CN105638686A - A compound sterilization composition containing copper(succinate+glutarate+adipate) - Google Patents
A compound sterilization composition containing copper(succinate+glutarate+adipate) Download PDFInfo
- Publication number
- CN105638686A CN105638686A CN201410649217.5A CN201410649217A CN105638686A CN 105638686 A CN105638686 A CN 105638686A CN 201410649217 A CN201410649217 A CN 201410649217A CN 105638686 A CN105638686 A CN 105638686A
- Authority
- CN
- China
- Prior art keywords
- adipic acid
- acid copper
- glue adipic
- tiger glue
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
A compound sterilization composition containing copper(succinate+glutarate+adipate) is disclosed. Effective components of the composition comprise an active component A and an active component B, wherein the active component A is the copper(succinate+glutarate+adipate), the active component B is one compound selected from aureonuclemycin, ningnanmycin and oxytetracycline hydrochloride, and the weight ratio of the active component A to the active component B is 1:80-80:1. The composition has synergistic effects for a plurality of diseases endangering agriculture production, reduces the using amount of pesticides, reduces the residual amount of pesticides on crops, reduces environment pollution, and is safe to human and livestock and good in environment compatibility. Drug resistance for diseases is not liable to generate.
Description
Technical field
The invention belongs to technical field of pesticide, it relates to the application of a kind of combination sterilization composition containing tiger glue adipic acid copper on corps diseases.
Background technology
Tiger glue adipic acid copper (Copper (succinate+glutarate+adipate)), cure mainly bacterial diseases of plants, cationic exchange on cupric ion and cause of disease mycoderm surface, make the protein coagulating on pathogenic bacteria cytolemma, part copper ion penetrates in pathogenic bacteria cell and is combined with some enzyme simultaneously, affects it active. Can be used for control cucumber bacterial angular leaf spot, and plant-growth is had hormesis.
Gold alloy hydride, Ningnanmycin, doxycycline monohydrate all belong to common fungicide, are widely used in the disease of farm crop.
But, in the actual procedure of agriculture production, the problem that controlling disease the most easily produces is the generation of disease drug resistance. Different varieties composition carries out composite, is prevent and treat the very common method of resistance disease. Not congruent carry out composite, according to practical application effect, judge certain composite be synergy, add and or antagonistic action. In most cases, the composite effect of sterilization is all additive effect, really has the seldom composite of synergism, especially synergism clearly, very high composite just less of synergy ratio. Study through contriver, find tiger glue adipic acid copper and gold alloy hydride, Ningnanmycin, doxycycline monohydrate is composite after can produce good synergism, and not yet open about the relevant report that tiger glue adipic acid copper and gold alloy hydride, Ningnanmycin, doxycycline monohydrate are composite.
Summary of the invention
It is an object of the invention to propose a kind of to there is the good combination sterilization composition containing tiger glue adipic acid copper of synergistic function, use cost effect low, anti-.
The combination sterilization composition effective constituent containing tiger glue adipic acid copper that the present invention proposes is active components A and activeconstituents B, activity is divided into A and activeconstituents B weight ratio is 1 80��80 1, described active components A is tiger glue adipic acid copper, the one that activeconstituents B is selected from gold alloy hydride, Ningnanmycin, doxycycline monohydrate, active components A and the preferred weight ratio of activeconstituents B are 1 50��50 1; The weight ratio being more preferably tiger glue adipic acid copper and gold alloy hydride is 1 25��30 1, and the weight ratio of tiger glue adipic acid copper and Ningnanmycin is 1 25��30 1, and the weight ratio of tiger glue adipic acid copper and doxycycline monohydrate is 1 25��25 1.
The combination sterilization composition containing tiger glue adipic acid copper that the present invention proposes is for preventing and treating the purposes of disease on farm crop, and described farm crop comprise food crop, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crops, flowers crop, medicinal crop, crop, green manure pasture crop;Described disease is Peptic Ulcers, angular leaf spot, anthrax, false smut, Powdery Mildew, root rot, virus disease, spot defoliation, damping-off, leaf blight or soft rot.
The weight ratio of active components A, activeconstituents B is 1 80��80 1. In usual composition, the weight percentage of active ingredient is the 0.5%��90% of gross weight, it is preferred that be 5%��80%. According to different preparation types, active component content scope is different. Usually, liquid preparation contains the active substance of be weight 1%��70%, it is preferred that be 5%��50%; Solid preparation contains the active substance of be weight 5%��80%, it is preferred that be 10%��80%.
