JP2013151470A - Flying insect pest attracting agent - Google Patents
Flying insect pest attracting agent Download PDFInfo
- Publication number
- JP2013151470A JP2013151470A JP2012267066A JP2012267066A JP2013151470A JP 2013151470 A JP2013151470 A JP 2013151470A JP 2012267066 A JP2012267066 A JP 2012267066A JP 2012267066 A JP2012267066 A JP 2012267066A JP 2013151470 A JP2013151470 A JP 2013151470A
- Authority
- JP
- Japan
- Prior art keywords
- vinegar
- acid
- propylene glycol
- acetate
- acetal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 82
- 241000238631 Hexapoda Species 0.000 title abstract description 20
- 235000021419 vinegar Nutrition 0.000 claims abstract description 125
- 239000000052 vinegar Substances 0.000 claims abstract description 121
- 239000005667 attractant Substances 0.000 claims abstract description 76
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims abstract description 38
- -1 propionaldehyde propylene glycol acetal Chemical class 0.000 claims abstract description 36
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims abstract description 27
- CZUGFKJYCPYHHV-UHFFFAOYSA-N 3-methylthiopropanol Chemical compound CSCCCO CZUGFKJYCPYHHV-UHFFFAOYSA-N 0.000 claims abstract description 24
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims abstract description 24
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims abstract description 23
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 claims abstract description 22
- AHXXIALEMINDAW-UHFFFAOYSA-N 4-(methoxymethyl)phenol Chemical compound COCC1=CC=C(O)C=C1 AHXXIALEMINDAW-UHFFFAOYSA-N 0.000 claims abstract description 22
- FINHMKGKINIASC-UHFFFAOYSA-N Tetramethylpyrazine Chemical compound CC1=NC(C)=C(C)N=C1C FINHMKGKINIASC-UHFFFAOYSA-N 0.000 claims abstract description 22
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims abstract description 22
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 22
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 claims abstract description 22
- VKCYHJWLYTUGCC-UHFFFAOYSA-N nonan-2-one Chemical compound CCCCCCCC(C)=O VKCYHJWLYTUGCC-UHFFFAOYSA-N 0.000 claims abstract description 22
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 claims abstract description 22
- CYIFVRUOHKNECG-UHFFFAOYSA-N tridecan-2-one Chemical compound CCCCCCCCCCCC(C)=O CYIFVRUOHKNECG-UHFFFAOYSA-N 0.000 claims abstract description 22
- IAEGWXHKWJGQAZ-UHFFFAOYSA-N trimethylpyrazine Chemical compound CC1=CN=C(C)C(C)=N1 IAEGWXHKWJGQAZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004480 active ingredient Substances 0.000 claims abstract description 16
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 claims abstract description 12
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims abstract description 11
- ZMAYRLMREZOVLE-UHFFFAOYSA-N 2-ethenyl-6-methoxyphenol Chemical compound COC1=CC=CC(C=C)=C1O ZMAYRLMREZOVLE-UHFFFAOYSA-N 0.000 claims abstract description 11
- PPPFYBPQAPISCT-UHFFFAOYSA-N 2-hydroxypropyl acetate Chemical compound CC(O)COC(C)=O PPPFYBPQAPISCT-UHFFFAOYSA-N 0.000 claims abstract description 11
- XHIUFYZDQBSEMF-UHFFFAOYSA-N 2-methylbutyl acetate Chemical compound CCC(C)COC(C)=O XHIUFYZDQBSEMF-UHFFFAOYSA-N 0.000 claims abstract description 11
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 claims abstract description 11
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 claims abstract description 11
- CLUWOWRTHNNBBU-UHFFFAOYSA-N 3-methylthiopropanal Chemical compound CSCCC=O CLUWOWRTHNNBBU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005711 Benzoic acid Substances 0.000 claims abstract description 11
- GRLJIIJNZJVMGP-UHFFFAOYSA-N S-Methyl butanethioate Chemical compound CCCC(=O)SC GRLJIIJNZJVMGP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000010233 benzoic acid Nutrition 0.000 claims abstract description 11
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims abstract description 11
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims abstract description 11
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims abstract description 11
- YOMSJEATGXXYPX-UHFFFAOYSA-N o-methoxy-p-vinylphenol Natural products COC1=CC(C=C)=CC=C1O YOMSJEATGXXYPX-UHFFFAOYSA-N 0.000 claims abstract description 11
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims abstract description 11
- UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 claims abstract description 11
- PDVLTWPJDBXATJ-UHFFFAOYSA-N cis- and trans-2-Isobutyl-4-methyl-1,3-dioxolane Chemical compound CC(C)CC1OCC(C)O1 PDVLTWPJDBXATJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000031902 chemoattractant activity Effects 0.000 claims description 67
- 239000003205 fragrance Substances 0.000 claims description 48
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 33
- 235000021420 balsamic vinegar Nutrition 0.000 claims description 22
- 235000013399 edible fruits Nutrition 0.000 claims description 20
- CHWNEIVBYREQRF-UHFFFAOYSA-N 4-Ethyl-2-methoxyphenol Chemical compound CCC1=CC=C(O)C(OC)=C1 CHWNEIVBYREQRF-UHFFFAOYSA-N 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- 235000014101 wine Nutrition 0.000 claims description 18
- 239000002418 insect attractant Substances 0.000 claims description 16
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 claims description 14
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 12
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 claims description 12
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 claims description 12
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 12
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 claims description 12
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 claims description 12
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 claims description 12
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 12
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims description 12
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 10
- 235000013339 cereals Nutrition 0.000 claims description 10
- 239000002304 perfume Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- BYGQBDHUGHBGMD-UHFFFAOYSA-N 2-methylbutanal Chemical compound CCC(C)C=O BYGQBDHUGHBGMD-UHFFFAOYSA-N 0.000 claims description 8
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 8
- QUMXDOLUJCHOAY-UHFFFAOYSA-N alpha-methylbenzyl acetate Natural products CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 claims description 7
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 claims description 6
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 claims description 6
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 claims description 6
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims description 6
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 claims description 6
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 claims description 6
- 229940116333 ethyl lactate Drugs 0.000 claims description 6
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 6
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 claims description 6
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 6
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 6
- 229940117955 isoamyl acetate Drugs 0.000 claims description 6
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- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid group Chemical group C(CCCCC)(=O)O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 5
- 239000001893 (2R)-2-methylbutanal Substances 0.000 claims description 4
- HVTGPXYNYDWJHK-UHFFFAOYSA-N 4-methyl-2-(phenylmethyl)-1,3-dioxolane Chemical compound O1C(C)COC1CC1=CC=CC=C1 HVTGPXYNYDWJHK-UHFFFAOYSA-N 0.000 claims description 4
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 claims description 3
- GWMSIWCZZKMUQM-UHFFFAOYSA-N 4-Methyl-2-pentyl-1,3-dioxolane Chemical compound CCCCCC1OCC(C)O1 GWMSIWCZZKMUQM-UHFFFAOYSA-N 0.000 claims description 3
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Landscapes
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、ハエ類、蚊類、コバエ類等の飛翔害虫、特に、ショウジョウバエ、ノミバエ、クロバネキノコバエ、キノコバエ、チョウバエ等のコバエを誘引する飛翔害虫誘引剤に関する。 The present invention relates to a flying pest attractant that attracts flying pests such as flies, mosquitoes, and fly flies, and particularly, fly flies such as Drosophila, flea flies, mushroom fly flies, mushroom flies, and fly flies.
