CN105901012A - Suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin - Google Patents

Suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin Download PDF

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Publication number
CN105901012A
CN105901012A CN201610399399.4A CN201610399399A CN105901012A CN 105901012 A CN105901012 A CN 105901012A CN 201610399399 A CN201610399399 A CN 201610399399A CN 105901012 A CN105901012 A CN 105901012A
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CN
China
Prior art keywords
pyraclostrobin
clothianidin
azoles bacterium
seed
bacterium aniline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610399399.4A
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Chinese (zh)
Inventor
朱刚
张志伟
王礼文
陈佛祥
吴泽伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Application filed by Guangdong Zhongxun Agri Science Corp filed Critical Guangdong Zhongxun Agri Science Corp
Priority to CN201610399399.4A priority Critical patent/CN105901012A/en
Publication of CN105901012A publication Critical patent/CN105901012A/en
Withdrawn legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

Abstract

The invention relates to a suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin. The mass of the pyraclostrobin accounts for 1-20% of the total mass of the composition, the mass of the penflufen accounts for 1-20% of the total mass of the composition, and the mass of the clothianidin accounts for 1-60% of the total mass of the composition. The weight ratio of the pyraclostrobin having bactericidal activity to the penflufen having bactericidal activity is 1:5-5:1, the weight ratio of the pyraclostrobin and penflufen having bactericidal activity to clothianidin having insecticidal activity is 1:1-1:20. The suspended seed coating can effectively improve the emergence rate of seeds after planting of peanut, corn and wheat, and has the good prevention effect on plant diseases and insect pests in the seedling stage.

