CN108308193A - The composition of containing chlorantraniliprole and carboxin - Google Patents
The composition of containing chlorantraniliprole and carboxin Download PDFInfo
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- CN108308193A CN108308193A CN201810357606.9A CN201810357606A CN108308193A CN 108308193 A CN108308193 A CN 108308193A CN 201810357606 A CN201810357606 A CN 201810357606A CN 108308193 A CN108308193 A CN 108308193A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Abstract
The present invention provides the cooperative compositions of a kind of containing chlorantraniliprole and carboxin, it is characterized in that other than the Rynaxypyr of component A and carboxin, further include at least one other fungicide or insecticide as B component medicament, and the auxiliary agent that can be used in Pesticide formulation, conventional pesticidal preparations are made, and applied to prevention plant pest.
Description
Technical field
The invention belongs to pesticides application technical fields, are related to a kind of composition pesticide, specifically a kind of benzene of worm containing chlorine
The composition of formamide and carboxin is applied to prevention plant pest.
Background technology
In agricultural production process, plant pest occur it is serious, endanger the positions such as plant roots, stem, leaf and fruit,
The organs of multiplication such as seed, stem tuber, make crop yield fall sharply, and quality decline is serious.When pest and disease damage occurs serious, cause crop exhausted
It receives.Therefore, it is prevention plant disease pest that plant pest has important prevention meaning, fungicide or insecticide in produce reality
Evil method the most economic, quick and effective.
Also, in actual production, plant pest often occurs simultaneously, such as kind biography, soil-borne disease and subterranean pest-insect, leaf
Face disease and leaf insects etc. usually occur simultaneously, single use fungicide or insecticide, and it is real not can be well solved production
Plant pest in border endangers problem.By fungicide and insecticide mixture, can remedy such and insufficient, the two has complementary advantages, can
Expand prevention spectrum, comprehensive effective disease and pest control harm becomes well received application form in production practice.Especially have
There are the fungicide and insecticide of synergistic effect, interact between each active principle, makes combined effect better than exclusive use effect
Theoretical summation, thus can play a multiplier effect in actual use, more favored by user.
Rynaxypyr (chlorantraniliprole) is a kind of insecticide of overseas enterprise's exploitation, belongs to ryania
Receptor activators.Can be used for preventing fruit tree, vegetables, cotton, sugarcane, rice, wheat, the Lepidoptera in the various crops such as corn,
The various pests such as Diptera, coleoptera, Isoptera.CAS accession number is 500008-45-7.Its structural formula is as follows：
Carboxin (carboxin) is the broad-spectrum germicide of overseas enterprise's exploitation, is had to various crop disease good anti-
Effect.
Benfuracard micro (benfuracarb), carbosulfan (carbosulfan), chlopyrifos (chlorpyrifos),
Phoxim (phoxim), betacyfluthrin (beta-cyfluthrin), gamma cyhalothrin (lambda-
Cyhalothrin), kappa-tefluthrin, Biphenthrin (bifenthrin), clothianidin (clothianidin), furan worm
Amine (dinotefuran), imidacloprid (imidacloprid), Diacloden (thiamethoxam), avermectin
(abamectin), emamectin-benzoate (emamectin benzoate), ethiprole (ethiprole), efficiently
Olefin conversion (diniconazole-M) is the insecticide or fungicide of a variety of broad spectrum activities.Above-mentioned medicament is to multiple diseases or insect pest table
Reveal excellent preventive effect.Above compound may include the various existence forms agriculturally used, such as salt, ester, isomers derivative.
The present invention pass through a large amount of formulation screening test the study found that when Rynaxypyr and carboxin composition with
Benfuracard micro, carbosulfan, chlopyrifos, phoxim, betacyfluthrin, gamma cyhalothrin, kappa-
Tefluthrin, Biphenthrin, clothianidin, dinotefuran, imidacloprid, Diacloden, avermectin, emamectin benzoate benzoic acid
When one or more kinds of medicaments in salt, ethiprole, efficient olefin conversion arbitrarily combine, surprising pesticide-germicide is shown
Effect shows good synergistic effect, actual effect is substantially better than the theoretical summation of exclusive use, has in production non-
Often it is widely applied foreground.
Invention content
The present invention relates to cooperative compositions, including active components A and B, the active components A be Rynaxypyr and
Carboxin, the active constituent B are Benfuracard micro, carbosulfan, chlopyrifos, phoxim, betacyfluthrin, height
Imitate lambda-cyhalothrin, kappa-tefluthrin, Biphenthrin, clothianidin, dinotefuran, imidacloprid, Diacloden, avermectin,
One or more kinds of combinations in emamectin-benzoate, ethiprole, efficient olefin conversion.In addition, further including agriculture
The auxiliary agent that can be used in medicine preparation processing.
The composition can be used to prevent the plant pest in various useful crops with particularly good effect, described to have
Include but not limited to conventional breeding crop, genetically modified crops, asexually propagated crop and asexual propagation material, domesticating and cultivating with crop
Wild plant etc., especially suitable for prevention cotton, peanut, wheat, barley, corn, rice, soybean, potato, rape, grass
Pest and disease damage on the crops such as level ground, vegetables, fruit tree.