コバエ等の飛翔害虫を捕獲する目的で、飛翔害虫誘引剤を利用した飛翔害虫トラップが市販されている。飛翔害虫誘引剤は、飛翔害虫トラップの使用環境に応じて、液剤、ゾル剤、ゲル剤等の様々な形態に製剤化されている。飛翔害虫を効率的に捕獲するためには、飛翔害虫に対して誘引効果の高い誘引物質(誘引剤)を用いることが重要となる。誘引物質を製剤化する場合、ゲル化物質等の賦形剤と混合し、剤形に適した組成となるように、誘引物質と賦形剤との割合を調整する必要がある。製剤の調製においては、一般に、賦形剤に対して誘引物質の使用量を少なくした方が製剤化し易い。従って、飛翔害虫誘引剤は、誘引物質の使用量が少量であっても、飛翔害虫に対して十分な誘引効果を備えるものが望まれる。 For the purpose of capturing flying pests such as fly flies, a flying pest trap using a flying pest attractant is commercially available. The flying insect attractant is formulated into various forms such as a liquid agent, a sol agent, a gel agent and the like according to the use environment of the flying insect trap. In order to efficiently capture the flying pest, it is important to use an attracting substance (attractant) having a high attracting effect on the flying pest. When formulating an attractant, it is necessary to adjust the ratio between the attractant and the excipient so that the composition is suitable for the dosage form by mixing with an excipient such as a gelling substance. In preparation of a preparation, it is generally easier to make a preparation by reducing the amount of attractant used relative to the excipient. Accordingly, it is desired that the flying pest attractant has a sufficient attracting effect on the flying pest even if the amount of attractant used is small.
従来、飛翔害虫トラップに使用する誘引剤として、例えば、果実、果実加工品、醸造酒、蒸留酒、香料、性誘引物質等を有効成分として用いたものが知られている(例えば、特許文献1及び2を参照)。 Conventionally, as attractants used for flying pest traps, for example, those using fruits, processed fruit products, brewed liquor, distilled liquor, fragrances, sex attractants and the like as active ingredients are known (for example, Patent Document 1). And 2).
特許文献1では、果実、果実加工品、醸造酒、蒸留酒、酒粕、乳酸菌飲料等を有効成分とする誘引剤が、ハエ取りトラップに格納されている。ハエは、ハエ取りトラップに設けられた誘引口から発せられる誘引剤の芳香成分に誘引される。誘引口からトラップ内部に侵入したハエは、誘引剤で体表面が濡らされることにより、そのまま脱出不能となったり、トラップ内部に据え付けられている粘着剤に捕獲されたりして、トラップ内で死滅するよう構成されている。 In Patent Document 1, an attractant containing active ingredients such as fruit, processed fruit products, brewed liquor, distilled liquor, sake lees, and lactic acid bacteria beverages is stored in a fly trap. The fly is attracted to the aromatic component of the attractant emitted from the attracting port provided in the fly trap. Flies that have entered the inside of the trap through the attracting port become unable to escape as they are wetted by the attracting agent, or are captured by the adhesive installed inside the trap and die inside the trap. It is configured as follows.
特許文献2では、ハエ類の性誘引物質が開示され、殺虫剤と組み合わせて使用されることが記載されている。 Patent Document 2 discloses a sex attractant for flies and describes that it is used in combination with an insecticide.
特許文献1に記載される果実、果実加工品、醸造酒、蒸留酒、酒粕、乳酸菌飲料等を有効成分とする誘引剤は、単独成分による使用では、飛翔害虫に対して十分な誘引効果を示さないことがある。また、これら有効成分の組み合わせによる使用でも、その組み合わせ方によっては、飛翔害虫に対する誘引活性が落ちる(又は忌避性が高まる)場合があり、組み合わせの効果について十分な検証がなされているとは言い難い。従って、特許文献1の誘引剤では、少量の使用で飛翔害虫を確実に誘引できるとは限らない。 The attractant containing active ingredients such as fruit, processed fruit product, brewed liquor, distilled liquor, sake lees, and lactic acid bacteria beverages described in Patent Document 1 exhibits a sufficient attracting effect against flying pests when used alone. There may not be. In addition, even when these active ingredients are used in combination, depending on how they are combined, the attracting activity against flying pests may decrease (or the repellency increases), and it is difficult to say that the effect of the combination has been sufficiently verified. . Therefore, the attractant of Patent Document 1 cannot always attract flying pests with a small amount of use.
特許文献2に記載される誘引剤は、ハエの性誘引物質を使用していることから、少量の使用でも一定の誘引効果が期待できる。しかしながら、性誘引物質は誘引剤として利用できる適用範囲が狭く、飛翔害虫の種類によっては十分な誘引効果を示さない場合もある。また、性誘引物質は高価であり、製造コスト上の問題もある。 Since the attractant described in Patent Document 2 uses a fly sex attractant, a certain attracting effect can be expected even in a small amount. However, the sex attractant has a narrow application range that can be used as an attractant, and depending on the type of flying insect, it may not show a sufficient attracting effect. In addition, the sex attractant is expensive and has a problem in manufacturing cost.
飛翔害虫用の誘引剤について、これまで様々な研究開発が行われてきたが、上記特許文献1及び2に記載される誘引剤を含め、効能及びコストの両面において十分に満足のいく誘引剤は未だ開発されていない。本発明は、上記問題点に鑑みてなされたものであり、ハエ類、蚊類、コバエ類等の飛翔害虫に対して少量でも優れた誘引効果を示す安価な誘引剤を提供することを目的とする。 Various research and development have been conducted so far on attractants for flying insects. However, attractants that are sufficiently satisfactory in terms of both efficacy and cost, including the attractants described in Patent Documents 1 and 2 above. Not yet developed. The present invention has been made in view of the above problems, and an object of the present invention is to provide an inexpensive attractant that exhibits an excellent attracting effect even with a small amount against flying insects such as flies, mosquitoes, and fly flies. To do.
上記問題を解決するための本発明に係る飛翔害虫誘引剤の特徴構成は、
食酢及び香料を含む誘引物質を有効成分とすることにある。
The characteristic configuration of the flying pest attractant according to the present invention for solving the above problem is as follows:
An attractive substance containing vinegar and fragrance is an active ingredient.
ハエ類、蚊類、コバエ類等の飛翔害虫を効果的且つ大量に誘引するためには、誘引剤として、少量でも高い誘引効果を示す誘引物質を含むものを用いることが重要である。
この点、本構成の飛翔害虫誘引剤は、食酢及び香料を含む誘引物質を有効成分としている。本発明者らによる鋭意研究の結果、食酢と香料とを混合することにより、飛翔害虫に対する誘引効果が、食酢又は香料の其々単独の誘引効果と比べて増強されることを見出した。従って、食酢及び香料を有効成分として含む誘引効果に優れた飛翔害虫誘引剤を使用することにより、ハエ類、蚊類、コバエ類等の飛翔害虫を効果的且つ大量に誘引することができる。また、食酢と香料とによる誘引効果の相乗効果が得られるため、製剤化した場合、誘引物質の使用量を少なくすることができ、製造コストを抑えることができる。
In order to attract flying pests such as flies, mosquitoes, and fly flies effectively and in large quantities, it is important to use an attractant containing an attracting substance that exhibits a high attracting effect even in a small amount.
In this regard, the flying insect attractant of this configuration has an attracting substance containing vinegar and a fragrance as an active ingredient. As a result of intensive studies by the present inventors, it has been found that, by mixing vinegar and fragrance, the attracting effect against flying pests is enhanced as compared with the individual attracting effect of vinegar or fragrance. Therefore, by using a flying pest attractant excellent in attracting effect containing vinegar and fragrance as active ingredients, flying pests such as flies, mosquitoes, and fly flies can be attracted effectively and in large quantities. Moreover, since the synergistic effect of the attracting effect by vinegar and a fragrance | flavor is acquired, when it formulates, the usage-amount of an attracting substance can be decreased and manufacturing cost can be held down.
