CN104222090A - Bactericidal composition containing kasugamycin and oxine-copper, and application thereof - Google Patents
Bactericidal composition containing kasugamycin and oxine-copper, and application thereof Download PDFInfo
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- CN104222090A CN104222090A CN201410449654.2A CN201410449654A CN104222090A CN 104222090 A CN104222090 A CN 104222090A CN 201410449654 A CN201410449654 A CN 201410449654A CN 104222090 A CN104222090 A CN 104222090A
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- bactericidal composition
- copper
- kasugarnycin
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- disease
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- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 24
- MMUFAGXJPKNAHT-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1 MMUFAGXJPKNAHT-UHFFFAOYSA-N 0.000 title abstract 3
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 title abstract 3
- 201000010099 disease Diseases 0.000 claims abstract description 23
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 23
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 10
- 235000009566 rice Nutrition 0.000 claims abstract description 10
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 7
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims abstract description 6
- 241000207199 Citrus Species 0.000 claims abstract description 6
- 235000020971 citrus fruits Nutrition 0.000 claims abstract description 6
- 241000233866 Fungi Species 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 4
- 235000013311 vegetables Nutrition 0.000 claims abstract description 4
- 235000021307 Triticum Nutrition 0.000 claims abstract description 3
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 3
- 239000000375 suspending agent Substances 0.000 claims abstract description 3
- 240000007594 Oryza sativa Species 0.000 claims abstract 4
- 244000241235 Citrullus lanatus Species 0.000 claims abstract 2
- 241000209140 Triticum Species 0.000 claims abstract 2
- IURRXCRWRKQLGC-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 IURRXCRWRKQLGC-UHFFFAOYSA-N 0.000 claims description 11
- 241000894006 Bacteria Species 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 4
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- 241000233622 Phytophthora infestans Species 0.000 claims description 2
- 208000025865 Ulcer Diseases 0.000 claims description 2
- 231100000397 ulcer Toxicity 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 20
- 240000003768 Solanum lycopersicum Species 0.000 abstract description 7
- 241000196324 Embryophyta Species 0.000 abstract description 6
- 235000007688 Lycopersicon esculentum Nutrition 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 208000035143 Bacterial infection Diseases 0.000 abstract description 2
- 241000724205 Rice stripe tenuivirus Species 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 description 27
- 239000010949 copper Substances 0.000 description 27
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 20
- 241000282376 Panthera tigris Species 0.000 description 9
- ZCXLQZOQWCXFNN-UHFFFAOYSA-N copper;hexanedioic acid Chemical compound [Cu].OC(=O)CCCCC(O)=O ZCXLQZOQWCXFNN-UHFFFAOYSA-N 0.000 description 9
- 239000003292 glue Substances 0.000 description 9
- 239000003242 anti bacterial agent Substances 0.000 description 7
- 229940088710 antibiotic agent Drugs 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000006870 function Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 241000219109 Citrullus Species 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 241000186361 Actinobacteria <class> Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003864 humus Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229940120693 copper naphthenate Drugs 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- YWKVMGDEOUPQGN-UHFFFAOYSA-N ethyl 2-[4-[2-(3-hydroxy-1-azabicyclo[2.2.2]octan-3-yl)ethynyl]phenyl]acetate Chemical compound C1=CC(CC(=O)OCC)=CC=C1C#CC1(O)C(CC2)CCN2C1 YWKVMGDEOUPQGN-UHFFFAOYSA-N 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- -1 sodium alkyl benzene Chemical class 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 241000186046 Actinomyces Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000187747 Streptomyces Species 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000001720 action spectrum Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
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- 239000002131 composite material Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 229940084434 fungoid Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
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- 230000001988 toxicity Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of plant protection, and relates to a bactericidal composition containing kasugamycin, and application of the bactericidal composition. The bactericidal composition comprises another component, namely oxine-copper, wherein the mass ratio of kasugamycin to oxine-copper is (10 to 1)-(1 to 100). The bactericidal composition can be processed into wettable powder, water dispersible granules, an emulsion in water, a microemulsion and a suspending agent, and the sum of the mass of A and the mass of B accounts for 1-80% of the total mass of the preparation. The bactericidal composition can be used for controlling fungi and bacterial diseases of multiple plants such as rice, wheat, vegetables, fruit trees and the like, and especially has a good effect for the late blight and gray mold of tomatoes, rice stripe disease, rice blast, watermelon angular leaf spot disease and citrus canker.
