CN102067878B - Ultra-low-volume liquid preparation containing carbosulfan - Google Patents
Ultra-low-volume liquid preparation containing carbosulfan Download PDFInfo
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Abstract
The invention relates to an ultra-low-volume liquid preparation containing carbosulfan, and application thereof to a paddy field. The pesticide preparation is an ultra-low-volume liquid preparation formed by compounding the carbosulfan with one of effective ingredients of chlorpyrifos, thiamethoxam, tsumacide, isoprocarb or fenobucarb; and the preparation is used for controlling piercing-sucking agricultural insects in paddy rice such as rice planthopper, aphid, leafhopper and whitefly. The pesticide provided by the invention is applicable to control of the insects by an ultra-low-volume spraying method. The ultra-low-volume liquid preparation has the advantages that the liquid preparation does not need to be diluted with water during the use process, the pesticide application efficiency is high, the control effect is obvious, and meanwhile a large amount of manpower and material resources can be saved compared with the traditional pesticide application method.
Description
Technical field
The present invention relates to a kind of ultra low volume liquids that contains carbosulfan and at paddy field, prevent and treat the application of rice hoppers.
Background technology
Rice fulgorid is one of the primary pest in harm south China and rice district, the middle and lower reach of Yangtze River, wherein brown planthopper and white-backed planthopper are the intermittent large insect occurring, becoming, the nymph rice strain base portion of trooping inhales juice, cause that rice plant Huang is withered, the deliquescing of stem stalk or the lodging of rotting, the harm of brown planthopper is the most serious, according to statistics, only 2005 and approximately 2.5 hundred million mu of left and right of hazard area in 2006, general paddy rice loss 5～10%, the outbreak year paddy rice underproduction 10～20%, the heavy field of part loses approximately 40～50%, even total crop failure.Small brown rice planthopper harm is mainly into, nymph is by sucking after the juice of (as the stripe disease) plant that suffers from virus disease, becomes band virion, and it not only constantly passes to healthy plant by virus, also passes to its offspring, by offspring, is continued to propagate.From 2004～2007 years continuous 4 years in Jiangsu, Shanghai, Anhui and part rice district, Zhejiang small brown rice planthopper wildness cause disaster, cause the large generation of stripe disease, according to relevant plant protection department statistics, the incidence of disease of stripe disease in recent years, rice seedling bed: 1～5%, heavy field 10～20%, the field 30～50% of especially severe, this class field is often ploughed and is replanted, and household economy loss is serious; Transplant field: due to the harm of small brown rice planthopper transmitted virus, the aobvious disease of dancing leaf blight morbidity forms weak stubble, dead seedling causes the loss of the underproduction suitable with brown planthopper.Visible, the harm of rice fulgorid is the grain-production of serious threat China and safety.
Carbosulfan (Buprofezin) belongs to thiadiazine ketone chitin synthesis inhibitor.Low toxicity is extremely light to skin and eye irritation effect.Strong to insect action of contace poison, also there is stomach poison function.Suppress insect chitin synthetic, disturb metabolism, cause nymph cast off a skin deformity or wing deformity and slowly dead.After general dispenser, within 3～7 days, just can find out effect, adult not had to direct killing power, but can shorten its life-span, reduce egg laying amount, and output be mostly addle-egg, even if larva hatching is also very fast dead.Leafhopper, plant hopper and aleyrodid and the scale insect activity of control Semiptera are high.The drug effect phase reaches more than 30 days.To pest natural enemy and insect pollinator safety.With other insecticides without mutual pesticide resistance problem.
But the agricultural chemicals of a kind of active ingredient of long-term single use will cause the generation of resistance very soon, thereby lose its using value.Itself and other pesticide active ingredient is combined into composite insecticide, is current a kind of conventional effectively and efficiently mode in the new insecticide pesticide of development.By the main purpose of the composite rear use of some single insecticidal constituents, except being its consumption of minimizing, improve insecticidal effect, outside the adverse effect that reduces toxic action and environment is produced, another important object is exactly pesticide resistance single component agricultural chemicals being produced in order to solve insect, make drug effect decline or be close to invalid agricultural chemicals and again recover insecticidal effect, even can also improve effect.Rule during agriculture chemical compounding is to guarantee that under certain desinsection control efficiency prerequisite, the composition of assembly should lack as far as possible.
