CN107027787A - The composition of fluorine-containing azoles bacterium aniline and Tolprocarb - Google Patents

The composition of fluorine-containing azoles bacterium aniline and Tolprocarb Download PDF

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Publication number
CN107027787A
CN107027787A CN201710295148.6A CN201710295148A CN107027787A CN 107027787 A CN107027787 A CN 107027787A CN 201710295148 A CN201710295148 A CN 201710295148A CN 107027787 A CN107027787 A CN 107027787A
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composition
fluorine
tolprocarb
agent
active components
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CN201710295148.6A
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不公告发明人
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Beijing Agricultural Science And Technology Center
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Beijing Agricultural Science And Technology Center
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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Abstract

The invention provides a kind of cooperative compositions of fluorine-containing azoles bacterium aniline and Tolprocarb, it is characterized in that in addition to the fluorine azoles bacterium aniline and Tolprocarb of component A, also B component medicament is used as including at least one other bactericide or insecticide, and the auxiliary agent that can be used in Pesticide formulation, conventional pesticidal preparations are made, and applied to preventing and treating plant pest.

Description

The composition of fluorine-containing azoles bacterium aniline and Tolprocarb
Technical field
The invention belongs to pesticides application technical field, it is related to a kind of composition pesticide, specifically a kind of fluorine-containing azoles bacterium The composition of aniline and Tolprocarb, applied to preventing and treating plant pest.
Background technology
In agricultural production process, plant pest occurs seriously, the position such as harm plant roots, stem, leaf, and fruit, The organs of multiplication such as seed, stem tuber, make crop yield fall sharply, and quality decline is serious.When pest and disease damage occurs serious, cause crop exhausted Receive.Therefore, plant pest has important meaning of preventing and treating in produce reality, and bactericide or insecticide are preventing and treating plant disease pests The most economic, the quick and effective method of evil.
Also, in actual production, plant pest often occurs, and such as plants biography, soil-borne disease and subterranean pest-insect, leaf simultaneously Face disease and leaf insects etc. usually occur simultaneously, and single use bactericide or insecticide can not solve production well real Plant pest harm problem in border.By bactericide and insecticide mixture, can remedy such and insufficient, both have complementary advantages, can Expand preventing and treating spectrum, comprehensive effective disease and pest control harm turns into well received application form in production practices.Especially have There are the bactericide and insecticide of synergy, each active principle interphase interaction makes combined effect better than exclusive use effect Theoretical summation, thus can be played a multiplier effect in actual use, more favored by user.
Fluorine azoles bacterium aniline (penflufen) category succinate dehydrogenase inhibitors (SDHI), by disturbing mitochondrial respiratory electricity In sub- transfer chain in complexⅱ succinate dehydrogenase activity, so as to suppress mitochondrial function.Be mainly used in preventing and treating potato, The soil in the various crop seedling stage such as paddy rice, wheat, barley, corn, cotton and maturity period is passed and seed-borne disease.Structural formula is as follows：
Amisulbrom (amisulbrom), Metalaxyl-M (metalaxyl-M), fludioxonil (fludioxonil), miaow are fresh Amine (prochloraz), hymexazos (hymexazol), Silthiopham (silthiofam), fenoxanil (fenoxanil), rice Pest ester (pefurazoate), jinggangmeisu (validamycin), kasugarnycin (kasugamycin), Acibenzolar (acibenzolar and acibenzolar-S-methyl), hexaconazole (hexaconazole), probenazole (probenazole), fluoxastrobin (fluoxastrobin), pyraclostrobin (pyraclostrobin), Fluoxastrobin (azoxystrobin), trifloxystrobin (trifloxystrobin), SSF 126 (metominostrobin), orysastrobin (orysastrobin), thifluzamide (thifluzamide), Difenoconazole (difenoconazole), Triadimenol (triadimenol), fluorine bacterium azoles (triflumizole), metconazole (metconazole), triticonazole (triticonazole), Kind bacterium azoles (ipconazole), Fenamidone (fenamidone), iprodione (iprodione) are a variety of broad-spectrum germicides, MTI-446 (dinotefuran), imidacloprid (imidacloprid), Acetamiprid (acetamiprid), clothianidin (clothianidin), Diacloden (thiamethoxam), Nitenpyram (nitenpyram), sulfoxaflor (sulfoxaflor), spiral shell worm ethyl ester (spirotetramat), chlopyrifos (chlorpyrifos), carbosulfan (carbosulfan), ethiprole (ethiprole), trifluoro-benzene pyrimidine (triflumezopyrim), metaflumizone (metaflumizone), ethofenprox (etofenprox), emamectin benzoate (emamectin benzoate), AVM (abamectin), Rynaxypyr (chlorantraniliprole), bromine cyanogen insect amide (cyantraniliprole), second Quito bacteriocidin (spinetoram), multiple killing teichomycin (spinosad), ring tebufenozide (chromafenozide) are a variety of wide spectrums Property insecticide.Above-mentioned medicament shows excellent preventive effect to multiple diseases or insect pest.