The specific example that can be mentioned that is the representative plant pest that composition for preventing and controlling of the invention can be used in some, the reality
Example is not limited to specified genus kind.It should be noted that the invention is not limited in examples in detail below, can be prolonged with same way
Other plant pests are reached, bracket indicates its cause of disease Latin name：
The crops such as beans, vegetables, oil crops, beet, sunflower, peanut, corn, rice and cotton samping off and vertical withered
Sick (Rhizoctonia solani), watermelon and cotton wilt, root rot (Fusarium oxysporum), Roots of Peanut
Maize ear rot (Fusarium solani), wild cabbage striped flea-beetle (Phyllotrata striolata), soybean, peanut are chrysomelid
(Paraluperodes suturalis nigrobilineatus), colorado potato bug (Leptinotarsa
Decemlineata), rape striped flea-beetle (Phyllotreta Stephens), vegetables aulacophora femoralis (Aulacophora
Indica), peanut cutworm (Agrotis segetum), peanut and potato grub (Holotrichia parallela),
Bakanae disease of rice (Fusarium moniliforme), false smut (Ustilaginoidea oryzae), rice blast
(Magnaporthe grisea), kernel smut (Tilletia barclayana), flax leaf spot (Cochliobolus
Miyabeanus), rice hoppers (Nilaparvata lugens), rice water weevil (Lissorhoptrus
Oryzophilus), rice thrips (Stenchaetothrips biformis), pachydiplosis oryzae (Orseolio oryzae), wheat
Smut (Ustilago tritici), bunt (Tilletia caries), flag smut (Urocystis
Occulta mould leaf blight (Monographella nivalis), septoria musiva leaf blight (Septoria tritici), white), is avenged
Powder disease (Blumeria graminis), full rot (Gaeumannomyces graminis), leaf rust (Puccinia
Recondita), stripe rust (P.striiformis), black rust (P.graminis), banded sclerotial blight (Rhizoctonia
Cerealis), head blight (Fusarium graminearum), root rot (Bipolaris sorokiniana), barley dust-brand
Sick (Ustilago hordei), stripe disease (Pyrenophora graminea), moire disease (Rhynchosporium
Secalis), net blotch (Pyrenophora teres), black loose smut of oat (Ustilago avenae), maize head smut
(Sphacelotheca reiliana), smut (Ustilago maydis), base rot disease (Fusarium
Graminearum), helminthosporium maydis (Bipolaris maydis), leaf blight (Exserohilum turcicum), onion smut
(Urocystis colchici), corn snout moth's larva (Ostrinia furnacalis), corn and wheat grub (Anomala
Corpulenta), corn black cutworm (Agrotis ypsilon), wireworm (Agriotes fuscicollis), small wheat aphid
Worm (Sitobion avenae), wheat midge (Sitodiplosis mosellana), yellow top borer (Chilotraca
Inluscatellus), yellow snout moth's larva (Aryroploce schistaceana), sugarcane tortoise (Alissonotum impressicolle),
Tomato, capsicum, eggplant and cucumber Bemisia tabaci (Bemisia tabaci), trialeurodes vaporariorum (Trialeurodes vaporariorum),
Yellow thrips (Thrips flavus), cotton thrips (Frankliniella intonsa), green plant bug (Lygocoris
Lucorum), tomato, eggplant, cucumber, celery, tobacco root-knot (Meloidogyne incognita), pepper root tie lines
Parasitosis (Meloidogyne hapla), groundnut root knot nematode disease (Meloidogyne arenaria), soybean cyst nematode Heterodera glycines
(Heterodera glycines), javanese root knot nematode (Meloidogyne javanica), soybean Cobb root
(Pratylenchus penetrans), lawn needle pierce nematode (Belonolaimus longicaudatus), corn lesion line
Worm (Pratylenchus zeae), globodera rostochiensis (Globodera rostochiensis), tomato kidney worm
(Rotylenchulus reniform), Yellow Rice Borer (Tryporyza incertulas), striped rice borer (Chilo
Suppressalis), rice leaf roller (Cnaphalocrocis medinalis), cotton cutworm (Agrotis
Segetum), bollworm (Helicoverpa armigera), pink bollworm (Pectinophora gossypiella), the grey wing in sea
Noctuid (Spodoptera littoralis), prodenia litura (Prodenia litura), black scurf of potato and rice banded sclerotial blight
Sick (Rhizoctonia solani), peanut sclerotium rolfsii (Sclerotium rolfsii), leaf spot (Cercospora
Arachidicola), crown rot (Aspergillus niger), cotton verticillium wilt (Verticillium dahliae), soybean
Rust (Phakopsora pachyrhizi), purple spot (Cercospora kikuchii), watermelon grafting
(Mycosphaerella melonis), Alternaria alternate (Alternaria alternata), scab of apple (Venturia
Inaequalis), powdery mildew (Podosphaera leucotricha), spot defoliation (Alternaria mali), rot
Sick (Valsa mali), ring spot (Physalospora piricola), brown spot (Marssonina coronaria), pears
Scab (Venturia nashicola), Cabbage Leaf Spot (Alternaria brassicae), tomato, capsicum and potato
Early blight (Alternaria solani), cucumber anthracnose (Colletotrichum orbiculare), citrus and capsicum charcoal
Subcutaneous ulcer disease (Colletotrichum glecosporioides), strawberry, grape and apple anthracnose (Glomerella
Cingulata), banana anthracnose (Colletotrichum musae), sigatoka (Mycosphaerella
Fijiensis), cucurbitaceae vegetable (cucumber, cucurbita pepo, pumpkin) powdery mildew (Sphaerotheca fuliginea), strawberry is white
Powder disease (Sphaerotheca aphanis), grapevine anthracnose (Sphaceloma ampelinum), powdery mildew (Erysiphe
Necator), white rot (Coniothyrium diptodictta), citrus scab (Sphaceloma fawcettii), Huang
Imperial disease (Liberobacter asiaticum), penicilliosis (Penicillium italicum), peach brown rot (Monilinia
Fructicola), sweet cherry brown rot (Monilinia laxa), rape, sclerotium blight of sunflower (Sclerotinia
Sclerotiorum), lawn coin pinta (Sclerotinia homoeocarpa), rape balck shank (Phoma lingam), fruit
The crops such as tree, vegetables gray mold (Botrytis cinerea), mango blossom-end rot (Phomopsis mangiferae), potato
Silver-colored maize ear rot (Helminthosporium solani), ornamental flower black spot (Septoria fhrysanth), diseases and insect pests of edible mushroom
(such as brown rot Mycogone perniciosa, brown spot Verticillium fungicola, green mold Trichoderma
Viride, Neurospora Neurospora crassa etc.), peach gummosis (Botryosphaeria ribis), Leaf Spot Caused by Corynespora cassiicola on Cucumber
(Corynespora cassiicola), beet cercospora leaf spot (Cercospora beticola), brassica vegetable (such as wild cabbage) are small
Diamond-back moth (Plutella xylostella), prodenia litura (Prodenia litura), beet armyworm (Laphygma
Exigua), apple tree manchurian fruit (Grapholitha inopinata), small heart-eating peach worm (Carposina
