CN107125248A - A kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone - Google Patents
A kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone Download PDFInfo
- Publication number
- CN107125248A CN107125248A CN201710214170.3A CN201710214170A CN107125248A CN 107125248 A CN107125248 A CN 107125248A CN 201710214170 A CN201710214170 A CN 201710214170A CN 107125248 A CN107125248 A CN 107125248A
- Authority
- CN
- China
- Prior art keywords
- ethyl ketone
- pyrrole ethyl
- thiazole pyrrole
- fluorine
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone, the bactericidal composition containing active components A and active component B, wherein active components A are selected from fluorine thiazole pyrrole ethyl ketone, and active component B is selected from any one following compound：ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin, fenoxanil, thifluzamide, bromothalonil or volution bacterium amine, and active components A and active component B weight ratio are the ︰ 1 of 1 ︰ 80 ~ 80.The present composition has synergistic effect to the multiple diseases for endangering agricultural production, reduces pesticide usage amount, reduces residual quantity of the agricultural chemicals on crop, alleviate environmental pollution, to person poultry safety, Environmental compatibility is good, and disease is not likely to produce the resistance to the action of a drug.
Description
The application is divisional application, and for the patent application of Shanxi Thompson Biological Technology Co., Ltd., " one kind contains for original application
The efficient bactericidal composite of fluorine thiazole pyrrole ethyl ketone ", the application Wei ︰ 201310590338.2 of original application, original application day is
2013.11.19。
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone in crops
Application in disease.
Background technology
ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin, fenoxanil, thifluzamide, bromothalonil or spiral shell
Ring bacterium amine belongs to common fungicide, is widely used in the disease of crops.
However, in the real process of agricultural production, controlling disease is easiest to generate the problem that the production of disease drug resistance
It is raw.Different cultivars composition is compounded, and is to prevent and treat resistance disease very common method.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy plus and or antagonism.In most cases, the compounding effect of sterilization
All it is additive effect, really has the compounding of synergistic effect seldom, especially synergistic effect is clearly, synergy ratio is very high answers
With just less.Study, found fluorine thiazole pyrrole ethyl ketone and ZEN 90160, dimoxystrobin, orysastrobin, benzene oxygen bacterium by inventor
Good synergistic effect can be produced after ester, pyraoxystrobin, fenoxanil, thifluzamide, bromothalonil or volution bacterium amine compounding, and is closed
In fluorine thiazole pyrrole ethyl ketone and ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin, fenoxanil, thifluzamide, bromine
The relevant report of bacterium nitrile or volution bacterium amine compounding is not yet disclosed.
The content of the invention
There is synergistic function, the fluorine-containing thiazole pyrrole that use cost is low, preventive effect is good the purpose of the present invention is to propose to a kind of
The efficient bactericidal composite of ethyl ketone.
The efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone proposed by the present invention contains active components A and active component B, living
Property composition A and active component B weight ratio be the ︰ 1 of 1 ︰ 80~80, described active components A is selected from fluorine thiazole pyrrole ethyl ketone, active component
B is selected from one of iprodione, Acibenzolar, fluazinam, pyridine bacterium amine, fluopicolide or Guardian and planted, active components A and activity
Weight ratio preferred composition B is the ︰ 1 of 1 ︰ 50~50；More preferably the weight ratio of fluorine thiazole pyrrole ethyl ketone and ZEN 90160 is 20:1~
1:20, the weight ratio of fluorine thiazole pyrrole ethyl ketone and dimoxystrobin is 20:1~1:20, the weight ratio of fluorine thiazole pyrrole ethyl ketone and orysastrobin
For 20:1~1:20, the weight ratio of fluorine thiazole pyrrole ethyl ketone and kresoxim-methyl is 20:1~1:20, fluorine thiazole pyrrole ethyl ketone and pyraoxystrobin
Weight ratio be 20:1~1:20, the weight ratio of fluorine thiazole pyrrole ethyl ketone and fenoxanil is 20:1~1:20, fluorine thiazole pyrrole ethyl ketone
Weight ratio with thifluzamide is 25:1~1:15, the weight ratio of fluorine thiazole pyrrole ethyl ketone and bromothalonil is 20:1~1:20, fluorine thiophene
The weight ratio of azoles pyrrole ethyl ketone and volution bacterium amine is 15:1~1:25；The most preferably weight ratio of fluorine thiazole pyrrole ethyl ketone and ZEN 90160
For 9:1~1:9, the weight ratio of fluorine thiazole pyrrole ethyl ketone and dimoxystrobin is 9:1~1:9, the weight of fluorine thiazole pyrrole ethyl ketone and orysastrobin
Amount is than being 9:1~1:9, the weight ratio of fluorine thiazole pyrrole ethyl ketone and kresoxim-methyl is 9:1~1:9, fluorine thiazole pyrrole ethyl ketone and pyraoxystrobin
Weight ratio be 9:1~1:9, the weight ratio of fluorine thiazole pyrrole ethyl ketone and fenoxanil is 9:1~1:9, fluorine thiazole pyrrole ethyl ketone and thiophene
The weight ratio of ofurace is 14:1~1:4, the weight ratio of fluorine thiazole pyrrole ethyl ketone and bromothalonil is 9:1~1:9, fluorine thiazole pyrrole ethyl ketone
Weight ratio with volution bacterium amine is 4:1~1:14.
The efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone proposed by the present invention is used for the purposes for preventing and treating disease on crops,
Described crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit
Class crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop, green manure pasture crop；
Described disease is that leaf blight, rust, glume blight, brown spot, powdery mildew, net blotch, moire disease, downy mildew, rice blast, line are withered
Disease, scab, epidemic disease, sclerotiniose, white rot, ring spot, spot defoliation or anthracnose.
Active components A, active component B weight ratio are the ︰ 1 of 1 ︰ 80~80.The weight hundred of active component in usual composition
It is the 0.5%~90% of gross weight, preferably 5%~80% to divide content.According to different preparation types, active component content
Scope is different.Generally, liquid preparation contains by weight 1%~70% active material, preferably 5%~50%；
Solid pharmaceutical preparation contains by weight 5%~80% active material, preferably 10%~80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, active component is in water during in favor of applying
It is scattered.Surface-active contents are the 5%~30% of total formulation weight, and surplus is solid or liquid diluent.
The present invention bactericidal composition can by user using it is preceding through dilute or directly use.Its preparation can be by usual
Processing method known in those skilled in the art prepare, i.e., after active material is mixed with liquid flux or solid carrier,
The one kind added in surfactant such as dispersant, stabilizer, wetting agent, binding agent, defoamer, disintegrant, antifreeze
Or it is several.
The bactericidal composition of the present invention, acceptable formulation in any sterilization can be processed on demand, wherein more preferably
Formulation be wettable powder, water dispersible granules, suspending agent, oil-suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent
Or microcapsule suspension-suspendinagent agent, seed coat agent can also be made, clothing suspending agent is planted.
Composition includes following constituent content when wettable powder is made：Active components A 0.5%~80%, active component
B 0.5%~80%, dispersant 2%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when water dispersible granules are made：Active components A 0.5%~80%, active component
B0.5%~80%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%, filler
Surplus.
Composition includes following constituent content when suspending agent or oil-suspending agent is made：Active components A 0.1%~50%, work
Property composition B0.1%~50%, dispersant 2%~10%, wetting agent 2%~10%, defoamer 0.01%~2%, thickener 0
~2%, antifreeze 0~8%, deionized water or vegetable oil add to 100%.
Composition includes following constituent content when suspension emulsion is made：Active components A 0.1%~50%, active component
B0.1%~50%, dispersant 2%~10%, defoamer 0.01%~2%, solvent 1%~15%, thickener 0~2%, breast
Agent 2%~12%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when aqueous emulsion is made：Active components A 0.5%~50%, active component
B0.5%~50%, solvent 1%~30%, emulsifying agent 1%~15%, antifreeze 0~8%, thickener 0~2%, defoamer
0.01%~2%, deionized water supplies surplus.
Composition includes following constituent content when microemulsion is made：Active components A 0.1%~50%, active component
B0.1%~50%, solvent 1%~30%, emulsifying agent 3%~25%, antifreeze 0~8%, defoamer 0.01%~2%, go
Ionized water supplies surplus.
Composition includes following constituent content when microcapsule suspending agent is made：Active components A 0.1%~50%, active component
B0.1%~50%, macromolecule cyst material 2%~10%, dispersant 1%~10%, organic solvent 1%~10%, emulsifying agent
1%~7%, defoamer 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
Composition includes following constituent content when microcapsule suspension-suspendinagent agent is made：Active components A 0.1%~50%, activity
It is composition B0.1%~50%, macromolecule cyst material 2%~10%, dispersant 1%~12%, wetting agent 1%~8%, organic
Solvent 1%~15%, emulsifying agent 1%~6%, defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~
5%th, deionized water adds to 100%；
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent or oil-suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：
(1) fluorine thiazole pyrrole ethyl ketone and ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin, fenoxanil, thiophene
After ofurace, bromothalonil or volution bacterium amine compounding, with obvious synergy and lasting effect；(2) cereal crops, beans are made
Thing, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil plant
Crop, flower crop, medicinal crop, crop, the disease on green manure pasture crop have greater activity；(3) agriculture is reduced
Medicinal dose, reduces residual quantity of the agricultural chemicals on crop, alleviates environmental pollution；(4) to person poultry safety, Environmental compatibility
It is good；And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~12
Fluorine thiazole pyrrole ethyl ketone, active component B, dispersant, wetting agent, filler are well mixed in mixed cylinder, through air-flow
Pulverizer remixes uniform after crushing, you can wettable powder product of the present invention is made, 1 is specifically shown in Table.
