CN105494345B - A kind of efficient bactericidal composite - Google Patents
A kind of efficient bactericidal composite Download PDFInfo
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- CN105494345B CN105494345B CN201610044705.2A CN201610044705A CN105494345B CN 105494345 B CN105494345 B CN 105494345B CN 201610044705 A CN201610044705 A CN 201610044705A CN 105494345 B CN105494345 B CN 105494345B
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- bacterium amine
- volution bacterium
- active component
- disease
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 20
- 239000002131 composite material Substances 0.000 title claims abstract description 12
- 241000894006 Bacteria Species 0.000 claims abstract description 86
- 150000001412 amines Chemical class 0.000 claims abstract description 79
- 201000010099 disease Diseases 0.000 claims abstract description 47
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 239000005784 Fluoxastrobin Substances 0.000 claims abstract description 28
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims abstract description 28
- 239000005762 Dimoxystrobin Substances 0.000 claims abstract description 25
- WXUZAHCNPWONDH-DYTRJAOYSA-N dimoxystrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1COC1=CC(C)=CC=C1C WXUZAHCNPWONDH-DYTRJAOYSA-N 0.000 claims abstract description 25
- 230000000694 effects Effects 0.000 claims abstract description 17
- 239000000375 suspending agent Substances 0.000 claims description 22
- 239000000839 emulsion Substances 0.000 claims description 18
- 235000007164 Oryza sativa Nutrition 0.000 claims description 16
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 16
- 235000009566 rice Nutrition 0.000 claims description 16
- 241000221785 Erysiphales Species 0.000 claims description 14
- 241000233679 Peronosporaceae Species 0.000 claims description 13
- 239000003094 microcapsule Substances 0.000 claims description 13
- 206010039509 Scab Diseases 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 7
- 241001530056 Athelia rolfsii Species 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 28
- 239000005800 Kresoxim-methyl Substances 0.000 abstract description 26
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 abstract description 25
- 239000005857 Trifloxystrobin Substances 0.000 abstract description 24
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 abstract description 24
- 150000001875 compounds Chemical class 0.000 abstract description 13
- 230000000855 fungicidal effect Effects 0.000 abstract description 5
- 238000001228 spectrum Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 30
- 238000013329 compounding Methods 0.000 description 29
- 239000003814 drug Substances 0.000 description 28
- 230000010165 autogamy Effects 0.000 description 26
- 230000003449 preventive effect Effects 0.000 description 22
- 239000004563 wettable powder Substances 0.000 description 17
- 241000209094 Oryza Species 0.000 description 15
- 239000013530 defoamer Substances 0.000 description 13
- 239000000575 pesticide Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002270 dispersing agent Substances 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- -1 (ethyl) (n-propyl) amine Chemical class 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 231100000820 toxicity test Toxicity 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 241000209140 Triticum Species 0.000 description 7
- 235000021307 Triticum Nutrition 0.000 description 7
- 230000002528 anti-freeze Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- 239000000080 wetting agent Substances 0.000 description 7
- 206010067482 No adverse event Diseases 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 5
- 238000013401 experimental design Methods 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 4
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 4
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 4
- 206010011732 Cyst Diseases 0.000 description 4
- 241000510928 Erysiphe necator Species 0.000 description 4
- 241000220223 Fragaria Species 0.000 description 4
- 235000016623 Fragaria vesca Nutrition 0.000 description 4
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 235000014443 Pyrus communis Nutrition 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 239000004562 water dispersible granule Substances 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 102000019265 Cytochrome c1 Human genes 0.000 description 1
- 108010007528 Cytochromes c1 Proteins 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000005837 Spiroxamine Substances 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- PUYXTUJWRLOUCW-UHFFFAOYSA-N spiroxamine Chemical compound O1C(CN(CC)CCC)COC11CCC(C(C)(C)C)CC1 PUYXTUJWRLOUCW-UHFFFAOYSA-N 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of efficient bactericidal composite, the bactericidal composition containing active components A Yu active component B, active components A is selected from volution bacterium amine, and active component B is selected from any one following compound：Trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160, and active components A and active component B weight ratio are 80: 1~1: 60.The present composition has greater activity to the multiple diseases in various crop, and has obvious synergistic effect, expands fungicidal spectrum.And with the characteristics of dosage is small, resistance of rainwater washing against, and synergy is obvious.
Description
The application is divisional application, and original application is " a kind of high for the patent application of Shaanxi Welch Crop Protection Co., Ltd.