At least containing a kind of tensio-active agent in the fungicidal composition of the present invention, the dispersion of active ingredient in water when being beneficial to use. Surfactant content is the 5%��30% of total formulation weight amount, and surplus is solid or liquid diluent.
The fungicidal composition of the present invention can by user before use through diluting or directly use. Its preparation can be prepared by common working method known in those skilled in the art, after mixing with liquid solvent or solid carrier by active substance, then add tensio-active agent such as one or more in dispersion agent, wetting agent, binding agent, defoamer, disintegrating agent, antifreezing agent etc.
The fungicidal composition of the present invention, acceptable formulation in any sterilization can be processed on demand, wherein more preferably formulation is wettable powder, water dispersible granules, suspension agent, suspended emulsion agent, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, it is also possible to make aqua, soluble powder, soluble granula, seed coat agent, kind clothing suspension agent.
Following component concentration is comprised: active components A 0.1%��80%, activeconstituents B0.1%��80%, dispersion agent 2%��10%, wetting agent 2%��10%, filler surplus when composition makes wettable powder.
Following component concentration is comprised: active components A 0.1%��80%, activeconstituents B0.1%��80%, dispersion agent 3%��12%, wetting agent 1%��8%, disintegrating agent 1%��10%, binding agent 0��8%, filler surplus when composition makes water dispersible granules.
Following component concentration is comprised: active components A 0.1%��50%, activeconstituents B0.1%��50%, dispersion agent 2%��10%, wetting agent 2%��10%, defoamer 0.01%��2%, thickening material 0��2%, antifreezing agent 0��8%, deionized water or vegetables oil add to 100% when composition makes suspension agent.
Following component concentration is comprised: active components A 0.1%��50%, activeconstituents B0.1%��50%, dispersion agent 2%��10%, defoamer 0.01%��2%, solvent 1%��15%, thickening material 0��2%, emulsifying agent 2%��12%, antifreezing agent 0��8%, deionized water add to 100% when composition makes suspended emulsion agent.
Following component concentration is comprised: active components A 0.1%��50%, activeconstituents B0.1%��50%, solvent 1%��30%, emulsifying agent 1%��15%, antifreezing agent 0��8%, thickening material 0��2%, defoamer 0.01%��2%, deionized water supply surplus when composition makes aqueous emulsion.
Following component concentration is comprised: active components A 0.1%��50%, activeconstituents B0.1%��50%, solvent 1%��30%, emulsifying agent 3%��25%, antifreezing agent 0��8%, defoamer 0.01%��2%, deionized water supply surplus when composition makes microemulsion.
Following component concentration is comprised: active components A 0.1%��50%, activeconstituents B0.1%��50%, polymer cyst material 2%��10%, dispersion agent 1%��10%, organic solvent 1%��10%, emulsifying agent 1%��7%, defoamer 0.01%��2%, pH adjusting agent 0.01%��5%, deionized water add to 100% when composition makes microcapsule suspending agent.
Following component concentration is comprised: active components A 0.1%��50%, activeconstituents B0.1%��50%, polymer cyst material 2%��10%, dispersion agent 1%��12%, wetting agent 1%��8%, organic solvent 1%��15%, emulsifying agent 1%��6%, defoamer 0.01%��2%, thickening material 0��2%, pH adjusting agent 0.01%��5%, deionized water add to 100% when composition makes microcapsule suspension-suspendinagent agent.
The main technical indicator of the wettable powder of the present invention:
The main technical indicator of the water dispersible granules of the present invention:
The main technical indicator of the suspension agent of the present invention:
The main technical indicator of the suspended emulsion agent of the present invention:
The main technical indicator of the aqueous emulsion of the present invention:
The main technical indicator of the microemulsion of the present invention:
The main technical indicator of the microcapsule suspending agent of the present invention:
The main technical indicator of the microcapsule suspension-suspendinagent agent of the present invention:
It is an advantage of the current invention that:
(1) tiger glue adipic acid copper and gold alloy hydride, Ningnanmycin, doxycycline monohydrate composite after, there is obvious synergy and lasting effect; (2) disease on food crop, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crops, flowers crop, medicinal crop, crop, green manure pasture crop all there is greater activity; (3) decrease pesticide usage amount, reduce the residual quantity of agricultural chemicals on crop, alleviate environmental pollution; (4) to person poultry safety, Environmental compatibility is good; And preparation clinging power strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the per-cent in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1��10 wettable powder
Tiger glue adipic acid copper, activeconstituents B, dispersion agent, wetting agent, filler being mixed in mixed cylinder, after micronizer mill is pulverized, remix is even, can obtain wettable powder product of the present invention, specifically in table 1.
