CN104161042B - A kind of composition pesticide of fluorine-containing azoles bacterium aniline and methoxy acrylic - Google Patents
A kind of composition pesticide of fluorine-containing azoles bacterium aniline and methoxy acrylic Download PDFInfo
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- CN104161042B CN104161042B CN201310187658.3A CN201310187658A CN104161042B CN 104161042 B CN104161042 B CN 104161042B CN 201310187658 A CN201310187658 A CN 201310187658A CN 104161042 B CN104161042 B CN 104161042B
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- azoles bacterium
- bacterium aniline
- fluorine
- active ingredient
- disease
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- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 title claims abstract description 194
- 241000894006 Bacteria Species 0.000 title claims abstract description 108
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 239000000575 pesticide Substances 0.000 title claims abstract description 29
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 19
- 239000011737 fluorine Substances 0.000 title claims abstract description 19
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 150000003851 azoles Chemical class 0.000 title claims abstract description 13
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical class [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 claims abstract description 80
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 58
- 201000010099 disease Diseases 0.000 claims abstract description 55
- 239000004480 active ingredient Substances 0.000 claims abstract description 53
- -1 phenylsulfonyl ester Chemical class 0.000 claims abstract description 23
- 239000000375 suspending agent Substances 0.000 claims description 20
- 235000007164 Oryza sativa Nutrition 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000003094 microcapsule Substances 0.000 claims description 13
- 235000009566 rice Nutrition 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 241000221785 Erysiphales Species 0.000 claims description 8
- 206010039509 Scab Diseases 0.000 claims description 8
- 239000004563 wettable powder Substances 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 241000918585 Pythium aphanidermatum Species 0.000 claims description 5
- 230000035613 defoliation Effects 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 241001530056 Athelia rolfsii Species 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims 1
- 208000025865 Ulcer Diseases 0.000 claims 1
- 239000002775 capsule Substances 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- 238000007920 subcutaneous administration Methods 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 31
- 239000003814 drug Substances 0.000 abstract description 28
- 239000005784 Fluoxastrobin Substances 0.000 abstract description 18
- 239000005869 Pyraclostrobin Substances 0.000 abstract description 18
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 abstract description 18
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 abstract description 18
- 239000005857 Trifloxystrobin Substances 0.000 abstract description 17
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 abstract description 17
- 150000001875 compounds Chemical class 0.000 abstract description 12
- 229940079593 drug Drugs 0.000 abstract description 9
- 238000012271 agricultural production Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 244000144972 livestock Species 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 38
- 238000013329 compounding Methods 0.000 description 31
- 230000003449 preventive effect Effects 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000012071 phase Substances 0.000 description 20
- 241000233679 Peronosporaceae Species 0.000 description 14
- 230000002265 prevention Effects 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 13
- 241000209094 Oryza Species 0.000 description 12
- 239000002518 antifoaming agent Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000000470 constituent Substances 0.000 description 9
- 240000008067 Cucumis sativus Species 0.000 description 8
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 8
- 240000008042 Zea mays Species 0.000 description 8
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 8
- 230000002528 anti-freeze Effects 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 235000009973 maize Nutrition 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 231100000820 toxicity test Toxicity 0.000 description 6
- 241000207199 Citrus Species 0.000 description 5
- 206010067482 No adverse event Diseases 0.000 description 5
- 240000001987 Pyrus communis Species 0.000 description 5
- 235000014443 Pyrus communis Nutrition 0.000 description 5
- 241000209140 Triticum Species 0.000 description 5
- 235000021307 Triticum Nutrition 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 230000010165 autogamy Effects 0.000 description 5
- 235000020971 citrus fruits Nutrition 0.000 description 5
- 238000013401 experimental design Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 206010011732 Cyst Diseases 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000011149 active material Substances 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UXPRZZZNGFVXRR-UHFFFAOYSA-N 2,3-difluoro-1h-pyrrole Chemical class FC=1C=CNC=1F UXPRZZZNGFVXRR-UHFFFAOYSA-N 0.000 description 1
- GOFJDXZZHFNFLV-UHFFFAOYSA-N 5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]pyrazole-4-carboxamide Chemical compound CC(C)CC(C)C1=CC=CC=C1NC(=O)C1=C(F)N(C)N=C1C GOFJDXZZHFNFLV-UHFFFAOYSA-N 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 208000031968 Cadaver Diseases 0.000 description 1
- 108010075028 Cytochromes b Proteins 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000510928 Erysiphe necator Species 0.000 description 1
- 239000005800 Kresoxim-methyl Substances 0.000 description 1
- 239000005815 Penflufen Substances 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 241000813090 Rhizoctonia solani Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 102000019259 Succinate Dehydrogenase Human genes 0.000 description 1
- 108010012901 Succinate Dehydrogenase Proteins 0.000 description 1
- 241000031845 Tilletia laevis Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000027721 electron transport chain Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000035806 respiratory chain Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of fluorine-containing azoles bacterium aniline and the composition pesticide of methoxy acrylic, effective active composition is active components A and active ingredient B, and wherein active components A is selected from fluorine azoles bacterium aniline, and active ingredient B is selected from any one following compound：Pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, fluoxastrobin or ZEN 90160, and active components A and the weight ratio of active ingredient B are 1 ︰, 80~80 ︰ 1.The present composition has synergistic effect to the multiple diseases for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the pesticide on crop, alleviate environmental pollution, to safety of human and livestock, Environmental compatibility is good, and disease is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to the pesticide group of a kind of fluorine-containing azoles bacterium aniline and methoxy acrylic
Close application of the object on corps diseases.