The present invention is studied by substantial amounts of formulation screening test and found, when fluorine azoles bacterium aniline and Tolprocarb composition With amisulbrom, Metalaxyl-M, fludioxonil, Prochloraz, hymexazos, Silthiopham, fenoxanil, pefurazoate, jinggangmeisu, Kasugarnycin, Acibenzolar, hexaconazole, probenazole, fluoxastrobin, pyraclostrobin, Fluoxastrobin, trifloxystrobin, SSF 126, Orysastrobin, thifluzamide, Difenoconazole, Triadimenol, fluorine bacterium azoles, metconazole, triticonazole, kind bacterium azoles, Fenamidone, different bacterium Urea, MTI-446, imidacloprid, Acetamiprid, clothianidin, Diacloden, Nitenpyram, sulfoxaflor, spiral shell worm ethyl ester, chlopyrifos, fourth Carbosulfan, ethiprole, trifluoro-benzene pyrimidine, metaflumizone, ethofenprox, emamectin benzoate, AVM, Rynaxypyr, bromine cyanogen When one or more kinds of medicaments in insect amide, ethyl pleocidin, multiple killing teichomycin, ring tebufenozide are combined, show Surprising pesticide-germicide effect, that is, show good synergy, and actual effect is substantially better than the theory of exclusive use Summation, has application prospect widely in production.
The content of the invention
The present invention relates to cooperative compositions, including active components A and B, described active components A for fluorine azoles bacterium aniline and Tolprocarb, described active component B is amisulbrom, Metalaxyl-M, fludioxonil, Prochloraz, hymexazos, silicon thiophene bacterium Amine, fenoxanil, pefurazoate, jinggangmeisu, kasugarnycin, Acibenzolar, hexaconazole, probenazole, fluoxastrobin, pyrazoles ether Bacterium ester, Fluoxastrobin, trifloxystrobin, SSF 126, orysastrobin, thifluzamide, Difenoconazole, Triadimenol, fluorine bacterium azoles, leaf bacterium Azoles, triticonazole, kind bacterium azoles, Fenamidone, iprodione, MTI-446, imidacloprid, Acetamiprid, clothianidin, Diacloden, Nitenpyram, Sulfoxaflor, spiral shell worm ethyl ester, chlopyrifos, carbosulfan, ethiprole, trifluoro-benzene pyrimidine, metaflumizone, ethofenprox, first dimension One kind in salt, AVM, Rynaxypyr, bromine cyanogen insect amide, ethyl pleocidin, multiple killing teichomycin, ring tebufenozide or More than one combinations.In addition, also including the auxiliary agent that can be used in Pesticide formulation.
