CN105660636A - Bactericidal composition containing copper(succinate+glutarate+adipate) - Google Patents
Bactericidal composition containing copper(succinate+glutarate+adipate) Download PDFInfo
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Abstract
The invention discloses a bactericidal composition containing copper(succinate+glutarate+adipate). The bactericidal composition contains an active ingredient A and an active ingredient B, wherein the active ingredient A is the copper(succinate+glutarate+adipate), the active ingredient B is any compound selected from benzene kresoxim and pyraoxystrobin, and the weight ratio of the active ingredient A to the active ingredient B is (1: 60) to (80: 1). The composition disclosed by the invention has a synergistic effect on a variety of diseases which endanger agricultural production, so that the dosage of pesticides is reduced, the residual quantity of the pesticides on crops is reduced, the environmental pollution is alleviated, the composition is safe to human and livestock and is good in environmental compatibility, and the resistance of the diseases to drugs is difficult to generate.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application on corps diseases of a kind of bactericidal composition containing tiger glue adipic acid copper.
Background technology
Tiger glue adipic acid copper (copper (succinate+glutarate+adipate)), copper ion and the cation exchange on cause of disease Mycoderma surface, make the protein coagulating on pathogen cell membrane, part copper ion penetrates in pathogen cell and is combined with some enzyme simultaneously, affects its activity. Can be used for preventing and treating cucumber bacterial angular leaf spot, and plant growing is had stimulation.
ZJ0712, pyraoxystrobin belong to methoxy acrylic bactericide, are widely used in the disease of crops.
But, in the real process of agricultural production, controlling disease is easiest to generate the problem that the generation of disease drug resistance. Different cultivars composition carries out composite, is prevent and treat the method that resistance disease is very common. Heterogeneity carries out composite, according to practical application effect, judge certain composite be potentiation, add and or antagonism. In most cases, the composite effect of sterilization is all additive effect, really have potentiation composite seldom, especially potentiation clearly, significantly high composite just less of potentiation ratio. Study through inventor, it has been found that can will produce good potentiation after composite to tiger glue adipic acid copper and ZJ0712, pyraoxystrobin, and not yet open about the relevant report that tiger glue adipic acid copper and ZJ0712, pyraoxystrobin are composite.
Summary of the invention
The purpose of the present invention is to propose to and a kind of there is the bactericidal composition containing tiger glue adipic acid copper with ZJ0712 or pyraoxystrobin that synergistic function, use cost are low, preventive effect is good.
The bactericidal composition containing tiger glue adipic acid copper that the present invention proposes contains active components A and active component B, active components A and active component B weight ratio are 1 60～80 1, described active components A is selected from tiger glue adipic acid copper, active component B one in ZJ0712, pyraoxystrobin, active components A and the preferred weight ratio of active component B are 1 40～60 1; The weight ratio being more preferably tiger glue adipic acid copper and ZJ0712 is 1 10～25 1, and the weight ratio of tiger glue adipic acid copper and pyraoxystrobin is 1 10～20 1.
The bactericidal composition containing tiger glue adipic acid copper that the present invention proposes is for preventing and treating the purposes of disease on crops, and described crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop; Described disease includes Peptic Ulcers, shot hole, white rot, anthrachose of grape, bacterial angular leaf spot, leaf blight, false smut, damping-off, sclerotiniose, powdery mildew, downy mildew, rust, anthrax, gray mold, brown spot, scab or epidemic disease.
Active components A, active component B weight ratio be 1 80～60 1.In usual compositions, the weight percentage of active component is the 0.5%～90% of gross weight, it is advantageous to be 5%～80%. According to different preparation types, active component content scope is different. Generally, liquid preparation contains the active substance of by weight 1%～70%, it is preferred that be 5%～50%; Solid preparation contains the active substance of by weight 5%～80%, it is preferred that be 10%～80%.
The bactericidal composition of the present invention at least contains a kind of surfactant, active component dispersion in water when being beneficial to use. Surface-active contents is the 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The bactericidal composition of the present invention can by user before use through diluting or directly using. Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, add one or more in surfactant such as dispersant, stabilizer, wetting agent, binding agent, defoamer, disintegrating agent, antifreeze etc.
