CN106689143A - Triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition and preparation method thereof - Google Patents
Triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition and preparation method thereof Download PDFInfo
- Publication number
- CN106689143A CN106689143A CN201611004189.7A CN201611004189A CN106689143A CN 106689143 A CN106689143 A CN 106689143A CN 201611004189 A CN201611004189 A CN 201611004189A CN 106689143 A CN106689143 A CN 106689143A
- Authority
- CN
- China
- Prior art keywords
- bactericide composition
- isocyanuric acid
- cyanuric acid
- bacterium azoles
- triflumizole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
Abstract
The invention discloses a triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition and a preparation method thereof. The triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition is characterized by comprising the following effective components based on total weight of the composition: 1-30% of Xinjunan, 1-30% of chloroisobromine cyanuric acid, 2-25% of an aid and 15-96% of packing. The preparation method comprises the following steps: adding the raw materials into an enamel stirring kettle, uniformly mixing, and performing air flow crushing or grinding, thereby obtaining the triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition of wettable powder or a suspending agent. As the triflumizole and the chloroisobromine cyanuric acid are matched for use, the composition has the characteristics of being low in toxin, low in residue, wide in insecticidal spectrum, good in lasting property, low in cost and particularly free of pollution in prevention and treatment, and is a relatively deal bactericide variety for preventing and treating diseases such as rice bacterial streak.
Description
Technical field
The present invention relates to a kind of synergic bactericide composition, show have stronger preventing and curing diseases to agricultural disease
Effect, can be applied to the multiple diseases such as preventing and treating bacterial leaf streak of rice, rice blast.The microbicide compositions are different from existing
Other microbicide compositions or agricultural chemicals single dose, using the conjunction of low toxicity highly effective pesticide fluorine bacterium azoles and chlorobromide isocyanuric acid both agricultural chemicals
Reason combination, can delay the generation of disease drug resistance, and safe using simple, prevention effect is good, and residual quantity is low environmentally safe,
Promote Crop securify and fine quality production, agricultural production and income is played an important role.
Background technology
Bacterial leaf streak of rice, rice blast are the important diseases of paddy rice, and the annual several hundred million mus of onset area, are China paddy rice
The serious hindrance of stable high yield.And it is developing direction and the struggle in agricultural plant protection field to realize the preventing and treating of rice disease harmless boilogical
Target.In recent years, although country prohibites and high-toxic pesticide is used on paddy rice, but because lacking in actual agricultural production process
Weary efficient disease control medicament and use high poison, the phenomenon of persistent pesticide also more universal, therefore, research and development are efficiently low
Poison, the novel agrochemical of low-residual are inevitable development trends.
Fluorine bacterium azoles belong to fluorine-containing imidazolyl heterocycle class efficiently, the systemic fungicide of low toxicity, low-residual, be sterol demethylation suppression
Preparation, has protection, treatment and eradicant action concurrently, is widely used in preventing and treating wheat class, vegetables, the powdery mildew of melon and fruit, rust, tea tree anthrax
Etc. disease, there is notable prevention effect to the powdery mildew and rice blast of various crop.But the fluorine bacterium azoles list of alone high content
Agent is of a relatively high in current use cost.
Chlorobromide isocyanuric acid（chloroisobromine cyanuric acid）Bacterium, fungi, virus tool to crop
There are strong killing, interior suction and protection dual-use function, the medicine is sprayed can at leisure discharge Cl and Br in crop surface, form time chlorine
Sour (HOCl) and bromic acid (HOBr), therefore with strong bactericidal action.Because alone chlorobromide isocyanuric acid is in Main Rice Diseases
The time limit of preventing and treating is more long, and the resistance to the action of a drug of crop disease has significant enhancing.
The content of the invention
The purpose of the present invention be directed at present efficiently, broad spectrum disease agricultural chemicals extremely lack and existing agricultural chemicals single dose exist
Various deficiencies, there is provided a kind of synergic bactericide composition with wettable powder or suspending agent as product forms, using low
The reasonable combination mixture of malicious highly effective pesticide fluorine bacterium azoles and chlorobromide isocyanuric acid both agricultural chemicals is used, and it had both retained the efficient agriculture of low toxicity
The broad-spectrum and the advantage good to the prevention effect of disease of medicine fluorine bacterium azoles and chlorobromide isocyanuric acid, can overcome lacking for presence again
Point, realizes the target of corps diseases non-environmental pollution control, reduces to other biological toxicity, reduces chemical substance in crops
Residual, expands fungicidal spectrum, reduces cost, will with adapt to that China used low toxicity highly effective pesticide production estimations such as paddy rice
Ask.