Imitate bactericidal composition ", the application Wei ︰ 2012101230406 of original application, original application day 2012.04.24.
Technical field
The invention belongs to technical field of pesticide, is related to a kind of application of efficient bactericidal composite in crop disease.
Technical background
Volution bacterium amine (Spiroxamine) chemical name：8- the tert-butyl group -1,4- dioxo spiros [4,5] decane -2- ylmethyls
(ethyl) (n-propyl) amine.Volution bacterium amine is that a kind of new, absorbability foliage fungicide is especially effective to powdery mildew.Effect
The fast and lasting period is grown, and has protection and therapeutic action concurrently.Both it can be used alone, can be killed again with other fungicide compoundings with expanding
Bacterium is composed.
Trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160 belong to methoxy acrylic bactericide.
The bactericide of methoxy acrylic is the outer inhibitor of quinone, by block cell pigment b and the electron transmission of cytochrome c 1,
Suppress mitochondrial respiratory.Systemic fungicide, there is protectiveness, therapeutic, eradicant and long residual effect, suppress spore germination.
In the real process of agricultural production, controlling disease is easiest to generate the problem that the generation of disease drug resistance.No
Compounded with kind composition, be to prevent and treat the very common method of resistance disease.Heterogeneity is compounded, and is imitated according to practical application
Fruit, to judge that certain compounding is synergy plus and or antagonism.In most cases, the compounding effect of agricultural chemicals is all to add
And effect, really have that the compounding of synergistic effect is seldom, especially synergistic effect clearly, the very high compounding of synergy ratio just more
It is few.Study, found volution bacterium amine and trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160 by inventor
Mutually compounding, there is a good synergistic effect within the specific limits, and about volution bacterium amine and trifloxystrobin, fluoxastrobin, dimoxystrobin,
The related compounding of kresoxim-methyl, ZEN 90160, at present at home and abroad there is not yet relevant report.
The content of the invention
There is synergistic function, the efficient sterilizing group that use cost is low, preventive effect is good the purpose of the present invention is to propose to a kind of
Compound.
The present invention is to be achieved through the following technical solutions：
A kind of efficient bactericidal composite, containing active components A and active component B, active components A and active component B weight
Than for 80: 1~1: 60, described active components A is selected from volution bacterium amine, active component B is selected from trifloxystrobin, fluoxastrobin, ether bacterium
One kind in amine, kresoxim-methyl, ZEN 90160.Active components A and active component B preferred weight ratio are 60: 1~1: 20；More
Preferably the weight ratio of volution bacterium amine and trifloxystrobin is the ︰ 10 of 30 ︰ 1~1；Volution bacterium amine and the weight of fluoxastrobin ratio be 30 ︰ 1~
1 ︰ 10；Volution bacterium amine and the weight of dimoxystrobin ratio are the ︰ 10 of 30 ︰ 1~1；Volution bacterium amine and the weight of kresoxim-methyl ratio be 30 ︰ 1~
1 ︰ 10；Volution bacterium amine and the weight of ZEN 90160 ratio are the ︰ 10 of 20 ︰ 1~1.
Described efficient bactericidal composite, it can be made into wettable powder, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspension
Agent, microcapsule suspension-suspendinagent agent, water dispersible granules, suspending agent can also be made.
Described efficient bactericidal composite is used for the disease for preventing and treating crop, and described crop includes fruit tree, vegetables, grain and made
Thing, ornamental plant, fibre crops.
Described disease include powdery mildew, moire disease, rust, stripe disease, downy mildew, rice blast, banded sclerotial blight, leaf spot,
Brown spot, net blotch, glume blight, scab, early blight, late blight, gray mold, anthracnose.
The amount of application when content of active component depends on being used alone in the present composition, also depends on a kind of chemical combination
Thing and the mixed ratio and synergistic effect degree of another compound, at the same it is also relevant with target disease.In usual composition
The weight percentage of active component is the 1%~90% of gross weight, preferably 5%~80%.According to different preparation classes
Type, active component content scope are different.Generally, liquid preparation contains by weight 1%~60% active material, preferably
Ground is 5%~50%；Solid pharmaceutical preparation contains by weight 5%~80% active material, preferably 10%~80%.
The present invention bactericidal composition at least contain a kind of surfactant, in favor of administration when active component in water
It is scattered.Surface-active contents are the 2%~30% of total formulation weight, and surplus is solid or liquid diluent.
