CN104521978B - A kind of bactericidal composition containing dimoxystrobin - Google Patents
A kind of bactericidal composition containing dimoxystrobin Download PDFInfo
- Publication number
- CN104521978B CN104521978B CN201410841252.7A CN201410841252A CN104521978B CN 104521978 B CN104521978 B CN 104521978B CN 201410841252 A CN201410841252 A CN 201410841252A CN 104521978 B CN104521978 B CN 104521978B
- Authority
- CN
- China
- Prior art keywords
- dimoxystrobin
- active ingredient
- agent
- active
- disease
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005762 Dimoxystrobin Substances 0.000 title claims abstract description 101
- WXUZAHCNPWONDH-DYTRJAOYSA-N dimoxystrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1COC1=CC(C)=CC=C1C WXUZAHCNPWONDH-DYTRJAOYSA-N 0.000 title claims abstract description 101
- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 15
- 239000004480 active ingredient Substances 0.000 claims abstract description 46
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 37
- 201000010099 disease Diseases 0.000 claims abstract description 36
- 239000000375 suspending agent Substances 0.000 claims description 21
- 235000007164 Oryza sativa Nutrition 0.000 claims description 20
- 235000009566 rice Nutrition 0.000 claims description 20
- 239000003094 microcapsule Substances 0.000 claims description 14
- 241000221785 Erysiphales Species 0.000 claims description 13
- 241000233679 Peronosporaceae Species 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 206010039509 Scab Diseases 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- 239000004563 wettable powder Substances 0.000 claims description 7
- 241001530056 Athelia rolfsii Species 0.000 claims description 3
- 239000005742 Bupirimate Substances 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- DSKJPMWIHSOYEA-UHFFFAOYSA-N bupirimate Chemical compound CCCCC1=C(C)N=C(NCC)N=C1OS(=O)(=O)N(C)C DSKJPMWIHSOYEA-UHFFFAOYSA-N 0.000 claims description 2
- 208000031968 Cadaver Diseases 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 31
- 150000001875 compounds Chemical class 0.000 abstract description 18
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 abstract description 17
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 abstract description 16
- 239000005745 Captan Substances 0.000 abstract description 16
- 239000005782 Fluopicolide Substances 0.000 abstract description 16
- 229940117949 captan Drugs 0.000 abstract description 16
- BBXXLROWFHWFQY-UHFFFAOYSA-N ethirimol Chemical compound CCCCC1=C(C)NC(NCC)=NC1=O BBXXLROWFHWFQY-UHFFFAOYSA-N 0.000 abstract description 16
- GBOYJIHYACSLGN-UHFFFAOYSA-N fluopicolide Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CNC(=O)C1=C(Cl)C=CC=C1Cl GBOYJIHYACSLGN-UHFFFAOYSA-N 0.000 abstract description 16
- 150000003839 salts Chemical class 0.000 abstract description 16
- 239000005764 Dithianon Substances 0.000 abstract description 15
- IUOKJNROJISWRO-UHFFFAOYSA-N N-(2-cyano-3-methylbutan-2-yl)-2-(2,4-dichlorophenoxy)propanamide Chemical compound CC(C)C(C)(C#N)NC(=O)C(C)OC1=CC=C(Cl)C=C1Cl IUOKJNROJISWRO-UHFFFAOYSA-N 0.000 abstract description 15
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 15
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 abstract description 13
- 230000000855 fungicidal effect Effects 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 40
- 238000012360 testing method Methods 0.000 description 35
- 230000003449 preventive effect Effects 0.000 description 31
- 238000013329 compounding Methods 0.000 description 28
- 241000209094 Oryza Species 0.000 description 19
- 239000000575 pesticide Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000012071 phase Substances 0.000 description 15
- 230000002265 prevention Effects 0.000 description 14
- 231100000820 toxicity test Toxicity 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 13
- 239000002518 antifoaming agent Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 240000008067 Cucumis sativus Species 0.000 description 8
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 8
- 229940079593 drug Drugs 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- 230000005764 inhibitory process Effects 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 7
- 240000003768 Solanum lycopersicum Species 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 238000013401 experimental design Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 241000219109 Citrullus Species 0.000 description 5
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 5
- 240000001987 Pyrus communis Species 0.000 description 5
- 235000014443 Pyrus communis Nutrition 0.000 description 5
- 230000002528 anti-freeze Effects 0.000 description 5
- 241000193738 Bacillus anthracis Species 0.000 description 4
- 206010011732 Cyst Diseases 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000010165 autogamy Effects 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 235000002566 Capsicum Nutrition 0.000 description 3
- 239000006002 Pepper Substances 0.000 description 3
- 241000722363 Piper Species 0.000 description 3
- 235000016761 Piper aduncum Nutrition 0.000 description 3
- 235000017804 Piper guineense Nutrition 0.000 description 3
- 235000008184 Piper nigrum Nutrition 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- -1 methoxyimino Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- WCZBUQIZTSIQFE-UHFFFAOYSA-N furan;thiophene Chemical compound C=1C=COC=1.C=1C=CSC=1 WCZBUQIZTSIQFE-UHFFFAOYSA-N 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 241001123534 Colletotrichum coccodes Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 102000018832 Cytochromes Human genes 0.000 description 1
- 108010052832 Cytochromes Proteins 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000510928 Erysiphe necator Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000006806 disease prevention Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing dimoxystrobin, the bactericidal composition containing active components A Yu active ingredient B, active components A is selected from dimoxystrobin, and active ingredient B is selected from any one following compound:Thifluzamide, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol or its salt, dithianon, and active components A and the weight ratio of active ingredient B are 1 ︰, 80~60 ︰ 1.The present composition has the multiple diseases in various crop greater activity, and with apparent synergistic effect, expands fungicidal spectrum.And with the characteristics of dosage is small, resistance of rainwater washing against, and synergy is apparent.
