CN103719107A - Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor - Google Patents
Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor Download PDFInfo
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- CN103719107A CN103719107A CN201310675277.XA CN201310675277A CN103719107A CN 103719107 A CN103719107 A CN 103719107A CN 201310675277 A CN201310675277 A CN 201310675277A CN 103719107 A CN103719107 A CN 103719107A
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Abstract
The invention discloses an ultra-low-volume liquor containing picoxystrobin and a sterol synthesis inhibitor and aims to solve the problems that the common sterol synthesis inhibitor on the market such as missible oil, a suspending agent, microemulsion, wettable powder or water dispersible granule is used in a long-term, single and heavy manner, which causes that germs have strong resistance. The ultra-low-volume liquor uses picoxystrobin and the sterol synthesis inhibitor as active constituents, meets the ultra-low-volume spray demand, and has the advantages of excellent efficacy, high efficiency, long period of preserving effect, high safety, rain wash resistance, water conservation and labor conservation; in addition, the components in the ultra-low-volume liquor have a synergistic interaction effect and are more excellent in effect than each single component.
Description
Technical field
The present invention relates to pesticide field, especially a kind of ultra low volume liquids containing ZEN 90160 and sterol synthetic inhibitor.
Background technology
Ultra low volume liquids is the solvent low by screening volatility, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, during its dispenser, be not watered, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.In the spray process of ultra low volume solvent, owing to not containing high volatile volatile composition in droplet, the size of droplet and quality do not have significant change from leave spraying apparatus arrival target process, thereby can effectively reduce volatilization with elegant.Meanwhile, droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Because ultra low volume liquids is used without being watered, thereby it is suitable for the occasion that water scarcity, damage by disease and insect fulminant large area occur, must dispenser on a large scale in the short time, and the spraying of ultra low volume solvent simultaneously can greatly reduce operator's labour intensity.
Ultra low volume liquids has following some advantage:
1) spouting liquid of ultra low volume liquids is few, be only conventional spraying hundreds of/mono-;
2) droplet of ultra low volume liquids is little, conventional spraying droplet diameter is many more than 200～600um, and ultra low volume electrostatic spray fogdrop diameter to be 35～45um, ultra low volume ground spraying droplet diameter be 70um, aerial ultra low volume spraying fogdrop diameter 30～60um, the former diameter that is less than conventional spraying droplet;
3) its spray pattern is for the spraying of drift accumulation property, facing to crop spraying;
4) concentration of ultra low volume liquids is generally a few percent to percent tens, and concentration is high, effective, and effect is fast;
5) work efficiency of ultra low volume liquids is high, and control in time, can timely and effectively prevent and treat fulminant insect, avoids the diffusion of insect;
6) compared with the conventional spraying of general ratio, ultra low volume liquids of the present invention can adopt ultra low volume spraying, can save agricultural chemicals more than 30%;
7) do not need water, thereby the present invention can save workman's heavy physical labor such as fetch water, make up a prescription, the hilly ground that is particularly useful for drought and fetches water difficult is used, and its use is more convenient;
8) ultra low volume liquids good drug efficacy, lasting period is long, and liquor is easy to penetrate fat-soluble insect body surface and enters in pest body, show as desinsection rapidly, good drug efficacy, auxiliary agent can play to active ingredient the protective effect of resistant to hydrolysis, anti-oxidant, anti-photodissociation etc., effectively extends the lasting period;
9) ultra low volume liquids, to crop safety, is difficult for producing poisoning, without obviously residual, can improve crop quality;
10) because ultra low volume liquids has the advantages such as province's medicine, laborsaving, water, good drug efficacy, holding effect be not long, thereby can effectively reduce expenses for prevention and control.
And at present, the kind of ultra low volume liquids is less, therefore in the urgent need to developing new ultra low volume liquids.
