CN102349506B - Ultralow-volume solvent containing Flusilazole - Google Patents
Ultralow-volume solvent containing Flusilazole Download PDFInfo
- Publication number
- CN102349506B CN102349506B CN201110269638.1A CN201110269638A CN102349506B CN 102349506 B CN102349506 B CN 102349506B CN 201110269638 A CN201110269638 A CN 201110269638A CN 102349506 B CN102349506 B CN 102349506B
- Authority
- CN
- China
- Prior art keywords
- flusilazole
- low volume
- ultra low
- volume liquids
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 title claims abstract description 124
- 239000002904 solvent Substances 0.000 title claims abstract description 36
- 238000005507 spraying Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims description 108
- 238000002360 preparation method Methods 0.000 claims description 78
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- 239000002131 composite material Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 150000003851 azoles Chemical class 0.000 claims description 14
- 240000007594 Oryza sativa Species 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 235000007164 Oryza sativa Nutrition 0.000 claims description 11
- -1 polyoxyethylene, phenethyl phenol Polymers 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 235000009566 rice Nutrition 0.000 claims description 11
- 241000221785 Erysiphales Species 0.000 claims description 9
- 206010039509 Scab Diseases 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
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- 235000013399 edible fruits Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 5
- 235000013311 vegetables Nutrition 0.000 claims description 5
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims description 4
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 4
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- 230000000740 bleeding effect Effects 0.000 claims description 4
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 claims description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 4
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- 239000002798 polar solvent Substances 0.000 claims description 4
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- 241001530056 Athelia rolfsii Species 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- YQZBFMJOASEONC-UHFFFAOYSA-N 1-Methyl-2-propylbenzene Chemical compound CCCC1=CC=CC=C1C YQZBFMJOASEONC-UHFFFAOYSA-N 0.000 claims description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical group CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229960001760 dimethyl sulfoxide Drugs 0.000 claims description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 2
- 229940093471 ethyl oleate Drugs 0.000 claims description 2
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 2
- 229940073769 methyl oleate Drugs 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- 229940116411 terpineol Drugs 0.000 claims description 2
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 15
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- 239000003814 drug Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 15
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- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 11
- 239000006013 carbendazim Substances 0.000 description 11
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 11
- 230000000857 drug effect Effects 0.000 description 9
- 230000003449 preventive effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
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- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 description 8
- 230000000855 fungicidal effect Effects 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 241000233866 Fungi Species 0.000 description 7
- 239000005807 Metalaxyl Substances 0.000 description 7
- 239000000417 fungicide Substances 0.000 description 7
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
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- 240000008067 Cucumis sativus Species 0.000 description 6
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- 239000005760 Difenoconazole Substances 0.000 description 6
- 239000005868 Metconazole Substances 0.000 description 6
- 241000233679 Peronosporaceae Species 0.000 description 6
- 240000001987 Pyrus communis Species 0.000 description 6
- 235000014443 Pyrus communis Nutrition 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 6
- 230000002045 lasting effect Effects 0.000 description 6
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 6
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 5
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 description 5
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 5
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 description 5
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an ultralow-volume solvent containing Flusilazole. Flusilazole or an active ingredient compounded by Flusilazole and an active component B, an accessory ingredient and a solvent are prepared into the ultralow-volume solvent. The ultralow-volume solvent containing Flusilazole comprises the following ingredients in percentage by weight: 1-10% of Flusilazole, 0-20% of active component B, 1-15% of accessory ingredient and the balance of solvent. The ultralow-volume solvent containing Flusilazole is suitable for ultralow-volume spraying, low-volume spraying and electrostatic spraying, has the advantages of high work efficiency, water conservation, good quick effect, long persistent period and rain scouring washing resistance.
Description
Technical field
The invention belongs to technical field of pesticide, specifically relate to the ultra low volume liquids of composite containing flusilazole.
Background technology
Flusilazole, chemical name: two (4-fluorophenyl)-(1H-1,2,4-triazol-1-yl methyl) monosilane, belong to triazole type systemic fungicide, can suppress sterol demethylation, destroy and stop the biosynthesis of ergosterol, cause cell membrane not form, make germ death.It is mainly used in preventing and treating Ascomycetes, Basidiomycetes, Fungi Imperfecti fungi, venturia inaequalis, Powdery Mildew, the wheat class nuclear cavity bacteria of Cereal, Septoria bacterium, snag shell bacterium etc., various pathogens on Guignardia and sweet Lay, leaf spot of peanut, but invalid to oomycetes, pear scab is had to special efficacy.
