CN105638686B - A kind of combination sterilization composition containing tiger glue adipic acid copper - Google Patents
A kind of combination sterilization composition containing tiger glue adipic acid copper Download PDFInfo
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Abstract
The invention discloses a kind of combination sterilization compositions containing tiger glue adipic acid copper, effective component is the bactericidal composition of active components A and active constituent B, wherein active components A is tiger glue adipic acid copper, active constituent B is selected from any one following compound: gold alloy hydride, Ningnanmycin, doxycycline monohydrate, and active components A and the weight ratio of active constituent B are 1 ︰, 80~80 ︰ 1.The present composition has synergistic effect to the multiple diseases for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the pesticide on crop, alleviate environmental pollution, to safety of human and livestock, Environmental compatibility is good, and disease is not likely to produce drug resistance.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of combination sterilization composition containing tiger glue adipic acid copper in crop disease
Application in evil.
Background technique
Tiger glue adipic acid copper (Copper (succinate+glutarate+adipate)), cures mainly bacterial diseases of plants, copper
Ion is exchanged with the cation in pathogen film surface, makes the protein coagulating on pathogen cell membrane, while part copper ion
Pathogen is penetrated into the cell in conjunction with certain enzymes, influences its activity.It can be used for preventing and treating cucumber bacterial angular leaf spot, and to plant
Object grows irritating effect.
Gold alloy hydride, Ningnanmycin, doxycycline monohydrate belong to common fungicide, are widely used in the disease of crops.
However, in the real process of agricultural production, the problem of controlling disease most easily produces is the production of disease drug resistance
It is raw.Different cultivars ingredient is compounded, and is to prevent and treat the very common method of resistance disease.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy, adduction or antagonism.In most cases, the compounding effect of sterilization
All be additive effect, really have the compounding of synergistic effect seldom, especially synergistic effect clearly, synergy ratio it is very high multiple
With just less.It is studied by inventor, after discovery compounds tiger glue adipic acid copper with gold alloy hydride, Ningnanmycin, doxycycline monohydrate
Good synergistic effect can be generated, and is compounded with gold alloy hydride, Ningnanmycin, doxycycline monohydrate about tiger glue adipic acid copper related
Report not yet discloses.
Summary of the invention
The purpose of the present invention is to propose to a kind of with synergistic function, use cost is low, preventive effect is good contains tiger glue adipic acid
The combination sterilization composition of copper.
Combination sterilization composition effective component proposed by the present invention containing tiger glue adipic acid copper is active components A and active constituent
B, activity is divided into A and active constituent B weight ratio is 1 ︰, 80~80 ︰ 1, and the active components A is tiger glue adipic acid copper, active constituent
B is planted selected from one of gold alloy hydride, Ningnanmycin, doxycycline monohydrate, and active components A and the preferred weight ratio of active constituent B are 1 ︰
50~50 ︰ 1;More preferably the weight ratio of tiger glue adipic acid copper and gold alloy hydride is 1 ︰, 25~30 ︰ 1, and tiger glue adipic acid copper is mould with Ningnan
The weight ratio of element is 1 ︰, 25~30 ︰ 1, and the weight ratio of tiger glue adipic acid copper and doxycycline monohydrate is 1 ︰, 25~25 ︰ 1.
Combination sterilization composition proposed by the present invention containing tiger glue adipic acid copper is used to prevent and treat the purposes of disease on crops, institute
The crops stated include cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit
Crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop, green manure pasture crop;Institute
The disease stated be canker, angular leaf spot, anthracnose, false smut, powdery mildew, root rot, virosis, spot defoliation, damping-off,
Leaf blight or soft rot.
Active components A, the weight ratio of active constituent B are 1 ︰, 80~80 ︰ 1.The weight hundred of active component in usual composition
Divide content for the 0.5%~90% of total weight, preferably 5%~80%.According to different preparation types, active component content
Range is different.In general, liquid preparation contains by weight 1%~70% active material, preferably 5%~50%;
Solid pharmaceutical preparation contains by weight 5%~80% active material, preferably 10%~80%.
In bactericidal composition of the invention at least contain a kind of surfactant, in favor of application when active component in water
Dispersion.Surface-active contents are the 5%~30% of total formulation weight, and surplus is solid or liquid diluent.