Background technology
Fluorine azoles bacterium aniline（penflufen）：Molecular formula is C18H24FN3O, chemical name are 2 ＇-[(RS) -1,3- dimethyl
Butyl] fluoro- 1, the 3- dimethyl pyrazoles -4- formailides of -5-, fluorine azoles bacterium aniline is a kind of succinate dehydrogenase inhibitors, mainly
Respiratory chain electron transmission Complex II is acted on, blocks energetic supersession.Kind of a biography can be prevented, the basidiomycetes and ascomycosis that soil passes
Evil, black scurf of potato, wheat sharp eyespot, rice sheath blight disease, sclerotinia sclerotiorum etc. caused by mainly having rhizoctonia also have wheat
Smut, the bunt of wheat, corn southern leaf blight etc..Treated, and seed can absorb fluorine azoles bacterium benzene in germination process
Amine is transmitted to other positions of plant by xylem, plays the role of cover crop.
Pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, fluoxastrobin or ZEN 90160 belong to methoxy acrylic and kill
Microbial inoculum, this kind of fungicidal activity is high, wide sterilization spectrum, and environmentally friendly, acts on the electron transport chain of fungal mitochondria
Compound III, prevent electron transmission, inhibit energy synthesis.Since action site is single, the resistance to the action of a drug, resistance to the action of a drug machine are also easy to produce
System is mainly that point mutation occurs on cytochrome b gene sequence.
However, in the real process of agricultural production, controlling disease is easiest to generate the problem that the production of disease drug resistance
It is raw.Different cultivars ingredient is compounded, and is to prevent the very common method of resistance disease.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy, adduction or antagonism.In most cases, the compounding effect of sterilization
All it is additive effect, the compounding for really having synergistic effect is seldom, and especially synergistic effect is clearly, synergy ratio is very high answers
With just less.It studies, is found fluorine azoles bacterium aniline and pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, the phonetic bacterium of fluorine by inventor
Can generate good synergistic effect after ester or ZEN 90160 compounding, and on fluorine azoles bacterium aniline and pyraclostrobin, trifloxystrobin,
The relevant report of phenylsulfonyl ester, fluoxastrobin or ZEN 90160 compounding not yet discloses.
The content of the invention
There is synergistic function, the fluorine-containing azoles bacterium benzene that use cost is low, preventive effect is good the purpose of the present invention is to propose to a kind of
The composition pesticide of amine and methoxy acrylic.
Active ingredient is work in the composition pesticide of fluorine-containing azoles bacterium aniline and methoxy acrylic proposed by the present invention
Property ingredient A and active ingredient B, active components A and active ingredient B weight ratios are 1 ︰, 80~80 ︰ 1, and the active components A is selected from
Fluorine azoles bacterium aniline, active ingredient B are selected from one of pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, fluoxastrobin or ZEN 90160
Kind, active components A is 1 ︰, 60~60 ︰ 1 with the preferred weight ratios of active ingredient B；More preferably fluorine azoles bacterium aniline and pyrazoles ether bacterium
Ester or trifloxystrobin or the weight ratio of fluoxastrobin are 1 ︰, 25~25 ︰ 1, the weight ratio of fluorine azoles bacterium aniline and phenylsulfonyl ester for 1 ︰ 15~
The weight ratio of 30 ︰ 1, fluorine azoles bacterium aniline and ZEN 90160 is 1 ︰, 30~25 ︰ 1；Most preferably fluorine azoles bacterium aniline and pyraclostrobin
Or trifloxystrobin or the weight ratio of fluoxastrobin are 1 ︰, 9~9 ︰ 1, the weight ratio of fluorine azoles bacterium aniline and phenylsulfonyl ester is 1 ︰, 1~14 ︰ 1,
The weight ratio of fluorine azoles bacterium aniline and ZEN 90160 is 1 ︰, 9~4 ︰ 1.
