CN107864966A - A kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim - Google Patents

A kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim Download PDF

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Publication number
CN107864966A
CN107864966A CN201711280046.3A CN201711280046A CN107864966A CN 107864966 A CN107864966 A CN 107864966A CN 201711280046 A CN201711280046 A CN 201711280046A CN 107864966 A CN107864966 A CN 107864966A
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benzene metsulfovax
azoles mepanipyrim
bactericidal composition
composition containing
azoles
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詹敏敏
冯亚东
廖永
张东辉
柴明根
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JIANGXI HEYI CHEMICALS Co Ltd
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JIANGXI HEYI CHEMICALS Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim, its active ingredient is benzene metsulfovax and azoles mepanipyrim, and the mass ratio of benzene metsulfovax and azoles mepanipyrim is 1:50‑50:1, remaining is to allow to use and acceptable auxiliary element in agricultural chemicals.Bactericidal composition of the present invention can be prepared into suspending agent, wettable powder, water dispersible granules, microemulsion, aqueous emulsion, granule and suspension seed-coating agent with known method.The present composition has obvious synergistic effect, and available for the plurality of plant diseases on the crops such as preventing and treating vegetables, melon and fruit, be particularly suitable for use in preventing and treating downy mildew, late blight and powdery mildew.

Description

A kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim
Technical field
The present invention relates to bactericidal composition technical field, specially a kind of sterilization group containing benzene metsulfovax Yu azoles mepanipyrim Compound.
Background technology
Benzene metsulfovax, chemical name：[[(6- fluoro benzothiazole -2- bases)-ethylaminocarbonyl] -2- methyl-propyls] ammonia Base isopropyl formate.Benzene metsulfovax are to be killed by Japanese combinatorial chemistry company and Ihara companies in the new of joint development in 1992 Microbial inoculum, its active site are substitution fluorine atom and amino acid peptide structure on phenyl ring, and the compound has very high selectivity, main right The late blight and downy mildew that crop is triggered by Oomycete germ have good prevention effect and therapeutic activity.
Azoles mepanipyrim, english common name：Ametoctradin, chemical name：5- ethyl -6- heptyl [1,2,4] triazole [1,5] pyrimidine -7- amine, molecular formula：C15H25N5, molecular weight：275.39 CA accession number：865318-97-4, vapour pressure：2.1 X 10-07 mPa (25oC), fusing point：198 DEG C, solubility in water：0.15 mg l-1(20oC), methanol：7200mg·l-1 （(20oC), toluene：100 mg·l-1,(20oC), ethyl acetate：800 mg·l-1(20oC), acetone：1900 mg·l-1 (20oC).Azoles mepanipyrim is brand-new triazolo pyrimidine series bactericidal agent, belongs to mitochondrial inhibitors, to downy mildew class and phytophthora class oomycetes Guiding principle fungi has control action, has extremely strong residual activity and rain wash resistance, to the downy mildew and phytophthora root rot of various crops With it is good the effect of.
In recent years, due to single drug and unscientific application method, many kinds of pathogens such as powdery mildew, downy mildew are caused Bacterium etc. generates resistance to many currently used agricultural chemicals, and the resistance to the action of a drug is increasingly severe, while formulation rate after resistance generation With the increase of spraying times, not only increase cost accounting, and aggravated environmental pollution, turn into chemical prevention one is big Problem.Therefore, it is badly in need of microbicide compositions efficiently, environmentally friendly, less toxic.Benzene metsulfovax and the mechanism of action of azoles mepanipyrim bactericide Difference, mutually compound in the range of on one point and expand fungicidal spectrum, improve the bactericidal effect of bactericide, avoid or delay disease drug resistance Generation, be advantageous to the integrated control of crop disease.In summary, the Bactericidal composite containing benzene metsulfovax Yu azoles mepanipyrim is developed Thing is significant.
Benzene metsulfovax and the bactericidal composition of azoles mepanipyrim there is no to report at present.