Bactericidal composition of the invention can used before through dilution or directly by user.Its preparation can be by usual
Processing method known in those skilled in the art preparation, i.e., after active material being mixed with liquid solvent or solid carrier,
Add one or more of surfactant such as dispersing agent, wetting agent, binder, defoaming agent, disintegrating agent, antifreeze etc..
Bactericidal composition of the invention can be processed into acceptable dosage form in any sterilization, wherein more preferably as needed
Dosage form be that wettable powder, water dispersible granules, suspending agent, suspoemulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, micro-capsule are outstanding
Aqua, soluble powder, soluble granula, seed coat agent, kind clothing suspending agent can also be made in floating-suspending agent.
Comprising following constituent content when wettable powder is made in composition: active components A 0.1%~80%, active constituent
B0.1%~80%, dispersing agent 2%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when water dispersible granules are made: active components A 0.1%~80%, active constituent
B0.1%~80%, dispersing agent 3%~12%, wetting agent 1%~8%, disintegrating agent 1%~10%, binder 0~8%, filler
Surplus.
Composition includes following constituent content when suspending agent is made: active components A 0.1%~50%, active constituent
B0.1%~50%, dispersing agent 2%~10%, wetting agent 2%~10%, defoaming agent 0.01%~2%, thickener 0~2%,
Antifreeze 0~8%, deionized water or vegetable oil add to 100%.
Composition includes following constituent content when suspoemulsion is made: active components A 0.1%~50%, active constituent
B0.1%~50%, dispersing agent 2%~10%, defoaming agent 0.01%~2%, solvent 1%~15%, thickener 0~2%, cream
Agent 2%~12%, antifreeze 0~8%, deionized water add to 100%.
Comprising following constituent content when aqueous emulsion is made in composition: active components A 0.1%~50%, active constituent
B0.1%~50%, solvent 1%~30%, emulsifier 1%~15%, antifreeze 0~8%, thickener 0~2%, defoaming agent
0.01%~2%, deionized water supplies surplus.
Comprising following constituent content when microemulsion is made in composition: active components A 0.1%~50%, active constituent
B0.1%~50%, emulsifier 3%~25%, antifreeze 0~8%, defoaming agent 0.01%~2%, is gone solvent 1%~30%
Ionized water supplies surplus.
Composition includes following constituent content when microcapsule suspending agent is made: active components A 0.1%~50%, active constituent
B0.1%~50%, macromolecule cyst material 2%~10%, dispersing agent 1%~10%, organic solvent 1%~10%, emulsifier
1%~7%, defoaming agent 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
Composition includes following constituent content when microcapsule suspension-suspendinagent agent is made: active components A 0.1%~50%, activity
It is ingredient B0.1%~50%, macromolecule cyst material 2%~10%, dispersing agent 1%~12%, wetting agent 1%~8%, organic
Solvent 1%~15%, emulsifier 1%~6%, defoaming agent 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~
5%, deionized water adds to 100%.
Wettable powder the key technical indexes of the invention:
Water dispersible granules the key technical indexes of the invention:
Suspending agent the key technical indexes of the invention:
Suspoemulsion the key technical indexes of the invention:
Aqueous emulsion the key technical indexes of the invention:
Microemulsion the key technical indexes of the invention:
Microcapsule suspending agent the key technical indexes of the invention:
Microcapsule suspension-suspendinagent agent the key technical indexes of the invention:
The present invention has the advantages that
(1) after tiger glue adipic acid copper is compounded with gold alloy hydride, Ningnanmycin, doxycycline monohydrate, there is apparent synergy and holding effect
Effect;(2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop,
Have a liking for crop, root crop, oil crops, flower crop, medicinal crop, crop, the disease on green manure pasture crop
There is greater activity;(3) reduce pesticide usage amount, reduce residual quantity of the pesticide on crop, alleviate environmental pollution;
(4) to safety of human and livestock, Environmental compatibility is good;And preparation adhesion strength enhances, resistance of rainwater washing against.
Specific embodiment
Below with reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The present invention is not limited thereto.
