oil, peppermint oil, bergamot oil, lavender oil, roux oil, and lemongrass oil were found to have excellent repellent effects on flying insects.
【００１０】さらに好ましくは、天然精油であるカシア
油、シトロネラ油、シナモン油、ゼラニウム油、ハッカ
油、ラベンダー油、レモングラス油から選ばれた１種又
は２種以上を有効成分として含有する飛翔昆虫忌避剤が
卓越した忌避効果を有する。これらの天然精油は、本願
発明において確認されたように飛翔昆虫に対して低濃度
でも忌避効果を有すると共に人畜に対する安全性が極め
て高く、しかも、マイルドな芳香を示すので屋外におい
てはもちろんのこと、屋内においても全く問題なく使用
できる。[0010] More preferably, a flying insect containing one or more selected from natural essential oils of cassia oil, citronella oil, cinnamon oil, geranium oil, peppermint oil, lavender oil and lemongrass oil as an active ingredient. The repellent has an excellent repellent effect. These natural essential oils, as confirmed in the present invention, have a repellent effect even at a low concentration on flying insects, are extremely high in safety for humans and animals, and have a mild aroma, so they are naturally used outdoors. It can be used indoors without any problem.
【００１１】さらに、本願発明者らの研究によれば、上
記天然精油と共にピレスロイド系殺虫剤を併用すること
により、飛翔昆虫に対する忌避効果をさらに増強できる
ことを見出した。上記天然精油と混合して用いることの
できるピレスロイド系殺虫剤としては以下のものが例示
できるが、これらに限定されるものではない。Further, according to the study of the present inventors, it has been found that the repellent effect against flying insects can be further enhanced by using a pyrethroid insecticide in combination with the above-mentioned natural essential oil. Examples of the pyrethroid-based insecticides that can be used by mixing with the above-mentioned natural essential oils include, but are not limited to, the following.
【００１２】一般名；構造名（商品名、メーカー） ●アレスリン； ３−アリル−２−メチルシクロペンタ
−２−エン−４−オン−１−イル ｄｌ−シス／トラン
ス−クリサンテマート（ピナミン、住友化学工業
（株）） ●ｄｌ・ｄ−Ｔ８０−アレスリン； ３−アリル−２−
メチルシクロペンタ−２−エン−４−オン−１−イル
ｄ−シス／トランス−クリサンテマート（ピナミンフォ
ルテ、住友化学工業（株）） ●ｄｌ・ｄ−Ｔ−アレスリン； ３−アリル−２−メチ
ルシクロペンタ−２−エン−４−オン−１−イル ｄ−
トランス−クリサンテマート（バイオアレスリン） ●ｄ・ｄ−Ｔ−アレスリン； ｄ−３−アリル−２−メ
チルシクロペンタ−２−エン−４−オン−１−イル ｄ
−トランス−クリサンテマート（エスビオール）General name; Structural name (trade name, manufacturer) ● Arlesrin; 3-allyl-2-methylcyclopenta-2-en-4-one-1-yl dl-cis / trans-chrysanthemate (pinamine, Sumitomo Chemical Co., Ltd.) dl-d-T80-aresulin; 3-allyl-2-
Methylcyclopenta-2-en-4-one-1-yl
d-cis / trans-chrysanthemate (Pinamine Forte, Sumitomo Chemical Co., Ltd.) dl · dT-aresulin; 3-allyl-2-methylcyclopenta-2-en-4-one-1-one Il d-
Trans-chrysanthemate (bioaresulin) ● d · dT-aresulin; d-3-allyl-2-methylcyclopenta-2-en-4-one-1-yl d
-Trans-Chrysanthemato (ESBIOL)
【００１３】●ｄ・ｄ−Ｔ８０−プラレトリン； ｄ−
２−メチル−４−オキソ−３−プロパルギルシクロペン
