CN107232197A - A kind of antibacterial volume increase composition of the ester containing chrysanthemin - Google Patents
A kind of antibacterial volume increase composition of the ester containing chrysanthemin Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
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Abstract
Increase production composition the present invention relates to a kind of antibacterial of ester containing chrysanthemin, effective active composition is active components A and active component B antibacterial volume increase composition, and active components A is chrysanthemin ester, and active component B is selected from any one following compound：Amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine, the present composition has greater activity to the multiple diseases in various crop, and with obvious synergistic effect, expand fungicidal spectrum, increase effective absorption of the crop to fertilizer simultaneously, supplemental crop inferior position part well grows, and adjusts the balance of crop internal water, so as to activate the metabolic system of crop, promote the characteristics of crop cell growth, root activity are strengthened.
Description
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of antibacterial volume increase composition the answering in crops of ester containing chrysanthemin
With.
Technical background
Chrysanthemin ester (code name WD-5) is a kind of new plant growth regulator of China's exploitation, shows have through field experiment
Obvious production-increasing function, chrysanthemin ester (the isopropyl base pitch base of mono- diethylin of N, N, one 4 one chlorine 1 completes vinegar) is that Wuhan University closes
, should into a kind of, noval chemical compound for having preferable production-increasing function to crops such as wheat, rape, cotton, sesames for testing, screening
Compound belongs to innovative product.
Humic acid copper (HA-Cu) belongs to the chelate of humic acid, and humic acid is that a kind of polynary organic acid is mixed,
They can react to form chelate with metal ion, and these chelates chemical property in alkaline solution is relatively stablized, and it is not only
There is stronger sterilizing ability, and without poisoning.Humic acid chelate also includes：Humic acid magnesium, zinc humic acid, humic acid urea
Iron, sodium humate etc., it can be compounded with chrysanthemin ester.
Amino-oligosaccharide, cycocel, TrinexAN_SNacethyl, first piperazine belong to conventional plant growth regulator, are widely used in adjusting
Save the growth of plant.
In the real process of agricultural production, controlling disease is easy to generate the problem that while prevented and treated disease to planting
The growth of thing in itself has inhibitory action.By bactericide and plant growth regulator compounding can effectively controlling disease while can be with
Promote the growth of plant roots and leaf.Heterogeneity is compounded, according to practical application effect, come judge certain compounding be synergy,
Plus and or antagonism.In most cases, the compounding effect of agricultural chemicals is all additive effect, really there is synergistic effect
Compounding is seldom, especially synergistic effect clearly, the very high compounding of synergy ratio it is just less.Study, send out by inventor
Now chrysanthemin ester is mutually compounded with amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine, had within the specific limits very
Good synergistic effect, the anti pathologic immunity power of high crop can be endured well, strengthens the activity of root system, so that the purpose of volume increase is reached,
And about the related compounding of chrysanthemin ester and amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine, at present at home and abroad still
Have no relevant report.
The content of the invention
The purpose of the present invention is to propose to it is a kind of with synergistic function, use cost be low, effect is good contains chrysanthemin ester
Antibacterial volume increase composition.
The present invention is to be achieved through the following technical solutions：
A kind of antibacterial volume increase composition of the ester containing chrysanthemin, composition is active components A and active component B, active components A with
Active component B weight ratio is 100:1~1:100, described active components A is chrysanthemin ester, and active component B is selected from amino-oligosacchride
One of element, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine are planted, and active components A and active component B's is more excellent heavy in composition
Amount is than being 60:1~1:60；Wherein most preferably the weight ratio of chrysanthemin ester and amino-oligosaccharide is 30:1~1:30, chrysanthemin ester with it is rotten
The weight ratio for growing sour copper is 10:1~1:35, the weight ratio of chrysanthemin ester and cycocel is 25:1~1:25, chrysanthemin ester and TrinexAN_SNacethyl
Weight ratio be 25:1~1:25, the weight ratio of chrysanthemin ester and first piperazine is 25:1~1:25.
Described plant growth regulator composition, wherein effective active composition content account for gross weight 0.05%~
50%, preferably 0.1%~30%.