Application Example one
Examples 1 to 10 wettable powder
Tiger glue adipic acid copper, active constituent B, dispersing agent, wetting agent, filler are uniformly mixed in mixed cylinder, through air-flow powder
Broken machine remixes uniformly after crushing, and can be prepared by wettable powder product of the present invention, is specifically shown in Table 1.
1 Examples 1 to 10 each component of table and parts by weight
11~20 water dispersible granules of embodiment
Tiger glue adipic acid copper, active constituent B, dispersing agent, wetting agent, disintegrating agent, filler etc. are obtained through air-flow crushing together
The partial size needed adds other auxiliary agents such as binder (can add can be not added), obtains granulation materials.Item is quantified into feeding fluidisation
In bed granulating drier after granulation and drying, it can be prepared by water dispersible granules product of the present invention, be specifically shown in Table 2.
2 embodiment of table, 11~20 each component and parts by weight
21~27 suspending agent of embodiment
By dispersing agent, wetting agent, defoaming agent, thickener (can add can be not added), antifreeze (can add can be not added), by high speed
Shear-mixed is uniform, tiger glue adipic acid copper, active constituent B is added, ball milling 2~3 hours, make diameter of particle all exist in the ball mill
5 μm hereinafter, surplus is supplied with deionized water or vegetable oil, can be prepared by suspending agent product of the present invention, specifically be shown in Table 3.
3 embodiment of table, 21~27 each component and parts by weight
Gold alloy hydride, Ningnanmycin, doxycycline monohydrate in table 1~3 are exchanged, novel formulation can be made.
28~30 suspoemulsion of embodiment
Dispersing agent, defoaming agent, thickener (can add can be not added), antifreeze (can add can be not added) are mixed by high speed shear
Uniformly, tiger glue adipic acid copper is added, in the ball mill ball milling 2~3 hours, makes diameter of particle all at 5 μm hereinafter, amber glue fertilizer is made
Sour copper suspending agent, it is then that active constituent B, solvent (can add can be not added), emulsifier and various auxiliary agent high speed agitators is direct
It emulsifies in suspending agent, surplus is supplied with deionized water, and suspoemulsion product of the present invention is made, is specifically shown in Table 4.
4 embodiment of table, 28~30 each component and parts by weight
31~38 aqueous emulsion of embodiment
Tiger glue adipic acid copper, active constituent B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase;By deionization
Water, antifreeze (can add can be not added), thickener (can add can be not added), defoaming agent mix, Cheng Junyi water phase.In high-speed stirring
It mixes down, oily phase is added in water phase, surplus is supplied with deionized water;It can be prepared by aqueous emulsion product of the present invention, be specifically shown in
Table 5.
5 embodiment of table, 31~38 each component and parts by weight
Gold alloy hydride, Ningnanmycin, doxycycline monohydrate in table 5 are exchanged, novel formulation can be made.
39~41 microemulsion of embodiment
Tiger glue adipic acid copper, active constituent B, solvent, emulsifier, antifreeze (can add can be not added), defoaming agent are sufficiently mixed
At the oily phase of homogeneous transparent, it is slowly added into deionized water under stiring, forms WO emulsion, then agitated heating, makes
Rapid phase inversion at oil-in-water type, be cooled to room temperature and make up to balance, through filtering, surplus is supplied with deionized water;It can be prepared by
Microemulsion product of the present invention, is specifically shown in Table 6.
6 embodiment of table, 39~41 each component and parts by weight
Embodiment 42,43 microcapsule suspending agents
Tiger glue adipic acid copper, active constituent B, macromolecule cyst material, solvent are mixed, makes to be dissolved into homogeneous oil phase, cut
Under tangent condition, by oil be added to containing emulsifier, pH adjusting agent, dispersing agent aqueous phase solution in, surplus is mended with deionized water
Foot, two kinds of materials react in oil-water interfaces, form high score ascus wall, and it is outstanding that the well dispersed micro-capsule of the present composition is made
Floating agent product.Specifically it is shown in Table 7.
