CN108402050A - The composition of containing chlorantraniliprole - Google Patents
The composition of containing chlorantraniliprole Download PDFInfo
- Publication number
- CN108402050A CN108402050A CN201810246117.6A CN201810246117A CN108402050A CN 108402050 A CN108402050 A CN 108402050A CN 201810246117 A CN201810246117 A CN 201810246117A CN 108402050 A CN108402050 A CN 108402050A
- Authority
- CN
- China
- Prior art keywords
- composition
- agent
- active components
- leaf
- worm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
- A01N29/02—Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of cooperative compositions of containing chlorantraniliprole, it is characterized by comprising active components As and B, wherein, A is Rynaxypyr, B is nitrile pyrrole mite ester, cyflumetofen, pyrazine ethiprole, pyridine ethiprole, fluorine thiophene worm sulfone, 2-cyano-3-amino-3-phenylancryic acetate, Silthiopham, 1, one or more kinds of combinations in 3 dichloropropylenes, sad mantoquita, dichlobentiazox, it further include the auxiliary agent that can be used in Pesticide formulation, conventional pesticidal preparations are made, are applied to prevention plant pest.
Description
Technical field
The invention belongs to pesticides application technical fields, are related to a kind of composition pesticide, the specifically benzoyl of worm containing chlorine
The composition of amine is applied to prevention plant pest.
Background technology
In agricultural production process, plant pest occur it is serious, endanger the positions such as plant roots, stem, leaf and fruit,
The organs of multiplication such as seed, stem tuber, make crop yield fall sharply, and quality decline is serious.When pest and disease damage occurs serious, cause crop exhausted
It receives.Therefore, it is prevention plant disease pest that plant pest has important prevention meaning, fungicide or insecticide in produce reality
Evil method the most economic, quick and effective.
Also, in actual production, plant pest often occurs simultaneously, such as kind biography, soil-borne disease and subterranean pest-insect, leaf
Face disease and leaf insects etc. usually occur simultaneously, single use fungicide or insecticide, and it is real not can be well solved production
Plant pest in border endangers problem.By fungicide and insecticide mixture, can remedy such and insufficient, the two has complementary advantages, can
Expand prevention spectrum, comprehensive effective disease and pest control harm becomes well received application form in production practice.Especially have
There are the fungicide and insecticide of synergistic effect, interact between each active principle, makes combined effect better than exclusive use effect
Theoretical summation, thus can play a multiplier effect in actual use, more favored by user.
Rynaxypyr (chlorantraniliprole) is a kind of insecticide of overseas enterprise's exploitation, belongs to ryania
Receptor activators.Can be used for preventing fruit tree, vegetables, cotton, sugarcane, rice, wheat, the Lepidoptera in the various crops such as corn,
The various pests such as Diptera, coleoptera, Isoptera.CAS accession number is 500008-45-7.Its structural formula is as follows：
Nitrile pyrrole mite ester (Cyenopyrafen), cyflumetofen (Cyflumetofen), pyrazine ethiprole
(pyrafluprole), pyridine ethiprole (pyriprole), fluorine thiophene worm sulfone (fluensulfone), 2-cyano-3-amino-3-phenylancryic acetate
(phenamacril), Silthiopham (silthiofam), 1,3- dichloropropylenes (1,3-dichloropropene), sad mantoquita
(copper octanoate), dichlobentiazox are the insecticide or fungicide of broad spectrum activity, to the insect pest in various crop
Or disease shows excellent preventive effect.Above compound may include the various existence forms agriculturally used, such as salt, ester, isomers
Equal derivatives.
The present invention passes through a large amount of formulation screening test the study found that when Rynaxypyr and nitrile pyrrole mite ester, fourth fluorine mite
Ester, pyrazine ethiprole, pyridine ethiprole, fluorine thiophene worm sulfone, 2-cyano-3-amino-3-phenylancryic acetate, Silthiopham, 1,3- dichloropropylenes, sad mantoquita,
When one or more kinds of medicaments in dichlobentiazox arbitrarily combine, surprising pesticide-germicide effect is shown,
Good synergistic effect is shown, actual effect is substantially better than the theoretical summation of exclusive use, has in production very wide
General application prospect.
Invention content
The present invention relates to cooperative compositions, including active components A and B, the active components A is Rynaxypyr,
The active constituent B is nitrile pyrrole mite ester, cyflumetofen, pyrazine ethiprole, pyridine ethiprole, fluorine thiophene worm sulfone, 2-cyano-3-amino-3-phenylancryic acetate, silicon
One or more kinds of combinations in metsulfovax, 1,3- dichloropropylenes, sad mantoquita, dichlobentiazox.In addition, also wrapping
Include the auxiliary agent that can be used in Pesticide formulation.
The composition can be used to prevent the plant pest in various useful crops with particularly good effect, described to have
Include but not limited to conventional breeding crop, genetically modified crops, asexually propagated crop and asexual propagation material, domesticating and cultivating with crop
Wild plant etc., especially suitable for prevention rice, wheat, corn, cotton, sugarcane, brassica vegetable (such as wild cabbage), cucumber,
A variety of diseases on the crops such as tomato, capsicum, potato, soybean, cowpea, Kidney bean, tobacco, citrus, apple, grape, watermelon, lawn
Insect pest.
