CN102415398A - Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof - Google Patents

Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof Download PDF

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Publication number
CN102415398A
CN102415398A CN2010102998461A CN201010299846A CN102415398A CN 102415398 A CN102415398 A CN 102415398A CN 2010102998461 A CN2010102998461 A CN 2010102998461A CN 201010299846 A CN201010299846 A CN 201010299846A CN 102415398 A CN102415398 A CN 102415398A
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mti
dimension salt
salt
dimension
compositions
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CN2010102998461A
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Inventor
王红明
刘德友
唐旺全
陈文明
赵维桢
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN2010102998461A priority Critical patent/CN102415398A/en
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Abstract

The invention discloses a composite insecticide composition containing dinotefuran and emamectin benzoate and a purpose thereof. The insecticide composition uses the dinotefuran and the emamectin benzoate as major effective ingredients, wherein the weight ratio of the dinotefuran to the emamectin benzoate is (0.1 to 80)/(0.5 to 80). The insecticide composition can be used for treating homoptera pests and hemiptera pests on crops and can be particularly used for preventing and treating delphacidae, whitefly, leafhopper and aphid, a higher synergy effect can be generated, the pest drug resistance is overcome and delayed, the insecticide speed is high, the duration is long, the medication cost is reduced, and the prevention and treatment effect is obviously higher than that obtained by using single agents.