7 embodiment 42 of table, 43 each components and parts by weight
Embodiment 44,45 microcapsule suspension-suspendinagent agents
Active constituent B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oily mutually in shearing condition
Under be added to containing emulsifier, pH adjusting agent aqueous phase solution in, well dispersed microcapsule suspending agent is made.By dispersing agent, wet
Profit agent, defoaming agent, thickener (can add can be not added) are uniformly mixed by high speed shear, tiger glue adipic acid copper are added, in the ball mill
Ball milling 2~3 hours, makes diameter of particle all at 5 μm hereinafter, suspending agent is made, suspending agent is then added to microcapsules and is suspended
In the aqueous phase solution of agent, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent of the present composition is made and produces
Product.Specifically it is shown in Table 8.
8 example 44 of table, 45 each components or its content
The embodiment of the present invention is the method combined using indoor toxicity test and field trial.First pass through indoor virulence survey
It is fixed, the synergy ratio (SR) after two kinds of medicaments compound by a certain percentage is defined, SR < 0.5 is antagonism, 0.5≤SR≤1.5
For summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field trial.
Test method: after prerun determines the effective inhibition concentration range of each medicament, medicament sets 5 by active constituent content respectively
A dosage processing, if clear water compares.It is carried out referring to " farm-chemical indoor determination test rule fungicide ", speed is grown using mycelia
Rate method measures medicament to the virulence of crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm (x), with minimum
Square law acquires virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley method
Two medicament different ratio synergy ratios (SR) are calculated, SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action,
SR > 1.5 is synergistic effect.Calculation formula is as follows:
Wherein: a, b are respectively active components A and active constituent B ratio shared in combination;
A is tiger glue adipic acid copper;
B is planted selected from one of gold alloy hydride, Ningnanmycin, doxycycline monohydrate.
Application Example two
For trying disease: mandarin tree canker
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design: tiger glue adipic acid copper and gold alloy hydride raw medicine and the two different ratio mixture are determined by preliminary experiment
Effective inhibition concentration range.
9 tiger glue adipic acid copper of table compounds the toxicity test analysis of results table to mandarin tree canker with gold alloy hydride
As shown in Table 9, tiger glue adipic acid copper and gold alloy hydride match the synergy in 1 80~80 ︰ 1 of ︰ to mandarin tree canker
Ratio SR is all larger than 1.5, both illustrates that mixture shows synergistic effect in 1 ︰, 80~80 ︰, 1 range, when tiger glue adipic acid copper with
For the proportion of gold alloy hydride in 1 25~30 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is 2.30 or more.It is tried through applicant
The optimum ratio for issuing after examination and approval existing tiger glue adipic acid copper and gold alloy hydride is 30:1,25:1,20:1,15:1,10:1,5:1,4:1,3:1,2:
1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:13,1:15,1:20,1:25, especially
It is that synergy ratio is maximum when tiger glue adipic acid copper is 2:1 with gold alloy hydride weight ratio, synergistic effect is the most obvious.
Application Example three
For trying disease: tomato virus disease
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design: tiger glue adipic acid copper and Ningnanmycin raw medicine and the two different ratio mixture are determined by preliminary experiment
Effective inhibition concentration range.
10 tiger glue adipic acid copper of table compounds the toxicity test analysis of results table to tomato virus disease with Ningnanmycin
As shown in Table 10, tiger glue adipic acid copper and Ningnanmycin are matched in 1 80~80 ︰ 1 of ︰ to the synergic ratio of tomato virus disease
Value SR is all larger than 1.5, illustrates that the two mixture in 1 ︰, 80~80 ︰, 1 range shows synergistic effect, when tiger glue adipic acid copper and rather
For the proportion of southern mycin in 1 25~30 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is 2.25 or more.It is tested through applicant
It was found that the optimum ratio of tiger glue adipic acid copper and Ningnanmycin be 30:1,25:1,20:1,15:1,10:1,5:1,4:1,3:1,2:1,
1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:13,1:15,1:20,1:25, especially
When tiger glue adipic acid copper and Ningnanmycin weight ratio are 4:1, synergy ratio is maximum, and synergistic effect is the most obvious.
Application Example four
For trying disease: soft rot of cabbage
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design: tiger glue adipic acid copper and doxycycline monohydrate raw medicine and the two different ratio mixture are determined by preliminary experiment
Effective inhibition concentration range.