The bactericidal composition of the present invention, acceptable dosage form in any sterilization can be processed on demand, wherein more preferably dosage form is wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, it is also possible to make effervescent tablet, seed coat agent, ultra low volume liquids.
Compositions comprises following constituent content when making wettable powder: active components A 0.1%～60%, active component B0.1%～80%, dispersant 2%～10%, wetting agent 2%～10%, filler surplus.
Compositions includes following constituent content when making water dispersible granules: active components A 0.1%～60%, active component B0.1%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrating agent 1%～10%, binding agent 0～8%, filler surplus.
Compositions includes following constituent content when making suspending agent: active components A 0.5%～50%, active component B0.5%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer 0.01%～2%, thickening agent 0～2%, antifreeze 0～8%, deionized water add to 100%.
Compositions includes following constituent content when making suspension emulsion: active components A 0.5%～50%, active component B0.5%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent 1%～15%, thickening agent 0～2%, emulsifying agent 2%～12%, antifreeze 0～8%, deionized water add to 100%.
Compositions comprises following constituent content when making aqueous emulsion: active components A 0.5%～50%, active component B0.5%～50%, solvent 1%～30%, emulsifying agent 1%～15%, antifreeze 0～8%, thickening agent 0～2%, defoamer 0.01%～2%, deionized water supply surplus.
Compositions comprises following constituent content when making microemulsion: active components A 0.5%～50%, active component B0.5%～50%, solvent 1%～30%, emulsifying agent 3%～25%, antifreeze 0～8%, defoamer 0.01%～2%, deionized water supply surplus.
Compositions includes following constituent content when making microcapsule suspending agent: active components A 0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersant 1%～10%, organic solvent 1%～10%, emulsifying agent 1%～7%, defoamer 0.01%～2%, pH adjusting agent 0.01%～5%, deionized water add to 100%.
Compositions includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A 0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersant 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifying agent 1%～6%, defoamer 0.01%～2%, thickening agent 0～2%, pH adjusting agent 0.01%～5%, deionized water add to 100%;
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1) tiger glue adipic acid copper and ZJ0712, pyraoxystrobin composite after, there is obvious potentiation and lasting effect; (2) disease on cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop all there is greater activity; (3) decrease pesticide usage amount, reduce pesticide residual quantity on crop, alleviate environmental pollution; (4) to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Detailed description of the invention
Below in conjunction with embodiment to further instruction of the present invention, the percentage ratio in embodiment is all weight percentage, but the invention is not limited in this.
Application Example one
Embodiment 1～8 wettable powder
By tiger glue adipic acid copper, active component B, dispersant, wetting agent, filler mix homogeneously in mixed cylinder, remix uniformly after jet mill is pulverized, can be prepared by wettable powder product of the present invention, be specifically shown in table 1.
Table 1 embodiment 1～8 each component and weight portion
Embodiment 9～16 water dispersible granules
Tiger glue adipic acid copper, active component B, dispersant, wetting agent, disintegrating agent, filler etc. are obtained through comminution by gas stream together the particle diameter needed, adds other auxiliary agents such as binding agent (can add and can be not added with), obtain granulation materials. Item is quantitatively sent in fluidized bed granulating dryer through granulating and dried, can be prepared by water dispersible granules product of the present invention, be specifically shown in table 2.
Table 2 embodiment 9～16 each component and weight portion
Embodiment 17～24 suspending agent
By dispersant, wetting agent, defoamer, thickening agent (can add and can be not added with), antifreeze (can add and can be not added with), through high speed shear mix homogeneously, add tiger glue adipic acid copper, active component B, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, surplus deionized water is supplied, and can be prepared by suspending agent product of the present invention, is specifically shown in table 3.