Description
The application is divisional application, and original application is " a kind of to contain dimoxystrobin for the patent application of Shaanxi Meibang Pesticide Co., Ltd.
Bactericidal composition ", the Application No. of original application:201210337096.1 original application day 21012.09.13.
Technical field
The invention belongs to technical field of pesticide, are related to a kind of bactericidal composition containing dimoxystrobin answering in crop disease
With.
Technical background
Dimoxystrobin (Dimoxystrobin) chemical name:(E) [a- (2,5- bis- of -2- (methoxyimino)-N- methyl -2
Toloxyl)-o- tolyl] acetamide, molecular formula:C19H22N2O3.It is the outer inhibitor of quinone, by acting on cytochromes
Compound bc1 hinders electronics conduction, to inhibit the respiration of mitochondria.With protectiveness, therapeutic and conductibility, inhibit spore
Son is sprouted and mycelial growth.
Thifluzamide, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol or its salt, dithianon are
Common fungicide, and it is widely used in the disease on crops, the salt of wherein ethirimol is bupirimate.
In the real process of agricultural production, controlling disease is easiest to generate the problem that the generation of disease drug resistance.No
It is compounded with kind ingredient, is to prevent the very common method of resistance disease.Heterogeneity is compounded, and is imitated according to practical application
Fruit, to judge that certain compounding is synergy, adduction or antagonism.In most cases, the compounding effect of pesticide is all to add
And effect, the compounding for really having synergistic effect is seldom, especially synergistic effect clearly, the very high compounding of synergy ratio just more
It is few.Studied by inventor, find by dimoxystrobin and thifluzamide, Isoprothiolane, fenoxanil, captan, fluopicolide,
Ethirimol or its salt, dithianon mutually compound, and have good synergistic effect within the specific limits, and in relation to dimoxystrobin and thiophene furan
The related compounding of amide, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol or its salt, dithianon, exists at present
Both at home and abroad there is not yet relevant report.
The content of the invention
The purpose of the present invention is to propose to it is a kind of have synergistic function, use cost is low, preventive effect is good containing dimoxystrobin
Bactericidal composition.
The present invention is to be achieved through the following technical solutions:
A kind of bactericidal composition containing dimoxystrobin, it is characterised in that contain active components A and active ingredient B, active components A
It is 1 ︰, 80~60 ︰ 1 with active ingredient B weight ratios, the active components A is selected from dimoxystrobin, and active ingredient B is selected from thiophene furan acyl
One of amine, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol or its salt, dithianon kind;Active components A
Preferred weight ratio with active ingredient B is 1 ︰, 60~40 ︰ 1;More preferably the weight ratio of dimoxystrobin and thifluzamide for 1 ︰ 15~
The weight ratio of 30 ︰ 1, dimoxystrobin and Isoprothiolane is 1 ︰, 25~10 ︰ 1, and the weight ratio of dimoxystrobin and fenoxanil is 1 ︰, 30~20 ︰ 1,
The weight ratio of dimoxystrobin and captan is 1 ︰, 30~5 ︰ 1, and the weight ratio of dimoxystrobin and fluopicolide is 1 ︰, 20~30 ︰ 1, ether bacterium
Amine and ethirimol or the weight ratio of its salt are 1 ︰, 25~10 ︰ 1, and the weight ratio of dimoxystrobin and dithianon is 1 ︰, 30~15 ︰ 1;Most
The preferably weight ratio of dimoxystrobin and thifluzamide is 1 ︰, 4~9 ︰ 1, and the weight ratio of dimoxystrobin and Isoprothiolane is 1 ︰, 14~4 ︰ 1, ether
The weight ratio of bacterium amine and fenoxanil is 1 ︰, 14~9 ︰ 1, and the weight ratio of dimoxystrobin and captan is 1 ︰, 19~1 ︰ 1, dimoxystrobin with
The weight ratio of fluopicolide is 1 ︰, 9~14 ︰ 1, and the weight ratio of dimoxystrobin and ethirimol or its salt is 1 ︰, 9~4 ︰ 1, dimoxystrobin with
The weight ratio of dithianon is 1 ︰, 9~4 ︰ 1.
