CN106818778A - A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition - Google Patents
A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition Download PDFInfo
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- CN106818778A CN106818778A CN201710073933.7A CN201710073933A CN106818778A CN 106818778 A CN106818778 A CN 106818778A CN 201710073933 A CN201710073933 A CN 201710073933A CN 106818778 A CN106818778 A CN 106818778A
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- Prior art keywords
- benzothiostrobin
- adipic acid
- acid copper
- glue adipic
- pesticide composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
- A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal pesticide composition containing benzothiostrobin and tiger glue adipic acid copper, comprising active ingredient benzothiostrobin and tiger glue adipic acid copper and conventional auxiliary element, the weight ratio of benzothiostrobin and tiger glue adipic acid copper is 1:20‑40:1.Show by substantial amounts of indoor and outdoor tests, a kind of composition of present invention offer is simple, safe, easy to use and can greatly improve the sterilized mixture preparation of plant part resistance against diseases, not only significantly improve preventive effect, reduce pesticide dosage, and fungicidal spectrum can be expanded, germicidal efficiency is improved, especially there is good preventive effect to cucumber bacterial angular leaf spot, cucumber downy mildew.
Description
Technical field
The invention discloses a kind of bactericidal pesticide composition, particularly relate to a kind of fertile containing benzothiostrobin and amber glue
The bactericidal pesticide composition of sour copper, belongs to field of pesticide preparation.
Background technology
Benzothiostrobin（benzothiostrobin）, chemical name is (E) -2- [2- (5- methoxybenzothiazole -2- sulphur
Methyl) phenyl] -3- methoxybenzene e pioic acid methyl esters, it is a kind of new Qo1 series bactericidal agents, its mechanism of action is that a class prevents disease
Electron transmission between opportunistic pathogen cytochrome b and c1, the compound for disturbing its respiration and ATP synthesis.With wide sterilization spectrum,
The advantages of bactericidal activity is high, amount of application is low, the lasting period is long, has treatment and protective effect concurrently, especially white to cucumber downy mildew, cucumber
Powder disease have strong bacteriostatic activity, also shows good prevention effect in field, for scab, anthracnose, gray mold,
Corn southern leaf blight, false smut, banana blight, banana sigatoka leaf spot disease also have excellent inhibitory activity.
（Benzothiostrobin structural formula）.
Tiger glue adipic acid copper（Copper (succinate+glutarate+adipate)), chemical name：Succinic acid copper, glutaric acid
Copper, hexanedioic acid copper, are a kind of bactericide of high-efficiency low-toxicity broad spectrum activity, the sun on its mechanism of action copper ion and cause of disease mycoderm surface
Ion exchange, makes the protein coagulating on edge bacterium cell membrane, at the same part copper ion penetrate into pathogen it is intracellular and certain
A little enzymes are combined, and influence its activity.Can be used to prevent and treat cucumber bacterial angular leaf spot, false smut, and have stimulation to plant growth.
However, when agricultural chemicals is repeatedly used alone with not scientifical use, its medicine phase extension, consumption is increased, and causes high cost,
It is unfavorable for the popularization and application in production.Such as angular leaf spot fungus etc. have generated resistance to some conventional medicaments, under causing preventive effect
Drop, disease is rampant, and drug cost increase and increasing environmental pollution are caused therewith frequently dispenser is caused again.
It is simple, safe, easy to use the invention provides a kind of composition in order to overcome the above-mentioned deficiency of prior art
And the sterilized mixture preparation of plant part resistance against diseases can be greatly improved, and preventive effect is not only significantly improved, pesticide dosage is reduced, and can
Expand fungicidal spectrum, improve germicidal efficiency.
The content of the invention
It is an object of the invention to provide a kind of benzothiostrobin and the synergistic complex bactericidal pesticide composition of tiger glue adipic acid copper.
Another object of the present invention is to prevent and treat bacterial angular leaf spot, downy mildew, false smut, leaf blight, anthracnose, black star
Disease, powdery mildew, epidemic disease, gray mold, blight dis-ease, leaf spot, rice blast, banded sclerotial blight.
The technical proposal of the invention is realized in this way：
A kind of bactericidal pesticide composition, it is characterised in that active component includes benzothiostrobin and tiger glue adipic acid copper, wherein, benzene thiophene
The weight ratio of bacterium ester and tiger glue adipic acid copper is 1:50~50:1, it is preferably 1: 20~40:1.