Description

Containing pyraclostrobin and fluorine azoles bacterium aniline and the suspension seed-coating agent of clothianidin
Technical field
The present invention relates to field of pesticide preparation, relate generally to one and cultivate peanut seed coat agent, be used for preventing and treating Soil-borne disease and pest damage.
Background technology
In modern agricultural production, utilizing seed coat agent that seed carries out chemicals treatment is preventing and treating underground Insect and crops soil pass, one of the method for economical and convenient of seed-borne disease.Seed coat agent is a kind of For crop or other plant seed treatment, the pesticidal preparations with film forming characteristics, it can The film referred to as planting clothing it is solidify to form at the surface of the seed.Seed coat agent in soil imbibition and not by Dissolve, it is allowed to seed normally germinates required moisture and air passes through, contained pesticide and seed manure Slowly discharge Deng material, it is possible to kill subterranean pest-insect, insect in seedling stage, there is preventing and treating sprout term disease With systematicness disease, improve percentage of seedgermination, promote the effect such as seedling healthy growth.
Suspension seed-coating agent is the one of seed coat agent, be by pesticide original medicine, film former, wetting agent, The one that dispersant, thickening agent, coloring agent, filler and water are made through waterproof pulverization is flowable Stable unit for uniform suspension.Owing to it is easy to use, safe, in the seed coat agent of numerous kinds In gain great popularity.
Pyraclostrobin is New-type wide-spectrum antibacterial, the mechanism of action: for mitochondrial respiratory inhibitor, I.e. by stoping electron transfer at cytochrome in synthesizing.There is protection, treatment, blade infiltration Conduction.Pyraclostrobin cream through field control effectiveness test result show to powdery mildew of cucumber, Downy mildew and banana freckle, leaf spot, sclerotiniose etc. have preferable prevention effect.
Fluorine azoles bacterium aniline belongs to pyrazole amide series bactericidal agent, for efficient, low toxicity, low-residual, holding effect The wide spectrum systemic fungicide that the variation of phase length, insecticide-applying way, protection and therapeutic effect are all excellent, Stem and leaf process, seed treatment and soil treatment can be made.
Clothianidin is a kind of insecticide in anabasine, is a class highly effective and safe, high selectivity Novel pesticide, its effect is similar with nAChR, have tag, stomach toxicity and Systemic activity.Be mainly used on Oryza sativa L., vegetable, fruit tree and other crops anti-eliminating aphis, leafhopper, The Semiptera such as thrips, plant hopper, coleoptera, Diptera and the insecticide of some Lepidoptera class pest, Have efficiently, wide spectrum, consumption are few, toxicity is low, drug effect lasting period length, to crop without poisoning, Use the advantages such as safety and conventional pesticide no interactions resistance, have interior suction and the osmosis of brilliance, It it is the another kind substituting high-toxic organic phosphorus pesticide.Its novel structure, special, performance and tradition Nicotinic insecticide is compared the most excellent, it is possible to become international large-scale insecticide variety.
Crops, from being seeded into results, not only face all kinds of disease, worm, the harm of grass, but also Endangered by birds, muroid.Ensureing on the premise of preventing disease pest control, how to accomplish rat destruction, Bird dispelling, significant in agricultural production.
Summary of the invention
It is an object of the present invention to provide a kind of suspension seed-coating agent, the seed before peanut seed is sowed Coating uses, and has parasite killing, a bactericidal effect, improves percentage of seedgermination, it is ensured that seedling stage crop not By soil-borne disease and pest damage.
For realizing the purpose of the present invention, the present invention adopts the following technical scheme that
A kind of containing pyraclostrobin and fluorine azoles bacterium aniline and the suspension seed-coating agent of clothianidin, pyrrole Azoles kresoxim-methyl accounts for compositions gross mass 1%~20%, fluorine azoles bacterium aniline account for compositions gross mass 1%~ 20%, clothianidin accounts for compositions gross mass 1%~60%, and remaining is insecticides adjuvant;Wherein have and kill The pyraclostrobin of bacterium activity is 1:5-5:1 with the weight ratio of fluorine azoles bacterium aniline;There is sterilization live Property pyraclostrobin, the weight ratio of clothianidin of fluorine azoles bacterium aniline weight sum and insecticidal activity For 1:1-1:20.
The insecticides adjuvant that the present invention relates to include dispersant, film former, coloring agent, thickening agent, The common pesticide seed coating additives such as antifreezing agent, preservative, defoamer.
In order to promote that between particles of active components, wetting and dispersing prevents its phase inter coagulation, of the present invention Suspension seed-coating agent also includes that wetting dispersing agent, described wetting dispersing agent are preferably fatty alcohol polyoxy second Alkene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid, alkylaryl polyglycol ether, Alkylsulfonate, arylsulphonate, fatty acid polyglycol ethylene glycol, dodecyl benzene sulfonate, poly- Oxyethylene group phenol formaldehyde condensate, polyoxyethylene poly-oxygen propylene aether block copolymer, naphthalene or alkyl Naphthalene formaldehyde condensate sulfonates, aliphatic alcohol polyoxyethylene sulfonate, alkylphenol polyoxyethylene Sulfonate, lignin and derivant sulfonate thereof, fatty acid ethane additive product phosphate, alkyl One in phenol polyethenoxy ether phosphate, alkylphenol polyoxyethylene formaldehyde condensation products sulfate Or it is two or more.
