CN104206388B - A kind of composition pesticide of fluorine-containing azoles bacterium aniline - Google Patents
A kind of composition pesticide of fluorine-containing azoles bacterium aniline Download PDFInfo
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- CN104206388B CN104206388B CN201310210950.2A CN201310210950A CN104206388B CN 104206388 B CN104206388 B CN 104206388B CN 201310210950 A CN201310210950 A CN 201310210950A CN 104206388 B CN104206388 B CN 104206388B
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- Prior art keywords
- fluorine
- azoles bacterium
- bacterium aniline
- fluorine azoles
- aniline
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- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 title claims abstract description 228
- 241000894006 Bacteria Species 0.000 title claims abstract description 143
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 43
- 239000011737 fluorine Substances 0.000 title claims abstract description 43
- 150000003851 azoles Chemical class 0.000 title claims abstract description 37
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000000575 pesticide Substances 0.000 title claims abstract description 27
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical class [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 claims abstract description 95
- 201000010099 disease Diseases 0.000 claims abstract description 52
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 52
- 230000000694 effects Effects 0.000 claims abstract description 16
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- 239000000375 suspending agent Substances 0.000 claims description 20
- 239000003094 microcapsule Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 11
- 244000052769 pathogen Species 0.000 claims description 10
- 230000001717 pathogenic effect Effects 0.000 claims description 10
- 239000004563 wettable powder Substances 0.000 claims description 10
- 241000233652 Chytridiomycota Species 0.000 claims description 6
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 37
- 239000005820 Prochloraz Substances 0.000 abstract description 22
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 abstract description 22
- 239000005842 Thiophanate-methyl Substances 0.000 abstract description 20
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 abstract description 20
- 239000005754 Cyazofamid Substances 0.000 abstract description 19
- 239000005774 Fenamidone Substances 0.000 abstract description 19
- YXKMMRDKEKCERS-UHFFFAOYSA-N cyazofamid Chemical compound CN(C)S(=O)(=O)N1C(C#N)=NC(Cl)=C1C1=CC=C(C)C=C1 YXKMMRDKEKCERS-UHFFFAOYSA-N 0.000 abstract description 19
- LMVPQMGRYSRMIW-KRWDZBQOSA-N fenamidone Chemical compound O=C([C@@](C)(N=C1SC)C=2C=CC=CC=2)N1NC1=CC=CC=C1 LMVPQMGRYSRMIW-KRWDZBQOSA-N 0.000 abstract description 19
- 229910021380 Manganese Chloride Inorganic materials 0.000 abstract description 18
- 229940099607 manganese chloride Drugs 0.000 abstract description 18
- 239000011565 manganese chloride Substances 0.000 abstract description 18
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical compound Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 abstract description 18
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 abstract description 17
- 239000006013 carbendazim Substances 0.000 abstract description 17
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 abstract description 17
- 150000001875 compounds Chemical class 0.000 abstract description 12
- 230000000855 fungicidal effect Effects 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract 1
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- 230000003449 preventive effect Effects 0.000 description 21
- 238000012360 testing method Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000003814 drug Substances 0.000 description 15
- 241000209094 Oryza Species 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 14
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- 231100000820 toxicity test Toxicity 0.000 description 14
- 241000221785 Erysiphales Species 0.000 description 13
- 235000007164 Oryza sativa Nutrition 0.000 description 13
- 239000002270 dispersing agent Substances 0.000 description 13
- 235000009566 rice Nutrition 0.000 description 13
- 240000008067 Cucumis sativus Species 0.000 description 12
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 12
- 239000013530 defoamer Substances 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 12
- 241000233679 Peronosporaceae Species 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 9
- 241000209140 Triticum Species 0.000 description 8
- 235000021307 Triticum Nutrition 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 230000005764 inhibitory process Effects 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 230000002528 anti-freeze Effects 0.000 description 7
- -1 compound fluorine azoles Chemical class 0.000 description 7
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- 229940079593 drug Drugs 0.000 description 6
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- 150000001412 amines Chemical class 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
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- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- GOFJDXZZHFNFLV-UHFFFAOYSA-N 5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]pyrazole-4-carboxamide Chemical compound CC(C)CC(C)C1=CC=CC=C1NC(=O)C1=C(F)N(C)N=C1C GOFJDXZZHFNFLV-UHFFFAOYSA-N 0.000 description 1
- 241000222382 Agaricomycotina Species 0.000 description 1
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- 241000221760 Claviceps Species 0.000 description 1
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- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 241000371644 Curvularia ravenelii Species 0.000 description 1