The specific example that can be mentioned that is the representative plant pest that composition for preventing and controlling of the invention can be used in some, the reality
Example is not limited to specified genus kind.It should be noted that the invention is not limited in examples in detail below, it can also be in the same manner
Other plant pests are extended to, bracket indicates its cause of disease Latin name：
Brassica vegetable (such as wild cabbage) diamondback moth (Plutella xylostella), prodenia litura (Prodenia
Litura), beet armyworm (Laphygma exigua), Yellow Rice Borer (Tryporyza incertulas), striped rice borer
(Chilo suppressalis), rice leaf roller (Cnaphalocrocis medinalis), cotton boll worm
(Helicoverpa armigera), pink bollworm (Pectinophora gossypiella), cutworm (Agroth
Segetum), extra large spodoptera (Spodoptera littoralis), prodenia litura (Prodenia litura), apple tree apple
Grapholita spp (Grapholitha inopinata), small heart-eating peach worm (Carposina niponensis), steinernema
(Adoxophyes orana), leaf roller (Pandemis heparana), moth-eaten moth (Cydia pomonella), citrus fruit fly
(Bactrocera dorsalis), the big trypetid of tangerine (Bactrocera minax), Mediterranean fruitfly (Ceratitis
Capitata), cherry fruit fly (Rhagoletis indifferens), phyllocnistis citrella stainton (Phyllocnistis citrella
Stainton), corn snout moth's larva (Ostrinia furnacalis), corn and wheat grub (Anomala corpulenta),
Corn cutworm (Agrotis ypsilon), wireworm (Agriotes fuscicollis), watermelon bollworm (Heliothis
Armigera), peanut and potato grub (Holotrichia parallela), yellow top borer (Chilotraca
Inluscatellus), yellow snout moth's larva (Aryroploce schistaceana), sugarcane tortoise (Alissonotum impressicolle),
Eating-core bean worm (Leguminivora glycinivorella), bean-pod borer (Etiella zinckenella), tea geometrid
(Ectropis oblique), tobacco oriental tobacco budworm (Helicoverpa assulta), grassland grasshopper (Locusta
Migratoria), rice locust (Oxya chinensis), loxostege sticticalis (Loxostege sticticalis), the forest U.S. is white
Moth (Hyphantria cunea), gypsymoth (Lymantria dispar), wheat aphid (Sitobion avenae), wheat
Suction pulp worm (Sitodiplosis mosellana), pear tree Grapholita spp (Grapholitha molesta), Schizaphis spp
(Schizaphis piricola), wood louse (Psylla chinensis), cotton aphid (Aphis gosypii), Btassica vegetable
Dish (such as wild cabbage) aphid (Brevicoryne brassicae), apple tree woolly aphid (Eriosoma lanigerum), mandarin tree is red
Spider (Panonychus citri), aphid (Toxoptera citricidus), wild cabbage striped flea-beetle (Phyllotrata
Striolata), soybean, peanut are chrysomelid (Paraluperodes suturalis nigrobilineatus), colorado potato bug
(Leptinotarsa decemlineata), vegetables aulacophora femoralis (Aulacophora indica), rice weevil
(Lissorhoptrus oryzophilus), tea tree tea lesser leafhopper (Empoasca flavescens), rice-leaf hopper
(Nephotettix bipunctatus), forest spot clothing plant hopper (Lycorma delicatula), tomato and potato wood louse
(Bactericera cockerelli), mandarin tree wood louse (Diaphorina citri), scale insect (such as arrowhead scales Unaspis
Yanonensis, ceroplastes rubens Ceroplastes rubens etc.), apple tree red spider：Panonychus citri (Panonychus Ulmi),
Tetranychus viennensis (Tetranychus viennensis), Tetranychus urticae (Tetranychus urticae), leek bradysia odoriphaga
(Bradysia odoriphaga), edible fungi maggot (Lycoriella pleuroti), Liriomyza brponiae (Tuta
Absoluta), Americal rice leaf miner (Liriomyza sativae), rice hoppers (Nilaparvata lugens), tomato,
Capsicum, eggplant and cucumber Bemisia tabaci (Bemisia tabaci), trialeurodes vaporariorum (Trialeurodes vaporariorum) save melon
Thrips (Thrips flavus), rice thrips (Stenchaetothrips biformis), cotton thrips
(Frankliniella intonsa), green plant bug (Lygocoris lucorum), ponderous borer (Monochamus
Alternatus), mulberry borer (Apriona germari), wheat scab (Fusarium graminearum), full rot
(Gaeumannomyces graminis), smut (Ustilago tritici), bunt (Tilletia
Caries), flag smut (Urocystis occulta), the mould leaf blight (Monographella nivalis) of snow, septoria musiva
Leaf blight (Septoria tritici), powdery mildew (Blumeria graminis), leaf rust (Puccinia
Recondita), stripe rust (P.striiformis), black rust (P.graminis), banded sclerotial blight (Rhizoctonia
Cerealis), root rot (Bipolaris sorokiniana), bakanae disease of rice (Fusarium moniliforme), rice are bent
Sick (Ustilaginoidea oryzae), rice blast (Magnaporthe grisea), kernel smut (Tilletia
Barclayana), flax leaf spot (Cochliobolus miyabeanus), cucumber downy mildew (Pseudoperonospora
Cubensis), downy mildew of garpe (Plasmopara viticola), Chinese cabbage downy mildew (Peronospora parasitica),
Potato and tomato late blight (Phytophthora infestans), Vegetables in Brassica clubroot (Plasmodiophora
Brassicae), tobacco black shank (Phytophthora parasitica var.nicotianae), capsicum epidemic disease
(Phytophthora capsic), ornamental plant corruption mildew (Pythium splendens), lawn rot index
(Pythium aphanidermatum), wild cabbage samping off (Pythium aphanidermatum), big smut
(Ustilago hordei), stripe disease (Pyrenophora graminea), moire disease (Rhynchosporium
Secalis), net blotch (Pyrenophora teres), black loose smut of oat (Ustilago avenae), maize head smut
(Sphacelotheca reiliana), smut (Ustilago maydis), onion smut (Urocystis
Colchici), the crops such as beans, alfalfa, bulb class, oil crops, sorghum, beet, sunflower, corn, cotton are dampinged off
Disease and damping-off (Rhizoctonia solani), watermelon and cotton wilt, root rot (Fusarium