Difenoconazole, chemical name: 1-{2-[4-(4-chlorobenzene oxygen)-2-chlorphenyl]-4-methyl isophthalic acid, 3-dioxin-pentane-2-ylmethyl }-1H-1,2,4-triazole, belongs to triazole type systemic fungicide, has protection, treatment and systemic activity.It belongs to sterol demethylation inhibitor, can suppress the biosynthesis of cell wall sterol, stops the growth of fungi.Its fungicidal spectrum is wide, can improve output and the guaranteed quality of crop for leaf surface treatment or seed treatment; To Ascomycetes, Basidiomycetes with partly know disease including Alternaria, Ascochyta, the mould genus of tail spore, Colletotrichum, ball Cuo Pseudomonas, Phoma, Ramularia, Septoria, Venturia, Erysiphaceae, Uredinales and some Seedborne pathogen have lasting protection and therapeutic action; Also fine to bitter rot or anthracnose of grape, white rot effect.
Carbendazim, chemical name: 2-(methoxyl group carbamyl) benzimidazole, the characteristic such as benzimidazole has efficiently, low toxicity, wide spectrum, systemic fungicide, and the lasting period is long, effective to many sac fungis, imperfect fungus and various basidiomycetes, invalid to phytocomycetes.It is for preventing and treating gibberella zeaze petch of wheat and barley, rice sheath blight disease, rice blast, sclerotium oryzicola, many fruit trees, vegetable disease, as powdery mildew, anthracnose, scab etc., carbendazim can be absorbed by plants and transfer to other positions through conduction, disturb the mitosis of germ cell, suppress its growth.
Isoprothiolane, chemical name: 1,3-dithiolane-2-vinyl Diisopropyl malonate is the interior absorption organosulfureous fungicide of efficient, low toxicity, low-residual.Rice blast is had to special efficacy, and rice plant can suppress germ intrusion after absorbing, and has especially suppressed phosphide N-methyltransferase, thereby suppresses pathogen growth, plays preventive and therapeutic action.
Tpn, chemical name: daconil M (or 2,4,5,6-tetrachloro-1,3-benzene dicarbonitrile), a kind of wide-spectrum bactericide, can with fungal cell in glyceraldehyde 3-phosphate dehydro-genase in the combined with protein of cysteine, destroy the metabolism of cell and loss of life power.Its Main Function is prevention fungal infection, there is no interior suction conduction, but has good adhesivity at plant surface, is not subject to rain drop erosion, has the longer drug effect phase.Tpn as various crop fungal diseases such as paddy rice, wheat, cotton, potato, tomato, pimento, corn, peanut, mango, grape, apple, pear tree, oranges and tangerines, lichee, longans, particularly has outstanding control efficiency to rust, anthracnose, powdery mildew, downy mildew on fruit tree, vegetables for control.
Metalaxyl; chemical name: N-(methoxy acetyl group)-N-(2; 6-xylyl)-DL-Alanine methyl esters; belong to the efficient systemic fungicide of amide-type; can interior inspiration enter in plant; the general bactericide of water-soluble ratio is much higher, can penetrate the cell membrane of the oomycetes that lipophilicity is little, plays bactericidal action.Therefore, metalaxyl has selectivity special efficacy to the downy mildew in Oomycete and phytophthora, for example, potato late blight, downy mildew of garpe, hop downy mildew, beet epidemic disease, white rust of colza, black shank etc. are had to good control efficiency.
Dimethomorph, chemical name: (E, Z)-4-[3-(4-chlorphenyl) 3-(3,4-Dimethoxyphenyl) acryloyl] morpholine, it is morpholine class broad-spectrum germicide, Peronosporaceae to phycomycetes and the fungi of Phytophthora have unique mode of action, are mainly the decomposition that causes spore cyst wall, thereby make thalline death.Except zoospore form and spore swarm stage, all there is to effect in each stage of oomycetes history of life, especially more responsive at the formation stages of sporangiophore and egg spore, under extremely low concentration, (< 0.25mg/L) is suppressed.If medication before sporulation, can suppress Sporulation completely.The interior absorption of this medicine is extremely strong, and root dispenser can enter by root each position of plant; Foliage spray, dimethomorph also can enter blade interior, and the germ doing in object has been invaded in control in time, newborn blade is also had to desirable protective effect simultaneously; Include two kinds of active components, can simultaneously form strong effectively diaphragm in crop surface after using, thereby show the superior efficacy of internal therapentics and outer protection.
