CN103947650B - A kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole - Google Patents
A kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole Download PDFInfo
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- CN103947650B CN103947650B CN201410152290.1A CN201410152290A CN103947650B CN 103947650 B CN103947650 B CN 103947650B CN 201410152290 A CN201410152290 A CN 201410152290A CN 103947650 B CN103947650 B CN 103947650B
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Abstract
The invention discloses a kind of bactericidal composition and application thereof containing oxime bacterium ester and Difenoconazole, said composition is undertaken composite by oxime bacterium ester and Difenoconazole, have good synergistic function, wherein the weight ratio of oxime bacterium ester and Difenoconazole is 1-10: 1-10. In the diseases such as the present composition has expanded fungicidal spectrum, improves germicidal efficiency, has avoided the resistance to the action of a drug of disease, has extended the medicine lasting period, glume blight, powdery mildew and the scab in control cereal crops, vegetables, fruit tree, there is good effect.
Description
Technical field
The present invention relates to a kind of composition pesticide, be specifically related to a kind of Bactericidal composite that contains oxime bacterium ester and DifenoconazoleThing and application thereof, belong to technical field of pesticide.
Background technology
Difenoconazole (Difenoconazole), chemical name: suitable, the chloro-4-[4-methyl-2-1H-1 of trans-3-, 2,4-Triazol-1-yl methyl)-1, the mute pentane-2-of 3-bis-yl) phenyl 4-chlorphenyl ether, belong to triazole bactericidal agent, to Ascomycetes, loadDaughter bacteria guiding principle and comprise Alternaria, Ascochyta, the mould genus of tail spore, Colletotrichum, ball Cuo Pseudomonas, Phoma, Ramularia, shellPin spore belongs to, Venturia is partly known disease interior, and Erysiphaceae, Uredinales and some Seedborne pathogen have lasting protection and treatmentEffect.
Oxime bacterium ester (Trifloxystrobin), chemical name: (2Z)-2-methoxyimino-2-[2-[[1-[3-(threeMethyl fluoride) phenyl] ethyleneimino] oxygen methyl] phenyl] methyl acetate, from natural products Strobilurins, extract,The new fungicides of a class of successfully developing as bactericide lead compound, has efficient, wide spectrum, protection, treatment, shovelExcept characteristics such as, infiltration, systemic activity, resistance of rainwater washing against, lasting period are long. Oxime bacterium ester is to Isosorbide-5-Nitrae-demethylation enzyme inhibitor, benzene firstAmide-type, it is effective that dicarboxyl amine and benzimidazole produce the bacterial strain of resistance, with at present existing bactericide without cross resistance; To severalAll Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and Fungi Imperfecti) disease is as powdery mildew, rust, glume blight, filigreeDisease, downy mildew, rice blast etc. all have good activity; Except powdery mildew, leaf spot are had special efficacy, to rust, downy mildew, vertical witheredSick, apple apple scab has good activity; Capable of being fast degraded in soil, water because of it, therefore to crop safety, environment is pacifiedEntirely.
Long-term a large amount of use of single bactericide, easily makes disease develop immunity to drugs, and causes dosage increasing, preventive effect to be fallenLow, the lasting period shortens, and is unfavorable for environment sustainable development. Delaying disease one of the conventional method that develops immunity to drugs is that difference is doneUndertaken composite by the active ingredient of mechanism. By lot of experiments, determine best synergistic complex ratio, to expand fungicidal spectrum, improveGermicidal efficiency.
In patent CN102246765A, CN102379292A, CN103348987A, disclose with oxime bacterium ester and benzeneEther methyl cyclic-azole is the composite preparation of active component, but they exist with the form such as aqua, suspending agent, have not yet to see thisThe relevant report of both water dispersible granules.
Summary of the invention
The object of the present invention is to provide a kind of bactericidal composition containing oxime bacterium ester and Difenoconazole, specifically disclose itThe formulation of water dispersible granules, said composition function admirable, bactericidal effect excellence, can avoid disease to develop immunity to drugs, and increases medicineLasting period, be beneficial to environment sustainable development.
The present invention also provides the application of above-mentioned bactericidal composition in control cereal crops, vegetables, fruit diseases.
The present invention is achieved by the following measures:
Containing a bactericidal composition for oxime bacterium ester and Difenoconazole, it is characterized in that: active constituents of medicine be oxime bacterium ester withDifenoconazole, the weight ratio of oxime bacterium ester and Difenoconazole is 1-10: 1-10, preferred proportion is 1-5:1-5, most preferred ratioFor 1-2.5:1-2.5.