The each component of 1 embodiment of table 1~12 and parts by weight
The water dispersible granules of embodiment 13~24
Fluorine thiazole pyrrole ethyl ketone, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained through air-flow crushing together
To the particle diameter of needs, other auxiliary agents such as binding agent (can add to be not added with) are added, materials of pelletizing are obtained.Item is quantified into feeding stream
Change in bed granulating drier after granulation and drying, you can water dispersible granules product of the present invention is made, is specifically shown in Table
2。
The each component of 2 embodiment of table 13~24 and parts by weight
The suspending agent of embodiment 25~36 or oil-suspending agent
By dispersant, wetting agent, defoamer, thickener (can add to be not added with), antifreeze (can add to be not added with), by a high speed
Shear-mixed is uniform, adds fluorine thiazole pyrrole ethyl ketone, active component B, ball milling 2~3 hours in ball mill make diameter of particle whole
Below 5 μm, surplus is supplied with deionized water or vegetable oil, you can suspending agent or oil-suspending agent production of the present invention is made
Product, are specifically shown in Table 3.
The each component of 3 embodiment of table 25~36 and parts by weight
The suspension emulsion of embodiment 37~42
Dispersant, defoamer, thickener (can add to be not added with), antifreeze (can add to be not added with) are mixed by high speed shear
Uniformly, add active component B, ball milling 2~3 hours in ball mill make diameter of particle all less than 5 μm, it is obtained it is active into
Divide B suspending agents, fluorine thiazole pyrrole ethyl ketone, solvent, emulsifying agent and various auxiliary agents are directly then emulsified into suspension with high speed agitator
In agent, surplus is supplied with deionized water, and suspension emulsion product of the present invention is made, 4 are specifically shown in Table.
The each component of 4 embodiment of table 37~42 and parts by weight
The aqueous emulsion of embodiment 43~48
Fluorine thiazole pyrrole ethyl ketone, active component B, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；To go from
Sub- water, antifreeze (can add to be not added with), thickener (can add to be not added with), defoamer are mixed, into homogeneous aqueous phase.At a high speed
Under stirring, aqueous phase is added into oil phase, surplus is supplied with deionized water；Aqueous emulsion product of the present invention is can be prepared by, specifically
It is shown in Table 5.
The each component of 5 embodiment of table 43~48 and parts by weight
ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin in table 1~5 are exchanged, novel formulation can be made.
Embodiment 49,50 microemulsions
Fluorine thiazole pyrrole ethyl ketone, active component B, solvent, emulsifying agent, antifreeze (can add to be not added with), defoamer are fully mixed
The oil phase of homogeneous transparent is synthesized, deionized water is slowly added under agitation, WO emulsion, then agitated heating is formed,
Rapid phase inversion is allowed into oil-in-water type, is cooled to room temperature and makes up to balance, through filtering, surplus is supplied with deionized water；It can make
Microemulsion product of the present invention is obtained, 6 are specifically shown in Table.
The embodiment 49 of table 6,50 each components and parts by weight
Embodiment 51,52 microcapsule suspending agents
Fluorine thiazole pyrrole ethyl ketone, active component B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase,
Under shearing condition, oil phase is added to containing in emulsifying agent, pH adjusting agent, the aqueous phase solution of dispersant, surplus deionized water
Supply, two kinds of materials react in oil-water interfaces, form high score ascus wall, the well dispersed micro-capsule of the present composition is made
Suspending agent product.Specifically it is shown in Table 7.
The embodiment 51 of table 7,52 each components and parts by weight
Embodiment 53,54 microcapsule suspension-suspendinagent agents
Fluorine thiazole pyrrole ethyl ketone, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing
Under the conditions of be added to containing in emulsifying agent, the aqueous phase solution of pH adjusting agent, well dispersed microcapsule suspending agent is made.Will be scattered
Agent, wetting agent, defoamer, thickener (can add to be not added with) are well mixed by high speed shear, active component B are added, in ball milling
Ball milling 2~3 hours in machine, make diameter of particle all below 5 μm, and suspending agent is made, suspending agent then is added into microcapsules
In the aqueous phase solution of suspending agent, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent of the present composition is made
Product, is specifically shown in Table 8.