The composition especially good effect can be used to prevent and treat the plant pest in various useful crops, described to have Include but is not limited to conventional breeding crop, genetically modified crops, asexually propagated crop and asexual propagation material, domesticating and cultivating with crop Wild plant etc., be particularly suitable for use in preventing and treating potato, paddy rice, wheat, barley, corn, cotton, peanut, vegetables, fruit tree etc. and make A variety of soil biographies, seed-borne disease and subterranean pest-insect on thing.
The instantiation that can be mentioned that can use the representative plant pest of composition for preventing and controlling of the invention, the reality for some Example is not limited to specified genus kind.It should be noted that the invention is not limited in example in detail below, can also be in the same manner Other plant pests are extended to, bracket indicates its cause of disease Latin name：
The silver-colored maize ear rot of black scurf of potato, rice sheath blight disease (Rhizoctonia solani), potato (Helminthosporium solani), maize head smut (Sphacelotheca reiliana), corn smut (Ustilago maydis), loose smut of wheat (Ustilago tritici), the bunt of wheat (Tilletia Caries), flag smut of wheat (Urocystis occulta), wheat avenge mould leaf blight (Monographella Nivalis), wheat sharp eyespot (Rhizoctonia cerealis), wheat leaf rust (Puccinia recondita), wheat Stripe rust (P.striiformis), the stem rust of wheat (P.graminis), big smut (Ustilago hordei), barley Stripe disease (Pyrenophora graminea), black loose smut of oat (Ustilago avenae), onion smut (Urocystis colchici), beans, alfalfa, bulb class, cotton, oil crops, sorghum, beet, sunflower, corn Deng crop samping off and damping-off (Rhizoctonia solani), bakanae disease of rice (Fusarium moniliforme), water Rice false smut (Ustilaginoidea oryzae), Kernel Smut of Rice (Tilletia barclayana), wheat scab (Fusarium graminearum), watermelon blight, soybean and peanut root rot (Fusarium oxysporum), fruit tree, The crop such as vegetables gray mold (Botrytis cinerea), cucumber downy mildew (Pseudoperonospora cubensis), Portugal Grape downy mildew (Plasmopara viticola), potato, tomato late blight (Phytophthora infestans), tobacco Balck shank (Phytophthora parasitica var.nicotianae), capsicum epidemic disease (Phytophthora capsic), Ornamental plant root rot (Pythium splendens), lawn rot index (Pythium aphanidermatum), wheat Full rot (Gaeumannomyces graminis), wheat powdery mildew (Blumeria graminis), powdery mildew of cucumber (Sphaerotheca fuliginea), apple mildew (Podosphaera leucotricha), apple tree canker (Valsa mali), the leaf blight of corn (Exserohilum turcicum), sigatoka (Mycosphaerella Fijiensis), Cabbage Leaf Spot (Alternaria brassicae), tomato and target (Alternaria Solani), apple peels and cores (Alternaria mali), grapevine anthracnose (Sphaceloma ampelinum), flower Raw southern blight (Sclerotium rolfsii), Causal Organism of Maize Basal Stalk (Fusarium graminearum), rice blast (Magnaporthe grisea), apple tree scab (Venturia inaequalis), pear scab (Venturia Nashicola), cucumber anthracnose (Colletotrichum orbiculare), citrus anthracnose (Colletotrichum Glecosporioides), bitter rot or anthracnose of grape (Glomerella cingulata), banana anthracnose (Colletotrichum Musae), soybean and sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Cabbage Leaf Spot (Alternaria Brassicae), tomato and target (Alternaria solani), apple peels and cores (Alternaria Mali), soybean rust (Phakopsora pachyrhizi), rice hoppers (Nilaparvata lugens), wheat aphid (Sitobion avenae), wheat midge (Sitodiplosis mosellana), corn and wheat grub (Anomala Corpulenta), corn cutworm (Agrotis ypsilon), corn wireworm (Agriotes fuscicollis), peanut Grub (Holotrichia parallela), Bradysia odoriphaga (Bradysia odoriphaga), edible fungi maggot (Lycoriella pleuroti), tea tree tea lesser leafhopper (Empoasca flavescens), wild cabbage striped flea-beetle (Phyllotrata