In above-mentioned bactericidal composition, the content of active constituents of medicine is 30-70wt%, preferably 40-60wt%.
The above-mentioned bactericidal composition containing oxime bacterium ester and Difenoconazole, can be by side known in those skilled in the artMethod, makes the upper any formulation allowing of agricultural, is preferably water dispersible granules.
When composition is made water dispersible granules, the component that comprises following percentage by weight: active constituents of medicine 30%-70%,Dispersant 4-10%, wetting agent 2-10%, disintegrant 1-20%, filler surplus. Preferably, composition is by following percentage by weightComponent composition: active constituents of medicine 30%-70%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus. More preferablyComponent by following percentage by weight forms: active constituents of medicine 40%-60%, dispersant 4.5%, wetting agent 2%, disintegrant12.5%, filler surplus.
Water dispersible granules preparation method is: Difenoconazole, oxime bacterium ester, dispersant, wetting agent, disintegrant, filler are existedIn mixer, mix, after airslide disintegrating mill is crushed to particle diameter 20-40 μ m, then mix, mediate amount of water 20-30wt%, carries out extruder grain, and 40-50 DEG C of oven dry can be made into oxime bacterium ester difenoconazole water dispersible granule product.
Described dispersant is calcium lignosulfonate, maleic acid-acrylic acid copolymer salt, PULLRONIC F68 blockCopolymer, alkylphenol sodium sulfonate, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, oxirane-One or more of propylene oxide block copolymer and polycarboxylate sodium. Preferred dispersants is by polycarboxylate sodium and lignin sulfonic acidCalcium in mass ratio 2:1 mixes.
Described wetting agent is selected from: lauryl sodium sulfate, a-sulfo methyl ester, sodium tetradecyl sulfate, 12Sodium alkyl benzene sulfonate, Negel, a-alkene sulfonic acid sodium, alkyl phenol polyethenoxy ether sodium sulfate, sodium lignin sulfonate, drawOpen one or more in powder BX, aliphatic acid sulfate and fatty acid ester sulfate, preferably wetting agent is by lauryl sodium sulfateWith sodium lignin sulfonate in mass ratio 1:1 mix.
Described disintegrant is selected from: potassium sulfate, sodium cellulose glycolate, potassium chloride, diammonium hydrogen phosphate, urea, sodium sulphate,One or more in ammonium sulfate, ammonium nitrate, calcium chloride and sodium chloride, preferably disintegrant by ammonium sulfate and urea is in mass ratio1.5:1 mix.
Described filler is selected from: kaolin, bentonite, talcum powder, attapulgite, diatomite, white carbon, starch, lightweightOne or more in calcium carbonate, preferred filler is white carbon.
Composition of the present invention be mainly used in preventing and treating the disease in cereal crops, vegetables, fruit tree, especially cereal crops,Glume blight, powdery mildew and scab in fruit and vegetables.
Beneficial effect of the present invention: (1) present composition effective active composition oxime bacterium ester and Difenoconazole belong to twoThe bactericide of planting the different mechanisms of action, both mutual mixtures can not produce conflict, and have expanded fungicidal spectrum, improve germicidal efficiency;(2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and dosage is little, has avoided diseaseThe resistance to the action of a drug, extended the medicine lasting period, be beneficial to environment sustainable development; (3) present composition is made water dispersible granules, keeps awayThe use of having exempted from organic solvent, has reduced environmental pollution, is also convenient to the packing of product and transport simultaneously; (4) present composition pairGlume blight, powdery mildew and scab on cereal crops, vegetables, fruit tree have special efficacy.
Detailed description of the invention
Below in conjunction with embodiment, to further instruction of the present invention, but the present invention is not limited thereto. If no special instructions,Percentage in following embodiment is all weight percentage.
The embodiment of the present invention is the method that adopts Toxicity Determination and field test to combine. First survey by indoor virulenceFixed, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5For summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field test.
Oxime bacterium ester and Difenoconazole are composite to powdery mildew of cucumber bacterium Toxicity Determination
Test medicine provides by Shandong Weifang Rainbow Chemical Co., Ltd..