Table 3 embodiment 17～24 each component and weight portion
Embodiment 25～28 suspension emulsion
By dispersant, defoamer, thickening agent (can add and can be not added with), antifreeze (can add and can be not added with) through high speed shear mix homogeneously, add active component B, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, prepare active component B suspending agent, then by tiger glue adipic acid copper, solvent, emulsifying agent and the various direct emulsifying of auxiliary agent high speed agitator to suspending agent, surplus deionized water is supplied, prepare suspension emulsion product of the present invention, be specifically shown in table 4.
Table 4 embodiment 25～28 each component and weight portion
Embodiment 29～34 aqueous emulsion
Tiger glue adipic acid copper, active component B, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase; Deionized water, antifreeze (can add and can be not added with), thickening agent (can add and can be not added with), defoamer are mixed, becomes homogeneous aqueous phase. Under high velocity agitation, aqueous phase adding oil phase, surplus deionized water is supplied; Can be prepared by aqueous emulsion product of the present invention, be specifically shown in table 5.
Table 5 embodiment 29～34 each component and weight portion
ZJ0712, pyraoxystrobin in table 1～5 are exchanged, novel formulation can be prepared.
Embodiment 35～37 microemulsion
Tiger glue adipic acid copper, active component B, solvent, emulsifying agent, antifreeze (can add and can be not added with), defoamer are sufficiently mixed uniformly transparent oil phase, under agitation it is slowly added into deionized water, form Water in Oil emulsion, then through agitating heating, so as to phase inversion becomes oil-in-water type rapidly, being cooled to room temperature and make up to balance, through filtering, surplus deionized water is supplied; Can be prepared by microemulsion product of the present invention, be specifically shown in table 6.
Table 6 embodiment 35～37 each component and weight portion
Embodiment 38,39 microcapsule suspending agent
By tiger glue adipic acid copper, active component B, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined containing emulsifying agent, pH adjusting agent, dispersant aqueous phase solution in, surplus deionized water is supplied, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition. It is specifically shown in table 7.
Table 7 embodiment 38,39 each component and weight portion
Embodiment 40,41 microcapsule suspension-suspendinagent agent
By tiger glue adipic acid copper, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, oil phase is joined in a shear condition containing emulsifying agent, pH adjusting agent aqueous phase solution in, make finely disseminated microcapsule suspending agent. By dispersant, wetting agent, defoamer, thickening agent (can add and can be not added with) through high speed shear mix homogeneously, add active component B, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, preparing suspending agent, then joined by suspending agent in the aqueous phase solution of micro-capsule suspension, deionized water supplies surplus, make the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition, be specifically shown in table 8.
Table 8 embodiment 40,41 each component and weight portion
The embodiment of the present invention is the method adopting Toxicity Determination and field test to combine. First pass through Toxicity Determination, potentiation ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is potentiation, on this basis, then carry out field test.
Test method: determine after the effective inhibition concentration scope of each medicament through prerun, medicament sets 5 dosage respectively and processes by active constituent content, if clear water comparison. Carry out with reference to " farm-chemical indoor determination test rule antibacterial ", adopt mycelial growth rate method to measure the medicament virulence to crop pathogenic bacteria. Measure colony diameter by decussation method after 72h, calculate each process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) converts logarithm value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least square, and thus calculate the EC of every kind of medicament50Value.Calculating two medicaments different ratio synergy ratio (SR) according to Wadley method, SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action simultaneously, and SR > 1.5 is potentiation. Computing formula is as follows:
Wherein: the ratio that a, b respectively active components A and active component B are shared in combination;
A is tiger glue adipic acid copper;
B one in ZJ0712, pyraoxystrobin.
Application Example two:
For examination disease: powdery mildew of cucumber
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
EXPERIMENTAL DESIGN: determine effective inhibition concentration scope of tiger glue adipic acid copper and the former medicine of ZJ0712 and the two different ratio mixture through pilot study.