Oxysporum), peanut root rot (Fusarium solani), the crops gray mold such as fruit tree, vegetables (Botrytis
Cinerea), rape, sclerotium blight of sunflower (Sclerotinia sclerotiorum), lawn coin pinta (Sclerotinia
Homoeocarpa), rape balck shank (Phoma lingam), scab of apple (Venturia inaequalis), powdery mildew
(Podosphaera leucotricha), spot defoliation (Alternaria mali), rot disease (Valsa mali), wheel line
Sick (Physalospora piricola), brown spot (Marssonina coronaria), pear scab (Venturia
Nashicola), Cabbage Leaf Spot (Alternaria brassicae), tomato, capsicum and target
(Alternaria solani), cucumber anthracnose (Colletotrichum orbiculare), citrus and pepper anthracnose
(Colletotrichum glecosporioides), strawberry, grape and apple anthracnose (Glomerella cingulata),
Banana anthracnose (Colletotrichum musae), the leaf blight of corn (Exserohilum turcicum), base rot disease
(Fusarium graminearum), helminthosporium maydis (Bipolaris maydis), sigatoka (Mycosphaerella
Fijiensis), cucurbitaceae vegetable (cucumber, cucurbita pepo, pumpkin) powdery mildew (Sphaerotheca fuliginea), strawberry is white
Powder disease (Sphaerotheca aphanis), grapevine anthracnose (Sphaceloma ampelinum), powdery mildew (Erysiphe
Necator), white rot (Coniothyrium diptodictta), citrus scab (Sphaceloma fawcettii), Huang
Imperial disease (Liberobacter asiaticum), penicilliosis (Penicillium italicum), peach brown rot (Monilinia
Fructicola), sweet cherry brown rot (Monilinia laxa), mango blossom-end rot (Phomopsis mangiferae), flower
Raw southern blight (Sclerotium rolfsii), leaf spot (Cercospora arachidicola), crown rot
(Aspergillus niger), cotton verticillium wilt (Verticillium dahliae), soybean rust (Phakopsora
Pachyrhizi), purple spot (Cercospora kikuchii), watermelon grafting (Mycosphaerella melonis), cigarette
Careless rust (Alternaria alternata), black scurf of potato and rice sheath blight disease (Rhizoctonia solani),
Potato silver maize ear rot (Helminthosporium solani), ornamental flower black spot (Septoria fhrysanth) are eaten
Fungus diseases (such as brown rot Mycogone perniciosa, brown spot Verticillium fungicola, green mold
Trichoderma viride, Neurospora Neurospora crassa etc.), peach gummosis (Botryosphaeria
Ribis), Leaf Spot Caused by Corynespora cassiicola on Cucumber (Corynespora cassiicola), beet cercospora leaf spot (Cercospora beticola), water
The bacterial blight of rice (Xanthomonas oryzae), bacillary glume blight (Burkholderi gluma), bacillary damping-off
(Pseudomonas plantarii), citrus bacterial canker disease (Xanthomonas campestris), peach Bacterial septicaemia syndrome
(Xanthomonas arboricola), wildfire (Pseudomonas syringae pv.tabaci), tobacco, tomato
With eggplant bacterial wilt (Pseudomonas solanacearum), cucumber bacterial angular leaf spot (Pseudomonas syringae
Pv.lachrymans), soft rot of Chinese cabbage (Erwinia carotovora), tomato, eggplant, cucumber, celery, tobacco root knot
Nematodiasis (Meloidogyne incognita), capsicum root knot nematode disease (Meloidogyne hapla), peanut root-knot nematode
Sick (Meloidogyne arenaria), soybean cyst nematode Heterodera glycines (Heterodera glycines), javanese root knot nematode
(Meloidogyne javanica), soybean Cobb root (Pratylenchus penetrans), lawn needle pierce nematode
(Belonolaimus longicaudatus), corn lesion nematode (Pratylenchus zeae), globodera rostochiensis
(Globodera rostochiensis), tomato kidney worm (Rotylenchulus reniform) etc..
In order to solve the above-mentioned technical problem, the present invention is realised by adopting the following technical scheme：
The present composition component A and B can be with arbitrary proportion mixtures, and usually a kind of active component content is higher than rest activity
Ingredient, preferably mixing ratio are 100：1 to 1：100 or 50：1 to 1：50.
The present composition can be by mixing active constituent with the auxiliary agent that can be used in Pesticide formulation, with known
Method is prepared as conventional preparation, such as missible oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, particle
Agent, dispersible oil-suspending agent, microcapsule suspending agent, suspension emulsion, suspension seed-coating agent, seed treatment suspending agent, seed treatment are dispersible
Pulvis etc..The active constituent of 0.1~95% weight, the preferably active constituent of 0.5~90% weight are typically contained in preparation.
The auxiliary agent that can be used in Pesticide formulation includes but not limited to：Water, solvent, filler, various surfactants
(emulsifier, dispersant, wetting agent etc.), adhesive, colorant, antifreezing agent, thickener, suspending agent, disintegrant, disappear at film forming agent
Infusion, bleeding agent, warning coloration, stabilizer, wall capsule material, pH adjusting agent, preservative etc..Also, suitably, in order to improve to spy
Ordered goods tolerance can be properly added safener；Or sometimes for crop growth is promoted, it can add in mixture composition
Add conventional agriculture fertilizer, medicament-fertilizer mixture is made.These auxiliary agents are all to commonly use in pesticidal preparations or allow the ingredient used, have no spy
It does not limit, one or more auxiliary agents may be selected and constitute, specific ingredient and dosage are according to recipe requirements by simply testing
It determines.
The production technology of the various application forms of composition belongs to existing known technology, and details are not described herein.