Niponensis), steinernema (Adoxophyes orana), leaf roller (Pandemis heparana), moth-eaten moth (Cydia
Pomonella), citrus fruit fly (Bactrocera dorsalis), the big trypetid of tangerine (Bactrocera minax), Mediterranean are real
Fly (Ceratitis capitata), cherry fruit fly (Rhagoletis indifferens), phyllocnistis citrella stainton
(Phyllocnistis citrella Stainton), watermelon bollworm (Heliothis armigera), eating-core bean worm
(Leguminivora glycinivorella), bean-pod borer (Etiella zinckenella), tea geometrid (Ectropis
Oblique), tobacco oriental tobacco budworm (Helicoverpa assulta), grassland grasshopper (Locusta migratoria), rice locust
Worm (Oxya chinensis), loxostege sticticalis (Loxostege sticticalis), forest fall webworms (Hyphantria
Cunea), gypsymoth (Lymantria dispar), pear tree Grapholita spp (Grapholitha molesta), Schizaphis spp
(Schizaphis piricola), wood louse (Psylla chinensis), cotton aphid (Aphis gosypii), Btassica vegetable
Dish (such as wild cabbage) aphid (Brevicoryne brassicae), apple tree woolly aphid (Eriosoma lanigerum), mandarin tree aphid
Worm (Toxoptera citricidus), tea tree tea lesser leafhopper (Empoasca flavescens), rice-leaf hopper
(Nephotettix bipunctatus), forest spot clothing plant hopper (Lycorma delicatula), tomato and potato wood louse
(Bactericera cockerelli), mandarin tree wood louse (Diaphorina citri), scale insect (such as arrowhead scales Unaspis
Yanonensis, ceroplastes rubens Ceroplastes rubens etc.), red spider (Panonychus citri), apple tree red spider：
Panonychus citri (Panonychus Ulmi), tetranychus viennensis (Tetranychus viennensis), Tetranychus urticae (Tetranychus
Urticae), ponderous borer (Monochamus alternatus), mulberry borer (Apriona germari), leek bradysia odoriphaga
(Bradysia odoriphaga), edible fungi maggot (Lycoriella pleuroti), Liriomyza brponiae (Tuta
Absoluta), Americal rice leaf miner (Liriomyza sativae) etc..
In order to solve the above-mentioned technical problem, the present invention is realised by adopting the following technical scheme：
Between medicament in present composition component A, between A and B can with arbitrary proportion mixture, usually a kind of activity at
Content is divided to be higher than rest activity ingredient, preferably mixing ratio is 100：1 to 1：100 or 50：1 to 1：50.
The present composition can be by mixing active constituent with the auxiliary agent that can be used in Pesticide formulation, with known
Method is prepared as conventional preparation, such as missible oil, suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wettable powder, particle
Agent, dispersible oil-suspending agent, microcapsule suspending agent, suspension emulsion, suspension seed-coating agent, seed treatment suspending agent, seed treatment are dispersible
Pulvis, seed treatment dry powder doses etc..The active constituent of 0.1~95% weight, preferably 0.5~90% weight are typically contained in preparation
Active constituent.
The auxiliary agent that can be used in Pesticide formulation includes but not limited to：Water, solvent, filler, various surfactants
(emulsifier, dispersant, wetting agent etc.), adhesive, colorant, antifreezing agent, thickener, suspending agent, disintegrant, disappear at film forming agent
Infusion, bleeding agent, warning coloration, synergist, stabilizer, wall capsule material, pH adjusting agent, preservative etc..Also, suitably, in order to
It improves to specific crop tolerance, safener can be properly added；It, can be in mixture group or sometimes for crop growth is promoted
It closes and adds conventional agriculture fertilizer in object, medicament-fertilizer mixture is made.These auxiliary agents be all commonly use in pesticidal preparations or allow to use at
Point, it is not particularly limited, one or more auxiliary agent may be selected and constitute, specific ingredient and dosage pass through letter according to recipe requirements
Single experiment determines.
The production technology of the various application forms of composition belongs to existing known technology, and details are not described herein.
The present composition can use in a variety of ways, be such as watered spraying in a usual manner and use, or directly spread fertilizer over the fields or ditch
Apply, or mix pesticide-clay mixture and spread fertilizer over the fields or seed treatment etc., when plant seeding, before emergence, vegetative growth phase and reproductive stage after emergence
It can be used.Dosage can change in wider range, and depending on the situation of soil, application method, crop, to be prevented
Plant pest type and seedling age size, weather conditions at that time and other factors.The present composition usually with 0.001~
The dosage of 1.0kg mixture of active principles/hectare is applied, or is applied with the dosage of 1~1000mg mixture of active principles/kg
With, or with the dosage application of 0.001~1.0kg mixture of active principles/100kg seeds；It is further preferable that with 0.01~
The dosage of 0.5kg mixture of active principles/hectare is applied, and is applied with the dosage of 10~500mg mixture of active principles/kg, or
Person is applied with the dosage of 0.01~0.5kg mixture of active principles/100kg seeds.
Compared with prior art, the present invention having the following technical effect that：
1, there is mixture composition good synergistic effect, application effect to be substantially better than single dose theoretical effect summation, that is, have
There is super superposition, can preferably control plant pest occurrence injury；
2, there is good complementarity in plant pest management spectrum between mixture composition active constituent, can expands very well
Big prevention spectrum, synthesis effectively control various plant pest occurrence injuries；
3, mixture composition has good synergistic effect, can reduce pharmaceutical use, reduces use cost and environment is dirty
Dye improves the safety to crop.
Specific implementation mode
Specific embodiments of the present invention are given below, it should be noted that the invention is not limited in implement in detail below
Example, all equivalent transformations made on the basis of the technical solutions of the present application each fall within protection scope of the present invention.
