CN105580817A - Pesticide composition containing copper (succinate + glutarate + adipate) - Google Patents
Pesticide composition containing copper (succinate + glutarate + adipate) Download PDFInfo
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- CN105580817A CN105580817A CN201410649396.2A CN201410649396A CN105580817A CN 105580817 A CN105580817 A CN 105580817A CN 201410649396 A CN201410649396 A CN 201410649396A CN 105580817 A CN105580817 A CN 105580817A
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Abstract
The invention a pesticide composition containing copper (succinate + glutarate + adipate), which includes an active component A and active component B as effective active components, wherein the active component A is the copper (succinate + glutarate + adipate) and the active component B is any one selected from fluoxastrobin and azoxystrobin, the weight ratio of the active component A to the active component B being 1:80-80:1. The pesticide composition has synergistic effects on various pests damaging agricultural production, reduces usage amount of pesticides and reduces residual amount on crops, reduces environment pollution, is safe to people and animals, is good in environment compatibility, and is not liable to cause drug resistance in the pests.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition containing tiger glue adipic acid copperApplication on corps diseases.
Background technology
Tiger glue adipic acid copper (copper (succinate+glutarate+adipate)), copper ion and cause of diseaseThe lip-deep cation exchange of mycoderm, makes the protein coagulating on pathogen cell membrane, simultaneouslyPart copper iontophoretic injection enters in pathogen cell and is combined with some enzyme, affects its activity. AvailableIn control cucumber bacterial angular leaf spot, and plant growth is had to spread effect.
Fluoxastrobin, Fluoxastrobin all belong to methoxy acrylic bactericide, are widely used inIn the disease of crops.
But, in the real process of agricultural production, prevent and treat the problem that disease the most easily producesIt is the generation of disease drug resistance. Different cultivars composition carries out composite, is to prevent and treat resistance disease veryCommon method. Heterogeneity is carried out composite, according to practical application effect, judges certainComposite be synergy, add and or antagonism. In most cases, the composite effect of sterilizationFruit is all additive effect, really has the composite little of synergistic effect, and especially synergistic effect is non-Chang Mingxian, synergy ratio very high composite just still less. Through inventor's research, finding willAfter tiger glue adipic acid copper and fluoxastrobin, azoxystrobin compound, can produce good synergistic effect, andRelevant report about tiger glue adipic acid copper and fluoxastrobin, azoxystrobin compound is not yet open.
Summary of the invention
The object of the invention is to propose one and have that synergistic function, use cost are low, preventive effectThe good bactericidal composition containing tiger glue adipic acid copper.
The bactericidal composition containing tiger glue adipic acid copper that the present invention proposes contains active components A and workProperty composition B, active components A and active component B weight ratio are 1 ︰ 80～80 ︰ 1, describedActive components A is selected from tiger glue adipic acid copper, and active component B is selected from fluoxastrobin, FluoxastrobinOne, active components A and the preferred weight ratio of active component B are 1 ︰ 60～60 ︰ 1;More preferably the weight ratio of tiger glue adipic acid copper and fluoxastrobin is 1 ︰ 10～30 ︰ 1, tiger glue adipic acidThe weight ratio of copper and Fluoxastrobin is 1 ︰ 10～20 ︰ 1.
The bactericidal composition containing tiger glue adipic acid copper that the present invention proposes is used for preventing and treating on crops sickThe purposes of evil, described crops comprise cereal crops, legume crop, fibre crops, sugar materialCrop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop,Oil crops, flowers crop, medicinal crop, raw material crop, green manure pasture crop; DescribedDisease comprise canker, shot hole, scab, white rot, anthrachose of grape, bacterial angular leaf spot,Leaf blight, anthracnose, false smut, damping-off, gray mold, sclerotiniose, rust, epidemic disease,Leaf spot, glume blight, moire disease, brown spot, net blotch, smut, downy mildew or white powderSick.
The weight ratio of active components A, active component B is 1 ︰ 80～80 ︰ 1. Conventionally compositionThe weight percentage of middle active component is 0.5%～90% of gross weight, be preferably 5%～80%. According to different preparation types, active component content scope is different. Conventionally liquid,Body preparation contains 1%～70% active material by weight, is preferably 5%～50%; GuBody preparation contains 5%～80% active material by weight, is preferably 10%～80%.