Propamocarb, chemical name: N-[3-(dimethylaminopropyl) amino] propyl formate, belong to carbamate fungicide, low toxicity, safety, there is good local systemic action, after processing soil, can be also upwards delivered to whole strain plant by Root Absorption very soon, after cauline leaf spraying is processed, can be absorbed and play a protective role rapidly by blade; Its mechanism of action is to suppress the phosphoric acid of germ cell membrane component and synthesizing of fatty acid, suppresses mycelial growth and spreads and sporangial formation and spore germination.Propamocarb is a kind of wide-spectrum bactericide; effective especially to algae Gammaproteobacteria fungi; mould to tow, dish stalk is mould, downy mildew, epidemic disease are mould, the rotten fungi such as mould has good killing action; also can make impregnation process and seed protectant, be applicable to the various crop such as the vegetables such as cucumber, tomato, pimento, lettuce, potato and tobacco, strawberry, flowers, fruit tree.
Fluazinam, the chloro-5-of chemical name: N-[3-(trifluoromethyl)-2-pyridine radicals] the chloro-4-of-3-(trifluoromethyl)-2,6-dinitroaniline; pyridine amine derivative; dinitroaniline series bactericidal agent, without result for the treatment of and systemic activity, is the protective fungicide of broad-spectrum high efficacy.Very effective to interlink spore genus, Phytophthora, Plasmopara, Sclerotinia and Venturia; Botrytis cinerea for resistance benzimidazole and dicarboximide series bactericidal agent also has good effect, to also having good effect by the microbial paddy rice damping off of head mold.Fluazinam utmost point resistance of rainwater washing against, the longevity of residure is long, has in addition the effect of controlling phytophagous mites concurrently.Carry the unique effect of compound to the active site of pathogenic bacteria because β-trifluoromethyl Fampridine part plays, can suppress sprouting, infiltration, the growth of mycelia and the formation of spore of pathogene spore in course of infection.
Flusilazole has the conventional formulations such as missible oil, suspending agent, microemulsion, wetting powder and water dispersible granules at present on the market, but the ultra low volume liquids of Flusilazole there is not yet report both at home and abroad; Ultra low volume liquids is a kind of take high boiling oily solvent as pesticide activity component dispersion medium, adds the special finish of one that suitable cosolvent and auxiliary agent are mixed with.When use, by ultra low volume sprayer, ultra low volume liquids is atomized into the droplet that particle diameter is 30～100 μ m, and in field diffusion and dispersion, after contacting with crop or pest, stick to rapidly crop or pest surface, and rapidly to internal penetration, play quick-acting effects; Simultaneously due to the character of finish, strong to the adhesiveness of crop, make it be difficult for being washed away from crop surface by rainwater, be conducive to the performance of drug effect and extend the pharmacy effect time.Fenoxanil, pyraclostrobin, epoxiconazole, metalaxyl, tpn, carbendazim, thiophanate-methyl, fluazinam, white urea cyanogen have missible oil, suspending agent, microemulsion, wetting powder, a water dispersible granules common on the market, but there are long-term single a large amount of uses, make germ produce very strong resistance, be unfavorable for the further raising of drug effect, increase the difficulty of bacteria-treating, need to strengthen dosage and spray medicine number of times, not only improve labour intensity but also strengthened cost accounting.In addition, a large amount of uses of medicament, must cause the residual quantity of environment to increase, and give environment, and there is not yet report both at home and abroad with the composite ultra low volume liquids of Flusilazole.