Embodiment 1：64% missible oil
Formula composition is：Active components A is 8%, and active constituent B is 56%, emulsifier phenethyl phenol polyethenoxy ether
4%, emulsifier polyoxyethylene sorbitan fatty acid ketone 5%, solvent xylene complements to 100%.
Preparation method is：All materials are put into batching kettle, stirring and dissolving is to fully transparent, after chemical examination is qualified, transfer
It is filling to storage tank.
Embodiment 2：30% suspending agent
Formula composition is：Active components A is 25%, and active constituent B is 5%, wetting agent sldium lauryl sulfate 5%, dispersion
Agent alkyl phenol polyoxyethylene ether phosphate 3%, antifreezing agent propylene glycol 5%, thickener xanthans 0.2%, water complements to 100%.
Preparation method is：By in active constituent and wetting agent, dispersant, antifreezing agent and water input stirred tank, it is sufficiently stirred
Afterwards, material is pumped into sand mill and is fully ground, after the completion of grinding, is pumped into high-speed shearing machine, after thickener is added, into
Row high speed shear obtains suspending agent after the completion of shearing.
Embodiment 3：80% water dispersible granules
Formula composition is：Active components A is 16%, and active constituent B is 64%, wetting agent sulfosuccinic acid monooctyl ester sodium salt
6%, dispersant is to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 4%, disintegrant sodium sulphate 5%, adhesive polyvinyl alcohol 0.5%,
Filler kaolin complements to 100%.
Preparation method is：After mixing by all materials, it crushes through airslide disintegrating mill, is uniformly mixed again, then, add
Enter a certain amount of water to mediate this mixture, extruder grain, through dry screening to get to water dispersible granules.
Embodiment 4：24% aqueous emulsion
Formula composition is：Active components A is 4%, and active constituent B is 20%, solvent xylene 10%, solvent cyclohexanone
6%, emulsifier sodium lauryl sulfate 5%, emulsifier alkylbenzene sulfonate 3%, antifreeze glycol 5%, water complements to
100%.
Preparation method is：After active components A and B are fully dissolved with solvent, input emulsifier forms oil after being sufficiently stirred
Phase；Antifreezing agent is added to the water dissolving, forms water phase；Water phase is slowly added in oil phase, is sheared using high-speed shearing machine, you can
Obtain aqueous emulsion.
Embodiment 5：12% microemulsion
Formula composition is：Active components A is 6%, and active constituent B is 6%, solvent xylene 9%, solvent Solvesso
2005%, emulsifier fatty alcohol polyoxyethylene ether 8%, emulsifier aerosol-OT salt 7%, antifreezing agent glycerine
4%, water complements to 100%.
Preparation method is：After active components A and B are fully dissolved with solvent, puts into emulsifier and antifreezing agent is uniformly mixed,
It is eventually adding deionized water, carries out high speed shear, you can obtains microemulsion.
Embodiment 6：70% wettable powder
Formula composition is：Active components A is 63%, and active constituent B is 7%, wetting agent calcium dodecyl benzene sulfonate 6%,
Dispersant APES formaldehyde condensation product sulfonate 4%, filler diatomite complements to 100%.
Preparation method is：Active constituent and each auxiliary agent are uniformly mixed, puts into mechanical disintegrating machine and just smash, later
It is crushed through airslide disintegrating mill, remixes uniformly, obtain wettable powder.
Embodiment 7：8% granule
Formula composition is：Active components A is 2%, and active constituent B is 6%, wetting agent lauryl sodium sulfate 0.8%, point
Powder alkyl naphthalene formaldehyde condensation product sodium sulfonate 0.9%, the red B 0.4% of Luo Dan, filler bentonite complement to 100%.
Preparation method is：After mixing by all materials, a certain amount of water is added to mediate this mixture, extruding is made
Grain, through dry screening to get to granule.
Embodiment 8：50% dispersible oil-suspending agent
Formula composition is：Active components A is 5%, and active constituent B is 45%, emulsifier castor oil polyoxyethylene ether 6%,
Emulsifier disecoctylmaleate sodium sulfonate 7%, three phenethyl phenol polyoxyethylene ether phosphate 4% of dispersant, thickener
White carbon 2%, decentralized medium methyl oleate complement to 100%.
Preparation method is：By in active constituent and emulsifier, dispersant and decentralized medium input stirred tank, it is sufficiently stirred
Afterwards, it is pumped into high-speed shearing machine, carries out high speed shear, then pump and be fully sanded into sand mill, be added and increase after sand milling is qualified
It thick dose, stirs evenly up to dispersible oil-suspending agent.
Embodiment 9：32% microcapsule suspending agent
Formula composition is：Active components A is 28%, and active constituent B is 4%, solvent xylene 10%, solvent O-phthalic
Dibutyl phthalate 8%, oiliness capsule skin 1, six methylene phenylene diisocyanates 5% of 6-, aqueous capsule skin hexamethylene diamine 3%, emulsifier polyalcohol
Fatty acid ester ethylene oxide addition product 9%, dispersant naphthalenesulfonic acid-formaldehyde condensate 6%, thickener aluminium-magnesium silicate 0.3%, point
Dispersion media water complements to 100%.
Preparation method is：After active components A and B are fully dissolved with solvent, oiliness capsule skin is added, is sufficiently stirred to form oil
Phase；It is poured into the water phase for being mixed with emulsifier and dispersant, carries out high speed shear, aqueous capsule skin is then added, stirs evenly,
It then raises temperature to 70 DEG C of heat preservation solidifications 2 hours, microcapsules is made, are eventually adding thickener, stir evenly up to microcapsule suspending agent.
Embodiment 10：45% suspension emulsion
Formula composition is：Active components A is 36%, and active constituent B is 9%, solvent xylene 10%, solvent Solvesso
1003%, emulsifier APES formaldehyde condensation product 7%, wetting agent sodium sulfate of polyethenoxy ether of fatty alcohol 3%, point
Powder fatty alcohol ethylene oxide adduct sulfoacid calcium 5%, antifreeze glycol 5%, thickener aluminium-magnesium silicate 0.3%, water is supplied
To 100%.