Seed and root is acted on, difficult drop-off and flying in order to ensure that limited farm chemical ingredients is concentrated Dissipate, decrease pesticide diffusion in the environment and non-target target contacted, described suspended seed coating Agent also needs to include film former.Described film former should ensure that institute's ready-made clothes film is ventilative, good water permeability, Normal seed germination grows, and ensures that institute's ready-made clothes film is insoluble in water again, active component energy in clothing film Slowly release, efficiency time is long.It is preferably arabic gum according to film former of the present invention, moves Thing glue, pectin, xanthan gum, methylcellulose, ethyl cellulose, sodium carboxymethyl cellulose, Hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, Polyethylene Glycol, polyvinylpyrrolidone, poly- One or more in acrylamide, sodium polyacrylate.
Coloring agent, also known as alert toner, can improve the use safety of suspension seed-coating agent, wherein said Coloring agent is preferably one or more in basic rhodamine, aqueous rhodo, acid scarlet.
Suspension seed-coating agent of the present invention also includes thickening agent, to improve the viscosity of disperse medium, Reduce the sedimentation velocity of particle, thus improve the stability of preparation.Preferably, described tackifier For xanthan gum, arabic gum, methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, Hydroxypropyl cellulose, sodium acrylate, sodium alginate, polyvinyl alcohol, polyvinylpyrrolidone, One or more in polyacrylamide, sodium polyacrylate, aluminium-magnesium silicate, bentonite.
In order to improve the stability of the low temperature storage of seed coat agent, suspension seed-coating agent of the present invention is also With the addition of antifreezing agent.Preferably, described antifreezing agent be ethylene glycol, propylene glycol, glycerol, oneself One or more in glycol, carbamide, ammonium sulfate, sodium chloride, calcium chloride.As excellent Choosing, defoamer of the present invention is machine silicone, C8-10Fatty alcohol, C10-20Satisfied fatty acid And one or more in esters;Described preservative is benzoic acid, benzaldehyde, benzene first Acid sodium, Potassium Benzoate, sorbic acid, sodium salicylate, 2-xenol, hydroxy benzaldehyde 1, One or more in 2-[4-morpholinodithio quinoline-3-ketone.
The preparation method of suspension seed-coating agent of the present invention is: by pyraclostrobin, fluorine azoles bacterium benzene Amine, clothianidin through comminution by gas stream, wetting dispersing agent, film former, coloring agent, thickening agent, After antifreezing agent, preservative, defoamer and distilled water are completely dissolved, put into sand mill in proportion and grind Grind 2 times, until it is 2-3 μm that the fineness of the particles of suspension reaches D50, D90 < 8 μm, i.e. Obtain product.During actual medication, the present invention can according to local controlling object a situation arises really The consumption that fixed described suspension seed-coating agent is suitable, usual formulation rate is the mass ratio of seed coat agent and seed For 1:50-100.
Suspension seed-coating agent prepared by the present invention is vivid suspension red, flowable, low temperature, Heat storage stability is qualified, and heat storage resolution ratio is less than 5%, and suspensibility is more than 90%, wet screening test 98 % passes through 45 μm standard screens, and fineness of the particles D50 is 2-3 μm.
After different seed coat agent active component mixing, each active component is due to composition, structure, physics and chemistry The difference of character so that the synergy between each active component be typically expressed as potentiation, Summation action or antagonism.So-called potentiation is exactly to cooperate effect between different material, Its effect produced is more than the sum total of each composition effect;And summation action is exactly its effect produced Fruit is equal to the sum total of each composition effect;Antagonism refers to that two kinds of materials act on living organism Time, the effect of the another kind of material of a kind of material interference, or the effect of interfering with an opponent each other, Make the phenomenon that general effect declines.
The determination method of indoor bactericidal activity of the present invention is:
Use pastille medium therapy: take the medicinal liquid 6mL of each single dose and mixture series concentration, add In the PDA culture medium of the 54mL being cooled to 45 DEG C, the pastille making required final concentration is cultivated Base flat board.Then 6mm diameter mycelia is produced from the slijmziekte bacterium colony edge cultivated 7 days Block, moves in each series pastille culture medium, and mycelia faces down, and each process repeats for 4 times.Place Manage complete, be placed in the constant temperature biochemical cultivation case of 25 ± 1 DEG C cultivation.
Data analysing method uses: according to the co-toxicity coefficient method (CTC) of Sun&Johnson (1960) Evaluating the potentiation of pharmacy mix, i.e. CTC≤80 is antagonism, and 80 < CTC < 120 are Summation action, CTC >=120 are potentiation.
Table 1, pyraclostrobin, the fluorine azoles bacterium aniline mixture toxicity test result to slijmziekte bacterium
From above technical scheme, suspension seed-coating agent of the present invention is with pyraclostrobin, fluorine Azoles bacterium aniline, clothianidin are compounding as effective ingredient, pyraclostrobin, fluorine azoles bacterium aniline according to 1:5-5:1 shows notable synergistic effect to slijmziekte bacterium, adds in fungicide mixture The clothianidin of content 10-30% preventive effect actual on antibacterial and potentiation do not have any impact, with Time can enough have complementary advantages, while preventing and kill off disease, it is possible to effectively prevent and kill off insect pest.
Detailed description of the invention