A kind of synergic bactericide composition takes following scheme to realize：A kind of synergic bactericide combination
Thing, it is characterised in that microbicide compositions are made up of active ingredient fluorine bacterium azoles and chlorobromide isocyanuric acid, composition preparing raw material weight
Amount percentage is that fluorine bacterium azoles content is 1~30%, and chlorobromide isocyanuric acid content is 1~30%, and auxiliary agent content is 2~25%, filler
Content is 15~96%.A kind of synergic bactericide composition is made suspending agent or wettable powder.
When this product formulation is wettable powder, described auxiliary agent auxiliary agent is by dispersant 1~20%, 1~5% group of wetting agent
Into dispersant uses lignosulfonates, NNO, one kind of pull open powder or any two or three mixture.Wherein, lignin
Sulfonate selects calcium lignosulfonate or sodium lignin sulfonate；Wetting agent uses sodium alkyl benzene sulfonate or alkyl benzene calcium sulfonate.Fill out
Material using silica-based, precipitated calcium carbonate, a kind of or mixture in white carbon, silica-based use potter's clay, kaolin and
Diatomite etc..
When this product formulation is suspending agent, by dispersion moisture agent 1~15%, antifreeze 0.3~3% increases described auxiliary agent
Thick dose 0.4~5%, defoamer 0.3~2% is constituted, and dispersion moisture agent uses polyoxyethylene tri-styryl phosphenylic acid salt, or alkane
Base naphthalene sulfonate, or one kind or mixture in APES；Antifreeze uses alcohols using antifreeze, from third
Glycol or glycerine or ethylene glycol；Thickener uses xanthans or aluminium-magnesium silicate；Defoamer uses organic silicon defoamer.Filler
Using water.
A kind of its preparation process of synergic bactericide composition：Fluorine bacterium azoles and chlorine bromine isocyanide are weighed by said ratio
Uric acid, auxiliary agent and filler, it is characterized in that first filling fluorine bacterium azoles, chlorobromide isocyanuric acid and auxiliary agent, filler in enamel stirred tank
Divide after being well mixed, after airslide disintegrating mill is crushed or sand mill grinds, remix uniform finished product, finished product meets or is higher than
Every compulsory index requirement of the country to wettable powder or suspending agent product.
Fluorine bacterium azoles of the present invention and chlorobromide isocyanuric acid Recompounded pesticide, low toxicity, low-residual, wide sterilization spectrum, synergy substantially, are prevented and treated
Effect is good, cost accounting reduction, is that preventing and treating bacterial leaf streak of rice does harm to ideal higher effective and lower toxic pesticide preparation variety.
The formulation that this microbicide compositions is made have production it is simple, efficiently, preparation low cost, environment compatibility is good etc. many excellent
Point.This microbicide compositions is different from existing other microbicide compositions, can delay drug-fast generation, reaches agriculture increasing
Product increases income the purpose with food safety production.
Specific embodiment
Further illustrate the present invention below with reference to embodiment, following embodiments be merely to illustrate the present invention and to the present invention
Without limitation.
Embodiment 1 is for determination chlorobromide isocyanuric acid with fluorine bacterium azoles different ratio consumption to Xanthomonas campestris pv. Oryzicola
Fungistatic effect, has carried out chlorobromide isocyanuric acid the indoor virulence of xanthomonas oryzae pv. oryzicola has been surveyed with fluorine bacterium azoles different ratio
It is fixed, respective concentration is made into according to percentage by weight in table, now result of the test is reported as follows：
The chlorobromide isocyanuric acid of table 1 is with fluorine bacterium azoles single dose and its mixture to Xanthomonas campestris pv. Oryzicola toxicity test result
Measurement result shows that chlorobromide isocyanuric acid matches mixtures with fluorine bacterium azoles with 8: 1~1: 8, can be compared with high inhibition paddy rice bacterium
The growth of property Population of Xanthomonas Oryzae Pv mycelia, and the synergy of 4: 1 ratio mixtures is most obvious.
