CN103392740B - Kasugamycin-containing sterilization composition and application thereof - Google Patents
Kasugamycin-containing sterilization composition and application thereof Download PDFInfo
- Publication number
- CN103392740B CN103392740B CN201310317869.4A CN201310317869A CN103392740B CN 103392740 B CN103392740 B CN 103392740B CN 201310317869 A CN201310317869 A CN 201310317869A CN 103392740 B CN103392740 B CN 103392740B
- Authority
- CN
- China
- Prior art keywords
- copper
- composition
- kasugarnycin
- kasugamycin
- disease
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 49
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 title abstract 4
- 230000001954 sterilising effect Effects 0.000 title abstract 3
- 238000004659 sterilization and disinfection Methods 0.000 title abstract 3
- 201000010099 disease Diseases 0.000 claims abstract description 24
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 24
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 10
- 235000009566 rice Nutrition 0.000 claims abstract description 10
- 240000003768 Solanum lycopersicum Species 0.000 claims abstract description 9
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims abstract description 7
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 7
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims abstract description 6
- 241000207199 Citrus Species 0.000 claims abstract description 6
- 241000233866 Fungi Species 0.000 claims abstract description 6
- 235000020971 citrus fruits Nutrition 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 4
- 235000013311 vegetables Nutrition 0.000 claims abstract description 4
- 235000021307 Triticum Nutrition 0.000 claims abstract description 3
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 3
- 239000000375 suspending agent Substances 0.000 claims abstract description 3
- 240000007594 Oryza sativa Species 0.000 claims abstract 4
- 244000241235 Citrullus lanatus Species 0.000 claims abstract 2
- 241000209140 Triticum Species 0.000 claims abstract 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 16
- 241000282376 Panthera tigris Species 0.000 claims description 10
- ZCXLQZOQWCXFNN-UHFFFAOYSA-N copper;hexanedioic acid Chemical compound [Cu].OC(=O)CCCCC(O)=O ZCXLQZOQWCXFNN-UHFFFAOYSA-N 0.000 claims description 10
- 239000003292 glue Substances 0.000 claims description 10
- 241000894006 Bacteria Species 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 208000025865 Ulcer Diseases 0.000 claims description 2
- 231100000397 ulcer Toxicity 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 32
- 239000010949 copper Substances 0.000 abstract description 32
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 25
- 230000000694 effects Effects 0.000 abstract description 20
- 241000196324 Embryophyta Species 0.000 abstract description 6
- 230000001580 bacterial effect Effects 0.000 abstract description 4
- 150000001413 amino acids Chemical class 0.000 abstract description 3
- 229940120693 copper naphthenate Drugs 0.000 abstract description 3
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 abstract description 3
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 abstract description 3
- 208000035143 Bacterial infection Diseases 0.000 abstract description 2
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 abstract 1
- 241000724205 Rice stripe tenuivirus Species 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- HPAXFNMMMBLYJU-UHFFFAOYSA-N copper sulfamic acid Chemical compound [Cu].S(N)(O)(=O)=O HPAXFNMMMBLYJU-UHFFFAOYSA-N 0.000 abstract 1
- MMUFAGXJPKNAHT-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1 MMUFAGXJPKNAHT-UHFFFAOYSA-N 0.000 abstract 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004021 humic acid Substances 0.000 abstract 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- IURRXCRWRKQLGC-UHFFFAOYSA-N copper;quinolin-8-ol Chemical group [Cu].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 IURRXCRWRKQLGC-UHFFFAOYSA-N 0.000 description 9
- 239000003242 anti bacterial agent Substances 0.000 description 7
- 229940088710 antibiotic agent Drugs 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 239000003905 agrochemical Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 241000219109 Citrullus Species 0.000 description 4
- 230000005669 field effect Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 241000186361 Actinobacteria <class> Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003864 humus Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- YWKVMGDEOUPQGN-UHFFFAOYSA-N ethyl 2-[4-[2-(3-hydroxy-1-azabicyclo[2.2.2]octan-3-yl)ethynyl]phenyl]acetate Chemical compound C1=CC(CC(=O)OCC)=CC=C1C#CC1(O)C(CC2)CCN2C1 YWKVMGDEOUPQGN-UHFFFAOYSA-N 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- -1 sodium alkyl benzene Chemical class 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 241000186046 Actinomyces Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 240000001307 Myosotis scorpioides Species 0.000 description 1