The bactericidal composition containing dimoxystrobin is used to prevent the disease of crops, and the crops make including grain
Object, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, tubers
Crop, oil crops, flower crop, medicinal crop, crop, green manure pasture crop;The disease includes powdery mildew, black
Star disease, downy mildew, gray mold, leaf mold, epidemic disease, rice blast, banded sclerotial blight, anthracnose, ring spot.
The amount of application when content of active ingredient depends on being used alone in the present composition, also depends on a kind of chemical combination
Object and another mixed ratio of compound and synergistic effect degree, at the same it is also related with target disease.In usual composition
The weight percentage of active ingredient is the 2%~90% of total weight, is preferably 5%~80%.According to different preparation classes
Type, active component content scope are different.In general, liquid preparation contains by weight 1%~60% active material, preferably
Ground is 5%~50%;Solid pharmaceutical preparation contains by weight 5%~80% active material, and preferably 10%~80%.
At least containing a kind of surfactant in the bactericidal composition of the present invention, so that active component is in water during application
It is scattered.Surface-active contents are the 2%~30% of total formulation weight, and surplus is solid or liquid diluent.
The bactericidal composition of the present invention can be used through dilution or directly before use by user.Its preparation can be by ability
Prepared by the processing method well known to field technique personnel, i.e., after active ingredient is mixed with liquid flux or solid carrier, add
Surfactant such as one or more of dispersant, stabilizer, wetting agent, binding agent, antifreeze, disintegrant, antifoaming agent etc..
The bactericidal composition of the present invention, can be processed into acceptable dosage form on any pesticide on demand.Wherein preferred agent
Type is wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, also
Microemulsion can be made.
Comprising following component and content when wettable powder is made in composition:Active components A 0.1%~60%, activity into
Divide B 0.1%~80%, dispersant 1%~12%, wetting agent 1%~8%, filler surplus.
Composition includes following component and content when water dispersible granules are made:Active components A 0.1%~60%, activity into
Point B 0.1%~80%, dispersant 1%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%,
Filler surplus.
Composition includes following component and content when suspending agent is made:Active components A 0.1%~50%, active ingredient B
0.1%~50%, dispersant 1%~10%, wetting agent 1%~10%, antifoaming agent 0.01%~2%, thickener 0~2%, anti-
Freeze agent 0~8%, deionized water adds to 100%.
Composition includes following component and content when suspension emulsion is made:Active components A 0.1%~50%, active ingredient B
0.1%~50%, emulsifier 1%~10%, dispersant 1%~10%, solvent 1%~20%, antifoaming agent 0.01%~2%,
Thickener 0~2%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following component and content when aqueous emulsion is made:Active components A 0.1%~50%, active ingredient B
0.1%~50%, solvent 1%~20%, emulsifier 1%~12%, antifreeze 0~8%, antifoaming agent 0.01%~2%, thickening
Agent 0~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspending agent is made:Active components A 0.1%~50%, activity into
Divide B0.1%~50%, macromolecule cyst material 1%~10%, dispersant 2%~10%, solvent 1%~10%, emulsifier
1%~7%, pH adjusting agent 0.01%~5%, antifoaming agent 0.01%~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspension-suspendinagent agent is made:Active components A 0.1%~50% is lived
It is property ingredient B0.1%~50%, macromolecule cyst material 1%~12%, dispersant 1%~12%, wetting agent 1%~8%, molten
Agent 1%~15%, emulsifier 1%~8%, antifoaming agent 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~
5%th, deionized water adds to 100%.
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
The advantage of the invention is that:
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose;(2) agriculture
Medicinal dose is reduced, and is reduced residual quantity of the pesticide on crop, is mitigated environmental pollution;(3) fungicidal spectrum is expanded, to multiple diseases
There is greater activity.