The embodiment 53 of table 8,54 each components and parts by weight
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
Calmly, the synergy ratio (SR) after clear and definite two kinds of medicaments are compounded by a certain percentage, SR ＜ 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR ＞ 1.5 are synergistic effect, on this basis, then carry out field test.
Test method：After determining the effective inhibition concentration scope of each medicament through prerun, medicament sets 5 respectively by active constituent content
Individual dosage processing, if clear water is compareed.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, the net growth of each processing is calculated
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum
Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley methods
Two medicament different ratio synergy ratios (SR) are calculated, SR ＜ 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action,
SR ＞ 1.5 are synergistic effect.Calculation formula is as follows：
Wherein：A, b are respectively active components A and active component B ratio shared in combination；
A is fluorine thiazole pyrrole ethyl ketone；
B selects ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin, fenoxanil, thifluzamide, bromothalonil
Or one of volution bacterium amine is planted.
Application Example two
For examination disease：Wheat leaf blight
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and ZEN 90160 active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 9 compounds the toxicity test analysis of results table to wheat leaf blight with ZEN 90160
As shown in Table 9, fluorine thiazole pyrrole ethyl ketone matches the synergy in 1 80~80 ︰ 1 of ︰ to wheat leaf blight with ZEN 90160
Ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when fluorine thiazole pyrrole ethyl ketone
Proportioning with ZEN 90160 is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.25, when fluorine thiazole
The proportioning of pyrrole ethyl ketone and ZEN 90160 is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio is more than 2.50, especially
It is when fluorine thiazole pyrrole ethyl ketone and ZEN 90160 weight ratio are 2：Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example three
For examination disease：Downy mildew of garpe
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and dimoxystrobin active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 10 compounds the toxicity test analysis of results table to downy mildew of garpe with dimoxystrobin
As shown in Table 10, fluorine thiazole pyrrole ethyl ketone matches the synergic ratio in 1 80~80 ︰ 1 of ︰ to downy mildew of garpe with dimoxystrobin
Value SR is all higher than 1.5, illustrate both in the range of the ︰ 1 of 1 ︰ 80~80 mixture show synergistic effect, when fluorine thiazole pyrrole ethyl ketone with
The proportioning of dimoxystrobin is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.25, when fluorine thiazole pyrrole second
The proportioning of ketone and dimoxystrobin is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio especially works as fluorine more than 2.40
Thiazole pyrrole ethyl ketone is 3 with dimoxystrobin weight ratio：Synergy ratio is maximum when 2, and synergistic effect is the most obvious.
Application Example four
For examination disease：Rice blast
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and orysastrobin active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 11 compounds the toxicity test analysis of results table to rice blast with orysastrobin
As shown in Table 11, fluorine thiazole pyrrole ethyl ketone matches the synergy in 1 80~80 ︰ 1 of ︰ to rice blast with orysastrobin
Ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when fluorine thiazole pyrrole ethyl ketone
Proportioning with orysastrobin is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.25, when fluorine thiazole
The proportioning of pyrrole ethyl ketone and orysastrobin is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio is more than 2.40, especially
It is when fluorine thiazole pyrrole ethyl ketone and orysastrobin weight ratio are 2：Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example five
For examination disease：Cucumber downy mildew
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and kresoxim-methyl active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 12 compounds the toxicity test analysis of results table to cucumber downy mildew with kresoxim-methyl
As shown in Table 12, fluorine thiazole pyrrole ethyl ketone matches the synergy in 1 80~80 ︰ 1 of ︰ to cucumber downy mildew with kresoxim-methyl
Ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when fluorine thiazole pyrrole ethyl ketone
Proportioning with kresoxim-methyl is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.25, when fluorine thiazole
The proportioning of pyrrole ethyl ketone and kresoxim-methyl is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio is more than 2.45, especially
It is when fluorine thiazole pyrrole ethyl ketone and kresoxim-methyl weight ratio are 2：Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example six
For examination disease：Wheat powdery mildew
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and pyraoxystrobin active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 13 compounds the toxicity test analysis of results table to wheat powdery mildew with pyraoxystrobin
As shown in Table 13, fluorine thiazole pyrrole ethyl ketone matches the synergic ratio in 1 80~80 ︰ 1 of ︰ to wheat powdery mildew with pyraoxystrobin
Value SR is all higher than 1.5, illustrate both in the range of the ︰ 1 of 1 ︰ 80~80 mixture show synergistic effect, when fluorine thiazole pyrrole ethyl ketone with