The present composition can use in a variety of ways, be such as watered spraying in a usual manner and use, or directly spread fertilizer over the fields or ditch
Apply, or mix pesticide-clay mixture and spread fertilizer over the fields or seed treatment etc., when plant seeding, before emergence, vegetative growth phase and reproductive stage after emergence
It can be used.Dosage can change in wider range, and depending on the situation of soil, application method, crop, to be prevented
Plant pest type and seedling age size, weather conditions at that time and other factors.The present composition usually with 0.001~
The dosage of 2.0kg mixture of active principles/hectare is applied, or is applied with the dosage of 1~2000mg mixture of active principles/kg
With, or with the dosage application of 0.001~1.0kg mixture of active principles/100kg seeds；It is further preferable that with 0.01~
The dosage of 1.0kg mixture of active principles/hectare is applied, and is applied with the dosage of 10~1000mg mixture of active principles/kg, or
Person is applied with the dosage of 0.01~0.8kg mixture of active principles/100kg seeds.
Compared with prior art, the present invention having the following technical effect that：
1, there is mixture composition good synergistic effect, application effect to be substantially better than single dose theoretical effect summation, that is, have
There is super superposition, can preferably control plant pest occurrence injury；
2, there is good complementarity in plant pest management spectrum between mixture composition active constituent, can expands very well
Big prevention spectrum, synthesis effectively control various plant pest occurrence injuries；
3, mixture composition has good synergistic effect, can reduce pharmaceutical use, reduces use cost and environment is dirty
Dye improves the safety to crop.
Specific implementation mode
Specific embodiments of the present invention are given below, it should be noted that the invention is not limited in implement in detail below
Example, all equivalent transformations made on the basis of the technical solutions of the present application each fall within protection scope of the present invention.
Embodiment 1：60% missible oil
Formula composition is：Active components A is 12%, and active constituent B is 48%, emulsifier castor oil polyoxyethylene ether 6%,
Emulsifier sorbitan ester 4%, solvent xylene complements to 100%.
Preparation method is：All materials are put into batching kettle, stirring and dissolving is to fully transparent, after chemical examination is qualified, transfer
It is filling to storage tank.
Embodiment 2：35% suspending agent
Formula composition is：Active components A is 5%, and active constituent B is 30%, wetting agent fatty alcohol polyoxyethylene ether sulfuric acid
Sodium 5%, dispersant is to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4%, antifreezing agent propylene glycol 5%, thickener aluminium-magnesium silicate
0.2%, water complements to 100%.
Preparation method is：By in active constituent and wetting agent, dispersant, antifreezing agent and water input stirred tank, it is sufficiently stirred
Afterwards, material is pumped into sand mill and is fully ground, after the completion of grinding, is pumped into high-speed shearing machine, after thickener is added, into
Row high speed shear obtains suspending agent after the completion of shearing.
Embodiment 3：75% water dispersible granules
Formula composition is：Active components A is 60%, and active constituent B is 15%, wetting agent sldium lauryl sulfate 5%, dispersion
Agent alkyl phenol polyoxyethylene ether phosphate 6%, disintegrant ammonium sulfate 4%, adhesive polyethylene glycol 0.5%, filler diatomite are mended
Enough to 100%.
Preparation method is：After mixing by all materials, it crushes through airslide disintegrating mill, is uniformly mixed again, then, add
Enter a certain amount of water to mediate this mixture, extruder grain, through dry screening to get to water dispersible granules.
Embodiment 4：10% aqueous emulsion
Formula composition is：Active components A is 5%, and active constituent B is 5%, solvent xylene 8%, solvent cyclohexanone 5%,
Emulsifier styrylphenol polyoxyethylene ether 4%, emulsifier aerosol-OT salt 5%, antifreezing agent glycerine
4%, water complements to 100%.
Preparation method is：After active components A and B are fully dissolved with solvent, input emulsifier forms oil after being sufficiently stirred
Phase；Antifreezing agent is added to the water dissolving, forms water phase；Water phase is slowly added in oil phase, is sheared using high-speed shearing machine, you can
Obtain aqueous emulsion.
Embodiment 5：15% microemulsion
Formula composition is：Active components A is 10%, and active constituent B is 5%, solvent xylene 10%, solvent Solvesso
1504%, emulsifier alkylbenzene sulfonate 6%, emulsifier disecoctylmaleate sodium sulfonate 7%, antifreeze glycol
5%, water complements to 100%.
Preparation method is：After active components A and B are fully dissolved with solvent, puts into emulsifier and antifreezing agent is uniformly mixed,
It is eventually adding deionized water, carries out high speed shear, you can obtains microemulsion.
Embodiment 6：81% wettable powder
Formula composition is：Active components A is 9%, and active constituent B is 72%, wetting agent lauryl sodium sulfate 6%, point
Powder calcium lignosulfonate 5%, filler attapulgite complement to 100%.
Preparation method is：Active constituent and each auxiliary agent are uniformly mixed, puts into mechanical disintegrating machine and just smash, later
It is crushed through airslide disintegrating mill, remixes uniformly, obtain wettable powder.
Embodiment 7：8% granule
Formula composition is：Active components A is 6%, and active constituent B is 2%, wetting agent pull open powder 0.6%, dispersant naphthalene sulphur
Sour sodium formaldehyde condensation product 1.0%, the red B 0.4% of colorant Luo Dan, filler bentonite complement to 100%.
Preparation method is：After mixing by all materials, a certain amount of water is added to mediate this mixture, extruding is made
Grain, through dry screening to get to granule.
Embodiment 8：27% dispersible oil-suspending agent
Formula composition is：Active components A is 24%, and active constituent B is 3%, emulsifier calcium dodecyl benzene sulfonate 6%,
Emulsifier alkaryl phenol polyethenoxy ether phosphate 7%, dispersant polycarboxylate 2%, thickener white carbon 1%, decentralized medium
Corn oil complements to 100%.
Preparation method is：By in active constituent and emulsifier, dispersant and decentralized medium input stirred tank, it is sufficiently stirred
Afterwards, it is pumped into high-speed shearing machine, carries out high speed shear, then pump and be fully sanded into sand mill, be added and increase after sand milling is qualified
It thick dose, stirs evenly up to dispersible oil-suspending agent.