The composition pesticide of fluorine-containing azoles bacterium aniline and methoxy acrylic proposed by the present invention is used to prevent crops
The purposes of upper disease, the crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, water
Orchard crop, dry fruit crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop,
Green manure pasture crop；The disease for banded sclerotial blight, smut, sclerotiniose, downy mildew, scab, epidemic disease, rust, powdery mildew,
Spot defoliation, rice blast, false smut, bakanae disease, damping-off, shot hole, anthracnose, brown spot, ring spot, droop, leaf
Pinta or leaf blight.
Active components A, the weight ratio of active ingredient B are 1 ︰, 80~80 ︰ 1.The weight hundred of active component in usual composition
Divide 0.5%~90% that content is total weight, be preferably 5%~80%.According to different preparation types, active component content scope
It is different.In general, liquid preparation contains by weight 1%~70% active material, preferably 5%~50%；Solid pharmaceutical preparation
Contain by weight 5%~80% active material, preferably 10%~80%.
At least containing a kind of surfactant in the bactericidal composition of the present invention, so that active component is in water during application
It is scattered.Surface-active contents are the 5%~30% of total formulation weight, and surplus is solid or liquid diluent.
The bactericidal composition of the present invention can be used through dilution or directly before use by user.Its preparation can be by usual
Processing method known in those skilled in the art prepare, i.e., after active material is mixed with liquid flux or solid carrier,
Add one kind in surfactant such as dispersant, stabilizer, wetting agent, binding agent, antifoaming agent, disintegrant, antifreeze
It is or several.
The bactericidal composition of the present invention, can be processed into acceptable dosage form in any sterilization, wherein more preferably on demand
Dosage form hang for wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or micro-capsule
Floating-suspending agent.
Comprising following constituent content when wettable powder is made in composition：Active components A 0.5%~80%, active ingredient
B0.5%~80%, dispersant 2%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when water dispersible granules are made：Active components A 0.5%~80%, active ingredient
B0.5%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%, filler surplus.
Composition includes following constituent content when suspending agent is made：Active components A 0.5%~50%, active ingredient B0.5%~
50%th, dispersant 2%~10%, wetting agent 2%~10%, antifoaming agent 0.01%~2%, thickener 0~2%, antifreeze 0~8%, go from
Sub- water adds to 100%.
Composition includes following constituent content when suspension emulsion is made：Active components A 0.5%~50%, active ingredient B0.5%~
50%th, dispersant 2%~10%, antifoaming agent 0.01%~2%, solvent 1%~15%, thickener 0~2%, emulsifier 2%~12%, freeze proof
Agent 0~8%, deionized water add to 100%.
Comprising following constituent content when aqueous emulsion is made in composition：Active components A 0.5%~50%, active ingredient B0.5%~
50%th, solvent 1%~30%, emulsifier 1%~15%, antifreeze 0~8%, thickener 0~2%, antifoaming agent 0.01%~2%, deionization
Water supplies surplus.
Comprising following constituent content when microemulsion is made in composition：Active components A 0.5%~50%, active ingredient B0.5%~
50%th, solvent 1%~30%, emulsifier 3%~25%, antifreeze 0~8%, antifoaming agent 0.01%~2%, deionized water supply surplus.
Composition includes following constituent content when microcapsule suspending agent is made：Active components A 0.5%~50%, active ingredient
B0.5%~50%, macromolecule cyst material 2%~10%, dispersant 1%~10%, organic solvent 1%~10%, emulsifier 1%~7%,
Antifoaming agent 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
Composition includes following constituent content when microcapsule suspension-suspendinagent agent is made：Active components A 0.5%~50%, activity into
Point B0.5%~50%, macromolecule cyst material 2%~10%, dispersant 1%~12%, wetting agent 1%~8%, organic solvent 1%~
15%th, emulsifier 1%~6%, antifoaming agent 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionized water add to
100%；
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：
（1）Fluorine azoles bacterium aniline is with after pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, fluoxastrobin or ZEN 90160 compounding, having
There are apparent synergy and lasting effect；（2）To cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruit
It is class crop, dry fruit crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop, green
Disease on fertile pasture crop has greater activity；（3）Reduce pesticide usage amount, reduce residual of the pesticide on crop
Amount, alleviates environmental pollution；（4）To safety of human and livestock, Environmental compatibility is good；And preparation adhesion strength enhances, resistance of rainwater washing against.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The present invention is not limited thereto.
Application Example one
1~14 wettable powder of embodiment
Fluorine azoles bacterium aniline, active ingredient B, dispersant, wetting agent, filler are uniformly mixed in mixed cylinder, through air-flow powder
Broken machine remixes uniformly after crushing, you can wettable powder product of the present invention is made, is specifically shown in Table 1.