Preparation method is：Active components A, wetting agent, dispersant, antifreezing agent and water are put into stirred tank, are sufficiently stirred
Afterwards, material is pumped into sand mill and is fully ground, suspending agent is made；After active constituent B is fully dissolved with solvent with breast
Agent is uniformly mixed, and is then added to it in Manufactured suspending agent under the conditions of high speed shear, and thickener is added, and is carried out high
Speed shearing, suspension emulsion is obtained after the completion of shearing.
Embodiment 11：27% suspension seed-coating agent
Formula composition is：Active components A is 9%, and active constituent B is 18%, wetting agent alcohol ethoxylate 6%,
Dispersant EO-PO block polyethers 4%, film forming agent polyvinyl alcohol-polyvinyl acetate copolymer 0.5%, antifreezing agent propylene glycol 5%,
Thickener xanthans 0.3%, the aqueous rhodo 0.9% of warning coloration, water complements to 100%.
Preparation method is：By active constituent and wetting agent, dispersant, antifreezing agent, warning coloration, film forming agent and water input stirring
In kettle, after being sufficiently stirred, it is pumped into high-speed shearing machine, carries out high speed shear, then pump and be fully sanded into sand mill, be sanded
Thickener is added after qualification, stirs evenly up to suspension seed-coating agent.
Embodiment 12：16% seed treatment suspending agent
Formula composition is：Active components A is 12%, and active constituent B is 4%, wetting agent alkyl phenol polyoxyethylene ether formaldehyde
Condensate sulfate 5%, dispersant styrene maleic anhydride copolymer 4%, antifreeze glycol 4%, thickener xanthans
0.2%, warning coloration rhodamine toner 0.7%, water complements to 100%.
Preparation method is：All materials are put into stirred tank, after being sufficiently stirred, are fully ground with sand mill, it is complete
At in rear suction cutter, after thickener is added, high speed shear is carried out, seed treatment suspending agent is obtained after the completion of shearing.
Application effect example：
1, test method
(1) to fusarium graminearum, rice wilt pathogens, peanut root rot bacterium and gaeumannomyces graminis bioactivity
Reference《NYT 1156.2-2006 farm-chemical indoor determination test rule fungicide part 2s：Inhibit cause of disease true
Bacterium mycelia growth test Plating》It carries out.
With fusarium graminearum (Fusarium graminearum), rice wilt pathogens (Rhizoctonia
Solani), peanut root rot bacterium (Fusarium solani) or gaeumannomyces graminis (Gaeumannomyces graminis)
For for trying pathogen.
Incidence tissue is acquired from field, laboratory isolates and purifies, is seeded in PDA culture medium and cultivates, and culture is straight to bacterium colony
Diameter is spare up to 5cm~6cm or so.
It is spare after the sterilizings such as PDA culture medium, deionized water, scribing line triangular flask, culture dish, pipette tips, card punch, inoculator.
Under aseptic technique, advance thawing is cooled to about 50 DEG C of sterilising medium and is quantitatively adding sterilizing scribing line three
In the bottle of angle, keep culture medium concordant with (60mL) at scribing line, then draw 600 μ L liquids successively from low concentration to high concentration, respectively
It is added in above-mentioned triangular flask, fully shakes up, rear equivalent is poured into 4 culture dishes (Φ 9cm), and it is flat that 5 concentration gradient band medicines are made
Plate.And it sets the processing without medicament and makees blank control.It will cultured pathogen, aseptically use sterilizing on culture medium
Card punch (Φ 5mm) cuts bacteria cake from the same circumference of colony edge, with inoculator by pure culture biscuits involvng inoculation in drug containing tablet center, bacterium
Silk down, covers ware lid, the dark culturing in 25 DEG C of incubators.According to mycelia growing state in blank control ware, slide calliper rule are used
Measure colony diameter.Each bacterium colony uses crossing method vertical measurement, takes its average value, calculates the inhibition grown to mycelia
Rate.
Each inhibiting rate for handling and being grown to mycelia is calculated by formula (1), (2), unit is percentage (%), and result of calculation is protected
Stay 2 significant digits.
D=D1-D2…………………………………………(1)
In formula：
D-bacterium colony increases diameter, and unit is millimeter (mm)；
D1- colony diameter, unit are millimeter (mm)；
D2- bacteria cake diameter, unit are millimeter (mm).
In formula：
I-mycelial growth inhibition rate, unit are percentage (%)；
D0- blank control bacterium colony increases diameter, and unit is millimeter (mm)；
Dt- chemicals treatment bacterium colony increases diameter, and unit is millimeter (mm).
(2) to the bioactivity of soybean cyst nematode Heterodera glycines
Reference《NY/T 1833.1-2009 farm-chemical indoor determination test rule nematicide part 1s：Inhibit plant
Pathogenic nematode tests dip method》It carries out.
It is to be collected from field for trying object with soybean cyst nematode Heterodera glycines (Heterodera glycines), moves into soybean root
Culture, it is spare after laying eggs.
The cyst of picking soybean cyst nematode Heterodera glycines is cleaned with 0.4mmoL/L liquor zinci chloridis from old complaint, is placed in culture dish
On wet filter paper, hatch at 20~25 DEG C, obtains age consistent second instar larvae.2min is centrifuged under 1000r/min, abandons supernatant,
Add water, then centrifuge, finally nematode is resuspended floating to every milliliter >=100 nematodes with water, it is spare.
With pipettor from low concentration to high concentration, prepared liquid 3mL is drawn successively and is added in test tube, is then drawn
The equivalent nematode suspension 3mL prepared is added in test tube, keeps liquid and nematode suspension mixed in equal amounts uniform.It is moved with pipettor
It takes the above-mentioned mixed liquor of certain volume in the aperture of porous biochemical test plate, is capped, for 24 hours in 25 DEG C of constant temperature incubations.Often handle 4
Secondary repetition often repeats leaching worm and is no less than 100, and sets the processing without medicament as blank control.
From taken in each processing 1mL mixed liquors under anatomical lens from nematode death condition, should not per repeated observation nematode number
Less than 100, snoop bus borer population and verge of death borer population are recorded.Judge that nematode death standard is stiff for nematode, with hair needle or
Bamboo silk needle touching is still unable to bending motion.