Current domestic cultural control damage by disease and insect generally adopts the conventional spray-on process of regular dosage form, and it is that pesticidal preparations is carried out to the extermination of disease and insect pest afterwards with large water gaging dilution, and this method of preventing and treating exists many-sided defect:
1, conventional spray-on process work efficiency is low, and work efficiency is only 2～5 mu/day per capita conventionally, is difficult to meet the needs of large-scale planting; Along with the enforcement of China's land transformation policy, soil presents the trend of intensive management, occurs increasing agricultural planting rich and influential family, crop contiguous plant area change; And along with the appearance of China's aging population and recruitment famine, labour becomes rare resource just gradually, human cost improves constantly, and agriculture production cost continues to increase; Agricultural production is obviously seasonal, and damage by disease and insect often needs a large amount of manpowers to prevent and treat at short notice.
2, conventional spray-on process prevention and elimination of disease and pests needs large water gaging, and water consumption reaches 450～900L/hm conventionally
2, and much away from water source and drought and water shortage area, conventional spray-on process is difficult to carry out or can not reaches desirable control efficiency.
3, it is short that conventional spray-on process makes the with medicament lasting period, is generally missible oil, aqua, wetting powder, suspending agent, aqueous emulsion etc. because conventional spray-on process makes the formulation of with medicament, has in the use certain defect:
(1) owing to adding the dilution of large water gaging, the concentration of liquid is very low, and surface tension is often larger, having the crop of wax coat or the lip-deep adhesiveness of target, wetability, permeability poor, is difficult to effectively enter in crop and target body, causes preventive effect poor;
(2) in illumination, high temperature, dry natural environment, the water in liquid is easy to evaporation, causes medicament only to remain in crop surface, easily photodissociation and dry after easily come off and lost efficacy from crop;
(3) mist droplet particle size of conventional spraying is larger, reaches 200～600 μ m, causes being sprayed onto the lip-deep liquid of crop or target and easily runs off.
(4) for a long time, the single and frequent use of pesticide species, makes biological target grow with each passing day to the resistance of medicament itself, is unfavorable for the prevention and control to pest.
Chinese Patent Application No.: 201010253385.4, name be called in the patent application document of " a kind of bactericidal composition ", disclose by active component (A) fluazinam and (B) any one in nitrile bacterium azoles, Difenoconazole, Tebuconazole, propiconazole, own azoles alcohol, Flutriafol, metconazole, epoxiconazole, Flusilazole, Fluquinconazole, tetraconazole, Triadimenol, triazolone, alkene azoles alcohol, penconazole, Cyproconazole form, the mass ratio of A and B is 1: 100～100: 1, and the formulation of said composition is the regular dosage forms such as missible oil, microemulsion, aqueous emulsion, suspending agent.Although said composition preventive effect has improved, in use procedure, need with the dilution of large water gaging, inapplicable for water-deficient area, and there is the defect of conventional formulation.
Chinese Patent Application No.: CN201010614877.1, name is called to disclose in the patent application document of " a kind of composition pesticide that contains metconazole " and the invention discloses a kind of composition pesticide containing in metconazole and triazole bactericidal agent Flusilazole, epoxiconazole, tetraconazole, tricyclazole, Flutriafol, and in composition pesticide, the ratio of weight and number of two kinds of active components is 80: 1～1: 80.This invention is to a certain degree improving preventive effect, has delayed resistance speed, has lowered use cost, but is prepared into regular dosage form, has the defect of regular dosage form.
Summary of the invention
The object of the invention is, in order to solve deficiency of the prior art, provides a kind of ultra low volume liquids of composite containing flusilazole, and its water consumption is few, and work efficiency is strong, safe, can effectively save labour, reduces labor intensity.
Technical scheme of the present invention: the ultra low volume liquids of composite containing flusilazole is by with Flusilazole, or Flusilazole and active component B composite be active component, add auxiliary agent and solvent to be prepared into ultra low volume liquids; Active component B is any one in Difenoconazole, own azoles alcohol, propiconazole, Tebuconazole, Flutriafol, nitrile bacterium azoles, Isoprothiolane, thifluzamide, fenoxanil, pyraclostrobin, metalaxyl, tpn, carbendazim, thiophanate-methyl, fluazinam, white urea cyanogen, Boscalid, iprodione, prothioconazoles, probenazole, ZEN 90160, dimoxystrobin, fluoxastrobin, tetraconazole, metconazole, dimethomorph, Propamocarb.