1 embodiment of table, 1~14 each component and parts by weight
15~28 water dispersible granules of embodiment
Fluorine azoles bacterium aniline, active ingredient B, dispersant, wetting agent, disintegrant, filler etc. are obtained together through air-flow crushing
The grain size needed, adds binding agent（Can add can be not added with）Etc. other auxiliary agents, granulation materials are obtained.Item is quantified into feeding fluidisation
In bed granulating drier after granulation and drying, you can water dispersible granules product of the present invention is made, is specifically shown in Table 2.
2 embodiment of table, 15~28 each component and parts by weight
29~42 suspending agent of embodiment
By dispersant, wetting agent, antifoaming agent, thickener（Can add can be not added with）, antifreeze（Can add can be not added with）, by a high speed
Shear-mixed is uniform, adds in fluorine azoles bacterium aniline, active ingredient B, when ball milling 2~3 is small in the ball mill, diameter of particle is made all to exist
Less than 5 μm, surplus is supplied with deionized water, you can suspending agent product of the present invention is made, is specifically shown in Table 3.
3 embodiment of table, 29~42 each component and parts by weight
43~49 suspension emulsion of embodiment
By dispersant, antifoaming agent, thickener（Can add can be not added with）, antifreeze（Can add can be not added with）It is mixed by high speed shear
Uniformly, fluorine azoles bacterium aniline is added in, when ball milling 2~3 is small in the ball mill, makes diameter of particle all below 5 μm, fluorine azoles bacterium is made
Then active ingredient B, solvent, emulsifier and various auxiliary agents are directly emulsified suspending agent by aniline suspending agent with high speed agitator
In, surplus is supplied with deionized water, and suspension emulsion product of the present invention is made, is specifically shown in Table 4,5.
4 embodiment of table, 43~46 each component and parts by weight
5 embodiment of table, 47~49 each component and parts by weight
50~58 aqueous emulsion of embodiment
Fluorine azoles bacterium aniline, active ingredient B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase；By deionization
Water, antifreeze（Can add can be not added with）, thickener（Can add can be not added with）, antifoaming agent mix, into homogeneous water phase.In high-speed stirring
It mixes down, water is added to oil phase, surplus is supplied with deionized water；Aqueous emulsion product of the present invention is can be prepared by, is specifically shown in
Table 6.
6 embodiment of table, 50~58 each component and parts by weight
Pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, fluoxastrobin or ZEN 90160 in table 1~6 are exchanged, can be made new
Preparation.
59~61 microemulsion of embodiment
By fluorine azoles bacterium aniline, active ingredient B, solvent, emulsifier, antifreeze（Can add can be not added with）, antifoaming agent is sufficiently mixed
Into the oil phase of homogeneous transparent, deionized water is slowly added under stiring, is formed WO emulsion, then agitated heating, is made
Rapid phase inversion into oil-in-water type, be cooled to room temperature and make up to balance, filtered, surplus is supplied with deionized water；It can be prepared by
Microemulsion product of the present invention, is specifically shown in Table 7.
7 embodiment of table, 59~61 each component and parts by weight
Embodiment 62,63 microcapsule suspending agents
Fluorine azoles bacterium aniline, active ingredient B, macromolecule cyst material, solvent are mixed, makes to be dissolved into homogeneous oil phase, cut
Under tangent condition, by oil phase be added to containing emulsifier, pH adjusting agent, dispersant aqueous phase solution in, surplus is mended with deionized water
Foot, two kinds of materials react in oil-water interfaces, form high score ascus wall, the well dispersed micro-capsule of the present composition is made and hangs
Floating agent product.Specifically it is shown in Table 8.
8 embodiment 62 of table, 63 each components and parts by weight
Embodiment 64,65 microcapsule suspension-suspendinagent agents
Active ingredient B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing condition
Under be added to containing emulsifier, pH adjusting agent aqueous phase solution in, well dispersed microcapsule suspending agent is made.By dispersant, wet
Moisten agent, antifoaming agent, thickener（Can add can be not added with）It is uniformly mixed by high speed shear, adds in fluorine azoles bacterium aniline, in the ball mill
When ball milling 2~3 is small, make diameter of particle all below 5 μm, suspending agent is made, suspending agent then is added to microcapsules suspends
In the aqueous phase solution of agent, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent production of the present composition is made
Product are specifically shown in Table 9.
9 embodiment 64 of table, 65 each components and parts by weight
The embodiment of the present invention is the method being combined using Toxicity Determination and field trial.First pass through indoor virulence survey
Calmly, the synergy ratio after clear and definite two kinds of medicaments compound by a certain percentage（SR）, SR ＜ 0.5 be antagonism, 0.5≤SR≤1.5
For summation action, SR ＞ 1.5 are synergistic effect, on this basis, then carry out field trial.