11 tiger glue adipic acid copper of table compounds the toxicity test analysis of results table to soft rot of cabbage with doxycycline monohydrate
As shown in Table 11, tiger glue adipic acid copper and doxycycline monohydrate are matched in 1 80~80 ︰ 1 of ︰ to the synergic ratio of soft rot of cabbage
Value SR is all larger than 1.5, illustrates that the two mixture in 1 ︰, 80~80 ︰, 1 range shows synergistic effect, when tiger glue adipic acid copper and water
For the proportion of syntomycin in 1 25~25 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is 2.30 or more.It is tested through applicant
It was found that the optimum ratio of tiger glue adipic acid copper and doxycycline monohydrate be 25:1,20:1,15:1,10:1,5:1,4:1,3:1,2:1,1:1,
2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:13,1:15,1:20,1:25 especially work as amber
Synergy ratio is maximum when glue adipic acid copper and doxycycline monohydrate weight ratio are 1:1, and synergistic effect is the most obvious.
It is found through experiment that: tiger glue adipic acid copper compounded with active constituent B after to the canker in various crop, angular leaf spot, charcoal
The prevention and treatment of subcutaneous ulcer disease, false smut, powdery mildew, root rot, virosis, spot defoliation, damping-off, leaf blight or soft rot has bright
Aobvious synergistic effect, synergy ratio SR are all larger than 1.5.
Effect experiment part: test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., is provided, 30% amber glue of comparison medicament
Adipic acid copper suspending agent (autogamy), 30% gold alloy hydride wettable powder (autogamy), 2% Ningnanmycin aqua (autogamy), 88% water
Syntomycin soluble powder (autogamy).
Five tiger glue adipic acid copper of Application Example and active constituent B and its compound prevention and treatment angular leaf spot of cucumber pharmacodynamic test.
This test arrangement investigates angular leaf spot of cucumber disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease
Phase application, 3 days after application, 7 days, 15 days investigation disease indexes and calculate preventive effect.Test result is as follows:
12 tiger glue adipic acid copper of table and active constituent B and its compound prevention and treatment angular leaf spot of cucumber pharmacodynamic test
As can be seen from Table 12, angular leaf spot of cucumber can be effectively prevented after tiger glue adipic acid copper is compounded with active constituent B, through applying
People, which tests after discovery tiger glue adipic acid copper is compounded with active constituent B, can also effectively prevent powdery mildew of cucumber, virosis, control efficiency
It is above 96%, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in test scope of medication to target crop.
Six tiger glue adipic acid copper of Application Example and active constituent B and its compound prevention and treatment soft rot of cabbage pharmacodynamic test.
This test arrangement investigates soft rot of cabbage disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease
Phase application, 5 days after application, 15 days, 30 days investigation disease indexes and calculate preventive effect.Test result is as follows:
13 tiger glue adipic acid copper of table and active constituent B and its compound prevention and treatment soft rot of cabbage pharmacodynamic test
As can be seen from Table 13, soft rot of cabbage can be effectively prevented after tiger glue adipic acid copper is compounded with active constituent B, through applying
People, which tests after discovery tiger glue adipic acid copper is compounded with active constituent B, can also effectively prevent Chinese cabbage anthracnose, and control efficiency is above
96%, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in test scope of medication to target crop.
Seven tiger glue adipic acid copper of Application Example and active constituent B and its compound prevention and treatment rice green smut pharmacodynamic test.
This test arrangement investigates rice green smut disease index before Shaanxi Province Hanzhong suburban area, medicine, occurs just in disease
Phase application, 3 days after application, 7 days, 15 days investigation disease indexes and calculate preventive effect.Test result is as follows:
14 tiger glue adipic acid copper of table and active constituent B and its compound prevention and treatment rice green smut pharmacodynamic test
As can be seen from Table 14, tiger glue adipic acid copper and active constituent B and its prevention and treatment rice green smut is compounded, is tried through applicant
Rice seedling blight, leaf blight can also be effectively prevented by issuing after examination and approval after existing tiger glue adipic acid copper is compounded with active constituent B, and control efficiency is high
In 97%, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in test scope of medication to target crop.