ZEN 90160, its Chinese name is (E)-3-methoxyl group-2-{2-[6-(trifluoromethyl)-2-pyridine oxygen methyl] phenyl } methyl acrylate, molecular structural formula is as shown in Figure 1.It belongs to mitochondrial respiratory inhibitor, by electronics between cytochrome b and C1, is shifted and is suppressed mitochondrial breathing.The bacterial strain that ZEN 90160 produces resistance to 14-demethylation enzyme inhibitor, benzamides, three carboxyl acylamides and benzimidazole is effective.ZEN 90160, after blade absorbs, will move in xylem, with current, in transportation system, flows, and it also flows in the gas phase of blade surface, and in xylem, flows again along with gas phase absorbs to enter after blade.It is applicable to crop and safety wheat class, recommends under dosage breaking, to crop safety, without poisoning.ZEN 90160 can be used in the foliage disease of control wheat class as leaf blight, leaf rust, glume blight, brown spot, powdery mildew etc., compared with existing strobilurin series bactericidal agent, wheat leaf blessing disease, net blotch and moire disease is had to better result for the treatment of.
At present, common sterol synthetic inhibitor mainly contains missible oil, suspending agent, microemulsion, wetting powder, water dispersible granules on the market.Problems long-term, single, a large amount of uses that such medicament exists, and cause germ to produce very strong resistance.The drug-fast enhancing of germ, causes the control efficiency of medicament to reduce, and has increased the difficulty of prevention and cure of germ, finally causes dosage and medication increased frequency, and the labour intensity of dispenser and use cost increase.Meanwhile, the aniseed of medicament is used, and causes again increasing of medicament residue, has not only affected the safety of crop, also to environment, has brought serious pollution simultaneously.Therefore, provide one to contain sterol synthetic inhibitor, and environmentally friendly, amount of application is few, and the medicament that use cost is low becomes the emphasis that people pay close attention to.
Summary of the invention
Goal of the invention of the present invention is: for the problem of above-mentioned existence, provide a kind of ultra low volume liquids containing ZEN 90160 and sterol synthetic inhibitor.The present invention suppresses as active component so that ZEN 90160 and sterol are synthetic, and composite by with other compositions prepared a kind of ultra low volume liquids.This ultra low volume liquids meets the requirement of ultra low volume spraying, has good drug efficacy, instant effect, lasting period length, safe, resistance of rainwater washing against, water-saving, saving of labor's advantage.Meanwhile, component of the present invention has the effect of Synergistic, and its effect is significantly better than each single dose component.
To achieve these goals, the present invention adopts following technical scheme:
Containing a ultra low volume liquids for ZEN 90160 and sterol synthetic inhibitor, by the component of following percentage by weight, formed:
ZEN 90160 1%～10%,
Sterol synthetic inhibitor 2%～20%,
Auxiliary agent 2%～15%,
Solvent surplus,
Described sterol synthetic inhibitor is the one in Fenarimol, pyrifenox, flumorph, thiophene fluorine bacterium glue, Grandox fumigant, pefurazoate.
Described auxiliary agent be in alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl benzene calcium sulfonate, phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether one or more.
Described solvent is one or more in DMF, methyl-sulfoxide, sulfolane, 1-METHYLPYRROLIDONE, methyl oleate, ethyl oleate, terpineol, repefral, tripropylene glycol butyl ether, n-octyl alcohol, 2-methyl naphthalene, two wires oil, diesel oil, soybean oil, cottonseed oil.
The preparation method of the aforementioned ultra low volume liquids containing ZEN 90160 and sterol synthetic inhibitor, comprise the steps: to take each component by proportioning, solvent is dropped in reactor, and solvent is stirred, in reactor, add ZEN 90160, sterol synthetic inhibitor, simultaneously after ZEN 90160, sterol synthetic inhibitor dissolve completely, in reactor, add remaining ingredient again, continue to stir 15-60 minute, mix, obtain ultra low volume liquids.
The preparation method of the aforementioned ultra low volume liquids containing ZEN 90160 and sterol synthetic inhibitor, comprise the steps: to take each component by proportioning, solvent is dropped in reactor, and solvent is stirred, in reactor, add ZEN 90160, sterol synthetic inhibitor, simultaneously after ZEN 90160, sterol synthetic inhibitor dissolve completely, in reactor, add remaining ingredient again, continue to stir 20-30 minute, mix, obtain ultra low volume liquids.
The present invention can solve conventional spray technique and prevent and treat the defects such as the work efficiency existing in method is low, labour intensity is large, water requirement is large, it is composite by ZEN 90160 (Pyraclostrobin) and sterol synthetic inhibitor, form a kind of ultra low volume liquids, be applicable to hot mist machine spraying.Wherein, sterol synthetic inhibitor is the one in Fenarimol, pyrifenox, flumorph, thiophene fluorine bacterium glue, Grandox fumigant, pefurazoate.