Test method：After prerun determines the effective inhibition concentration scope of each medicament, medicament sets 5 respectively by active constituent content
A dosage processing, if clear water compares.Reference《Farm-chemical indoor determination test rule fungicide》It carries out, using mycelial growth speed
Rate method measures virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing
Amount, mycelial growth inhibition rate.
Net growth（mm）=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value（y）, liquor strength（μg/mL）It is converted into numerical value（x）, with minimum
Square law acquires virulence regression equation（y=a+bx）, and thus calculate the EC of each medicament50Value.Simultaneously according to Wadley method meters
Calculate two medicament different ratio synergy ratios（SR）, SR ＜ 0.5 be antagonism, 0.5≤SR≤1.5 be summation action, SR
＞ 1.5 is synergistic effect.Calculation formula is as follows：
Wherein：A, b is respectively active components A and active ingredient B ratio shared in combination；
A is fluorine azoles bacterium aniline；
B is selected from one of pyraclostrobin, trifloxystrobin, phenylsulfonyl ester, fluoxastrobin or ZEN 90160 kind.
Application Example two：
For trying disease：Rice sheath blight disease
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine azoles bacterium aniline and pyraclostrobin active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
Toxicity test result
10 fluorine azoles bacterium aniline of table compounds the toxicity test analysis of results table to rice sheath blight disease with pyraclostrobin
As shown in Table 10, fluorine azoles bacterium aniline matches the synergy in 1 80~80 ︰ 1 of ︰ to rice sheath blight disease with pyraclostrobin
Ratio SR is all higher than 1.5, both illustrates that mixture shows synergistic effect in the range of 1 ︰, 80~80 ︰ 1, when fluorine azoles bacterium aniline with
For the proportioning of pyraclostrobin in 1 25~25 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.25；When fluorine azoles bacterium
For the proportioning of aniline and pyraclostrobin in 1 9~9 ︰ 1 of ︰, synergistic effect is the most prominent, and synergy ratio is more than 2.40.Through Shen
It is 25 to ask someone to test the optimum ratio for finding fluorine azoles bacterium aniline and pyraclostrobin：1、20：1、15：1、10：1、8：1、7：1、6：
1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：8、1：10、1：15、1：20、1：25, especially work as fluorine
Azoles bacterium aniline is 1 with pyraclostrobin weight ratio：Synergy ratio is maximum when 1, and synergistic effect is the most apparent.
Application Example three
For trying disease：Downy mildew of garpe
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Having for fluorine azoles bacterium aniline and trifloxystrobin active compound and the two different ratio mixture is determined by pilot study
Imitate inhibition concentration scope.
11 fluorine azoles bacterium aniline of table compounds the toxicity test analysis of results table to downy mildew of garpe with trifloxystrobin
As shown in Table 11, fluorine azoles bacterium aniline is matched in 1 80~80 ︰ 1 of ︰ with trifloxystrobin to the synergy ratio of downy mildew of garpe
SR is all higher than 1.5, illustrates that the two mixture in the range of 1 ︰, 80~80 ︰ 1 shows synergistic effect, when fluorine azoles bacterium aniline and oxime bacterium
For the proportioning of ester in 1 25~25 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.20；When fluorine azoles bacterium aniline and oxime
For the proportioning of bacterium ester in 1 9~9 ︰ 1 of ︰, synergistic effect is the most prominent, and synergy ratio is more than 2.45.It tests and finds through applicant
Fluorine azoles bacterium aniline and the optimum ratio of trifloxystrobin are 25：1、20：1、15：1、10：1、8：1、7：1、6：1、5：1、4：1、3：1、2：
1、1：1、1：2、1：3、1：4、1：5、1：6、1：8、1：10、1：15、1：20、1：25, especially when fluorine azoles bacterium aniline and trifloxystrobin
Weight ratio is 1：Synergy ratio is maximum when 1, and synergistic effect is the most apparent.