In bactericidal composition of the present invention, at least contain a kind of surfactant, while being beneficial to useThe dispersion of active component in water. Surface-active contents is 5%～30% of total formulation weight amount,Surplus is solid or liquid diluent.
Bactericidal composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, is about to activeAfter material mixes with liquid flux or solid carrier, then add surfactant as dispersant, steadyDetermine one or more in agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc.
Bactericidal composition of the present invention, can be processed in any sterilization acceptable dose on demandType, wherein more preferably formulation be wettable powder, water dispersible granules, suspending agent, suspension emulsion,Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent, can also make effervesceTablet, seed coat agent, ultra low volume liquids.
When making wettable powder, composition comprises following constituent content: active components A 0.1%～80%, active component B0.1%～80%, dispersant 2%～10%, wetting agent 2%～10%, fill outMaterial surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 0.1%～80%, active component B0.1%～80%, dispersant 3%～12%, wetting agent 1%～8%, collapseSeparate agent 1%～10%, binding agent 0～8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer0.01%～2%, thickener 0～2%, antifreeze 0～8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent1%～15%, thickener 0～2%, emulsifying agent 2%～12%, antifreeze 0～8%, deionized waterAdd to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, solvent 1%～30%, emulsifying agent 1%～15%, antifreeze 0～8%,Thickener 0～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
When making microemulsion, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, solvent 1%～30%, emulsifying agent 3%～25%, antifreeze 0～8%,Defoamer 0.01%～2%, deionized water are supplied surplus.
When making microcapsule suspending agent, composition comprises following constituent content: active components A0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersionAgent 1%～10%, organic solvent 1%～10%, emulsifying agent 1%～7%, defoamer 0.01%～2%,PH adjusting agent 0.01%～5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersionAgent 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifying agent 1%～6%,Defoamer 0.01%～2%, thickener 0～2%, pH adjusting agent 0.01%～5%, deionized waterAdd to 100%;
Wettable powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) after tiger glue adipic acid copper and fluoxastrobin, azoxystrobin compound, there is obvious synergyAnd lasting effect; (2) to cereal crops, legume crop, fibre crops, sugar crop, melonClass crop, fruits crop, dry fruit crop, hobby crop, root crop, oil plant are doneDisease on thing, flowers crop, medicinal crop, raw material crop, green manure pasture crop all hasHigh activity; (3) reduced agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, subtractedLight environmental pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength increasesBy force, resistance of rainwater washing against.
Detailed description of the invention
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment isPercentage by weight, but the present invention is not limited thereto.
Application Example one
Embodiment 1～8 wettable powder
By tiger glue adipic acid copper, active component B, dispersant, wetting agent, filler in mixed cylinderMix, after airslide disintegrating mill is pulverized, mix again, can make of the present inventionWettable powder product, specifically in table 1.
The each component of table 1 embodiment 1～8 and weight portion
Embodiment 9～16 water dispersible granules
By tiger glue adipic acid copper, active component B, dispersant, wetting agent, disintegrant, filler etc.Obtain through air-flow crushing the particle diameter needing together, then add binding agent (can add and can not add) etc. itsIts auxiliary agent, obtains the materials of granulating. Item is quantitatively sent in fluidized bed granulation drying machine through systemGrain and dry after, can make water dispersible granules product of the present invention, specifically in table 2.
The each component of table 2 embodiment 9～16 and weight portion
Embodiment 17～24 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (canAdd and can not add), mix through high speed shear, add tiger glue adipic acid copper, active component B,Ball milling 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, and surplus spendsIonized water is supplied, and can make suspending agent product of the present invention, specifically in table 3.
The each component of table 3 embodiment 17～24 and weight portion
Embodiment 25～28 suspension emulsions
By dispersant, defoamer, thickener (can add and can not add), (can add can for antifreezeDo not add) mix through high speed shear, add active component B, ball milling in ball mill2～3 hours, make diameter of particle all below 5 μ m, make active component B suspending agent, soAfter by the direct emulsification of high speed agitator for tiger glue adipic acid copper, solvent, emulsifying agent and various auxiliary agentIn suspending agent, surplus is supplied by deionized water, makes suspension emulsion product of the present invention,Specifically in table 4.