The percentage by weight of the described each component of ultra low volume liquids is:
The preferred boiling point of described solvent is the solvent higher than 60 ℃ higher than 160 ℃, flash-point, and solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent;
(1) applicable aromatic hydrocarbon solvent comprises that trimethylbenzene, o-dichlorohenzene, the above aromatic hydrocarbons of C10 are as durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil;
(2) applicable plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, castor oil, turpentine oil, and esterified vegetable oil is as methyl oleate, ethyl oleate;
(3) applicable polar solvent solvent comprises that acetophenone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, DMF, DMA, the above alcohols of C6 are as n-hexyl alcohol, n-octyl alcohol, terpineol.
Described auxiliary agent comprises surfactant, synergist, bleeding agent etc., be mainly used to improve adhesiveness, wetability and the permeability of preparation to crop and target, strengthen crop and the absorption of target to medicament, reduce the volatility of solvent, improve the stability of preparation, reduce the viscosity of preparation, thereby play the effect that improves drug effect.
Surfactant is selected from fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the combination of one or more in calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate.
Synergist is selected from one or more combination of Synergistic Phosphorus, sulfoxide, piperonyl butoxide etc.
One or more the combination that bleeding agent is selected from azone, thiophene ketone, oozes soon T, described ooze soon T and can directly on market, buy, and is also fast penetrant T or fast T.
The ultra low volume liquids preparation method of composite containing flusilazole of the present invention is at normal temperatures and pressures, active component and solvent are dropped in the reaction vessel of band stirring, low whipping speed is under 60～150 revs/min, solvent is by active component stirring and dissolving, add again auxiliary component, fully stir 15～60 minutes, it is mixed, obtain composite containing flusilazole ultra low volume liquids.
The present invention is suitably in banded sclerotial blight, scab, powdery mildew and the anthracnose of the crops such as control paddy rice, fruit tree, vegetables and applies.
Application process of the present invention is ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray; Conventionally spray with ultra low volume sprayer, or with electrostatic atomiser spraying, also can add a small amount of water dilution and carry out low-gallonage spraying.
The invention has the beneficial effects as follows:
1. water-saving, the present invention blends with adding water hardly in the process of spraying, but directly medicament is sprayed onto on the blade and stem stalk of crop, and through damage by disease and insect target is convenient away from water source and drought and water shortage area dispenser.
2. work efficiency is high, by using ultra low volume sprayer dispenser, can increase substantially efficiency, improve work efficiency several times to tens times, reduce cost of labor, effectively lower labour intensity, can prevent and treat timely and effectively explosive insect.
3. drug concentration is high, and the lasting period is long.The content of conventional dose own is high, blend the liquid units activity component content spraying after water low, and ultra low volume is directly by reagent spray, the active component content of medicament own is low, but the units activity constituent concentration content of spraying liquor is high, is conducive to improve drug effect; Secondly, ultra low volume adopts low-volatile oil to make solvent, and active component is penetrated into blade deep layer, and resistance of rainwater washing against extends the lasting period, thereby reduces medication number of times, reduces agricultural cost.
4. Synergistic: Flusilazole is a kind of triazole bactericidal agent, can play synergistic function from the bactericide compounded of other different mechanisms of action, and expanding prevention target is composed, and delays the pesticide resistance of germ, reduces the pollution of environment.
5. save agricultural chemicals.Compared with routine spraying, generally can save agricultural chemicals more than 30%.
6. safe, ultra low volume finish is to crop safety, and its active component does not adopt severe toxicity and high-toxic pesticide, is also comparatively safe to people.
Embodiment
For a better understanding of the present invention, describe technology contents of the present invention in detail with example below, but do not limit the scope of the invention.
Example 1
1% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method: in the reaction vessel with electric stirring, under normal temperature and pressure, press formula rate first with solvent by active component Flusilazole stirring and dissolving, mixing speed control is 60 revs/min, add again auxiliary component, fully stir 60 minutes, it is mixed, obtain 1% Flusilazole ultra low volume liquids.
Example 2
3% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method: in the reaction vessel with electric stirring, under normal temperature, press formula rate first with solvent by active component Flusilazole stirring and dissolving, mixing speed control is 120 revs/min, add again auxiliary component, fully stir 30 minutes, it is mixed, obtain 3% Flusilazole ultra low volume liquids.