ト−２−エニル ｄ−シス／トランス−クリサンテマー
ト（エトック、住友化学工業（株）） ●フラメトリン； ５−（２−プロパギル）−３−フリ
ルメチル クリサンテマート（ピナミンＤ、住友化学工
業（株）） ●エンペントリン； １−エチニル−２−メチルペント
−２−エニル ｄ−シス／トランス−クリサンテマート
（ペーパースリン、住友化学工業（株）） ●テラレスリン； ２−アリル−３−メチル−２−シク
ロペンテン−１−オン−４−イル−２，２，３，３，テ
トラメチル−シクロプロパンカルボキシラート（ノック
スリン、住友化学工業（株）） ●トランスフルスリン； ２，３，５，６−テトラフル
オロベンジル−２，２−ジメチル−３−（２，２−ジク
ロロビニル）シクロプロパンカルボキシラート（バイエ
ル）• d · d-T80-praletrin; d-
2-Methyl-4-oxo-3-propargylcyclopent-2-enyl d-cis / trans-chrysanthemate (Etoc, Sumitomo Chemical Co., Ltd.) Flamethrin; 5- (2-propargyl) -3-furyl Methyl chrysanthemate (Pinamine D, Sumitomo Chemical Co., Ltd.) ● Empentrin; 1-ethynyl-2-methylpent-2-enyl d-cis / trans-chrysanthemate (Papersuline, Sumitomo Chemical Co., Ltd.) ● Teralesulin; 2-allyl-3-methyl-2-cyclopenten-1-one-4-yl-2,2,3,3, tetramethyl-cyclopropanecarboxylate (Noxulin, Sumitomo Chemical Co., Ltd.) Fluthulin; 2,3,5,6-tetrafluorobenzyl-2,2-dimethyl-3- (2,2-dichlorovinyl) Black propane carboxylate (Bayer)
【００１４】本願発明の飛翔昆虫忌避剤は、上記有効成
分をそのまま飛翔昆虫の忌避を要求される区域等に適用
することもできるが、通常好ましくは適当な担体その他
の配合剤を用いて適用区域、適用方法等に適した各種の
形態に調製して利用される。本願発明の忌避剤の形態と
しては、（１）有効成分を担体に保持又は溶剤に溶解さ
せて吸液芯を有する容器に充填し、加熱蒸散及び送風蒸
散のうち少なくとも１つ以上の方法により閉鎖空間に蒸
散させる剤、（２）有効成分を担体に保持させ、閉鎖空
間に常温蒸散させることにより害虫の飛来及び吸血行動
を抑制させる剤、（３）ピレスロイド系殺虫剤とともに
本願発明にかかわる有効成分を配合することにより、ピ
レスロイド系殺虫剤の配合量を大きく削減でき、そのた
め安全性が高く、かつ効力を維持できる剤等が例示でき
る。The flying insect repellent of the present invention can be applied to an area where the above active ingredient is required to repel flying insects as it is, but it is usually preferable to apply the active ingredient using an appropriate carrier or other compounding agent. It is prepared and used in various forms suitable for application methods and the like. As the form of the repellent of the present invention, (1) the active ingredient is retained in a carrier or dissolved in a solvent and filled in a container having a liquid absorbing core, and closed by at least one of heat evaporation and air evaporation. An agent that evaporates into a space; (2) an agent that holds an active ingredient in a carrier and evaporates at room temperature into a closed space to suppress flying of insects and blood sucking behavior; and (3) an active ingredient according to the present invention together with a pyrethroid-based insecticide. By compounding the compound, a compounding amount of the pyrethroid-based insecticide can be greatly reduced, and therefore, an agent having high safety and maintaining efficacy can be exemplified.