The proportioning of pyraoxystrobin is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.30, when fluorine thiazole pyrrole second
The proportioning of ketone and pyraoxystrobin is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio especially works as fluorine more than 2.50
Thiazole pyrrole ethyl ketone is 2 with pyraoxystrobin weight ratio：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Application Example seven
For examination disease：Rice blast
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and fenoxanil active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 14 compounds the toxicity test analysis of results table to rice blast with fenoxanil
As shown in Table 14, fluorine thiazole pyrrole ethyl ketone matches the synergy in 1 80~80 ︰ 1 of ︰ to rice blast with fenoxanil
Ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when fluorine thiazole pyrrole ethyl ketone
Proportioning with fenoxanil is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.25, when fluorine thiazole
The proportioning of pyrrole ethyl ketone and fenoxanil is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio is more than 2.40, especially
It is when fluorine thiazole pyrrole ethyl ketone and fenoxanil weight ratio are 1：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Application Example eight
For examination disease：Rice sheath blight disease
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and thifluzamide active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 15 compounds the toxicity test analysis of results table to rice sheath blight disease with thifluzamide
As shown in Table 15, fluorine thiazole pyrrole ethyl ketone matches the synergy in 1 80~80 ︰ 1 of ︰ to rice sheath blight disease with thifluzamide
Ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 80~80, when fluorine thiazole pyrrole ethyl ketone
Proportioning with thifluzamide is 25:1~1:When 15, synergistic effect is more prominent, and synergy ratio is more than 2.30, when fluorine thiazole
The proportioning of pyrrole ethyl ketone and thifluzamide is 14:1~1:When 4, synergistic effect is protruded the most, and synergy ratio is more than 2.40.Through
Applicant's experiment finds that the optimum ratio of fluorine thiazole pyrrole ethyl ketone and thifluzamide is 25 ︰ 1,24 ︰ 1,23 ︰ 1,22 ︰ 1,21 ︰ 1,20 ︰
1st, 19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,
When 3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,
Especially when fluorine thiazole pyrrole ethyl ketone and thifluzamide weight ratio are 3：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Application Example nine
For examination disease：Apple anthracnose
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and bromothalonil active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 16 and toxicity test analysis of results table of the bromothalonil compounded to apple anthracnose
As shown in Table 16, fluorine thiazole pyrrole ethyl ketone matches the synergic ratio in 1 80~80 ︰ 1 of ︰ to apple anthracnose with bromothalonil
Value SR is all higher than 1.5, illustrate both in the range of the ︰ 1 of 1 ︰ 80~80 mixture show synergistic effect, when fluorine thiazole pyrrole ethyl ketone with
The proportioning of bromothalonil is 20:1~1:When 20, synergistic effect is more prominent, and synergy ratio is more than 2.30, when fluorine thiazole pyrrole second
The proportioning of ketone and bromothalonil is 9:1~1:When 9, synergistic effect is protruded the most, and synergy ratio especially works as fluorine more than 2.45
Thiazole pyrrole ethyl ketone is 1 with bromothalonil weight ratio：Synergy ratio is maximum when 2, and synergistic effect is the most obvious.
Application Example ten
For examination disease：Wheat rust
Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design：Fluorine thiazole pyrrole ethyl ketone and volution bacterium amine active compound and the two different ratio mixture are determined by pilot study
Effective inhibition concentration scope.
The fluorine thiazole pyrrole ethyl ketone of table 17 compounds the toxicity test analysis of results table to wheat rust with volution bacterium amine
As shown in Table 17, fluorine thiazole pyrrole ethyl ketone matches the synergic ratio in 1 80~80 ︰ 1 of ︰ to wheat rust with volution bacterium amine
Value SR is all higher than 1.5, illustrate both in the range of the ︰ 1 of 1 ︰ 80~80 mixture show synergistic effect, when fluorine thiazole pyrrole ethyl ketone with
The proportioning of volution bacterium amine is 15:1~1:When 25, synergistic effect is more prominent, and synergy ratio is more than 2.30, when fluorine thiazole pyrrole
The proportioning of ethyl ketone and volution bacterium amine is 4:1~1:When 14, synergistic effect is protruded the most, and synergy ratio is more than 2.40.Through Shen
Ask someone experiment find the optimum ratio of fluorine thiazole pyrrole ethyl ketone and volution bacterium amine for 15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,11 ︰ 1,10 ︰ 1,
9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰ 9,1 ︰ 10,1 ︰
11st, when 1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20,1 ︰ 21,1 ︰ 22,1 ︰ 23,1 ︰ 24,1 ︰ 25, especially
It is when fluorine thiazole pyrrole ethyl ketone and volution bacterium amine weight ratio are 1：Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Fluorine thiazole pyrrole ethyl ketone and ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, azoles bacterium are found through applicant's experiment
The optimum ratio of ester, fenoxanil or bromothalonil be 20 ︰ 1,19 ︰ 1,18 ︰ 1,17 ︰ 1,16 ︰ 1,15 ︰ 1,14 ︰ 1,13 ︰ 1,12 ︰ 1,
11 ︰ 1,10 ︰ 1,9 ︰ 1,8 ︰ 1,7 ︰ 1,6 ︰ 1,5 ︰ 1,4 ︰ 1,3 ︰ 1,2 ︰ 1,1 ︰ 1,1 ︰ 2,1 ︰ 3,1 ︰ 4,1 ︰ 5,1 ︰ 6,1 ︰ 7,1 ︰ 8,1 ︰
9th, when 1 ︰ 10,1 ︰ 11,1 ︰ 12,1 ︰ 13,1 ︰ 14,1 ︰ 15,1 ︰ 16,1 ︰ 17,1 ︰ 18,1 ︰ 19,1 ︰ 20, synergistic effect is more obvious.