- 241000228436 Dothideales Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000015220 Febrile disease Diseases 0.000 description 1
- 241000221661 Helotiales Species 0.000 description 1
- 241000193034 Myriangiales Species 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- 239000005815 Penflufen Substances 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 241000122123 Penicillium italicum Species 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 241001223281 Peronospora Species 0.000 description 1
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- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 241001503460 Plasmodiophorida Species 0.000 description 1
- 241000221300 Puccinia Species 0.000 description 1
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- 241001361634 Rhizoctonia Species 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- 241000233656 Saprolegniales Species 0.000 description 1
- 241001533598 Septoria Species 0.000 description 1
- 102000019259 Succinate Dehydrogenase Human genes 0.000 description 1
- 108010012901 Succinate Dehydrogenase Proteins 0.000 description 1
- 241001544321 Thanatephorus cucumeris Species 0.000 description 1
- 241000722133 Tilletia Species 0.000 description 1
- 241000031845 Tilletia laevis Species 0.000 description 1
- 239000005858 Triflumizole Substances 0.000 description 1
- 241001154828 Urocystis <tapeworm> Species 0.000 description 1
- 241000221576 Uromyces Species 0.000 description 1
- 241000221561 Ustilaginales Species 0.000 description 1
- 241000233791 Ustilago tritici Species 0.000 description 1
- 241001645362 Valsa Species 0.000 description 1
- 241000082085 Verticillium <Phyllachorales> Species 0.000 description 1
- 208000000260 Warts Diseases 0.000 description 1
- 241001314279 Zoopagales Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
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- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
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- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of composition pesticide of fluorine-containing azoles bacterium aniline, active ingredient is active components A and active component B, and active components A is selected from fluorine azoles bacterium aniline, and active component B is selected from any one following compound：Fluorine bacterium azoles, Prochloraz, prochloraz-manganese chloride complex, Fenamidone, thiophanate-methyl, carbendazim or cyazofamid, and active components A and active component B weight ratio are 1:80~80:1.The present composition has greater activity to the multiple diseases in various crop, and has obvious synergistic effect, expands fungicidal spectrum.And with the characteristics of dosage is small, resistance of rainwater washing against, and synergy is obvious.
Description
Technical field
The invention belongs to technical field of pesticide, is related to a kind of composition pesticide of fluorine-containing azoles bacterium aniline in crop disease
Using.
Technical background
Fluorine azoles bacterium aniline（penflufen）：Molecular formula is C18H24FN3O, chemical name are 2 ＇-[(RS) -1,3- dimethyl
Butyl] fluoro- 1, the 3- dimethyl pyrazoles -4- formailides of -5-, fluorine azoles bacterium aniline is a kind of succinate dehydrogenase inhibitors, mainly
Respiratory chain electron transmission Complex II is acted on, blocks energetic supersession；Kind of a biography can be prevented and treated, the basidiomycetes and ascomycosis that soil passes
Evil, mainly there is black scurf of potato caused by rhizoctonia, wheat sharp eyespot, rice sheath blight disease, sclerotinia sclerotiorum etc., also wheat
Smut, the bunt of wheat, corn southern leaf blight etc..Seed after processing can absorb fluorine azoles bacterium benzene in germination process
Amine, other positions of plant are transmitted to by xylem, play a part of cover crop.
Fluorine bacterium azoles, Prochloraz and its salt, Fenamidone, thiophanate-methyl, carbendazim or cyazofamid belong to conventional sterilization
Agent, it is widely used in the disease of crops, the wherein salt of Prochloraz can be prochloraz-manganese chloride complex and prochloraz nantokite, fluorine azoles bacterium benzene
Amine may also be fabricated which missible oil with fluorine bacterium azoles or Prochloraz.
In the real process of agricultural production, controlling disease is easiest to generate the problem that the drug-fast generation of germ.No
Compounded with kind composition, be to prevent and treat the very common method of resistance germ.Heterogeneity is compounded, and is imitated according to practical application
Fruit, to judge that certain compounding is synergy plus and or antagonism.In most cases, the compounding effect of agricultural chemicals is all to add
And effect, really have that the compounding of synergistic effect is seldom, especially synergistic effect clearly, the very high compounding of synergy ratio just more
It is few.Studied by inventor, find with effective active composition B mutually to compound fluorine azoles bacterium aniline, have within the specific limits very
Good synergistic effect, and about fluorine azoles bacterium aniline and fluorine bacterium azoles, Prochloraz, prochloraz-manganese chloride complex, Fenamidone, thiophanate-methyl,
The related compounding of carbendazim or cyazofamid, at present at home and abroad there is not yet relevant report.
The content of the invention
There is synergistic function, the fluorine-containing azoles bacterium benzene that use cost is low, preventive effect is good the purpose of the present invention is to propose to a kind of
The composition pesticide of amine.