The each component of table 1 embodiment 1��10 and weight part
Embodiment 11��20 water dispersible granules
Tiger glue adipic acid copper, activeconstituents B, dispersion agent, wetting agent, disintegrating agent, filler etc. are obtained through comminution by gas stream together the particle diameter needed, then adds other auxiliary agents such as binding agent (can add and can not add), obtain granulation materials. Item is quantitatively sent in fluidized bed granulation drying machine through granulating and after drying, water dispersible granules product of the present invention can be obtained, specifically in table 2.
The each component of table 2 embodiment 11��20 and weight part
Embodiment 21��27 suspension agent
By dispersion agent, wetting agent, defoamer, thickening material (can add and can not add), antifreezing agent (can add and can not add), mix through high speed shear, add tiger glue adipic acid copper, activeconstituents B, ball milling 2��3 hours in ball mill, make diameter of particle all below 5 ��m, surplus deionized water or vegetables oil are supplied, and can obtain suspension agent product of the present invention, specifically in table 3.
The each component of table 3 embodiment 21��27 and weight part
Gold alloy hydride in table 1��3, Ningnanmycin, doxycycline monohydrate are exchanged, new preparation can be obtained.
Embodiment 28��30 suspended emulsion agent
Dispersion agent, defoamer, thickening material (can add and can not add), antifreezing agent (can add and can not add) are mixed through high speed shear, add tiger glue adipic acid copper, ball milling 2��3 hours in ball mill, make diameter of particle all below 5 ��m, obtained tiger glue adipic acid copper suspension agent, then by activeconstituents B, solvent (can add and can not add), emulsifying agent and the various direct emulsification of auxiliary agent high speed agitator in suspension agent, surplus deionized water is supplied, obtained suspended emulsion agent product of the present invention, specifically in table 4.
The each component of table 4 embodiment 28��30 and weight part
Embodiment 31��38 aqueous emulsion
Tiger glue adipic acid copper, activeconstituents B, solvent, emulsifying agent are added together, make to be dissolved into even oil phase; Deionized water, antifreezing agent (can add and can not add), thickening material (can add and can not add), defoamer are mixed, Cheng Junyi aqueous phase. Under high velocity agitation, aqueous phase being added oil phase, surplus deionized water is supplied; Aqueous emulsion product of the present invention can be obtained, specifically in table 5.
The each component of table 5 embodiment 31��38 and weight part
Gold alloy hydride in table 5, Ningnanmycin, doxycycline monohydrate are exchanged, new preparation can be obtained.
Embodiment 39��41 microemulsion
Tiger glue adipic acid copper, activeconstituents B, solvent, emulsifying agent, antifreezing agent (can add and can not add), defoamer are fully mixed into the oil phase of homogeneous transparent, under agitation slowly add deionized water, form Water in Oil emulsion, again through stirring heating, make it to turn rapidly oil-in-water-type of coordinating, being chilled to room temperature to make it to reach balance, after filtration, surplus deionized water is supplied; Microemulsion product of the present invention can be obtained, specifically in table 6.
The each component of table 6 embodiment 39��41 and weight part
Embodiment 42,43 microcapsule suspending agent
By tiger glue adipic acid copper, activeconstituents B, polymer cyst material, solvent mixing, make to be dissolved into even oil phase, in a shear condition, oil phase is joined in the aqueous phase solution containing emulsifying agent, pH adjusting agent, dispersion agent, surplus deionized water is supplied, bi-material reacts at water-oil interface, forms high score ascus wall, makes the finely disseminated microcapsule suspending agent product of the present composition. Specifically in table 7.
Table 7 embodiment 42,43 each component and weight part
Embodiment 44,45 microcapsule suspension-suspendinagent agent
By activeconstituents B, polymer cyst material, solvent mixing, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution containing emulsifying agent, pH adjusting agent in a shear condition, make finely disseminated microcapsule suspending agent. Dispersion agent, wetting agent, defoamer, thickening material (can add and can not add) are mixed through high speed shear, add tiger glue adipic acid copper, ball milling 2��3 hours in ball mill, make diameter of particle all below 5 ��m, obtained suspension agent, then being joined by suspension agent in the aqueous phase solution of micro-capsule suspension, deionized water supplies surplus, makes the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition. Specifically in table 8.