The each component of table 4 embodiment 25～28 and weight portion
Embodiment 29～34 aqueous emulsions
Tiger glue adipic acid copper, active component B, solvent, emulsifying agent are added together, make to be dissolved intoEvenly oil phase; By deionized water, antifreeze (can add and can not add), (can add can be or not thickenerAdd), defoamer mixes, and becomes homogeneous water. Under high-speed stirred, water is addedOil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, toolBody is in table 5.
The each component of table 5 embodiment 29～34 and weight portion
Fluoxastrobin, Fluoxastrobin in table 1～5 are exchanged, can make novel formulation.
Embodiment 35～37 microemulsions
By tiger glue adipic acid copper, active component B, solvent, emulsifying agent, antifreeze, (can add can be notAdd), defoamer is fully mixed into the oil phase of homogeneous transparent, under agitation slowly adds deionizationWater, forms WO emulsion, then through agitating heating, makes it rapid phase inversion and become oil-in-water type,Be chilled to room temperature and make it to reach balance, after filtration, surplus is supplied by deionized water; Can make thisThe microemulsion product that invention is described, specifically in table 6.
The each component of table 6 embodiment 35～37 and weight portion
Embodiment 38,39 microcapsule suspending agents
By tiger glue adipic acid copper, active component B, macromolecule cyst material, solvent, make moltenSolution becomes even oil phase, under shearing condition, oil phase is joined and contains emulsifying agent, pH adjustingIn the aqueous phase solution of agent, dispersant, surplus is supplied by deionized water, and bi-material is at profit circleFace reacts, and forms macromolecule cyst wall, makes the finely disseminated micro-capsule of the present composition outstandingFloating agent product. Specifically in table 7.
Table 7 embodiment 38,39 each component and weight portions
Embodiment 40,41 microcapsule suspensions-suspending agent
By tiger glue adipic acid copper, macromolecule cyst material, solvent, make to be dissolved into even oil phase,Oil phase is joined under shearing condition in the aqueous phase solution that contains emulsifying agent, pH adjusting agent,Make finely disseminated microcapsule suspending agent. By dispersant, wetting agent, defoamer, thickener (canAdd and can not add) mix through high speed shear, add active component B, ball in ball millGrind 2～3 hours, make diameter of particle all below 5 μ m, make suspending agent, then will hangFloating agent joins in the aqueous phase solution of micro-capsule suspension, and deionized water is supplied surplus, makes thisFinely disseminated microcapsule suspension-the suspending agent of invention composition product, specifically in table 8.
Table 8 embodiment 40,41 each component and weight portions
The embodiment of the present invention is the method that adopts Toxicity Determination and field test to combine. FirstBy Toxicity Determination, the synergy ratio after clear and definite two kinds of medicaments are composite by a certain percentage(SR), SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 isSynergistic effect, on this basis, then carries out field test.
Test method: after the effective inhibition concentration scope of each medicament is determined in prerun, medicament is by effectiveComponent content is established respectively 5 dosage processing, establishes clear water contrast. With reference to " the indoor biometric of agricultural chemicalsDetermine test rule bactericide " carry out, adopt mycelial growth rate method to measure medicament to crop germVirulence. After 72h, measure colony diameter by right-angled intersection method, calculate each processing net growth,Mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) conversionBecome logarithm value (x), try to achieve virulence regression equation (y=a+bx) with least square method, and thusCalculate the EC of every kind of medicament50Value. Calculate the different proportionings of two medicaments according to Wadley method simultaneouslySynergy ratio (SR), SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action,SR > 1.5 is synergistic effect. Computing formula is as follows:
Wherein: a, b are respectively active components A and active component B shared ratio in combination;
A is tiger glue adipic acid copper;
B is selected from the one in fluoxastrobin, Fluoxastrobin.
Application Example two:
For trying disease: rice green smut
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design: determine tiger glue adipic acid copper and the former medicine of fluoxastrobin and the two through pilot studyEffective inhibition concentration scope of different proportioning mixtures.