Embodiment 9：21% microcapsule suspending agent
Formula composition is：Active components A is 7%, and active constituent B is 14%, solvent xylene 10%, solvent O-phthalic
Dibutyl phthalate 6%, oiliness capsule skin 1, six methylene phenylene diisocyanates 4% of 6-, aqueous capsule skin propane diamine 3%, emulsifier triphen second
Alkenyl phenol polyethenoxy ether 7%, dispersant sodium methylene bis-naphthalene sulfonate 5%, thickener xanthans 0.2%, decentralized medium water are mended
Enough to 100%.
Preparation method is：After active components A and B are fully dissolved with solvent, oiliness capsule skin is added, is sufficiently stirred to form oil
Phase；It is poured into the water phase for being mixed with emulsifier and dispersant, carries out high speed shear, aqueous capsule skin is then added, stirs evenly,
It then raises temperature to 70 DEG C of heat preservation solidifications 2 hours, microcapsules is made, are eventually adding thickener, stir evenly up to microcapsule suspending agent.
Embodiment 10：56% suspension emulsion
Formula composition is：Active components A is 48%, and active constituent B is 8%, solvent xylene 10%, emulsifier polyalcohol
Fatty acid ester ethylene oxide addition product 6%, wetting agent ethylene oxide sorbitanmonolaureate 5%, dispersant alkyl naphthalene formaldehyde
Condensation product sodium sulfonate 3%, antifreezing agent propylene glycol 5%, thickener aluminium-magnesium silicate 0.3%, water complements to 100%.
Preparation method is：Active components A, wetting agent, dispersant, antifreezing agent and water are put into stirred tank, are sufficiently stirred
Afterwards, material is pumped into sand mill and is fully ground, suspending agent is made；After active constituent B is fully dissolved with solvent with breast
Agent is uniformly mixed, and is then added to it in Manufactured suspending agent under the conditions of high speed shear, and thickener is added, and is carried out high
Speed shearing, suspension emulsion is obtained after the completion of shearing.
Embodiment 11：44% suspension seed-coating agent
Formula composition is：Active components A is 4%, and active constituent B is 40%, wetting agent alkyl phenol polyoxyethylene ether formaldehyde
Condensate sulfate 6%, dispersant EO-PO block polyethers 4%, film forming agent polyvinyl alcohol-polyvinyl acetate copolymer 0.5%,
Antifreezing agent glycerine 5%, thickener xanthans 0.3%, warning coloration rhodamine toner 1.0%, water complements to 100%.
Preparation method is：By active constituent and wetting agent, dispersant, antifreezing agent, warning coloration, film forming agent and water input stirring
In kettle, after being sufficiently stirred, it is pumped into high-speed shearing machine, carries out high speed shear, then pump and be fully sanded into sand mill, be sanded
Thickener is added after qualification, stirs evenly up to suspension seed-coating agent.
Embodiment 12：24% seed treatment suspending agent
Formula composition is：Active components A is 6%, and active constituent B is 18%, wetting agent dialkyl succinylsuccinate sulfonated ester
4%, dispersant styrene maleic anhydride copolymer 5%, antifreezing agent propylene glycol 5%, thickener xanthans 0.2%, warning color acid
Property bright red 1%, water complements to 100%.
Preparation method is：All materials are put into stirred tank, after being sufficiently stirred, are fully ground with sand mill, it is complete
At in rear suction cutter, after thickener is added, high speed shear is carried out, seed treatment suspending agent is obtained after the completion of shearing.
Application effect example：
1, test method
(1) to the bioactivity of mandarin tree red spider
Reference《The 13rd part of NY/T 1154.13-2008 farm-chemical indoor determination test rules insecticide：Leaf dish is sprayed
Method》It carries out.
It is for trying object, choosing indoor raising with mandarin tree red spider (Panonychus citri), physiological status is consistent
Deutonymph tested.
It chooses and grows consistent mandarin tree young sprout blade, make diameter 2cm leaf dish with card punch, one is placed in culture dish
Wet sponge block puts filter paper thereon, and ready deutonymph is inoculated into leaf dish by foliation dish per 2 leaf dish of ware with small writing brush on filter paper
On, each leaf dish connects deutonymph 15.The atomisation pressure of Potter spray towers is adjusted 1.47 × 105The stable state of Pa, will
Clean fog-spray nozzle is cleaned 2 times with acetone, then 2 times wash with distilled water.Then the culture dish for connecting deutonymph is placed in again
Potter spray towers spraying tower chassis is sprayed, and per ware spouting liquid 1mL, is taken out after liquid sedimentation 1min, being transferred to temperature is
It is raised in (25 ± 1) DEG C, RH 80%, the growth cabinet that the photoperiod is L ︰ D=(16 ︰ 8) h.4 repetitions are often handled, are often repeated
30 (1 wares), if blank control is made in the processing without medicament.
Investigation result (death standard after processing 48h：Polypide is touched with writing brush, polypide is stiff), total worm is recorded respectively
Number and death toll.The death rate is calculated by (1) formula, unit is percentage (%), and result of calculation retains 2 significant digits.
In formula：
P1- the death rate, unit are percentage (%)；
K-expression death borer population, unit is head；
N-expression handles total borer population, and unit is head.
(2) to the bioactivity of cucumber root-knot nematode
Reference《NY/T 1833.1-2009 farm-chemical indoor determination test rule nematicide part 1s：Inhibit plant
Pathogenic nematode tests dip method》It carries out.
It is to be collected from field for trying object with cucumber root-knot nematode (Meloidogyne incognita), moves into cucumber root
Portion is cultivated, spare after laying eggs.