The content of the invention
It is above-mentioned to solve it is an object of the invention to provide a kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim The problem of being proposed in background technology.
To achieve the above object, the present invention provides following technical scheme：A kind of killing containing benzene metsulfovax and azoles mepanipyrim Bacteria composition, its active ingredient are benzene metsulfovax and azoles mepanipyrim, and the mass ratio of benzene metsulfovax and azoles mepanipyrim is 50:1-1: 50。
Preferably, the mass ratio of active ingredient benzene metsulfovax and azoles mepanipyrim is 20:1-1:20.
Preferably, active ingredient benzene metsulfovax and gross mass percentage composition of the azoles mepanipyrim in bactericidal composition are 1%- 90%。
Preferably, the formulation of the bactericidal composition is using suspending agent, wettable powder, water dispersible granules, microemulsion, water Any one in emulsion, granule and suspension seed-coating agent.
Preferably, the bactericidal composition is used to prevent and treat the plurality of plant diseases on the crops such as vegetables, melon and fruit, especially suitable In preventing and treating downy mildew, late blight and powdery mildew.
Compared with prior art, the beneficial effects of the invention are as follows：The present invention bactericidal composition on one point in the range of have very Good synergistic effect, prevention effect significantly improves compared with single dose；Field dosage can be greatly decreased in the present invention, reduce life Production and use cost, reduce residues of pesticides, are advantageous to the sustainable development of environment；Have in bactericidal composition disclosed by the invention It is different to imitate the mechanism of action of composition, is advantageous to avoid or delays the generation of disease drug resistance；In addition, the present invention can also expand it is anti- Spectrum is controlled, while crop downy mildew, late blight and powdery mildew is prevented and treated, virosis can be prevented and treated.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
Bactericidal composition of the present invention using bactericidal composition of the present invention using benzene metsulfovax as a kind of active ingredient, with azoles mepanipyrim For another active ingredient, the combination between them has obvious synergistic function to downy mildew, late blight and powdery mildew, Rather than just the simple addition of two kinds of drug actions, specifically it is illustrated with following biologicall test example.
The Toxicity Determination of Assays Example 1, benzene metsulfovax and azoles mepanipyrim compounding to cucumber downy mildew
Subjects：Cucumber downy mildew germ
This experiment uses pot-culture method.Dipped to pick up from artificial climate room under 10 DEG C or so of distillation washing with writing brush and carry downy mildew The sporangium at the cucumber leaves back side of germ, is made into 2.0-3 × 105Individual sporangium/mL suspension.Choose two of growing way unanimously Piece leaf period cucumber seedling, each processing supply examination melon seedling from 5 basins, sprayed with Potter spray towers under 50PSI pressure, each place Manage about 5mL.Each medicament sets 5 concentration gradients, and blank control is used as to spray equivalent clear water.Sprayed after chemicals treatment 24h Mist is inoculated with bacterium of downy mildew of cucumber sporangia suspension, and cucumber seedling is placed in growth cabinet after inoculation（Relative humidity 100%, temperature 15-20 DEG C of degree）Cultivate, 16-24 DEG C of keeping temperature, the moisturizing of relative humidity 90% or so induction after 24h, the state of an illness is investigated after 5 days and is referred to Number, and calculate prevention effect.
Grade scale
0 grade：Blade disease-free spot；
1 grade：Lesion area accounts for less than the 5% of full wafer leaf area；
3 grades：Lesion area accounts for the 6%-10% of full wafer leaf area；
5 grades：Lesion area accounts for the 11%-25% of full wafer leaf area；
7 grades：Lesion area accounts for the 26%-50% of full wafer leaf area；
9 grades：Lesion area accounts for full wafer leaf area more than 50%.