Example 3
6% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method: in the reaction vessel with electric stirring, under normal temperature, press formula rate first with solvent by active component Flusilazole stirring and dissolving, mixing speed control is 100 revs/min, add again auxiliary component, fully stir 45 minutes, it is mixed, obtain 6% Flusilazole ultra low volume liquids.
Example 4
10% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method: in the reaction vessel with electric stirring, under normal temperature, press formula rate first with solvent by active component Flusilazole stirring and dissolving, mixing speed control is 150 revs/min, add again auxiliary component, fully stir 15 minutes, it is mixed, obtain 10% Flusilazole ultra low volume liquids.
Example 5
8% Flusilazole Difenoconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 6
15% Flusilazole Difenoconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 7
25% Flusilazole Difenoconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 8
The own azoles alcohol of 8% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 9
The own azoles alcohol of 15% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 10
The own azoles alcohol of 27% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 11
8% Flusilazole propiconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 12
13% Flusilazole propiconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 13
22% Flusilazole propiconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 14
6% Flusilazole Tebuconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 15
12% Flusilazole Tebuconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 16
24% Flusilazole Tebuconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 17
7% Flusilazole Isoprothiolane ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 18
13% Flusilazole Isoprothiolane ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 19
20% Flusilazole Isoprothiolane ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 20
7% Flusilazole thifluzamide ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 21
13% Flusilazole thifluzamide low capacity liquor
Press following weight proportion:
Preparation method is with embodiment 3
Example 22
25% Flusilazole thifluzamide low capacity liquor
Press following weight proportion:
Preparation method is with embodiment 4
Example 23
6% Flusilazole fenoxanil ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 24
12% Flusilazole fenoxanil ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 25
19% Flusilazole fenoxanil ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 26
5% Flusilazole pyraclostrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 27
11% Flusilazole pyraclostrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 28
13% Flusilazole pyraclostrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 29
9% Flusilazole metalaxyl ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 30
13% Flusilazole metalaxyl ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 31
19% Flusilazole metalaxyl ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 32
8% Flusilazole tpn ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 33
10% Flusilazole tpn ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 34
17% Flusilazole tpn ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 35
10% Flusilazole carbendazim ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 36
15% Flusilazole carbendazim ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 37
25% Flusilazole carbendazim ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 38
6% Flusilazole thiophanate-methyl ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 39
10% Flusilazole thiophanate-methyl ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 40
13% Flusilazole thiophanate-methyl ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 41
6% Flusilazole fluazinam ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 42
10% Flusilazole fluazinam ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 43
16% Flusilazole fluazinam ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 44
4% Flusilazole frost urea cyanogen ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 45
11% Flusilazole frost urea cyanogen ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 46
8% Flusilazole Boscalid ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 47
13% Flusilazole Boscalid ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 48
6% Flusilazole iprodione ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 49
12% Flusilazole iprodione ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 50
7% Flusilazole prothioconazoles ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 51
15% Flusilazole prothioconazoles low capacity liquor
Press following weight proportion:
Preparation method is with embodiment 3
Example 52
7% Flusilazole probenazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 53
16% Flusilazole probenazole low capacity liquor
Press following weight proportion:
Preparation method is with embodiment 4
Example 54
4% Flusilazole ZEN 90160 ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 55
10% Flusilazole ZEN 90160 ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 56
8% Flusilazole dimoxystrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 57
11% Flusilazole dimoxystrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 58
7% Flusilazole fluoxastrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 59
14% Flusilazole fluoxastrobin ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 60
5.5% Flusilazole tetraconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 61
15% Flusilazole tetraconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 62
5% Flusilazole Flutriafol ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 63
13% Flusilazole Flutriafol ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 2
Example 64
4% Flusilazole metconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 65
12% Flusilazole metconazole ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 66
8% Flusilazole dimethomorph ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 67
11% Flusilazole dimethomorph ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 4
Example 68
8% Flusilazole nitrile bacterium azoles ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 69
16% Flusilazole nitrile bacterium azoles ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 70
5.5% Flusilazole Propamocarb ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
Example 71
10% Flusilazole Propamocarb ultra low volume liquids
Press following weight proportion:
Preparation method is with embodiment 3
The oily liquids that each example ultra low volume liquids is outward appearance homogeneous transparent above.