Description
The application is the divisional application of " bactericidal composition containing kasugarnycin and application " application for a patent for invention, original application day: on July 26th, 2013, application number: 2013103178694
Technical field
The invention belongs to plant protection art, particularly relate to containing kasugarnycin with containing the agriculturally useful compositions of copper component, the present composition can effective controlling plant diseases.
Background technology
In recent years, due to single and not Scientific Usage of Drugs, damage by disease and insect has produced pesticide resistance in various degree, and causes environmental pollution and ecotope increasingly to destroy.Along with the raising of people's living standard and the enhancing of health perception, the manufacture and exploit of environmentally friendly agricultural chemicals progressively receives the concern of agricultural chemicals R&D worker, is the effective way of environmental protect, minimizing or delaying drug resistance and raising drug effect.Wherein, the research and development of highly efficiency compositional agent are especially one of focus of research containing farm antibiotics bactericidal composition.
Farm antibiotics, refers to and is produced by fermentable, had agricultural chemicals function, for agriculturally preventing and treating the secondary metabolite of the pests such as Pest organism mouse.The microorganisms such as actinomycetes, fungi, bacterium all can produce farm antibiotics, and wherein the farm antibiotics of actinomycetes generation is maximum.The many important farm antibiotics of current extensive use is all from streptomyces, be separated the actinomycetes obtained produce.Farm antibiotics is the earliest streptomycin, and has promoted antibiotic thus in application agriculturally, obtains and develop rapidly after 20 century 70s.Kasugarnycin is the metabolite that a kind of Actinomyces microaureus produces, belong to low toxicity farm antibiotics, it is a kind of interior absorption antibiotic formulations, permeability is strong also can be moved in plant corpus, instant effect after spray medicine, resistance of rainwater washing against, the lasting period is long, having prevention, treatment, growth regulating effect, is the favourable agents of the crop bacteriums such as control vegetables, melon and fruit and paddy rice and fungal disease.
Cupric active ingredient agricultural chemicals has good preventive and therapeutic effect to common fungoid and bacterial disease.Inventor finds, the composition of kasugarnycin and some copper agent has good synergy preventive effect to fungus and bacterium, and fungicidal spectrum is widened.At present, also do not find that kasugarnycin and copper agent are as the report of the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, fatty acid copper, Thiodiazole-copper, nitroacid copper, copper naphthenate, amino acid copper, copper acetate, amine sulfonic acid copper etc.
Summary of the invention
The object of the invention is environmental protect, expand action spectrum, minimizing or delaying drug resistance, raising drug effect, a kind of bactericidal composition and the application that contain kasugarnycin are provided.
The present invention is achieved through the following technical solutions:
Bactericidal composition containing kasugarnycin, it is characterized in that said composition includes A and B of effective amount, A is kasugarnycin, B is selected from the one in copper 8-hydroxyquinolinate, tiger glue adipic acid copper, Thiodiazole-copper, copper humate, nitroacid copper, copper naphthenate, amino acid copper, copper acetate, amine sulfonic acid copper, and the ratio of quality and the number of copies of A and B is 10:1-1:100.Preferably, the ratio of quality and the number of copies of A and B is 1:1-1:50.
Above-mentioned composition of the present invention is processed into wetting powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, and the percentage that A and B quality sum accounts for preparation gross mass is 1-80%.
Composition of the present invention can prevent and treat the fungus and bacterium disease of the various plants such as paddy rice, wheat, vegetables, fruit tree, and preferred disease is the late blight of tomato and gray mold, stripe disease and rice blast, watermelon angular leaf spot, citrus ulcer.
Composition of the present invention compared with prior art, produces following beneficial effect:
1, purposes is widened: composition can prevent and treat the multiple diseases of crops.
2, use cost is reduced: improve preventive effect because composition has, control spectrum increases, decrease Pesticide use number of times, reduce use cost.
3, pesticide resistance is delayed: the composition containing kasugarnycin and copper agent is that the component of different mechanism of action is composite, and disease not easily develops immunity to drugs.
4, environmental friendliness: to people and animals and non-target organism toxicity low, degraded is fast in the environment, and low-residual is free from environmental pollution.
Embodiment
Below described in embodiment only for explaining the present invention, for not departing from amendment that the present invention's spirit and principle make, replacement or improvement, all belong to the scope of protection of present invention.
Embodiment 1 15% kasugarnycin copper 8-hydroxyquinolinate water dispersible granules
By kasugarnycin 1g, copper 8-hydroxyquinolinate 14g, naphthalenesulfonate formaldehyde condensation compound 4g, sodium alkyl benzene sulfonate 1.5g, gum Arabic 0.5g, 100g mixing supplied by white carbon, mixture is carried out granulation after ultra-fine grinding, drying, screening, both 15% kasugarnycin copper 8-hydroxyquinolinate water dispersible granules.