The death rate is calculated by (3) formula, and unit is percentage (%), and result of calculation retains 2 significant digits：
In formula：
P1- the death rate, unit are percentage (%)；
K-expression death borer population, unit is head；
N-expression handles total borer population, and unit is head.
(3) to the bioactivity of colorado potato bug
Reference《The 14th part of NY/T 1154.14-2008 farm-chemical indoor determination test rules insecticide：Leaf dipping method》
It carries out.
It is for trying object, choosing indoor raising, physiology shape with colorado potato bug (Leptinotarsa decemlineata)
4 consistent instar larvaes of state are tested, using potato leaf as foodstuff.
Fresh potato leaf is dipped in liquid medicine to be measured, takes out and dries after 10s, be placed in and filtered containing 1% moisturizing
In the culture dish of paper, test worm is accessed, often handles 4 repetitions, often repeatedly 30, if blank control is made in the processing without medicament.It will
Test worm is placed in that temperature is (25 ± 1) DEG C, humidity is 60%~80%, photoperiod L:D=(16:8) it raises and sees under h condition
It examines.48h investigation results (death standard after processing：Polypide is touched with writing brush, polypide is stiff), total borer population and dead is recorded respectively
Die number.The death rate is calculated by (3) formula.
(4) to the bioactivity of rice water weevil
Bibliography is reported, biological activity determination is carried out with dipping seedling method.The specific method is as follows：
It is for trying object, choosing indoor raising, physiology with rice water weevil (Lissorhoptrus oryzophilus)
The rice water weevil adult of state consistency is tested.
The rice seedling of robust growth is chosen, 10 plants are one group, by rice seedlings stem above section in reagent agent solution
It takes out, is put into 25mm × 300mm test tubes after dipping 10s, access test worm, often handle 4 repetitions, often repeatedly 30, if being free of
Blank control is made in the processing of medicament.Be disposed, nozzle is tightened with gauze, be placed in temperature be (26 ± 1) DEG C, humidity be 70%~
75%, photoperiod L:D=(14:10) it raises and observes under h condition.Handle 48h after investigation result, record respectively total borer population and
Death toll.Pest death standard is：Polypide is touched with writing brush, polypide is stiff.The death rate is calculated by (3) formula.
(5) to the bioactivity of corn wireworm
It is for trying object, choosing indoor raising, physiological status one with corn wireworm (Agriotes fuscicollis)
3 instar larvaes caused are tested.
Sandy loam is crossed into 20 mesh sieve, the sandy loam is weighed by every part of 1.0kg after being dried with far infrared flash dryer, takes
Prepared liquid is sequentially added in the soil sample from low to high by concentration, adds suitable quantity of water, makes soil moisture content about 18%, will
The pesticide-clay mixture is fitted into after being stirred evenly in " V " type mixing machine have been accessed the glass of test worm and has supported in scolite, is put into fresh with tender
Maize seedling prevents test worm from escaping as food, beyond the Great Wall rubber plug.4 repetitions are often handled, often repeatedly 30, and set the place without medicament
Reason is used as blank control.48h investigation results (death standard after processing：Polypide is touched with writing brush, polypide is stiff), remember respectively
Record total borer population and death toll.The death rate is calculated by (3) formula.
(6) to the bioactivity of Sporisorium reilianum
Bibliography is reported, biological activity determination is carried out with turbidity method.The specific method is as follows：
It is to acquire morbidity group from field for trying pathogen with Sporisorium reilianum (Sphacelotheca reiliana)
It knits, the indoor fresh teleutospore powder of separation picking is spare.
Electronic balance, pressure steam sterilizer, superclean bench, transmissometer, constant-temperature shaking incubator, pipettor are got out,
Sterilizing pipette tips, triangular flask, measuring cup, improvement reason look into culture solution, deionized water, spare.
Improvement reason looks into the preparation method of culture solution：Potassium nitrate KNO is weighed respectively310g, potassium dihydrogen phosphate KH2PO45g, sulphur
Sour magnesium MgSO42.5g, iron chloride FeCl3In 0.02g and glucose 30g to measuring cup, with water dissolution and it is settled to 1L.
10mg maize head smut germ teleutospore powder is weighed, impregnates exhibition with 0.03% Tween-20 sterile water solutions of 10mL
After 4h, 4000r/min centrifuges 10min, abandons supernatant.0.25% potassium permanganate KMnO is added in spore sediment4It is water-soluble
Liquid 10mL, concussion shake up, and stand 25min.Centrifugation, abandons supernatant.0.05mol/L hydrochloric acid solution 10mL are added in sediment,
Concussion shakes up, and stands 6h, and supernatant is abandoned in centrifugation.Spore sediment is finally transferred to 200mL sterilizing improvement reasons and looks into culture solution
In, mixing is prepared into band bacteria culture fluid, training is shaken then in 25 DEG C, under the conditions of 150r/min for 24 hours, is adjusted with sterile deionized water
Spore suspension turbidity is spare to 800.
Under aseptic technique, 25mL improvement reasons are added in 50mL skies triangular flask and look into culture solution, inoculates and has prepared
100 μ L of spore suspension, then draw 250 μ L liquids successively from low concentration to high concentration, be separately added into above-mentioned triangular flask,
It mixes well, by mixed liquor at 25 DEG C, is cultivated under the conditions of 150r/min.And it sets the processing without medicament and makees blank control.Culture
Before, the turbidity of culture solution under 650nm wavelength is measured with transmissometer.After constant-temperature table culture 28 hours, it is muddy to measure each processing
Turbidity.
According to investigation result, growth inhibition ratio of each processing to germ is calculated by formula (4), unit is percentage (%),
Result of calculation retains 2 significant digits.
In formula：
P-growth inhibition ratio；
A0- blank control turbidity value added；
A1- chemicals treatment turbidity value added.
(7) to the bioactivity of rice hoppers
Reference《The 11st part of NY/T 1154.11-2008 farm-chemical indoor determination test rules insecticide：Rice stem impregnates
Method》It carries out.