【００１５】前記（１）の剤では、処理薬量として効力
の面では単位容積あたり０．１ｍｇ／ｈｒ／ｍ３以上が
望ましく、経済性及び安全性の面では１０ｍｇ／ｈｒ／
ｍ３以下が望ましい。前記（２）の剤では、担体の薬剤
保持能力により任意の濃度で担持させることが可能であ
るが、蒸散性の面では０．１ｗｔ％以上が望ましく、担
体の形状維持又は誤食等における安全性の面では１０ｗ
ｔ％以下が望ましい。また、処理薬量としては、効力の
面では単位容積あたり３０ｍｇ／ｍ３以上が望ましく、
経済性及び安全性の面では１０００ｍｇ／ｍ３以下が望
ましい。前記（３）の剤では、ピレスロイド系殺虫剤の
蒸散量として、効力の面では単位容積あたり０．０００
３ｍｇ／ｍ３以上が望ましく、経済性及び安全性の面で
は０．０３ｍｇ／ｍ３以下が望ましい。In the agent of the above (1), the treatment dose is preferably 0.1 mg / hr / m 3 or more per unit volume in terms of efficacy, and 10 mg / hr / m 3 in terms of economy and safety.
m 3 or less is desirable. The agent of the above (2) can be loaded at any concentration depending on the drug holding capacity of the carrier, but it is desirably 0.1 wt% or more in terms of transpiration, and is safe in maintaining the shape of the carrier or accidental eating. 10w in terms of sex
t% or less is desirable. Further, the amount of the treatment agent is desirably 30 mg / m 3 or more per unit volume in terms of efficacy,
From the viewpoint of economy and safety, it is desirable that the concentration is 1000 mg / m 3 or less. In the agent of the above (3), the amount of pyrethroid insecticide transpiration is 0.000 per unit volume in terms of efficacy.
3 mg / m 3 or more is desirable, and from the viewpoint of economy and safety, 0.03 mg / m 3 or less is desirable.
【００１６】本願発明に用いることができる薬剤保持体
は、不織布、シート、フィルム等に加工してなる形状
や、粉剤、錠剤マット等に加工してなる形状等が挙げら
れる。さらに、材料としては、例えば天然繊維としてパ
ルプ、綿、羊毛、麻、絹、合成繊維としてポリプロピレ
ン、ポリエチレン、ポリアミド、ポリエチレンテレフタ
レート、ポリブチレンテレフタレート、ポリサルフォ
ン、レーヨン、メタアクリル酸樹脂、ガラス繊維や、ゼ
オライト、タルク、ホワイトカーボン、珪藻土、石灰、
シリカゲル、活性炭等の多孔質が例示できる。The drug carrier usable in the present invention includes a shape processed into a nonwoven fabric, a sheet, a film, and the like, and a shape processed into a powder, a tablet mat, and the like. Further, as a material, for example, pulp, cotton, wool, hemp, silk as a natural fiber, polypropylene, polyethylene, polyamide, polyethylene terephthalate, polybutylene terephthalate, polysulfone, rayon, methacrylic resin, glass fiber, or zeolite as a synthetic fiber , Talc, white carbon, diatomaceous earth, lime,
Examples thereof include porous materials such as silica gel and activated carbon.
【００１７】また、液剤に調製するための溶剤として
は、水性、油性どちらでもよく、水、メチルアルコー
ル、エチルアルコール等のアルコール類、フタル酸ジエ
チル、ミリスチン酸イソプロピル、ステアリン酸ブチル
等のエステル類、ヘキサン、ケロシン、パラフィン等の
脂肪族炭化水素類、ベンゼン、キシレン等の芳香族炭化
水素類、さらに、エチレングリコール、エチレングリコ
ールジエチルエーテル等のエーテル類を例示できる。The solvent for preparing the liquid preparation may be aqueous or oily, and may be water, alcohols such as methyl alcohol and ethyl alcohol, esters such as diethyl phthalate, isopropyl myristate and butyl stearate; Examples thereof include aliphatic hydrocarbons such as hexane, kerosene, and paraffin; aromatic hydrocarbons such as benzene and xylene; and ethers such as ethylene glycol and ethylene glycol diethyl ether.