Further, the weight ratio in the bactericidal pesticide composition shared by active constituent content is 1 ~ 90%, preferably 10
~70%。
Further, bactericidal pesticide composition of the invention can by user using it is preceding through dilute or directly use.
Further, bactericidal pesticide composition of the invention is aided with auxiliary element by conventional by by pesticide activity component
Preparation method be made any one formulation in Pesticide formulation, selected from wettable powder, aqueous emulsion, microemulsion, can divide
Dissipate any one in oil-suspending agent, microcapsule suspending agent, water dispersible granules, suspending agent.
Further, auxiliary agent of the present invention have dispersant, wetting agent, disintegrant, binding agent, defoamer, antifreeze,
Thickener.
Further, composition of the invention can also add other agricultural active compositions, for example bactericide, insecticide,
The agricultural active composition such as herbicide, fertilizer.
Compared with prior art, advantages of the present invention is：
1st, the synergy measurement result of benzothiostrobin of the present invention and tiger glue adipic acid copper mixture bactericidal pesticide composition shows,
Sterilized virulence to bacterial angular leaf spot, downy mildew is stronger, and both compound has obvious synergistic function, and kill rate is high.
2nd, after benzothiostrobin of the present invention and tiger glue adipic acid copper mixture, benzothiostrobin biological bactericide is not only maintained
Many merits, and the dosage of mixture is reduced, drug effect is improved, and reduces use cost.
3rd, after benzothiostrobin of the present invention and tiger glue adipic acid copper mix, best of breed ratio can reach anti-with low usage amount
The optimal effectiveness of effect, reduce peasant household using mu into and use cost, reduced while reaching top gain, and reduce usage amount
Harm to environment.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.As described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the limitation to the scope of the claims of the present invention.It should be pointed out that it is all it is of the invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be determined by the appended claims.
First, example of formulations
1st, embodiment 1：18% benzothiostrobin tiger glue adipic acid copper wettable powder（5:1）
Benzothiostrobin 15%
Tiger glue adipic acid copper 3%
Naphthalenesulfonate formaldehyde condensation compound（NNO） 10%
Aluminium-magnesium silicate 3%
Lauryl sodium sulfate 4%
Diatomite surplus
The preparation method of the wettable powder is：Active component and auxiliary material are stirred by the formula, using air-flow powder
Broken method processing, sieving, you can wettable powder of the present invention is obtained.
2nd, embodiment 2:28% benzothiostrobin tiger glue adipic acid copper granule（5:2）
Benzothiostrobin 20%
Tiger glue adipic acid copper 8%
Cornstarch 10%
Polyvinyl alcohol 5%
Ethanol 2%
Sodium lignin sulfonate 12%
Kaolin surplus
The preparation method of the granule is：It is well mixed according to the formula active component and other auxiliary agents, using high pressure spray
The mode of mist is uniformly sprayed onto on load weighted kaolin, after being sufficiently stirred for absorption, screening, you can particle of the present invention is obtained
Agent.
3rd, embodiment 3:39% benzothiostrobin tiger glue adipic acid aqueous emulsion of copper（3:10）
Benzothiostrobin 9%
Tiger glue adipic acid copper 30%
2 hexylene glycol [2,4] 2%
Solvent naphtha 5%
Alkyl phenol formaldehyde resin polyoxyethylene ether（Nongru-700 #） 10%
AEO（AEO-5） 8%
Water surplus
The preparation method of the aqueous emulsion is：After being well mixed according to the formula active component and other auxiliary agents, cut through high speed
After cutting emulsification, you can aqueous emulsion of the present invention is obtained.
4th, embodiment 4：15% thiophene bacterium ester tiger glue adipic acid copper water dispersion granula（1:2）
Benzothiostrobin 5%
Tiger glue adipic acid copper 10%
Triethanolamine 8%
Sodium Benzoate 2%
Polyoxyethylene poly-oxygen propylene aether 5%
Ammonium sulfate 5%
Dispersant NNO 3.5%
Water surplus
The preparation method of the water dispersible granules：Active component and other auxiliary agents are well mixed inlet air flow powder according to the formula
It is broken, in mixer, spray into and mediate agent deionized water, mediation devices parameter carries out extruder grain, dries, after screening, you can system
Obtain water dispersible granules of the present invention.