It is for trying object, choosing indoor raising with rice hoppers (Nilaparvata lugens), physiological status is consistent
3 age nymphs tested.
The tillering stage rice seedlings for taking the stalwartness of laboratory cultures consistent connect root and take, clean, be cut into the company root rice of 10cm long
Stem dries in the air to surface in shady place without washmarking.Ready rice stem is respectively placed in the liquid of various concentration and impregnates 30s, is taken out
It slightly dries afterwards, root moisturizing is encased with the rayon balls soaked with clear water, outsourcing preservative film is placed in test tube, per 3 plants of test tube.
Test worm is put into test tube with pest sucking device, nozzle is sealed with wet gauze, often pipe 15, often repeatedly 2 is managed, 4 repetitions of each concentration.
If blank control is made in the processing without medicament.It connects the test tube after worm to be positioned over (25 ± 1) DEG C, relative humidity 60%~80%, light
Period L:D=16h:It is raised in the growth cabinet of 8h.72h investigation results (death standard after processing：Polypide is touched with writing brush,
Polypide is stiff), total borer population and death toll are recorded respectively.The death rate is calculated by (3) formula.
(8) to the bioactivity of rape striped flea-beetle, rice thrips and wheat aphid
Reference《The 6th part of NY/T 1154.6-2006 farm-chemical indoor determination test rules insecticide：Insecticidal activity is tried
Test dip method》It carries out.
With rape striped flea-beetle (Phyllotrata striolata), rice thrips (Stenchaetothrips
Biformis) or wheat aphid (Sitobion avenae) is for trying object, choosing indoor raising, the consistent worm of physiological status
Body is tested (rape striped flea-beetle chooses 3 instar larvaes, and rice thrips chooses 2 age nymphs, and wheat aphid chooses aptery adult aphid).
By 3 instar larvae of rape striped flea-beetle, or the rice leaf with 2 age thrips nymphs, or with the small of aptery adult aphid
Wheat blade soaks into the liquid 10s, dries, is placed in the culture dish containing moisturizing filter paper after taking-up, often handles 4 repetitions, often weighs
It is 30 multiple, if blank control is made in the processing without medicament.By test worm be placed in temperature be (25 ± 1) DEG C, humidity is 60%~80%,
Photoperiod is L:D=(16:8) it raises and observes under h condition.Investigation result (death standard after processing 48h：Worm is touched with writing brush
Body, polypide are stiff), total borer population and death toll are recorded respectively.The death rate is calculated by (3) formula.
(9) to the bioactivity of cotton cutworm
Reference《The 15th part of NYT 1154.15-2009 farm-chemical indoor determination test rules insecticide：Subterranean pest-insect
Dip method》It carries out.
Be to choose indoor raising for trying object with cotton cutworm (Agrotis segetum), physiological status it is consistent 3
Instar larvae is tested.
Larva is soaked into the liquid 10s to take out, extra liquid is sucked with filter paper, test worm is transferred to equipped with new with tender
In fresh cotton seedling teat glass, nozzle is covered with moist black cloth, is placed in 25 DEG C ± 1 DEG C, the perseverance of relative humidity 60%~80%
It is raised in warm insectary.4 repetitions are often handled, often repeatedly 30, and the processing without medicament is set as blank control.After processing
48h investigation result (death standards：Polypide is touched with writing brush, polypide is stiff), total borer population and death toll are recorded respectively.It presses
(3) formula calculates the death rate.
(10) to the bioactivity of Ustilago tritici
Bibliography is reported, biological activity determination is carried out with spore germination method.The specific method is as follows：
It is to acquire wheat disease fringe, room from field for trying pathogen with Ustilago tritici (Ustilago tritici)
The interior fresh teleutospore powder of separation picking is spare.
It is spare after the sterilizings such as PDA culture medium, deionized water, scribing line triangular flask, culture dish, pipette tips.
Under aseptic technique, the sterilizing PDA culture medium for advance thawing being cooled to about 50 DEG C is quantitatively adding sterilizing stroke
In wire triangle bottle, keep culture medium concordant with (60mL) at scribing line, then draw 600 μ L liquids successively from low concentration to high concentration,
It is separately added into above-mentioned triangular flask, fully shakes up, rear equivalent is poured into 4 culture dishes (Φ 9cm), and 5 concentration gradient bands are made
Medicine tablet, cooled to room temperature are spare.And it sets the processing without medicament and makees blank control.Picking 4mg or so conidia powder is put into
In 50mL sterile waters, in filtered through gauze to triangular flask after fully shaking up, spore suspension is made.It is flat in the PDA prepared
0.1mL spore suspensions are added dropwise on plate per ware, are smoothened with spatula, (10 × 20 times) observations under microscope low-power field, each
Visual field spore number is 80 or so.It then will treated that PDA plate is placed under 24 DEG C of dark conditions cultivates.Exist every 6h
Microscopically observation compares spore germination situation, and culture is observed each processing miospore sprouting situation and (formed with spore germination afterwards for 24 hours
Germ tube length be considered as sproutings when being more than spore radius), 3 visuals field are investigated per ware PDA plate, investigate spore sum at 200
More than.Calculate inhibition of germination.
Inhibiting rate of each concentration for the treatment of to spore germination is calculated by formula (5), (6), unit is percentage (%), result of calculation
Retain 2 significant digits.
In formula：
R-spore germination rate, unit are percentage (%)；
Ng- spore germination number, unit are a；
NtThe spore sum of-investigation, unit is a.
In formula：
I-inhibition of germination, unit are percentage (%)；
R0- blank control spore germination rate, unit are percentage (%)；
Rt- chemicals treatment spore germination rate, unit are percentage (%).
(11) compositions contemplated activity judges
Compositions contemplated activity, which is used for reference in the transnational agricultural chemicals enterprise formulation patents such as Bayer, Syngenta, Tao Shi, judges composition
The method (COLBY methods) of expection activity：COLBY, S.R.：“Calculating Synergistic and Antagonistic
Responses of Herbicide Combinations ", Weeds 15, p.20~22,1967 carry out.