【００１８】また、本願発明の対象害虫には、アカイエ
カ、チカイエカ、ヒトスジシマカ、シナハマダラカなど
の蚊類、イエバエ、ヒメイエバエ、センチニクバエ、ケ
ブカクロバエ、キイロショウジョウバエ、ノミバエ等の
ハエ類、オオチョウバエ、ホシチョウバエ等のチョウバ
エ類、セスジユスリカ、アカムシユスリカ等のユスリカ
類、イガ、コイガ、ノシメマダラメイガ等の蛾類などの
飛翔昆虫が挙げられる。また、使用場面としても一般家
庭、倉庫、畜鶏舎、工場、飲食店、キャンプ、バーベキ
ュー等多様な場面に使用が可能である。The insect pests of the present invention include mosquitoes such as Culex pipiens, Culex pipiens, Aedes albopictus, and Anopheles mosquitoes; flies such as house flies, Himee flies; Flying insects such as midges such as Drosophila, Sesame midge and Akamushi midges, and moths such as Iga, Koiga and Noshime-Damameiga. In addition, it can be used in various scenes such as a general household, a warehouse, a poultry house, a factory, a restaurant, a camping, a barbecue, and the like.
【００１９】[0019]
【試験例】以下に、試験例により本願発明を具体的に説
明する。但し、本願発明はこの試験例のみに限定される
ものではない。 試験例１ （１）供試剤 オレンジ油、カシア油、グレープフルーツ油、クローブ
油、シダーウッド油、シトロネラ油、シナモン油、シナ
モンリーフ油、ゼラニウム油、タイムホワイト油、ハッ
カ油、ヒバ油、ピメント油、フェンネル油、ペニーロー
ヤル油、ペパーミント油、ベルガモット油、ラベンダー
油、ルー油、レモングラス油及び対照薬剤としてジエチ
ルトルアミド（ＤＥＥＴ）を用いた。アセトンにて０．
６３６％（Ｗ／Ｖ）に希釈した上記薬剤を直径９ｃｍの
東洋ろ紙Ｎｏ．５Ａに１ｍｌ（有効成分として１ｇ／ｍ
２）塗布し、アセトンを風乾したものを供試剤とした。Test Examples Hereinafter, the present invention will be specifically described with reference to test examples. However, the present invention is not limited to only this test example. Test Example 1 (1) Test agent Orange oil, cassia oil, grapefruit oil, clove oil, cedarwood oil, citronella oil, cinnamon oil, cinnamon leaf oil, geranium oil, thyme white oil, peppermint oil, hiba oil, pimento oil, Fennel oil, penny royal oil, peppermint oil, bergamot oil, lavender oil, roux oil, lemongrass oil and diethyltoluamide (DEET) as control drug were used. 0. with acetone.
The above drug diluted to 636% (W / V) was diluted with Toyo Filter Paper No. 9 cm in diameter. 1 ml in 5A (1 g / m as active ingredient)
2 ) The sample was coated and air-dried with acetone to give a test agent.
【００２０】（２）供試虫 アカイエカ（Ｃｕｌｅｘ ｐｉｐｉｅｎｓ ｐａｌｌｅ
ｎｓ）、オオチョウバエ（Ｔｅｌｍａｔｏｓｃｏｐｕｓ
ａｌｂｉｐｕｎｃｔａｔｕｓ）、キイロショウジョウ
バエ（Ｄｒｏｓｏｐｈｉｌａ ｍｅｌａｎｏｇａｓｔｅ
ｒ）いずれも室温２８℃、長日条件下（１４Ｌ１０Ｄ）
で飼育中の個体群を用いた。(2) Test insects Culex pipiens palle
ns), Drosophila (Telmatoscopus)
albipunktus, Drosophila melanogaster (Drosophila melanogaste)
r) All at room temperature of 28 ° C under long day conditions (14L10D)
The population being raised in was used.