Found through experiment：To the leaf blight in various crop, rust, grain husk after fluorine thiazole pyrrole ethyl ketone and active component B compoundings
Rot, brown spot, powdery mildew, net blotch, moire disease, downy mildew, rice blast, banded sclerotial blight, scab, epidemic disease, sclerotiniose, white rot
Disease, ring spot, the preventing and treating of spot defoliation or anthracnose have obvious synergistic effect, and synergy ratio SR is all higher than 1.5.
Effect experiment part：Test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, comparison medicament：20% fluorine
Thiazole pyrrole ethyl ketone oil-suspending agent (autogamy), 25% chlorfenapyr suspending agent (autogamy), 10% dimoxystrobin suspending agent (autogamy), 10%
Orysastrobin suspending agent (autogamy), 25% kresoxim-methyl wettable powder (purchased in market), 20% pyraoxystrobin suspending agent (autogamy).
The fluorine thiazole pyrrole ethyl ketone of Application Example 11 and active component B and its compounding preventing and treating cucumber downy mildew test of pesticide effectiveness
This test arrangement investigates cucumber downy mildew disease index before Xian District, Shanxi Province suburban area, medicine, occurs just in disease
Phase dispenser, 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
The fluorine thiazole pyrrole ethyl ketone of table 18 and active component B and its compounding preventing and treating cucumber downy mildew test of pesticide effectiveness
As can be seen from Table 18, fluorine thiazole pyrrole ethyl ketone after active component B compoundings with can effectively prevent and treat cucumber downy mildew, through Shen
Ask someone also can effectively prevent and treat powdery mildew of cucumber, cucumber anthracnose after experiment finds fluorine thiazole pyrrole ethyl ketone and active component B compoundings, prevent
Control effect and be above 97%, better than the preventive effect of single dose, and preventive effect phase is long.To target crop without bad shadow in experiment scope of medication
Ring.
The difluoro thiazole pyrrole ethyl ketone of Application Example ten and active component B and its compounding preventing and treating rice blast test of pesticide effectiveness
This test arrangement investigates rice blast disease index before Shaanxi Province's Hanzhong City, medicine, is applied in disease early period of origination
Medicine, 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
The fluorine thiazole pyrrole ethyl ketone of table 19 and active component B and its compounding preventing and treating rice blast test of pesticide effectiveness
As can be seen from Table 19, fluorine thiazole pyrrole ethyl ketone after active component B compoundings with can effectively prevent and treat rice blast, through Shen
Ask someone also can effectively prevent and treat rice sheath blight disease, paddy rice leaf blight after experiment finds fluorine thiazole pyrrole ethyl ketone and active component B compoundings, prevent
Control effect and be above 97%, better than the preventive effect of single dose, and preventive effect phase is long.To target crop without bad shadow in experiment scope of medication
Ring.