striolata), tomato, capsicum, eggplant and cucumber Bemisia tabaci (Bemisia tabaci), tomato and Ma Ling Potato wood louse (Bactericera cockerelli), mandarin tree wood louse (Diaphorina citri), mandarin tree scale insect are (as sweared Sharp a red-spotted lizard Unaspis yanonensis, ceroplastes rubens Ceroplastes rubens etc.), apple tree cotten aphid (Eriosoma Lanigerum), mite class (such as Panonychus citri Panonychus citri, tetranychus viennensis Tetranychus viennensis, two spots Tetranychid Tetranychus urticae), Grapholita spp (Grapholitha inopinata), brassica vegetable (such as wild cabbage) it is small Diamond-back moth (Plutella xylostella), prodenia litura (Prodenia litura), Yellow Rice Borer (Tryporyza Incertulas), striped rice borer (Chilo suppressalis), rice leaf roller (Cnaphalocrocis medinalis), Rice thripses (Stenchaetothrips biformis), Lissorhoptrus oryzophilus Kuschel (Lissorhoptrus oryzophilus) etc..
In order to solve the above-mentioned technical problem, the present invention, which is adopted the following technical scheme that, is achieved：
The present composition component A and B can be with arbitrary proportion mixtures, and a kind of usual active component content is higher than rest activity Composition, preferably mixing ratio are 100：1 to 1：100 or 50：1 to 1：50.
The present composition can be by the way that active component be mixed with the auxiliary agent that can be used in Pesticide formulation, with known Method is prepared as conventional preparation, such as missible oil, wettable powder, seed treatment suspending agent, water dispersible granules, suspending agent, water and milk Agent, microemulsion, suspension seed-coating agent, seed treatment dry powder doses, seed treatment dispersible pulvis, granule etc..Typically contain in preparation There is the active component of the active component of 0.1~95% weight, preferably 0.5~90% weight.
The auxiliary agent that can be used in Pesticide formulation includes but is not limited to：Water, solvent, filler, various surfactants (emulsifying agent, dispersant, wetting agent etc.), adhesive, film forming agent, colouring agent, antifreezing agent, thickener, suspending agent, disintegrant, disappear Infusion, bleeding agent, warning coloration, synergist, stabilizer, wall capsule material, pH adjusting agent, preservative etc..Also, suitably, in order to Improve to specific crop tolerance, safener can be properly added；Or sometimes for crop growth is promoted, can be in mixture group Conventional agriculture fertilizer is added in compound, medicament-fertilizer mixture is made.These auxiliary agents be all commonly use in pesticidal preparations or allow to use into Point, it is not particularly limited, one or more auxiliary agent may be selected and constitutes, specific composition and consumption pass through letter according to recipe requirements Single experiment is determined.
The production technology of the various application forms of composition belongs to existing known technology, will not be repeated here.
The present composition can be used in a variety of ways, be such as watered spraying in a usual manner and used, or directly spread fertilizer over the fields or ditch Apply, or mix pesticide-clay mixture and spread fertilizer over the fields, or seed treatment etc., when plant seeding, emerge before, emerge after vegetative growth phase and reproductive stage It can be used.Dosage can change in relative broad range, and depending on the situation of soil, application method, crop, to be prevented and treated Plant pest species and seedling age size, weather conditions at that time and other factors.The present composition generally with 0.001~ The consumption of 1.0kg mixture of active principles/100kg seeds is applied, or with 0.001~1.0kg mixture of active principles/hectare Consumption apply；It is further preferable that applied with the consumption of 0.001~0.5kg mixture of active principles/100kg seeds, or with The consumption of 0.01~0.5kg mixture of active principles/hectare is applied.