【００２１】（３）試験方法（追い出し効果） 扉を有する鋼鉄製シリンダー（高さ１０ｃｍ、直径２０
ｃｍ）の上にガラスシリンダー（高さ３３ｃｍ、直径２
０ｃｍ）を置き、直径５ｃｍの穴を有するガラスプレー
トをかぶせ、ゴム栓をした試験装置で実施した。試験装
置内に供試虫を約２０匹入れた後、各供試剤を試験装置
下方の扉から挿入すると同時に上方のゴム栓を取り除
き、上方に１６メッシュナイロンネットを張ったガラス
シリンダー（高さ２０ｃｍ、直径２０ｃｍ）をかぶせ
た。各供試剤の設置から３時間後にガラスプレートの穴
から上方のシリンダー内に追い出された個体数をカウン
トした。アセトンのみを塗布したろ紙を設置した区を無
処理区とし、次式により補正追い出し率を求めた。(3) Test Method (Ejection Effect) A steel cylinder having a door (height 10 cm, diameter 20)
cm) on a glass cylinder (height 33 cm, diameter 2)
0 cm) was placed, covered with a glass plate having a hole with a diameter of 5 cm, and the test apparatus was equipped with a rubber stopper. After about 20 test insects were placed in the test apparatus, each test agent was inserted from the lower door of the test apparatus, and at the same time, the upper rubber stopper was removed. A glass cylinder (height: 16 mesh nylon net) was stretched upward. 20 cm, diameter 20 cm). Three hours after the placement of each test agent, the number of individuals expelled from the holes in the glass plate into the cylinder above was counted. The section where the filter paper coated with only acetone was installed was regarded as a non-treatment section, and the corrected ejection ratio was determined by the following equation.
【００２２】[0022]
【数１】 (Equation 1)
【００２３】各供試剤の各供試虫に対する追い出し効果
を表１に示す。Table 1 shows the expulsion effect of each test agent on each test insect.
【００２４】[0024]
【表１】 [Table 1]
【００２５】以上の結果より、本願発明に関わる天然精
油をろ紙に１ｇ／ｍ２塗布したものは、蚊類、チョウバ
エ類、ショウジョウバエ類に対していずれも既存の忌避
剤であるジエチルトルアミド（ＤＥＥＴ）より高い追い
出し効果を示した。Based on the above results, the filter paper coated with the natural essential oil according to the present invention at 1 g / m 2 was applied to diethyltoluamide (DEET) which is an existing repellent against mosquitoes, Drosophila and Drosophila. ) Showed a higher kick-out effect.
【００２６】試験例２ （１）供試剤 表２に示す精油を表２に示す担体に練り込み、１個２０
ｇの錠剤に打錠したものを用いた。Test Example 2 (1) Test Agent The essential oil shown in Table 2 was kneaded into the carrier shown in Table 2, and one of them was used.
g tablets were used.
【００２７】[0027]
【表２】 [Table 2]
【００２８】（２）供試虫 ヒトスジシマカ（Ａｅｄｅｓ ａｌｂｏｐｉｃｔｕｓ） 室温２８℃、長日条件下（１４Ｌ１０Ｄ）で飼育中の個
体群を用いた。(2) Test Insects Aedes albopictus A population of animals raised at room temperature of 28 ° C. under long-day conditions (14L10D) was used.