本発明に係る飛翔害虫誘引剤において、前記香料が、ヘキサン酸、2−メチルブタナール、2−メチルブタナールプロピレングリコールアセタール、プロピオン酸エチル、酢酸プロピル、酪酸エチル、イソバレルアルデヒド2,3−ブタンジオールアセタール、ヘキサン酸エチル、フェニルアセトアルデヒド、ヘキサナールプロピレングリコールアセタール、安息香酸エチル、フェニルアセトアルデヒドプロピレングリコールアセタール、インドール、イソブタノール、酢酸フェニルエチル、酢酸イソアミル、アセトアルデヒド、フェニルエチルアルコール、イソ吉草酸、イソ酪酸、乳酸エチル、ジアセチル、酢酸、酢酸エチル、アセタール、フルフラール、アセトイン、ヘプタナール、2−ヘプタノン、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールからなる群から選択される少なくとも一種であることが好ましい。 In the flying pest attractant according to the present invention, the fragrance is hexanoic acid, 2-methylbutanal, 2-methylbutanal propylene glycol acetal, ethyl propionate, propyl acetate, ethyl butyrate, isovaleraldehyde 2,3-butane Diol acetal, ethyl hexanoate, phenylacetaldehyde, hexanal propylene glycol acetal, ethyl benzoate, phenylacetaldehyde propylene glycol acetal, indole, isobutanol, phenylethyl acetate, isoamyl acetate, acetaldehyde, phenylethyl alcohol, isovaleric acid, isobutyric acid, Ethyl lactate, diacetyl, acetic acid, ethyl acetate, acetal, furfural, acetoin, heptanal, 2-heptanone, propylene glycol monoacetate , Propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxymethylphenol, isoamyl alcohol, benzaldehyde, 2-methylbutyric acid, isobarrel Aldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde propylene glycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2,3,5-trimethylpyrazine, 2,3-pentanedione, dimethyldisulfide, tetramethylpyrazine, Preferably, it is at least one selected from the group consisting of 2-tridecanone, 2-nonanone, vinyl guaiacol, and 4-ethyl guaiacol. Arbitrariness.
本構成の飛翔害虫誘引剤は、香料として、上記香料の中から選択される少なくとも一種の香料が含まれている。これら香料は、飛翔害虫に対して相応の誘引効果を示すことから、結果として、ハエ類、蚊類、コバエ類等の飛翔害虫に対して相応の誘引効果を示す。また、上記香料と食酢とを組み合わせることにより、高い相乗効果が得られるため、製剤化した場合、誘引物質の使用量を少なくすることができる。 The flying insect attractant of this configuration contains at least one kind of fragrance selected from the above fragrances as a fragrance. Since these fragrances have a corresponding attracting effect on flying pests, as a result, they exhibit a corresponding attracting effect on flying pests such as flies, mosquitoes, and fly flies. Moreover, since a high synergistic effect is acquired by combining the said fragrance | flavor and vinegar, when it formulates, the usage-amount of an attractant can be decreased.
本発明に係る飛翔害虫誘引剤において、前記香料が、インドール、イソブタノール、酢酸フェニルエチル、酢酸イソアミル、アセトアルデヒド、フェニルエチルアルコール、イソ吉草酸、イソ酪酸、乳酸エチル、ジアセチル、酢酸、酢酸エチル、アセタール、フルフラール、アセトイン、ヘプタナール、2−ヘプタノン、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールからなる群から選択される少なくとも一種であることが好ましい。 In the flying pest attractant according to the present invention, the perfume is indole, isobutanol, phenylethyl acetate, isoamyl acetate, acetaldehyde, phenylethyl alcohol, isovaleric acid, isobutyric acid, ethyl lactate, diacetyl, acetic acid, ethyl acetate, acetal , Furfural, acetoin, heptanal, 2-heptanone, propylene glycol monoacetate, propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxy Methylphenol, isoamyl alcohol, benzaldehyde, 2-methylbutyric acid, isovaleraldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde Dopropylene glycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2,3,5-trimethylpyrazine, 2,3-pentanedione, dimethyldisulfide, tetramethylpyrazine, 2-tridecanone, 2-nonanone, vinyl guaiacol, And at least one selected from the group consisting of 4-ethylguaiacol.
本構成の飛翔害虫誘引剤では、香料として、上記香料の中から選択される少なくとも一種が含まれている。これら香料は、飛翔害虫に対して相応の誘引効果を示すことから、結果として、ハエ類、蚊類、コバエ類等の飛翔害虫に対して相応の誘引効果を示す。また、上記香料と食酢とを組み合わせることにより、より高い相乗効果が得られるため、製剤化した場合、誘引物質の使用量をより少なくすることができる。 In the flying pest attractant of this configuration, at least one selected from the above fragrances is included as a fragrance. Since these fragrances have a corresponding attracting effect on flying pests, as a result, they exhibit a corresponding attracting effect on flying pests such as flies, mosquitoes, and fly flies. Moreover, since the higher synergistic effect is acquired by combining the said fragrance | flavor and vinegar, when it formulates, the usage-amount of an attractant can be decreased more.
本発明に係る飛翔害虫誘引剤において、前記香料が、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールからなる群から選択される少なくとも一種であることが好ましい。 In the flying pest attractant according to the present invention, the perfume is propylene glycol monoacetate, propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxymethylphenol, isoamyl alcohol, benzaldehyde, 2-methylbutyric acid, isovaleraldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde propylene glycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2, 3, 5 -Trimethylpyrazine, 2,3-pentanedione, dimethyl disulfide, tetramethylpyrazine, 2-tridecanone, 2-nonanone, vinyl guaiacol And it is preferably at least one selected from the group consisting of 4-ethyl guaiacol.
本構成の飛翔害虫誘引剤では、香料として、上記香料の中から選択される少なくとも一種が含まれている。これら香料は、飛翔害虫に対して相応の誘引効果を示すことから、結果として、ハエ類、蚊類、コバエ類等の飛翔害虫に対して相応の誘引効果を示す。また、上記香料と食酢とを組み合わせることにより、さらに高い相乗効果が得られるため、製剤化した場合、誘引物質の使用量をさらに少なくすることができる。 In the flying pest attractant of this configuration, at least one selected from the above fragrances is included as a fragrance. Since these fragrances have a corresponding attracting effect on flying pests, as a result, they exhibit a corresponding attracting effect on flying pests such as flies, mosquitoes, and fly flies. Moreover, since a higher synergistic effect can be obtained by combining the fragrance and vinegar, the amount of attractant used can be further reduced when formulated.
本発明に係る飛翔害虫誘引剤において、前記食酢が、果実酢及び/又は穀物酢であることが好ましい。 In the flying insect pest attractant according to the present invention, the vinegar is preferably fruit vinegar and / or cereal vinegar.
本構成の飛翔害虫誘引剤では、食酢として、果実酢及び/又は穀物酢を有効成分としている。果実酢及び/又は穀物酢は、食酢の中でも飛翔害虫に対して高い誘引効果を示す。従って、本構成の飛翔害虫誘引剤は、飛翔害虫の誘引剤として、果実酢及び/又は穀物酢と、上記香料とを組み合わせると、両者の相乗効果により、高い誘引効果を示す。また、製剤化した場合、誘引物質の使用量をより少なくすることができる。 In the flying pest attractant of this configuration, fruit vinegar and / or cereal vinegar are used as active ingredients as vinegar. Fruit vinegar and / or cereal vinegar show a high attractive effect against flying pests among vinegars. Therefore, the flying insect pest attractant of this configuration shows a high attracting effect due to the synergistic effect of both the fruit vinegar and / or grain vinegar and the above fragrance as a flying pest attractant. In addition, when formulated, the amount of attractant used can be reduced.
本発明に係る飛翔害虫誘引剤において、前記果実酢が、バルサミコ酢及び/又はワインビネガーであり、前記穀物酢が、黒酢であることが好ましい。 In the flying pest attractant according to the present invention, the fruit vinegar is preferably balsamic vinegar and / or wine vinegar, and the grain vinegar is preferably black vinegar.
本構成の飛翔害虫誘引剤では、果実酢が、バルサミコ酢及び/又はワインビネガーであり、穀物酢が、黒酢であることから、飛翔害虫に対して特に誘引効果が高い。従って、本構成の飛翔害虫誘引剤は、飛翔害虫の誘引剤として、バルサミコ酢、ワインビネガー、及び/又は黒酢と、上記香料とを組み合わせると、両者の相乗効果がさらに高まり、非常に高い誘引効果を示す。また、製剤化した場合、誘引物質の使用量をさらに少なくすることができる。 In the flying pest attractant of this configuration, the fruit vinegar is balsamic vinegar and / or wine vinegar, and the grain vinegar is black vinegar, so the attracting effect is particularly high against the flying pest. Therefore, the flying pest attractant of this configuration is combined with balsamic vinegar, wine vinegar, and / or black vinegar and the above fragrance as a flying pest attractant, and the synergistic effect of both is further increased, resulting in a very high attraction. Show the effect. In addition, when formulated, the amount of attractant used can be further reduced.