Toxicity test result
Table 9 tiger glue adipic acid copper and the composite toxicity test analysis of results table to powdery mildew of cucumber of ZJ0712
As shown in Table 9, the potentiation ratio SR of powdery mildew of cucumber is all higher than 1.5 when 1 60～80 1 by tiger glue adipic acid copper and ZJ0712 proportioning, illustrate that both all show potentiation at mixture in 1 60～80 1 scopes, when the proportioning of tiger glue adipic acid copper and ZJ0712 is when 1 10～25 1, potentiation is more prominent, and potentiation ratio is all more than 2.15. Testing, through applicant, the optimum ratio finding tiger glue adipic acid copper and ZJ0712 is 25:1,20:1,19:1,18:1,17:1,16:1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, especially when tiger glue adipic acid copper and ZJ0712 weight ratio are 10:1, potentiation ratio is maximum, and potentiation is the most obvious.
Application Example three
For examination disease: sclerotinia rot of colza
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
EXPERIMENTAL DESIGN: determine effective inhibition concentration scope of tiger glue adipic acid copper and the former medicine of pyraoxystrobin and the two different ratio mixture through pilot study.
Table 10 tiger glue adipic acid copper and the composite toxicity test analysis of results table to sclerotinia rot of colza of pyraoxystrobin
As shown in Table 10, the potentiation ratio SR of sclerotinia rot of colza is all higher than 1.5 when 1 80～60 1 by tiger glue adipic acid copper and pyraoxystrobin proportioning, illustrate that both all show potentiation at mixture in 1 80～60 1 scopes, when the proportioning of tiger glue adipic acid copper and pyraoxystrobin is when 1 10～20 1, potentiation is more prominent, and potentiation ratio is all more than 2.25. Testing, through applicant, the optimum ratio finding tiger glue adipic acid copper and pyraoxystrobin is 20:1,19:1,18:1,17:1,16:1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, especially when tiger glue adipic acid copper and pyraoxystrobin weight ratio are 4:1, potentiation ratio is maximum, and potentiation is the most obvious.
Find through test: the preventing and treating of the Peptic Ulcers in various crop, shot hole, white rot, anthrachose of grape, bacterial angular leaf spot, leaf blight, false smut, damping-off, sclerotiniose, powdery mildew, downy mildew, rust, anthrax, gray mold, brown spot, scab or epidemic disease is had obvious potentiation with active component B after composite by tiger glue adipic acid copper, and potentiation ratio SR is all higher than 1.5.
Effect experiment part: test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided, comparison medicament 30% tiger glue adipic acid copper wettable powder (commercial), 10% ZJ0712 suspending agent (autogamy), 20% pyraoxystrobin suspending agent (autogamy).
Application Example four tiger glue adipic acid copper and active component B and composite prevent and treat the angular leaf spot of cucumber test of pesticide effectiveness
This test arrangement, at Xian District, Shanxi Province suburban area, investigates angular leaf spot of cucumber disease index before medicine, in disease early period of origination dispenser, within after dispenser 5 days, 15 days, 30 days, investigate disease indexes and calculate preventive effect. Result of the test is as follows:
Table 11 tiger glue adipic acid copper and active component B and composite prevent and treat the angular leaf spot of cucumber test of pesticide effectiveness
As can be seen from Table 11, angular leaf spot of cucumber can be effectively prevented and treated after tiger glue adipic acid copper is composite with active component B, test through applicant and find that tiger glue adipic acid copper and active component B can also effectively prevent and treat powdery mildew of cucumber, downy mildew, epidemic disease, Peptic Ulcers, anthrax, scab after composite, prevention effect is above 97%, it is better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example five tiger glue adipic acid copper and active component B and the composite preventing and treating watermelon anthrax test of pesticide effectiveness thereof
This test arrangement, in Weinan City Dali County, Shaanxi Province, investigates watermelon anthrax disease index before medicine, in disease early period of origination dispenser, within after dispenser 3 days, 10 days, 20 days, investigate disease indexes and calculate preventive effect. Result of the test is as follows:
Table 12 tiger glue adipic acid copper and active component B and the composite preventing and treating watermelon anthrax test of pesticide effectiveness thereof
As can be seen from Table 12, effectively preventing and treating watermelon anthrax after tiger glue adipic acid copper is composite with active component B, test finding that tiger glue adipic acid copper and active component B can also effectively prevent and treat Citrullus vulgaris powdery mildew after composite through applicant, prevention effect is above 97%, it is better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example six tiger glue adipic acid copper and active component B and the composite preventing and treating rice green smut test of pesticide effectiveness thereof