Surfactant selected by the bactericidal composition of the present invention is known in those skilled in the art：It can be selected from
One or more in dispersant, wetting agent, thickener or defoamer.According to different dosage forms, this area can also be contained in preparation
Stabilizer, antifreeze well known to technical staff etc..
The bactericidal composition of invention can be used by user before use through dilution or directly.Its preparation can be by this area
Prepared by the processing method well known to technical staff, i.e., after active component is mixed with liquid flux or solid carrier, add table
One or more in face activating agent such as dispersant, stabilizer, wetting agent, binding agent, defoamer.
Composition includes following component and content when wettable powder is made：Active components A 1%~80%, active component
B 1%~60%, dispersant 1%~12%, wetting agent 1%~8%, filler surplus.
Composition includes following component and content when suspension emulsion is made：Active components A 0.5%~50%, active component B
0.5%~50%, emulsifying agent 1%~10%, dispersant 1%~10%, solvent 0~20%, defoamer 0.01%~2%, increasing
Thick dose 0~2%, antifreeze 0~8%, stabilizer 0~3%, deionized water add to 100%.
Composition includes following component and content when aqueous emulsion is made：Active components A 0.5%~50%, active component B
0.5%~50%, solvent 1%~20%, emulsifying agent 1%~12%, antifreeze 0~8%, defoamer 0.01%~2%, thickening
Agent 0~2%, deionized water add to 100%.
Composition includes following component and content when microemulsion is made：Active components A 0.5%~50%, active component B
0.5%~50%, emulsifying agent 3%~25%, solvent 1%~10%, antifreeze 0~8%, stabilizer 0~3%, defoamer
0.01%~2%, deionized water adds to 100%.
Composition includes following component and content when microcapsule suspending agent is made：Active components A 0.5%~50%, activity into
Divide B 0.5%~50%, macromolecule cyst material 1%~10%, dispersant 2%~10%, solvent 1%~10%, emulsifying agent
1%~7%, pH adjusting agent 0.01%~5%, defoamer 0.01%~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspension-suspendinagent agent is made：Active components A 0.5%~50%, live
Property composition B 0.5%~50%, macromolecule cyst material 1%~12%, dispersant 1%-12%, wetting agent 1%-8%, solvent
1%~15%, emulsifying agent 1%~8%, defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%,
Deionized water adds to 100%.
Composition includes following component and content when water dispersible granules are made：Active components A 1%~80%, active component
B 1%~60%, dispersant 1%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%, filler
Surplus.
Composition includes following component and content when suspending agent is made：Active components A 0.5%~50%, active component B
0.5%~50%, dispersant 1%~10%, wetting agent 1%~10%, defoamer 0.01%~2%, thickener 0~2%, anti-
Freeze agent 0~8%, deionized water adds to 100%.
The wettable powder the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The advantage of the invention is that：
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose；(2) agriculture
Medicinal dose is reduced, and is reduced residual quantity of the agricultural chemicals on crop, is mitigated environmental pollution；(3) fungicidal spectrum is expanded, to multiple diseases
As powdery mildew, moire disease, rust, stripe disease, downy mildew, rice blast, banded sclerotial blight, leaf spot, brown spot, net blotch, glume blight,
Scab, early blight, gray mold, anthracnose, late blight have greater activity.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The wettable powder of example 1~14
Volution bacterium amine, active component B, dispersant, wetting agent, filler are mixed, are well mixed in mixed cylinder, through air-flow
Pulverizer remixes uniformly after crushing, you can wettable powder product of the present invention is made.Specifically it is shown in Table 1,2.
The component of 1 example of table 1~8 and content
The each component of 2 example of table 9~14 and content
Trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160 in table are exchanged, novel formulation can be made.
The suspension emulsion of example 15~28
Dispersant, defoamer will be added in active component B, thickener, antifreeze, stabilizer, will be mixed by high speed shear
Uniformly, ball milling 2~3 hours in ball mill, make diameter of particle all below 5 μm, active component B suspending agents are made, then
Active components A, emulsifying agent, solvent and various auxiliary agents are directly emulsified in suspending agent with high speed agitator, institute of the present invention is made
The suspension emulsion product stated.Specifically it is shown in Table 3,4,5.
The each component of 3 example of table 15~19 and content
The each component of 4 example of table 19~22 and content
The each component of 5 example of table 23~28 and content
Trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160 in table are exchanged, novel formulation can be made.
The aqueous emulsion of example 29~42
Volution bacterium amine, active component B, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；By deionized water,
Antifreeze, thickener, defoamer mix, into homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added into oil phase, this is made
The described aqueous emulsion product of invention.Specifically it is shown in Table 6,7,8.
The each component of 6 example of table 29~32 and content
The each component of 7 example of table 33~36 and content
The each component of 8 example of table 37~42 and content
Trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160 in table are exchanged, novel formulation can be made.
The microemulsion of example 43~47
Volution bacterium amine, active component B are dissolved in the homogenizer equipped with solvent, by emulsifying agent, antifreeze, defoamer,
Stabilizer is added in the homogenizer equipped with above-mentioned solution, and surplus is mixed and homogenized strongly after being supplied with deionized water, most
The transparent microemulsion product of the present invention of clear appearance is obtained afterwards.Specifically it is shown in Table 9.
43~47 points of table 9 and content
Trifloxystrobin, fluoxastrobin, kresoxim-methyl, dimoxystrobin, ZEN 90160 in table are exchanged, novel formulation can be made.
The microcapsule suspending agent of example 48~52
Volution bacterium amine, active component B, macromolecule cyst material, solvent are mixed, makes to be dissolved into homogeneous oil phase, is shearing
Under the conditions of, by oil phase be added to containing emulsifying agent, pH adjusting agent, dispersant, defoamer aqueous phase solution in, surplus deionization
Water is supplied, and two kinds of materials react in oil-water interfaces, forms high score ascus wall, and well dispersed micro- of the present composition is made
Capsule suspending agent product.Specifically it is shown in Table 10.
10 48~52 each components of table and content
Trifloxystrobin, fluoxastrobin, dimoxystrobin, kresoxim-methyl, ZEN 90160 in table are exchanged, novel formulation can be made.
The microcapsule suspension-suspendinagent agent of example 53~56
Volution bacterium amine, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing condition
Under be added to containing emulsifying agent, pH adjusting agent aqueous phase solution in, well dispersed microcapsule suspending agent is made.By dispersant, wet
Profit agent, defoamer, thickener are well mixed by high speed shear, addition active component B, ball milling 2~3 hours in ball mill,
Make diameter of particle all below 5 μm, suspending agent is made, then suspending agent is added to the aqueous phase solution of micro-capsule suspension
In, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent product of the present composition is made.Specifically it is shown in Table 11.
The each component of 11 example of table 53~56 and content
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
It is fixed, clear and definite two kinds of medicaments compound by a certain percentage after synergy ratio (SR), SR ＜ 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR ＞ 1.5 are synergistic effect, on this basis, then carry out field test.
Test method：After prerun determines the effective inhibition concentration scope of each medicament, medicament sets 5 respectively by active constituent content
Individual dosage processing, if clear water compares.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum
Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley methods
Two medicament different ratio synergy ratios (SR) are calculated, SR ＜ 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action,
SR ＞ 1.5 are synergistic effect.Calculation formula is as follows：
Wherein：A, b is respectively active components A and active component B ratio shared in combination；
A is volution bacterium amine；
B is selected from one of trifloxystrobin, fluoxastrobin, kresoxim-methyl, dimoxystrobin, ZEN 90160 kind.
Application Example two：
For trying disease：Apple mildew.
Experimental design：Determine that volution bacterium amine and the effectively suppression of both trifloxystrobins different ratio mixture are dense by pilot study
Spend scope.
Toxicity test result
The volution bacterium amine of table 12 compounds the toxicity test analysis of results table to apple mildew with trifloxystrobin
As shown in Table 12, volution bacterium amine increases with the proportioning of trifloxystrobin compounding preventing and treating apple mildew in 1 80~60 ︰ 1 of ︰
Effect ratio SR is all higher than 1.5, illustrates that both show synergistic effect, volution bacterium amine and oxime at the mixture in the range of the ︰ 60 of 80 ︰ 1~1
The proportioning of bacterium ester is in the ︰ 10 of 30 ︰ 1~1；Synergistic effect is more prominent, and volution bacterium amine is 3 with trifloxystrobin weight ratio：Synergy ratio when 1
Maximum, synergistic effect are the most obvious.The proportioning that discovery volution bacterium amine and trifloxystrobin are tested through applicant is 30：1、25：1、20：1、
15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：
9、1：When 10, volution bacterium amine compounds withered to powdery mildew, moire disease, rust, stripe disease, downy mildew, rice blast, line with trifloxystrobin
The preventing and treating of disease, leaf spot, brown spot, net blotch, glume blight, scab, early blight, late blight has obvious synergistic effect,
Synergy ratio is more than 2.02.
Application Example three：
For trying disease：Wheat rust.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Having for volution bacterium amine and fluoxastrobin active compound and the two different ratio mixture is determined by pilot study
Imitate inhibition concentration scope.
Toxicity test result
The volution bacterium amine of table 13 compounds the toxicity test analysis of results table to wheat rust with fluoxastrobin
As shown in Table 13, volution bacterium amine increases with the proportioning of fluoxastrobin compounding preventing and treating wheat rust in 80 1~1 ︰ 60 of ︰
Effect ratio SR is all higher than 1.5, illustrates that both show synergistic effect, volution bacterium amine and fluorine at the mixture in the range of the ︰ 60 of 80 ︰ 1~1
The proportioning of Fluoxastrobin is in the ︰ 10 of 30 ︰ 1~1；Synergistic effect is more prominent, and volution bacterium amine is 3 with fluoxastrobin weight ratio：Synergy when 1
Ratio is maximum, and synergistic effect is the most obvious.The proportioning that discovery volution bacterium amine and fluoxastrobin are tested through applicant is 30：1、25：
1、20：1、15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、
1：8、1：9、1：When 10, volution bacterium amine is compounded to powdery mildew, moire disease, rust, stripe disease, downy mildew, rice blast with fluoxastrobin
The preventing and treating of disease, banded sclerotial blight, leaf spot, brown spot, net blotch, glume blight, scab, early blight, late blight has obvious increasing
Effect acts on, and synergy ratio is more than 2.01.
Application Example four：
For trying disease：Pear scab.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：The effective of volution bacterium amine and dimoxystrobin active compound and the two different ratio mixture is determined by pilot study
Inhibition concentration scope.
Toxicity test result
The volution bacterium amine of table 14 compounds the toxicity test analysis of results table to pear scab with dimoxystrobin
As shown in Table 14, volution bacterium amine increases with the proportioning of dimoxystrobin compounding preventing and treating pear scab in 80 1~1 ︰ 60 of ︰
Effect ratio SR is all higher than 1.5, illustrates that both show synergistic effect, volution bacterium amine and ether at the mixture in the range of the ︰ 60 of 80 ︰ 1~1
The proportioning of bacterium amine is in the ︰ 10 of 30 ︰ 1~1；Synergistic effect is more prominent, and volution bacterium amine is 3 with dimoxystrobin weight ratio：Synergy ratio when 1
Maximum, synergistic effect are the most obvious.The proportioning that discovery volution bacterium amine and dimoxystrobin are tested through applicant is 30：1、25：1、20：1、
15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：
9、1：When 10, volution bacterium amine compounds withered to powdery mildew, moire disease, rust, stripe disease, downy mildew, rice blast, line with dimoxystrobin
The preventing and treating of disease, leaf spot, brown spot, net blotch, glume blight, scab, early blight, late blight has obvious synergistic effect,
Synergy ratio is more than 2.02.
Application Example five：
For trying disease：Sigatoka.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Having for volution bacterium amine and kresoxim-methyl active compound and the two different ratio mixture is determined by pilot study
Imitate inhibition concentration scope.
Toxicity test result
The volution bacterium amine of table 15 compounds the toxicity test analysis of results table to sigatoka with kresoxim-methyl
As shown in Table 15, volution bacterium amine compounds the proportioning for preventing and treating sigatoka in 1 80~60 ︰ 1 of ︰ with kresoxim-methyl,
Synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at mixtures in the range of the ︰ 60 of 80 ︰ 1~1, volution bacterium amine with
The proportioning of kresoxim-methyl is in the ︰ 10 of 30 ︰ 1~1；Synergistic effect is more prominent, and volution bacterium amine is 3 with kresoxim-methyl weight ratio：Increase when 1
It is maximum to imitate ratio, synergistic effect is the most obvious.The proportioning that discovery volution bacterium amine and kresoxim-methyl are tested through applicant is 30：1、
25：1、20：1、15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、
1：7、1：8、1：9、1：When 10, volution bacterium amine and kresoxim-methyl compound to powdery mildew, moire disease, rust, stripe disease, downy mildew,
The preventing and treating of rice blast, banded sclerotial blight, leaf spot, brown spot, net blotch, glume blight, scab, early blight, late blight has substantially
Synergistic effect, synergy ratio is more than 2.17.