The present invention compared with prior art, has the following technical effect that：
1st, mixture composition has good synergy, and application effect is substantially better than single dose theoretical effect summation, that is, had There is super superposition, plant pest occurrence injury can be better controled over；
2nd, there is good complementarity in plant pest management spectrum between mixture composition active component, can expands very well Big preventing and treating spectrum, synthesis effectively controls various plant pest occurrence injuries；
3rd, mixture composition has good synergy, can reduce medicament usage amount, and reduction use cost and environment are dirty Dye, improves the security to crop.
Embodiment
Specific embodiment of the invention given below is, it is necessary to which explanation is that the invention is not limited in implement in detail below Example, all equivalents done on the basis of technical scheme each fall within protection scope of the present invention.
Embodiment 1：20% missible oil
Being formulated composition is：Active components A is 8%, and active component B is 12%, and emulsifying agent styryl phenol polyethenoxy gathers Oxypropylene ether 4%, emulsifying agent aerosol-OT salt 5%, solvent xylene complements to 100%.
Preparation method is：All materials are put into batching kettle, stirring and dissolving after chemical examination is qualified, is shifted to fully transparent It is filling to storage tank.
Embodiment 2：14% seed treatment suspending agent
Being formulated composition is：Active components A is 5%, and active component B is 9%, wetting agent sulfosuccinic acid monooctyl ester sodium salt 4%, Dispersant maleic acid-acrylic acid copolymer sodium salt 6%, antifreeze glycol 5%, thickener aluminium-magnesium silicate 0.2%, warning coloration rose Rare smart 1%, water complements to 100%.
Preparation method is：By in active component and wetting agent, dispersant, antifreezing agent, warning coloration and water input stirred tank, fill Divide after stirring, will be fully ground in material suction sand mill, and after the completion of grinding, be pumped into high-speed shearing machine, add and thicken After agent, high speed shear is carried out, seed treatment suspending agent is made after the completion of shearing.
Embodiment 3：45% water dispersible granules
Being formulated composition is：Active components A is 30%, and active component B is 15%, wetting agent lauryl sodium sulfate 4%, point Powder calcium lignosulfonate 5%, disintegrant sodium sulphate 5%, adhesive carboxymethyl cellulose 0.2%, filler diatomite is complemented to 100%.
Preparation method is：After all materials are well mixed, crush, be well mixed again through airslide disintegrating mill, then, plus Enter a certain amount of water to mediate this mixture, extruder grain, through drying screening, that is, obtain water dispersible granules.
Embodiment 4：18% aqueous emulsion
Being formulated composition is：Active components A is 6%, and active component B is 12%, solvent xylene 10%, cyclohexanone 4%, breast Agent polyoxyethylene sorbitan aliphatic acid ketone 4%, emulsifier sodium lauryl sulfate 6%, antifreeze glycol 5%, water Complement to 100%.
Preparation method is：After active components A and B solvents are fully dissolved, input emulsifying agent forms oil after being sufficiently stirred for Phase；Antifreezing agent is added to the water dissolving, aqueous phase is formed；Aqueous phase is slowly added in oil phase, sheared using high-speed shearing machine, you can Obtain aqueous emulsion.
Embodiment 5：12% microemulsion
Being formulated composition is：Active components A is 4%, and active component B is 8%, solvent xylene 10%, emulsifying agent alkyl phenol Formaldehyde resin APEO 6%, emulsifying agent aerosol-OT salt 9%, antifreeze glycol 4%, water is complemented to 100%.
Preparation method is：After active components A and B solvents are fully dissolved, input emulsifying agent and antifreezing agent are well mixed, Deionized water is eventually adding, high speed shear is carried out, you can microemulsion is obtained.
Embodiment 6：56% wettable powder
Being formulated composition is：Active components A is 18%, and active component B is 38%, and wetting agent sldium lauryl sulfate 5% disperses The phenethyl phenol polyoxyethylene ether phosphate 6% of agent three, filler kaolin complements to 100%.
Preparation method is：Active component and each auxiliary agent are well mixed, carry out just smashing in the mechanical disintegrating machine of input, afterwards Crushed through airslide disintegrating mill, remix uniform, i.e., obtained wettable powder.
Embodiment 7：5% granule
Being formulated composition is：Active components A is 2%, and active component B is 3%, the contracting of wetting agent APES formaldehyde Compound sulfate 0.6%, dispersant calcium lignosulfonate 1.2%, colouring agent carbon black 0.2%, filler bentonite is complemented to 100%.
Preparation method is：After all materials are well mixed, add a certain amount of water and mediate this mixture, extruding is made Grain, through drying screening, that is, obtains granule.
Embodiment 8：32% suspension seed-coating agent
Being formulated composition is：Active components A is 22%, and active component B is 10%, wetting agent APES formaldehyde Condensate sulfate 3%, dispersant sodium sulfate of polyethenoxy ether of fatty alcohol 5%, film forming agent polyvinyl alcohol-polyvinyl acetate copolymerization Thing 0.5%, antifreeze glycol 5%, thickener xanthans 0.2%, warning coloration rhodamine toner 0.8%, water complements to 100%.
Preparation method is：By active component and wetting agent, dispersant, antifreezing agent, warning coloration, film forming agent and water input stirring In kettle, after being sufficiently stirred for, it is pumped into high-speed shearing machine, carries out high speed shear, then pump is fully sanded into sand mill, is sanded Thickener is added after qualified, stirs and produces suspension seed-coating agent.
Application effect example：
1st, test method
(1) to the bioactivity of Rhizoctonia solani Kuhn, wheat avenge mould leaf spoting bacteria and Sclerotium rolfssi
Reference《NYT 1156.2-2006 farm-chemical indoor determination test rule bactericide part 2s：Suppress cause of disease true Bacterium mycelial growth tests Plating》Carry out.
With Rhizoctonia solani Kuhn (Rhizoctonia solani), wheat avenge mould leaf spoting bacteria (Monographella Nivalis) or Sclerotium rolfssi (Sclerotium rolfsii) be for examination pathogen, by laboratory inclined-plane preservation bacterial strain connect The activation culture in PDA culture medium is planted, culture to colony diameter is standby up to 6cm or so.
It is standby after the sterilizings such as PDA culture medium, deionized water, line triangular flask, culture dish, pipette tips, card punch, inoculator.
Under aseptic technique, the sterilizing PDA culture medium for advance thawing being cooled into about 50 DEG C is quantitatively adding sterilizing and drawn In wire triangle bottle, make culture medium concordant with (60mL) at line, then draw 600 μ L decoctions successively from low concentration to high concentration, It is separately added into above-mentioned triangular flask, fully shakes up, rear equivalent is poured into 4 culture dishes (Φ 9cm), and 5 concentration gradient bands are made Medicine flat board.And set the processing without medicament and make blank control.Will on PDA cultured pathogen, aseptically with going out Bacterium card punch (Φ 5mm) cuts bacteria cake from the same circumference of colony edge, with inoculator by pure culture biscuits involvng inoculation in pastille flat board center, Mycelia down, covers ware lid, the dark culturing in 25 DEG C of incubators.According to mycelial growth situation in blank control ware, with card Chi measures colony diameter.Each bacterium colony uses crossing method vertical survey, takes its average value, calculates the suppression to mycelial growth Rate.
Inhibiting rate of each concentration for the treatment of to mycelial growth is calculated by formula (1), (2), unit is percentage (%), calculates knot Fruit retains 2 significant digits.
D=D1-D2…………………………………………(1)
In formula：
D-bacterium colony increases diameter, and unit is millimeter (mm)；
D1- colony diameter, unit is millimeter (mm)；
D2- bacteria cake diameter, unit is millimeter (mm).