The antibacterial volume increase composition of the described ester containing chrysanthemin is used to prevent and treat crop disease and promotes the purposes of plant growth.
Described crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits and made
Thing, dry fruit crop, hobby crop, root crop, oil crops, flower crop, medicinal crop, crop, green manure are herded
Careless crop, described disease is soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, red mould
Disease, mosaic disease, gray mold or anthracnose.
Surfactant selected by the antibacterial volume increase composition of the present invention is known in those skilled in the art：Can be with
One or more in dispersant, wetting agent, thickener or defoamer.This can also be contained according to different dosage forms, in preparation
Stabilizer, antifreeze well known to art personnel etc..
The antibacterial volume increase composition of the present invention, acceptable formulation on any agricultural chemicals can be processed on demand, wherein excellent
Select formulation outstanding for wettable powder, soluble granule, soluble powder, soluble liquid, water dispersible granules, aqua or micro-capsule
Floating agent, can also be made aqueous emulsion, microemulsion, suspending agent, effervescent agent, seed coat agent.
Composition includes following constituent content when wettable powder is made：Active components A 0.05%~15%, active component
B0.05%~50%, dispersant 2%~10%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when soluble granule is made：Active components A 0.05%~15%, activity into
Point B0.05%~50%, binding agent 0~8%, colouring agent 0.1%-2%, dispersant 2%~10%, wetting agent 2%~10%,
Filler surplus.
Composition includes following constituent content when soluble powder is made：Active components A 0.05%~15%, active component
B0.05%~50%, dispersant 2%~8%, wetting agent 1%-7%, stabilizer 0~5%, filler surplus.
Composition includes following constituent content when soluble liquid is made：Active components A 0.05%~15%, active component
B0.05%~50%, emulsifying agent 1%~10%, cosolvent 2%~6%, solvent add to 100%.
Composition includes following constituent content when water dispersible granules are made：Active components A 0.05%~15%, active component
B0.05%~50%, dispersant 3%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%, fill out
Expect surplus.
Composition includes following constituent content when aqua is made：Active components A 0.05%~15%, active component
B0.05%~50%, cosolvent 2%~6%, wetting agent 1%-10%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following constituent content when microcapsule suspending agent is made：Active components A 0.05%~15%, active component
B0.05%~50%, macromolecule cyst material 2%~10%, dispersant 1%~10%, solvent 1%~10%, emulsifying agent 1%
~7%, defoamer 0.01%~2%, pH adjusting agent 0.01%~5%, deionized water add to 100%.
Composition includes following constituent content when thermal fog is made：Active components A 0.001%~20%, active component
B0.1%~50%, dispersant 3~12%, wetting agent 1~8%, stabilizer 0~5%, cosolvent 5%~10%, more than solvent
Amount.
Ultra low volume liquids, which are made, in composition includes following constituent content：Active components A 0.001%~20%, activity into
Point B0.1%~50%, dispersant 3~12%, wetting agent 1~8%, synergist 1~5%, bleeding agent 1%~10%, more than solvent
Amount.
The wettable powder the key technical indexes of the present invention：
The soluble granule the key technical indexes of the present invention：
The soluble powder the key technical indexes of the present invention：
The soluble liquid the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The aqua the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
Thermal fog the key technical indexes of the present invention：
Ultra low volume liquids the key technical indexes of the present invention：
The advantage of the invention is that：
(1) to pears, apple, Portugal after chrysanthemin ester is compounded with amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine
There is obvious promotion growth to make for grape, citrus, banana, strawberry, watermelon, Chinese cabbage, cucumber, capsicum, tomato, wheat, paddy rice, tobacco
With, and can prevent and treat soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, head blight,
Mosaic disease, gray mold or anthracnose；(2) pesticide usage amount is reduced, residual quantity of the reduction agricultural chemicals on crop, mitigates environment dirty
Dye；(3) while increasing effective absorption of crop fertilizer, supplemental crop inferior position part well grows, regulation crop internal water
Balance, so as to activate the metabolic system of crop, promotes crop cell to increase, the characteristics of root activity is strengthened.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~13
Chrysanthemin ester, active component B, dispersant, wetting agent, filler are well mixed in mixed cylinder, through airslide disintegrating mill
Remixed after crushing uniform, you can wettable powder product of the present invention is made, 1 is specifically shown in Table.