Specific embodiment:With reference to embodiment to further instruction of the present invention, the percentage in embodiment is
Weight percent, but the present invention is not limited thereto.
Application Example one
0 wettable powder of Examples 1 to 2
Dimoxystrobin, active ingredient B, dispersant, wetting agent, filler are mixed, are uniformly mixed in mixed cylinder, through air-flow powder
Broken machine remixes uniformly after crushing, you can wettable powder product of the present invention is made.Specifically it is shown in Table 1,2.
1 embodiment of table, 1~12 each component and content
2 embodiment of table, 13~20 each component and content
21~40 water dispersible granules of embodiment
Dimoxystrobin, active ingredient B, dispersant, wetting agent, disintegrant, filler are needed together through air-flow crushing
Grain size adds other auxiliary agents such as binding agent (can add can be not added with), obtains granulation materials.Item is quantified into feeding fluidized bed granulation
In drying machine after granulation and drying, water dispersible granules product of the present invention is made.Specifically it is shown in Table 3,4.
3 embodiment of table, 21~32 each component and content
4 embodiment of table, 33~40 each component and content
41~60 suspending agent of embodiment
By dispersant, wetting agent, antifoaming agent, thickener (can add can be not added with), antifreeze (can add can be not added with) by a high speed
Shear-mixed is uniform, adds in dimoxystrobin, active ingredient B, and surplus is supplied with deionized water, when ball milling 2~3 is small in the ball mill,
Make diameter of particle all below 5 μm, suspending agent product of the present invention is made.Specifically it is shown in Table 5,6.
5 embodiment of table, 41~52 each component and content
6 embodiment of table, 53~60 each component and content
61~76 suspension emulsion of embodiment
By dispersant, antifoaming agent, thickener (can add can be not added with), antifreeze (can add can be not added with), deionized water through excessively high
Fast shear-mixed is uniform, adds in dimoxystrobin, when ball milling 2~3 is small in the ball mill, makes diameter of particle all below 5 μm, is made
Then active ingredient B, solvent, emulsifier and various auxiliary agents are directly emulsified suspension by dimoxystrobin suspending agent with high speed agitator
In agent, suspension emulsion product of the present invention is made.Specifically it is shown in Table 7,8,9.
7 embodiment of table, 61~65 each component and content
8 embodiment of table, 66~70 each component and content
9 embodiment of table, 71~76 each component and content
By table 1 into table 9 thifluzamide, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol or its salt,
Dithianon exchanges, and novel formulation can be made.
77~82 aqueous emulsion of embodiment
Dimoxystrobin, active ingredient B, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase;By deionized water, resist
Jelly agent (can add can be not added with), thickener (can add can be not added with), antifoaming agent mix, into homogeneous water phase.Under high velocity agitation,
Water is added to oil phase, aqueous emulsion product of the present invention is made.Specifically it is shown in Table 10.
10 embodiment of table, 77~82 each component and content
83~85 microcapsule suspending agent of embodiment
Dimoxystrobin, active ingredient B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, in shearing bar
Under part, by oil phase be added to containing emulsifier, pH adjusting agent, dispersant, antifoaming agent aqueous phase solution in, surplus deionized water
It supplies, two kinds of materials react in oil-water interfaces, form high score ascus wall, the well dispersed micro-capsule of the present composition is made
Suspending agent product.Specifically it is shown in Table 11.
11 embodiment of table, 83~85 each component and content
86~88 microcapsule suspension-suspendinagent agent of embodiment
Active ingredient B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing condition
Under be added to containing emulsifier, pH adjusting agent aqueous phase solution in, well dispersed microcapsule suspending agent is made.By dispersant, wet
Profit agent, antifoaming agent, thickener (can add can be not added with) are uniformly mixed by high speed shear, add in dimoxystrobin, in the ball mill ball milling 2
~3 it is small when, make diameter of particle all below 5 μm, suspending agent be made, then suspending agent is added to the water of micro-capsule suspension
In phase solution, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent product of the present composition is made.Specifically
It is shown in Table 12.
12 embodiment of table, 86~88 each component and content
The embodiment of the present invention is the method being combined using Toxicity Determination and field trial.First pass through indoor virulence survey
It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after synergy ratio (SR), SR < 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR > 1.5 are synergistic effect, on this basis, then carry out field trial.