4 Flusilazole ultra low volume liquids that example 1～4 of the present invention is obtained and 40% Flusilazole EC and 10% Flusilazole EW carry out field control effectiveness test, establish each community and select field planting one-tenth pear tree in age 5 strains of 3 years, repeat 4 times; 7 days, 14 days investigation preventive effects after medicine, the method for investigation drug effect is: 5 strains are investigated in each community, and every strain is got a point by east, south, west, north, middle direction, every some investigation 2 strains, record total strain number and diseased plant number at different levels, check the occurrence degree of pear scab.Result of the test is as table 1:
The control efficiency of table 1 to pear scab
Field test results shows, the ultra low volume liquids of Flusilazole is better than missible oil and aqueous emulsion to the preventive effect of pear scab, and lasting effect is more better than missible oil and aqueous emulsion.
Test example 2: the ultra low volume liquids of Flusilazole and carbendazim is prevented and treated the field trial of powdery mildew of cucumber.
Two kinds of ultra low volume liquids that example 35,37 of the present invention is obtained and 40% Flusilazole EC and 40% silicon azoles carbendazim SC carry out field control effectiveness test, establish each community and select to transplant the cucumber ground 40m of 2 months
2, repeat 4 times; 14 days investigation preventive effects after medicine, the method for investigation drug effect is: 5 samplings of each community diagonal, every some investigation 3 strains, record total number of sheets and the sick number of sheets at different levels, check the occurrence degree of powdery mildew of cucumber.Result of the test is as table 2:
The control efficiency of table 2 to powdery mildew of cucumber
Field test results shows, the ultra low volume liquids of Flusilazole and carbendazim composition can effectively be prevented and treated powdery mildew of cucumber, and effect is better than Flusilazole and takes the control efficiency of oily single dose and Flusilazole and the composite suspending agent of carbendazim.
Test example 3: the ultra low volume liquids of Flusilazole and tpn is prevented and treated the field trial of sigatoka.
Two kinds of mixtures and 40% Flusilazole (EC), 40% tpn (SC) that example 32,33 of the present invention is obtained carry out field control effectiveness test, establish each community and select high banana 5 strains of the field planting 1m of 2 years, repeat 4 times; 14 days investigation preventive effects after medicine, the method for investigation drug effect is: two strains are investigated in each community, and every strain is got a point by east, south, west, north, middle direction, every some investigation 2 strains, record total number of sheets and the sick number of sheets at different levels, check the occurrence degree of leaf spot.Result of the test is as table 3:
The control efficiency of table 3 to sigatoka
Field test results shows, the ultra low volume liquids of Flusilazole and tpn composition can effectively be prevented and treated sigatoka, and effect is better than the control efficiency of tpn or Flusilazole single dose.
Test example 4: the ultra low volume liquids of Flusilazole and own azoles alcohol is prevented and treated the field trial of rice sheath blight disease.
Three kinds of mixtures and 30% kresoxim-methyl SC, 50% kresoxim-methyl WGD that example 7～8 of the present invention is obtained carry out field control effectiveness test, and establishing each community area is rice area 60m
2, repeat 3 times; 15 days investigation preventive effects, the method for investigation drug effect is: 5 pockets are investigated in each community, and every pocket is got a point by east, south, west, north, middle direction, every some investigation 2 strains, record total strain number and diseased plant number at different levels, check the occurrence degree of banded sclerotial blight.Result of the test is as table 4:
The control efficiency of table 4 to rice sheath blight disease
Field test results shows, the ultra low volume liquids of Flusilazole and own azoles alcohol composition can effectively be prevented and treated rice sheath blight disease, and effect is better than the control efficiency of own azoles alcohol or Flusilazole single dose.
Claims (6)
1. a ultra low volume liquids for composite containing flusilazole, is characterized in that: it is composite as active component take Flusilazole and active component B, adds auxiliary agent and solvent to be prepared into ultra low volume liquids; Active component B is own azoles alcohol;
Percentage by weight between the each component of described ultra low volume liquids is:
Flusilazole 10%
Active component B 5%
Auxiliary agent 1%～15%
Solvent surplus;
Described auxiliary agent comprises surfactant, synergist, bleeding agent; Surfactant is one or more the combination in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate; Synergist be Synergistic Phosphorus, sulfoxide, piperonyl butoxide in one or more combination; Bleeding agent is azone, thiophene ketone, oozes one or more the combination in T soon.