The embodiment of the invention discloses a kind of suspension seed-coating agent.Those skilled in the art can use for reference Present disclosure, is suitably modified technological parameter and realizes.Special needs to be pointed out is, all similar Replacing and change apparent to those skilled in the art, they are considered as including In the present invention.The product of the present invention is described by embodiment, and related personnel is obvious In without departing from present invention, spirit and scope, product as herein described can be modified or Suitably change and combination, realize and apply the technology of the present invention.
In order to be further appreciated by the present invention, the one provided the present invention below in conjunction with embodiment is hanged Floating seed coat agent is described in detail.
Embodiment 1:30% pyraclostrobin fluorine azoles bacterium aniline clothianidin suspension seed-coating agent.
Following material is weight ratio: 2% pyraclostrobin, 3% fluorine azoles bacterium aniline, 25% thiophene worm Amine, 2% dodecyl benzene sulfonate, 0.4%PVA, 2% azarin, 1%% ethylene glycol, 0.2% prevent Rotten agent, 0.1% defoamer, surplus is distilled water.
Testing and carry out in Guangdong Huizhou Peanut Fields, suspension seed-coating agent is with pyraclostrobin, fluorine azoles Bacterium aniline, clothianidin are the seed coat agent that active component is compounding, and single dose is respectively 5% clothianidin and suspends Seed coat agent, 2.5% pyraclostrobin suspension seed-coating agent, 2% fluorine azoles bacterium aniline seed coat agent, respectively suspend Seed coat agent test seed and experimental enviroment are the most identical.
Test situation is as follows: according to registration product testing amount ratio relatively, three above single dose processes Qu Jun has droop, Holotrichia diomphalia Bates subterranean pest-insect to occur.2% pyraclostrobin 3% fluorine azoles bacterium aniline 25% Clothianidin mixture is 85.8% to the preventive effect of slijmziekte, and subterranean pest-insect is prevented and kill off effect Fruit is 92.5%, and single dose preventive effect is below 70%.Single dose treatment region is to slijmziekte and root rot Preventing and treating substantially relatively mixture treatment region poor, the process of mixture relatively single dose substantially has controlling disease advantage. For the preventing and treating of subterranean pest-insect, single dose clothianidin and the clothianidin no significant difference containing mixture.Combine Close and state knowable to test situation, 2% pyraclostrobin 3% fluorine azoles bacterium aniline 25% clothianidin mixture There is good pest control treatment effect.
Embodiment 2: for corn trials.
The 30% pyraclostrobin fluorine azoles bacterium aniline clothianidin using embodiment 1 to prepare suspends Seed coat agent, for Semen Maydis, tests and carries out in yueyang, hunan corn field, and suspension seed-coating agent is with pyrrole Azoles kresoxim-methyl, fluorine azoles bacterium aniline, clothianidin are the seed coat agent that active component is compounding, and single dose is respectively It is 5% clothianidin suspension seed-coating agent, 2.5% pyraclostrobin suspension seed-coating agent, 2% fluorine azoles bacterium aniline Seed coat agent, each suspension seed-coating agent test seed and experimental enviroment are the most identical.
Test situation is as follows, and according to registration product testing amount ratio relatively, single dose treatment region is to Semen Maydis The preventing and treating of root rot substantially relatively mixture treatment region is poor, and mixture relatively single dose processes substantially has anti-curing the disease Evil advantage.2% pyraclostrobin 3% fluorine azoles bacterium aniline 25% clothianidin mixture is to slijmziekte Preventive effect be 83.6%, the preventive effect to subterranean pest-insect is 97.1%, and single dose preventive effect is the lowest In 75%.For the preventing and treating of subterranean pest-insect, single dose clothianidin and the clothianidin containing mixture without substantially Difference, can have preferable prevention effect to cutworm and Holotrichia diomphalia Bates.Summary test situation Understanding, 2% pyraclostrobin 3% fluorine azoles bacterium aniline 25% clothianidin mixture has good insect protected Cure the disease effect.
Embodiment 3: test for Semen Tritici aestivi.
The 30% pyraclostrobin fluorine azoles bacterium aniline clothianidin using embodiment 1 to prepare suspends Seed coat agent, for Semen Tritici aestivi, tests and carries out in Henan wheat field, and suspension seed-coating agent is with pyrazoles ether Bacterium ester, fluorine azoles bacterium aniline, clothianidin are the seed coat agent that active component is compounding, and single dose is respectively 5% Clothianidin suspension seed-coating agent, 2.5% pyraclostrobin suspension seed-coating agent, 2% fluorine azoles bacterium aniline kind clothing Agent, each suspension seed-coating agent test seed and experimental enviroment are the most identical.
Test situation is as follows, 2% pyraclostrobin 3% fluorine azoles bacterium aniline 25% clothianidin treatment region Disease, insect pest occur.The preventing and treating substantially relatively mixture of Wheat Seedling disease is processed by single dose treatment region District is poor, and mixture relatively single dose processes substantially has controlling disease advantage.For subterranean pest-insect wireworm And the preventing and treating of early stage aphid, single dose clothianidin and the clothianidin no significant difference containing mixture, can Enough have preferable prevention effect to cutworm and Holotrichia diomphalia Bates.Summary test situation understands, 2% pyrrole Azoles kresoxim-methyl 3% fluorine azoles bacterium aniline 25% clothianidin mixture has good pest control treatment effect.
The explanation of above example is only intended to help to understand that the method for the present invention and core thereof are thought Think.It should be pointed out that, for those skilled in the art, without departing from this On the premise of bright principle, it is also possible to the present invention is carried out some improvement and modification, these improve and Modify in the protection domain also falling into the claims in the present invention.