Test method:After prerun determines the effective inhibition concentration scope of each medicament, medicament sets 5 respectively by active constituent content
A dosage processing, if clear water compares.Reference《Farm-chemical indoor determination test rule fungicide》It carries out, using mycelial growth speed
Rate method measures virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into numerical value (x), with minimum
Square law acquires virulence regression equation (y=a+bx), and thus calculates the EC of each medicament50Value.Simultaneously according to Wadley methods
Two medicament different ratio synergy ratios (SR) are calculated, SR < 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action,
SR > 1.5 are synergistic effect.Calculation formula is as follows:
Wherein:A, b is respectively active components A and active ingredient B ratio shared in combination;A is dimoxystrobin;B is selected from
One of thifluzamide, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol or its salt, dithianon kind.
Application Example two:
For trying disease:Rice sheath blight disease;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:Through
It crosses pilot study and determines dimoxystrobin and thifluzamide active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
13 dimoxystrobin of table compounds the toxicity test analysis of results table to rice sheath blight disease with thifluzamide
As shown in Table 13, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ rice sheath blight disease with thifluzamide, synergy ratio SR
1.5 are all higher than, both illustrates that mixture shows synergistic effect in the range of 1 ︰, 80~60 ︰ 1, when dimoxystrobin and thifluzamide
For proportioning in 1 15~30 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.20.Dimoxystrobin and thiophene furan are found through experiment
The optimum ratio of amide is 30:1、25:1、20:1、15:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、
1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:15, especially when dimoxystrobin and thifluzamide weight ratio are 2:1
When synergy ratio it is maximum, synergistic effect is the most apparent.
Application Example three:
For trying disease:Rice blast;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:Through
Cross effective inhibition concentration scope that pilot study determines dimoxystrobin and isoprothiolane and the two different ratio mixture.
Toxicity test result
14 dimoxystrobin of table compounds the toxicity test analysis of results table to rice blast with Isoprothiolane
As shown in Table 14, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ rice blast with Isoprothiolane, and synergy ratio SR is equal
More than 1.5, illustrate that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when the proportioning of dimoxystrobin and Isoprothiolane
In 1 25~10 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.25.Dimoxystrobin and Isoprothiolane are found through experiment
Optimum ratio is 10:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:15、
1:20、1:25, especially when dimoxystrobin and Isoprothiolane weight ratio are 1:Synergy ratio is maximum when 5, and synergistic effect is the most apparent.
Application Example four:
For trying disease:Rice blast;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:Through
It crosses pilot study and determines dimoxystrobin and fenoxanil active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
15 dimoxystrobin of table compounds the toxicity test analysis of results table to rice blast with fenoxanil
As shown in Table 15, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ rice blast with fenoxanil, synergy ratio SR
1.5 are all higher than, both illustrates that mixture shows synergistic effect in the range of 1 ︰, 80~60 ︰ 1, when dimoxystrobin and fenoxanil
For proportioning in 1 30~20 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.20.Dimoxystrobin and rice blast are found through experiment
The optimum ratio of amide is 20:1、15:1、10:1、5:1、4:1、3:1、2:1、1:1、2:3、1:2、1:3、1:4、1:5、1:6、1:
7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:20、1:25、1:30, especially when dimoxystrobin and rice blast acyl
Amine weight ratio is 2:Synergy ratio is maximum when 3, and synergistic effect is the most apparent.
Application Example five:
For trying disease:Downy mildew of garpe;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:Through
It crosses pilot study and determines dimoxystrobin and captan active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
16 dimoxystrobin of table compounds the toxicity test analysis of results table to downy mildew of garpe with captan
As shown in Table 16, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ downy mildew of garpe with captan, and synergy ratio SR is equal
More than 1.5, illustrate that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when the proportioning of dimoxystrobin and captan
In 1 30~5 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.20.When dimoxystrobin and captan weight ratio are 1:
Synergy ratio is maximum when 10, and synergistic effect is the most apparent.
Application Example six:
For trying disease:Tomato blight;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:By
Pilot study determines dimoxystrobin and fluopicolide active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
17 dimoxystrobin of table compounds the toxicity test analysis of results table to tomato blight with fluopicolide
As shown in Table 17, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ tomato blight with fluopicolide, synergy ratio SR
1.5 are all higher than, illustrates that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when dimoxystrobin and fluopicolide
Proportioning in 1 20~30 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.15.When dimoxystrobin and fluopicolide
Weight ratio is 3:Synergy ratio is maximum when 2, and synergistic effect is the most apparent.
Application Example seven:
For trying disease:Powdery mildew of cucumber;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:Through
It crosses pilot study and determines dimoxystrobin and ethirimol or its salt active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
18 dimoxystrobin of table compounds the toxicity test analysis of results table to powdery mildew of cucumber with ethirimol or its salt
As shown in Table 18, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ powdery mildew of cucumber with ethirimol or its salt, synergic ratio
Value SR is all higher than 1.5, illustrates that the two mixture in the range of 1 ︰, 80~60 ︰ 1 shows synergistic effect, when dimoxystrobin and ethirimol
Or the proportioning of its salt, in 1 25~10 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.20.When dimoxystrobin is phonetic with second
Phenol or its salt weight ratio are 2:Synergy ratio is maximum when 5, and synergistic effect is the most apparent.
Application Example eight:
For trying disease:Pepper anthracnose;Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.;Experimental design:Through
It crosses pilot study and determines dimoxystrobin and dithianon active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
19 dimoxystrobin of table compounds the toxicity test analysis of results table to pepper anthracnose with dithianon
As shown in Table 19, dimoxystrobin is matched in 1 80~60 ︰ 1 of ︰ pepper anthracnose with dithianon, synergy ratio SR
1.5 are all higher than, both illustrates that mixture shows synergistic effect in the range of 1 ︰, 80~60 ︰ 1, when dimoxystrobin and dithianon
For proportioning in 1 30~15 ︰ 1 of ︰, synergistic effect is more prominent, and synergy ratio is all higher than 2.20.When dimoxystrobin and dithianon weight
Than for 1:Synergy ratio is maximum when 2, and synergistic effect is the most apparent.
It is found through experiment:Dimoxystrobin and thifluzamide, Isoprothiolane, fenoxanil, captan, fluopicolide, ethirimol
It is or withered to powdery mildew, scab, downy mildew, gray mold, leaf mold, epidemic disease, rice blast, line in various crop after its salt compounding
The prevention of disease, anthracnose, ring spot has apparent synergistic effect, and synergy ratio is more than 1.50.
Test of pesticide effectiveness part:Test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided.
The table of comparisons of 20 comparison medicament of table
Number | Comparison medicament | Number | Comparison medicament |
Medicament 1 | 10% dimoxystrobin suspending agent (autogamy) | Medicament 5 | 50% captan wettable powder (purchased in market) |
Medicament 2 | 240g/L thifluzamides suspending agent (purchased in market) | Medicament 6 | 30% fluopicolide water dispersible granules (autogamy) |
Medicament 3 | 30% Isoprothiolane microemulsion (purchased in market) | Medicament 7 | 25% ethirimol suspending agent (autogamy) |
Medicament 4 | 20% fenoxanil suspending agent (autogamy) | Medicament 8 | 22.7% dithianon suspending agent (purchased in market) |
Nine dimoxystrobin of Application Example and active ingredient B and its compounding prevention pear scab test of pesticide effectiveness
This test arrangement investigates the pear scab state of an illness before Xianyang, Shanxi province city, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 2 times.3 days after second of dispenser, disease index is investigated respectively and calculates preventive effect within 7 days, 14 days.It is real
It is as follows to test result:
21 dimoxystrobin of table and active ingredient B and its compounding prevention pear scab test of pesticide effectiveness
As can be seen from Table 21, for dimoxystrobin with can effectively prevent pear scab after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long, and can prevent pear tree powdery mildew, ring spot, anthracnose, and preventive effect is all higher than
96%.It has no adverse effects in experiment scope of medication to target crop.
Ten dimoxystrobin of Application Example and active ingredient B and its compounding prevention downy mildew of garpe test of pesticide effectiveness
This test arrangement investigates the downy mildew of garpe state of an illness before Shaanxi Province Weinan suburban area, medicine, in first time at state of an illness initial stage
Dispenser, every dispenser in 7 days once, are total to dispenser 2 times.10 days after second of dispenser, disease index is investigated respectively and is calculated within 20 days, 30 days
Preventive effect.The following institute of experimental result
Show:22 dimoxystrobin of table and active ingredient B and its compounding prevention downy mildew of garpe test of pesticide effectiveness
As can be seen from Table 22, for dimoxystrobin with can effectively prevent downy mildew of garpe after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long, and can prevent uncinula necator, gray mold, anthracnose, and preventive effect is all higher than
96%.It has no adverse effects in experiment scope of medication to target crop.