A kind of composition pesticide of fluorine-containing azoles bacterium aniline, active ingredient are active components A and active component B, active components A
It is 1 with active component B weight ratio:80~80:1, described active components A is selected from fluorine azoles bacterium aniline, and active component B is selected from fluorine bacterium
One kind in azoles, Prochloraz, prochloraz-manganese chloride complex, Fenamidone, thiophanate-methyl, carbendazim or cyazofamid, active components A and work
Property composition B preferred weight ratio be 1:60~60:1；More preferably：Fluorine azoles bacterium aniline and the weight ratio of fluorine bacterium azoles are 1:20~
20:1, the weight ratio of fluorine azoles bacterium aniline and Prochloraz is 1:25~15:1, the weight ratio of fluorine azoles bacterium aniline and prochloraz-manganese chloride complex is
1:25~20:1, the weight ratio of fluorine azoles bacterium aniline and Fenamidone is 1:20~20:1, fluorine azoles bacterium aniline and thiophanate-methyl
Weight ratio is 1:25~15:1, the weight ratio of fluorine azoles bacterium aniline and carbendazim is 1:30~15:1, fluorine azoles bacterium aniline and cyazofamid
Weight ratio be 1:20~20:1；Most preferably：Fluorine azoles bacterium aniline and the weight ratio of fluorine bacterium azoles are 1:9~9:1, fluorine azoles bacterium aniline
Weight ratio with Prochloraz is 1:14~4:1, the weight ratio of fluorine azoles bacterium aniline and prochloraz-manganese chloride complex is 1:9~9:1, fluorine azoles bacterium benzene
The weight of amine and Fenamidone ratio is 1:9~9:1, the weight ratio of fluorine azoles bacterium aniline and thiophanate-methyl is 1:14~4:1, fluorine azoles
The weight of bacterium aniline and carbendazim ratio is 1:14~4:1, the weight ratio of fluorine azoles bacterium aniline and cyazofamid is 1:9~9:1.
The composition pesticide of described fluorine-containing azoles bacterium aniline, is made wettable powder, water dispersible granules, suspending agent, water and milk
Agent, microemulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
The composition pesticide of described fluorine-containing azoles bacterium aniline is used for the disease for preventing and treating crops, and described crops include grain
It is food crop, legume crop, oil crops, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, thermophilic
Good crop, root crop, flower crop, medicinal crop, crop and green manure pasture crop.
Described disease is caused by Basidiomycotina, Ascomycotina, Mastigomycotina or Deuteromycotina pathogen
Disease, the pathogen of wherein Basidiomycotina has Teliomycetes, Hymenomycetes, Heterobasidiomycetae, Holobasidiomycetidae
And Gasteromycete, Puccinia of its Teliomycetes including Uredinales, Uromyces, glue Rust, Phakopsora, more spore rest fungus
The double spore Rust of category, wart, grid Rust, Ustilaginales, Ustilago, Urocystis, leaf Ustilago, Tilletia,
Kernel smut category, real ball Ustilago and axle Ustilago, disease caused by Basidiomycotina pathogen mainly have smut, raw meat
Smut, banded sclerotial blight or rust etc.；Ascomycotina pathogen have Hemiascomycetes, Plectomycetes, gang pyrenomycetes, chamber Gammaproteobacteria and
Discomycete, its gang pyrenomycetes include Erysiphales and Spheeriales, and Spheeriales has long beak shell category, Gibberella, Valsa, top
Softgel shell category and Claviceps, its chamber Gammaproteobacteria have Myriangiales, Dothideales, lattice spore chamber Zoopagales, and discomycete has Helotiales, ascus
Major Diseases caused by bacterium subphylum pathogen have powdery mildew, sclerotiniose etc.；Mastigomycotina disease has Plasmodiophoromycetes, Chytridiomycetes and ovum
Gammaproteobacteria, Oomycete include Saprolegniales and Peronosporales, and Peronosporales includes pythium, Phytophthora and Peronospora, and it represents Major Diseases
There are downy mildew or epidemic disease etc.；Deuteromycotina pathogen has Hyphomycetes and Coelomycetes, and wherein Hyphomycetes includes Pyricularia Sacc., powder spore
Category, Penicillium, Cercospora, Fusarium, Verticillium, interlink spore genus, Bipolaris, prominent navel Helminthosporium, Drechslera, silk
Pyrenomycetes category, Coelomycetes include Colletotrichum, Pestalotia, Phoma, big stem point category, phomopsis genus, Septoria, color two
Spore category, Ascochyta, its caused Major Diseases have gray mold, damping-off, rice blast, anthracnose, scab, rice sheath blight disease,
Penicilliosis, corn big (small) pinta, false smut etc..
The amount of application when content of active component depends on being used alone in the bactericidal composition of the present invention, also depends on one
The mixed ratio and synergistic effect degree of kind compound and another compound, at the same it is also relevant with target disease.Usual group
The weight percentage of active component is the 1%~90% of gross weight, preferably 5%~80% in compound.According to different preparations
Type, active component content scope are different.Generally, liquid preparation contains by weight 1%~60% active material, preferably
Ground is 5%~50%；Solid pharmaceutical preparation contains by weight 5%~80% active material, preferably 10%~80%.
The present invention bactericidal composition at least contain a kind of surfactant, in favor of administration when active component in water
It is scattered.Surface-active contents are the 2%~30% of total formulation weight, and surplus is solid or liquid diluent.
Surfactant selected by the bactericidal composition of the present invention is known in those skilled in the art, by user
Through dilution or directly using its preparation before use, it can be prepared, will lived by processing method known in those skilled in the art
After property composition mixes with liquid flux or solid carrier, surfactant such as dispersant, stabilizer, wetting agent, bonding are added
One or more in agent, defoamer etc..
Composition includes following component and content when wettable powder is made：Active components A 0.5%~80%, active component
B0.5%~80%, dispersant 1%~12%, wetting agent 1%~8%, filler surplus.