The existing preparation of carbosulfan mainly contains missible oil, granule, wetting powder, water dispersible granules, microemulsion, suspending agent and film-spreading oil solution etc.And carbosulfan ultra low volume liquids has no report both at home and abroad.
Ultra low volume spraying technology, abroad just begins one's study as far back as the forties, until the initial stage sixties, after the U.S. has solved ultra low volume spraying agent, this pesticide application technology just starts many countries in the world and grows up gradually.Because the benefit of this technology is very remarkable, by dozens of country, used so far, as the countries such as the U.S., Canada, Australia, adopt aircraft, tractor to carry out ultra low volume spraying, the ultra-low-volume sprayer of Thailand, Brazil and the mainly employing such as Chinese, hand-held, backpack carries out small-scale spray pesticide.
Summary of the invention
The object of the invention is according to above-mentioned situation, provide a kind of a kind of and carbosulfan in chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa the composite ultra low volume liquids forming.Not only can eliminate the pierce-suck type pest such as aphid, plant hopper, leafhopper, aleyrodid and to a large amount of uses due to carbosulfan, may cause the resistance producing, can also make its control efficiency obviously improve.
The present invention is a kind of with the composite ultra low volume liquids forming of a kind of active ingredient in carbosulfan and chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa, for preventing and treating rice hoppers, aphid, leafhopper, aleyrodid and pierce-suck type pest.
Described weight ratio of constituents example is a kind of composition in chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa: carbosulfan=1.0～80.0: 1.0～30.0.Preferred weight ratio is a kind of composition in chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa: carbosulfan=2.0～35.0: 2.0～25.0.After it is composite, can not only delay the generation of the pierce-suck type pest resistances such as aphid, plant hopper, leafhopper, aleyrodid, the killing of sucking pest such as aphid, plant hopper, leafhopper, aleyrodid are all had to certain synergistic effect.
It is carbosulfan 1.0%～30.0% that this ultra low volume liquids includes effective constituent mass fraction, chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa are respectively 1.0%～40.0%, and chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa and carbosulfan component ratio are 40: 1～2.
In addition, this ultra low volume liquids also comprises cosolvent 1.0%～10.0%, and solvent complements to 100%.
Applicable cosolvent is selected from cyclohexanone, methyl-sulfoxide, or 1-METHYLPYRROLIDONE.
Applicable solvent is many Fluhyzons, as a line oil or two wires wet goods, and heavy aromatics, vegetable oil is as turpentine oil or cottonseed oil, corn oil.Preferred two wires oil or the above aromatic hydrocarbons of C10.
Ultra low volume liquids of the present invention adopts manner known in the art preparation, normally active ingredient and cosolvent, solvent is fully uniformly mixed and is formed.
Applicable target crop is the cereal crops such as paddy rice, wheat, the economic crops such as soybean, peanut, cotton, tea tree, the vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, the ground family crops such as cucumber, pumpkin, watermelon, the fruit tree crops such as grape, oranges and tangerines, apple, pear tree, peach.
Adopt pesticides application ultra low volume spraying method of the present invention to prevent and treat.
Ultra low volume liquids of the present invention is applicable to control rice thrips, rice gall midge, rice fulgorid, rice leafhopper, and wheat mythimna separata, aphid, aleyrodid, scale insect etc., be specially adapted to ultra low volume spraying method and prevent and treat rice hoppers.
The present invention carries out the composite ultra low volume liquids forming by carbosulfan and chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa, take rice fulgorid as research object, the comparative study proof of imitating by composite synergistic effect, field not only can reduce or eliminate pierce-suck type pest a large amount of uses due to carbosulfan etc. are caused to the resistance producing, and can also make its control efficiency obviously improve.Result of study sees attached list 1～5.
Use DPS software to carry out statistical analysis, obtain toxicity regression line (Y=a+bx) and correlation coefficient (r) value, LC50, the LC90 equivalence of test medicament and adopt the abundant method of Sun Yun to obtain the co-toxicity coefficient of each mixed ratio with reference to NY/T 1154.7-2006, selecting optimal proportion.Toxicity Determination result shows, chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa are mixed the co-toxicity coefficient of rice fulgorid are all greater than to 100 with 5 kinds of different proportions of carbosulfan respectively, illustrate that two composite reagents are to have certain synergistic effect for preventing and treating rice fulgorid, can apply in practice.