Drug effect computational methods：
Disease index (%)=
Prevention effect (%)=
Prevention effect is converted into niqueMin (y), and liquor strength (μ g/mL) is converted into logarithm value (x), and poison is calculated with least square method Concentration EC in power equation and suppression50, according to the toxicity index and co-toxicity coefficient (CTC) of the abundant method calculating medicaments of Sun Yun.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100
B in A percentage composition+B medicament toxicity index × mixture in theoretical toxicity index (TTI)=A medicament toxicity index × mixture Percentage composition
Co-toxicity coefficient (CTI)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
When CTC≤80, then composition shows as antagonism, when 80<CTC<120, then composition show as summation action, when CTC >=120, then composition show as synergistic effect.
Toxicity Determination result is referring to table 1
The benzene metsulfovax of table 1 compound the Toxicity Determination result to cucumber downy mildew with azoles mepanipyrim
Result of the test shows, benzene metsulfovax and azoles mepanipyrim compounding preventing and treating cucumber downy mildew, matches 50:1-1:When between 50, Co-toxicity coefficient has certain synergistic effect all more than 120.0, and matches 10:1-1:When between 10, co-toxicity coefficient is high In 200.0, synergistic effect becomes apparent from.
The Toxicity Determination of Assays Example 2, benzene metsulfovax and azoles mepanipyrim compounding to tomato late blight
Subjects：Tomato late blight germ
This experiment uses pot-culture method.Tomato is potted plant when growing to 2-4 leaf periods, and numbering is standby.Experiment is existed with pathogen Cultivated on suitable culture medium, after sporangium to be generated, sporangium is washed down with sterilized water, filtered with double gauze, it is made 1 × 105Individual sporangium/mL suspension.According to agent activity, 5-7 series mass concentration is set.Decoction is uniformly sprayed in leaf Treat that decoction natural air drying is standby to whole wettings in face.Often handle 3 basins, 4 repetitions, and set containing only solvent and surfactant and Blank control is made in processing without active ingredient.After chemicals treatment 24h, with crops sprayer, uniformly sprinkling connects on tomato leaf Kind.After inoculation, cultivated 7 days under conditions of 18-20 DEG C of temperature, relative humidity more than 90%.Count the disease on every plant of tomato leaf Spot area, investigation prevention effect.Often handling at least 30 leaves of investigation, stage division is：
0 grade：Blade disease-free spot；
1 grade：Only a small amount of small scab, lesion area account for less than the 10% of full wafer leaf area on blade；
3 grades：Lesion area accounts for the 10%-25% of full wafer leaf area on blade；
5 grades：Lesion area accounts for the 26%-50% of full wafer leaf area on blade；
7 grades：Lesion area accounts for more than the 50% of full wafer leaf area on blade；
9 grades：Full leaf morbidity is withered.
Drug effect calculating, toxicity index and co-toxicity coefficient（CTC）Calculate, analysis method is same as above.
Toxicity Determination result is referring to table 2
The benzene metsulfovax of table 2 compound the Toxicity Determination result to tomato late blight with azoles mepanipyrim
Result of the test shows, benzene metsulfovax and azoles mepanipyrim compounding preventing and treating tomato late blight, matches 50:1-1:When between 50, Co-toxicity coefficient has certain synergistic effect all more than 120.0, and matches 10:1-1:When between 10, co-toxicity coefficient is high In 200.0, synergistic effect becomes apparent from.
The Toxicity Determination of Assays Example 3, benzene metsulfovax and azoles mepanipyrim compounding to cucumber powdery mildew's pathogen
Subjects：Cucumber powdery mildew's pathogen
This experiment uses pot-culture method.Potted plant to grow to 4-5 piece true leaves, numbering is standby.Caused by morbidity cucumber leaves in 24h Powdery Mildew Fresh spores are uniformly shaken off to be inoculated in on examination cucumber seedling.According to agent activity, set 5-7 series mass dense Degree.After inoculation 24 hours, decoction is uniformly sprayed in blade face to whole wettings, treat that decoction natural air drying is standby.Often handle 3 basins, 4 Secondary repetition, and set the processing for not containing effect composition containing only solvent and surfactant and make blank control.Examination material after inoculation moves Into growth cabinet（Relative humidity 100%, 20 ± 2 DEG C of temperature）Culture 7 days.Lesion area on the every basin cucumber leaves of statistics, Disease index is investigated, and calculates prevention effect.