Application Example six：
For trying disease：Rice sheath blight disease.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Having for volution bacterium amine and ZEN 90160 active compound and the two different ratio mixture is determined by pilot study
Imitate inhibition concentration scope.
Toxicity test result
The volution bacterium amine of table 16 compounds the toxicity test analysis of results table to rice sheath blight disease with ZEN 90160
As shown in Table 16, volution bacterium amine compounds the proportioning for preventing and treating rice sheath blight disease in 1 80~60 ︰ 1 of ︰ with ZEN 90160,
Synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at mixtures in the range of the ︰ 60 of 80 ︰ 1~1, volution bacterium amine with
The proportioning of ZEN 90160 is in the ︰ 10 of 20 ︰ 1~1；Synergistic effect is more prominent, and volution bacterium amine is 2 with ZEN 90160 weight ratio：Increase when 1
It is maximum to imitate ratio, synergistic effect is the most obvious.The proportioning that discovery volution bacterium amine and ZEN 90160 are tested through applicant is 20：1、
15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：
9、1：When 10, volution bacterium amine compounds withered to powdery mildew, moire disease, rust, stripe disease, downy mildew, rice blast, line with ZEN 90160
The preventing and treating of disease, leaf spot, brown spot, net blotch, glume blight, scab, early blight, late blight has obvious synergistic effect,
Synergy ratio is more than 2.03.
The volution bacterium amine of Application Example seven and active component B and its compounding preventing and treating wheat rust test of pesticide effectiveness
This test arrangement is ground in Zaozhuang City of the Shandong Province Tai Er village, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, provide, 50% volution bacterium amine aqueous emulsion (purchased in market) of control, 25% trifloxystrobin suspending agent (autogamy), 10% fluoxastrobin missible oil
(autogamy), 20% dimoxystrobin wettable powder (autogamy), 20% kresoxim-methyl wettable powder (autogamy), 25% ZEN 90160 hang
Floating agent (autogamy).
Wheat rust feelings are investigated before medicine, in state of an illness first time at initial stage dispenser, every dispenser in 7 days once, is total to dispenser 3 times.3rd
7 days after secondary dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 30 days.Experimental result is as follows：
The volution bacterium amine of table 17 and active component B and its compounding preventing and treating wheat rust test of pesticide effectiveness
As can be seen from Table 17, volution bacterium amine is prevented and treated with can effectively prevent and treat sweet tea wheat rust after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is grown.Target crop is had no adverse effects in experiment scope of medication.
The volution bacterium amine of Application Example eight and active component B and its compounding preventing and treating uncinula necator test of pesticide effectiveness
This test arrangement is ground in Shaanxi Province Weinan suburban area, test medicine by Shaanxi Welch Crop Protection Co., Ltd.
Hair, provide, 50% volution bacterium amine aqueous emulsion (purchased in market) of control, 25% trifloxystrobin suspending agent (autogamy), 10% fluoxastrobin missible oil
(autogamy), 20% dimoxystrobin wettable powder (autogamy), 20% kresoxim-methyl wettable powder (autogamy), 25% ZEN 90160 hang
Floating agent (autogamy).
The uncinula necator state of an illness is investigated before medicine, in state of an illness first time at initial stage dispenser, every dispenser in 7 days once, is total to dispenser 2 times.
7 days after second of dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 30 days.Experimental result is as follows：
The volution bacterium amine of table 18 and active component B and its compounding preventing and treating uncinula necator test of pesticide effectiveness
As can be seen from Table 18, volution bacterium amine is prevented and treated with can effectively prevent and treat uncinula necator after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is grown.Target crop is had no adverse effects in experiment scope of medication.
The volution bacterium amine of Application Example nine and active component B and its compounding preventing and treating Chinese cabbage downy mildew test of pesticide effectiveness
This test arrangement in Shandong Province Zaozhuang, by Shaanxi Welch Crop Protection Co., Ltd. researched and developed, provided by test medicine,
Compare 50% volution bacterium amine aqueous emulsion (purchased in market), 25% trifloxystrobin suspending agent (autogamy), 10% fluoxastrobin missible oil (autogamy),
20% dimoxystrobin wettable powder (autogamy), 20% kresoxim-methyl wettable powder (autogamy), 25% chlorfenapyr suspending agent are (certainly
With).