The pieces of an egg of picking root-knot nematode wash with water from old complaint, are placed on the wet filter paper of culture dish, are incubated at 20~25 DEG C
Change, obtains age consistent second instar larvae.2min is centrifuged under 1000r/min, abandons supernatant, adds water, then centrifuge, it finally will with water
Nematode is resuspended floating to every milliliter >=100 nematodes, spare.
With pipettor from low concentration to high concentration, prepared liquid 3mL is drawn successively and is added in test tube, is then drawn
The equivalent nematode suspension 3mL prepared is added in test tube, keeps liquid and nematode suspension mixed in equal amounts uniform.It is moved with pipettor
It takes the above-mentioned mixed liquor of certain volume in the aperture of porous biochemical test plate, is capped, for 24 hours in 25 DEG C of constant temperature incubations.Often handle 4
Secondary repetition often repeats leaching worm and is no less than 100, and sets the processing without medicament as blank control.
From taken in each processing 1mL mixed liquors under anatomical lens from nematode death condition, should not per repeated observation nematode number
Less than 100, snoop bus borer population and verge of death borer population are recorded.Judge that nematode death standard is stiff for nematode, with hair needle or
Bamboo silk needle touching is still unable to bending motion.The death rate is calculated by (1) formula.
(3) to the bioactivity of paddy rice rice leaf roller, wild cabbage diamondback moth and cotton boll worm
Reference《The 14th part of NY/T 1154.14-2008 farm-chemical indoor determination test rules insecticide：Leaf dipping method》
It carries out.
With paddy rice rice leaf roller (Cnaphalocrocis medinalis), wild cabbage diamondback moth (Plutella
Xylostella) or cotton boll worm (Helicoverpa armigera) is for trying object, choosing indoor raising, physiological status
3 consistent instar larvaes are tested.
Fresh tender rice leaf, cabbage leaves or cotton leaf are dipped in liquid medicine to be measured (the vertical volume of rice rice
Leaf snout moth's larva is material to be tested with rice leaf, and wild cabbage diamondback moth is material to be tested, cotton boll worm cotton leaf with cabbage leaves
For material to be tested), it takes out after 10s and dries, be placed in the culture dish containing 1% moisturizing filter paper, access test worm, often handle 4 weights
It is multiple, often repeatedly 30, if blank control is made in the processing without medicament.It is (25 ± 1) DEG C, humidity 60% that test worm, which is placed in temperature,
~80%, photoperiod L:D=(16:8) it raises and observes under h condition.Investigation result after processing 48h, records total borer population respectively
And death toll.Death standard is：Polypide is touched with writing brush, polypide is stiff.The death rate is calculated by (1) formula.
(4) to the bioactivity of apple tree small heart-eating peach worm
Bibliography is reported, biological activity determination is carried out with fruit infusion process.The specific method is as follows：
It is for trying object, choosing indoor raising, physiology with apple tree small heart-eating peach worm (Carposina niponensis)
3 instar larvaes of state consistency are tested.
The handsome griggles of gold that acquisition does not spray from field, surface clean it is clean after, cut away half from centre.Use tweezers
It clips half block apple and throughout manages and impregnate 5s in liquid, be placed into after taking-up in small plastic cup (bore 6cm, bottom diameter 4cm, it is high
5.5cm), section is upward.Then test worm is chosen on apple section with writing brush, covers plastic cup cover.4 repetitions are often handled, often
30 are repeated, if blank control is made in the processing without medicament.By test worm be placed in temperature be (25 ± 1) DEG C, humidity be 60%~
80%, photoperiod L:D=(16:8) it raises and observes under h condition.Handle 48h after investigation result, record respectively total borer population and
Death toll.Pest death standard is：Polypide is touched with writing brush, polypide is stiff.The death rate is calculated by (1) formula.
(5) to the bioactivity of Phytophthora infestans germ, gaeumannomyces graminis and fusarium moniliforme
Reference《NY/T 1156.2-2006 farm-chemical indoor determination test rule fungicide part 2s：Inhibit cause of disease true
Bacterium mycelia growth test Plating》It carries out.
With Phytophthora infestans germ (Phytophthora infestans), gaeumannomyces graminis (Gaeumannomyces
Graminis) or fusarium moniliforme (Fusarium moniliforme) is for trying pathogen.
Incidence tissue is acquired from field, laboratory isolates and purifies, is seeded on culture medium and cultivates, and culture to colony diameter reaches
5cm~6cm or so is spare.The oat medium culture of Phytophthora infestans germ, gaeumannomyces graminis and fusarium moniliforme PDA
Medium culture.
Oat medium formula：Oat 50g, agar powder 18g, deionized water 1000mL.
PDA culture medium is laboratory conventional medium, omits its formula herein.
It is spare after the sterilizings such as culture medium, deionized water, scribing line triangular flask, culture dish, pipette tips, card punch, inoculator.
Under aseptic technique, advance thawing is cooled to about 50 DEG C of sterilising medium and is quantitatively adding sterilizing scribing line three
In the bottle of angle, keep culture medium concordant with (60mL) at scribing line, then draw 600 μ L liquids successively from low concentration to high concentration, respectively
It is added in above-mentioned triangular flask, fully shakes up, rear equivalent is poured into 4 culture dishes (Φ 9cm), and it is flat that 5 concentration gradient band medicines are made
Plate.And it sets the processing without medicament and makees blank control.It will cultured pathogen, aseptically use sterilizing on culture medium
Card punch (Φ 5mm) cuts bacteria cake from the same circumference of colony edge, with inoculator by pure culture biscuits involvng inoculation in drug containing tablet center, bacterium
Silk down, covers ware lid, and (for Phytophthora infestans germ in 20 DEG C of cultures, remaining germ is in 25 DEG C of trainings for dark culturing in incubator
It supports).According to mycelia growing state in blank control ware, with calliper colony diameter.Each bacterium colony is hung down using crossing method
It is straight to measure, its average value is taken, the inhibiting rate grown to mycelia is calculated.