Grade scale
0 grade：Blade disease-free spot；
1 grade：Lesion area accounts for less than the 5% of full wafer leaf area；
3 grades：Lesion area accounts for the 6%-15% of full wafer leaf area；
5 grades：Lesion area accounts for the 16%-25% of full wafer leaf area；
7 grades：Lesion area accounts for the 26%-50% of full wafer leaf area；
9 grades：Lesion area accounts for full wafer leaf area more than 50%.
Drug effect calculating, toxicity index and co-toxicity coefficient（CTC）Calculate, analysis method is same as above.
Toxicity Determination result is referring to table 3
The benzene metsulfovax of table 3 compound the Toxicity Determination result to cucumber powdery mildew's pathogen with azoles mepanipyrim
Result of the test shows, benzene metsulfovax and azoles mepanipyrim compounding preventing and treating cucumber powdery mildew's pathogen, matches 50:1-1:Between 50 When, co-toxicity coefficient has certain synergistic effect all more than 120.0, and matches 10:1-1:When between 10, co-toxicity coefficient 200.0 are above, synergistic effect becomes apparent from.
Above measurement result shows that benzene metsulfovax prevent and treat cucumber downy mildew, Phytophthora infestans with a kind of compounding in azoles mepanipyrim The proportioning of disease and powdery mildew of cucumber is 50:1-1:When between 50, co-toxicity coefficient all more than 120.0 there is certain synergy to make With, and match 10:1-1:When between 10, more than 200.0, synergistic effect becomes apparent from co-toxicity coefficient.
Combination sterilization composition of the present invention can be prepared into suspending agent, the wettable of suitable agricultural use with known method Pulvis, water dispersible granules, microemulsion, aqueous emulsion, granule and suspension seed-coating agent.Illustrated, matched somebody with somebody with specific embodiment below Percentage is mass percent in side, and benzene metsulfovax active compound effective content is 95%, azoles mepanipyrim active compound effective content is 98%.
Suspending agent embodiment
Ratio by each components such as pesticide active ingredient, dispersant, wetting agent, thickener, defoamer, antifreezing agent and water in formula It is well mixed, half product is obtained after sand mill wet method sand milling, benefit, which is mixed with water to filter, after analysis produces suspending agent.
Embodiment 1:40% benzene metsulfovax azoles mepanipyrim suspending agent
Benzene metsulfovax 10%, azoles mepanipyrim 30%, ethylene glycol（Antifreezing agent）5%th, pull open powder（Wetting agent）1.5%th, lignin sulfonic acid Sodium（Dispersant）2%th, polycarboxylate（Dispersant）2%th, xanthans（Thickener）0.1%th, sodium benzoate（Preservative）0.2%th, it is organic Silicon defoaming agent（Defoamer）0.1%th, deionized water polishing is to 100%.
Embodiment 2:30% benzene metsulfovax azoles mepanipyrim suspending agent
Benzene metsulfovax 26%, azoles mepanipyrim 4%, ethylene glycol（Antifreezing agent）5%th, pull open powder（Wetting agent）2%th, sodium lignin sulfonate （Dispersant）3%th, xanthans（Thickener）0.1%th, aluminium-magnesium silicate（Thickener）0.5%th, sodium benzoate（Preservative）0.2%th, it is organic Silicon defoaming agent（Defoamer）0.1%th, deionized water polishing is to 100%.