Composition includes following component and content when water dispersible granules are made：Active components A 0.5%~80%, active component
B0.5%~80%, dispersant 1%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%, filler surplus.
Composition includes following component and content when suspending agent is made：Active components A 0.5%~50%, active component B0.5%
~50%, dispersant 1%~10%, wetting agent 1%~10%, defoamer 0.01%~2%, thickener 0~2%, antifreeze 0~8%, go
Ionized water adds to 100%.
Composition includes following component and content when suspension emulsion is made：Active components A 0.5%~50%, active component B0.5%
~50%, emulsifying agent 1%~10%, dispersant 1%~10%, solvent 0~20%, defoamer 0.01%~2%, thickener 0~2%, freeze proof
Agent 0~8%, stabilizer 0~3%, deionized water add to 100%.
Composition includes following component and content when aqueous emulsion is made：Active components A 0.5%~50%, active component B0.5%
~50%, solvent 1%~20%, emulsifying agent 1%~12%, antifreeze 0~8%, defoamer 0.01%~2%, thickener 0~2%, go from
Sub- water adds to 100%.
Composition includes following component and content when microemulsion is made：Active components A 0.5%~50%, active component B0.5%
~50%, emulsifying agent 3%~25%, solvent 1%~10%, antifreeze 0~8%, stabilizer 0~3%, defoamer 0.01%~2%, go from
Sub- water adds to 100%.
Composition includes following component and content when microcapsule suspending agent is made：Active components A 0.5%~50%, active component
B0.5%~50%, macromolecule cyst material 1%~10%, dispersant 2%~10%, solvent 1%~10%, emulsifying agent 1%~7%, pH are adjusted
Section agent 0.01%~5%, defoamer 0.01%~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspension-suspendinagent agent is made：Active components A 0.5%~50%, activity
Composition B0.5%~50%, macromolecule cyst material 1%~12%, dispersant 1%-12%, wetting agent 1%-8%, solvent 1%~15%, breast
Agent 1%~8%, defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：（1）The present composition has good synergy and lasting effect within the specific limits, prevents
Effect is higher than single dose；（2）Pesticide usage amount is reduced, and is reduced residual quantity of the agricultural chemicals on crop, is mitigated environmental pollution；（3）Expand
Fungicidal spectrum, to the multiple diseases such as line caused by Basidiomycotina, Ascomycotina, Mastigomycotina or Deuteromycotina pathogen
Rot, sclerotiniose, rust, smut, bunt, helminthosporium maydis, powdery mildew, downy mildew, epidemic disease, gray mold, damping-off, rice
The diseases such as seasonal febrile diseases, anthracnose, scab, penicilliosis or false smut have special efficacy.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~20
Fluorine azoles bacterium aniline, active ingredient B, dispersant, wetting agent, filler are mixed, are well mixed in mixed cylinder, through gas
Stream pulverizer remixes uniformly after crushing, you can wettable powder product of the present invention is made.Specifically it is shown in Table 1.
The each component of 1 embodiment of table 1~20 and content
The water dispersible granules of embodiment 21~40
By fluorine azoles bacterium aniline, active component B, dispersant, wetting agent, binding agent（Can add to be not added with）, disintegrant, filler one
The particle diameter needed through air-flow crushing is played, obtains materials of pelletizing.Item is quantified to be sent into fluidized bed granulating dryer and passed through
After pelletizing and drying, water dispersible granules product of the present invention is made.Specifically it is shown in Table 2.
The each component of 2 embodiment of table 21~40 and content
The suspending agent of embodiment 41~60
By dispersant, wetting agent, defoamer, thickener（Can add to be not added with）, antifreeze（Can add to be not added with）By at a high speed
Shear-mixed is uniform, adds fluorine azoles bacterium aniline, active component B, and surplus is supplied with deionized water, and ball milling 2~3 is small in ball mill
When, make diameter of particle all below 5 μm, suspending agent product of the present invention is made.Specifically it is shown in Table 3.
The each component of 3 embodiment of table 41~60 and content
By active component B fluorine bacterium azoles, Prochloraz, prochloraz-manganese chloride complex, Fenamidone, thiophanate-methyl, more bacterium in table 1~3
Spirit or cyazofamid exchange, and novel formulation can be made.
The suspension emulsion of embodiment 61~68
By dispersant, defoamer, thickener in above-mentioned formulation material（Can add to be not added with）, antifreeze（Can add to be not added with）, warp
It is uniform to cross high speed shear-mixed, adds fluorine azoles bacterium aniline, ball milling 2~3 hours in ball mill, makes diameter of particle all at 5 μm
Hereinafter, fluorine azoles bacterium aniline suspending agent is made, it is then that active component B, solvent, emulsifying agent and various auxiliary agent high speed agitators is straight
Emulsification is connect into suspending agent, suspension emulsion product of the present invention is made.Specifically it is shown in Table 4.
The each component of 4 embodiment of table 61~68 and content
The aqueous emulsion of embodiment 69~76
Fluorine azoles bacterium aniline, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Active component B, by deionization
Water, antifreeze（Can add to be not added with）, thickener（Can add to be not added with）, defoamer mix, into homogeneous aqueous phase.In high-speed stirring
Mix down, aqueous phase is added into oil phase, aqueous emulsion product of the present invention is made.Specifically it is shown in Table 5.