Description

A kind of compound pesticide compositions that contains MTI-446 and first dimension salt and uses thereof
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compound pesticide compositions that contains MTI-446 and first dimension salt and uses thereof.
Background technology
MTI-446 (dinotefuran) is the third generation nicotinic insecticide of Mitsui chemical company exploitation.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and chloro-pyridine base, chloro thiazolyl before its tetrahydrofuran base has replaced do not contain the halogen family element.Simultaneously, also different at aspect of performance with nicotine.So people are referred to as " furans nicotine " at present.The MTI-446 chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, structural formula is following:
A new generation's anabasine insecticide MTI-446 mainly acts on insect neurotransmission system, makes the insect paralysis dead.This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has promptly shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crops such as paddy rice, fruit tree, vegetables.To rice grub brown planthopper, white-backed planthopper, small brown rice planthopper, rice leafhopper, rice spider rafter stinkbug, star stinkbug, green rice bug resemble, red must fleahopper, rice negatively mixes worm, rice tube water snout moth's larva is efficient.Effective to striped rice borer, oryza chinensis class.Efficient to vegetables, fruit insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in diagonal angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza are effective.MTI-446 has very wide insecticidal spectrum, and fool proof again to crop, people and animals and environment, is equipped with the method for using of various uses again, this agricultural chemicals large-tonnage agricultural chemicals that is expected to become international.
First dimension salt (Proclaim) chemical name is: 4 '-methylamino-4 '-deoxidation AVM B1 benzoate.Be from fermented product AVM B 1A kind of new and effective semisynthetic antibiotics insecticide that begins to synthesize, it has super-high-efficient, low toxicity (preparation is closely nontoxic), noresidue, the nuisanceless characteristics that wait biopesticide.Efficiently, wide spectrum, the longevity of residure be long, is good insecticidal/acaricidal agent.The mode of action is the main action of contace poison that has concurrently with the stomach toxicity, and crop is not had interior absorption ability, uses crop epidermal tissue but can effectively infiltrate, thereby has the longer longevity of residure.In soil, be prone to degraded, noresidue, free from environmental pollution, in the routine dose scope to useful insect and natural enemy, people, animal safety, can with most of combined use of pesticides.
But homoptera pest, particularly rice fulgorid and aphid are under the condition of present long-term prescription, and resistance increases gradually, and the agent of agricultural chemicals list descends to the effect of control of insect gradually.The inventor finds that after deliberation the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, does not find the Pesticidal combination of relevant MTI-446 and first dimension salt up to now as yet.
Summary of the invention
The purpose of this invention is to provide a kind of compound pesticide compositions that contains MTI-446 and first dimension salt, this Pesticidal combination is the multifunctional insecticide composition of control homoptera pest.
Another object of the present invention provides this Pesticidal combination and prevents and treats the application on the insecticidal materials of resistance Homoptera, Semiptera insect in preparation, particularly the application on the insecticidal materials of preparation control plant hopper, aleyrodid, leafhopper and aphid.
The objective of the invention is to realize through following technical scheme:
A kind of compound pesticide compositions that contains MTI-446 and first dimension salt, this Pesticidal combination is main active ingredient with MTI-446 and first dimension salt, wherein, the weight ratio of MTI-446 and first dimension salt is 0.1~80: 0.5~80.Effective ingredient is present in the composition with the synergy effective dose in this Pesticidal combination.
The weight ratio preferred 1~30: 1~30 of MTI-446 and first dimension salt further is preferably 1~10: 1~15 in this Synergistic insecticidal compositions.
In the present composition, the two percentage by weight that accounts for composition of MTI-446 and first dimension salt is 1~80%, is preferably 1~65%, most preferably 5~40%.
Pesticidal combination of the present invention is that main active ingredient and insecticides adjuvant and excipient are mixed with any one formulation that allows on the agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule with MTI-446 and first dimension salt.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, APES, polyoxyethylene polyoxy third rare block compound (like farming breast 33 #), one or more combinations of conventional auxiliary agent such as NPE, excipient comprises conventional excipients such as isopropyl alcohol, solvent naphtha, solvent naphtha, water, antifreezing agent (like propane diols), deionized water.Above auxiliary agent, excipient can singly be used or mix and use.
Pesticidal combination of the present invention has good preventive effect to Homoptera, the Semiptera insect that rice fulgorid and aphid etc. is easy to generate resistance; And the inhibition insect is to single preparation (MTI-446 or first dimension salt bes's arbitrary) pesticide resistance generation.Therefore, above-mentioned Pesticidal combination can be used for preparing the insecticidal materials of preventing and treating resistance Homoptera, Semiptera insect, is particularly useful for preparing the insecticidal materials of control aleyrodid, plant hopper, leafhopper and aphid." % " of the present invention is mass percent.
Beneficial effect compared with prior art of the present invention: the present invention has obvious synergistic function to preventing and treating resistance Homoptera, Semiptera insect such as rice fulgorid, aphid etc.; Overcome and delayed pest resistance to insecticide; The expanding prevention spectrum, desinsection speed is fast, has obviously improved control efficiency; Reduce control recruitment, drug cost; Alternative high-toxic pesticide; Have concurrently quick-acting and long-acting; Compare with the agent of first dimension salt list with MTI-446, produce and the use cost reduction; Suppress the resistance enhancing of homoptera pest to agricultural chemicals, its effect is used apparently higher than its single agent.