Ultra low volume liquids of the present invention can be applicable to ultra low volume spraying, can be used for preventing and treating crop powdery mildew and the anthracnose such as fruit tree and forest.The advantages such as the present invention has that work efficiency is high, Synergistic, preventive effect are good, simple to operate, water-saving saving of labor, safety and environmental protection.
Compared with prior art, the present invention has the following advantages:
1) ultra low volume liquids product employing high flash solvent of the present invention is material, and the ultra low volume liquids product flash-point of production is high, is in use difficult for catching fire, high to people and crop safety, job safety;
2) the present invention can use the dispenser of hot mist machine, can increase substantially efficiency, improve work efficiency several times to tens times, reduce agricultural cost;
3) the present invention is take ZEN 90160 as main active, and the speed of knocking down is fast, and preventive effect is outstanding, safety and environmental protection, and work efficiency is high, and preventive effect is outstanding;
4) the present invention is simple to operate, and labour intensity is little, can reduce workman's labour intensity;
5) dosage of the present invention is low, water saving, saving of labor, saves time, and can effectively reduce and use cost.
Accompanying drawing explanation
Examples of the present invention will be described by way of reference to the accompanying drawings, wherein:
Fig. 1 is the molecular structure of ZEN 90160.
Embodiment
Disclosed all features in this specification, or the step in disclosed all methods or process, except mutually exclusive feature and/or step, all can combine by any way.
Disclosed arbitrary feature in this specification, unless narration especially all can be replaced by other equivalences or the alternative features with similar object.That is,, unless narration especially, each feature is an example in a series of equivalences or similar characteristics.
The preparation method who adopts in the embodiment of the present invention is as follows: by proportioning, take each component, solvent is dropped in reactor, and solvent is stirred, in reactor, add ZEN 90160, sterol synthetic inhibitor simultaneously, after ZEN 90160, sterol synthetic inhibitor dissolve completely, then add remaining ingredient in reactor, continue to stir 20-30 minute, mix, obtain ultra low volume liquids.
Embodiment 1
Prepare 16% ZEN 90160 Fenarimol ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 1kg,
Fenarimol 15.0kg,
Fatty alcohol-polyoxyethylene ether 3.0 kg,
Alkylphenol polyoxyethylene 6.0 kg,
DMF 5.0 kg,
Methyl oleate 30.0kg,
Tripropylene glycol butyl ether 40kg.
Embodiment 2
Prepare 12% ZEN 90160 Fenarimol ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 10.0 kg,
Fenarimol 2.0kg,
Alkyl benzene calcium sulfonate 3.0 kg,
Alkylphenol polyoxyethylene 4.0 kg,
1-METHYLPYRROLIDONE 20.0 kg,
Ethyl oleate 30.0kg,
Cottonseed oil 31kg.
Embodiment 3
Prepare 8% ZEN 90160 Fenarimol ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 5.0 kg,
Fenarimol 3.0kg,
Phenethyl phenol polyethenoxy ether 4.0 kg,
Alkylphenol polyoxyethylene 4.5 kg,
1-METHYLPYRROLIDONE 35.0 kg,
Tripropylene glycol butyl ether 30.0kg,
Cottonseed oil 18.5kg.
Embodiment 4
Prepare 15% ZEN 90160 pyrifenox ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 10.0 kg,
Pyrifenox 5.0kg,
Castor oil polyoxyethylene ether 4.0 kg,
Phenethyl phenol polyethenoxy ether 3.5 kg,
Methyl-sulfoxide 14.0 kg,
1-METHYLPYRROLIDONE 25.0 kg,
Methyl oleate 12 kg,
2-methyl naphthalene 26.5kg.
Embodiment 5
Prepare 23% ZEN 90160 pyrifenox ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 3.0 kg,
Pyrifenox 20.0 kg,
Phenethyl phenol polyethenoxy ether 5.0 kg,
Fatty alcohol-polyoxyethylene ether 3.5 kg,
Methyl-sulfoxide 20.0 kg,
N-octyl alcohol 12 kg,
Methyl oleate 36.5 kg.