- 241000187747 Streptomyces Species 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000001720 action spectrum Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 229940084434 fungoid Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of plant protection, and relates to a kasugamycin-containing sterilization composition and an application thereof. The kasugamycin-containing sterilization composition contains effective amounts of A and B, wherein A is kasugamycin, B is one of oxine-copper, copper(succinate+glutarate+adipate), thiediazole copper, humic acid copper, nitroacid copper, copper naphthenate, amino acid copper, copper acetate and sulfamic acid copper, and the mass fraction ratio of A to B is (10:1)-(1:100). The composition can be processed into wettable powder, water dispersible granules, an aqueous emulsion, a microemulsion and a suspending agent, and the mass sum of A and B accounts for 1-80% of the total mass of the preparation. The composition can be used for preventing and treating fungi and bacterial diseases of multiple plants such as rice, wheat, vegetables and fruit trees and has an excellent effect on late blight and gray mold of tomatoes, rice stripe diseases and rice blast, angular leaf spot of watermelons and citrus bacterial canker diseases.
Description
Technical field
The invention belongs to plant protection field, particularly relate to and contain kasugarnycin and the agriculturally useful compositions that contains copper component, the present composition is controlling plant diseases effectively.
Background technology
In recent years, due to single and Scientific Usage of Drugs not, damage by disease and insect has produced pesticide resistance in various degree, and causes environmental pollution and ecotope increasingly to destroy.Along with the raising of people's living standard and the enhancing of health perception, the development of environmentally friendly agricultural chemicals and exploitation progressively receive agricultural chemicals R&D worker's concern, are the effective ways of improving environment, minimizing or delaying drug resistance and raising drug effect.Wherein, the research and development of highly efficiency compositional agent especially contain one of focus that farm antibiotics bactericidal composition is research.
Farm antibiotics, refer to by microorganism fermentation produce, have agricultural chemicals function, for the secondary metabolites of the anti-pests such as Chinese caterpillar fungus mouse of curing the disease in agricultural.The microorganisms such as actinomycetes, fungi, bacterium all can produce farm antibiotics, and the farm antibiotics that wherein actinomycetes produce is maximum.The many important farm antibiotics of extensive use is at present all that the separated actinomycetes that obtain produce from streptomyces.Farm antibiotics is the earliest streptomycin, and has promoted thus the application of antibiotic in agricultural, has obtained development rapidly after 20 century 70s.Kasugarnycin is the metabolite that a kind of Actinomyces microaureus produces, belong to low toxicity farm antibiotics, it is a kind of interior absorption antibiotic formulations, permeability is strong also can be moved in plant corpus, instant effect after spray medicine, resistance of rainwater washing against, the lasting period is long, having prevention, treatment, growth regulating effect, is the desirable medicament of the crop bacteriums such as control vegetables, melon and fruit and paddy rice and fungal disease.
Cupric active ingredient agricultural chemicals has good preventive and therapeutic effect to common fungoid and bacterial disease.Inventor's discovery, the composition of kasugarnycin and some copper agent has good synergy preventive effect to fungus and bacterium, and fungicidal spectrum is widened.At present, also do not find that kasugarnycin and copper agent are as the report of the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, fatty acid copper, Thiodiazole-copper, nitroacid copper, copper naphthenate, amino acid copper, copper acetate, amine sulfonic acid copper etc.
Summary of the invention
The object of the invention is to improve environment, expand action spectrum, minimizing or delaying drug resistance, raising drug effect, a kind of bactericidal composition that contains kasugarnycin and application are provided.
The present invention is achieved through the following technical solutions:
The bactericidal composition that contains kasugarnycin, it is characterized in that A and B that said composition comprises effective dose, A is kasugarnycin, B is selected from a kind of in copper 8-hydroxyquinolinate, tiger glue adipic acid copper, Thiodiazole-copper, copper humate, nitroacid copper, copper naphthenate, amino acid copper, copper acetate, amine sulfonic acid copper, and the ratio of quality and the number of copies of A and B is 10:1-1:100.Preferably, the ratio of quality and the number of copies of A and B is 1:1-1:50.
Above-mentioned composition of the present invention is processed into wetting powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, and the percentage that A and B quality sum account for preparation gross mass is 1-80%.
Composition of the present invention can be prevented and treated the fungus and bacterium disease of the various plants such as paddy rice, wheat, vegetables, fruit tree, the late blight that preferred disease is tomato and gray mold, stripe disease and rice blast, watermelon angular leaf spot, citrus ulcer.
Composition of the present invention compared with prior art, produces following beneficial effect:
1, purposes is widened: composition can be prevented and treated the multiple diseases of crops.
2, reduce use cost: because composition has the preventive effect of raising, control spectrum increases, reduced agricultural chemicals access times, reduced use cost.
3, delay pesticide resistance: the composition that contains kasugarnycin and copper agent is that the component of different mechanism of action is composite, and disease is difficult for developing immunity to drugs.
4, environmental friendliness: low to people and animals and non-target organism toxicity, in environment, degrade fast, low-residual, free from environmental pollution.
Embodiment
Below described in embodiment only for explaining the present invention, modification, replacement or improvement for not departing from the present invention spirit and principle and making, all belong to the scope of protection of present invention.
Embodiment 115% kasugarnycin copper 8-hydroxyquinolinate water dispersible granules
By kasugarnycin 1g, copper 8-hydroxyquinolinate 14g, naphthalenesulfonate formaldehyde condensation compound 4g, sodium alkyl benzene sulfonate 1.5g, gum Arabic 0.5g, white carbon is supplied 100g and is mixed, mixture is carried out to granulation after ultra-fine grinding, dry, screening, both 15% kasugarnycin copper 8-hydroxyquinolinate water dispersible granules.
Embodiment 230% kasugarnycin tiger glue adipic acid copper wetting powder
Kasugarnycin 1g, tiger glue adipic acid copper 29g, sodium lignin sulfonate 2g, white carbon are supplied to 100g and mix, each component is dry, cooling, levigate, both must be mixed with 30% kasugarnycin tiger glue adipic acid copper wetting powder.
Embodiment 318% kasugarnycin Thiodiazole-copper water dispersible granules
By kasugarnycin 1g, Thiodiazole-copper 17g, naphthalenesulfonate formaldehyde condensation compound 4g, sodium alkyl benzene sulfonate 1.5g, gum Arabic 0.5g, white carbon is supplied 100g and is mixed, mixture is carried out to granulation after ultra-fine grinding, dry, screening, both 18% kasugarnycin Thiodiazole-copper water dispersible granules.
Embodiment 412% kasugarnycin humus copper aqua
Kasugarnycin 2g, humus copper 10g water are fully dissolved, add phenethyl phenol polyethenoxy ether 2g, agriculture breast 500#2g, stir, water complements to 100g, has both obtained 12% kasugarnycin humus copper aqua.
The effect of the bactericidal composition that embodiment 5 contains kasugarnycin to tomato disease
According to scheme, preparation built agent and single dose preparation, and carry out active preliminary experiment.According to determination of activity trial test, preparation is mixed with to the concentration needing.Before test, in tomato field, establish corresponding single dose and blank, at disease initial stage of origination, adopt the conventional conventional spray of manual sprayer, every medicament sprays 50 strains.7-10d dispenser 1 time again after the 1st dispenser.10-20d after the 2nd dispenser, investigates the tomato plant disease situation of listing.Use Abbot formula, convert percentage to preventive effect.
In theoretical effect, x is the effect of the substance A of concentration while being a, and y is the effect of the substance B of concentration while being b, and relatively theoretical effect and actual effect are evaluated the synergy of composition.Composition to the result of tomato plant disease respectively in Table 1.
The field effect of the bactericidal composition that table 1 contains kasugarnycin to tomato disease
As seen from Table 1, kasugarnycin respectively with the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of tomato late blight, gray mold higher than corresponding single dose theoretical effect, show that composition has obvious synergistic function.
The effect of the bactericidal composition that embodiment 6 contains kasugarnycin to rice disease
Testing scheme, with embodiment 5, the results are shown in Table 2.
The field effect of the bactericidal composition that table 2 contains kasugarnycin to rice disease
As seen from Table 2, kasugarnycin respectively with the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of stripe disease and rice blast the theoretical effect higher than corresponding single dose, show that composition has obvious synergistic function.
The effect of the bactericidal composition that embodiment 7 contains kasugarnycin to watermelon angular leaf spot
Testing scheme, with embodiment 5, the results are shown in Table 3.
The field effect of the bactericidal composition that table 3 contains kasugarnycin to watermelon angular leaf spot
As seen from Table 3, kasugarnycin respectively with the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of watermelon angular leaf spot higher than corresponding single dose theoretical effect, show that composition has obvious synergistic function.
The effect of the bactericidal composition that embodiment 8 contains kasugarnycin to citrus bacterial canker disease
Testing scheme, with embodiment 5, the results are shown in Table 4.
The field effect of the bactericidal composition that table 4 contains kasugarnycin to citrus bacterial canker disease
As seen from Table 4, kasugarnycin respectively with the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of citrus bacterial canker disease the theoretical effect higher than corresponding single dose, show that composition has obvious synergistic function.
Claims (4)
1. the bactericidal composition that contains kasugarnycin, is characterized in that A and B that said composition comprises effective dose, and A is kasugarnycin, and B is selected from tiger glue adipic acid copper, and the ratio of quality and the number of copies of A and B is 1:1-1:29.
2. according to the bactericidal composition that contains kasugarnycin of claim 1, composition is processed into wetting powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, and the percentage that A and B quality sum account for preparation gross mass is 1-80%.
3. according to the bactericidal composition that contains kasugarnycin of claim 2, composition can be prevented and treated the fungus and bacterium disease of paddy rice, wheat, vegetables, fruit tree.
4. according to the bactericidal composition that contains kasugarnycin of claim 3, the late blight that disease is tomato and gray mold, stripe disease and rice blast, watermelon angular leaf spot, citrus ulcer.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449654.2A CN104222090B (en) | 2013-07-26 | 2013-07-26 | Bactericidal composition containing kasugarnycin and copper 8-hydroxyquinolinate and application |
| CN201310317869.4A CN103392740B (en) | 2013-07-26 | 2013-07-26 | Kasugamycin-containing sterilization composition and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310317869.4A CN103392740B (en) | 2013-07-26 | 2013-07-26 | Kasugamycin-containing sterilization composition and application thereof |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410449654.2A Division CN104222090B (en) | 2013-07-26 | 2013-07-26 | Bactericidal composition containing kasugarnycin and copper 8-hydroxyquinolinate and application |
| CN201410449688.1A Division CN104255743A (en) | 2013-07-26 | 2013-07-26 | Sterilization composition containing kasugamycin and thiediazole copper and application of sterilization composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103392740A CN103392740A (en) | 2013-11-20 |
| CN103392740B true CN103392740B (en) | 2014-10-29 |
Family
ID=49556653
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310317869.4A Active CN103392740B (en) | 2013-07-26 | 2013-07-26 | Kasugamycin-containing sterilization composition and application thereof |
| CN201410449654.2A Active CN104222090B (en) | 2013-07-26 | 2013-07-26 | Bactericidal composition containing kasugarnycin and copper 8-hydroxyquinolinate and application |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410449654.2A Active CN104222090B (en) | 2013-07-26 | 2013-07-26 | Bactericidal composition containing kasugarnycin and copper 8-hydroxyquinolinate and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN103392740B (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104542601A (en) * | 2013-10-11 | 2015-04-29 | 兴农药业（中国）有限公司 | Pesticide composition containing copper quinolate and kasugamycin and application of pesticide composition |
| CN104094975B (en) * | 2014-07-29 | 2016-09-07 | 海南正业中农高科股份有限公司 | Agriculturally useful compositions containing dithiocyano-methane and application |
| CN104222108B (en) * | 2014-09-02 | 2016-08-24 | 浙江龙湾化工有限公司 | A kind of compound disinfectant containing Thiodiazole-copper |
| CN104255716B (en) * | 2014-09-02 | 2016-08-24 | 浙江龙湾化工有限公司 | A kind of Thiodiazole-copper water dispersible granules and preparation method thereof |
| CN105638686B (en) * | 2014-11-14 | 2019-05-17 | 陕西美邦药业集团股份有限公司 | A kind of combination sterilization composition containing tiger glue adipic acid copper |
| CN104488870B (en) * | 2014-12-24 | 2016-08-17 | 陕西汤普森生物科技有限公司 | A kind of composition pesticide containing bromothalonil |
| CN107232197A (en) * | 2016-03-28 | 2017-10-10 | 陕西韦尔奇作物保护有限公司 | A kind of antibacterial volume increase composition of the ester containing chrysanthemin |
| CN106614705A (en) * | 2016-12-30 | 2017-05-10 | 陕西省蒲城美尔果农化有限责任公司 | Sterilization composition containing oxine-copper and flusilazole |
| CN106614599A (en) * | 2016-12-30 | 2017-05-10 | 陕西省蒲城美尔果农化有限责任公司 | Bactericidal composition containing quinoline copper and kasugamycin |
| CN106973907A (en) * | 2017-03-29 | 2017-07-25 | 兴农药业（中国）有限公司 | A kind of composition pesticide containing copper 8-hydroxyquinolinate and kasugarnycin and its application |
| CN107439551A (en) * | 2017-08-27 | 2017-12-08 | 王章修 | Bactericidal composition containing kasugarnycin and copper rosinate |
| CN109258656A (en) * | 2018-09-30 | 2019-01-25 | 浙江海正化工股份有限公司 | Composition pesticide and its preparation method and application containing Ningnanmycin and copper 8-hydroxyquinolinate |
| CN109430275A (en) * | 2018-10-25 | 2019-03-08 | 中国农业科学院植物保护研究所 | Agricultural bactericide and application with bactericidal activity |
| CN109645023A (en) * | 2019-01-27 | 2019-04-19 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of the copper containing imidazole quinoline |
| CN110537543A (en) * | 2019-06-04 | 2019-12-06 | 广西汇丰生物科技有限公司 | Pesticide composition containing kasugamycin and quinolinone and bactericide |
| CN112998017B (en) * | 2019-12-21 | 2022-06-17 | 浙江新农化工股份有限公司 | Application of composition containing kasugamycin and zinc thiazole in preventing and treating soft rot of dendrobium officinale |
| AR124887A1 (en) * | 2021-02-17 | 2023-05-17 | Upl Corporation Ltd | A SYNERGIC AGRICULTURAL COMPOSITION |
| CN115067344B (en) * | 2021-03-12 | 2024-03-12 | 顺毅股份有限公司 | Pesticide suspending agent compounded by copper quinolinate and kasugamycin |
| CN113647393A (en) * | 2021-07-27 | 2021-11-16 | 惠州市银农科技股份有限公司 | Suspending agent containing kasugamycin and oxine-copper and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101263822A (en) * | 2007-11-25 | 2008-09-17 | 江苏辉丰农化股份有限公司 | Bactericidal composition for preventing and treating rice blast |
| CN102835396A (en) * | 2012-10-03 | 2012-12-26 | 利尔化学股份有限公司 | Sterilization composition, pesticide and application |
| CN102885086A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Kasugamycin and copper chloride wettable powder and preparation process thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102669100B (en) * | 2012-04-20 | 2014-02-26 | 浙江海正化工股份有限公司 | Oxine-copper and validamycin compound pesticide composition and preparation method and application thereof |
-
2013
- 2013-07-26 CN CN201310317869.4A patent/CN103392740B/en active Active
- 2013-07-26 CN CN201410449654.2A patent/CN104222090B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101263822A (en) * | 2007-11-25 | 2008-09-17 | 江苏辉丰农化股份有限公司 | Bactericidal composition for preventing and treating rice blast |
| CN102885086A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Kasugamycin and copper chloride wettable powder and preparation process thereof |
| CN102835396A (en) * | 2012-10-03 | 2012-12-26 | 利尔化学股份有限公司 | Sterilization composition, pesticide and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104222090A (en) | 2014-12-24 |
| CN104222090B (en) | 2016-03-02 |
| CN103392740A (en) | 2013-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103392740B (en) | Kasugamycin-containing sterilization composition and application thereof | |
| CN105028470A (en) | Nematicidal composition containing fosthiazate and application thereof | |
| CN102217621A (en) | Bactericide composition containing pyraclostrobin and copper rosinate | |
| CN101999356A (en) | Sterilization composition containing fluopicolide and metalaxyl and application thereof | |
| CN102696614B (en) | Trifloxystrobin-containing compound pesticide bactericidal composition and preparation | |
| CN104255743A (en) | Sterilization composition containing kasugamycin and thiediazole copper and application of sterilization composition | |
| CN101584329B (en) | 2-cyano-3-amino-3-phenylancryic acetate and propineb-containing synergistic antiseptic composition | |
| CN105123803A (en) | Botanical fungicide containing thymol and kasugamycin | |
| CN104094975B (en) | Agriculturally useful compositions containing dithiocyano-methane and application | |
| CN102138562B (en) | Antibacterial composition containing polyoxin and amide compounds | |
| CN102812964A (en) | Pesticide composition containing thiacloprid and validamycin | |
| CN103651452A (en) | Bactericidal composition containing octyl trichlamide and carbendazim and application of bactericidal composition | |
| CN101194620B (en) | Bactericide agent composition containing tebuconazole | |
| CN102150675A (en) | Bactericidal composition containing captan and thiocatbamate compound | |
| CN102640757B (en) | Compound pesticide sterilization composition containing trifloxystrobin | |
| CN102626081B (en) | Ultralow-volume liquid for preventing and treating oomycetes disease | |
| CN108703145A (en) | A kind of nematicidal composition | |
| CN101536699A (en) | Bactericidal composition | |
| CN101632375B (en) | Pyricularia amide compound sterilization composition | |
| CN103688967A (en) | Weeding composition containing halosulfuron-methyl and pyriftalid | |
| CN112602720A (en) | Bactericide composition containing triphenyltin acetate and difenoconazole and preparation method thereof | |
| CN110800758A (en) | Light calcium carbonate-containing bactericidal composition, preparation method and application thereof | |
| CN109938029A (en) | A kind of fragrant phenoxy phenoxy propionic acid Herbicidal combinations of brassinolide-containing class compound | |
| CN109548789A (en) | The eugenol compound preparation and preparation method and application for preventing and treating tobacco black shank | |
| CN103931620A (en) | Insecticidal composition containing silvchongxian'an and nereistoxin insecticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Kasugamycin-containing sterilization composition and application thereof Effective date of registration: 20160822 Granted publication date: 20141029 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2016460000002 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20190605 Granted publication date: 20141029 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2016460000002 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Kasugamycin-containing sterilization composition and application thereof Effective date of registration: 20190617 Granted publication date: 20141029 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2019460000007 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP03 | Change of name, title or address |
Address after: Fuchang Village, Laocheng Development Zone, Chengmai County, Hainan Province, 571923 Patentee after: Hainan Zhengye Biotechnology Co.,Ltd. Address before: 571924 Fuchang village, Laocheng Development Zone, Chengmai County, Hainan Province Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |
|
| CP03 | Change of name, title or address |