The inhibiting rate that each concentration for the treatment of grows mycelia is calculated by formula (2), (3), unit is percentage (%), calculates knot
Fruit retains 2 significant digits.
D=D1-D2…………………………………………(2)
In formula：
D-bacterium colony increases diameter, and unit is millimeter (mm)；
D1- colony diameter, unit are millimeter (mm)；
D2- bacteria cake diameter, unit are millimeter (mm).
In formula：
I-mycelial growth inhibition rate, unit are percentage (%)；
D0- blank control bacterium colony increases diameter, and unit is millimeter (mm)；
Dt- chemicals treatment bacterium colony increases diameter, and unit is millimeter (mm).
(6) to the bioactivity of corn grub
Reference《The 15th part of NYT 1154.15-2009 farm-chemical indoor determination test rules insecticide：Subterranean pest-insect
Dip method》It carries out.
Be to choose indoor raising for trying object with corn grub (Anomala corpulenta), physiological status it is consistent 2
Instar larvae is tested.
Larva is soaked into the liquid 10s to take out, extra liquid is sucked with filter paper, test worm is transferred to equipped with new with tender
In fresh corn seedling teat glass, nozzle is covered with moist black cloth, is placed in 25 DEG C ± 1 DEG C, the perseverance of relative humidity 60%~80%
It is raised in warm insectary.4 repetitions are often handled, often repeatedly 30, and the processing without medicament is set as blank control.After processing
72h investigation result (death standards：Polypide obviously shrinks or needle thorn is unable to normal creepage of gastrointestinal functions), total borer population and death toll are recorded respectively.
The death rate is calculated by (1) formula.
(7) to the bioactivity of Kidney bean Americal rice leaf miner
Reference《The 6th part of NY/T 1154.6-2006 farm-chemical indoor determination test rules insecticide：Insecticidal activity is tried
Test dip method》It carries out.
It is for trying object, choosing indoor raising, physiological status one with Kidney bean Americal rice leaf miner (Liriomyza sativae)
2 instar larvaes caused are tested.
The Phaseolus Leaves of 2 instar larvae containing Kidney bean Americal rice leaf miner are dipped in liquid medicine to be measured, takes out and dries after 5s, set
In the culture dish containing 1% moisturizing filter paper, 4 repetitions are often handled, often repeatedly 30, if blank pair is made in the processing without medicament
According to.Test worm is placed in temperature is (25~27) DEG C, humidity is 60%~70%, photoperiod L:D=(14:10) it is raised under h condition
It supports and observes.(larva of energy normal creepage of gastrointestinal functions is calculated as worm living, polypide blackening or needle thorn to investigation result under anatomical lens after processing 72h
Nonresponder is calculated as dead worm afterwards), total borer population and death toll are recorded respectively.The death rate is calculated by (1) formula.
(8) compositions contemplated activity judges
Compositions contemplated activity, which is used for reference in the transnational agricultural chemicals enterprise formulation patents such as Bayer, Syngenta, Tao Shi, judges composition
The method (COLBY methods) of expection activity：COLBY, S.R.：“Calculating Synergistic and Antagonistic
Responses of Herbicide Combinations ", Weeds 15, p.20~22,1967 carry out.
Two-spot compositions contemplated activity is calculated by (4) formula：
In formula：
Death rate when 1 dosage of X-medicament is P or inhibiting rate；
Death rate when 2 dosage of Y-medicament is Q or inhibiting rate；
Actual or inhibiting rate after E-medicament 1 is mixed according to the above ratio with medicament 2, the i.e. practical work of composition
Property；
E0The theoretical death rate or inhibiting rate that 1 dosage of-medicament is 2 dosage of P+ medicaments when being Q, i.e. the expected of composition are lived
Property.
As E ＞ E0When, i.e., if the substantial activity of Mixed Pharmacy is more than calculated expection activity, the composition just has
There is super superposition, that is, acts synergistically.
Ternary composition expection activity is calculated by (5) formula：
In formula：
Death rate when 1 dosage of X-medicament is P or inhibiting rate；
Death rate when 2 dosage of Y-medicament is Q or inhibiting rate；
Death rate when 3 dosage of Z-medicament is R or inhibiting rate；
E0The theoretical death rate or inhibiting rate that 1 dosage of-medicament is 2 dosage of P+ medicaments when be 3 dosage of Q+ medicaments being R, i.e. group
Close the expection activity of object；
E-medicament 1,2 and 3 presses the actual or inhibiting rate when different ratio mixture, the i.e. substantial activity of composition；
As E ＞ E0When, i.e., if the substantial activity of Mixed Pharmacy is more than calculated expection activity, the composition just has
There is super superposition, that is, acts synergistically.
2, test result
Test result refers to table 1~11, it is seen then that active components A (Rynaxypyr) be selected from active constituent B (fourth fluorine
Mite ester, fluorine thiophene worm sulfone, dichlobentiazox, 1,3- dichloropropylene, pyrazine ethiprole, sad mantoquita, nitrile pyrrole mite ester, silicon thiophene
Bacterium amine, pyridine ethiprole, 2-cyano-3-amino-3-phenylancryic acetate) medicament mixture after, substantial activity is all higher than expection activity, illustrates Rynaxypyr
There is synergistic effect with the medicament mixture in active constituent B.