This test arrangement, in Hanzhong City suburb, Shaanxi Province, investigates rice green smut disease index before medicine, in disease early period of origination dispenser, within after dispenser 5 days, 15 days, 30 days, investigate disease indexes and calculate preventive effect. Result of the test is as follows:
Table 13 tiger glue adipic acid copper and active component B and the composite preventing and treating rice green smut test of pesticide effectiveness thereof
As can be seen from Table 13, tiger glue adipic acid copper and active component B and composite preventing and treating rice green smut thereof, test through applicant and find that tiger glue adipic acid copper and active component B can also effectively prevent and treat Rice Leaf rot, damping-off, rust after composite, prevention effect is above 96%, it is better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example seven tiger glue adipic acid copper and active component B and composite prevent and treat the downy mildew of garpe test of pesticide effectiveness
This test arrangement, in Weinan City suburb, Shaanxi Province, investigates downy mildew of garpe disease index before medicine, in disease early period of origination dispenser, within after dispenser 3 days, 10 days, 20 days, investigate disease indexes and calculate preventive effect. Result of the test is as follows:
Table 14 tiger glue adipic acid copper and active component B and composite prevent and treat the downy mildew of garpe test of pesticide effectiveness
As can be seen from Table 14, downy mildew of garpe can be effectively prevented and treated after tiger glue adipic acid copper is composite with active component B, test through applicant and find that tiger glue adipic acid copper and active component B can also effectively prevent and treat uncinula necator, gray mold, anthrachose of grape, white rot after composite, prevention effect is above 97%, it is better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, after tiger glue adipic acid copper and ZJ0712, pyraoxystrobin are composite to the preventive effect of the Common Diseases such as the Peptic Ulcers in various crop, shot hole, white rot, anthrachose of grape, bacterial angular leaf spot, leaf blight, false smut, damping-off, sclerotiniose, powdery mildew, downy mildew, rust, anthrax, gray mold, brown spot, scab or epidemic disease all more than 95%, being better than single dose preventive effect, potentiation is obvious.
Claims (6)
1. the bactericidal composition containing tiger glue adipic acid copper, effective active composition is active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 60～80 1, described active components A is tiger glue adipic acid copper, active component B one in ZJ0712, pyraoxystrobin.
2. the bactericidal composition containing tiger glue adipic acid copper according to claim 1, it is characterised in that: the weight ratio of active components A and active component B is 1 40～60 1.
3. the bactericidal composition containing tiger glue adipic acid copper according to claim 2, it is characterised in that:
The weight ratio of tiger glue adipic acid copper and ZJ0712 is 1 10～25 1;
The weight ratio of tiger glue adipic acid copper and pyraoxystrobin is 1 10～20 1.
4. the bactericidal composition containing tiger glue adipic acid copper according to any one of claim 1 to 3, it is characterised in that: compositions makes wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspendinagent agent.
5. the bactericidal composition containing tiger glue adipic acid copper according to claim 4 is for preventing and treating the purposes of disease on crops.
6. purposes according to claim 5, it is characterised in that: described disease is Peptic Ulcers, shot hole, white rot, anthrachose of grape, bacterial angular leaf spot, leaf blight, false smut, damping-off, sclerotiniose, powdery mildew, downy mildew, rust, anthrax, gray mold, brown spot, scab or epidemic disease.
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Cited By (1)
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| CN106818778A (en) * | 2017-02-10 | 2017-06-13 | 佛山市普尔玛农化有限公司 | A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition |
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| CN102626099A (en) * | 2012-03-28 | 2012-08-08 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing cupric nonyl phenolsulfonate and methoxy-acrylate bactericide |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102626099A (en) * | 2012-03-28 | 2012-08-08 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing cupric nonyl phenolsulfonate and methoxy-acrylate bactericide |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106818778A (en) * | 2017-02-10 | 2017-06-13 | 佛山市普尔玛农化有限公司 | A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition |
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