The Chinese cabbage downy mildew state of an illness is investigated before medicine, in state of an illness first time at initial stage dispenser, every dispenser in 7 days once, is total to dispenser 2 times.
7 days after second of dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 30 days.Experimental result is as follows：
The volution bacterium amine of table 19 and active component B and its compounding preventing and treating Chinese cabbage downy mildew test of pesticide effectiveness
As can be seen from Table 19, volution bacterium amine is prevented and treated with can effectively prevent and treat Chinese cabbage downy mildew after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is grown.Target crop is had no adverse effects in experiment scope of medication.
The volution bacterium amine of Application Example ten and active component B and its compounding preventing and treating powdery mildew of strawberry test of pesticide effectiveness
This test arrangement in Liaocheng of Shandong Province, by Shaanxi Welch Crop Protection Co., Ltd. researched and developed, carried by test medicine
For 50% volution bacterium amine aqueous emulsion (purchased in market) of control, 25% trifloxystrobin suspending agent (autogamy), 10% fluoxastrobin missible oil are (certainly
With), 20% dimoxystrobin wettable powder (autogamy), 20% kresoxim-methyl wettable powder (autogamy), 25% ZEN 90160 suspend
Agent (autogamy).
The powdery mildew of strawberry medicine state of an illness is investigated, in state of an illness first time at initial stage dispenser, every dispenser in 7 days once, is total to dispenser 2 times.The
7 days after secondary dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 30 days.Experimental result is as follows：
The volution bacterium amine of table 20 and active component B and its compounding preventing and treating powdery mildew of strawberry test of pesticide effectiveness
As can be seen from Table 20, volution bacterium amine is prevented and treated with can effectively prevent and treat powdery mildew of strawberry after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is grown.Target crop is had no adverse effects in experiment scope of medication.
The volution bacterium amine of Application Example 11 and active component B and its compounding preventing and treating sigatoka test of pesticide effectiveness
This experimental arrangement in Nanning, by Shaanxi Welch Crop Protection Co., Ltd. researched and developed, provided by test medicine,
Compare 50% volution bacterium amine aqueous emulsion (purchased in market), 25% trifloxystrobin suspending agent (autogamy), 10% fluoxastrobin missible oil (autogamy),
20% dimoxystrobin wettable powder (autogamy), 20% kresoxim-methyl wettable powder (autogamy), 25% chlorfenapyr suspending agent are (certainly
With).
The sigatoka state of an illness is investigated before medicine, in state of an illness first time at initial stage dispenser, every dispenser in 7 days once, is total to dispenser 2 times.
7 days after second of dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 30 days.Experimental result is as follows：
The volution bacterium amine of table 21 and active component B and its compounding preventing and treating sigatoka test of pesticide effectiveness
As can be seen from Table 21, volution bacterium amine is prevented and treated with can effectively prevent and treat sigatoka after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is grown.Target crop is had no adverse effects in experiment scope of medication.
The volution bacterium amine of Application Example 12 and active component B and its compounding preventing and treating rice blast test of pesticide effectiveness
This test arrangement in Shaanxi Province's Hanzhong City, by Shaanxi Welch Crop Protection Co., Ltd. researched and developed, carried by test medicine
For 50% volution bacterium amine aqueous emulsion (purchased in market) of control, 25% trifloxystrobin suspending agent (autogamy), 10% fluoxastrobin missible oil are (certainly
With), 20% dimoxystrobin wettable powder (autogamy), 20% kresoxim-methyl wettable powder (autogamy), 25% ZEN 90160 suspend
Agent (autogamy).
The rice blast state of an illness is investigated before medicine, in state of an illness first time at initial stage dispenser, every dispenser in 7 days once, is total to dispenser 3 times.
7 days after third time dispenser, disease index is investigated respectively and calculates preventive effect within 14 days, 30 days.Experimental result is as follows：
The volution bacterium amine of table 22 and active component B and its compounding preventing and treating rice blast test of pesticide effectiveness
As can be seen from Table 22, volution bacterium amine is prevented and treated with can effectively prevent and treat rice blast after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is grown.Target crop is had no adverse effects in experiment scope of medication.
The experiment by different places throughout the country is drawn afterwards, volution bacterium amine and trifloxystrobin, fluoxastrobin, dimoxystrobin,
Kresoxim-methyl, ZEN 90160 compounding after to the powdery mildew in various crop, moire disease, rust, stripe disease, downy mildew, rice blast,
The common diseases such as banded sclerotial blight, leaf spot, brown spot, net blotch, glume blight, scab, early blight, gray mold, anthracnose, late blight
Harmful preventive effect 95% with excellent, it is obvious in single dose preventive effect, synergistic effect.
Claims (5)
- A kind of 1. efficient bactericidal composite, it is characterised in that containing active components A and active component B, active components A and activity into It is 80: 1~1: 60 to divide B weight ratio, and described active components A is selected from volution bacterium amine, and active component B is selected from fluoxastrobin, ether bacterium One of amine, ZEN 90160 are planted.
- 2. efficient bactericidal composite according to claim 1, it is characterised in that：Active components A and active component B weight Than for the ︰ 20 of 60 ︰ 1~1.
- 3. efficient bactericidal composite according to claim 2, it is characterised in that：Volution bacterium amine and the weight of fluoxastrobin ratio For the ︰ 10 of 30 ︰ 1~1；Volution bacterium amine and the weight of dimoxystrobin ratio are the ︰ 10 of 30 ︰ 1~1；Volution bacterium amine and the weight of ZEN 90160 ratio For the ︰ 10 of 20 ︰ 1~1.
- 4. according to the efficient bactericidal composite described in any one in claim 1-3, it is characterised in that：Composition is made wettable Property pulvis, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
- 5. efficient bactericidal composite according to claim 4, it is characterised in that：Composition is used to prevent and treat powdery mildew, moire Disease, rust, stripe disease, downy mildew, rice blast, banded sclerotial blight, leaf spot, brown spot, net blotch, glume blight, scab, early epidemic Disease, gray mold, late blight, the purposes of anthracnose.
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| CN106212483A (en) * | 2016-08-16 | 2016-12-14 | 田文华 | A kind of containing fluoxastrobin with the bactericidal composition of fluorine azoles Acibenzolar |
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| US4851405A (en) * | 1987-03-07 | 1989-07-25 | Bayer Aktiengesellschaft | Aminomethyl heterocyclic compounds |
| WO2001037666A2 (en) * | 1999-11-22 | 2001-05-31 | Bayer Aktiengesellschaft | Fungicidally active substance combinations |
| CN101218914A (en) * | 1996-12-13 | 2008-07-16 | 拜尔作物科学股份公司 | Plant protection agents |
| CN102308824A (en) * | 2011-04-26 | 2012-01-11 | 陕西韦尔奇作物保护有限公司 | Bactericide composition containing spiroxamine and methoxyl acrylate |
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| PH11991042549B1 (en) * | 1990-06-05 | 2000-12-04 | ||
| RU2001117068A (en) * | 1998-11-20 | 2003-06-27 | Байер Акциенгезельшафт (De) | COMBINATIONS OF SUBSTANCES WITH FUNGICIDAL ACTIVITY |
| DE10103832A1 (en) * | 2000-05-11 | 2001-11-15 | Bayer Ag | Synergistic combination of fungicides for use in plant protection, comprises 2-(pyrimidinyloxy-phenyl)-2-(methoxyimino)-N-methyl-acetamide derivative and e.g. spiroxamine, quinoxyfen or tebuconazole |
| ZA200707407B (en) * | 2005-02-04 | 2008-11-26 | Mitsui Chemicals Inc | Composition for preventing plant diseases and method for preventing the diseases |
| DE102005058838A1 (en) * | 2005-12-09 | 2007-06-14 | Bayer Cropscience Ag | Fungicidal combination of active ingredients |
| AR069187A1 (en) * | 2007-11-05 | 2010-01-06 | Basf Se | METHOD, USE AND AGENT TO PROTECT A PLANT AGAINST PHAKOPSORA |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4851405A (en) * | 1987-03-07 | 1989-07-25 | Bayer Aktiengesellschaft | Aminomethyl heterocyclic compounds |
| CN101218914A (en) * | 1996-12-13 | 2008-07-16 | 拜尔作物科学股份公司 | Plant protection agents |
| WO2001037666A2 (en) * | 1999-11-22 | 2001-05-31 | Bayer Aktiengesellschaft | Fungicidally active substance combinations |
| CN102308824A (en) * | 2011-04-26 | 2012-01-11 | 陕西韦尔奇作物保护有限公司 | Bactericide composition containing spiroxamine and methoxyl acrylate |
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