以下、本発明の実施形態について説明する。ただし、本発明は、以下に説明する実施形態に記載される構成に限定されることを意図しない。 Hereinafter, embodiments of the present invention will be described. However, the present invention is not intended to be limited to the configurations described in the embodiments described below.
[飛翔害虫誘引剤に使用する食酢]
本発明の飛翔害虫誘引剤は、ハエ類、蚊類、コバエ類等の飛翔害虫、特に、ショウジョウバエ、ノミバエ、クロバネキノコバエ、キノコバエ、チョウバエ等のコバエを効果的に誘引し得る誘引剤であり、食酢及び香料を含む誘引物質を有効成分として含有する。食酢としては、例えば、米酢、黒酢、香酢等の穀物酢、スダチ酢、柿酢、リンゴ酢、ワインビネガー、バルサミコ酢等の果実酢、もろみ酢、合成酢等が挙げられ、中でも穀物酢、果実酢が好適に用いられ、さらに好ましくは、穀物酢の中で黒酢が、果実酢の中でワインビネガーやバルサミコ酢が用いられる。これらのうち、飛翔害虫誘引剤として、上記食酢のうち一種、又は複数種を含有させることができるが、果実酢に、黒酢及びワインビネガーの少なくとも一方を含ませることが好ましく、さらに好ましくは、バルサミコ酢に、黒酢及びワインビネガーの少なくとも一方を含ませたものである。これにより、飛翔害虫誘引剤から種々の芳香成分を発散させることができ、結果として、種々の飛翔害虫に対して高い誘引効果を示すことが可能となる。複数種の食酢を含有させる場合、食酢の混合割合に特に制限はなく、誘引対象となる飛翔害虫の種類に応じて、適宜選択され得る。
[Vinegar used as flying pest attractant]
The flying pest attractant of the present invention is an attractant capable of effectively attracting flying pests such as flies, mosquitoes, and fly flies, especially fly flies such as Drosophila, flea flies, mushroom fly, mushroom fly, and fly fly. An attractive substance containing vinegar and fragrance is contained as an active ingredient. Examples of edible vinegar include grain vinegar such as rice vinegar, black vinegar, and perfume vinegar, sudachi vinegar, persimmon vinegar, apple vinegar, wine vinegar, balsamic vinegar and other fruit vinegar, moromi vinegar, and synthetic vinegar. Vinegar and fruit vinegar are preferably used, more preferably black vinegar among grain vinegar and wine vinegar and balsamic vinegar among fruit vinegar. Among these, as a flying pest attractant, one or more of the above vinegar can be included, but it is preferable to include at least one of black vinegar and wine vinegar in the fruit vinegar, more preferably Balsamic vinegar contains at least one of black vinegar and wine vinegar. Thereby, various aromatic components can be diffused from the flying pest attractant, and as a result, a high attracting effect can be exhibited against various flying pests. When multiple types of vinegar are included, the mixing ratio of vinegar is not particularly limited, and can be appropriately selected according to the type of flying pests to be attracted.
ここで、本明細書中に記載される用語「バルサミコ酢」とは、一般には、イタリア北部のエミリア・ロマーニャ州モデナ地方において、ブドウを原料に伝統的製法で作られた酢を意味する。本場のバルサミコ酢は、省令や法律(例えば、1965年発令の省令であるアチャート・バルサミコ・ディ・モデナ)によって定義されている。アチャート・バルサミコ・ディ・モデナによれば、バルサミコ酢は、伝統的技術により製造され、濃縮ブドウ果汁に少なくとも10年熟成したワインビネガーを所定の割合で含有させることにより、濃縮ブドウ果汁のアルコール発酵及び酢酸発酵を促進し、独特の風味や芳香を醸し出すものとされる。バルサミコ酢の熟成には、例えば、樫、栗、桑、ネズ等の木材で作られた樽が使用される。完成したバルサミコ酢は、甘酸っぱさを有しており、芳香が深く、濃褐色を呈した液体である。バルサミコ酢は、酢酸含有量が6重量%以上、アルコール度が1.5重量%以下、糖分含有量が30g/L以上のものが市場に流通されている。 Here, the term “balsamic vinegar” described in the present specification generally means vinegar made by a traditional manufacturing method using grapes as a raw material in Emena Romagna Province, Northern Italy. Genuine balsamic vinegar is defined by ministerial ordinances and laws (for example, Achart Balsamico Modena, a ministerial ordinance issued in 1965). According to Achart Balsamic di Modena, balsamic vinegar is produced by traditional techniques, and the concentrated grape juice contains wine vinegar that has been aged for at least 10 years in a certain proportion, thereby allowing alcohol fermentation of the concentrated grape juice. It promotes acetic acid fermentation and produces a unique flavor and aroma. For maturation of balsamic vinegar, for example, a barrel made of wood such as persimmon, chestnut, mulberry, and rat is used. The finished balsamic vinegar has a sweet and sour taste, a deep aroma, and a dark brown liquid. Balsamic vinegar has an acetic acid content of 6% by weight or more, an alcohol content of 1.5% by weight or less, and a sugar content of 30 g / L or more in the market.
このように、バルサミコ酢は、本来、厳密に定義された食酢である。しかしながら、本発明における「バルサミコ酢」は、その構成成分、性質、状態等が上述した「本場のバルサミコ酢」と同等であればよい。従って、例えば、イタリア以外の国で製造された食酢であっても、性質が「本場のバルサミコ酢」と実質同等であれば、「バルサミコ酢」とみなし、そのような食酢も本発明の範囲に含まれる。 Thus, balsamic vinegar is originally a strictly defined vinegar. However, the “balsamic vinegar” in the present invention may be the same as the “genuine balsamic vinegar” described above in terms of its components, properties, state, and the like. Therefore, for example, even vinegar produced in a country other than Italy is regarded as “balsamic vinegar” if the properties are substantially equivalent to “genuine balsamic vinegar”, such vinegar is also within the scope of the present invention. included.
本明細書中に記載される用語「黒酢」とは、JAS法により規定される米酢や、麦酢の一種である。JAS法に規定される黒酢は、玄米黒酢と、大麦黒酢とに分類され、玄米黒酢の場合は、陶器の壷に蒸し米(精米していない米)、麹、水を入れ、糖化、アルコール発酵、酢酸発酵までを1つの壷で進行させ、さらに熟成させた酢のことであり、大麦黒酢は、大麦のみを使用してアルコール発酵、酢酸発酵までを1つの壷で進行させ、さらに熟成させた酢のことである。また、原料である米及び大麦の使用量は、酢1Lあたりにつき180g以上であることが必要である。このように、黒酢も厳密に定義された食酢であるが、その構成成分、性質、状態等が上述した「黒酢」と同等であれば、「黒酢」とみなし、そのような食酢も本発明の範囲に含まれる。 The term “black vinegar” described in the present specification is a kind of rice vinegar or barley vinegar defined by the JAS method. Black vinegar stipulated in the JAS Law is classified into brown rice black vinegar and barley black vinegar. In the case of brown rice black vinegar, put steamed rice (unpolished rice), rice bran, and water in a pottery bowl, Saccharification, alcohol fermentation, acetic acid fermentation is a vinegar that has been aged and further aged. Barley black vinegar uses only barley to allow alcoholic fermentation and acetic acid fermentation to proceed in a single koji. It is vinegar that has been further aged. Moreover, the usage-amount of the rice and barley which are raw materials needs to be 180 g or more per liter of vinegar. In this way, black vinegar is also a strictly defined vinegar, but if its constituents, properties, state, etc. are equivalent to the above-mentioned “black vinegar”, it is regarded as “black vinegar”, and such vinegar also It is included in the scope of the present invention.
本明細書中に記載される用語「ワインビネガー」とは、JAS法に規定されるブドウ酢の一種である。JAS法に規定されるブドウ酢は、原料であるブドウの搾汁の使用量が酢1Lあたりにつき300g以上のものをいう。ワインビネガーは、上記ブドウ酢の内、ブドウの搾汁をアルコール発酵させた後、酢酸発酵させて製造されたブドウ酢のことをいう。このように、ワインビネガーも厳密に定義された食酢であるが、その構成成分、性質、状態等が上述した「ワインビネガー」と同等であれば、「ワインビネガー」とみなし、そのような食酢も本発明の範囲に含まれる。 The term “wine vinegar” described in the present specification is a kind of grape vinegar as defined in the JAS Law. The grape vinegar prescribed in the JAS method means that the amount of grape juice used as a raw material is 300 g or more per liter of vinegar. Wine vinegar refers to grape vinegar produced by subjecting grape juice to alcoholic fermentation and then acetic acid fermentation. In this way, wine vinegar is also a strictly defined vinegar, but if its constituents, properties, state, etc. are equivalent to the above-mentioned “wine vinegar”, it is regarded as “wine vinegar” and such vinegar is also It is included in the scope of the present invention.