Embodiment 3:10.2% benzene metsulfovax azoles mepanipyrim suspending agent
Benzene metsulfovax 0.2%, azoles mepanipyrim 10%, ethylene glycol（Antifreezing agent）5%th, pull open powder（Wetting agent）1.5%th, lignin sulfonic acid Sodium（Dispersant）5%th, xanthans（Thickener）0.15%th, aluminium-magnesium silicate（Thickener）1%th, sodium benzoate（Preservative）0.2%th, it is organic Silicon defoaming agent（Defoamer）0.1%th, deionized water polishing is to 100%.
Embodiment 4:45% benzene metsulfovax azoles mepanipyrim suspending agent
Benzene metsulfovax 40%, azoles mepanipyrim 5%, ethylene glycol（Antifreezing agent）5%th, pull open powder（Wetting agent）1.5%th, sodium lignin sulfonate （Dispersant）2%th, polycarboxylate（Dispersant）3%th, xanthans（Thickener）0.1%th, sodium benzoate（Preservative）0.2%th, organosilicon Defoamer（Defoamer）0.1%th, deionized water polishing is to 100%.
Wettable powder embodiment
Pesticide active ingredient, auxiliary agent and filler are well mixed in the ratio of formula, remix to obtain after air-flow crushing wettable Property pulvis.
Embodiment 5:11% benzene metsulfovax azoles mepanipyrim wettable powder
Benzene metsulfovax 1%, azoles mepanipyrim 10%, lauryl sodium sulfate（Wetting agent）2%th, Negel（Dispersant）2%、 Sodium lignin sulfonate（Dispersant）4%th, white carbon（Filler）10%th, kaolin（Filler）Polishing is to 100%.
Embodiment 6:51% benzene metsulfovax azoles mepanipyrim wettable powder
Benzene metsulfovax 50%, azoles mepanipyrim 1%, Negel（Dispersant）1%th, sodium lignin sulfonate（Dispersant）1%th, gather Carboxylate（Dispersant）2%th, white carbon（Filler）5%th, kaolin（Filler）Polishing is to 100%.
Embodiment 7:20% benzene metsulfovax azoles mepanipyrim wettable powder
Benzene metsulfovax 15%, azoles mepanipyrim 5%, lauryl sodium sulfate（Wetting agent）1%th, Negel（Dispersant）2%、 White carbon（Filler）5%th, kaolin（Filler）Polishing is to 100%.
Water dispersible granules embodiment
Pesticide active ingredient, auxiliary agent and filler are well mixed in the ratio of formula, wettable powder is obtained after air-flow crushing, then Add a certain amount of water, through mediate, be granulated, dry, sieve be made water dispersible granules.
Embodiment 8:51% benzene metsulfovax azoles mepanipyrim water dispersible granules
Benzene metsulfovax 1%, azoles mepanipyrim 50%, lauryl sodium sulfate（Wetting agent）2%th, Negel（Dispersant）3%、 Sodium lignin sulfonate（Dispersant）5%th, polycarboxylate（Dispersant）2%th, ammonium sulfate（Disintegrant）5%th, kaolin（Filler）Polishing is extremely 100%。
Embodiment 9:70% benzene metsulfovax azoles mepanipyrim water dispersible granules
Benzene metsulfovax 60%, azoles mepanipyrim 10%, lauryl sodium sulfate（Wetting agent）4%th, sodium lignin sulfonate（Dispersant） 7%th, Negel（Dispersant）3%th, polycarboxylate（Dispersant）2%th, ammonium sulfate（Filler）Polishing is to 100%.
Microemulsion embodiment
Pesticide active ingredient is dissolved in solvent and cosolvent, adds surfactant, it is well mixed to obtain microemulsion.