Embodiment 6
Prepare 15% ZEN 90160 pyrifenox ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 8.0 kg,
Pyrifenox 7.0 kg,
Phenethyl phenol polyethenoxy ether 14.0 kg,
Alkylaryl polyoxyethylene polyoxypropylene ether 6.5 kg,
1-METHYLPYRROLIDONE 25.0 kg,
Methyl oleate 12 kg,
Repefral 27.5kg.
Embodiment 7
Prepare 5% ZEN 90160 flumorph ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 2.0 kg,
Flumorph 3.0 kg,
Fatty alcohol-polyoxyethylene ether 4.0 kg,
Alkylaryl polyoxyethylene polyoxypropylene ether 4.0 kg,
1-METHYLPYRROLIDONE 25.0 kg,
Methyl oleate 20.0kg,
Rapeseed oil 42 kg.
Embodiment 8
Prepare 11% ZEN 90160 flumorph azoles ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 9.0 kg,
Flumorph 2.0 kg,
Agriculture breast 600# 5.0 kg,
Phenethyl phenol polyethenoxy ether 4.5 kg,
1-METHYLPYRROLIDONE 30.0 kg,
Terpineol complements to 49.5kg.
Embodiment 9
Prepare 18% ZEN 90160 flumorph ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 3.0 kg,
Flumorph 15.0 kg,
Alkyl phenol formaldehyde resin polyoxyethylene ether 8.0 kg,
Phenethyl phenol polyethenoxy ether 6.5 kg,
Methyl-sulfoxide 25.0 kg,
N-octyl alcohol 12 kg,
Diesel oil 30.5kg.
Embodiment 10
Prepare 10% ZEN 90160 thiophene fluorine bacterium glue ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 5.0 kg,
Thiophene fluorine bacterium glue 5.0 kg,
Fatty alcohol-polyoxyethylene ether 4.0 kg,
Calcium dodecyl benzene sulfonate 4.0 kg,
1-METHYLPYRROLIDONE 25.0 kg,
Two wires oil 20.0 kg,
Repefral 37kg.
Embodiment 11
Prepare 12% ZEN 90160 thiophene fluorine bacterium glue ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 9.0 kg,
Thiophene fluorine bacterium glue 3.0 kg,
Alkyl phenol formaldehyde resin polyoxyethylene ether 4.0 kg,
Phenethyl phenol polyethenoxy ether 5.0 kg,
1-METHYLPYRROLIDONE 30.0 kg,
Cottonseed oil 49kg.
Embodiment 12
Prepare 20% ZEN 90160 thiophene fluorine bacterium glue ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 5.0 kg,
Thiophene fluorine bacterium glue 15.0 kg,
Alkylphenol polyoxyethylene 11.0 kg,
Alkyl benzene calcium sulfonate 4.0 kg,
1-METHYLPYRROLIDONE 30.0 kg,
Two wires oil complements to 35 kg.
Embodiment 13
Prepare 5% ZEN 90160 Grandox fumigant ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 2.0 kg,
Grandox fumigant 3.0 kg,
Fatty alcohol-polyoxyethylene ether 4.0 kg,
Alkylaryl polyoxyethylene polyoxypropylene ether 4.0 kg,
1-METHYLPYRROLIDONE 25.0 kg,
Methyl oleate 20.0kg,
Rapeseed oil 42 kg.
Embodiment 14
Prepare 11% ZEN 90160 Grandox fumigant azoles ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 9.0 kg,
Grandox fumigant 2.0 kg,
Fatty alcohol-polyoxyethylene ether 1.0 kg,
Phenethyl phenol polyethenoxy ether 1.0 kg,
1-METHYLPYRROLIDONE 30.0 kg,
Terpineol 57 kg.
Embodiment 15
Prepare 18% ZEN 90160 Grandox fumigant ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 3.0 kg,
Grandox fumigant 15.0 kg,
Alkyl phenol formaldehyde resin polyoxyethylene ether 8.0 kg,
Phenethyl phenol polyethenoxy ether 6.5 kg,
Methyl-sulfoxide 25.0 kg,
N-octyl alcohol 12 kg,
Methyl oleate 30.5kg.
Embodiment 16
Prepare 22% ZEN 90160 pefurazoate ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 2.0 kg,
Pefurazoate 20.0 kg,
Fatty alcohol-polyoxyethylene ether 4.0 kg,
Alkylaryl polyoxyethylene polyoxypropylene ether 4.0 kg,
1-METHYLPYRROLIDONE 25.0 kg,
Methyl oleate 20.0kg,
Rapeseed oil 25 kg.