11 dimoxystrobin of Application Example and active ingredient B and its compounding prevention rice blast test of pesticide effectiveness
This test arrangement investigates the rice blast state of an illness before Shaanxi Province's Hanzhong City, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 3 times.3 days after third time dispenser, disease index is investigated respectively and calculates preventive effect within 7 days, 14 days.It is real
It is as follows to test result:
23 dimoxystrobin of table and active ingredient B and its compounding prevention rice blast test of pesticide effectiveness
As can be seen from Table 23, for dimoxystrobin with can effectively prevent rice blast after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long, and can prevent rice sheath blight disease, and preventive effect is all higher than 96%.In experiment medication model
It encloses and interior has no adverse effects to target crop.
12 dimoxystrobin of Application Example and active ingredient B and its compounding prevention powdery mildew of cucumber test of pesticide effectiveness
This test arrangement investigates the powdery mildew of cucumber state of an illness before Shaanxi Province Jingyang County, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 2 times.7 days after second of dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 20 days.
Experimental result is as follows:
24 dimoxystrobin of table and active ingredient B and its compounding prevention powdery mildew of cucumber test of pesticide effectiveness
As can be seen from Table 24, for dimoxystrobin with can effectively prevent powdery mildew of cucumber after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long, and can prevent cucumber downy mildew, scab, gray mold, and preventive effect is all higher than
96%.It has no adverse effects in experiment scope of medication to target crop.
13 dimoxystrobin of Application Example and active ingredient B and its compounding prevention ring rot of apple test of pesticide effectiveness
This test arrangement investigates the ring rot of apple state of an illness before Xianyang, Shanxi province city, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 3 times.3 days after third time dispenser, disease index is investigated respectively and calculates preventive effect within 7 days, 14 days.It is real
It is as follows to test result:
25 dimoxystrobin of table and active ingredient B and its compounding prevention ring rot of apple test of pesticide effectiveness
As can be seen from Table 25, for dimoxystrobin with can effectively prevent ring rot of apple after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long, and can prevent apple mildew, scab, and preventive effect is all higher than 96%.It is testing
It has no adverse effects in scope of medication to target crop.
14 dimoxystrobin of Application Example and active ingredient B and its compounding prevention tomato blight test of pesticide effectiveness
This test arrangement investigates the tomato blight state of an illness before Xian District, Shanxi Province suburban area, medicine, is applied for the first time in state of an illness initial stage
Medicine, every dispenser in 7 days once, are total to dispenser 2 times.7 days after second of dispenser, disease index is investigated respectively and is calculated anti-within 14 days, 30 days
Effect.Experimental result is as follows:
26 dimoxystrobin of table and active ingredient B and its compounding prevention tomato blight test of pesticide effectiveness
As can be seen from Table 26, for dimoxystrobin with can effectively prevent tomato blight after active ingredient B compoundings, control effect is excellent
In the preventive effect of single dose, and preventive effect phase is long, and can prevent anthracnose of tomato, gray mold, leaf mold, and preventive effect is all higher than 96%.
It has no adverse effects in experiment scope of medication to target crop.
15 dimoxystrobin of Application Example and active ingredient B and its compounding prevention watermelon anthrax test of pesticide effectiveness
This test arrangement investigates the watermelon anthrax state of an illness before Shaanxi Province Weinan City Dali County, medicine, in state of an illness initial stage first
Secondary dispenser, every dispenser in 7 days once, are total to dispenser 2 times.7 days after second of dispenser, disease index is investigated respectively and is counted within 10 days, 20 days
Calculate preventive effect.Experimental result is as follows:
27 dimoxystrobin of table and active ingredient B and its compounding prevention watermelon anthrax test of pesticide effectiveness
As can be seen from Table 27, for dimoxystrobin with can effectively prevent watermelon anthrax after active ingredient B compoundings, control effect is equal
Better than the preventive effect of single dose, and preventive effect phase is long, and can prevent watermelon powdery mildew, and preventive effect is all higher than 96%.In experiment medication model
It encloses and interior has no adverse effects to target crop.
Drawn by all parts of the country experiment, after dimoxystrobin and active ingredient B compounding in various crop powdery mildew, black star
The preventive effect of the Common Diseases such as disease, downy mildew, gray mold, leaf mold, epidemic disease, rice blast, banded sclerotial blight, anthracnose, ring spot is big
In 95%, better than single dose preventive effect, synergy is apparent.
Claims (4)
1. a kind of bactericidal composition containing dimoxystrobin, it is characterised in that:Effective active composition is active components A and active ingredient B,
Active components A is 1 ︰, 25 ~ 10 ︰ 1 with active ingredient B weight ratios, and the active components A is dimoxystrobin, and active ingredient B is phonetic for second
Phenol or bupirimate.
2. the bactericidal composition according to claim 1 containing dimoxystrobin, it is characterised in that:Wettable powder is made in composition
Agent, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
3. the bactericidal composition according to claim 1 containing dimoxystrobin is used to prevent the application of corps diseases.