After the effective inhibition concentration scope of each medicament is determined in prerun, each medicament is established respectively a series of by active constituent contentConcentration gradient processing, establishes clear water for contrast. Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelia rawLong performance rate method is measured the virulence of medicament to powdery mildew of cucumber. After 72h, measure colony diameter by right-angled intersection method, calculate each processing cleanIncrement, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, withLittle square law is tried to achieve virulence regression equation (y=a+bx), and calculates thus the EC of every kind of medicament50Value. Simultaneously according to WadleyMethod is calculated the different proportioning synergy ratios of two medicaments (SR), and SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are done for being addedWith, SR > 1.5 is synergistic effect. Computing formula is as follows:
Wherein:
A1, b1 are respectively oxime bacterium ester and Difenoconazole shared ratio in combination;
A is oxime bacterium ester;
B is Difenoconazole.
Result of the test is as shown in table 1:
As shown in Table 1, oxime bacterium ester, the EC of Difenoconazole to powdery mildew of cucumber50Be respectively 8.887mg/L and51.438mg/L, the virulence of oxime bacterium ester is apparently higher than the virulence of Difenoconazole. Oxime bacterium ester and Difenoconazole are at 1-10:Within the scope of 1-10, mixture all shows synergistic effect, within the scope of 1-5:1-5 synergy more obvious, within the scope of 1-2.5:1-2.5Synergy is the most remarkable.
Lower mask body is enumerated representative embodiment of the present invention.
Embodiment 133% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 3%, Difenoconazole 30%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, dodecylSodium sulphate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%.
Preparation method is: Difenoconazole, oxime bacterium ester, dispersant, wetting agent, disintegrant, filler is mixed in mixerClose evenly, after airslide disintegrating mill is crushed to particle diameter 20-40 μ m, then mix, mediate amount of water 20-30%, push and makeGrain, 40-50 DEG C of oven dry, can be made into 33% water dispersible granules.
Embodiment 254% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 9%, Difenoconazole 45%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, dodecylSodium sulphate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%. Preparation method is with embodiment 1.
Embodiment 370% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 20%, Difenoconazole 50%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, dodecylSodium sulphate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%. Preparation method is with embodiment 1.
Embodiment 440% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 20%, Difenoconazole 20%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, dodecylSodium sulphate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%. Preparation method is with embodiment 1.
Embodiment 556% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 40%, Difenoconazole 16%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, dodecylSodium sulphate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%. Preparation method is with embodiment 1.
Embodiment 630% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 25%, Difenoconazole 5%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, dodecylSodium sulphate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%. Preparation method is with embodiment 1.
Embodiment 760% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 54.5%, Difenoconazole 5.5%, polycarboxylate sodium 3%, calcium lignosulfonate 1.5%, 12Sodium alkyl sulfate 1%, sodium lignin sulfonate 1%, ammonium sulfate 7.5%, urea 5%, white carbon add to 100%. The same embodiment of preparation method1。
Embodiment 840.7% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 3.7%, Difenoconazole 37%, alkylphenol sodium sulfonate 8%, calcium lignosulfonate 1.5%, tenSodium dialkyl sulfate 1%, sodium lignin sulfonate 1%, potassium sulfate 15%, urea 7%, sodium cellulose glycolate 5%, bentonite add to100%. Preparation method is with embodiment 1.
Embodiment 930.6% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 5.1%, Difenoconazole 25.5%, polycarboxylate sodium 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt1.5%, ethylene oxide-propylene oxide block copolymer 2%, lauryl sodium sulfate 1%, a-alkene sulfonic acid sodium 2%, sodium chloride 25%,Talcum powder adds to 100%. Preparation method is with embodiment 1.
Embodiment 1035% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 10%, Difenoconazole 25%, polycarboxylate sodium 3%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 2%, ringOxidative ethane-propylene oxide block copolymer 2%, lauryl sodium sulfate 1%, a-alkene sulfonic acid sodium 2%, sodium chloride 25%, concave convex rodSoil adds to 100%. Preparation method is with embodiment 1.
Embodiment 1162% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 31%, Difenoconazole 31%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, calcium lignosulfonate 2%,Fatty acid ester sulfate 1%, Nekal BX 2%, calcium chloride 22%, bentonite add to 100%. Preparation method is with embodiment 1.
Embodiment 1256% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 40%, Difenoconazole 16%, maleic acid-acrylic acid copolymer salt 3%, polyoxyethylene-polyoxyPropylene-based block copolymer 2%, ethylene oxide-propylene oxide block copolymer 1%, aliphatic acid sulfate 1%, sodium lignin sulfonate 2%,Sodium sulphate 20%, starch add to 100%. Preparation method is with embodiment 1.
Embodiment 1337.2% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 31%, Difenoconazole 6.2%, calcium lignosulfonate 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt2%, ethylene oxide-propylene oxide block copolymer 2%, neopelex 1.5%, a-alkene sulfonic acid sodium 2%, ammonium sulfate12.5%, diatomite adds to 100%. Preparation method is with embodiment 1.
Embodiment 1444% oxime bacterium ester difenoconazole water dispersible granule
Formula is: oxime bacterium ester 40%, Difenoconazole 4%, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt 3%, naphthalenesulfonateformaldehyde formaldehyde contractingCompound sodium salt 4%, ethylene oxide-propylene oxide block copolymer 2%, sodium tetradecyl sulfate 1%, a-alkene sulfonic acid sodium 2%, chlorinationPotassium 10%, urea 5%, attapulgite add to 100%. Preparation method is with embodiment 1.
Oxime bacterium ester prepared by above-described embodiment and Difenoconazole complex preparation constant product quality are tested, knotFruit sees the following form 2.
Data by table 2 can find out, in embodiment 8,9,10,11,12,13,14, and degradation after heat storage, and useThe embodiment 1,2,3,4,5,6,7 of preferred promoter is before heat storage and after heat storage, and quality is all good, and preferred promoter is in product qualityPlay key effect.
Effect experiment
1, the oxime bacterium ester of being prepared by above-described embodiment and Difenoconazole complex preparation control wheat glume blight situation are carried outThe test of pesticide effectiveness. This EE carries out in this locality, and contrast medicament is 50% trifloxystrobin water dispersible granule (commercial), 10% phenyl ether methyl cyclicAzoles water dispersible granules (commercial).
Test in wheat glume blight early stage (heading stage), with the spraying of workers and peasants-16 type knapsack hand sprayer cauline leaf,Dispenser in every 7 days once, is sprayed medicine three times altogether. Be watered 450kg by per hectare preparation and be equipped with liquid. Dispenser was fine the same day, daily mean temperature23 DEG C, relative humidity 50%, after medicine, 48h is interior without rainfall. Before dispenser and after dispenser for the third time, within 7 days, investigate the disease number of sheets and disease index,Finally calculate prevention effect.
Preventive effect computational methods are:
Above-described check plot is clear water check plot, does not spray medicament.
Duration of test, in test scope of medication, complex preparation of the present invention has no adverse effects to wheat, and experimental result is as followsShown in:
As can be seen from Table 3, after oxime bacterium ester and Difenoconazole are composite, can effectively prevent and treat the generation of wheat glume blight, controlEffect is all better than contrasting medicament. Wherein, use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiment, andWheat glume blight preventive effect is reached more than 90%; Other embodiment preventive effects, in 80% left and right, are also better than contrasting medicament.
2, the oxime bacterium ester of being prepared by above-described embodiment and Difenoconazole complex preparation control banana freckle situation are carried outThe test of pesticide effectiveness, this EE is in Haikou City, Hainan Province, and contrast medicament is 50% trifloxystrobin water dispersible granule (commercial), 10% phenylateMethyl cyclic-azole water dispersible granules (commercial).
Test in banana freckle early stage, with the spraying of workers and peasants-16 type knapsack hand sprayer cauline leaf, within every 7 days, executeMedicine once, is total to dispenser 3 times, and dispenser was fine the same day, 27 DEG C of daily mean temperatures, and after medicine, 48h is interior without rainfall. Before dispenser and dispenser for the third timeWithin latter 7 days, investigate the disease number of sheets and disease index, finally calculate prevention effect.
Preventive effect computational methods are as follows:
Above-described check plot is clear water check plot, does not spray medicament.
Duration of test, in test scope of medication, complex preparation of the present invention has no adverse effects to banana, and result of the test is as follows:
As can be seen from Table 4, after oxime bacterium ester and Difenoconazole are composite, can effectively prevent and treat the generation of banana freckle, controlEffect is all better than contrasting medicament. Wherein, use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiment, andBanana freckle preventive effect is reached more than 90%; Other embodiment preventive effects, in 80% left and right, are also better than contrasting medicament.
3, oxime bacterium ester, the Difenoconazole complex preparation prepared by above-described embodiment are prevented and treated powdery mildew of cucumber situation and are carried out medicineEffect test. This EE carries out in locality, and contrast medicament is 50% trifloxystrobin water dispersible granule (commercial), 10% DifenoconazoleWater dispersible granules (commercial).
Test in powdery mildew of cucumber early stage, with the spraying of workers and peasants-16 type knapsack hand sprayer cauline leaf, within every 7 days, executeMedicine once, is total to dispenser 3 times, and dispenser was fine the same day, 27 DEG C of daily mean temperatures, and after medicine, 48h is interior without rainfall. Before dispenser and dispenser for the third timeWithin latter 7 days, investigate the disease number of sheets and disease index, finally calculate prevention effect.
Preventive effect computational methods are as follows:
Above-described check plot is clear water check plot, does not spray medicament.
Duration of test, in test scope of medication, complex preparation of the present invention has no adverse effects to cucumber, and result of the test is as follows:
As can be seen from Table 5, after oxime bacterium ester and Difenoconazole are composite, can effectively prevent and treat the generation of powdery mildew of cucumber, anti-Control effect and be all better than contrasting medicament. Wherein, use the embodiment preventive effect of preferred promoter and proportioning will obviously be better than other embodiment,And powdery mildew of cucumber preventive effect is reached more than 90%; Other embodiment preventive effects, in 80% left and right, are also better than contrasting medicament.
Claims (7)
1. containing a bactericidal composition for oxime bacterium ester and Difenoconazole, it is characterized in that: formulation is water dispersible granules, by weighing belowThe component composition of amount percentage: active constituents of medicine 30%-70%, dispersant 4-10%, wetting agent 2-10%, disintegrant 1-20%, fill outMaterial surplus, described active constituents of medicine comprises that weight ratio is oxime bacterium ester and the Difenoconazole of 1-10: 1-10;
Dispersant by polycarboxylate sodium and calcium lignosulfonate in mass ratio 2:1 mix, wetting agent is by dodecyl sulphateSodium and sodium lignin sulfonate in mass ratio 1:1 mix, and disintegrant is 1.5:1 mixing by ammonium sulfate and urea in mass ratioBecome, filler is white carbon.
2. bactericidal composition according to claim 1, is characterized in that: the weight ratio of oxime bacterium ester and Difenoconazole is 1-5:1-5。
3. bactericidal composition according to claim 1, is characterized in that: the weight ratio of oxime bacterium ester and Difenoconazole is 1-2.5:1-2.5。
4. bactericidal composition according to claim 1, is characterized in that: composition is by the component group of following percentage by weightBecome: active constituents of medicine 30%-70%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus.
5. bactericidal composition according to claim 4, is characterized in that: composition is by the component group of following percentage by weightBecome: active constituents of medicine 40%-60%, dispersant 4.5%, wetting agent 2%, disintegrant 12.5%, filler surplus.
6. in claim 1-5, the bactericidal composition containing oxime bacterium ester and Difenoconazole described in any one is done at control grainApplication in thing, vegetables, fruit diseases.
7. application according to claim 6, is characterized in that: described disease is glume blight, powdery mildew or scab.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005036963A1 (en) * | 2003-09-23 | 2005-04-28 | Bayer Cropscience Aktiengesellschaft | Concentrated suspensions |
| CN102246765A (en) * | 2011-07-27 | 2011-11-23 | 南宁市德丰富化工有限责任公司 | Composite bactericide containing trifloxystrobin |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
| CN102657179A (en) * | 2012-04-26 | 2012-09-12 | 杭州宇龙化工有限公司 | Sterilization composition containing phenylate diazole and trifloxystrobin |
| CN103348987A (en) * | 2013-07-31 | 2013-10-16 | 河北博嘉农业有限公司 | Film-spreading oil agent capable of preventing and curing rice banded sclerotial blight |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005036963A1 (en) * | 2003-09-23 | 2005-04-28 | Bayer Cropscience Aktiengesellschaft | Concentrated suspensions |
| CN102246765A (en) * | 2011-07-27 | 2011-11-23 | 南宁市德丰富化工有限责任公司 | Composite bactericide containing trifloxystrobin |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
| CN102657179A (en) * | 2012-04-26 | 2012-09-12 | 杭州宇龙化工有限公司 | Sterilization composition containing phenylate diazole and trifloxystrobin |
| CN103348987A (en) * | 2013-07-31 | 2013-10-16 | 河北博嘉农业有限公司 | Film-spreading oil agent capable of preventing and curing rice banded sclerotial blight |
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Effective date of registration: 20171116 Address after: No. 8, Hai Pu North Road, New River ecological and chemical technology industry base in Pingdu City, Qingdao, Shandong Patentee after: Qingdao run agricultural chemical Co., Ltd. Address before: Haiyuan Binhai Economic Development Zone, Shandong province Weifang city 262737 Street No. 600 Patentee before: Shandong Weifang Rainbow Chemical Co., Ltd. |
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