Application Example four
For trying disease：Powdery mildew of cucumber
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine azoles bacterium aniline and phenylsulfonyl ester active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
12 fluorine azoles bacterium aniline of table compounds the toxicity test analysis of results table to powdery mildew of cucumber with phenylsulfonyl ester
As shown in Table 12, fluorine azoles bacterium aniline is matched in 1 80~80 ︰ 1 of ︰ with phenylsulfonyl ester to the synergic ratio of powdery mildew of cucumber
Value SR is all higher than 1.5, illustrates that the two mixture in the range of 1 ︰, 80~80 ︰ 1 shows synergistic effect, when fluorine azoles bacterium aniline and benzene
For the proportioning of kresoxim-methyl in 1 15~30 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.25；When fluorine azoles bacterium aniline
For proportioning with phenylsulfonyl ester in 1 1~14 ︰ 1 of ︰, synergistic effect is the most prominent, and synergy ratio is more than 2.40.Through applicant
Experiment finds that the optimum ratio of fluorine azoles bacterium aniline and phenylsulfonyl ester is 30：1、20：1、15：1、14：1、13：1、12：1、11：1、
10：1、9：1、8：1、7：1、6：1、5：1、3：1、2：1、1：1、1：5、1：10、1：15, especially when fluorine azoles bacterium aniline and phenylate bacterium
Ester weight ratio is 9：Synergy ratio is maximum when 1, and synergistic effect is the most apparent.
Application Example five
For trying disease：Smut of maize
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine azoles bacterium aniline and fluoxastrobin active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
13 fluorine azoles bacterium aniline of table compounds the toxicity test analysis of results table to smut of maize with fluoxastrobin
As shown in Table 13, fluorine azoles bacterium aniline is matched in 1 80~80 ︰ 1 of ︰ with fluoxastrobin to the synergic ratio of smut of maize
Value SR is all higher than 1.5, illustrates that the two mixture in the range of 1 ︰, 80~80 ︰ 1 shows synergistic effect, when fluorine azoles bacterium aniline and fluorine
For the proportioning of Fluoxastrobin in 1 25~25 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.20；When fluorine azoles bacterium aniline
For proportioning with fluoxastrobin in 1 9~9 ︰ 1 of ︰, synergistic effect is the most prominent, and synergy ratio is more than 2.50.It is tried through applicant
The optimum ratio for issuing after examination and approval existing fluorine azoles bacterium aniline and fluoxastrobin is 25：1、20：1、15：1、10：1、8：1、7：1、6：1、5：1、4：
1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：8、1：10、1：15、1：20、1：25, especially when fluorine azoles bacterium aniline
It is 1 with fluoxastrobin weight ratio：Synergy ratio is maximum when 1, and synergistic effect is the most apparent.
Application Example six
For trying disease：Wheat sharp eyespot
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine azoles bacterium aniline and ZEN 90160 active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
14 fluorine azoles bacterium aniline of table compounds the toxicity test analysis of results table to wheat sharp eyespot with ZEN 90160
As shown in Table 14, fluorine azoles bacterium aniline is matched in 1 80~80 ︰ 1 of ︰ with ZEN 90160 to the synergic ratio of wheat sharp eyespot
Value SR is all higher than 1.5, illustrates that the two mixture in the range of 1 ︰, 80~80 ︰ 1 shows synergistic effect, when fluorine azoles bacterium aniline and pyridine
For the proportioning of oxygen bacterium ester in 1 30~25 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is more than 2.25；When fluorine azoles bacterium aniline
For proportioning with ZEN 90160 in 1 9~4 ︰ 1 of ︰, synergistic effect is the most prominent, and synergy ratio is more than 2.40.It is tried through applicant
The optimum ratio for issuing after examination and approval existing fluorine azoles bacterium aniline and ZEN 90160 is 25：1、20：1、10：1、8：1、6：1、5：1、4：1、3：1、2：1、
1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：15、1：20、1：30, especially when fluorine azoles bacterium aniline with
ZEN 90160 weight ratio is 1：Synergy ratio is maximum when 2, and synergistic effect is the most apparent.
It is found through experiment：After fluorine azoles bacterium aniline and active ingredient B compounding in various crop banded sclerotial blight, smut, bacterium
Core disease, downy mildew, scab, epidemic disease, rust, powdery mildew, spot defoliation, rice blast, false smut, bakanae disease, damping-off, sore
The prevention of scall, anthracnose, brown spot, ring spot, droop, leaf spot or leaf blight has apparent synergistic effect, synergy
Ratio SR is all higher than 1.5.
Effect experiment part：Test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, 20% fluorine azoles of comparison medicament
Bacterium aniline suspending agent（Autogamy）, 250 g/l of pyraclostrobin missible oils（It is purchased in market）, 45% trifloxystrobin wettable powder（Autogamy）、10%
Phenylsulfonyl ester suspending agent（Autogamy）, 10% fluoxastrobin missible oil（Autogamy）, 25% chlorfenapyr suspending agent（Autogamy）.