Table 8 example 44,45 each component or its content
The embodiment of the present invention is the method adopting Toxicity Determination and field test to combine. First pass through Toxicity Determination, synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonistic action, 0.5��SR��1.5 are summation action, SR > 1.5 is synergism, on this basis, then carry out field test.
Test method: determine after the effective inhibition concentration scope of each medicament through prerun, medicament establishes 5 dosage process respectively by active constituent content, if clear water comparison.Carry out with reference to " farm-chemical indoor determination test rule sterilant ", adopt mycelial growth rate method to measure medicament to the virulence of crop germ. Measure colony diameter with cross interior extrapolation after 72h, calculate each process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (�� g/mL) converts logarithmic value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least squares, and thus calculate the EC of often kind of medicament50Value. Calculating two medicaments different ratio synergy ratio (SR) according to Wadley method, SR < 0.5 is antagonistic action, and 0.5��SR��1.5 are summation action simultaneously, and SR > 1.5 is synergism. Calculation formula is as follows:
Wherein: a, b are respectively active components A and activeconstituents B ratio shared in combination;
A is tiger glue adipic acid copper;
The one that B is selected from gold alloy hydride, Ningnanmycin, doxycycline monohydrate.
Application Example two
For examination disease: mandarin tree Peptic Ulcers
Test medicine provides by Shaanxi Mei Bang agricultural chemicals company limited.
Test design: determine tiger glue adipic acid copper and effective inhibition concentration scope of the former medicine of gold alloy hydride and the two different ratio mixture through pilot study.
Table 9 tiger glue adipic acid copper and the composite toxicity test analysis of results table to mandarin tree Peptic Ulcers of gold alloy hydride
As shown in Table 9, the synergy ratio SR of mandarin tree Peptic Ulcers is all greater than 1.5 when 1 80��80 1 by tiger glue adipic acid copper and gold alloy hydride proportioning, illustrate that both all show synergism at mixture in 1 80��80 1 scopes, when the proportioning of tiger glue adipic acid copper and gold alloy hydride is when 1 25��30 1, synergism is more outstanding, and synergy ratio is all more than 2.30. Testing, through applicant, the optimum ratio finding tiger glue adipic acid copper and gold alloy hydride is 30:1,25:1,20:1,15:1,10:1,5:1,4:1,3:1,2:1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:13,1:15,1:20,1:25, especially when tiger glue adipic acid copper and gold alloy hydride weight ratio are 2:1, synergy ratio is maximum, and synergism is the most obvious.
Application Example three
For examination disease: tomato virus disease
Test medicine provides by Shaanxi Mei Bang agricultural chemicals company limited.
Test design: determine tiger glue adipic acid copper and effective inhibition concentration scope of the former medicine of Ningnanmycin and the two different ratio mixture through pilot study.
Table 10 tiger glue adipic acid copper and the composite toxicity test analysis of results table to tomato virus disease of Ningnanmycin
As shown in Table 10, the synergy ratio SR of tomato virus disease is all greater than 1.5 when 1 80��80 1 by tiger glue adipic acid copper and Ningnanmycin proportioning, illustrate that both all show synergism at mixture in 1 80��80 1 scopes, when the proportioning of tiger glue adipic acid copper and Ningnanmycin is when 1 25��30 1, synergism is more outstanding, and synergy ratio is all more than 2.25. Testing, through applicant, the optimum ratio finding tiger glue adipic acid copper and Ningnanmycin is 30:1,25:1,20:1,15:1,10:1,5:1,4:1,3:1,2:1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:13,1:15,1:20,1:25, especially when tiger glue adipic acid copper and Ningnanmycin weight ratio are 4:1, synergy ratio is maximum, and synergism is the most obvious.
Application Example four
For examination disease: soft rot of cabbage
Test medicine provides by Shaanxi Mei Bang agricultural chemicals company limited.
Test design: determine tiger glue adipic acid copper and effective inhibition concentration scope of the former medicine of doxycycline monohydrate and the two different ratio mixture through pilot study.