According to subordinate list 1-5, field control effectiveness test data all show, carbosulfan and chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa carry out the composite ultra low volume liquids forming to the quick-acting of rice fulgorid, lasting effect, anti-efficiency significantly better than contrasting medicament.
Adopt this pesticides application ultra low volume spraying method, do not need thin up liquid in use procedure, dispenser work efficiency is high, and preventive effect is remarkable.Traditional application method of comparing can be saved a large amount of manpower and materials.
Embodiment
The present invention is a kind of a kind of composition and composite Recompounded pesticide forming of carbosulfan in chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa, its a kind of composition in chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa and carbosulfan and suitable auxiliary agent and the composite ultra low volume liquids forming of carrier.A kind of component content in complex preparation in containing chlopyrifos, Diacloden, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa is 1.0～40.0%, and carbosulfan content is 1.0～30.0%.
The present invention describes with the following example, but does not limit the scope of the invention.
Embodiment 1, carbosulfan, chlopyrifos ultra low volume liquids
A, 2.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, by carbosulfan 1.0kg, chlopyrifos 1.0kg, 1-METHYLPYRROLIDONE 3.0kg, neopelex 2.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 2.0kg, chlopyrifos 10.0kg, 1-METHYLPYRROLIDONE 5.0kg, neopelex 4.5kg, residue complements to 100kg with C10 aromatic solvent, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 6.0kg, chlopyrifos 24.0kg, 1-METHYLPYRROLIDONE 7.5kg, neopelex 5.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, chlopyrifos 40.0kg, 1-METHYLPYRROLIDONE 10.0kg, neopelex 7.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 2, carbosulfan, Diacloden ultra low volume liquids
A, 2.0% carbosulfan Diacloden ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, Diacloden 1.0kg, 1-METHYLPYRROLIDONE 3.0kg, neopelex 2.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan Diacloden ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 2.0kg, Diacloden 10.0kg, 1-METHYLPYRROLIDONE 5.0kg, neopelex 4.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan Diacloden ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 6.0kg, Diacloden 24.0kg, 1-METHYLPYRROLIDONE 7.5kg, neopelex 5.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan Diacloden ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, Diacloden 40.0kg, 1-METHYLPYRROLIDONE 10.0kg, neopelex 7.5kg, residue complements to 100kg with two wires oil solvent, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 3, carbosulfan, meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids
A, 2.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, meta-tolyl-N-methylcarbamate (MTMC) 1.0kg, 1-METHYLPYRROLIDONE 3.0kg, neopelex 2.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 2.0kg, meta-tolyl-N-methylcarbamate (MTMC) 10.0kg, 1-METHYLPYRROLIDONE 5.0kg, neopelex 4.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 6.0kg, meta-tolyl-N-methylcarbamate (MTMC) 24.0kg, 1-METHYLPYRROLIDONE 7.5kg, neopelex 5.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, meta-tolyl-N-methylcarbamate (MTMC) 40.0kg, 1-METHYLPYRROLIDONE 10.0kg, neopelex 7.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 4, carbosulfan, Mobucin ultra low volume liquids
A, 2.0% carbosulfan Mobucin ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, Mobucin 1.0kg, 1-METHYLPYRROLIDONE 3.0kg, neopelex 2.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan Mobucin ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 2.0kg, Mobucin 10.0kg, 1-METHYLPYRROLIDONE 5.0kg, neopelex 4.5kg, two wires oil solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan/Mobucin ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 6.0kg, Mobucin 24.0kg, 1-METHYLPYRROLIDONE 7.5kg, neopelex 5.5kg, residue complements to 100kg with C10 aromatic solvent, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan/Mobucin ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, Mobucin 40.0kg, 1-METHYLPYRROLIDONE 10.0kg, neopelex 7.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 5, carbosulfan, Bassa ultra low volume liquids
A, 2.0% carbosulfan Bassa ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, Bassa 1.0kg, 1-METHYLPYRROLIDONE 3.0kg, neopelex 2.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan Bassa ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 2.0kg, Bassa 10.0kg, 1-METHYLPYRROLIDONE 5.0kg, neopelex 4.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan Bassa ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 6.0kg, Bassa 24.0kg, 1-METHYLPYRROLIDONE 7.5kg, neopelex 5.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan Bassa ultra low volume liquids 100kg
Take finished product ultra low volume liquids as weight 100% calculating, carbosulfan 1.0kg, Bassa 40.0kg, 1-METHYLPYRROLIDONE 10.0kg, neopelex 7.5kg, C10 aromatic solvent complements to 100kg, pour in enamel stirred tank, stir about 30 minutes, to completely transparent, detect up-to-standard after, metering encapsulation is finished product.