Embodiment 10:30% benzene metsulfovax azoles mepanipyrim microemulsion
Benzene metsulfovax 22%, azoles mepanipyrim 8%, 1-METHYLPYRROLIDONE（Solvent）5%th, phenethyl phenol polyoxyethylene method（Emulsification Agent）5%th, calcium dodecyl benzene sulfonate（Emulsifying agent）5%th, castor oil polyoxyethylene ether（Emulsifying agent）5%th, deionized water polishing is extremely 100%。
Aqueous emulsion embodiment
Pesticide active ingredient is dissolved in solvent and cosolvent, adds surfactant, it is well mixed to obtain oil phase；Will be water-soluble Property the component such as component and deionized water be mixed to prepare aqueous phase, then oil phase is added in aqueous phase, stirring while adding, high speed shear is allowed to Aqueous emulsion is obtained as homogeneous emulsion.
Embodiment 11:24% benzene metsulfovax azoles mepanipyrim aqueous emulsion
Benzene metsulfovax 20%, azoles mepanipyrim 4%, ethylene glycol（Antifreezing agent）5%th, 1-METHYLPYRROLIDONE（Solvent）5%th, cyclohexanone （Solvent）9%th, phenethyl phenol polyoxyethylene method（Emulsifying agent）7%th, calcium dodecyl benzene sulfonate（Emulsifying agent）5%th, deionized water polishing To 100%.
Granule embodiment
Pesticide active ingredient, various auxiliary agents and filler etc. are well mixed in the ratio of formula, after air-flow crushing, add humic Acid and carrier, are granulated to obtain granule using comminutor.
Embodiment 12:1% benzene metsulfovax azoles mepanipyrim granule
Benzene metsulfovax 0.5%, azoles mepanipyrim 0.5%, AEO（Emulsifying agent）1%th, 1-METHYLPYRROLIDONE（It is molten Agent）1%th, zinc sulfate（Nutrient）3%th, humic acid（Organic matter）50%th, bentonite（Carrier）Polishing is to 100%.
Suspension seed-coating agent embodiment
Ratio by each components such as pesticide active ingredient, dispersant, wetting agent, thickener, defoamer, antifreezing agent and water in formula It is well mixed, half product is obtained after sand mill wet method sand milling, the well mixed filtering of water, film forming agent and colouring agent is added after analysis Produce suspension seed-coating agent.
Embodiment 13:11% benzene metsulfovax azoles mepanipyrim suspension seed-coating agent
Benzene metsulfovax 10%, azoles mepanipyrim 1%, ethylene glycol（Antifreezing agent）5%th, sodium methylene bis-naphthalene sulfonate（Wetting agent）1%th, it is wooden Plain sodium sulfonate（Dispersant）3%th, polycarboxylate（Dispersant）1%th, xanthans（Thickener）0.15%th, aluminium-magnesium silicate（Thickener）1%、 Polyvinyl alcohol（PVA）(film forming agent) 0.5%, solvent red（HRR）（Colouring agent）2%th, sodium benzoate（Preservative）0.2%th, organosilicon disappears Infusion（Defoamer）0.1%th, deionized water polishing is to 100%.
Field information example 1：Benzene metsulfovax compound the field control effectiveness test to uncinula necator with azoles mepanipyrim
Subjects：Uncinula necator
Test medicine and dosage are shown in Table 4, often handle 4 cells and repeat, each 20 square metres of plot area.In disease early period of origination Carry out first time dispenser, even spraying, be sprayed onto untill blade drips, using clear water processing as blank control.The medicine of spray in every 10 days, Share medicine 3 times.The incidence of 10 days investigation uncinula necators before first time medicine and after third time medicine.Each cell uses five Point sampling, every is investigated two plants, and every plant of all blades of investigation, the percentage that whole leaf area is accounted for lesion area is remembered to be classified Carry.Calculate each processing disease index and prevention effect.Grade scale：
0 grade：Disease-free spot；
1 grade：Lesion area accounts for less than the 5% of whole leaf area；
3 grades：Lesion area accounts for the 6%-15% of whole leaf area；
5 grades：Lesion area accounts for the 16%-25% of whole leaf area；
7 grades：Lesion area accounts for the 26%-50% of whole leaf area；
9 grades：Lesion area accounts for whole leaf area more than 50%；
Drug effect computational methods：
Disease index=
Prevention effect（%）=
Field test results are shown in Table 4
The benzene metsulfovax of table 4 compound the field test results to uncinula necator with azoles mepanipyrim
As can be seen that benzene metsulfovax, azoles mepanipyrim single dose are respectively to the preventive effect of uncinula necator from the result of the test of table 4 76.21%th, 73.51%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, minimum preventive effect is 88.08%, It has been up to 92.45%.The result of field test fully shows, to uncinula necator after benzene metsulfovax and azoles mepanipyrim compounding With significant synergistic function, in the case where mu effective ingredient consumption is reduced compared with single dose, prevention effect greatly improves.Cause This, the present composition has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and residues of pesticides.