1 Rynaxypyr of table is with cyflumetofen mixture to the synergy effect of mandarin tree red spider
2 Rynaxypyr of table is with fluorine thiophene worm sulfone mixture to the synergy effect of cucumber root-knot nematode
3 Rynaxypyr of table is with dichlobentiazox mixtures to the synergy effect of paddy rice rice leaf roller
4 Rynaxypyr of table is with 1,3- dichloropropylenes mixture to the synergy effect of wild cabbage diamondback moth
5 Rynaxypyr of table is with pyrazine ethiprole mixture to the synergy effect of apple tree small heart-eating peach worm
6 Rynaxypyr of table is with sad mantoquita mixture to the synergy effect of Phytophthora infestans germ
7 Rynaxypyr of table is with nitrile pyrrole mite ester mixture to the synergy effect of corn grub
8 Rynaxypyr of table is with Silthiopham mixture to the synergy effect of gaeumannomyces graminis
9 Rynaxypyr of table, pyridine ethiprole are with 2-cyano-3-amino-3-phenylancryic acetate mixture to the synergy effect of fusarium moniliforme
10 Rynaxypyr of table, cyflumetofen are with sad mantoquita mixture to the synergy effect of Kidney bean Americal rice leaf miner
11 Rynaxypyr of table, pyrazine ethiprole imitate the synergy of cotton boll worm with 1,3- dichloropropylenes mixture
It answers
Claims (5)
1. a kind of composition, which is characterized in that including active components A and B.
2. composition as described in claim 1, which is characterized in that the active components A is Rynaxypyr.
3. composition as described in claim 1, which is characterized in that the active constituent B be nitrile pyrrole mite ester, cyflumetofen,
Pyrazine ethiprole, pyridine ethiprole, fluorine thiophene worm sulfone, 2-cyano-3-amino-3-phenylancryic acetate, Silthiopham, 1,3- dichloropropylenes, sad mantoquita,
One or more kinds of combinations in dichlobentiazox.
4. composition as claimed in claim 1,2 or 3, which is characterized in that further include pesticide system other than active components A and B
The auxiliary agent that can be used in agent processing.
5. the composition as described in claim 1,2,3 or 4, which is characterized in that be applied to prevention plant pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810246117.6A CN108402050A (en) | 2018-03-23 | 2018-03-23 | The composition of containing chlorantraniliprole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810246117.6A CN108402050A (en) | 2018-03-23 | 2018-03-23 | The composition of containing chlorantraniliprole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108402050A true CN108402050A (en) | 2018-08-17 |
Family
ID=63133297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810246117.6A Withdrawn CN108402050A (en) | 2018-03-23 | 2018-03-23 | The composition of containing chlorantraniliprole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108402050A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221147A (en) * | 2018-09-25 | 2019-01-18 | 江苏省农药研究所股份有限公司 | A kind of ternary composition of 2-cyano-3-amino-3-phenylancryic acetate-containing, seed treatment suspending agent and its application |
| WO2021064731A1 (en) * | 2019-10-03 | 2021-04-08 | Adama Makhteshim Ltd. | Pesticidal mixtures |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651438A (en) * | 2012-09-18 | 2014-03-26 | 青岛星牌作物科学有限公司 | Suspending agent containing chlorantraniliprole and fipronil and preparation method thereof |
-
2018
- 2018-03-23 CN CN201810246117.6A patent/CN108402050A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651438A (en) * | 2012-09-18 | 2014-03-26 | 青岛星牌作物科学有限公司 | Suspending agent containing chlorantraniliprole and fipronil and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨柳等: "25%氯虫苯甲酰胺悬浮剂对稻纵卷叶螟防治试验", 《广东农业科学》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221147A (en) * | 2018-09-25 | 2019-01-18 | 江苏省农药研究所股份有限公司 | A kind of ternary composition of 2-cyano-3-amino-3-phenylancryic acetate-containing, seed treatment suspending agent and its application |
| WO2021064731A1 (en) * | 2019-10-03 | 2021-04-08 | Adama Makhteshim Ltd. | Pesticidal mixtures |
| CN114745957A (en) * | 2019-10-03 | 2022-07-12 | 阿达玛马克西姆有限公司 | Pesticidal mixtures |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107087620A (en) | Composition containing isotianil and fluorine azoles bacterium acyl azanol | |
| CN108684685A (en) | A kind of composition of fluorine-containing thiophene worm sulfone | |
| WO2022034611A1 (en) | Synergistic pesticidal composition of insecticides and fungicides | |
| CN106942236A (en) | The composition of fluorine-containing azoles bacterium aniline and Dichlobentiazox | |
| CN108308193A (en) | The composition of containing chlorantraniliprole and carboxin | |
| CN107593723A (en) | A kind of composition containing fluxametamide | |
| CN108402043A (en) | A kind of bactericidal composition of the metsulfovax containing isopropyl | |
| CN108402050A (en) | The composition of containing chlorantraniliprole | |
| CN107047572A (en) | Composition containing isotianil and smart furalaxyl | |
| CN107372520A (en) | The bactericidal composition of containing fluopyram | |
| CN107027773A (en) | Composition containing isotianil and Dichlobentiazox | |
| CN107372532A (en) | The bactericidal composition of the urethane of pyrrole containing tetrazolium | |
| CN107535510A (en) | A kind of composition containing fluralaner | |
| CN108541710A (en) | The composition of containing chlorantraniliprole and amisulbrom | |
| CN107027787A (en) | The composition of fluorine-containing azoles bacterium aniline and Tolprocarb | |
| CN107646852A (en) | Composition containing fluquinconazole and aminopyrifen | |
| CN110384109A (en) | A kind of bactericidal composition | |
| CN107711849A (en) | Composition containing fluquinconazole and tebufloquin | |
| CN108541714A (en) | The composition of containing chlorantraniliprole and Silthiopham | |
| CN110384104A (en) | A kind of bactericidal composition | |
| CN107027761A (en) | A kind of Pesticidal combination of the ether of pyrrole containing fluoroform | |
| CN107027767A (en) | The bactericidal composition of fluorine-containing azoles bacterium aniline | |
| CN106889089A (en) | The composition of fluorine-containing azoles ring bacterium amine and Tolprocarb | |
| CN107668041A (en) | A kind of bactericidal composition containing Fluquinconazole | |
| CN116941630A (en) | Insecticidal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180817 |