5th, embodiment 4:33% benzothiostrobin tiger glue adipic acid copper microcapsule suspending agent（10:1）
Benzothiostrobin 30%
Tiger glue adipic acid copper 3%
Ethylenediamine 6.5%
Sodium lignin sulfonate 8%
Xanthans 4%
Potassium sorbate 3%
Propane diols 4.5%
Urea resin prepolymer 23%
Water surplus
The preparation method of the microcapsule suspending agent is：According to it is described formula first active component is dissolved in dimethylbenzene, then by its
Its auxiliary agent mixes, and is well mixed in mixing kettle, and adding urea resin prepolymer carries out elevated cure, adds deionized water
With other auxiliary agents, make particle diameter below 5 microns, you can microcapsule suspending agent of the present invention is obtained.
6th, embodiment 6:21% benzothiostrobin tiger glue adipic acid copper suspending agent（1：20）
Benzothiostrobin 1%
Tiger glue adipic acid copper 20%
AEO（AEO-5） 13%
Hexylene glycol 7%
Polycarboxylate 6%
Naphthalenesulfonate formaldehyde condensation compound（NNO） 5%
Dispersing agent MF 5%
Epoxychloropropane 1.5%
Arabic gum 3%
Deionized water surplus
The preparation method of the suspending agent is：First other auxiliary agents are mixed according to the formula, is well mixed in mixing kettle, so
Benzothiostrobin and tiger glue adipic acid copper are added afterwards, is sanded 2-3 times in sand mill, then be pumped into mixing in mixing kettle, make particle diameter 5
Micron is following, you can suspending agent of the present invention is obtained.
2nd, toxicity is determined
1st, to the Toxicity Determination of cucumber bacterial angular leaf spot
After determining effective inhibition concentration of benzothiostrobin and tiger glue adipic acid copper through prerun experiment, each medicament is set by active ingredient
Different disposal group.Cucumber bacterial angular leaf spot germ, picks up from Guangzhou, Guangdong from area Liang Kou towns are changed and gathers the bacillary angle of cucumber
Pinta blade, separates by conventional organization partition method, is verified according to Koch's Postulates, is transferred to after separation on LP culture mediums
It is placed in 4 DEG C of refrigerators and saves backup.
After determining the effective inhibition concentration scope of each medicament through prerun, medicament is respectively provided with various dose by active constituent content
Treatment, if blank.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, surveyed using mycelial growth rate method
Determine virulence of the medicament to crop germ.Colony diameter is determined with crossing method after 72h, each treatment net growth, mycelia is calculated
Growth inhibition ratio.
Prevention effect is converted into probit value（y）, liquor strength（μg/mL）It is converted into logarithm value（x）, asked with least square method
Concentration EC in obtaining virulence regression equation and suppressing50.The toxicity index and common poison of two medicament different ratios are calculated according to the abundant methods of Sun Yun
Coefficient（CTC）.
If co-toxicity coefficient CTC≤80, composition shows as antagonism；If 80<CTC<120, then composition show as
Summation action；If CTC >=120, composition shows as synergistic effect.
The benzothiostrobin of different ratio is shown in tiger glue adipic acid copper to the Toxicity Determination result of cucumber bacterial angular leaf spot
Table 1.
As can be seen from the table, the bacillary angle of cucumber is prevented and treated as active ingredient carries out compounding with benzothiostrobin and tiger glue adipic acid copper
Pinta, mass ratio is 1:40-40:Co-toxicity coefficient is more than 120 in the range of 1, with synergistic effect.Mass ratio is 5:When 1, altogether
Malicious coefficient CTC values are more than 250, and synergistic function is obvious.
2nd, the Toxicity Determination to cucumber downy mildew of benzothiostrobin and tiger glue adipic acid copper compounding
After determining effective inhibition concentration of benzothiostrobin and tiger glue adipic acid copper through prerun experiment, each medicament is set by active ingredient
Different disposal group, reference《Farm-chemical indoor determination test rule-bactericide》Carry out, medicine is determined using mycelial growth rate method
Agent measures colony diameter after 72 h to the virulence of crop germ with crossing method, calculates each treatment net growth, mycelial growth
Inhibiting rate.
Prevention effect is converted into probit value（y）, liquor strength（μg/mL）It is converted into logarithm value（x）, asked with least square method
Concentration EC in obtaining virulence regression equation and suppressing50.The toxicity index and common poison of two medicament different ratios are calculated according to the abundant methods of Sun Yun
Coefficient（CTC）.
If co-toxicity coefficient CTC≤80, composition shows as antagonism；If 80<CTC<120, then composition show as
Summation action；If CTC >=120, composition shows as synergistic effect.
The benzothiostrobin of different ratio the results are shown in Table 2 with tiger glue adipic acid copper to the Toxicity Determination of cucumber downy mildew.
As can be seen from the table, cucumber downy mildew is prevented and treated as active ingredient carries out compounding with benzothiostrobin and tiger glue adipic acid copper,
Mass ratio is 1:20-40:Co-toxicity coefficient is more than 120 in the range of 1, with synergistic effect.Mass ratio is 5:When 2, poison is altogether
Number CTC values are more than 200, and synergistic function is obvious.
3rd, field control effectiveness test
1st, the field control effectiveness test of angular leaf spot of cucumber is prevented and treated
In order to further verify practical application effect of the invention, preventing and treating cucumber angle spot is carried out using the medicament of the embodiment of the present invention
Sick field control effectiveness test.
Reagent agent：（1）18% benzothiostrobin tiger glue adipic acid copper wettable powder（5:1）；（2）28% benzothiostrobin amber
Glue adipic acid copper granule（5:2）；（3）39% benzothiostrobin tiger glue adipic acid aqueous emulsion of copper（3：10）；（4）15% benzothiostrobin amber
Glue adipic acid copper water dispersion granula（1:2）；（5）33% benzothiostrobin tiger glue adipic acid copper microcapsule suspending agent（10:1）；（6）21% benzene thiophene
Bacterium ester tiger glue adipic acid copper suspending agent（1：20）；（7）Comparative example 1：20% benzothiostrobin suspending agent；（8）Comparative example 2:30% amber glue
Adipic acid copper wettable powder.
Experiment in Guangzhou from changing area Liang Kou towns cucumber ground, the first time dispenser on the 4th of August in 2015, August 10 day in 2015 the
Secondary dispenser, altogether dispenser 2 times, check plot spray equivalent clear water.When making up a prescription, after first medicament is fully diluted with a small amount of water, add
Suitable quantity of water carries out complete stool spraying treatment, even spraying.Respectively at 7 days after last medicine, investigation in 14 days disease indexs and calculate preventive effect,
Result of the test is as shown in table 3.
Table of field test results is bright, after benzothiostrobin and the bactericidal pesticide composition preparation medicine of tiger glue adipic acid copper 7,14 days it is right
The preventing and treating of cucumber bacterial angular leaf spot is more than 80%, hence it is evident that be better than the preventive effect of single active component.In addition, during dispenser not
It was found that the composition pesticide has poisoning to produce cucumber crop, it was demonstrated that composition pesticide security of the invention is also preferable.
2nd, the field control effectiveness test of cucumber downy mildew is prevented and treated
In order to further verify practical application effect of the invention, carry out preventing and treating cucumber downy mildew using the medicament of the embodiment of the present invention
Sick field control effectiveness test.
Reagent agent：（1）18% benzothiostrobin tiger glue adipic acid copper wettable powder（5:1）；（2）28% benzothiostrobin amber
Glue adipic acid copper granule（5:2）；（3）39% benzothiostrobin tiger glue adipic acid aqueous emulsion of copper（3：10）；（4）15% benzothiostrobin amber
Glue adipic acid copper water dispersion granula（1:2）；（5）33% benzothiostrobin tiger glue adipic acid copper microcapsule suspending agent（10:1）；（6）21% benzene thiophene
Bacterium ester tiger glue adipic acid copper suspending agent（1：20）；（7）Comparative example 1：20% benzothiostrobin suspending agent；（8）Comparative example 2:30% amber glue
Adipic acid copper wettable powder.