The each component of 5 embodiment of table 69~76 and content
The microemulsion of embodiment 77~84
By fluorine azoles bacterium aniline, active component B, solvent, emulsifying agent, antifreeze（Can add to be not added with）, defoamer is sufficiently mixed
Into the oil phase of homogeneous transparent, deionized water is slowly added under agitation, is formed WO emulsion, then agitated heating, is made
Rapid phase inversion into oil-in-water type, be cooled to room temperature and make up to balance, filtered, surplus is supplied with deionized water；It can be prepared by
Microemulsion product of the present invention, is specifically shown in Table 6.
The each component of 6 embodiment of table 77~84 and parts by weight
Active component B fluorine bacterium azoles, Prochloraz, Fenamidone, thiophanate-methyl, carbendazim or cyazofamid in table 4~6 is mutual
Change, novel formulation can be made.
Embodiment 85,86 microcapsule suspending agents
Fluorine azoles bacterium aniline, active component B, macromolecule cyst material, solvent are mixed, makes to be dissolved into homogeneous oil phase, is cutting
Under tangent condition, by oil phase be added to containing emulsifying agent, pH adjusting agent, dispersant aqueous phase solution in, surplus is mended with deionized water
Foot, two kinds of materials react in oil-water interfaces, form high score ascus wall, the well dispersed micro-capsule of the present composition is made and hangs
Floating agent product.Specifically it is shown in Table 7.
The embodiment 85 of table 7,86 each components and parts by weight
In table 7 active component B be fluorine bacterium azoles, Prochloraz, prochloraz-manganese chloride complex, Fenamidone, thiophanate-methyl, carbendazim or
Cyazofamid.
Embodiment 87,88 microcapsule suspension-suspendinagent agents
Active component B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing condition
Under be added to containing emulsifying agent, pH adjusting agent aqueous phase solution in, well dispersed microcapsule suspending agent is made.By dispersant, wet
Moisten agent, defoamer, thickener（Can add to be not added with）It is well mixed by high speed shear, fluorine azoles bacterium aniline is added, in ball mill
Ball milling 2~3 hours, make diameter of particle all below 5 μm, suspending agent is made, suspending agent then is added into microcapsules suspends
In the aqueous phase solution of agent, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent production of the present composition is made
Product, specifically it is shown in Table 8.
The embodiment 87 of table 8,88 each components and parts by weight
Active component B is fluorine bacterium azoles, Prochloraz, Fenamidone, thiophanate-methyl, carbendazim or cyazofamid in table 8.
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
Calmly, the synergy ratio after clear and definite two kinds of medicaments compound by a certain percentage（SR）, SR ＜ 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR ＞ 1.5 are synergistic effect, on this basis, then carry out field test.
Test method:After prerun determines the effective inhibition concentration scope of each medicament, medicament sets 5 respectively by active constituent content
Individual dosage processing, if clear water compares.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, calculates the net growth of each processing
Amount, mycelial growth inhibition rate.
Net growth（mm）=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value（y）, liquor strength（μg/mL）It is converted into logarithm value（x）, with minimum
Square law tries to achieve virulence regression equation（y=a+bx）, and thus calculate the EC of every kind of medicament50Value.Simultaneously according to Wadley method meters
Calculate two medicament different ratio synergy ratios（SR）, SR ＜ 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action, SR
＞ 1.5 is synergistic effect.Calculation formula is as follows:
Wherein:A, b is respectively active components A and active component B ratio shared in combination；
A is fluorine azoles bacterium aniline；B is selected from fluorine bacterium azoles, Prochloraz, prochloraz-manganese chloride complex, Fenamidone, thiophanate-methyl, more bacterium
One of spirit or cyazofamid kind.
Virulence experiment part：Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Application Example two：
For trying disease：Powdery mildew of cucumber；Experimental design：Determine fluorine azoles bacterium aniline with both fluorine bacterium azoles not by pilot study
With effective inhibition concentration scope of proportioning mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 9 compounds the toxicity test analysis of results table to powdery mildew of cucumber with fluorine bacterium azoles
As shown in Table 9, fluorine azoles bacterium aniline prevents and treats the proportioning of powdery mildew of cucumber 1 with fluorine bacterium azoles compounding:80~80:When 1, increase
Effect ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect in the range of 1, fluorine azoles bacterium aniline with
The proportioning of fluorine bacterium azoles is 1:20~20: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, at the same fluorine azoles bacterium aniline with
The proportioning of fluorine bacterium azoles is 1:9~9:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, tests and finds through applicant,
The proportioning of fluorine azoles bacterium aniline and fluorine bacterium azoles be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,
10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰
10th, 1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when fluorine azoles bacterium aniline and fluorine bacterium azoles
Weight ratio is 3:Synergy ratio is maximum when 2, and synergistic effect is the most obvious.