Compositions contemplated activity is calculated by (7) formula：
In formula：
Inhibiting rate when 1 dosage of X-medicament is P or the death rate；
Inhibiting rate when 2 dosage of Y-medicament is Q or the death rate；
Inhibiting rate when 3 dosage of Z-medicament is R or the death rate；
E0The theoretical inhibiting rate or the death rate that 1 dosage of-medicament is 2 dosage of P+ medicaments when be 3 dosage of Q+ medicaments being R, i.e. group
Close the expection activity of object；
Practical inhibiting rate when E-medicament 1,2 and 3 is by different ratio mixture or the death rate, the i.e. substantial activity of composition；
As E ＞ E0When, i.e., if the substantial activity of Mixed Pharmacy is more than calculated expection activity, the composition just has
There is super superposition, that is, acts synergistically.
2, test result
Test result refers to table 1~15, it is seen then that active components A (Rynaxypyr and carboxin) with selected from activity at
Divide B (imidacloprid, avermectin, phoxim, Biphenthrin, carbosulfan, efficient olefin conversion, chlopyrifos, ethiprole, thiophene worm
Piperazine, dinotefuran, Benfuracard micro, clothianidin, gamma cyhalothrin, emamectin-benzoate, efficient cyfluthrin
Pyrethroids etc.) medicament mixture after, substantial activity is all higher than expection activity, illustrates that the medicament in active components A and active constituent B is mixed
With with synergistic effect.
The synergy effect of 1 Rynaxypyr of table, carboxin and imidacloprid mixture to fusarium graminearum
The synergy effect of 2 Rynaxypyr of table, carboxin and avermectin mixture to soybean cyst nematode Heterodera glycines
The synergy effect of 3 Rynaxypyr of table, carboxin and phoxim mixture to colorado potato bug
The synergy effect of 4 Rynaxypyr of table, carboxin and Biphenthrin mixture to rice water weevil
The synergy effect of 5 Rynaxypyr of table, carboxin and carbosulfan mixture to corn wireworm
6 Rynaxypyr of table, carboxin are with efficient olefin conversion mixture to the synergy effect of Sporisorium reilianum
The synergy effect of 7 Rynaxypyr of table, carboxin and chlorpyrifos mixture pairing rice wilt pathogens
The synergy effect of 8 Rynaxypyr of table, carboxin and ethiprole mixture to rice hoppers
The synergy effect of 9 Rynaxypyr of table, carboxin and Diacloden mixture to rape striped flea-beetle
10 Rynaxypyr of table, carboxin and the dinotefuran mixed synergy effect to rice thrips
The synergy effect of 11 Rynaxypyr of table, carboxin and Benfuracard micro mixture to peanut root rot bacterium
The synergy effect of 12 Rynaxypyr of table, carboxin and clothianidin mixture to wheat aphid
The synergy effect of 13 Rynaxypyr of table, carboxin and gamma cyhalothrin mixture to cotton cutworm
14 Rynaxypyr of table, carboxin and emamectin-benzoate mixture are to Ustilago tritici
Synergy effect
15 Rynaxypyr of table, carboxin and betacyfluthrin mixture imitate the synergy of gaeumannomyces graminis
It answers
Claims (5)
1. a kind of composition, which is characterized in that including active components A and B.
2. composition as described in claim 1, which is characterized in that the active components A is Rynaxypyr and the rust that withers
Spirit.
3. composition as described in claim 1, which is characterized in that the active constituent B is Benfuracard micro, fourth sulphur gram hundred
Prestige, chlopyrifos, phoxim, betacyfluthrin, gamma cyhalothrin, kappa-tefluthrin, Biphenthrin, thiophene worm
In amine, dinotefuran, imidacloprid, Diacloden, avermectin, emamectin-benzoate, ethiprole, efficient olefin conversion
One or more combination.
4. composition as claimed in claim 1,2 or 3, which is characterized in that further include pesticide system other than active components A and B
The auxiliary agent that can be used in agent processing.
5. the composition as described in claim 1,2,3 or 4, which is characterized in that be applied to prevention plant pest.
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| CN201810357606.9A CN108308193A (en) | 2018-04-20 | 2018-04-20 | The composition of containing chlorantraniliprole and carboxin |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109566639A (en) * | 2018-12-29 | 2019-04-05 | 广西壮族自治区农业科学院玉米研究所 | A kind of composition pesticide for preventing and treating maize head smut |
| CN111406760A (en) * | 2019-12-30 | 2020-07-14 | 金华市农业科学研究院 | Synergistic pesticide composition, preparation method and application thereof |
| CN112273397A (en) * | 2020-10-29 | 2021-01-29 | 中诚国联（河南）生物科技有限公司 | Pesticide-fertilizer granules containing chlorantraniliprole and cyfluthrin and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120184A (en) * | 2012-06-01 | 2013-05-29 | 北京明德立达农业科技有限公司 | Fosthiazate pesticide composition and application thereof |
| CN106386846A (en) * | 2015-08-01 | 2017-02-15 | 华中农业大学 | Insecticidal composition containing clothianidin, chlopyrifos and chlorantraniliprole, and preparation method thereof |
-
2018
- 2018-04-20 CN CN201810357606.9A patent/CN108308193A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120184A (en) * | 2012-06-01 | 2013-05-29 | 北京明德立达农业科技有限公司 | Fosthiazate pesticide composition and application thereof |
| CN106386846A (en) * | 2015-08-01 | 2017-02-15 | 华中农业大学 | Insecticidal composition containing clothianidin, chlopyrifos and chlorantraniliprole, and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109566639A (en) * | 2018-12-29 | 2019-04-05 | 广西壮族自治区农业科学院玉米研究所 | A kind of composition pesticide for preventing and treating maize head smut |
| CN111406760A (en) * | 2019-12-30 | 2020-07-14 | 金华市农业科学研究院 | Synergistic pesticide composition, preparation method and application thereof |
| CN112273397A (en) * | 2020-10-29 | 2021-01-29 | 中诚国联（河南）生物科技有限公司 | Pesticide-fertilizer granules containing chlorantraniliprole and cyfluthrin and application thereof |
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Application publication date: 20180724 |