Toxicity test result
The composite toxicity test analysis of results table to rice green smut of table 9 tiger glue adipic acid copper and fluoxastrobin
As shown in Table 9, tiger glue adipic acid copper and fluoxastrobin proportioning in the time of 1 ︰ 80～80 ︰ 1 to waterThe synergy ratio SR of rice false smut is all greater than 1.5, illustrates that both are in 1 ︰ 80～80 ︰ 1 scopesInterior mixture all shows synergistic effect, when the proportioning of tiger glue adipic acid copper and fluoxastrobin is at 1 ︰When 10～30 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.30. Through ShenAsk someone to test and find that the optimum ratio of tiger glue adipic acid copper and fluoxastrobin is 30:1,25:1,20:1、15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10, especially synergy ratio maximum in the time that tiger glue adipic acid copper and fluoxastrobin weight ratio are 3:1,Synergistic effect is the most obvious.
Application Example three
For trying disease: pepper anthracnose
Test medicine provides by Shaanxi Meibang Pesticide Co., Ltd..
Experimental design: determine tiger glue adipic acid copper and the former medicine of Fluoxastrobin and the two not through pilot studyWith effective inhibition concentration scope of proportioning mixture.
Table 10 tiger glue adipic acid copper and the azoxystrobin compound toxicity test analysis of results table to pepper anthracnose
As shown in Table 10, tiger glue adipic acid copper and Fluoxastrobin proportioning in the time of 1 ︰ 80～80 ︰ 1 to pepperyThe synergy ratio SR of green pepper anthracnose is all greater than 1.5, illustrates that both are in 1 ︰ 80～80 ︰ 1 scopesInterior mixture all shows synergistic effect, when the proportioning of tiger glue adipic acid copper and Fluoxastrobin is at 1 ︰When 10～20 ︰ 1, synergistic effect is more outstanding, and synergy ratio is all more than 2.25. Through ShenAsk someone to test and find that the optimum ratio of tiger glue adipic acid copper and Fluoxastrobin is 20:1,15:1,12:1、10：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5,1:6,1:7,1:8,1:9,1:10, especially when tiger glue adipic acid copper and FluoxastrobinSynergy ratio maximum when weight ratio is 2:1, synergistic effect is the most obvious.
Find through test: routed in various crop after tiger glue adipic acid copper and active component B are compositeUlcer disease, shot hole, scab, white rot, anthrachose of grape, bacterial angular leaf spot, leaf blight,Anthracnose, false smut, damping-off, gray mold, sclerotiniose, rust, epidemic disease, leaf spot,The control of glume blight, moire disease, brown spot, net blotch, smut, downy mildew or powdery mildewHave obvious synergistic effect, synergy ratio SR is all greater than 1.5.
Effect experiment part: test medicine is researched and developed, provided by Shaanxi Meibang Pesticide Co., Ltd., rightAccording to medicament 30% tiger glue adipic acid copper wettable powder (commercial), 10% fluoxastrobin missible oil (certainlyJoin), 250 grams per liter Fluoxastrobin suspending agents (commercial).
Application Example four tiger glue adipic acid coppers and active component B and the composite angular leaf spot of cucumber of preventing and treating thereofThe test of pesticide effectiveness
This test arrangement is at Xian District, Shanxi Province suburban area, and before medicine, investigation angular leaf spot of cucumber disease refers toNumber, in the dispenser of disease early period of origination, 5 days, 15 days, 30 days investigation disease indexes after dispenserAnd calculate preventive effect. Result of the test is as follows:
Table 11 tiger glue adipic acid copper and active component B and the composite angular leaf spot of cucumber test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 11, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeAngular leaf spot of cucumber, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat cucumber downy mildew, epidemic disease, powdery mildew, anthracnose, scab, controlEffect, all higher than 96%, is better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medicationTarget crop is had no adverse effects.
Application Example five tiger glue adipic acid coppers and active component B and the composite wheat rust medicine of preventing and treating thereofEffect test
This test arrangement, at Xian District, Shanxi Province suburban area, is investigated wheat rust disease index before medicine,In the dispenser of disease early period of origination, also meter of 3 days, 10 days, 20 days investigation disease indexes after dispenserCalculate preventive effect. Result of the test is as follows:
Table 12 tiger glue adipic acid copper and active component B and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 12, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeWheat rust, tests and finds that tiger glue adipic acid copper and active component B also can after composite through applicantEffectively to prevent and treat wheat leaf blight, net blotch, moire disease, prevention effect is all higher than 96%, excellentIn the preventive effect of single dose, and the preventive effect phase is long. Test scope of medication in to target crop without bad shadowRing.