Embodiment 2 30% kasugarnycin tiger glue adipic acid copper wetting powder
Kasugarnycin 1g, tiger glue adipic acid copper 29g, sodium lignin sulfonate 2g, white carbon are supplied 100g mixing, each component is dry, cooling, levigate, both must be mixed with 30% kasugarnycin tiger glue adipic acid copper wetting powder.
Embodiment 3 18% kasugarnycin Thiodiazole-copper water dispersible granules
By kasugarnycin 1g, Thiodiazole-copper 17g, naphthalenesulfonate formaldehyde condensation compound 4g, sodium alkyl benzene sulfonate 1.5g, gum Arabic 0.5g, 100g mixing supplied by white carbon, mixture is carried out granulation after ultra-fine grinding, drying, screening, both 18% kasugarnycin Thiodiazole-copper water dispersible granules.
Embodiment 4 12% kasugarnycin humus copper aqua
Kasugarnycin 2g, humus copper 10g water are fully dissolved, adds phenethyl phenol polyethenoxy ether 2g, agriculture breast 500#2g, stir, complement to 100g with water, both obtained 12% kasugarnycin humus copper aqua.
The bactericidal composition of embodiment 5 containing kasugarnycin is to the effect of tomato disease
According to scheme, preparation built agent and unit dose preparation, and carry out active preliminary experiment.According to determination of activity trial test, by the concentration that Formulation becomes to need.Establish corresponding single dose and blank in tomato field before test, at disease initial stage of origination, adopt the conventional conventional spray of manual sprayer, every medicament sprays 50 strains.7-10d dispenser 1 time again after 1st dispenser.10-20d after 2nd dispenser, investigates tomato plant disease incidence of listing.Use Abbot formula, convert percentage to preventive effect.
In theoretical effect, the effect of the substance A that x is concentration when being a, the effect of the substance B that y is concentration when being b, compares theoretical effect and actual effect, evaluates the synergy of composition.Composition to the result of tomato plant disease respectively in table 1.
The bactericidal composition of table 1 containing kasugarnycin is to the field efficacy of tomato disease
As seen from Table 1, kasugarnycin respectively to the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of tomato late blight, gray mold higher than corresponding single dose theoretical effect, show that composition has obvious synergistic function.
The bactericidal composition of embodiment 6 containing kasugarnycin is to the effect of rice disease
Testing scheme, with embodiment 5, the results are shown in Table 2.
The bactericidal composition of table 2 containing kasugarnycin is to the field efficacy of rice disease
As seen from Table 2, kasugarnycin respectively to the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of stripe disease and rice blast higher than the theoretical effect of corresponding single dose, show that composition has obvious synergistic function.
The bactericidal composition of embodiment 7 containing kasugarnycin is to the effect of watermelon angular leaf spot
Testing scheme, with embodiment 5, the results are shown in Table 3.
The bactericidal composition of table 3 containing kasugarnycin is to the field efficacy of watermelon angular leaf spot
As seen from Table 3, kasugarnycin respectively to the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the actual effect of watermelon angular leaf spot higher than corresponding single dose theoretical effect, show that composition has obvious synergistic function.
The bactericidal composition of embodiment 8 containing kasugarnycin is to the effect of citrus bacterial canker disease
Testing scheme, with embodiment 5, the results are shown in Table 4.
The bactericidal composition of table 4 containing kasugarnycin is to the field efficacy of citrus bacterial canker disease
As seen from Table 4, kasugarnycin respectively to the composition of copper 8-hydroxyquinolinate, tiger glue adipic acid copper, copper humate, Thiodiazole-copper to the theoretical effect of the actual effect of citrus bacterial canker disease higher than corresponding single dose, show that composition has obvious synergistic function.
Claims (5)
1. the bactericidal composition containing kasugarnycin, it is characterized in that said composition includes A and B of effective amount, A is kasugarnycin, and B selects copper 8-hydroxyquinolinate, and the ratio of quality and the number of copies of A and B is 10:1-1:100.
2. the bactericidal composition containing kasugarnycin according to claim 1, the ratio of quality and the number of copies of A and B is 1:1-1:50.
3. the bactericidal composition containing kasugarnycin according to claim 2, composition is processed into wetting powder, water dispersible granules, aqueous emulsion, microemulsion, suspending agent, and the percentage that A and B quality sum accounts for preparation gross mass is 1-80%.
