CN101785464A - Oxine-copper composite bactericide - Google Patents
Oxine-copper composite bactericide Download PDFInfo
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- CN101785464A CN101785464A CN201010131884A CN201010131884A CN101785464A CN 101785464 A CN101785464 A CN 101785464A CN 201010131884 A CN201010131884 A CN 201010131884A CN 201010131884 A CN201010131884 A CN 201010131884A CN 101785464 A CN101785464 A CN 101785464A
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Abstract
The invention relates to an oxine-copper composite bactericide and belongs to the technical field of agricultural bactericides. The oxine-copper composite bactericide comprises the following active ingredients: oxine-copper and at least one bactericide for preventing and controlling downy mildew, wherein the weight ratio of the oxine-copper to the bactericide for preventing and controlling the downy mildew is 40:1-1:40; and the bactericide for preventing and controlling the downy mildew is selected from one of the following substances: oxadixyl, metalaxyl, propamocarb, cymoxanil, dimethomorph, pyrazol kresoxim methyl, cyazofamid, azoxystrobin, fluopicolide, mandipropamid and famoxadone. The oxine-copper composite bactericide is mainly used for preventing and controlling the downy mildew, late blight and the like harming cruciferous vegetables and fruit trees such as cucumber downy mildew, grape downy mildew, potato late blight and the like. The oxine-copper composite bactericide has the characteristics of improving effects, retarding pesticide resistance and the like and has the advantages of large prevention and control range, good prevention and control effect, small pesticide dosage and low agricultural cost.
Description
Technical field
The present invention relates to a kind of oxine-copper composite bactericide, belong to the disinfectant use in agriculture technical field.
Background technology
Copper 8-hydroxyquinolinate is novel organic copper preparation, is generated by oxine and copper sulphate reaction.Organic quinoline and mantoquita have the double sterilization activity, the G-protein synthesis that can suppress early stage cellular expression, suppress the metabolism of germ spore, the control cell divides once more and breaks up, it is active to have the multiple spot contact again concurrently, the pathogen spore that utilizes chelated copper to be sprouted absorbs, and directly kills the steamed stuffed bun cell in pathogen inside, thereby reaches the effect of preventing and curing diseases.Crop all had by fungi, bacterial multiple diseases kill significantly and inhibitory action, especially the downy mildew that caused by Oomycete, late blight etc. are had excellent control efficiency.
The spirit of Evil frost, metalaxyl, Propamocarb, white urea cyanogen, dimethomorph, pyraclostrobin, cyanogen frost azoles, Fluoxastrobin, fluorine pyrrole bacterium amine, mandipropamid An, oxazole bacterium ketone all are medicaments commonly used of preventing and treating the downy mildew bactericide in producing.Owing to use throughout the year, the existing pesticide resistance report of above various medicaments causes effect to descend, and with copper 8-hydroxyquinolinate and several bactericide compounded use, has very significant synergistic effect, can delay pesticide resistance, improves the control efficiency to cucumber downy mildew.
Copper 8-hydroxyquinolinate is Yu the situation of composite uses such as the spirit of Evil frost, metalaxyl, Propamocarb, white urea cyanogen, dimethomorph, pyraclostrobin, cyanogen frost azoles, Fluoxastrobin, fluorine pyrrole bacterium amine, mandipropamid An, oxazole bacterium ketone awaits further research.
Summary of the invention
The object of the present invention is to provide a kind of oxine-copper composite bactericide, prevention and treatment range is big, and control efficiency is good, and the little and agricultural cost of dosage is low.
Oxine-copper composite bactericide of the present invention, active ingredient comprise copper 8-hydroxyquinolinate and at least a downy mildew bactericide of preventing and treating, and wherein copper 8-hydroxyquinolinate is 40: 1～1: 40 with the weight ratio of preventing and treating the downy mildew bactericide.
The described downy mildew bactericide of preventing and treating is selected from a kind of: Evil frost spirit in the following material, metalaxyl, Propamocarb, white urea cyanogen, dimethomorph, pyraclostrobin, the white azoles of cyanogen, Fluoxastrobin, fluorine pyrrole bacterium amine, mandipropamid An with oxazole bacterium ketone etc.
Copper 8-hydroxyquinolinate and prevent and treat the 1～90% suitable of downy mildew fungicidal activity ingredients constitute microbicide compositions gross weight.