The trifluoro thiazole pyrrole ethyl ketone of Application Example ten and active component B and its compounding preventing and treating tomato blight test of pesticide effectiveness
This test arrangement investigates tomato blight disease index before Xianyang, Shanxi province suburban area, medicine, in disease early period of origination
Dispenser, 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
The fluorine thiazole pyrrole ethyl ketone of table 20 and active component B and its compounding preventing and treating tomato blight test of pesticide effectiveness
As can be seen from Table 20, fluorine thiazole pyrrole ethyl ketone is with can effectively prevent and treat tomato blight, preventing and treating effect after active component B compoundings
Fruit is above 97%, and better than the preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The tetrafluoro thiazole pyrrole ethyl ketone of Application Example ten and active component B and its compounding preventing and treating uncinula necator test of pesticide effectiveness
This test arrangement investigates uncinula necator disease index before Shaanxi Province Weinan City Dali County, medicine, occurs in disease
Dispenser at initial stage, 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
The fluorine thiazole pyrrole ethyl ketone of table 21 and active component B and its compounding preventing and treating uncinula necator test of pesticide effectiveness
As can be seen from Table 21, fluorine thiazole pyrrole ethyl ketone after active component B compoundings with can effectively prevent and treat uncinula necator, through Shen
Ask someone also can effectively prevent and treat downy mildew of garpe after experiment finds fluorine thiazole pyrrole ethyl ketone and active component B compoundings, prevention effect is high
In 97%, better than the preventive effect of single dose, and preventive effect phase is long.Target crop is had no adverse effects in experiment scope of medication.
The fluorine thiazole pyrrole ethyl ketone of Application Example 15 prevents and treats the wheat rust test of pesticide effectiveness with active component B and its compounding
This test arrangement investigates wheat rust disease index before Xianyang, Shanxi province city Liquan County, medicine, occurs just in disease
Phase dispenser, 3 days after dispenser, investigates disease indexes and calculates preventive effect for 10 days, 20 days.Result of the test is as follows：
The fluorine thiazole pyrrole ethyl ketone of table 22 prevents and treats the wheat rust test of pesticide effectiveness with active component B and its compounding
As can be seen from Table 22, fluorine thiazole pyrrole ethyl ketone after active component B compoundings with can effectively prevent and treat wheat rust, through application
People's experiment finds fluorine thiazole pyrrole ethyl ketone with also can effectively prevent and treat wheat glume blotch, wheat leaf blessing disease, wheat after active component B compoundings
Net blotch and moire disease, prevention effect are above 97%, and better than the preventive effect of single dose, and preventive effect phase is long.In experiment scope of medication
Target crop is had no adverse effects.
The experiment by different places throughout the country is drawn afterwards, fluorine thiazole pyrrole ethyl ketone and ZEN 90160, dimoxystrobin, oxime ether
To the leaf in various crop after bacterium amine, kresoxim-methyl, pyraoxystrobin, fenoxanil, thifluzamide, bromothalonil or volution bacterium amine compounding
Rot, rust, glume blight, brown spot, powdery mildew, net blotch, moire disease, downy mildew, rice blast, banded sclerotial blight, scab, epidemic disease
The preventive effect of the Common Diseases such as disease, sclerotiniose, white rot, ring spot, spot defoliation or anthracnose is more than 97%, better than list
Agent preventive effect, synergistic effect is obvious.
Claims (6)
1. a kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone, effective active composition is active components A and active component B,
It is characterized in that：Active components A is the ︰ 1 of 1 ︰ 80 ~ 80 with active component B weight ratio, and described active components A is selected from fluorine thiazole pyrrole
Ethyl ketone, active component B be selected from ZEN 90160, dimoxystrobin, orysastrobin, kresoxim-methyl, pyraoxystrobin, fenoxanil, thifluzamide,
One of bromothalonil or volution bacterium amine are planted.
2. the efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone according to claim 1, it is characterised in that：Active components A
Weight ratio with active component B is the ︰ 1 of 1 ︰ 50 ~ 50.
3. the efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone according to claim 2, it is characterised in that：
The weight ratio of fluorine thiazole pyrrole ethyl ketone and ZEN 90160 is 20:1~1:20；
The weight ratio of fluorine thiazole pyrrole ethyl ketone and dimoxystrobin is 20:1~1:20；
The weight ratio of fluorine thiazole pyrrole ethyl ketone and orysastrobin is 20:1~1:20；
The weight ratio of fluorine thiazole pyrrole ethyl ketone and kresoxim-methyl is 20:1~1:20；
Fluorine thiazole pyrrole ethyl ketone and the weight ratio of pyraoxystrobin are 20:1~1:20；
The weight ratio of fluorine thiazole pyrrole ethyl ketone and fenoxanil is 20:1~1:20；
The weight ratio of fluorine thiazole pyrrole ethyl ketone and thifluzamide is 25:1~1:15；
The weight ratio of fluorine thiazole pyrrole ethyl ketone and bromothalonil is 20:1~1:20；
Fluorine thiazole pyrrole ethyl ketone and the weight ratio of volution bacterium amine are 15:1~1:25.
4. the efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone according to any one of claim 1 to 3, its feature exists
In：Wettable powder, water dispersible granules, suspending agent, oil-suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule is made in composition
Suspending agent or microcapsule suspension-suspendinagent agent.