Application Example six tiger glue adipic acid coppers and active component B and the composite citrus scab of preventing and treating thereofThe test of pesticide effectiveness
This test arrangement is at Xian District, Shanxi Province suburban area, and before medicine, investigation citrus scab disease refers toNumber, in the dispenser of disease early period of origination, 5 days, 15 days, 30 days investigation disease indexes after dispenserAnd calculate preventive effect. Result of the test is as follows:
Table 13 tiger glue adipic acid copper and active component B and the composite citrus scab test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 13, tiger glue adipic acid copper and active component B and composite control oranges and tangerines thereofShot hole, tests and finds that tiger glue adipic acid copper and active component B are also passable after composite through applicantEffectively control citrus anthracnose, canker, prevention effect is all higher than 95%, is better than single dosePreventive effect, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example seven tiger glue adipic acid coppers and active component B and the composite downy mildew of garpe of preventing and treating thereofThe test of pesticide effectiveness
This test arrangement, in Weinan City Dali County, Shaanxi Province, is investigated downy mildew of garpe disease before medicineIndex, in the dispenser of disease early period of origination, after dispenser, 3 days, 10 days, 20 days investigation diseases refer toCount and calculate preventive effect. Result of the test is as follows:
Table 14 tiger glue adipic acid copper and active component B and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 14, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeDowny mildew of garpe, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat uncinula necator, anthracnose, anthrachose of grape, white rot, gray mold, controlEffect, all higher than 95%, is better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medicationTarget crop is had no adverse effects.
After draw through different local throughout the country tests, tiger glue adipic acid copper and fluoxastrobin,After azoxystrobin compound to the canker in various crop, shot hole, scab, white rot, blackAcne disease, bacterial angular leaf spot, leaf blight, anthracnose, false smut, damping-off, gray mold,Sclerotiniose, rust, epidemic disease, leaf spot, glume blight, moire disease, brown spot, net blotch,The preventive effect of the Common Diseases such as smut, downy mildew or powdery mildew all, more than 95%, is better than single dosePreventive effect, synergistic effect is obvious.
Claims (6)
1. containing a bactericidal composition for tiger glue adipic acid copper, effective active composition is active componentA and active component B, is characterized in that: active components A and active component B weight ratio are 1︰ 80～80 ︰ 1, described active components A is tiger glue adipic acid copper, active component B is selected from fluorineOne in Fluoxastrobin, Fluoxastrobin.
2. the bactericidal composition containing tiger glue adipic acid copper according to claim 1, its featureBe: the weight ratio of active components A and active component B is 1 ︰ 60～60 ︰ 1.
3. the bactericidal composition containing tiger glue adipic acid copper according to claim 2, its featureBe:
The weight ratio of tiger glue adipic acid copper and fluoxastrobin is 1 ︰ 10～30 ︰ 1;
The weight ratio of tiger glue adipic acid copper and Fluoxastrobin is 1 ︰ 10～20 ︰ 1.
4. according to the sterilization group containing tiger glue adipic acid copper described in any one in claims 1 to 3Compound, is characterized in that: composition make wettable powder, water dispersible granules, suspending agent,Suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent.
5. the bactericidal composition containing tiger glue adipic acid copper according to claim 4 is for controlThe purposes of disease on crops.
6. purposes according to claim 5, is characterized in that: described disease is for burstingUlcer disease, shot hole, scab, white rot, anthrachose of grape, bacterial angular leaf spot, leaf blight,Anthracnose, false smut, damping-off, gray mold, sclerotiniose, rust, epidemic disease, leaf spot,Glume blight, moire disease, brown spot, net blotch, smut, downy mildew or powdery mildew.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106818778A (en) * | 2017-02-10 | 2017-06-13 | 佛山市普尔玛农化有限公司 | A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Applicant after: Shaanxi Mei Bang Pharmaceutical Group Limited by Share Ltd Address before: 715500 Industrial Park of Agrochemical Base, Pucheng County, Shaanxi Province, Weinan City, Shaanxi Province Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Applicant after: Shaanxi Mei Bang Pharmaceutical Group Limited by Share Ltd Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Applicant before: Shaanxi Meibang Pesticide Co., Ltd. |
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160518 |