【００２９】（３）試験方法（侵入・吸血阻止効果） ８畳の居室（３３ｍ３）を２部屋用い、各部屋に大きさ
１ｍ×１ｍ×１ｍ、側面に２０ｃｍ×２０ｃｍの窓を開
けた段ボール製の箱を設置し、その中に吸血源としてラ
ットを入れたケージを置いた。その後、一方の部屋にお
いて箱内で各供試剤５個（１００ｇ）を設置し、両方の
部屋に供試虫１００匹を放った。２時間後に各部屋にお
ける箱内侵入数及び吸血数をカウントした。処理区及び
無処理区の侵入率及び吸血率より、次式により侵入阻止
率及び吸血阻止率を求めた。(3) Test method (invasion / blood-sucking inhibitory effect) Two 8-mat room (33 m 3 ) rooms were used, each having a size of 1 m x 1 m x 1 m and a 20 cm x 20 cm window on the side. Box was placed in which a cage containing rats as a blood-sucking source was placed. Thereafter, five test agents (100 g) were placed in the box in one room, and 100 test insects were released in both rooms. Two hours later, the number of penetrated boxes and the number of sucked blood in each room were counted. From the intrusion rate and the blood absorption rate in the treated section and the non-treatment section, the intrusion inhibition rate and the blood absorption inhibition rate were determined by the following formulas.
【００３０】[0030]
【数２】 (Equation 2)
【００３１】[0031]
【数３】 (Equation 3)
【００３２】[0032]
【表３】 [Table 3]
【００３３】以上の結果より、本願発明に係わる天然精
油を練り込んだ錠剤を、有効成分換算で３０ｍｇ／ｍ３
以上の薬量で常温蒸散させることにより、ヒトスジシマ
カに対していずれも既存の忌避剤であるジエチルトルア
ミド（ＤＥＥＴ）より高い侵入阻止効果及び吸血阻止効
果を示した。From the above results, it was found that the tablets containing the natural essential oil according to the present invention were kneaded at 30 mg / m 3 in terms of active ingredient.
By evaporating at room temperature at the above dose, all of Aedes albopictus showed higher invasion inhibiting effect and blood absorption inhibiting effect than diethyltoluamide (DEET) which is an existing repellent.
【００３４】試験例３ （１）供試剤 表４に示された精油を灯油で溶解し、吸液芯を有するプ
ラスチック容器に充填したものを用いた。Test Example 3 (1) Test Agent The essential oil shown in Table 4 was dissolved in kerosene and filled in a plastic container having an absorbent core.
【００３５】[0035]
【表４】 [Table 4]
【００３６】（２）供試虫 ヒトスジシマカ（Ａｅｄｅｓ ａｌｂｏｐｉｃｔｕｓ） 室温２８℃、長日条件下（１４Ｌ１０Ｄ）で飼育中の個
体群を用いた。(2) Test Insects Aedes albopictus An individual population bred at room temperature of 28 ° C. under long-day conditions (14L10D) was used.
【００３７】（３）試験方法（侵入・吸血阻止効果） ２部屋並んだ８畳の居室（１部屋３３ｍ３で間に扉があ
る）において、一方の部屋に供試虫１００匹を放ち、他
方の部屋で吸血源としてラットを入れたケージを置い
た。その後、ケージを置いた部屋で各供試剤を加熱して
５ｍｇ／ｈｒ（０．１５ｍｇ／ｈｒ／ｍ３）蒸散させ、
間の扉を開放し、４時間後に処理した部屋に侵入した個
体数及び吸血数をカウントした。供試剤を処理しない場
合を無処理区とし、処理区及び無処理区の侵入率及び吸
血率より、次式により侵入阻止率及び吸血阻止率を求め
た。(3) Test method (invasion / blood-sucking inhibitory effect) In an 8 tatami room with two rooms arranged side by side (one room 33 m 3 with a door between them), 100 test insects are released in one room and the other is released. In each room, a cage containing a rat as a blood sucking source was placed. Then, each test agent was heated in the room where the cage was placed to evaporate 5 mg / hr (0.15 mg / hr / m 3 ),
The door between them was opened, and after 4 hours, the number of individuals and the number of blood sucked into the treated room were counted. The case where the test agent was not treated was regarded as a non-treated section, and the invasion inhibition rate and the blood absorption inhibition rate were calculated from the invasion rates and the blood absorption rates of the treated section and the untreated section by the following formulas.