Table 11 tiger glue adipic acid copper and the composite toxicity test analysis of results table to soft rot of cabbage of doxycycline monohydrate
As shown in Table 11, the synergy ratio SR of soft rot of cabbage is all greater than 1.5 when 1 80��80 1 by tiger glue adipic acid copper and doxycycline monohydrate proportioning, illustrate that both all show synergism at mixture in 1 80��80 1 scopes, when the proportioning of tiger glue adipic acid copper and doxycycline monohydrate is when 1 25��25 1, synergism is more outstanding, and synergy ratio is all more than 2.30. Testing, through applicant, the optimum ratio finding tiger glue adipic acid copper and doxycycline monohydrate is 25:1,20:1,15:1,10:1,5:1,4:1,3:1,2:1,1:1,2:3,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:13,1:15,1:20,1:25, especially when tiger glue adipic acid copper and doxycycline monohydrate weight ratio are 1:1, synergy ratio is maximum, and synergism is the most obvious.
Find through test: tiger glue adipic acid copper and activeconstituents B composite after the control of the Peptic Ulcers in various crop, angular leaf spot, anthrax, false smut, Powdery Mildew, root rot, virus disease, spot defoliation, damping-off, leaf blight or soft rot is had obvious synergism, synergy ratio SR is all greater than 1.5.
Effect experiment part: test medicine, by the research and development of Shaanxi Mei Bang agricultural chemicals company limited, offer, compares medicament 30% tiger glue adipic acid copper suspension agent (autogamy), 30% gold alloy hydride wettable powder (autogamy), 2% Ningnanmycin aqua (autogamy), 88% doxycycline monohydrate soluble powder (autogamy).
Application Example five tiger glue adipic acid copper and activeconstituents B and composite prevent and treat the angular leaf spot of cucumber test of pesticide effectiveness.
This test arrangement is in suburb, Xi'an City, Shanxi Province, and investigation angular leaf spot of cucumber disease index before medicine, in disease, initial stage dispenser occurs, and 3 days, 7 days, 15 days investigation disease indexes after dispenser also calculate anti-effect. Test-results is as follows:
Table 12 tiger glue adipic acid copper and activeconstituents B and composite prevent and treat the angular leaf spot of cucumber test of pesticide effectiveness
As can be seen from Table 12, tiger glue adipic acid copper and activeconstituents B composite after can effectively prevent and treat angular leaf spot of cucumber, through applicant test find tiger glue adipic acid copper and activeconstituents B composite after can also effectively prevent and treat powdery mildew of cucumber, virus disease, prevention effect is all higher than 96%, the anti-effect being better than single dose, and the anti-effect phase is long. In test scope of medication, mark target crop is had no adverse effects.
Application Example six tiger glue adipic acid copper and activeconstituents B and composite prevent and treat the soft rot of cabbage test of pesticide effectiveness.
This test arrangement is in suburb, Xi'an City, Shanxi Province, and investigation soft rot of cabbage disease index before medicine, in disease, initial stage dispenser occurs, and 5 days, 15 days, 30 days investigation disease indexes after dispenser also calculate anti-effect. Test-results is as follows:
Table 13 tiger glue adipic acid copper and activeconstituents B and composite prevent and treat the soft rot of cabbage test of pesticide effectiveness
As can be seen from Table 13, tiger glue adipic acid copper and activeconstituents B composite after can effectively prevent and treat soft rot of cabbage, through applicant test find tiger glue adipic acid copper and activeconstituents B composite after can also effectively prevent and treat Chinese cabbage anthrax, prevention effect is all higher than 96%, the anti-effect being better than single dose, and the anti-effect phase is long. In test scope of medication, mark target crop is had no adverse effects.
Application Example seven tiger glue adipic acid copper and activeconstituents B and the composite control rice green smut test of pesticide effectiveness thereof.
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and investigation rice green smut disease index before medicine, in disease, initial stage dispenser occurs, and 3 days, 7 days, 15 days investigation disease indexes after dispenser also calculate anti-effect. Test-results is as follows:
Table 14 tiger glue adipic acid copper and activeconstituents B and the composite control rice green smut test of pesticide effectiveness thereof
As can be seen from Table 14, tiger glue adipic acid copper and activeconstituents B and composite control rice green smut thereof, through applicant test find tiger glue adipic acid copper and activeconstituents B composite after can also effectively prevent and treat rice seedling blight, leaf blight, prevention effect is all higher than 97%, the anti-effect being better than single dose, and the anti-effect phase is long. In test scope of medication, mark target crop is had no adverse effects.