The each component of 1 embodiment of table 1~13 and parts by weight
The soluble granule of embodiment 14~26
Chrysanthemin ester, active component B, binding agent, colouring agent, dispersant, wetting agent, filler are mixed in mixed cylinder
It is even, pass through extruder grain, drying, and screened obtained soluble granule product of the present invention, be specifically shown in Table 2.
The each component of 2 embodiment of table 14~26 and parts by weight
The soluble powder of embodiment 27~39
Chrysanthemin ester, active component B, dispersant, wetting agent, stabilizer (can add to be not added with), filler are mixed in mixed cylinder
Close uniform, remixed after being crushed through airslide disintegrating mill uniform, you can soluble powder product of the present invention is made, is specifically shown in
Table 3.
The each component of 3 embodiment of table 27~39 and parts by weight
The soluble liquid of embodiment 40~52
Emulsifying agent, cosolvent are well mixed by high speed shear, chrysanthemin ester, active component B, the ball in ball mill is added
Mill 2~3 hours, makes diameter of particle all below 5 μm, surplus is supplied with solvent, you can solubility of the present invention is made
Liquor product, is specifically shown in Table 4.
The each component of 4 embodiment of table 40~52 and parts by weight
The water dispersible granules of embodiment 53~62
Chrysanthemin ester, active component B, dispersant, wetting agent, disintegrant, filler etc. are needed through air-flow crushing together
Particle diameter, add other auxiliary agents such as binding agent (can add to be not added with), obtain pelletize materials.Item is quantified into feeding fluid bed system
In grain drying machine after granulation and drying, you can water dispersible granules product of the present invention is made, 5 are specifically shown in Table.
The each component of 5 embodiment of table 53~62 and content
The aqua of embodiment 63~75
Chrysanthemin ester, active component B, wetting agent, antifreeze (can add to be not added with), solvent, deionized water etc. are mixed together,
The aqua product of the present composition is made, 6 are specifically shown in Table.
The each component of 6 embodiment of table 63~75 and parts by weight
Amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine in table 1~6 are exchanged, novel formulation can be made.
Embodiment 76,77 microcapsule suspending agents
Chrysanthemin ester, active component B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, in shearing bar
Under part, oil phase is added to containing in emulsifying agent, pH adjusting agent, the aqueous phase solution of dispersant, surplus is supplied with deionized water, two
Plant material to react in oil-water interfaces, form high score ascus wall, the well dispersed microcapsule suspending agent of the present composition is made
Product.Specifically it is shown in Table 7.
The embodiment 76 of table 7,77 each components and parts by weight
Embodiment 78,79 thermal fogs
Active component chrysanthemin ester, active component B, dispersant, wetting agent, stabilizer, cosolvent, solvent are matched by regulation
Put into modulation kettle, be uniformly mixing to obtain single phase product, the thermal fog product of the present composition is made, 8 are specifically shown in Table.
The embodiment 78 of table 8,79 components and content
Embodiment 80,81 ultra low volume liquids
Active component chrysanthemin ester, active component B, dispersant, wetting agent, stabilizer, cosolvent, solvent are matched by regulation
Put into modulation kettle, be uniformly mixing to obtain single phase product, the ultra low volume liquids product of the present composition is made, is specifically shown in Table
9。
The embodiment 80 of table 9,81 components and content
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
Calmly, the synergy ratio (SR) after clear and definite two kinds of medicaments are compounded by a certain percentage, SR ＜ 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR ＞ 1.5 are synergistic effect, on this basis, then carry out field test.
Test method：After determining the effective inhibition concentration scope of each medicament through prerun, medicament sets 5 respectively by active constituent content
Individual dosage processing, if clear water is compareed.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, the net growth of each processing is calculated
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum
Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley methods
Two medicament different ratio synergy ratios (SR) are calculated, SR ＜ 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action,
SR ＞ 1.5 are synergistic effect.Calculation formula is as follows：
Wherein：A, b are respectively active components A and active component B ratio shared in combination；
A is chrysanthemin ester；
B is selected from one of amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine and planted.