Seven fluorine azoles bacterium aniline of Application Example and active ingredient B and its compounding prevention cucumber downy mildew test of pesticide effectiveness
This test arrangement investigates cucumber downy mildew disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease
Phase dispenser 5 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
15 fluorine azoles bacterium aniline of table and active ingredient B and its compounding prevention cucumber downy mildew test of pesticide effectiveness
As can be seen from Table 15, fluorine azoles bacterium aniline after active ingredient B compoundings with can effectively prevent cucumber downy mildew, through application
People, which tests, finds fluorine azoles bacterium aniline with can also effectively prevent powdery mildew of cucumber, droop, epidemic disease, bacterium after active ingredient B compoundings
Core disease, control effect are above 96%, and better than the preventive effect of single dose, and preventive effect phase is long.Experiment scope of medication in target crop without
Harmful effect.
Application Example octafluoro azoles bacterium aniline and active ingredient B and its compounding prevention rice sheath blight disease test of pesticide effectiveness
This test arrangement investigates rice sheath blight disease disease index before Shaanxi Province Hanzhong suburban area, medicine, occurs just in disease
Phase dispenser 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
16 fluorine azoles bacterium aniline of table and active ingredient B and its compounding prevention rice sheath blight disease test of pesticide effectiveness
As can be seen from Table 16, fluorine azoles bacterium aniline after active ingredient B compoundings with can effectively prevent rice sheath blight disease, through application
People test find can also effectively to prevent after fluorine azoles bacterium aniline and active ingredient B compounding rice blast, false smut, bakanae disease,
Damping-off, leaf blight, leaf spot, control effect are above 96%, and better than the preventive effect of single dose, and preventive effect phase is long.In experiment medication model
It encloses and interior has no adverse effects to target crop.
Nine fluorine azoles bacterium aniline of Application Example and active ingredient B and its compounding prevention smut of maize test of pesticide effectiveness
This test arrangement investigates smut of maize disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease
Phase dispenser 5 days after dispenser, investigates disease indexes and calculates preventive effect for 15 days, 30 days.Result of the test is as follows：
17 fluorine azoles bacterium aniline of table and active ingredient B and its compounding prevention smut of maize test of pesticide effectiveness
As can be seen from Table 17, fluorine azoles bacterium aniline and active ingredient B and its compounding prevention smut of maize, control effect are equal
Higher than 95%, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
Ten fluorine azoles bacterium aniline of Application Example and active ingredient B and its compounding prevention pear scab test of pesticide effectiveness
This test arrangement investigates pear scab disease index before Xianyang, Shanxi province suburban area, medicine, occurs just in disease
Phase dispenser 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
18 fluorine azoles bacterium aniline of table and active ingredient B and its compounding prevention pear scab test of pesticide effectiveness
As can be seen from Table 18, fluorine azoles bacterium aniline after active ingredient B compoundings with can effectively prevent pear scab, through application
People, which tests, finds fluorine azoles bacterium aniline with can also effectively prevent pear tree rust, spot defoliation, foxiness after active ingredient B compoundings
Disease, ring spot, control effect are above 95%, and better than the preventive effect of single dose, and preventive effect phase is long.To target in experiment scope of medication
Crop has no adverse effects.
11 fluorine azoles bacterium aniline of Application Example and active ingredient B and its compounding prevention downy mildew of garpe test of pesticide effectiveness
This test arrangement investigates downy mildew of garpe disease index before Shaanxi Province Weinan City Dali County, medicine, occurs in disease
Initial stage dispenser 10 days after dispenser, investigates disease indexes and calculates preventive effect for 20 days, 30 days.Result of the test is as follows：
19 fluorine azoles bacterium aniline of table and active ingredient B and its compounding prevention downy mildew of garpe test of pesticide effectiveness
As can be seen from Table 19, fluorine azoles bacterium aniline after active ingredient B compoundings with can effectively prevent downy mildew of garpe, through application
People, which tests, finds fluorine azoles bacterium aniline with can also effectively prevent uncinula necator, anthracnose, control effect after active ingredient B compoundings
95% is above, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
Ten difluoro azoles bacterium aniline of Application Example and active ingredient B and its compounding prevention citrus anthracnose test of pesticide effectiveness
This test arrangement investigates citrus anthracnose disease index before Shaanxi Province Hanzhong suburban area, medicine, occurs just in disease
Phase dispenser 7 days after dispenser, investigates disease indexes and calculates preventive effect for 14 days, 25 days.Result of the test is as follows：
20 fluorine azoles bacterium aniline of table and active ingredient B and its compounding prevention citrus anthracnose test of pesticide effectiveness
As can be seen from Table 20, fluorine azoles bacterium aniline after active ingredient B compoundings with can effectively prevent citrus anthracnose, through application
People, which tests, finds fluorine azoles bacterium aniline with can also effectively prevent citrus scab after active ingredient B compoundings, and control effect is above
96%, better than the preventive effect of single dose, and preventive effect phase is long.It has no adverse effects in experiment scope of medication to target crop.