Application Example eight tiger glue adipic acid copper and activeconstituents B and the composite control mandarin tree Peptic Ulcers test of pesticide effectiveness thereof.
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and investigation mandarin tree Peptic Ulcers disease index before medicine, in disease, initial stage dispenser occurs, and 3 days, 10 days, 20 days investigation disease indexes after dispenser also calculate anti-effect. Test-results is as follows:
Table 15 tiger glue adipic acid copper and activeconstituents B and the composite control mandarin tree Peptic Ulcers test of pesticide effectiveness thereof
As can be seen from Table 15, tiger glue adipic acid copper and activeconstituents B composite after can effectively prevent and treat mandarin tree Peptic Ulcers, through applicant test find tiger glue adipic acid copper and activeconstituents B composite after can also effectively prevent and treat mandarin tree Powdery Mildew, prevention effect is all higher than 95%, the anti-effect being better than single dose, and the anti-effect phase is long. In test scope of medication, mark target crop is had no adverse effects.
Application Example nine tiger glue adipic acid copper and activeconstituents B and the composite control apple peels and cores test of pesticide effectiveness thereof.
This test arrangement is in suburb, Xianyang, Shanxi province city, and investigation apple peels and cores disease index before medicine, in disease, initial stage dispenser occurs, and 3 days, 10 days, 20 days investigation disease indexes after dispenser also calculate anti-effect. Test-results is as follows:
Table 16 tiger glue adipic acid copper and activeconstituents B and the composite control apple peels and cores test of pesticide effectiveness thereof
As can be seen from Table 16, tiger glue adipic acid copper and activeconstituents B composite after can effectively preventing and treating apple-tree spot defoliation, test through applicant find tiger glue adipic acid copper and activeconstituents B composite after can also effectively preventing and treating apple-tree Powdery Mildew, anthrax, root rot, prevention effect is all higher than 95%, the anti-effect being better than single dose, and the anti-effect phase is long. In test scope of medication, mark target crop is had no adverse effects.
After through drawing in test in all parts of the country different local, after tiger glue adipic acid copper and gold alloy hydride, Ningnanmycin are composite to the anti-effect of the common diseases such as the Peptic Ulcers in various crop, angular leaf spot, anthrax, false smut, Powdery Mildew, root rot, virus disease, spot defoliation, damping-off, leaf blight or soft rot all more than 95%, being better than the anti-effect of single dose, synergism is obvious.
Claims (6)
1. the combination sterilization composition containing tiger glue adipic acid copper, effective active composition is active components A and activeconstituents B, it is characterized in that: active components A and activeconstituents B weight ratio are 1 80��80 1, described active components A is tiger glue adipic acid copper, the one that activeconstituents B is selected from gold alloy hydride, Ningnanmycin, doxycycline monohydrate.
2. the combination sterilization composition containing tiger glue adipic acid copper according to claim 1, it is characterised in that: the weight ratio of active components A and activeconstituents B is 1 50��50 1.
3. the combination sterilization composition containing tiger glue adipic acid copper according to claim 2, it is characterised in that:
The weight ratio of tiger glue adipic acid copper and gold alloy hydride is 1 25��30 1;
The weight ratio of tiger glue adipic acid copper and Ningnanmycin is 1 25��30 1;
The weight ratio of tiger glue adipic acid copper and doxycycline monohydrate is 1 25��25 1.
4. the combination sterilization composition containing tiger glue adipic acid copper according to any one of claim 1 to 3, it is characterised in that: composition makes wettable powder, water dispersible granules, suspension agent, suspended emulsion agent, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
5. the combination sterilization composition containing tiger glue adipic acid copper according to claim 4 is for preventing and treating the purposes of disease on farm crop.