The present invention bactericidal composition on one point in the range of have good synergistic effect, prevention effect is obvious compared with single dose Improve；Field dosage can be greatly decreased in the present invention, reduce production and use cost, reduce residues of pesticides, be advantageous to The sustainable development of environment；The mechanism of action of active ingredient is different in bactericidal composition disclosed by the invention, be advantageous to avoid or Delay the generation of disease drug resistance；In addition, the present invention can also expand preventing and treating spectrum, in preventing and treating crop downy mildew, late blight and white While powder disease, virosis can be prevented and treated.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (9)

  1. A kind of 1. bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim, it is characterised in that：Its active ingredient is benzene metsulfovax With azoles mepanipyrim, the mass ratio of benzene metsulfovax and azoles mepanipyrim is 1:50-50:1.
  2. A kind of 2. bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 1, it is characterised in that：Have The mass ratio for imitating composition benzene metsulfovax and azoles mepanipyrim is 1:20-20:1.
  3. A kind of 3. bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 1, it is characterised in that：Have The mass ratio for imitating composition benzene metsulfovax and azoles mepanipyrim is 1:10-10:1.
  4. 4. a kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 1 or 2 or 3, its feature It is：Active ingredient benzene metsulfovax and gross mass percentage composition of the azoles mepanipyrim in bactericidal composition are 1%-90%.
  5. 5. a kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 1 or 2 or 3, its feature It is：Active ingredient benzene metsulfovax and gross mass percentage composition of the azoles mepanipyrim in bactericidal composition are 10%-70%.
  6. 6. a kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 1 or 2 or 3, its feature It is：Active ingredient benzene metsulfovax and gross mass percentage composition of the azoles mepanipyrim in bactericidal composition are 30%-50%.
  7. A kind of 7. bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 3, it is characterised in that：Institute The formulation for stating bactericidal composition uses suspending agent, wettable powder, water dispersible granules, microemulsion, aqueous emulsion, granule and suspension Any one in seed coat agent.
  8. A kind of 8. bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim, it is characterised in that：The bactericidal composition is used to prevent Control the plurality of plant diseases on the crops such as vegetables, melon and fruit.
  9. A kind of 9. bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim according to claim 8, it is characterised in that：Institute State composition and be applied to preventing and treating downy mildew, late blight and powdery mildew.
CN201711280046.3A 2017-12-06 2017-12-06 A kind of bactericidal composition containing benzene metsulfovax Yu azoles mepanipyrim Pending CN107864966A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101232814A (en) * 2005-07-27 2008-07-30 巴斯福股份公司 Fungicidal mixtures based on azolopyrimidinylamines
CN103688963A (en) * 2013-12-13 2014-04-02 广西田园生化股份有限公司 Ultra-low volume liquid containing ametoctradin composition and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101232814A (en) * 2005-07-27 2008-07-30 巴斯福股份公司 Fungicidal mixtures based on azolopyrimidinylamines
CN103688963A (en) * 2013-12-13 2014-04-02 广西田园生化股份有限公司 Ultra-low volume liquid containing ametoctradin composition and preparation method thereof

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Application publication date: 20180403