Among the present invention:
The chemical name of copper 8-hydroxyquinolinate (oxine-copper) is: copper 8-quinolinolate;
The chemical name of Evil frost spirit (oxadixyl) is: 2-methoxyl group-N-(2-oxo-1,3-oxazoles alkane-3-yl) acetyl-2 ', 6 '-dimethylaniline;
The chemical name of metalaxyl (metalaxyl) is: D, L-N-(2, the 6-3,5-dimethylphenyl)-N-(2 '-methoxyl group acetyl) methyl lactamine;
The chemical name of Propamocarb (propamocarb) is: 3-(dimethylamino) propyl carbamic acid propyl ester;
The chemical name of frost urea cyanogen (cymoxanil) is: carbonyl 2-cyano group-N-[(ethylamino-)]-2-(methoxyl group imido grpup) acetamide;
The chemical name of dimethomorph (dimethomorph) is: (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine;
The chemical name of pyraclostrobin (pyraclostrobin) is: methyl (N)-[[[1-(4-chlorobenzene) pyrazoles-3 base)-oxygen]-the O-methoxyl group]-the N-methoxymethyl carbamate;
The chemical name of cyanogen frost azoles (cyazofamid) is: 4-chloro-2-cyano group-5-p-methylphenyl-imidazoles-1-N, N-dimethyl methyl acid amides;
The chemical name of Fluoxastrobin (azoxystrobin) is: (E)-2-{2-[6 (2-cyano-benzene oxygen) pyrimidine-4-base oxygen] phenyl }-the 3-methoxy acrylate;
The chemical name of fluorine pyrrole bacterium amine (fluopicolide) is: 2, and 6-two chloro-N-[(3-chloro-5-trifluoromethyl-2-pyridine radicals) methyl] benzamide;
The chemical name of mandipropamid amine (mandipropamid) is: 2-(4-chloro-phenyl) N-[2-(3-methoxyl group-4-(2-third alkynyloxy group)-phenyl)-ethyl group]-2-(2-third alkynyloxy group)-with acid amides;
The chemical name of oxazole bacterium ketone (famoxadone) is: 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-azoles quinoline-2,4-diketone;
Above-mentioned active component all is bactericide well known in the art, can buy by various commercial channel.
Except that copper 8-hydroxyquinolinate and preventing and treating the downy mildew bactericide, according to routine operation, can select carrier, auxiliary agent and the functional additive etc. of adaptation for use, as thinner, antifreezing agent, thickener, stabilizing agent and defoamer etc., and can be made into different formulation products according to instructions for use, as be mixed with missible oil, wetting powder, microemulsion, aqueous emulsion, aqueous suspension agent, water dispersible granules etc.
Auxiliary agent also claims surfactant, can be emulsifier, dispersant, wetting agent or bleeding agent.Surfactant can be nonionic or anionic, can singlely use, and also can mix use by two or more arbitrary proportions.Described emulsifier mainly contains alkylphenol-polyethenoxy polyethenoxy ether, benzylphenol APEO, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate, phenethyl phenol polyethenoxy polyethenoxy ether, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene formaldehyde condensation products, and the phosphate neutralized salt of these compounds, alkyl benzene sulphonate (sodium salt or calcium salt) or directly use commercially available emulsifier monomer and composite product.The newborn 500# series of concrete example such as farming, 600# series, 400# series, 1600# series, NP (OP) series, AEO is serial, BY is serial, this dish series, tween is serial and composite kind 2201,0201B, 0201C, 0203B etc.
Described dispersant; wetting agent; bleeding agent has lignosulfonates (sodium salt or calcium salt); Negel; condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate; how sulfonic formaldehyde condensation compound; methanonaphthalene sodium sulfonate dibutyl is sulfonic formaldehyde condensation compound how; N-methyl fatty acyl group sodium taurocholate; alkylphenol-polyethenoxy formaldehyde condensation products sulphate; the alkylphenol polyoxyethylene phosphate; the withered powder of tea; saponin; lignosulfite; fatty alcohol polyoxyethylene ether sulfate; lauryl sodium sulfate; neopelex; ooze T soon; draw back what JFC of powder; can use separately, but also arbitrary proportion mixes use.
Described antifreezing agent makes a kind of in spent glycol, glycerine, propane diols, urea or the diethylene glycol (DEG) etc.
Described filler mainly contains white carbon, kaolin, precipitated calcium carbonate, diatomite, quartz sand, talcum powder and ammonium sulfate, sodium sulphate, sodium chloride, potassium chloride, potassium sulphate etc., can use separately or two or more arbitrary proportion mixing use.
Bactericide of the present invention is mainly used in the downy mildew, late blight of control danger to vegetables, fruit tree etc., can use according to the common water spray method of converting.
The present invention is through a large amount of desk research and field experiment, and screening is determined, the product main feature: the one, and composition shows fabulous synergistic effect in certain ratio range; The 2nd, because copper 8-hydroxyquinolinate is efficient copper agent compound, different with the existing mechanism of action that other prevents and treats the downy mildew bactericide, there is not mutual pesticide resistance, is difficult for developing immunity to drugs, therefore yet, rationally be mixed and delay single pesticide resistance that is produced with copper 8-hydroxyquinolinate and other bactericide, two kinds of bactericide compounded uses, prevention and treatment range is big, and control efficiency is good, dosage is little, and application cost is low.