Experiment is carried out in Qingyuan City Fugang County head town cucumber, and dispenser is administered to 2016 6 twice, for the first time altogether for experiment
The moon 10, on June 15th, 2016, check plot spray equivalent clear water are administered to for the second time.It is first with a small amount of water that medicament is abundant when making up a prescription
After dilution, adding suitable quantity of water carries out complete stool spraying treatment, even spraying.Respectively at 7 days after last medicine, 14 days investigation the state of an illness refer to
Preventive effect is counted and calculates, result of the test is as shown in table 4.
Table of field test results is bright, after benzothiostrobin and the bactericidal pesticide composition preparation medicine of tiger glue adipic acid copper 7,14 days it is right
The preventing and treating of cucumber downy mildew is more than 80%, hence it is evident that be better than the preventive effect of single active component.In addition, not finding institute during dispenser
Stating composition pesticide has poisoning to produce cucumber crop, it was demonstrated that composition pesticide security of the invention is also preferable.
Claims (7)
1. a kind of bactericidal pesticide composition, it is characterised in that active component is benzothiostrobin and tiger glue adipic acid copper.
2. bactericidal pesticide composition according to claim 1, it is characterised in that active component includes benzothiostrobin and amber glue
Adipic acid copper, wherein, the weight ratio of benzothiostrobin and tiger glue adipic acid copper is 1:50~50:1, it is preferably 1: 20~40:1.
3. in bactericidal pesticide composition described in bactericidal pesticide composition according to claim 1 shared by active constituent content
Weight ratio is 1 ~ 90%, preferably 10 ~ 70%.
4. bactericidal pesticide composition according to claim 1 bactericidal pesticide composition of the invention by by pesticide activity into
Divide and be aided with any one formulation that auxiliary element is made up in Pesticide formulation of conventional preparation method, selected from wettable powder
Agent, aqueous emulsion, microemulsion, dispersible any one in oil-suspending agent, microcapsule suspending agent, water dispersible granules, suspending agent.
5. bactericidal pesticide composition according to claim 3, composition of the invention can also add other agricultural actives
The agricultural active composition such as composition, such as bactericide, Insecticides (tech) ＆ Herbicides (tech), fertilizer.
6. the bactericidal pesticide composition in claim 1-5 described in any one claim is used in answering for preventing and treating corps diseases
With.
7. application according to claim 6, it is characterised in that the corps diseases application is the bacillary angle spot of preventing and treating
Disease, downy mildew, false smut, leaf blight, anthracnose, scab, powdery mildew, epidemic disease, gray mold, blight dis-ease, leaf spot, rice blast
Disease, banded sclerotial blight.
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| CN201710073933.7A CN106818778A (en) | 2017-02-10 | 2017-02-10 | A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition |
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| CN201710073933.7A CN106818778A (en) | 2017-02-10 | 2017-02-10 | A kind of benzothiostrobin and tiger glue adipic acid copper bactericidal pesticide composition |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105580805A (en) * | 2014-11-16 | 2016-05-18 | 陕西美邦农药有限公司 | Pesticide composition containing copper (succinate + glutarate + adipate) |
| CN105580817A (en) * | 2014-11-14 | 2016-05-18 | 陕西美邦农药有限公司 | Pesticide composition containing copper (succinate + glutarate + adipate) |
| CN105660638A (en) * | 2014-11-18 | 2016-06-15 | 陕西美邦农药有限公司 | Bactericidal composition containing copper(succinate+glutarate+adipate) and strobilurin |
| CN105660636A (en) * | 2014-11-17 | 2016-06-15 | 陕西美邦农药有限公司 | Bactericidal composition containing copper(succinate+glutarate+adipate) |
-
2017
- 2017-02-10 CN CN201710073933.7A patent/CN106818778A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105580817A (en) * | 2014-11-14 | 2016-05-18 | 陕西美邦农药有限公司 | Pesticide composition containing copper (succinate + glutarate + adipate) |
| CN105580805A (en) * | 2014-11-16 | 2016-05-18 | 陕西美邦农药有限公司 | Pesticide composition containing copper (succinate + glutarate + adipate) |
| CN105660636A (en) * | 2014-11-17 | 2016-06-15 | 陕西美邦农药有限公司 | Bactericidal composition containing copper(succinate+glutarate+adipate) |
| CN105660638A (en) * | 2014-11-18 | 2016-06-15 | 陕西美邦农药有限公司 | Bactericidal composition containing copper(succinate+glutarate+adipate) and strobilurin |
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Application publication date: 20170613 |