[飛翔害虫誘引剤に使用する香料]
本発明の飛翔害虫誘引剤に用いられる香料としては、例えば、ヘキサン酸、2−メチルブタナール、2−メチルブタナールプロピレングリコールアセタール、プロピオン酸エチル、酢酸プロピル、酪酸エチル、イソバレルアルデヒド2,3−ブタンジオールアセタール、ヘキサン酸エチル、フェニルアセトアルデヒド、ヘキサナールプロピレングリコールアセタール、安息香酸エチル、フェニルアセトアルデヒドプロピレングリコールアセタール、インドール、イソブタノール、酢酸フェニルエチル、酢酸イソアミル、アセトアルデヒド、フェニルエチルアルコール、イソ吉草酸、イソ酪酸、乳酸エチル、ジアセチル、酢酸、酢酸エチル、アセタール、フルフラール、アセトイン、ヘプタナール、2−ヘプタノン、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールが挙げられる。
[Perfume used for flying insect attractant]
Examples of the fragrance used in the flying insect attractant of the present invention include hexanoic acid, 2-methylbutanal, 2-methylbutanal propylene glycol acetal, ethyl propionate, propyl acetate, ethyl butyrate, isovaleraldehyde 2,3. -Butanediol acetal, ethyl hexanoate, phenylacetaldehyde, hexanal propylene glycol acetal, ethyl benzoate, phenylacetaldehyde propylene glycol acetal, indole, isobutanol, phenylethyl acetate, isoamyl acetate, acetaldehyde, phenylethyl alcohol, isovaleric acid, iso Butyric acid, ethyl lactate, diacetyl, acetic acid, ethyl acetate, acetal, furfural, acetoin, heptanal, 2-heptanone, propylene glycol mono Cetate, propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxymethylphenol, isoamyl alcohol, benzaldehyde, 2-methylbutyric acid, iso Valeraldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde propylene glycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2,3,5-trimethylpyrazine, 2,3-pentanedione, dimethyldisulfide, tetramethylpyrazine , 2-tridecanone, 2-nonanone, vinyl guaiacol, and 4-ethyl guaiacol.
上記香料のうち、より好ましい香料として、インドール、イソブタノール、酢酸フェニルエチル、酢酸イソアミル、アセトアルデヒド、フェニルエチルアルコール、イソ吉草酸、イソ酪酸、乳酸エチル、ジアセチル、酢酸、酢酸エチル、アセタール、フルフラール、アセトイン、ヘプタナール、2−ヘプタノン、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールが挙げられる。 Among the above fragrances, more preferable fragrances include indole, isobutanol, phenylethyl acetate, isoamyl acetate, acetaldehyde, phenylethyl alcohol, isovaleric acid, isobutyric acid, ethyl lactate, diacetyl, acetic acid, ethyl acetate, acetal, furfural, acetoin. , Heptanal, 2-heptanone, propylene glycol monoacetate, propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxymethylphenol, isoamyl Alcohol, benzaldehyde, 2-methylbutyric acid, isovaleraldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde pro Lenglycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2,3,5-trimethylpyrazine, 2,3-pentanedione, dimethyldisulfide, tetramethylpyrazine, 2-tridecanone, 2-nonanone, vinyl guaiacol, and 4-ethyl guaiacol is mentioned.
上記香料のうち、さらに好ましい香料として、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールが挙げられる。
本発明においては、上記列挙した全ての香料の中から、少なくとも一種を香料として飛翔害虫誘引剤に含有させることができる。
Among the above fragrances, more preferred fragrances include propylene glycol monoacetate, propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxymethyl. Phenol, isoamyl alcohol, benzaldehyde, 2-methylbutyric acid, isovaleraldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde propylene glycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2,3,5-trimethylpyrazine, 2,3-pentanedione, dimethyl disulfide, tetramethylpyrazine, 2-tridecanone, 2-nonanone, vinyl guaiacol, and - include ethyl guaiacol.
In the present invention, among all the fragrances listed above, at least one fragrance can be contained in the flying pest attractant.
上記列挙した香料は単独でも飛翔害虫に対する誘引剤として機能するが、食酢と上記香料とを混合することにより、飛翔害虫に対する誘引効果が食酢又は香料の其々単独の誘引効果と比べて増強される。特に、プロピレングリコールモノアセテート、プロピオンアルデヒドプロピレングリコールアセタール、酢酸2−メチルブチル、フェニル酢酸、酢酸イソブチル、2−メチルブタノール、コハク酸ジエチル、メチオノール、オクタン酸、4−メトキシメチルフェノール、イソアミルアルコール、ベンズアルデヒド、2−メチル酪酸、イソバレルアルデヒドプロピレングリコールアセタール、2−エチルヘキサン酸、アセトアルデヒドプロピレングリコールアセタール、チオ酪酸メチル、メチオナール、安息香酸、ヘキサナール、2,3,5−トリメチルピラジン、2,3−ペンタンジオン、ジメチルジスルフィド、テトラメチルピラジン、2−トリデカノン、2−ノナノン、ビニルグアヤコール、及び4−エチルグアヤコールからなる群から選択される少なくとも一種の香料と、バルサミコ酢、ワインビネガー、及び/又は黒酢とを混合すると、飛翔害虫に対して顕著な誘引効果の増強が得られる。バルサミコ酢、ワインビネガー、及び黒酢は、飛翔害虫に対して特に誘引効果が高いことが見出されているが、これら食酢は食酢の中でも比較的高価である。しかしながら、本発明に係る飛翔害虫誘引剤は、これら食酢と、香料とによる誘引効果の相乗効果が得られるため、高価なバルサミコ酢、ワインビネガー、黒酢等の使用量を低減することができる。従って、本発明に係る飛翔害虫誘引剤は、飛翔害虫誘引剤の製造コストを抑えることができる。 The fragrances listed above function alone as attractants for flying pests, but by mixing vinegar and the above fragrances, the attracting effects on flying pests are enhanced compared to the vinegar or perfume alone attracting effects. . In particular, propylene glycol monoacetate, propionaldehyde propylene glycol acetal, 2-methylbutyl acetate, phenylacetic acid, isobutyl acetate, 2-methylbutanol, diethyl succinate, methionol, octanoic acid, 4-methoxymethylphenol, isoamyl alcohol, benzaldehyde, 2 -Methylbutyric acid, isovaleraldehyde propylene glycol acetal, 2-ethylhexanoic acid, acetaldehyde propylene glycol acetal, methyl thiobutyrate, methional, benzoic acid, hexanal, 2,3,5-trimethylpyrazine, 2,3-pentanedione, dimethyl From the group consisting of disulfide, tetramethylpyrazine, 2-tridecanone, 2-nonanone, vinyl guaiacol, and 4-ethyl guaiacol At least the one perfume is-option, when mixed balsamic vinegar, wine vinegar, and / or a black vinegar, enhancement of remarkable attracting effect on flies pests is obtained. Balsamic vinegar, wine vinegar, and black vinegar have been found to have a particularly attractive effect on flying pests, but these vinegars are relatively expensive among vinegars. However, since the flying pest attractant according to the present invention has a synergistic effect of attracting the vinegar and perfume, the amount of expensive balsamic vinegar, wine vinegar, black vinegar and the like can be reduced. Therefore, the flying insect attractant according to the present invention can suppress the manufacturing cost of the flying insect attractant.