Embodiment:
The invention will be further described below in conjunction with embodiment.
Composition all is weight percentage among the embodiment, and bioactive treatment dosage is active constituent content.
1, the processing of suspending agent and embodiment:
Press proportion of composing, the copper 8-hydroxyquinolinate of capacity and other bactericide, wetting agent, dispersant, thickener, antifreezing agent etc. are mixed with water, through high speed shear, the wet method sand milling, even at last matter is filtered and is promptly got product.Capital equipment is batching still, colloid mill or even matter mixer, sand mill.
Embodiment 1 (30% suspending agent)
The water of copper 8-hydroxyquinolinate 15%, Evil frost spirit 15%, 601 phosphate ester salts 3%, NP-10#1%, xanthans 0.2%, bentonite 5%, ethylene glycol 4% and surplus.
Embodiment 2 (35% suspending agent)
The water of copper 8-hydroxyquinolinate 25%, metalaxyl 10%, NP-10 phosphate ester salt 4%, AEO-10#2%, xanthans 0.15%, aluminium-magnesium silicate 1%, ethylene glycol 4% and surplus.
Embodiment 3 (35% suspending agent)
The water of copper 8-hydroxyquinolinate 20%, cyanogen frost azoles 15%, sodium lignin sulfonate 6%, JFC2%, xanthans 0.1%, white carbon 4%, ethylene glycol 4% and surplus.
Embodiment 4 (40% suspending agent)
The water of copper 8-hydroxyquinolinate 25%, dimethomorph 15%, sodium lignin sulfonate 6%, JFC2%, xanthans 0.1%, white carbon 4%, ethylene glycol 4% and surplus.
Embodiment 5 (45% suspending agent)
The water of copper 8-hydroxyquinolinate 30%, Fluoxastrobin 15%, sodium lignin sulfonate 6%, JFC2%, xanthans 0.1%, white carbon 4%, ethylene glycol 4% and surplus.
Embodiment 6 (50% suspending agent)
The water of copper 8-hydroxyquinolinate 30%, oxazole bacterium ketone 20%, sodium lignin sulfonate 6%, JFC2%, xanthans 0.1%, white carbon 4%, ethylene glycol 4% and surplus.
2, the processing of wetting powder and embodiment:
Pesticide active ingredient copper 8-hydroxyquinolinate and several bactericide, wetting agent, dispersant, filler are mixed in proportion the mixed again wetting powder that gets behind comminution by gas stream.Capital equipment has mixer, airslide disintegrating mill.
Embodiment 7 (30% wetting powder)
Copper 8-hydroxyquinolinate 20%, Propamocarb 10%, lauryl sodium sulfate 1%, draw back the kaolin of powder 1.5%, sodium lignin sulfonate 3%, NNO2%, white carbon 10% and surplus.
Embodiment 8 (40% wetting powder)
Copper 8-hydroxyquinolinate 25%, white urea cyanogen 15%, neopelex 1.5%, draw back the kaolin of powder 1.5%, calcium lignosulfonate 3%, NNO3%, white carbon 10% and surplus.
Embodiment 9 (50% wetting powder)
Copper 8-hydroxyquinolinate 40%, fluorine pyrrole bacterium amine 10%, lauryl sodium sulfate 1.5%, draw back the kaolin of powder 2%, sodium lignin sulfonate 5%, NNO4%, white carbon 10% and surplus.
Embodiment 10 (50% wetting powder)
Copper 8-hydroxyquinolinate 40%, mandipropamid amine 10%, lauryl sodium sulfate 1.5%, draw back the kaolin of powder 2%, sodium lignin sulfonate 5%, NNO4%, white carbon 10% and surplus.
3, the processing of water dispersible granules and embodiment:
Pesticide active ingredient copper 8-hydroxyquinolinate and bactericide, wetting agent, dispersant, filler are mixed in proportion, through comminution by gas stream, after add water after, make the water dispersible granules product through kneading, granulation, drying, screening; Maybe the powder that will pulverize water spray, granulation, drying in the fluidized granulating machine sieved afterwards and made product.Capital equipment has mixer, airslide disintegrating mill, kneader, Squeezinggranulator, drying room or fluid-bed drying, or fluidized granulating machine, screening machine.
Embodiment 11 (30% water dispersible granules)
The bentonite of copper 8-hydroxyquinolinate 20%, pyraclostrobin 10%, lauryl sodium sulfate 2%, sodium lignin sulfonate 4%, NNO2%, white carbon 20% and surplus.