Application Example three：
For trying disease：Citrus anthracnose；Experimental design：Determine fluorine azoles bacterium aniline with both Prochlorazs not by pilot study
With effective inhibition concentration scope of proportioning mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 10 compounds the toxicity test analysis of results table to citrus anthracnose with Prochloraz
As shown in Table 10, fluorine azoles bacterium aniline prevents and treats the proportioning of citrus anthracnose 1 with Prochloraz compounding:80~80:When 1,
Synergy ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect, fluorine azoles bacterium aniline in the range of 1
Proportioning with Prochloraz is 1:25~15: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, while fluorine azoles bacterium aniline
Proportioning with Prochloraz is 1:14~4:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, tests and sends out through applicant
Existing, the optimum ratio of fluorine azoles bacterium aniline and Prochloraz is 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰
1st, 5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰
14th, 1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when fluorine azoles bacterium aniline with
Prochloraz weight ratio is 1:Synergy ratio is maximum when 4, and synergistic effect is the most obvious.
Application Example four：
For trying disease：Cucumber anthracnose；Experimental design：Fluorine azoles bacterium aniline and prochloraz-manganese chloride complex two are determined by pilot study
Effective inhibition concentration scope of person's different ratio mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 11 compounds the toxicity test analysis of results table to cucumber anthracnose with prochloraz-manganese chloride complex
As shown in Table 11, fluorine azoles bacterium aniline prevents and treats the proportioning of cucumber anthracnose 1 with prochloraz-manganese chloride complex compounding:80~80:1
When, synergy ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect, fluorine azoles bacterium in the range of 1
The proportioning of aniline and prochloraz-manganese chloride complex is 1:25~20: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, while fluorine
The proportioning of azoles bacterium aniline and prochloraz-manganese chloride complex is 1:9~9:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, through Shen
Experiment of asking someone finds, the optimum ratio of fluorine azoles bacterium aniline and prochloraz-manganese chloride complex is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,
14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,
1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,
1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein when fluorine azoles bacterium aniline and prochloraz-manganese chloride complex weight ratio are 2:Synergy ratio is maximum when 5, increases
Effect effect is the most obvious.
Application Example five：
For trying disease：Downy mildew of garpe；Experimental design：Fluorine azoles bacterium aniline and both Fenamidones are determined by pilot study
Effective inhibition concentration scope of different ratio mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 12 compounds the toxicity test analysis of results table to downy mildew of garpe with Fenamidone
As shown in Table 12, fluorine azoles bacterium aniline prevents and treats the proportioning of downy mildew of garpe 1 with Fenamidone compounding:80~80:1
When, synergy ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect, fluorine azoles bacterium in the range of 1
The proportioning of aniline and Fenamidone is 1:20~20: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, while fluorine azoles
The proportioning of bacterium aniline and Fenamidone is 1:9~9:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, through applicant
Experiment finds, the optimum ratio of fluorine azoles bacterium aniline and Fenamidone is 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,
13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,
1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when fluorine azoles
Bacterium aniline is 1 with Fenamidone weight ratio:Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Application Example six：
For trying disease：Rice sheath blight disease；Experimental design：Fluorine azoles bacterium aniline and thiophanate-methyl two are determined by pilot study
Effective inhibition concentration scope of person's different ratio mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 13 compounds the toxicity test analysis of results table to rice sheath blight disease with thiophanate-methyl
As shown in Table 13, fluorine azoles bacterium aniline prevents and treats the proportioning of rice sheath blight disease 1 with thiophanate-methyl compounding:80~80:1
When, synergy ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect, fluorine azoles bacterium in the range of 1
The proportioning of aniline and thiophanate-methyl is 1:25~15: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, while fluorine
The proportioning of azoles bacterium aniline and thiophanate-methyl is 1:14~4:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, warp
Applicant, which tests, to be found, the optimum ratio of fluorine azoles bacterium aniline and thiophanate-methyl is 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰
1st, 9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰
11st, 1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, wherein
When fluorine azoles bacterium aniline and thiophanate-methyl weight ratio are 1:Synergy ratio is maximum when 6, and synergistic effect is the most obvious.
Application Example seven：
For trying disease：Sclerotinia sclerotiorum；Experimental design：Determine fluorine azoles bacterium aniline with both carbendazim not by pilot study
With effective inhibition concentration scope of proportioning mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 14 compounds the toxicity test analysis of results table to sclerotinia sclerotiorum with carbendazim
As shown in Table 14, fluorine azoles bacterium aniline prevents and treats the proportioning of sclerotinia sclerotiorum 1 with carbendazim compounding:80~80:When 1,
Synergy ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect, fluorine azoles bacterium aniline in the range of 1
Proportioning with carbendazim is 1:30~15: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, while fluorine azoles bacterium aniline
Proportioning with carbendazim is 1:14~4:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, tests and sends out through applicant
Existing, the optimum ratio of fluorine azoles bacterium aniline and carbendazim is 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰
1st, 5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰
14th, 1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25,1 ︰ 26,1 ︰ 27,1 ︰ 28,1 ︰
29th, 1 ︰ 30, wherein fluorine azoles bacterium aniline are 1 with carbendazim weight ratio:Synergy ratio is maximum when 7, and synergistic effect is the most obvious.