本発明の飛翔害虫誘引剤は、食酢と香料とを有効成分として含有しているが、これらを単に混合して用いてもよく、また製剤化して用いてもよい。これら食酢と香料との混合割合は、特に制限はなく、適宜選択され得るが、食酢の含有量を0.1〜90重量%の範囲、好ましくは2〜50重量%の範囲とした場合、香料の含有量を、0.001〜10重量%の範囲、好ましくは0.01〜5重量%の範囲とすることができる。このような割合に調整することにより、飛翔害虫の誘引効果において、食酢と香料とによる誘引効果の高い相乗効果を得ることができる。 The flying pest attractant of the present invention contains vinegar and a fragrance as active ingredients, but these may be used simply as a mixture, or may be used as a formulation. The mixing ratio of these vinegar and fragrance is not particularly limited and may be appropriately selected. When the content of vinegar is in the range of 0.1 to 90% by weight, preferably in the range of 2 to 50% by weight, the fragrance The content of can be 0.001 to 10% by weight, preferably 0.01 to 5% by weight. By adjusting to such a ratio, in the effect of attracting flying pests, a synergistic effect with a high attracting effect by vinegar and flavor can be obtained.
本発明の飛翔害虫誘引剤を製剤化する場合、当該剤形としては、例えば、液剤、ゾル剤、ゲル剤、ペースト剤、フロアブル剤、顆粒剤、粉末剤等を挙げることができる。剤形は、飛翔害虫誘引剤の成分及び組成、飛翔害虫の種類、飛翔害虫トラップの使用場所等に応じて、適宜選択され得る。 When formulating the flying pest attractant of the present invention, examples of the dosage form include solutions, sols, gels, pastes, flowables, granules, powders and the like. The dosage form can be appropriately selected according to the components and composition of the flying insect attractant, the type of flying insect, the place where the flying insect trap is used, and the like.
[飛翔害虫誘引剤に使用する食酢及び香料以外の有効成分]
本発明の飛翔害虫誘引剤は、飛翔害虫に対する誘引活性を高めるために、酒類、酒粕、糖類、果実、果実加工品、乳酸製品、魚介類、魚介類加工品、魚介類抽出物、食肉、食肉加工品、及び食肉抽出物からなる群から選択される少なくとも一つを含んでもよい。これにより、ハエ類、蚊類、コバエ類等の飛翔害虫に対してさらに高い誘引効果を示すことができる。
[Active ingredients other than vinegar and fragrance used for flying pest attractants]
The flying pest attractant of the present invention has an alcoholic beverage, sake lees, sugar, fruit, processed fruit product, lactic acid product, fishery product, processed fishery product, fishery product extract, meat, meat in order to enhance the attracting activity against the flying pest. You may include at least one selected from the group which consists of a processed product and a meat extract. Thereby, a higher attraction effect can be shown against flying pests such as flies, mosquitoes, and fly flies.
酒類としては、例えば、紹興酒、桂花陳酒、日本酒、マッコリ、果実酒、ブドウ酒、リンゴ酒、梅酒、ワイン、ビール、ブランデー、ウイスキー、ラム酒、ジン、焼酎、ウォッカ、リキュール、白酒、泡盛等が挙げられる。 Examples of liquors include Shaoxing liquor, Keika Chen liquor, Japanese liquor, Makgeolli, fruit liquor, grape liquor, apple liquor, plum liquor, wine, beer, brandy, whiskey, rum, gin, shochu, vodka, liqueur, white liquor, Awamori, etc. Can be mentioned.
糖類としては、例えば、砂糖、黒糖、ハチミツ類、液糖、ブドウ糖、ショ糖、麦芽糖、三温糖、オリゴ糖、多糖類、甜菜糖、メープルシロップ、トレハロース等が挙げられる。 Examples of the saccharide include sugar, brown sugar, honey, liquid sugar, glucose, sucrose, maltose, trisaccharide, oligosaccharide, polysaccharide, sugar beet, maple syrup, trehalose and the like.
果実としては、例えば、リンゴ、オレンジ、ミカン、レモン、ブドウ、メロン、スイカ、ナシ、バナナ、マンゴー、パイナップル、キウイ、パパイア、イチゴ、カキ、アボガド、セイヨウスモモ、ブルーベリー、ヤマモモ、オウトウ、モモ等が挙げられる。 Examples of fruits include apples, oranges, mandarin oranges, lemons, grapes, melons, watermelons, pears, bananas, mangoes, pineapples, kiwis, papayas, strawberries, oysters, avocados, sweet potatoes, blueberries, sweet potatoes, sweet potatoes, peaches, etc. Can be mentioned.
果実加工品としては、例えば、フルーツジュース、フルーツゼリー、フルーツ寒天、フルーツ缶詰、ドライフルーツ、フルーツペースト、フルーツピューレ等が挙げられる。 Examples of the processed fruit product include fruit juice, fruit jelly, fruit agar, canned fruit, dried fruit, fruit paste, and fruit puree.
乳酸製品としては、例えば、カルピス(登録商標)、ヤクルト(登録商標)等の乳酸菌飲料、ヨーグルト、チーズ、漬物等の乳酸食品が挙げられる。 Examples of lactic acid products include lactic acid bacteria beverages such as Calpis (registered trademark) and Yakult (registered trademark), and lactic acid foods such as yogurt, cheese, and pickles.
魚介類としては、例えば、サバ、カツオ、ムロアジ、イワシ、マグロ、ブリ、タイ、イカ、タコ、エビ、カニ、コイ、フナ、アユ、ナマズ、ブラックバス等が挙げられる。 Examples of the seafood include mackerel, skipjack, muroji, sardine, tuna, yellowtail, Thailand, squid, octopus, shrimp, crab, carp, crucian carp, sweetfish, catfish, black bass and the like.
魚介類加工品としては、例えば、カツオブシ、サバブシ、干物、練物、魚粉、魚卵加工品等が挙げられる。 Examples of processed fishery products include cutlet beetles, sababushi, dried fish, paste, fish meal, processed fish eggs, and the like.
魚介類抽出物としては、例えば、カツオブシフレーバー、サバブシフレーバー、ムロアジフレーバー、エビフレーバー、カニフレーバー、魚油などが挙げられる。 Examples of the seafood extract include cutlet of flavor, mackerel flavor, muro azi flavor, shrimp flavor, crab flavor, and fish oil.
食肉としては、例えば、牛肉、豚肉、鶏肉、羊肉、馬肉等が挙げられる。 Examples of the meat include beef, pork, chicken, lamb, and horse meat.
食肉加工品としては、例えば、ハム、ソーセージ、ベーコン、挽肉、人造肉、干物、燻製肉、肉骨粉等が挙げられる。 Examples of processed meat products include ham, sausage, bacon, ground meat, artificial meat, dried fish, smoked meat, and meat-and-bone meal.
食品抽出物としては、例えば、牛肉エキス、豚肉エキス、鶏肉エキス、羊肉エキス、馬肉エキス、ビーフフレーバー、ポークフレーバー、チキンフレーバー、動物性油脂等が挙げられる。 Examples of the food extract include beef extract, pork extract, chicken extract, lamb extract, horse meat extract, beef flavor, pork flavor, chicken flavor, and animal fats and oils.
[飛翔害虫誘引剤に使用する有効成分以外の添加剤]
本発明の飛翔害虫誘引剤には、上述した物質の他に、誘引剤としての効力を損なわない限り、例えば、殺菌剤、防黴剤、防腐剤、酸化防止剤、紫外線吸収剤、界面活性剤、着色剤、甘味料、苦味剤、pH調整剤、油脂、乳化剤、脂肪族多価アルコール又は糖アルコール等の保湿成分、増量剤、精製水等の成分を適宜含ませてもよい。上記保湿成分としては、脂肪族多価アルコール、ソルビトール等の糖アルコール、キサンタンガム等の増粘多糖類、沸点が200℃以上の水溶性溶剤、界面活性剤等が挙げられるが、とりわけ、脂肪族多価アルコール、糖アルコール、及び増粘多糖類が好ましい。脂肪族多価アルコールとしては、グリセリン、プロピレングリコール、トリエチレングリコール、1,3−ブチレングリコール、ヘキシレングリコール等が挙げられ、中でもグリセリンが好ましい。上記有効成分以外の添加剤の種類及び含量は、製剤の剤形により、適宜決定される。
[Additives other than active ingredients used for flying insect attractants]
In addition to the substances described above, the flying pest attractant of the present invention includes, for example, bactericides, antifungal agents, antiseptics, antioxidants, ultraviolet absorbers, surfactants, as long as the efficacy as an attractant is not impaired. , Coloring agents, sweeteners, bittering agents, pH adjusting agents, fats and oils, emulsifiers, moisturizing components such as aliphatic polyhydric alcohols or sugar alcohols, bulking agents, purified water and the like may be included as appropriate. Examples of the moisturizing component include aliphatic polyhydric alcohols, sugar alcohols such as sorbitol, thickening polysaccharides such as xanthan gum, water-soluble solvents having a boiling point of 200 ° C. or higher, surfactants, and the like. Preferred are monohydric alcohols, sugar alcohols, and thickening polysaccharides. Examples of the aliphatic polyhydric alcohol include glycerin, propylene glycol, triethylene glycol, 1,3-butylene glycol, hexylene glycol, and the like. Among them, glycerin is preferable. The kind and content of additives other than the above active ingredients are appropriately determined depending on the dosage form of the preparation.