【００３８】[0038]
【数４】 (Equation 4)
【００３９】[0039]
【数５】 (Equation 5)
【００４０】[0040]
【表５】 [Table 5]
【００４１】以上の結果より、本発明に関わる天然精油
を灯油に溶解し、吸液芯を有するプラスチック容器に充
填したものを、部屋で０．１５ｍｇ／ｈｒ／ｍ３の薬量
で加熱蒸散させることにより、ヒトスジシマカに対し
て、いずれも既存の忌避剤であるジエチルトルアミド
（ＤＥＥＴ）より高い侵入阻止効果及び吸血阻止効果を
示した。From the above results, the natural essential oil according to the present invention was dissolved in kerosene and filled in a plastic container having a liquid absorbing core, and heated and evaporated in a room at a dose of 0.15 mg / hr / m 3 . As a result, all showed higher invasion-inhibiting and blood-sucking inhibitory effects against Aedes albopictus than diethyltoluamide (DEET), which is an existing repellent.
【００４２】試験例４ （１）供試剤 表６に示す精油を灯油で溶解し、吸液芯を有するプラス
チック容器に充填したものを用いた。Test Example 4 (1) Test Agent The essential oil shown in Table 6 was dissolved in kerosene and filled in a plastic container having an absorbent core.
【００４３】[0043]
【表６】 [Table 6]
【００４４】（２）供試虫 ヒトスジシマカ（Ａｅｄｅｓ ａｌｂｏｐｉｃｔｕｓ） 室温２８℃、長日条件下（１４Ｌ１０Ｄ）で飼育中の個
体群を用いた。、(2) Test Insects Aedes albopictus An individual population bred under room temperature conditions of 28 ° C. and long day conditions (14L10D) was used. ,
【００４５】（３）試験方法 （侵入・吸血阻止効果）２部屋並んだ８畳の居室（１部
屋３３ｍ３で間に扉がある）において、一方の部屋に供
試虫１００匹を放ち、他方の部屋で吸血源としてラット
を入れたケージを置いた。その後、ケージを置いた部屋
で各供試剤を加熱して５ｍｇ／ｈｒ（０．１５ｍｇ／ｈ
ｒ／ｍ３）蒸散させ、間の扉を開放し、４時間後に処理
した部屋に侵入した個体数及び吸血数をカウントした。
供試剤を処理しない場合を無処理区とし、処理区及び無
処理区の侵入率および吸血率より、次式により侵入阻止
率及び吸血阻止率を求めた。(3) Test method (Effects of preventing invasion and blood sucking) In an 8-tatami room with two rooms arranged side by side (33 m 3 per room with a door between them), 100 test insects are released in one room and the other is released. In each room, a cage containing a rat as a blood sucking source was placed. Thereafter, each test agent was heated in the room where the cage was placed to 5 mg / hr (0.15 mg / h).
r / m 3 ) Evaporated, the door between them was opened, and after 4 hours, the number of individuals and the number of blood sucked into the treated room were counted.
The case where the test agent was not treated was regarded as a non-treated section, and the invasion inhibition rate and the blood absorption inhibition rate were calculated from the invasion rate and the blood absorption rate of the treated section and the untreated section by the following formulas.