4. the bactericidal composition containing kasugarnycin according to claim 3, composition can prevent and treat the fungus and bacterium disease of paddy rice, wheat, vegetables, fruit tree.
5. the bactericidal composition containing kasugarnycin according to claim 4, described disease is the late blight of tomato and gray mold, stripe disease and rice blast, watermelon angular leaf spot, citrus ulcer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310317869.4A CN103392740B (en) | 2013-07-26 | 2013-07-26 | Kasugamycin-containing sterilization composition and application thereof |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310317869.4A Division CN103392740B (en) | 2013-07-26 | 2013-07-26 | Kasugamycin-containing sterilization composition and application thereof |
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| CN104222090A true CN104222090A (en) | 2014-12-24 |
| CN104222090B CN104222090B (en) | 2016-03-02 |
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| CN201310317869.4A Active CN103392740B (en) | 2013-07-26 | 2013-07-26 | Kasugamycin-containing sterilization composition and application thereof |
| CN201410449654.2A Active CN104222090B (en) | 2013-07-26 | 2013-07-26 | Bactericidal composition containing kasugarnycin and copper 8-hydroxyquinolinate and application |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104542601A (en) * | 2013-10-11 | 2015-04-29 | 兴农药业（中国）有限公司 | Pesticide composition containing copper quinolate and kasugamycin and application of pesticide composition |
| CN106614705A (en) * | 2016-12-30 | 2017-05-10 | 陕西省蒲城美尔果农化有限责任公司 | Sterilization composition containing oxine-copper and flusilazole |
| CN106973907A (en) * | 2017-03-29 | 2017-07-25 | 兴农药业（中国）有限公司 | A kind of composition pesticide containing copper 8-hydroxyquinolinate and kasugarnycin and its application |
| CN109258656A (en) * | 2018-09-30 | 2019-01-25 | 浙江海正化工股份有限公司 | Composition pesticide and its preparation method and application containing Ningnanmycin and copper 8-hydroxyquinolinate |
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| CN110537543A (en) * | 2019-06-04 | 2019-12-06 | 广西汇丰生物科技有限公司 | Pesticide composition containing kasugamycin and quinolinone and bactericide |
| CN113647393A (en) * | 2021-07-27 | 2021-11-16 | 惠州市银农科技股份有限公司 | Suspending agent containing kasugamycin and oxine-copper and preparation method thereof |
| WO2022175654A1 (en) * | 2021-02-17 | 2022-08-25 | UPL Corporation Limited | A synergistic agricultural composition |
| CN115067344A (en) * | 2021-03-12 | 2022-09-20 | 顺毅股份有限公司 | Oxine-copper and kasugamycin compounded pesticide suspending agent |
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| CN104094975B (en) * | 2014-07-29 | 2016-09-07 | 海南正业中农高科股份有限公司 | Agriculturally useful compositions containing dithiocyano-methane and application |
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| CN106973907A (en) * | 2017-03-29 | 2017-07-25 | 兴农药业（中国）有限公司 | A kind of composition pesticide containing copper 8-hydroxyquinolinate and kasugarnycin and its application |
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| CN109430275A (en) * | 2018-10-25 | 2019-03-08 | 中国农业科学院植物保护研究所 | Agricultural bactericide and application with bactericidal activity |
| CN109645023A (en) * | 2019-01-27 | 2019-04-19 | 陕西上格之路生物科学有限公司 | A kind of bactericidal composition of the copper containing imidazole quinoline |
| CN110537543A (en) * | 2019-06-04 | 2019-12-06 | 广西汇丰生物科技有限公司 | Pesticide composition containing kasugamycin and quinolinone and bactericide |
| WO2022175654A1 (en) * | 2021-02-17 | 2022-08-25 | UPL Corporation Limited | A synergistic agricultural composition |
| CN115067344A (en) * | 2021-03-12 | 2022-09-20 | 顺毅股份有限公司 | Oxine-copper and kasugamycin compounded pesticide suspending agent |
| CN115067344B (en) * | 2021-03-12 | 2024-03-12 | 顺毅股份有限公司 | Pesticide suspending agent compounded by copper quinolinate and kasugamycin |
| CN113647393A (en) * | 2021-07-27 | 2021-11-16 | 惠州市银农科技股份有限公司 | Suspending agent containing kasugamycin and oxine-copper and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103392740B (en) | 2014-10-29 |
| CN104222090B (en) | 2016-03-02 |
| CN103392740A (en) | 2013-11-20 |
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