The fluorine bacterium azoles chlorobromide isocyanuric acid wettable powder of embodiment 2 25%
Chlorobromide isocyanuric acid 20%
Fluorine bacterium azoles 5%
NNO（Dispersant）3%
Sodium lignin sulfonate（Dispersant）7%
Sodium alkyl benzene sulfonate（Dispersant）1%
White carbon（Filler） 65%
Material is weighed by above-mentioned part by weight, each material is sequentially added under agitation, crushed through airslide disintegrating mill and be stirred for mixing
After uniform, product is obtained, carry out preventing and treating bacterial leaf streak of rice field control effectiveness test, drug effect is preferable, to paddy bacterial bar
Pinta preventive effect is 80%.
10 days preventive effects after the fluorine bacterium azoles chlorobromide isocyanuric acid wettable powder of table 2 25% preventing and treating bacterial leaf streak of rice medicine
(%)
（Jiangsu Jiangdu）
The fluorine bacterium azoles chlorobromide isocyanuric acid suspending agent of embodiment 3 30%
Chlorobromide isocyanuric acid 24%
Fluorine bacterium azoles 6%
NPE（NP-9）（Dispersion moisture agent）8%
Propane diols（Antifreeze）1%
Xanthans（Thickener）1%
Organic silicon defoamer（SAG612）2%
Water（Filler）58%
Material is weighed by above-mentioned part by weight, after being uniformly mixed, is sanded through sand mill and is obtained product, carry out preventing and treating paddy rice
Bacterial stripe field control effectiveness test.
10 days preventive effects (%) after the fluorine bacterium azoles chlorobromide isocyanuric acid suspending agent of table 3 30% preventing and treating bacterial leaf streak of rice medicine
（Nanchang city）
Above measurement result shows that 30% fluorine bacterium azoles chlorobromide isocyanuric acid suspending agent exists to bacterial leaf streak of rice preventive effect
More than 83%, and with the remarkable advantage of harmless boilogical preventing and treating, beneficial to agricultural extension application.
Claims (7)
1. a kind of synergic bactericide composition, it is characterised in that containing active ingredient fluorine bacterium azoles, chlorobromide isocyanuric acid and help
Agent, filler, on the basis of the gross weight of composition, fluorine bacterium azoles content is 1~30%, and chlorobromide isocyanuric acid content is 1~30%,
Auxiliary agent content is 2~25%, and filer content is 15~96%.
2. a kind of synergic bactericide composition according to claim 1, it is characterised in that the fluorine bacterium azoles：Chlorine bromine
Isocyanuric acid=8: 1~1: 8, weight portion.
3. a kind of synergic bactericide composition according to claim 1, it is characterised in that the fluorine bacterium azoles：Chlorine bromine
Isocyanuric acid=1: 4, weight portion.
4. a kind of synergic bactericide composition according to claim 1, it is characterised in that the agent of described composition
Type is suspending agent or wettable powder.
5. a kind of synergic bactericide composition according to claim 4, it is characterised in that the auxiliary agent of wettable powder
By dispersant 1~20%, wetting agent 1~5% is constituted.
6. a kind of synergic bactericide composition according to claim 4, it is characterised in that the auxiliary agent of suspending agent by point
Wetting agent 1~15% is dissipated, antifreeze 0.3~3%, thickener 0.4~5%, defoamer 0.3~2% is constituted.
7. a kind of preparation method of synergic bactericide composition, it is characterised in that first by fluorine bacterium azoles, chlorobromide isocyanuric acid and
After auxiliary agent, filler are sufficiently mixed uniformly in enamel stirred tank, after airslide disintegrating mill is crushed or sand mill grinds, remix
Even finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611004189.7A CN106689143A (en) | 2016-11-15 | 2016-11-15 | Triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611004189.7A CN106689143A (en) | 2016-11-15 | 2016-11-15 | Triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106689143A true CN106689143A (en) | 2017-05-24 |
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| CN201611004189.7A Pending CN106689143A (en) | 2016-11-15 | 2016-11-15 | Triflumizole and chloroisobromine cyanuric acid-containing synergetic bactericide composition and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110521728A (en) * | 2019-09-20 | 2019-12-03 | 漯河市农业科学院 | A kind of microbicide compositions for wheat powdery mildew prevention and treatment |
-
2016
- 2016-11-15 CN CN201611004189.7A patent/CN106689143A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110521728A (en) * | 2019-09-20 | 2019-12-03 | 漯河市农业科学院 | A kind of microbicide compositions for wheat powdery mildew prevention and treatment |
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| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170524 |
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| WD01 | Invention patent application deemed withdrawn after publication |