【００４６】[0046]
【数６】 (Equation 6)
【００４７】[0047]
【数７】 (Equation 7)
【００４８】[0048]
【表７】 [Table 7]
【００４９】以上の結果より、本願発明に関わる天然精
油をピレスロイド系殺虫剤と共に灯油で溶解し、吸液芯
を有するプラスチック容器に充填したものを、部屋で
０．１５ｍｇ／ｈｒ／ｍ３の薬量で加熱蒸散させること
により、ヒトスジシマカに対していずれも天然精油単剤
及びピレスロイド系殺虫剤単剤より高い侵入阻止効果及
び吸血阻止効果を示した。From the above results, it was found that the natural essential oil according to the present invention was dissolved in kerosene together with a pyrethroid-based insecticide and filled in a plastic container having a liquid-absorbing wick, and 0.15 mg / hr / m 3 of drug was obtained in the room. By heat evaporation in this amount, all of Aedes albopictus showed higher invasion-inhibiting and blood-sucking inhibiting effects than the natural essential oil alone and the pyrethroid-based insecticide alone.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4H011 AC06 BA01 BA06 BB15 BB22 BC01 BC03 BC18 BC19 BC20 DA03 DA07 DA13 DB04 DE02 DE03 DH10 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4H011 AC06 BA01 BA06 BB15 BB22 BC01 BC03 BC18 BC19 BC20 DA03 DA07 DA13 DB04 DE02 DE03 DH10
Claims (4)
グレープフルーツ油、クローブ油、シダーウッド油、シ
トロネラ油、シナモン油、シナモンリーフ油、ゼラニウ
ム油、タイムホワイト油、ハッカ油、ヒバ油、ピメント
油、フェンネル油、ペニーローヤル油、ペパーミント
油、ベルガモット油、ラベンダー油、ルー油、レモング
ラス油から選ばれた１種又は２種以上を有効成分として
含有することを特徴とする飛翔昆虫忌避剤。Claims: 1. Natural essential oils, orange oil, cassia oil,
Grapefruit oil, clove oil, cedarwood oil, citronella oil, cinnamon oil, cinnamon leaf oil, geranium oil, thyme white oil, peppermint oil, hiba oil, pimento oil, fennel oil, penny royal oil, peppermint oil, bergamot oil, lavender oil A flying insect repellent, comprising as an active ingredient one or two or more selected from oil, roux oil and lemongrass oil.
間に有効成分量として３０ｍｇ／ｍ３〜１０００ｍｇ／
ｍ３設置し、常温蒸散させることにより害虫の飛来及び
吸血行動を抑制させる請求項１記載の飛翔昆虫忌避剤。2. The active ingredient is held on a carrier, and the amount of the active ingredient is 30 mg / m 3 to 1000 mg / in a closed space.
m 3 was placed, flying insect repellent according to claim 1, wherein for suppressing the flying and blood-sucking behavior pests by cold evaporation.
解させ、加熱蒸散及び送風蒸散のうち少なくとも１つ以
上の蒸散により閉鎖空間に０．１ｍｇ／ｈｒ／ｍ３〜１
０ｍｇ／ｈｒ／ｍ３蒸散させることにより害虫の飛来及
び吸血行動を抑制させる請求項１記載の飛翔昆虫忌避
剤。3. The active ingredient is held in a carrier or dissolved in a solvent, and is 0.1 mg / hr / m 3 to 1 mg / hr in a closed space by at least one of heat evaporation and air evaporation.
Flying insect repellent according to claim 1, wherein for suppressing the flying and blood-sucking behavior pests by causing 0mg / hr / m 3 transpiration.
上を有効成分として含有する請求項１〜３のいずれか１
項記載の飛翔昆虫忌避剤。4. The method according to claim 1, wherein one or more pyrethroid insecticides are contained as an active ingredient.
The flying insect repellent according to the above item.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000369829A JP2002173407A (en) | 2000-12-05 | 2000-12-05 | Flying insect repellent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000369829A JP2002173407A (en) | 2000-12-05 | 2000-12-05 | Flying insect repellent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2002173407A true JP2002173407A (en) | 2002-06-21 |
Family
ID=18839809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000369829A Pending JP2002173407A (en) | 2000-12-05 | 2000-12-05 | Flying insect repellent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2002173407A (en) |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000053515A (en) * | 1998-08-10 | 2000-02-22 | Ikari Shodoku Kk | Repellent against musca domestica |
-
2000
- 2000-12-05 JP JP2000369829A patent/JP2002173407A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000053515A (en) * | 1998-08-10 | 2000-02-22 | Ikari Shodoku Kk | Repellent against musca domestica |
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