Embodiment
Below in conjunction with embodiment the present invention is described further:
Embodiment 1:
Taking by weighing MTI-446, first dimension salt, to adopt the conventional formulation method to be mixed with main effectively composition quality percentage composition by different proportion be 3% MTI-446 first dimension salt missible oil, and the contrast medicament is respectively 3% MTI-446 missible oil and 3% first dimension salt missible oil, and concrete ratio is seen table 1,2.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting the resistant rice plant hopper is target pest, every processing repetition 3 times, and every concentration is handled 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method 50, use LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, and the result sees table 1:
The toxicity test of table 1 MTI-446 and the composite and single agent antagonism of first dimension salt rice fulgorid
Can be known that by table 1 MTI-446 and first dimension salt are composite, co-toxicity coefficient shows good synergistic effects all greater than 120.
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance wheat aphid is target pest, and every processing repetition 3 times is with toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid of probability value method calculating 50, use LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, and the result sees table 2:
The toxicity test of table 2 MTI-446 and the composite and single agent antagonism of first dimension salt wheat aphid
Can know that by table 2 MTI-446 and first dimension salt is composite, the co-toxicity coefficient of wheat aphid all greater than 120, is shown good synergistic effects.
Embodiment 2:
Take by weighing 2g MTI-446,3g first dimension salt, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33 #2g, APES 1g, solvent naphtha 13g adds water to 100g.Above raw material is mixed by the method input mixing kettle high speed of routine preparation aqueous emulsion, and processing main active ingredient weight percentage is 5% MTI-446-emamectin benzoate water emulsion.
Embodiment 3:
Take by weighing 0.5g MTI-446,4.5g first dimension salt, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33 #2g, APES 1g, propane diols 10g adds water to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation microemulsion, processing main active ingredient weight percentage is 5% MTI-446-first dimension salt microemulsion.
Embodiment 3 is prevented and treated the paddy rice brown planthopper test of pesticide effectiveness, and the contrast medicament is 5% first dimension salt WDG and 5% MTI-446 WP, dilutes according to the extension rate of 3 li of forms; 30 kilograms of soups are used on every mu of ground, dilution back; Looked into behind the medicine 2 days, the result of 5 days and 10 days, result is seen table 3:
Table 3: the MTI-446-composite field test results of first dimension salt to the paddy rice brown planthopper
Field efficacy is the result show, MTI-446 first dimension salt composite antagonism rice fulgorid has good control efficiency, and control efficiency all is better than single agent kind.
Embodiment 3 is prevented and treated the wheat aphid field medicine effect test, and the contrast medicament is 5% first dimension salt WDG and 5% MTI-446 WP, dilutes according to the extension rate of 3 li of forms; 30 kilograms of soups are used on every mu of ground, dilution back; Looked into behind the medicine 2 days, the result of 5 days and 10 days, result is seen table 4:
Table 4: the MTI-446-composite field test results of first dimension salt to wheat aphid
Field efficacy is the result show, MTI-446 first dimension salt composite antagonism wheat aphid has good control efficiency, and control efficiency all is better than single agent kind.
Embodiment 4:
Take by weighing 1g MTI-446,15g first dimension salt, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 16% MTI-446-first dimension salt missible oil.
Embodiment 5: take by weighing 50g MTI-446,20g first dimension salt; Lignin 10g, Negel 2g, add to 100g with diatomite; Above raw material is mixed in micronizer, and processing main active ingredient weight percentage is 70% MTI-446 and first dimension salt wetting powder.
Embodiment 6: take by weighing 2g MTI-446,40g first dimension salt, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 42% MTI-446-first dimension salt missible oil.
Embodiment 7: take by weighing 12g MTI-446,3g first dimension salt, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and under the effect of sand mill, processing main active ingredient weight percentage is 15% MTI-446-first dimension salt suspension agent.
Embodiment 8: take by weighing 5g MTI-446,0.5g first dimension salt, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 5.5% MTI-446-first dimension salt missible oil.
Embodiment 9: take by weighing 30g MTI-446,5g first dimension salt, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and under the effect of sand mill, processing main active ingredient weight percentage is 35% MTI-446-first dimension salt suspension agent.
Embodiment 10: take by weighing 20g MTI-446,4g first dimension salt, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and under the effect of sand mill, processing main active ingredient weight percentage is 24% MTI-446-first dimension salt suspension agent.
Embodiment 11: take by weighing 30g MTI-446,1g first dimension salt, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and under the effect of sand mill, processing main active ingredient weight percentage is 31% MTI-446-first dimension salt suspension agent.
Embodiment 12: take by weighing 2g MTI-446,5g first dimension salt; The 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g; Polyvinyl alcohol 5g; Borax 2g, diatomite complements to 100g, and it is 7% MTI-446-emamectin benzoate water dispersible granule that above raw material is processed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 13: take by weighing 1g MTI-446,10g first dimension salt; The 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g; Polyvinyl alcohol 5g; Borax 2g, diatomite complements to 100g, and it is 11% MTI-446-emamectin benzoate water dispersible granule that above raw material is processed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 14: take by weighing 0.2g MTI-446,60g first dimension salt; Lignin 10g, Negel 2g, add to 100g with diatomite; Above raw material is mixed in micronizer, and processing main active ingredient weight percentage is 60.2% MTI-446 and first dimension salt wetting powder.
Embodiment 15: take by weighing 7g MTI-446,70g first dimension salt, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 77% MTI-446-first dimension salt missible oil.