Eight tiger glue adipic acid copper of Application Example and active constituent B and its compound prevention and treatment mandarin tree canker pharmacodynamic test.
This test arrangement investigates mandarin tree canker disease index before Shaanxi Province Hanzhong suburban area, medicine, occurs in disease
Initial stage application, 3 days after application, 10 days, 20 days investigation disease indexes and calculate preventive effect.Test result is as follows:
15 tiger glue adipic acid copper of table and active constituent B and its compound prevention and treatment mandarin tree canker pharmacodynamic test
As can be seen from Table 15, mandarin tree canker can be effectively prevented after tiger glue adipic acid copper is compounded with active constituent B, through Shen
It asks someone that mandarin tree powdery mildew can also be effectively prevented after test discovery tiger glue adipic acid copper is compounded with active constituent B, control efficiency is equal
Higher than 95%, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in test scope of medication to target crop.
Nine tiger glue adipic acid copper of Application Example and active constituent B and its compound prevention and treatment apple peels and cores drug effect examination
It tests.
This test arrangement investigates apple peels and cores disease index before Xianyang, Shanxi province suburban area, medicine, in disease
Early period of origination application, 3 days after application, 10 days, 20 days investigation disease indexes and calculate preventive effect.Test result is as follows:
16 tiger glue adipic acid copper of table and active constituent B and its compound prevention and treatment apple peels and cores pharmacodynamic test
As can be seen from Table 16, energy effectively preventing and treating apple-tree spot defoliation after tiger glue adipic acid copper is compounded with active constituent B,
Through applicant test discovery tiger glue adipic acid copper compounded with active constituent B after can also with effectively preventing and treating apple-tree powdery mildew, anthracnose,
Root rot, control efficiency are above 95%, and better than the preventive effect of single dose, and preventive effect phase is long.Target is made in test scope of medication
Object has no adverse effects.
The test by different places throughout the country obtains afterwards, and tiger glue adipic acid copper is compounded with gold alloy hydride, Ningnanmycin
Afterwards in various crop canker, angular leaf spot, anthracnose, false smut, powdery mildew, root rot, virosis, spot defoliation,
The preventive effect of the Common Diseases such as damping-off, leaf blight or soft rot 95% or more, is better than single dose preventive effect, and synergistic effect is obvious.
Claims (6)
1. a kind of combination sterilization composition containing tiger glue adipic acid copper, effective active composition is active components A and active constituent B,
Be characterized in that: active components A is 1 ︰, 80~80 ︰ 1 with active constituent B weight ratio, and the active components A is tiger glue adipic acid copper,
Active constituent B is Ningnanmycin.
2. the combination sterilization composition according to claim 1 containing tiger glue adipic acid copper, it is characterised in that: active components A with
The weight ratio of active constituent B is 1 ︰, 50~50 ︰ 1.
3. the combination sterilization composition according to claim 2 containing tiger glue adipic acid copper, it is characterised in that: tiger glue adipic acid copper with
The weight ratio of Ningnanmycin is 1 ︰, 25~30 ︰ 1.
4. the combination sterilization composition according to any one of claim 1 to 3 containing tiger glue adipic acid copper, it is characterised in that:
Wettable powder, water dispersible granules, suspending agent, suspoemulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or micro-capsule is made in composition
Suspension-suspending agent.
5. the use that the combination sterilization composition according to claim 4 containing tiger glue adipic acid copper is used to prevent and treat disease on crops
On the way.
6. purposes according to claim 5, it is characterised in that: the disease is canker, angular leaf spot, anthracnose, rice
Bent disease, powdery mildew, root rot, virosis, spot defoliation, damping-off, leaf blight or soft rot.
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MXPA01011718A (en) * | 2001-11-15 | 2003-05-23 | Lapisa S A De C V | Fungicide and bactericide composition for plants. |
CN103392740A (en) * | 2013-07-26 | 2013-11-20 | 海南正业中农高科股份有限公司 | Kasugamycin-containing sterilization composition and application thereof |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Applicant after: Shaanxi Mei Bang Pharmaceutical Group Limited by Share Ltd Address before: 715500 Industrial Park of Agrochemical Base, Pucheng County, Shaanxi Province, Weinan City, Shaanxi Province Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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