飛翔害虫誘引剤に、殺虫剤をさらに組み合わせることも有効である。飛翔害虫誘引剤と、殺虫剤とを混合しても、飛翔害虫誘引剤の誘引効果は実質的に低下しない。組み合わせ可能な殺虫剤としては、例えば、アレスリン、プラレトリン、イミプロトリン、フタルスリン、トランスフルトリン、レスメトリン、フェノトリン、シフェノトリン、ペルメトリン、サイパーメスリン、エトフェンプロックス、シフルスリン、デルタメスリン、ビフェントリン、フェンバレレート、フェンプロパスリン、エムペンスリン、シラフルオフェン、メトフルトリン、プロフルトリン、天然ピレトリン、除虫菊エキス等のピレスロイド系化合物、カルバリル、プロポクスル、メソミル、チオジカルブ等のカーバメート系化合物、フェニトロチオン、ダイアジノン、マラソン、ピリダフェンチオン、プロチオホス、オキシム、クロルピリオス、ジクロルボス等の有機リン系化合物、メトキサジアゾン等のオキサジアゾール系化合物、エチプロール、ピリプロール、フィプロニル等のフェニルピラゾール系化合物、アミドフルメト等のスルホンアミド系化合物、メトプレン、ハイドロプレン、ピリプロキシフェン等の昆虫成長制御化合物、クロチアニジン、ニテンピラム、ジノテフラン、アセタミプリド、チアメトキサム、チアクロプリド、イミダクロプリド等のネオニコチノイド系化合物等が挙げられる。本発明においては、これらのうち、殺虫剤として、一種または複数種の化合物を含有させることが可能である。 It is also effective to further combine an insecticide with the flying insect attractant. Even if the flying insect attractant and the insecticide are mixed, the attracting effect of the flying insect attractant is not substantially lowered. Examples of insecticides that can be combined include allethrin, praretrin, imiprotorin, phthalthrin, transfluthrin, resmethrin, phenothrin, ciphenothrin, permethrin, cypermethrin, etofenprox, cyfluthrin, deltamethrin, bifenthrin, fenvalerate, fenpropathrin, Empensulin, silafluophene, metfurthrin, profluthrin, natural pyrethrin, pyrethroid compounds such as pesticide chrysanthemum extract, carbamate compounds such as carbaryl, propoxur, mesomil, thiodicarb, fenitrothion, diazinon, marathon, pyridafenthione, prothiophos, oxime, chlorpyrios, dichlorvos, etc. Phosphorus compounds, oxadiazoles such as methoxadiazone Compounds, phenylpyrazole compounds such as ethiprole, pyriprole, fipronil, sulfonamide compounds such as amidoflumet, insect growth control compounds such as metoprene, hydroprene, pyriproxyfen, clothianidin, nitenpyram, dinotefuran, acetamiprid, thiamethoxam, thiacloprid, And neonicotinoid compounds such as imidacloprid. In the present invention, among these, one or more kinds of compounds can be contained as insecticides.
これらの殺虫剤のうち、とりわけ、ネオニコチノイド系化合物を有効成分とするネオニコチノイド系殺虫剤を好適に使用することができる。ネオニコチノイド系殺虫剤としては、クロチアニジン、ニテンピラム、ジノテフラン、アセタミプリド、チアメトキサム、チアクロプリド、イミダクロプリド等が使用可能であり、特に、水溶性のものは使用に適している。ネオニコチノイド系殺虫剤は、飛翔害虫に対する忌避性が小さく、飛翔害虫を、食酢及び香料を含む誘引物質の高い誘引作用により殺虫剤の近傍にまで引き寄せることが可能である。そして、誘引された飛翔害虫が、少量でも殺虫剤に接触又は摂取すれば、確実に飛翔害虫を死滅させることが可能である。最も好適に使用可能な殺虫剤は、ジノテフランである。ジノテフランは、ネオニコチノイド系殺虫剤であり、水溶性でもある。飛翔害虫誘引剤とジノテフランとを組み合わせる場合、ジノテフランの含有量は、総重量に対して0.01〜1.0重量%とするのが好ましい。ジノテフランの含有量が0.01重量%未満であれば、十分な殺虫効果が得られない虞がある。一方、ジノテフランの含有量を1.0重量%より大きくしても殺虫効果は大きく向上しないため、通常、1.0重量%が上限となる。 Among these insecticides, in particular, neonicotinoid insecticides containing a neonicotinoid compound as an active ingredient can be suitably used. As the neonicotinoid insecticide, clothianidin, nitenpyram, dinotefuran, acetamiprid, thiamethoxam, thiacloprid, imidacloprid and the like can be used, and particularly those that are water-soluble are suitable for use. Neonicotinoid insecticides have low repellency against flying insects, and can attract flying insects to the vicinity of insecticides due to the attracting action of attractants including vinegar and fragrances. And if the attracted flying pest contacts or ingests the pesticide even in a small amount, it is possible to surely kill the flying pest. The most suitably used insecticide is dinotefuran. Dinotefuran is a neonicotinoid insecticide and is also water soluble. When combining a flying insect attractant and dinotefuran, the content of dinotefuran is preferably 0.01 to 1.0% by weight based on the total weight. If the content of dinotefuran is less than 0.01% by weight, a sufficient insecticidal effect may not be obtained. On the other hand, even if the content of dinotefuran is larger than 1.0% by weight, the insecticidal effect is not greatly improved, so 1.0% by weight is usually the upper limit.
次に、本発明の飛翔害虫誘引剤の効果を確認するため、本発明に基づく実施例について説明する。また、本発明との比較のために、比較例についても合わせて説明する。 Next, in order to confirm the effect of the flying pest attractant of the present invention, examples based on the present invention will be described. For comparison with the present invention, comparative examples will also be described.
<実施例1〜30、及び比較例1〜30>
直径100mm×高さ44mmのプラスチック容器に、表1〜6に示す誘引剤4gを含浸させた脱脂綿(4cm角)を入れ、蓋(開口部:7mm2×20個)をして供試サンプルとした。誘引剤には、以下の表1〜6に示す食酢、香料の成分以外に、溶剤(エタノール)、殺虫成分(ジノテフラン0.1重量%)、保湿成分、苦味剤、防腐剤、精製水が含まれている。実施例1〜30の其々に対応する比較例1〜30は、各実施例の誘引剤から香料を除いたものを供試サンプルとした。また、実施例1及び実施例7に対する参考例として、実施例1及び実施例7の誘引剤から其々食酢を除いた供試サンプルを作成し、参考例1及び参考例7とした。約25m3の試験室床面に供試サンプルを併設し、ショウジョウバエ200匹を放ち、2時間後に供試サンプル内のショウジョウバエを計数した。各実施例の捕獲虫数比は、対応する比較試験により捕獲したショウジョウバエの数を1とした場合の捕獲倍数で表した。各試験は3回行った。
<Examples 1-30 and Comparative Examples 1-30>
Absorbent cotton (4 cm square) impregnated with 4 g of the attractant shown in Tables 1 to 6 is put into a plastic container having a diameter of 100 mm and a height of 44 mm, and a lid (opening: 7 mm 2 × 20) is used as a test sample. did. In addition to the vinegar and fragrance components shown in Tables 1 to 6 below, the attractant includes a solvent (ethanol), an insecticidal component (dinotefuran 0.1% by weight), a moisturizing component, a bitter agent, an antiseptic, and purified water. It is. In Comparative Examples 1 to 30 corresponding to Examples 1 to 30, samples obtained by removing the fragrance from the attractant of each Example were used as test samples. In addition, as reference examples for Example 1 and Example 7, test samples in which vinegar was removed from the attractants of Example 1 and Example 7 were prepared as Reference Example 1 and Reference Example 7. A test sample was placed on the floor of a test room of about 25 m 3 , 200 Drosophila were released, and 2 hours later, Drosophila in the test sample was counted. The ratio of the number of insects captured in each example was expressed as the number of captures when the number of Drosophila captured by the corresponding comparative test was 1. Each test was performed three times.