Application Example eight：
For trying disease：Peronophythora litchi；Experimental design：Fluorine azoles bacterium aniline and both cyazofamids are determined by pilot study
Effective inhibition concentration scope of different ratio mixture.
Toxicity test result
The fluorine azoles bacterium aniline of table 15 compounds the toxicity test analysis of results table to peronophythora litchi with cyazofamid
As shown in Table 15, fluorine azoles bacterium aniline prevents and treats the proportioning of peronophythora litchi 1 with cyazofamid compounding:80~80:1
When, synergy ratio SR is all higher than 1.5, illustrates both 1:80~80:Mixture shows synergistic effect, fluorine azoles bacterium in the range of 1
The proportioning of aniline and cyazofamid is 1:20~20: 1, synergistic effect is more prominent, and synergy ratio is all higher than 2.30, while fluorine azoles bacterium
The proportioning of aniline and cyazofamid is 1:9~9:1, synergistic effect is more prominent, and synergy ratio is all higher than 2.40, is tested through applicant
It was found that the optimum ratio of fluorine azoles bacterium aniline and cyazofamid be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,
12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰
8th, 1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, wherein when fluorine azoles bacterium aniline
It is 2 with cyazofamid weight ratio:Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Found through experiment, to the Basidiomycotina in various crop, sac fungus after fluorine azoles bacterium aniline and active component B compoundings
Multiple diseases caused by subphylum, Mastigomycotina or Deuteromycotina pathogen for example banded sclerotial blight, sclerotiniose, rust, smut,
Bunt, helminthosporium maydis, powdery mildew, downy mildew, epidemic disease, gray mold, damping-off, rice blast, anthracnose, scab, penicilliosis
Or the preventing and treating of the disease such as false smut has obvious synergistic effect, synergy ratio is more than 1.5.
Effect experiment part：Test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, and compares 20% fluorine azoles bacterium
Aniline suspending agent（Autogamy）, 30% triflumizole wettable powder（It is purchased in market）, 25% Prochloraz missible oil（It is purchased in market), 50% prochloraz-manganese chloride complex
Wettable powder（It is purchased in market）, 50% Fenamidone suspending agent（It is purchased in market）70% thiophanate-methyl wettable powder（It is purchased in market）, more than 25%
Bacterium spirit wettable powder（It is purchased in market）, 10% cyazofamid suspending agent（It is purchased in market）.The state of an illness is investigated before medicine, in state of an illness first time at initial stage dispenser,
Dispenser 1 time altogether.
Application Example nine：
Fluorine azoles bacterium aniline and active component B and its compounding preventing and treating wheat powdery mildew test of pesticide effectiveness, this experimental arrangement is in Shaanxi
Province Xi'an suburban area, 2 days after dispenser, disease index is investigated respectively and calculates preventive effect within 10 days, 30 days.Experimental result is as follows：
The fluorine azoles bacterium aniline of table 16 and active component B and its compounding preventing and treating wheat powdery mildew test of pesticide effectiveness
As can be seen from Table 16, fluorine azoles bacterium aniline is prevented with can effectively prevent and treat wheat powdery mildew after active component B and its compounding
Effect is controlled more than 97%, better than the preventive effect of single dose, and preventive effect phase is grown, and it is black to prevent and treat loose smut of wheat, wheat raw meat
Fringe disease, wheat sharp eyespot, wheat rust, target crop is had no adverse effects in experiment scope of medication.
Application Example ten：
Fluorine azoles bacterium aniline and active component B and its compounding preventing and treating cucumber downy mildew test of pesticide effectiveness, this experimental arrangement is in Shaanxi
Province Xianyang suburban area, 2 days after dispenser, disease index is investigated respectively and calculates preventive effect within 10 days, 30 days.Experimental result is as follows：
The fluorine azoles bacterium aniline of table 17 and active component B and its compounding preventing and treating cucumber downy mildew test of pesticide effectiveness
As can be seen from Table 17, fluorine azoles bacterium aniline is prevented with can effectively prevent and treat cucumber downy mildew after active component B and its compounding
Effect is controlled more than 97%, better than the preventive effect of single dose, and preventive effect phase is grown, and can prevent and treat powdery mildew of cucumber, cucumber anthracnose
And gray mold of cucumber, target crop is had no adverse effects in experiment scope of medication.
Application Example 11：
Fluorine azoles bacterium aniline and active component B and its compounding preventing and treating rice sheath blight disease test of pesticide effectiveness, this experimental arrangement is in Shaanxi
Hanzhong City is saved, 2 days after dispenser, disease index is investigated respectively and calculates preventive effect within 10 days, 30 days.Experimental result is as follows：
The fluorine azoles bacterium aniline of table 18 and active component B and its compounding preventing and treating rice sheath blight disease test of pesticide effectiveness
As can be seen from Table 18, fluorine azoles bacterium aniline is prevented with can effectively prevent and treat rice sheath blight disease after active component B and its compounding
Effect is controlled more than 97%, better than the preventive effect of single dose, and preventive effect phase is grown, and can prevent and treat rice green smut and rice rice blast
Disease, target crop is had no adverse effects in experiment scope of medication.