2. the ultra low volume liquids of composite containing flusilazole according to claim 1, is characterized in that: described solvent boiling point is the solvent higher than 60 ℃ higher than 160 ℃, flash-point, and solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, the above heavy aromatics of C10; Plant oil solvent comprises soybean oil, rapeseed oil, castor oil, esterified vegetable oil; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, DMF, DMA, the above alcohols of C6.
3. the ultra low volume liquids of composite containing flusilazole according to claim 2, is characterized in that: the above heavy aromatics of described C10 comprises durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene; Described esterified vegetable oil comprises methyl oleate, ethyl oleate; The above alcohols of described C6 comprises n-hexyl alcohol, n-octyl alcohol, terpineol.
4. the preparation method of the ultra low volume liquids of composite containing flusilazole as claimed in claim 1, it is characterized in that: the preparation method of described ultra low volume liquids is at normal temperatures and pressures, active component and solvent are dropped in the reaction vessel of band stirring, low whipping speed is under 60～150 revs/min, solvent is active component stirring and dissolving, then adds auxiliary component, fully stirs 15～60 minutes, it is mixed, obtain composite containing flusilazole ultra low volume liquids.
5. the application of the ultra low volume liquids of composite containing flusilazole as claimed in claim 1, is characterized in that: its application in banded sclerotial blight, scab, powdery mildew and the anthracnose of control paddy rice, fruit tree, vegetable crop.
6. the application process of the ultra low volume liquids of composite containing flusilazole as claimed in claim 1, is characterized in that: its application process is ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.
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| CN102657183A (en) * | 2012-04-12 | 2012-09-12 | 广西田园生化股份有限公司 | Thifluzamide-containing ultra low volume liquid formulation |
| CN102669160A (en) * | 2012-04-28 | 2012-09-19 | 广东中迅农科股份有限公司 | Sterilization composite containing thifluzamide and flusilazole |
| CN102696619A (en) * | 2012-05-23 | 2012-10-03 | 钦州学院 | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide |
| CN105076157A (en) * | 2012-09-19 | 2015-11-25 | 陕西美邦农药有限公司 | Bactericidal composition containing dimoxystrobin and triazoles |
| CN103636641A (en) * | 2013-11-19 | 2014-03-19 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cymoxanil |
| CN103798237B (en) * | 2013-11-19 | 2015-09-09 | 广西田园生化股份有限公司 | A kind of ultra low volume liquids containing Boscalid |
| CN103798242B (en) * | 2013-11-19 | 2015-08-12 | 广西田园生化股份有限公司 | Containing the ultra low volume liquids of Boscalid and triazole bactericidal agent |
| CN103704225A (en) * | 2013-12-13 | 2014-04-09 | 广西田园生化股份有限公司 | Ultralow-volume liquid of ametoctradin and phenyl and o-phthalimide-containing fungicide composition, and preparation method thereof |
| CN103651432A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin and benzamide fungicide composition and preparation method of ultra-low volume liquid |
| CN103651431B (en) * | 2013-12-13 | 2015-12-02 | 广西田园生化股份有限公司 | Containing the ultra low volume liquids and its preparation method and application of pungent azoles mepanipyrim and methoxy acrylic bactericide composition |
| CN103719108A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing picoxystrobin and morpholine bactericide and application thereof |
| CN103688963A (en) * | 2013-12-13 | 2014-04-02 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin composition and preparation method thereof |
| CN103719107A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor |
| CN103999874B (en) * | 2014-05-28 | 2018-06-19 | 甘肃省农业科学院植物保护研究所 | A kind of grease paste and its preparation method and application |
| CN104872171A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Paddy field composite bactericide containing flutriafol, isoprothiolane and flusilazole, and application thereof |
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| CN107593694B (en) * | 2017-09-01 | 2020-07-24 | 中国热带农业科学院环境与植物保护研究所 | Aqueous emulsion |
| CN107593755B (en) * | 2017-09-01 | 2020-05-19 | 中国热带农业科学院环境与植物保护研究所 | Preparation method of aqueous emulsion |
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