4. application according to claim 3, it is characterised in that:The disease is powdery mildew, scab, downy mildew, ash
Mildew, leaf mold, epidemic disease, rice blast, banded sclerotial blight, anthracnose, ring spot.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410841252.7A CN104521978B (en) | 2012-09-13 | 2012-09-13 | A kind of bactericidal composition containing dimoxystrobin |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410841252.7A CN104521978B (en) | 2012-09-13 | 2012-09-13 | A kind of bactericidal composition containing dimoxystrobin |
CN201210337096.1A CN103651441B (en) | 2012-09-13 | 2012-09-13 | Bactericidal composition containing dimoxystrobin |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210337096.1A Division CN103651441B (en) | 2012-09-13 | 2012-09-13 | Bactericidal composition containing dimoxystrobin |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104521978A CN104521978A (en) | 2015-04-22 |
CN104521978B true CN104521978B (en) | 2018-05-18 |
Family
ID=52837760
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410841252.7A Expired - Fee Related CN104521978B (en) | 2012-09-13 | 2012-09-13 | A kind of bactericidal composition containing dimoxystrobin |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104521978B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109169672A (en) * | 2018-11-29 | 2019-01-11 | 江西禾益化工股份有限公司 | A kind of bactericidal composition containing alkene oxime amine and its application |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102113485A (en) * | 2009-12-30 | 2011-07-06 | 青岛奥迪斯生物科技有限公司 | Bactericidal composition containing ethirimol and kresoxim-methyl |
-
2012
- 2012-09-13 CN CN201410841252.7A patent/CN104521978B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102113485A (en) * | 2009-12-30 | 2011-07-06 | 青岛奥迪斯生物科技有限公司 | Bactericidal composition containing ethirimol and kresoxim-methyl |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109169672A (en) * | 2018-11-29 | 2019-01-11 | 江西禾益化工股份有限公司 | A kind of bactericidal composition containing alkene oxime amine and its application |
Also Published As
Publication number | Publication date |
---|---|
CN104521978A (en) | 2015-04-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104161042B (en) | A kind of composition pesticide of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
CN103371153B (en) | Bactericidal composition containing thifluzamide Yu methoxy acrylic | |
CN104412982B (en) | A kind of compound highly effective bactericidal composition of fluorine-containing ether bacterium amide | |
CN104938488B (en) | High-efficiency bactericidal composition | |
CN105191939B (en) | A kind of bactericidal composition | |
CN104137836B (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
CN104126585B (en) | A kind of combination sterilization composition of fluorine-containing azoles bacterium aniline | |
CN103651441B (en) | Bactericidal composition containing dimoxystrobin | |
CN105494345B (en) | A kind of efficient bactericidal composite | |
CN104521978B (en) | A kind of bactericidal composition containing dimoxystrobin | |
CN104604863B (en) | A kind of bactericidal composition containing dimoxystrobin | |
CN105211082B (en) | A kind of composition pesticide containing dimoxystrobin | |
CN105284806B (en) | A kind of bactericidal composition containing zoxamide and methoxy acrylic | |
CN104412983B (en) | A kind of efficient bactericidal composite of fluorine-containing ether bacterium amide | |
CN104026135B (en) | A kind of efficient bactericidal composite containing fluorine mepanipyrim | |
CN104521975B (en) | A kind of bactericidal composition containing dimoxystrobin | |
CN104106582B (en) | A kind of bactericidal composition containing chlorine nalidixic bacterium ester and thiocarbamates | |
CN105211063B (en) | A kind of bactericidal composition containing dimoxystrobin and antibioticses | |
CN104012536B (en) | A kind of bactericidal composition of fluorine-containing mepanipyrim and methoxy acrylic | |
CN104115855B (en) | A kind of efficient bactericidal composite containing chlorine nalidixic bacterium ester | |
CN104412998B (en) | A kind of efficient bactericidal composite of fluorine-containing ether bacterium amide | |
CN104412996B (en) | A kind of high-efficient pesticide composition of fluorine-containing ether bacterium amide | |
CN105900990B (en) | A kind of bactericidal composition of Quinoxyfen-containinsterilization | |
CN104012556B (en) | A kind of bactericidal composition containing fluorine mepanipyrim and thiocarbamates | |
CN105685035B (en) | A kind of bactericidal composition containing dimoxystrobin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
|
CP03 | Change of name, title or address | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180518 |
|
CF01 | Termination of patent right due to non-payment of annual fee |