Application Example 12：
Fluorine azoles bacterium aniline and active component B and its compounding preventing and treating capsicum epidemic disease test of pesticide effectiveness, this experimental arrangement is in Shaanxi Province
Xi'an Changan District, 2 days after dispenser, disease index is investigated respectively and calculates preventive effect within 10 days, 30 days.Experimental result is as follows：
The fluorine azoles bacterium aniline of table 19 and active component B and its compounding preventing and treating capsicum epidemic disease test of pesticide effectiveness
As can be seen from Table 19, fluorine azoles bacterium aniline is prevented and treated with can effectively prevent and treat capsicum epidemic disease after active component B and its compounding
Effect more than 97%, better than the preventive effect of single dose, and grow, and can prevent and treat pepper anthracnose by preventive effect phase, in experiment medication model
Enclose and interior target crop is had no adverse effects.
Application Example 13：
Fluorine azoles bacterium aniline and active component B and its compounding preventing and treating citrus anthracnose test of pesticide effectiveness, this experimental arrangement is in Shaanxi
Hanzhong City is saved, 2 days after dispenser, disease index is investigated respectively and calculates preventive effect within 10 days, 30 days.Experimental result is as follows：
The fluorine azoles bacterium aniline of table 20 and active component B and its compounding preventing and treating citrus anthracnose test of pesticide effectiveness
As can be seen from Table 20, fluorine azoles bacterium aniline is prevented with can effectively prevent and treat citrus anthracnose after active component B and its compounding
Effect is controlled more than 97%, better than the preventive effect of single dose, and preventive effect phase is grown, and can prevent and treat Penicillium italicum, in experiment medication
In the range of target crop is had no adverse effects.
Application Example 14：
Fluorine azoles bacterium aniline and active component B and its compounding preventing and treating sclerotinia sclerotiorum test of pesticide effectiveness, this experimental arrangement is in Shaanxi
Hanzhong City is saved, 2 days after dispenser, disease index is investigated respectively and calculates preventive effect within 10 days, 30 days.Experimental result is as follows：
The fluorine azoles bacterium aniline of table 21 and active component B and its compounding preventing and treating sclerotinia sclerotiorum test of pesticide effectiveness
As can be seen from Table 21, fluorine azoles bacterium aniline is prevented with can effectively prevent and treat sclerotinia sclerotiorum after active component B and its compounding
Effect is controlled more than 97%, better than the preventive effect of single dose, and preventive effect phase is grown, to target crop without bad in experiment scope of medication
Influence.
The experiment by different places throughout the country is drawn afterwards, fluorine azoles bacterium aniline and fluorine bacterium azoles, Prochloraz, prochloraz-manganese chloride complex
Salt, Fenamidone, thiophanate-methyl, carbendazim or cyazofamid compounding after in various crop by Basidiomycotina, sac fungus
Multiple diseases caused by subphylum, Mastigomycotina or Deuteromycotina pathogen for example banded sclerotial blight, sclerotiniose, rust, smut,
Bunt, helminthosporium maydis, powdery mildew, downy mildew, epidemic disease, gray mold, damping-off, rice blast, anthracnose, scab, penicilliosis
It is obvious better than single dose preventive effect, synergistic effect or the preventive effect of the disease such as false smut is more than 97%.
Claims (6)
1. a kind of composition pesticide of fluorine-containing azoles bacterium aniline, active ingredient is active components A and active component B, it is characterised in that：
Active components A and active component B weight ratio are 1:80~80:1, described active components A is fluorine azoles bacterium aniline, active component B
For fluorine bacterium azoles.
2. the composition pesticide of fluorine-containing azoles bacterium aniline according to claim 1, it is characterised in that：Active components A and activity
Composition B weight ratio is 1:60~60:1.
3. the composition pesticide of fluorine-containing azoles bacterium aniline according to claim 2, it is characterised in that：
Fluorine azoles bacterium aniline and the weight ratio of fluorine bacterium azoles are 1:20~20:1.
4. the composition pesticide of fluorine-containing azoles bacterium aniline according to any one of claim 1 to 3, it is characterised in that：Combination
Thing be made wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-
Suspending agent.
5. the composition pesticide of fluorine-containing azoles bacterium aniline according to claim 4 is used for the purposes for preventing and treating disease on crops.
6. purposes according to claim 5, it is characterised in that：Described disease be by Basidiomycotina, Ascomycotina,
Disease caused by the pathogen of Mastigomycotina or Deuteromycotina.
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| CN107251900A (en) * | 2017-06-28 | 2017-10-17 | 江苏丘陵地区镇江农业科学研究所 | A kind of composition pesticide and its application of fluorine-containing azoles bacterium acyl azanol and Prochloraz |
| CN109418270A (en) * | 2017-09-01 | 2019-03-05 | 浙江省化工研究院有限公司 | A kind of bactericidal composition of fluorine-containing phenylate amide |
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| CN102640756A (en) * | 2003-10-23 | 2012-08-22 | 拜尔农作物科学股份公司 | Synergistic fungicidal active combinations |
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