In formula：
I-mycelial growth inhibition rate, unit is percentage (%)；
D0- blank control bacterium colony increases diameter, and unit is millimeter (mm)；
Dt- chemicals treatment bacterium colony increases diameter, and unit is millimeter (mm).
(2) to the bioactivity of rice hoppers
Reference《The part of NYT 1154.11-2008 farm-chemical indoor determination test rules insecticide the 11st：Rice stem impregnates Method》Carry out.
It is, for examination object, to choose indoor feeding, physiological status is consistent with rice hoppers (Nilaparvata lugens) 3 age nymphs tested.
The healthy and strong consistent tillering stage rice seedlings of laboratory cultures are taken, even root takes, and cleans, is cut into the company root rice of 10cm length Stem, dries in the air to surface without washmarking in shady place.Ready rice stem is respectively placed in the decoction of various concentrations and soaks 30s, is taken out Slightly dry afterwards, root moisturizing is encased with the rayon balls soaked with clear water, outsourcing preservative film is placed in test tube, per 3 plants of test tube. Test worm is put into test tube with pest sucking device, the mouth of pipe is sealed with wet gauze, often pipe 15, often repeatedly 2 managed, each 4 repetitions of concentration. If blank control is made in the processing without medicament.Connect the test tube after worm to be positioned over (25 ± 1) DEG C, relative humidity 60%~80%, light Period L:D=16h:Raised in 8h growth cabinet.
72h investigation results (death standard after processing：Polypide is touched with writing brush, polypide is stiff), total worm is recorded respectively Number and death toll.Calculate the death rate.
The death rate is calculated by formula (3), and unit is percentage (%), and result of calculation retains 2 significant digits：
In formula：
P1- the death rate, unit is percentage (%)；
The dead borer population of K-expression, unit is head；
N-expression handles total borer population, and unit is head.
(3) to the bioactivity of wheat aphid
Reference《The part of NYT 1154.6-2006 farm-chemical indoor determination test rules insecticide the 6th：Insecticidal activity is tried Test dip method》Carry out.
It is that, for examination object, indoor fresh wheat leaf blade is raised, and chooses physiology with wheat aphid (Sitobion avenae) The aptery adult aphid of state consistency is tested.
The wheat leaf blade with aptery adult aphid is clipped with tweezers, soaks and is taken out after 5s in the decoction of various concentrations, use filter paper Unnecessary decoction is sucked, is placed on and is covered with the culture dish of moistening filter paper.30 are often repeated, 4 repetitions are often handled, if without medicament Blank control is made in processing.Test worm after processing is placed in (25 ± 1) DEG C, relative humidity 60%~80%, photoperiod L:D= 16h:Raised in 8h growth cabinet.48h investigation results (death standard after processing：Polypide is touched with writing brush, polypide can not live It is dynamic), total borer population and death toll are recorded respectively.The death rate is calculated by (3) formula.
(4) to the bioactivity of peanut grub
Reference《The part of NYT 1154.15-2009 farm-chemical indoor determination test rules insecticide the 15th：Subterranean pest-insect Dip method》Carry out.
It is, for examination object, to choose indoor feeding, physiological status is consistent with peanut grub (Holotrichia parallela) Larva tested.
Larva is soaked into the liquid 10s to take out, unnecessary decoction is sucked with filter paper, test worm is transferred to equipped with new with tender In fresh peanut seedling teat glass, the mouth of pipe is covered with moist black cloth, is placed in 25 DEG C ± 1 DEG C, the perseverance of relative humidity 60%~80% Raised in warm insectary.Often handle 4 repetitions, often repeatedly 30, and set the processing without medicament as blank control.After processing 48h investigation result (death standards：Polypide is touched with writing brush, polypide is stiff), total borer population and death toll are recorded respectively.Press (3) formula calculates the death rate.
(5) compositions contemplated activity judges
Judge composition in the transnational agricultural chemicals enterprise formulation patents such as compositions contemplated activity reference Bayer, elder generation just reach, Tao Shi The method (COLBY methods) of expection activity：COLBY, S.R.：“Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 15, p.20~22,1967 are carried out.