6. purposes according to claim 5, it is characterised in that: described disease is Peptic Ulcers, angular leaf spot, anthrax, false smut, Powdery Mildew, root rot, virus disease, spot defoliation, damping-off, leaf blight or soft rot.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649217.5A CN105638686B (en) | 2014-11-14 | 2014-11-14 | A kind of combination sterilization composition containing tiger glue adipic acid copper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649217.5A CN105638686B (en) | 2014-11-14 | 2014-11-14 | A kind of combination sterilization composition containing tiger glue adipic acid copper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105638686A true CN105638686A (en) | 2016-06-08 |
| CN105638686B CN105638686B (en) | 2019-05-17 |
Family
ID=56479962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410649217.5A Active CN105638686B (en) | 2014-11-14 | 2014-11-14 | A kind of combination sterilization composition containing tiger glue adipic acid copper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105638686B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114521566A (en) * | 2022-02-21 | 2022-05-24 | 广西壮族自治区农业科学院 | Synergistic composition for preventing and treating soft rot of taro |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA01011718A (en) * | 2001-11-15 | 2003-05-23 | Lapisa S A De C V | Fungicide and bactericide composition for plants. |
| US20080160059A1 (en) * | 2006-11-08 | 2008-07-03 | Quimica Agronomica De Mexico | Antibiotic/antimycotic preparation and use in plants |
| CN103392740A (en) * | 2013-07-26 | 2013-11-20 | 海南正业中农高科股份有限公司 | Kasugamycin-containing sterilization composition and application thereof |
-
2014
- 2014-11-14 CN CN201410649217.5A patent/CN105638686B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA01011718A (en) * | 2001-11-15 | 2003-05-23 | Lapisa S A De C V | Fungicide and bactericide composition for plants. |
| US20080160059A1 (en) * | 2006-11-08 | 2008-07-03 | Quimica Agronomica De Mexico | Antibiotic/antimycotic preparation and use in plants |
| CN103392740A (en) * | 2013-07-26 | 2013-11-20 | 海南正业中农高科股份有限公司 | Kasugamycin-containing sterilization composition and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| 张兴: "《生物农药概览（第二版）》", 30 April 2011, 中国农业出版社 * |
| 杨平华: "《农田常用杀菌剂使用技术》", 31 January 2009, 四川科学技术出版社 * |
| 袁会珠 李卫国: "《现代农药应用技术图解》", 30 June 2013, 中国农业科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114521566A (en) * | 2022-02-21 | 2022-05-24 | 广西壮族自治区农业科学院 | Synergistic composition for preventing and treating soft rot of taro |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105638686B (en) | 2019-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104336023A (en) | Sterilization composition containing oxathiapiprolin | |
| CN104336079A (en) | A compound sterilization composition containing oxathiapiprolin | |
| CN104642360A (en) | Sterilization composition containing fluorothiazole pyriethanone and methoxyl acrylate | |
| CN104336033A (en) | A compound sterilization composition containing oxathiapiprolin and thiocarbamate | |
| CN105851058A (en) | Sterilization composition containing captan and copper preparation | |
| CN104798787A (en) | Composition containing benzovindiflupyr and triazole | |
| CN104412982A (en) | Compound efficient antibacterial composition containing fluoride ether bacteria amide | |
| CN103651451A (en) | Pesticide composition containing penthiopyrad | |
| CN104137836B (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
| CN104642341A (en) | Bactericidal composition containing zinc thiazole | |
| CN105851059A (en) | Germicidal composition containing bromothalonil and copper preparation | |
| CN104642346A (en) | High-efficient bactericidal composition containing zinc thiazole | |
| CN105557700A (en) | Composition containing benzovindiflupyr | |
| CN105409970A (en) | Sterilizing composition containing benzovindifluypr and triazole | |
| CN104126585A (en) | Compound bactericidal composition containing penflufen | |
| CN105660638A (en) | Bactericidal composition containing copper(succinate+glutarate+adipate) and strobilurin | |
| CN103875696B (en) | A kind of bactericidal composition containing amine benzene pyrrole bacterium ketone | |
| CN103621562B (en) | A kind of bactericidal composition | |
| CN103444743B (en) | A kind of Quinoxyfen-containinsterilization and the bactericidal composition of methoxy acrylic | |
| CN105638686A (en) | A compound sterilization composition containing copper(succinate+glutarate+adipate) | |
| CN105494404A (en) | Sterilization composition containing benzovindiflupyr | |
| CN103583541B (en) | A kind of bactericidal composition containing Fenarimol | |
| CN105660651A (en) | Microbicidal composition containing copper(succinate+glutarate+adipate) as well as triazoles | |
| CN105660636A (en) | Bactericidal composition containing copper(succinate+glutarate+adipate) | |
| CN105454292A (en) | Compound sterilizing composition containing copper oxychloride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Applicant after: Shaanxi Mei Bang Pharmaceutical Group Limited by Share Ltd Address before: 715500 Industrial Park of Agrochemical Base, Pucheng County, Shaanxi Province, Weinan City, Shaanxi Province Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |