CN102217638A - Pesticide composition for preventing and treating plant virus diseases - Google Patents

Pesticide composition for preventing and treating plant virus diseases Download PDF

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Publication number
CN102217638A
CN102217638A CN2011101069763A CN201110106976A CN102217638A CN 102217638 A CN102217638 A CN 102217638A CN 2011101069763 A CN2011101069763 A CN 2011101069763A CN 201110106976 A CN201110106976 A CN 201110106976A CN 102217638 A CN102217638 A CN 102217638A
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Prior art keywords
copper
moroxydine hydrochloride
hydroxyquinolinate
pesticide composition
plant virus
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CN102217638B (en
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吴培军
王睿
陈佛祥
王礼文
朱刚
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CHENGDU KELILONG BIOCHEMICAL CO LTD
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CHENGDU KELILONG BIOCHEMICAL CO LTD
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Abstract

The invention relates to a pesticide composition for preventing and treating plant virus diseases. The pesticide composition comprises two active components of moroxydine hydrochloride and oxine-cooper, wherein a weight part ratio of the moroxydine hydrochloride to the oxine-cooper is 10:1-1:5. According to a combination of the two active components of the pesticide composition provided by the present invention, a synergistic effect is provided, control efficiency is improved, generation of the plant virus resistance is delayed, the use amount of the pesticide is reduced, such that cost is reduced and environmental pollution is decreased.

Description

A kind of composition pesticide that is used to prevent and treat the viroses of plant
Technical field
The composition pesticide that the present invention relates to is to be active ingredient with Moroxydine Hydrochloride and copper 8-hydroxyquinolinate, is applicable to and prevents and treats the viroses of plant on the agricultural.
Background technology
Virus disease is the important disease of a class that harms the crops, and, control difficulty great because of endangering has the title of plant cancer.In recent years, the viroses of plant endanger more and more serious on fruits and vegetables, flowers and diversified economy crop, widely used agent for preventing and treating plant virus example hydrochloric acid moroxydine copper acetate, tiger glue adipic acid copper Moroxydine Hydrochloride, hot bacterium amine salt acid moroxydine etc. on producing at present, long-term use has caused plant virus that it has been produced stronger resistance, dosage and cost constantly increase, for this reason, develop a kind of novel plant prevention and cure of viruses composition and seem very urgent.
Moroxydine Hydrochloride, english common name moroxydine hydrochloride is a kind of wide spectrum, low toxicity agent for prevention and control of virus.After soup after the dilution sprayed application to plant leaf surface, medicament can enter in the plant corpus by the aqueous vapor hole, suppressed or destroy the formation of nucleic acid and lipoprotein, stoped the reproduction process of virus, played the effect of control virus.
Copper 8-hydroxyquinolinate, english common name oxine-copper is generated by the reaction of 8--oxyquinoline and copper sulphate, can suppress G-protein synthetic of cellular expression, suppresses the metabolism of germ spore, and the control cell divides once more and breaks up.
Summary of the invention
Technical problem to be solved: in order to satisfy the needs of agricultural production, make full use of two kinds of composite synergy that produce of active component and complementation, the actual preventive effect of raising and delay the speed that viral pesticide resistance produces, the invention provides a kind of efficient, low toxicity, environmental protection and help the agent for preventing and treating plant virus of viral resistance management, be used to prevent and treat the crop disease viral disease.
For addressing the above problem, the inventor finds that by a large amount of biologicall test screenings Moroxydine Hydrochloride and copper 8-hydroxyquinolinate are composite with certain proportion, and (TMV) has synergistic function to tobacco mosaic virus disease.
Technical scheme: the present invention is an active ingredient with Moroxydine Hydrochloride and copper 8-hydroxyquinolinate, and the ratio of quality and the number of copies of Moroxydine Hydrochloride and copper 8-hydroxyquinolinate is 10:1~1:5, and all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element.
The present composition is prepared into known method and is fit to any one formulation that agricultural goes up use, reasonable formulation is water dispersible granules, suspending agent or suspended emulsion, wetting powder, aqueous emulsion or microemulsion, and the active ingredient total content is 5%~80% in the preparation.
The auxiliary agent that uses in the present composition comprises that solvent, dispersant, stabilizing agent, emulsifier, antifreezing agent, thickener etc. and other are of value to active ingredient stablizes and bring into play drug effect in preparation known substance, all be the various compositions of using or allow use in the pesticidal preparations always, be not particularly limited, concrete composition and consumption require to determine by simple test according to prescription.
Product described in the invention can finished product preparation form provide, promptly each material mixes in the composition, the form that the composition of composition also can single agent provides, and directly mixes in jar or bucket before the use, is diluted to needed concentration then.The frequency of administration of the present composition and amount of application change with weather condition and crop state variation, can reach the control requirement by using suitable formulation.
The present composition is applicable to control crop disease viral disease.
Beneficial effect: compared with prior art, beneficial effect of the present invention is: 1, two kinds of active ingredients of Moroxydine Hydrochloride and copper 8-hydroxyquinolinate are composite has a synergistic effect, has improved control efficiency.2, delay the pesticide resistance of plant virus.3, two kinds of active ingredients of Moroxydine Hydrochloride and copper 8-hydroxyquinolinate are composite, reduced the agricultural chemicals usage amount, thereby reduced cost and the pollution that has reduced environment.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage more short and sweet, the present invention describes with following specific embodiment, but the present invention only limits to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to describe the present invention, can not be interpreted as the restriction to scope of the present invention.Should be pointed out that all any modifications of being made within the spirit and principles in the present invention, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.
The inventor is by a large amount of screening tests, the abundant method of utilization Sun Yun is carried out the synergistic effect analysis of different proportionings to Moroxydine Hydrochloride and copper 8-hydroxyquinolinate composition, discovery is in certain ratio range, and Moroxydine Hydrochloride and copper 8-hydroxyquinolinate combination have synergistic function to tobacco mosaic virus (TMV) disease.
Embodiment 1: Moroxydine Hydrochloride and oxine-copper composite are to the Toxicity Determination and the prescription screening of tobacco mosaic virus disease
Test material: pick up from the sick leaf of tobacco mosaic virus disease in field, preservation was standby after laboratory grinding filtration obtained virus filtration liquid.
Test method: adopt conventional method the present composition (Moroxydine Hydrochloride, copper 8-hydroxyquinolinate) to be carried out indoor synergy test indoor.Calculate dense EC in the inhibition with method of least squares 50(95% confidence limit) calculates co-toxicity coefficient (CTC) with the abundant method of Sun Yun again.
Co-toxicity coefficient (CTC) 〉=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80<co-toxicity coefficient (CTC)<120 shows as summation action.
Figure 123287DEST_PATH_IMAGE001
Table 1 is the different disposal Toxicity Determination result sick to capsicum tobacco mosaic virus (TMV).
Figure 750709DEST_PATH_IMAGE002
Measurement result shows that Moroxydine Hydrochloride and copper 8-hydroxyquinolinate have obvious synergistic effect between proportioning 10:1~1:5, and co-toxicity coefficient (is seeing Table 1) more than 140.
Composition of the present invention can be made agricultural with known method and go up any one formulation that can process of using.
Below describe with specific embodiment.So the percentage in the prescription all is weight percentage.The various preparation processing technologies of the present composition are prior art, can change to some extent according to different situations.
Embodiment 2:80% Moroxydine Hydrochloride copper 8-hydroxyquinolinate water dispersible granules.
Moroxydine Hydrochloride 56.5%, copper 8-hydroxyquinolinate 23.5%, lauryl sodium sulfate (wetting agent) 5%, polycarboxylate (dispersant) 3%, sodium chloride (disintegrant) 2%, polyethylene glycol (binding agent) 3%, soluble starch (stabilizing agent) 3%, kaolin (carrier) complements to 100%.Dry pulverization process, granulation, drying, screening preparation system promptly get 80% Moroxydine Hydrochloride copper 8-hydroxyquinolinate water dispersible granules in proportion with above-mentioned prescription.
This embodiment is used to prevent and treat the capsicum tobacco mosaic virus disease, and 80% Moroxydine Hydrochloride copper 8-hydroxyquinolinate water dispersible granules effective ingredient consumption, 210 gram/hectares are converted water spray, and 10 days preventive effects are 88.6% behind the medicine; 80% Moroxydine Hydrochloride water dispersible granules effective ingredient consumption, 1200 gram/hectares are converted water spray, and 10 days preventive effects are 80.4% behind the medicine; 33.5% copper 8-hydroxyquinolinate suspending agent effective ingredient consumption, 300 gram/hectares are converted water spray, behind the medicine 10 days 62.1%.80% Moroxydine Hydrochloride copper 8-hydroxyquinolinate water dispersible granules control capsicum tobacco mosaic virus disease effect is excellent 80% Moroxydine Hydrochloride water dispersible granules and 33.5% copper 8-hydroxyquinolinate suspending agent obviously, because pharmacy control efficacy improves, the compound drug effective ingredient consumption reduces, reduced drug cost, delay viral drug-fast generation, reduced environmental pollution, the mixture drug effect is better than single agent.
Embodiment 3:40% Moroxydine Hydrochloride copper 8-hydroxyquinolinate suspending agent.
Moroxydine Hydrochloride 35%, copper 8-hydroxyquinolinate 5%, methyl naphthalene sulfonate formaldehyde condensate (wetting agent) 10%, the newborn 600# phosphate of farming (dispersant) 3%, xanthans (thickener) 1%, ethylene glycol (antifreeze) 4%, soluble starch (stabilizing agent) 3%, deionized water complements to 100%.Above-mentioned prescription is mixed in proportion, after grinding, high shear, promptly make 40% Moroxydine Hydrochloride copper 8-hydroxyquinolinate suspending agent.
This embodiment is used to prevent and treat the marmor upsilon disease, and 40% Moroxydine Hydrochloride copper 8-hydroxyquinolinate suspending agent effective ingredient consumption, 400 gram/hectares are converted water spray, and 10 days preventive effects are 89.1% behind the medicine; 80% Moroxydine Hydrochloride water dispersible granules effective ingredient consumption, 1200 gram/hectares are converted water spray, and 10 days preventive effects are 82.7% behind the medicine; 33.5% copper 8-hydroxyquinolinate suspending agent effective ingredient consumption, 300 gram/hectares are converted water spray, behind the medicine 10 days 66.0%.The sick effect of 40% Moroxydine Hydrochloride copper 8-hydroxyquinolinate suspending agent control marmor upsilon is excellent 80% Moroxydine Hydrochloride water dispersible granules and 33.5% copper 8-hydroxyquinolinate suspending agent obviously, because pharmacy control efficacy improves, the compound drug effective ingredient consumption reduces, reduced drug cost, delay viral drug-fast generation, reduced environmental pollution, the mixture drug effect is better than single agent.

Claims (4)

1. a composition pesticide that is used to prevent and treat the viroses of plant is characterized in that active ingredient is Moroxydine Hydrochloride and copper 8-hydroxyquinolinate.
2. a kind of composition pesticide that is used to prevent and treat the viroses of plant according to claim 1, it is characterized in that: the ratio of weight and number of Moroxydine Hydrochloride and copper 8-hydroxyquinolinate is: 10:1~1:5.
3. a kind of composition pesticide that is used to prevent and treat the viroses of plant according to claim 1 and 2 is characterized in that: Moroxydine Hydrochloride and the percentage by weight of copper 8-hydroxyquinolinate weight summation in composition are 5%~80%.
4. a kind of composition pesticide that is used to prevent and treat the viroses of plant according to claim 1 and 2 is characterized in that: be used to prevent and treat the viroses of plant.
CN 201110106976 2011-04-27 2011-04-27 Pesticide composition for preventing and treating plant virus diseases Active CN102217638B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102696677A (en) * 2012-06-15 2012-10-03 郑州郑氏化工产品有限公司 Medicament composition for preventing maize rough dwarf disease
CN102696654A (en) * 2012-05-31 2012-10-03 利尔化学股份有限公司 Composition having antiviral action, pesticide and application thereof
CN103798272A (en) * 2012-11-14 2014-05-21 陕西汤普森生物科技有限公司 Bactericidal composition containing pyraclostrobin and moroxydine hydrochloride
CN113907079A (en) * 2021-11-10 2022-01-11 西南大学 Application of chloralkanoyl fluoroquinolone in preparing medicine for preventing and treating citrus canker

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1057158A (en) * 1991-04-13 1991-12-25 王非传 Prevention and cure agent for plant virus diseases
CN1086959A (en) * 1992-11-19 1994-05-25 蒋炳生 A kind of viroses of plant prophylactic and manufacture method thereof
CN1148933A (en) * 1996-10-07 1997-05-07 石家庄曙光制药厂 Soluble prophylactico-therapeutic agent for plant virus
CN1325625A (en) * 2001-06-06 2001-12-12 章阿恩 Application of oxine-copper in agricultural disinfectant and its product
CN1505932A (en) * 2002-12-12 2004-06-23 河北省农林科学院植物保护研究所 Plant viral disease preventing and controlling agent and its prepn process
CN1618288A (en) * 2003-11-20 2005-05-25 齐齐哈尔四友化工有限公司 Agent for treating and preventing plant virus diseases
CN101591205A (en) * 2009-07-02 2009-12-02 郭红甫 A kind of medicament-fertilizer mixture of preventing and treating crop virosis
CN101785464A (en) * 2010-03-25 2010-07-28 青岛瀚生生物科技股份有限公司 Oxine-copper composite bactericide

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1057158A (en) * 1991-04-13 1991-12-25 王非传 Prevention and cure agent for plant virus diseases
CN1086959A (en) * 1992-11-19 1994-05-25 蒋炳生 A kind of viroses of plant prophylactic and manufacture method thereof
CN1148933A (en) * 1996-10-07 1997-05-07 石家庄曙光制药厂 Soluble prophylactico-therapeutic agent for plant virus
CN1325625A (en) * 2001-06-06 2001-12-12 章阿恩 Application of oxine-copper in agricultural disinfectant and its product
CN1505932A (en) * 2002-12-12 2004-06-23 河北省农林科学院植物保护研究所 Plant viral disease preventing and controlling agent and its prepn process
CN1618288A (en) * 2003-11-20 2005-05-25 齐齐哈尔四友化工有限公司 Agent for treating and preventing plant virus diseases
CN101591205A (en) * 2009-07-02 2009-12-02 郭红甫 A kind of medicament-fertilizer mixture of preventing and treating crop virosis
CN101785464A (en) * 2010-03-25 2010-07-28 青岛瀚生生物科技股份有限公司 Oxine-copper composite bactericide

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102696654A (en) * 2012-05-31 2012-10-03 利尔化学股份有限公司 Composition having antiviral action, pesticide and application thereof
CN102696677A (en) * 2012-06-15 2012-10-03 郑州郑氏化工产品有限公司 Medicament composition for preventing maize rough dwarf disease
CN103798272A (en) * 2012-11-14 2014-05-21 陕西汤普森生物科技有限公司 Bactericidal composition containing pyraclostrobin and moroxydine hydrochloride
CN103798272B (en) * 2012-11-14 2016-01-13 陕西汤普森生物科技有限公司 The bactericidal composition of a kind of pyraclostrobin-containing and Moroxydine Hydrochloride
CN113907079A (en) * 2021-11-10 2022-01-11 西南大学 Application of chloralkanoyl fluoroquinolone in preparing medicine for preventing and treating citrus canker

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