The experiment by different places throughout the country is drawn afterwards, fluorine azoles bacterium aniline and pyraclostrobin, trifloxystrobin, phenylate
Bacterium ester, fluoxastrobin or ZEN 90160 compounding after in various crop banded sclerotial blight, smut, sclerotiniose, downy mildew, black star
Disease, epidemic disease, rust, powdery mildew, spot defoliation, rice blast, false smut, bakanae disease, damping-off, shot hole, anthracnose, foxiness
The preventive effect of the Common Diseases such as disease, ring spot, droop, leaf spot or leaf blight is more than 95%, better than single dose preventive effect, synergy
Effect is apparent.
Claims (6)
1. the composition pesticide of a kind of fluorine-containing azoles bacterium aniline and methoxy acrylic, effective active composition is active components A
With active ingredient B, it is characterised in that：Active components A and active ingredient B weight ratios are 1 ︰, 80~80 ︰ 1, the active components A
For fluorine azoles bacterium aniline, active ingredient B is phenylsulfonyl ester.
2. the composition pesticide of fluorine-containing azoles bacterium aniline according to claim 1 and methoxy acrylic, feature exist
In：Active components A and the weight ratio of active ingredient B are 1 ︰, 60~60 ︰ 1.
3. the composition pesticide of fluorine-containing azoles bacterium aniline according to claim 2 and methoxy acrylic, feature exist
In：
The weight ratio of fluorine azoles bacterium aniline and phenylsulfonyl ester is 1 ︰, 15~30 ︰ 1.
4. the pesticide combination of fluorine-containing azoles bacterium aniline according to any one of claim 1 to 3 and methoxy acrylic
Object, it is characterised in that：Wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro- is made in composition
Capsule suspending agent or microcapsule suspension-suspendinagent agent.
5. the composition pesticide of fluorine-containing azoles bacterium aniline according to claim 4 and methoxy acrylic is used to prevent agriculture
The purposes of disease on crop.
6. purposes according to claim 5, it is characterised in that：The disease is banded sclerotial blight, smut, sclerotiniose, frost
Mildew, scab, epidemic disease, rust, powdery mildew, spot defoliation, rice blast, false smut, bakanae disease, damping-off, shot hole, charcoal
Subcutaneous ulcer disease, brown spot, ring spot, droop, leaf spot or leaf blight.
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| CN104170827A (en) * | 2014-09-01 | 2014-12-03 | 山东南海生物药业研制开发有限公司 | Pesticide composition containing penflufen and trifloxystrobin and preparation method thereof |
| WO2017004744A1 (en) * | 2015-07-03 | 2017-01-12 | Bayer Cropscience (China) Co., Ltd. | Use of penflufen |
| WO2017020180A1 (en) * | 2015-07-31 | 2017-02-09 | Bayer Cropscience (China) Co., Ltd. | Method and use of penflufen for controlling corn head smut |
| CN105901012A (en) * | 2016-06-08 | 2016-08-31 | 广东中迅农科股份有限公司 | Suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin |
| CN106070229B (en) * | 2016-06-22 | 2019-01-15 | 漯河市傅牌农业科技有限公司 | A kind of bactericidal composition of fluorine azoles bacterium aniline and coumoxystrobin |
| CN106135243B (en) * | 2016-07-01 | 2019-01-15 | 山东金野农化有限公司 | A kind of bactericidal composition of fluorine-containing azoles bacterium aniline and chlorine nalidixic bacterium ester |
| CN107027787A (en) * | 2017-04-28 | 2017-08-11 | 北京科发伟业农药技术中心 | The composition of fluorine-containing azoles bacterium aniline and Tolprocarb |
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| CN1533380A (en) * | 2001-07-25 | 2004-09-29 | �ݶ�ũ�����ѧ�ɷݹ�˾ | N-pyrazolylcarboxanilides as fungicides |
| CN102469786A (en) * | 2009-07-07 | 2012-05-23 | 拜尔农作物科学股份公司 | Process for improving seedling growth and/or early emergence of crops |
| CN102640756A (en) * | 2003-10-23 | 2012-08-22 | 拜尔农作物科学股份公司 | Synergistic fungicidal active combinations |
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| CN1533380A (en) * | 2001-07-25 | 2004-09-29 | �ݶ�ũ�����ѧ�ɷݹ�˾ | N-pyrazolylcarboxanilides as fungicides |
| CN102640756A (en) * | 2003-10-23 | 2012-08-22 | 拜尔农作物科学股份公司 | Synergistic fungicidal active combinations |
| CN102469786A (en) * | 2009-07-07 | 2012-05-23 | 拜尔农作物科学股份公司 | Process for improving seedling growth and/or early emergence of crops |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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| OL01 | Intention to license declared | ||
| OL01 | Intention to license declared |