表1〜6の結果から、誘引剤として食物酢に香料を添加したもの(実施例1〜30)は、何れも、対応する比較例(比較例1〜30)と比べて、ハエ類、蚊類、コバエ類等の飛翔害虫に対して高い誘引効果を示した。また、参考例1及び参考例7の結果から、香料のみの飛翔害虫に対する誘引効果は、比較例1及び比較例7と比較しても非常に低い値であり、香料のみでは、飛翔害虫に対して十分な誘引効果を示さないことが示された。従って、本発明に係る食物酢と香料とを組み合わせた誘引剤は、その相乗効果によりハエ類、蚊類、コバエ類等の飛翔害虫を大量に誘引できることが判明した。 From the results of Tables 1 to 6, all of the vinegars added with a fragrance as an attractant (Examples 1 to 30) were compared to the corresponding comparative examples (Comparative Examples 1 to 30), flies and mosquitoes. It showed a high attracting effect against flying pests such as mosquitoes and fly flies. In addition, from the results of Reference Example 1 and Reference Example 7, the attracting effect on the flying pest of only the fragrance is a very low value as compared with Comparative Example 1 and Comparative Example 7. It has been shown that it does not show a sufficient attracting effect. Therefore, it has been found that the attractant combining the food vinegar and the fragrance according to the present invention can attract a large amount of flying pests such as flies, mosquitoes, and fly flies due to their synergistic effects.
<実施例31>
本発明に係る飛翔害虫誘引剤を用いて粘着シートタイプの飛翔害虫誘引装置を構成し、誘引試験を行った。粘着シートタイプの飛翔害虫誘引装置の内部に、以下に示す誘引剤10gを含有する粘着シートを配置した。コバエ類が発生しているゴミ箱近傍に当該飛翔害虫誘引装置を設置し、1日経過後、装置内部に捕獲されたコバエ類の数を計数した。
その結果、85匹のショウジョウバエを捕獲した。実施例31で用いた飛翔害虫誘引剤の構成を以下に示す。
(1)食酢
白ワインビネガー :10重量%
黒酢 :25重量%
(2)香料
コハク酸ジエチル :0.1重量%
アセタール :0.1重量%
プロピレングリコールモノアセテート :0.2重量%
イソアミルアルコール :0.1重量%
プロピオンアルデヒドプロピレングリコールアセタール :0.2重量%
安息香酸エチル :0.01重量%
フェニルアセトアルデヒドプロピレングリコールアセタール :0.01重量%
(3)他成分
溶剤(エタノール)、紹興酒、三温糖、ゲル化剤、防腐剤、精製水
<Example 31>
An adhesive sheet type flying insect attracting apparatus was constructed using the flying insect attractant according to the present invention, and an attraction test was conducted. An adhesive sheet containing 10 g of the attractant shown below was disposed inside the adhesive sheet type flying pest attracting apparatus. The flying insect attracting device was installed near the trash box where the fly was generated, and after one day, the number of the fly was captured inside the device.
As a result, 85 Drosophila were captured. The structure of the flying pest attractant used in Example 31 is shown below.
(1) Vinegar white wine vinegar: 10% by weight
Black vinegar: 25% by weight
(2) Fragrance Diethyl succinate: 0.1% by weight
Acetal: 0.1% by weight
Propylene glycol monoacetate: 0.2% by weight
Isoamyl alcohol: 0.1% by weight
Propionaldehyde propylene glycol acetal: 0.2% by weight
Ethyl benzoate: 0.01% by weight
Phenylacetaldehyde propylene glycol acetal: 0.01% by weight
(3) Other components Solvent (ethanol), Shaoxing liquor, tri-sugar, gelling agent, preservative, purified water
<実施例32>
本発明に係る飛翔害虫誘引剤を用いて容器タイプの飛翔害虫誘引装置を構成し、誘引試験を行った。容器タイプの飛翔害虫誘引装置は、直径80mm×高さ35mmのプラスチック容器であり、1500mm2の開口部を備える蓋を設けた。容器内には、以下に示す誘引剤40gを含浸させた不織布(50mm角×高さ20mm)を配置した。当該飛翔害虫誘引装置をコバエ類が発生しているキッチンに設置し、装置に捕獲されたコバエ類の数をカウントした。
その結果、約1ヵ月にわたりショウジョウバエやノミバエ等のコバエ類に対して優れた誘引性を示し、装置に捕獲したコバエ類の総数は約250匹に達した。実施例32で用いた飛翔害虫誘引剤の構成を以下に示す。
(1)食酢
バルサミコ酢 :15重量%
(2)香料
アセトアルデヒドプロピレングリコールアセタール :0.3重量%
アセトアルデヒド :0.2重量%
メチオノール :0.5重量%
チオ酪酸メチル :0.01重量%
2‐メチルブタナール :0.02重量%
酢酸フェニルエチル :0.01重量%
4‐メトキシメチルフェノール :0.01重量%
オクタン酸 :0.05重量%
(3)他成分
溶剤(エタノール)、殺虫成分(ジノテフラン0.1重量%)、保湿成分、
苦味剤、防腐剤、精製水
<Example 32>
A container-type flying pest attracting apparatus was constructed using the flying pest attractant according to the present invention, and an attraction test was conducted. The container-type flying pest attracting apparatus is a plastic container having a diameter of 80 mm and a height of 35 mm, and provided with a lid having an opening of 1500 mm 2 . In the container, a non-woven fabric (50 mm square × height 20 mm) impregnated with an attractant 40 g shown below was placed. The flying insect attracting device was installed in a kitchen where the fly was generated, and the number of fly that was captured by the device was counted.
As a result, it showed excellent attractability to fruit flies such as Drosophila and fleas for about one month, and the total number of fruit flies captured in the device reached about 250. The structure of the flying pest attractant used in Example 32 is shown below.
(1) Vinegar balsamic vinegar: 15% by weight
(2) Fragrance Acetaldehyde propylene glycol acetal: 0.3% by weight
Acetaldehyde: 0.2% by weight
Methionol: 0.5% by weight
Methyl thiobutyrate: 0.01% by weight
2-Methylbutanal: 0.02% by weight
Phenylethyl acetate: 0.01% by weight
4-Methoxymethylphenol: 0.01% by weight
Octanoic acid: 0.05% by weight
(3) Other ingredients Solvent (ethanol), insecticidal ingredients (dinotefuran 0.1% by weight), moisturizing ingredients,
Bitterings, preservatives, purified water
上記実施例の結果より、本発明に係る飛翔害虫誘引剤は、食酢と香料とを混合することにより、ハエ類、蚊類、コバエ類等の飛翔害虫に対する誘引効果が増強され、飛翔害虫を効果的且つ大量に誘引できることが判明した。従って、本発明に係る飛翔害虫誘引剤は、食酢と香料とによる誘引効果の相乗効果が得られるため、少量でも優れた誘引効果を示す安価な誘引剤となることができる。 From the results of the above examples, the flying pest attractant according to the present invention has an enhanced effect of attracting flying pests such as flies, mosquitoes, and fly flies by mixing vinegar and perfume. It has been found that it can be attracted in large quantities. Therefore, the flying insect pest attractant according to the present invention can provide a synergistic effect of the attracting effect of vinegar and fragrance, and therefore can be an inexpensive attractant that exhibits an excellent attracting effect even in a small amount.
本発明によれば、飛翔害虫に対して高い誘引効果を有する飛翔害虫誘引剤を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the flying insect attractant which has a high attracting effect with respect to a flying insect can be provided.
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