Embodiment 12 (40% water dispersible granules)
The bentonite of copper 8-hydroxyquinolinate 20%, dimethomorph 20%, neopelex 2.5%, calcium lignosulfonate 4%, NNO3%, white carbon 15% and surplus.
Embodiment 13 (50% water dispersible granules)
Copper 8-hydroxyquinolinate 40%, cyanogen frost azoles 10%, lauryl sodium sulfate 1.5%, draw back the bentonite of powder 2%, NNO5%, white carbon 10% and surplus.
Embodiment 14 (60% water dispersible granules)
The bentonite of copper 8-hydroxyquinolinate 40%, metalaxyl 20%, lauryl sodium sulfate 3%, sodium lignin sulfonate 4%, NNO2%, white carbon 10% and surplus.
Embodiment 15 (70% water dispersible granules)
Copper 8-hydroxyquinolinate 50%, Fluoxastrobin 20%, neopelex 3.5%, draw back the bentonite of powder 1.5%, calcium lignosulfonate 4%, NNO3%, white carbon 5% and surplus.
Embodiment 16 (80% water dispersible granules)
Copper 8-hydroxyquinolinate 65%, oxazole bacterium ketone 15%, lauryl sodium sulfate 4%, draw back the kaolin of powder 2%, sodium lignin sulfonate 5%, NNO4% and surplus.
Complex preparation control vegetables of the present invention and fruit diseases field control effectiveness test result are as follows:
Table 1 40% copper 8-hydroxyquinolinate dimethomorph suspending agent (embodiment 4) control cucumber downy mildew field control effectiveness test
Table 2 40% copper 8-hydroxyquinolinate frost urea cyanogen wetting powder (embodiment 8) is prevented and treated the potato late blight field control effectiveness test
Table 3 50% copper 8-hydroxyquinolinate cyanogen frost azoles water dispersible granules (embodiment 13) is prevented and treated the downy mildew of garpe field control effectiveness test
Claims (3)
1. an oxine-copper composite bactericide is characterized in that active ingredient comprises copper 8-hydroxyquinolinate and at least a downy mildew bactericide of preventing and treating, and wherein copper 8-hydroxyquinolinate is 40: 1～1: 40 with the weight ratio of preventing and treating the downy mildew bactericide.
2. oxine-copper composite bactericide according to claim 1 is characterized in that the described downy mildew bactericide of preventing and treating is selected from a kind of: Evil frost spirit in the following material, metalaxyl, Propamocarb, white urea cyanogen, dimethomorph, pyraclostrobin, the white azoles of cyanogen, Fluoxastrobin, fluorine pyrrole bacterium amine, mandipropamid An with oxazole bacterium ketone.
3. oxine-copper composite bactericide according to claim 1 and 2 is characterized in that copper 8-hydroxyquinolinate and prevents and treats 1～90% of downy mildew fungicidal activity ingredients constitute microbicide compositions gross weight.
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| CN101999374A (en) * | 2010-10-13 | 2011-04-06 | 山东农业大学 | Hot fogging concentrate for controlling cucumber downy mildew in plastic greenhouses |
| CN102217638A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition for preventing and treating plant virus diseases |
| CN102217599A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition containing oxine-copper and kresoxim-methyl |
| CN102217621A (en) * | 2011-07-18 | 2011-10-19 | 青岛瀚生生物科技股份有限公司 | Bactericide composition containing pyraclostrobin and copper rosinate |
| CN102308835A (en) * | 2011-04-29 | 2012-01-11 | 广东中迅农科股份有限公司 | Pesticide composition containing streptomycin sulfate and oxine-copper |
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| CN101999374A (en) * | 2010-10-13 | 2011-04-06 | 山东农业大学 | Hot fogging concentrate for controlling cucumber downy mildew in plastic greenhouses |
| CN102217599B (en) * | 2011-04-27 | 2013-02-06 | 成都科利隆生化有限公司 | Pesticide composition containing oxine-copper and kresoxim-methyl |
| CN102217638A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition for preventing and treating plant virus diseases |
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| CN105981724A (en) * | 2015-02-10 | 2016-10-05 | 中化农化有限公司 | Oxine-copper-containing sterilization composition |
| CN105981724B (en) * | 2015-02-10 | 2018-09-28 | 中化农化有限公司 | Bactericidal composition containing copper 8-hydroxyquinolinate |
| CN105052944A (en) * | 2015-09-18 | 2015-11-18 | 梁龙华 | Sterilization composition and application thereof |
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| CN108184879A (en) * | 2017-12-28 | 2018-06-22 | 柳州市惠农化工有限公司 | A kind of composition containing copper 8-hydroxyquinolinate and Propineb, preparation method and applications |
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