Claims (4)

1. one kind contains pyraclostrobin and fluorine azoles bacterium aniline and the suspended seed coating of clothianidin Agent, it is characterised in that: effective ingredient is pyraclostrobin and fluorine azoles bacterium aniline and clothianidin, Pyraclostrobin accounts for compositions gross mass 1%~20%, and fluorine azoles bacterium aniline accounts for compositions gross mass 1%~20%, clothianidin accounts for compositions gross mass 1%~60%, and remaining is insecticides adjuvant.
One the most according to claim 1 contain pyraclostrobin and fluorine azoles bacterium aniline and The suspension seed-coating agent of clothianidin, it is characterised in that: there is pyraclostrobin and the fluorine of bactericidal activity The weight ratio of azoles bacterium aniline is 1:5-5:1.
One the most according to claim 1 contain pyraclostrobin and fluorine azoles bacterium aniline and The suspension seed-coating agent of clothianidin, it is characterised in that: there is the pyraclostrobin of bactericidal activity, fluorine Azoles bacterium aniline weight sum is 1:1-1:20 with the weight ratio of the clothianidin of insecticidal activity.
4. the one described in claim 1 contains pyraclostrobin and fluorine azoles bacterium aniline and thiophene worm The suspension seed-coating agent of amine is at preventing and treating Semen arachidis hypogaeae, Semen Maydis, Wheat Seedling pest and disease damage and improves seed The application of emergence rate.
CN201610399399.4A 2016-06-08 2016-06-08 Suspended seed coating prepared from pyraclostrobin, penflufen and clothianidin Withdrawn CN105901012A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107258777A (en) * 2017-06-21 2017-10-20 北京明德立达农业科技有限公司 A kind of seed treatment microcapsules suspension suspending agent of pyraclostrobin-containing and fluorine azoles bacterium aniline and preparation method thereof
CN108450471A (en) * 2018-03-12 2018-08-28 佛山市盈辉作物科学有限公司 A kind of seed coat agent containing fluorine azoles bacterium aniline, pyraclostrobin and fluorine thiazole pyrrole ethyl ketone
CN115886025A (en) * 2022-10-25 2023-04-04 上海沪联生物药业(夏邑)股份有限公司 Seed treatment agent containing penflufen and clothianidin and application thereof
CN116210714A (en) * 2023-02-14 2023-06-06 上海沪联生物药业(夏邑)股份有限公司 Seed treatment composition containing penflufen, prothioconazole and neonicotinoid compounds

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103237449A (en) * 2010-07-26 2013-08-07 拜耳知识产权有限责任公司 Use of succinate dehydrogenase inhibitors and/or respiratory chain complex III inhibitors for improving the ratio of harmful to beneficial microorganisms
CN104161042A (en) * 2013-05-18 2014-11-26 陕西美邦农药有限公司 Pesticide composition containing penflufen and methoxy acrylate
CN105265471A (en) * 2015-11-05 2016-01-27 山东棉花研究中心 Disease resistance and insect prevention composition containing ganoderan and clothianidin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103237449A (en) * 2010-07-26 2013-08-07 拜耳知识产权有限责任公司 Use of succinate dehydrogenase inhibitors and/or respiratory chain complex III inhibitors for improving the ratio of harmful to beneficial microorganisms
CN104161042A (en) * 2013-05-18 2014-11-26 陕西美邦农药有限公司 Pesticide composition containing penflufen and methoxy acrylate
CN105265471A (en) * 2015-11-05 2016-01-27 山东棉花研究中心 Disease resistance and insect prevention composition containing ganoderan and clothianidin

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107258777A (en) * 2017-06-21 2017-10-20 北京明德立达农业科技有限公司 A kind of seed treatment microcapsules suspension suspending agent of pyraclostrobin-containing and fluorine azoles bacterium aniline and preparation method thereof
CN108450471A (en) * 2018-03-12 2018-08-28 佛山市盈辉作物科学有限公司 A kind of seed coat agent containing fluorine azoles bacterium aniline, pyraclostrobin and fluorine thiazole pyrrole ethyl ketone
CN115886025A (en) * 2022-10-25 2023-04-04 上海沪联生物药业(夏邑)股份有限公司 Seed treatment agent containing penflufen and clothianidin and application thereof
CN116210714A (en) * 2023-02-14 2023-06-06 上海沪联生物药业(夏邑)股份有限公司 Seed treatment composition containing penflufen, prothioconazole and neonicotinoid compounds

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