Compositions contemplated activity is calculated by (4) formula：
In formula：
Inhibiting rate or the death rate when consumption of X-medicament 1 is P；
Inhibiting rate or the death rate when consumption of Y-medicament 2 is Q；
Inhibiting rate or the death rate when consumption of Z-medicament 3 is R；
E0The consumption of-medicament 1 is that the consumption of P+ medicaments 2 is theoretical inhibiting rate or the death rate, i.e. group when the consumption of Q+ medicaments 3 is R The expection activity of compound；
E-medicament 1,2 and 3 is by the actual inhibiting rate or the substantial activity of the death rate, i.e. composition during different ratio mixture；
As E ＞ E0When, if that is, the substantial activity of Mixed Pharmacy exceedes calculated expection activity, said composition just has There is super superposition, that is, act synergistically.
2nd, result of the test
Result of the test refers to table 1~6, it is seen then that active components A (fluorine azoles bacterium aniline and Tolprocarb) with selected from activity into After the medicament mixture for dividing B (trifloxystrobin, fluoxastrobin, fludioxonil, sulfoxaflor etc.), substantial activity is all higher than expection activity, Illustrate that active components A has synergy with the medicament mixture in active component B.
The synergy effect of the fluorine azoles bacterium aniline of table 1, Tolprocarb and trifloxystrobin mixture to Rhizoctonia solani Kuhn
The synergy of the fluorine azoles bacterium aniline of table 2, Tolprocarb and fluoxastrobin mixture to wheat avenge mould leaf spoting bacteria is imitated Should
The synergy effect of the fluorine azoles bacterium aniline of table 3, Tolprocarb and fludioxonil mixture to Sclerotium rolfssi
The synergy effect of the fluorine azoles bacterium aniline of table 4, Tolprocarb and sulfoxaflor mixture to water rice hopper
The synergy effect of the fluorine azoles bacterium aniline of table 5, Tolprocarb and Diacloden mixture to wheat aphid
The fluorine azoles bacterium aniline of table 6, Tolprocarb and the dinotefuran mixed synergy effect to peanut grub

Claims (5)

1. a kind of composition, it is characterised in that including active components A and B.
2. composition as claimed in claim 1, it is characterised in that described active components A be fluorine azoles bacterium aniline and Tolprocarb。
3. composition as claimed in claim 1, it is characterised in that described active component B is amisulbrom, smart first frost Spirit, fludioxonil, Prochloraz, hymexazos, Silthiopham, fenoxanil, pefurazoate, jinggangmeisu, kasugarnycin, Acibenzolar, oneself Azoles alcohol, probenazole, fluoxastrobin, pyraclostrobin, Fluoxastrobin, trifloxystrobin, SSF 126, orysastrobin, thifluzamide, Difenoconazole, Triadimenol, fluorine bacterium azoles, metconazole, triticonazole, kind bacterium azoles, Fenamidone, iprodione, MTI-446, imidacloprid, Acetamiprid, clothianidin, Diacloden, Nitenpyram, sulfoxaflor, spiral shell worm ethyl ester, chlopyrifos, carbosulfan, ethiprole, three Fluorobenzene pyrimidine, metaflumizone, ethofenprox, emamectin benzoate, AVM, Rynaxypyr, bromine cyanogen insect amide, sterilizing ethyl more One or more kinds of combinations in element, multiple killing teichomycin, ring tebufenozide.
4. the composition as described in claim 1,2 or 3, it is characterised in that in addition to active components A and B, in addition to agricultural chemicals system The auxiliary agent that can be used in agent processing.
5. the composition as described in claim 1,2,3 or 4, it is characterised in that be applied to preventing and treating plant pest.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019186359A1 (en) * 2018-03-26 2019-10-03 Upl Ltd Fungicidal combinations
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