During use, directly the above-mentioned finished product being mixed with is added in ultra low volume spraying device, opening sprayer unit just can the effective pest control of large area.
Subordinate list 1 carbosulfan and chlorpyrifos mixture ultra low volume liquids and single dose control rice fulgorid field efficacy result
Subordinate list 2 carbosulfans and Thiamethoxam compound ultra low volume liquids and single dose control rice fulgorid field efficacy result
Subordinate list 3 carbosulfans and the composite ultra low volume liquids of meta-tolyl-N-methylcarbamate (MTMC) and single dose control rice fulgorid field efficacy result
Subordinate list 4 carbosulfans and the composite ultra low volume liquids of Mobucin and single dose control rice fulgorid field efficacy result
Subordinate list 5 carbosulfans and fenobucarb composite ultra low volume liquids and single dose control rice fulgorid field efficacy result
Claims (1)
1. containing the ultra low volume liquids of carbosulfan, described ultra low volume liquids is by carbosulfan 1.0kg, chlopyrifos 1.0kg, and 1-METHYLPYRROLIDONE 3.0kg, neopelex 2.5kg, two wires oil solvent complements to 100kg; Or carbosulfan 2.0kg, chlopyrifos 10.0kg, 1-METHYLPYRROLIDONE 5.0kg, neopelex 4.5kg, residue complements to 100kg with C10 aromatic solvent; Or carbosulfan 6.0kg, chlopyrifos 24.0kg, 1-METHYLPYRROLIDONE 7.5kg, neopelex 5.5kg, two wires oil solvent complements to 100kg; Carbosulfan 1.0kg, chlopyrifos 40.0kg, 1-METHYLPYRROLIDONE 10.0kg, neopelex 7.5kg, two wires oil solvent complements to 100kg and forms.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102273441B (en) * | 2011-09-13 | 2015-01-07 | 广西田园生化股份有限公司 | Ultralow volume liquid containing azoxystronbin |
| CN102349506B (en) * | 2011-09-13 | 2014-07-09 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
| CN102273442A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing epoxiconazole |
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| CN1274530A (en) * | 2000-04-21 | 2000-11-29 | 常州农药厂 | Pesticide capable of preventing and killing rice gall insect |
| CN1799360A (en) * | 2004-12-31 | 2006-07-12 | 潘贞德 | A group of soluble liquid pesticide making carbosulfan as raw material |
| CN101084747A (en) * | 2006-06-06 | 2007-12-12 | 中国农业科学院植物保护研究所 | Microemulsion liquid agent for pesticide novel preparation |
| CN101703066A (en) * | 2009-09-27 | 2010-05-12 | 广西田园生化股份有限公司 | Ultralow-volume compound medicament for preventing and controlling cotton aphids |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1274530A (en) * | 2000-04-21 | 2000-11-29 | 常州农药厂 | Pesticide capable of preventing and killing rice gall insect |
| CN1799360A (en) * | 2004-12-31 | 2006-07-12 | 潘贞德 | A group of soluble liquid pesticide making carbosulfan as raw material |
| CN101084747A (en) * | 2006-06-06 | 2007-12-12 | 中国农业科学院植物保护研究所 | Microemulsion liquid agent for pesticide novel preparation |
| CN101703066A (en) * | 2009-09-27 | 2010-05-12 | 广西田园生化股份有限公司 | Ultralow-volume compound medicament for preventing and controlling cotton aphids |
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