Claims (10)

1. a compound pesticide compositions that contains MTI-446 and first dimension salt is characterized in that this Pesticidal combination is main active ingredient with MTI-446 and first dimension salt, and wherein, the weight ratio of MTI-446 and first dimension salt is 0.1~80: 0.5~80.
2. Pesticidal combination according to claim 1 is characterized in that the weight ratio of described MTI-446 and first dimension salt is 1~30: 1~30.
3. Pesticidal combination according to claim 2 is characterized in that the weight ratio of described MTI-446 and first dimension salt is 1~10: 1~15.
4. the Synergistic insecticidal compositions that contains MTI-446 and first dimension salt according to claim 1 is characterized in that it is 1~80% that MTI-446 and first are tieed up the two weight percentage that accounts for composition of salt.
5. the Synergistic insecticidal compositions that contains MTI-446 and first dimension salt according to claim 4 is characterized in that it is 1~65% that MTI-446 and first are tieed up the two weight percentage that accounts for composition of salt.
6. the compound pesticide compositions that contains MTI-446 and first dimension salt according to claim 5 is characterized in that it is 5~40% that MTI-446 and first are tieed up the two weight percentage that accounts for composition of salt.
7. the Synergistic insecticidal compositions that contains MTI-446 and first dimension salt according to claim 1 is characterized in that it is that main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals with MTI-446 and first dimension salt.
8. the Synergistic insecticidal compositions that contains MTI-446 and first dimension salt according to claim 7 is characterized in that said formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the described Synergistic insecticidal compositions that contains MTI-446 and first dimension salt of claim 1 is prevented and treated the application on the insecticidal materials of resistance Homoptera, Semiptera insect in preparation.
10. the application of Synergistic insecticidal compositions on the insecticidal materials of preparation control plant hopper, aleyrodid, leafhopper and aphid that contains MTI-446 and first dimension salt according to claim 9.
CN2010102998461A 2010-09-28 2010-09-28 Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof Pending CN102415398A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101990898A (en) * 2010-11-29 2011-03-30 陕西韦尔奇作物保护有限公司 Dinotefuran-containing pesticide composition
CN102763668A (en) * 2012-07-04 2012-11-07 河北威远生物化工股份有限公司 Insecticidal composition containing dinotefuran and emamectin benzoate
CN105028456A (en) * 2015-06-12 2015-11-11 福建省德盛生物工程有限责任公司 Low-volume spray containing emamectin benzoate and dinotefuran
CN108902164A (en) * 2018-08-08 2018-11-30 河北威远生物化工有限公司 A kind of composition pesticide and its preparation and application
CN111149812A (en) * 2020-01-17 2020-05-15 河南远见农业科技有限公司 Insecticide composition containing emamectin benzoate and dinotefuran and application thereof

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Publication number Priority date Publication date Assignee Title
CN1646018A (en) * 2002-02-21 2005-07-27 拜尔农作物科学股份公司 Synergistic insecticide mixtures
CN101208009A (en) * 2005-07-27 2008-06-25 三井化学株式会社 Composition for preventing and removing pest
EP2000029A1 (en) * 2007-06-06 2008-12-10 Bayer CropScience AG Insecticide and fungicide active agent combinations
CN101583277A (en) * 2006-12-22 2009-11-18 拜尔农作物科学股份公司 Pesticide composition comprising propamocarb-fosetylate and an insecticidally active substance

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646018A (en) * 2002-02-21 2005-07-27 拜尔农作物科学股份公司 Synergistic insecticide mixtures
CN101208009A (en) * 2005-07-27 2008-06-25 三井化学株式会社 Composition for preventing and removing pest
CN101583277A (en) * 2006-12-22 2009-11-18 拜尔农作物科学股份公司 Pesticide composition comprising propamocarb-fosetylate and an insecticidally active substance
EP2000029A1 (en) * 2007-06-06 2008-12-10 Bayer CropScience AG Insecticide and fungicide active agent combinations

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101990898A (en) * 2010-11-29 2011-03-30 陕西韦尔奇作物保护有限公司 Dinotefuran-containing pesticide composition
CN102763668A (en) * 2012-07-04 2012-11-07 河北威远生物化工股份有限公司 Insecticidal composition containing dinotefuran and emamectin benzoate
CN105028456A (en) * 2015-06-12 2015-11-11 福建省德盛生物工程有限责任公司 Low-volume spray containing emamectin benzoate and dinotefuran
CN108902164A (en) * 2018-08-08 2018-11-30 河北威远生物化工有限公司 A kind of composition pesticide and its preparation and application
CN111149812A (en) * 2020-01-17 2020-05-15 河南远见农业科技有限公司 Insecticide composition containing emamectin benzoate and dinotefuran and application thereof

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Application publication date: 20120418