5. the efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone according to claim 4 is used to prevent and treat disease on crops
Purposes.
6. purposes according to claim 5, it is characterised in that described disease is：
Leaf blight, rust, glume blight, brown spot, powdery mildew, net blotch, moire disease, downy mildew, rice blast, banded sclerotial blight, black star
Disease, epidemic disease, sclerotiniose, white rot, ring spot, spot defoliation or anthracnose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214170.3A CN107125248A (en) | 2013-11-19 | 2013-11-19 | A kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310590338.2A CN104642336A (en) | 2013-11-19 | 2013-11-19 | High-efficiency bactericidal composition containing fluorothiazole pyrithylone |
| CN201710214170.3A CN107125248A (en) | 2013-11-19 | 2013-11-19 | A kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310590338.2A Division CN104642336A (en) | 2013-11-19 | 2013-11-19 | High-efficiency bactericidal composition containing fluorothiazole pyrithylone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107125248A true CN107125248A (en) | 2017-09-05 |
Family
ID=53234395
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310590338.2A Pending CN104642336A (en) | 2013-11-19 | 2013-11-19 | High-efficiency bactericidal composition containing fluorothiazole pyrithylone |
| CN201710214170.3A Pending CN107125248A (en) | 2013-11-19 | 2013-11-19 | A kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310590338.2A Pending CN104642336A (en) | 2013-11-19 | 2013-11-19 | High-efficiency bactericidal composition containing fluorothiazole pyrithylone |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN104642336A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106818779A (en) * | 2017-02-15 | 2017-06-13 | 海南省植物保护总站（海南省农药检定所） | A kind of bactericidal composition comprising fluorine thiazole pyrrole ethyl ketone |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101969781A (en) * | 2007-10-23 | 2011-02-09 | 杜邦公司 | Fungicidal compounds and mixtures |
-
2013
- 2013-11-19 CN CN201310590338.2A patent/CN104642336A/en active Pending
- 2013-11-19 CN CN201710214170.3A patent/CN107125248A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101969781A (en) * | 2007-10-23 | 2011-02-09 | 杜邦公司 | Fungicidal compounds and mixtures |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104642336A (en) | 2015-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104412981B (en) | A kind of bactericidal composition of fluorine-containing ether bacterium amide and methoxy acrylic | |
| CN104161042B (en) | A kind of composition pesticide of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
| CN107125247A (en) | A kind of bactericidal composition of fluorine-containing thiazole pyrrole ethyl ketone and methoxy acrylic | |
| CN104412982B (en) | A kind of compound highly effective bactericidal composition of fluorine-containing ether bacterium amide | |
| CN105191939B (en) | A kind of bactericidal composition | |
| CN103371190A (en) | Pesticide combination containing pyrimidine nucleosides antibiotics | |
| CN103518724B (en) | Bactericidal composition containing fluopyram and methoxyacrylate | |
| CN104137836B (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
| CN104126585B (en) | A kind of combination sterilization composition of fluorine-containing azoles bacterium aniline | |
| CN103651451A (en) | Pesticide composition containing penthiopyrad | |
| CN104285954B (en) | A kind of bactericidal composition | |
| CN104412983B (en) | A kind of efficient bactericidal composite of fluorine-containing ether bacterium amide | |
| CN105284806B (en) | A kind of bactericidal composition containing zoxamide and methoxy acrylic | |
| CN107125248A (en) | A kind of efficient bactericidal composite of fluorine-containing thiazole pyrrole ethyl ketone | |
| CN107396926A (en) | It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic | |
| CN105028419B (en) | A kind of bactericidal composition containing Fenarimol | |
| CN105638686B (en) | A kind of combination sterilization composition containing tiger glue adipic acid copper | |
| CN104106582B (en) | A kind of bactericidal composition containing chlorine nalidixic bacterium ester and thiocarbamates | |
| CN105746547B (en) | A kind of bactericidal composition of amine-containing benzene pyrrole bacterium ketone | |
| CN104012556B (en) | A kind of bactericidal composition containing fluorine mepanipyrim and thiocarbamates | |
| CN103535362A (en) | Efficient bactericidal composition | |
| CN107347884A (en) | A kind of bactericidal composition containing isopropyl metsulfovax | |
| CN104719308B (en) | A kind of bactericidal composition of fluorine-containing azoles Acibenzolar | |
| CN105454292A (en) | Compound sterilizing composition containing copper oxychloride | |
| CN105519536A (en) | Benzovindiflupyr containing pesticidal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170905 |
|
| WD01 | Invention patent application deemed withdrawn after publication |