Embodiment 17
Prepare 11% ZEN 90160 pefurazoate azoles ultra low volume liquids
In the present embodiment, the quality of each component is as follows:
ZEN 90160 9.0 kg,
Pefurazoate 2.0 kg,
Alkyl benzene calcium sulfonate 5.0 kg,
Phenethyl phenol polyethenoxy ether 4.5 kg,
1-METHYLPYRROLIDONE 30.0 kg,
Terpineol 49.5 kg.
Embodiment 18
Prepare 18% ZEN 90160 pefurazoate ultra low volume liquids
ZEN 90160 3.0 kg,
Pefurazoate 15.0 kg,
Alkyl phenol formaldehyde resin polyoxyethylene ether 8.0 kg,
Phenethyl phenol polyethenoxy ether 6.5 kg,
Methyl-sulfoxide 25.0 kg,
Sulfolane 10.0 kg,
N-octyl alcohol 12 kg,
Methyl oleate 20.5 kg.
It is below field trial.
Test example 1: the ultra low volume liquids of ZEN 90160 and sterol synthetic inhibitor is prevented and treated the field trial of sigatoka
Dispenser place: in the banana garden of Tan Luo town, Nanning
Using method: embodiment ultra low volume spraying, 25% ZEN 90160 EC, 25% Tebuconazole EC spray respectively with conventional workers and peasants' 16 type sprayers., the method for investigation drug effect is: 10 strains are investigated in each community, and every strain is got a point by east, south, west, north, middle direction, every some random searching 2 strains, every strain banana is down investigated 8～13 leaves from top, records total strain number and diseased plant number at different levels, checks the occurrence degree of leaf spot.Result of the test is as shown in table 1, and table 1 is the control efficiency to sigatoka.
The control efficiency of table 1 to sigatoka
Field test results shows, ultra low volume liquids prepared by the embodiment of the present invention can effectively be prevented and treated sigatoka, under approximate equal effective ingredient consumption, and effect and be better than leaf spot specific drug Tebuconazole and the control efficiency of ZEN 90160 single dose.
The present invention is not limited to aforesaid embodiment.The present invention expands to any new feature or any new combination disclosing in this manual, and the arbitrary new method disclosing or step or any new combination of process.
Claims (3)
1. containing a ultra low volume liquids for ZEN 90160 and sterol synthetic inhibitor, it is characterized in that, by the component of following percentage by weight, formed:
ZEN 90160 1%～10%,
Sterol synthetic inhibitor 2%～20%,
Auxiliary agent 2%～15%,
Solvent surplus,
Described sterol synthetic inhibitor is the one in Fenarimol, pyrifenox, flumorph, thiophene fluorine bacterium glue, Grandox fumigant, pefurazoate.
2. contain according to claim 1 the ultra low volume liquids of ZEN 90160 and sterol synthetic inhibitor, it is characterized in that, described auxiliary agent be in alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl benzene calcium sulfonate, phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether one or more.
3. according to the ultra low volume liquids containing ZEN 90160 and sterol synthetic inhibitor described in claim 1 or 2, it is characterized in that, described solvent is one or more in DMF, methyl-sulfoxide, sulfolane, 1-METHYLPYRROLIDONE, methyl oleate, ethyl oleate, terpineol, repefral, tripropylene glycol butyl ether, n-octyl alcohol, 2-methyl naphthalene, two wires oil, diesel oil, soybean oil, cottonseed oil.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310675277.XA CN103719107A (en) | 2013-12-13 | 2013-12-13 | Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor |
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| CN201310675277.XA CN103719107A (en) | 2013-12-13 | 2013-12-13 | Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102349506A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
| CN102657210A (en) * | 2012-05-15 | 2012-09-12 | 玉林师范学院 | Hot fogging concentrate containing pyraclostrobin and sterol synthesis inhibitor |
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- 2013-12-13 CN CN201310675277.XA patent/CN103719107A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102349506A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
| CN102657210A (en) * | 2012-05-15 | 2012-09-12 | 玉林师范学院 | Hot fogging concentrate containing pyraclostrobin and sterol synthesis inhibitor |
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Application publication date: 20140416 |