Application Example two：
For examination disease：Tomato blight
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective suppression of chrysanthemin ester and both amino-oligosaccharides different ratio mixture is determined by pilot study
Concentration range.
Toxicity test result
The chrysanthemin ester of table 10 compounds the toxicity test analysis of results table to tomato blight with amino-oligosaccharide
As shown in Table 10, chrysanthemin ester compounds the proportioning for preventing and treating tomato blight in 100 1~1 ︰ 100 of ︰ with amino-oligosaccharide,
Synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at mixtures in the range of the ︰ 100 of 100 ︰ 1~1, chrysanthemin ester with
The proportioning of amino-oligosaccharide is 30: 1~1: 30, and synergistic effect is more prominent, and synergy ratio is more than 2.25, wherein chrysanthemin ester
It is 1 with amino-oligosaccharide weight ratio：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.Chrysanthemin ester is found through applicant's experiment
Proportioning with amino-oligosaccharide is 30:1、25:1、20:1、15:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:
1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:15、1:20、1:25、
1:When 30, to soft rot, virosis, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, head blight, gray mold or anthrax
The preventing and treating of disease has obvious synergistic effect, and synergy ratio is more than 1.50.
Application Example three：
For examination disease：Canker of apple fruit
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Determine that the effectively suppression of chrysanthemin ester and both humic acid copper different ratio mixture is dense by pilot study
Spend scope.
Toxicity test result
The chrysanthemin ester of table 11 compounds the toxicity test analysis of results table to canker of apple fruit with humic acid copper
As shown in Table 11, chrysanthemin ester prevents and treats canker of apple fruit proportioning in 100 1~1 ︰ 100 of ︰ with humic acid copper compounding, increases
Effect ratio SR is all higher than 1.5, illustrates that both mixtures in the range of the ︰ 100 of 100 ︰ 1~1 show synergistic effect, chrysanthemin ester and corruption
Grow the proportioning of sour copper 10: 1~1: 35, synergistic effect is more prominent, synergy ratio more than 2.35, wherein chrysanthemin ester with it is rotten
It is 1 to grow sour weight of copper ratio：Synergy ratio is maximum when 10, and synergistic effect is the most obvious.Chrysanthemin ester and corruption are found through applicant's experiment
The proportioning for growing sour copper is 10:1、5:1、1:1、1:5、1:6、1:7、1:8、1:9、1:10、1:10、1:12、1:13、1:14、1:15、
1:16、1:17、1:18、1:19、1:20、1:21、1:22、1:23、1:24、1:25、1:26、1:27、1:28、1:29、1:30、1:
When 35, to soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, head blight, mosaic disease, ash
The preventing and treating of mildew or anthracnose has obvious synergistic effect, and synergy ratio is more than 1.50.
Application Example four：
For examination disease：Watermelon anthrax
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective inhibition concentration of chrysanthemin ester and both cycocels different ratio mixture is determined by pilot study
Scope.
Toxicity test result
The chrysanthemin ester of table 12 compounds the toxicity test analysis of results table to watermelon anthrax with cycocel
As shown in Table 12, the proportioning that chrysanthemin ester compounds preventing and treating watermelon anthrax with cycocel increases in 100 1~1 ︰ 100 of ︰
Effect ratio SR is all higher than 1.5, both illustrate that in the range of the ︰ 100 of 100 ︰ 1~1 mixtures show synergistic effect, chrysanthemin ester with it is short
The proportioning of element is strengthened 25: 1~1: 25, synergistic effect is more prominent, synergy ratio is more than 2.25, and wherein chrysanthemin ester is strengthened with short
Plain weight ratio is 1：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.Chrysanthemin ester and cycocel are found through applicant's experiment
Proportioning be 25:1、20:1、15:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、
1:5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:16、1:17、1:18、1:19、1:20、1:
When 25, to soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, head blight, mosaic disease, ash
The preventing and treating of mildew or anthracnose has obvious synergistic effect, and synergy ratio is more than 1.50.
Application Example five：
For examination disease：Tobacco mosaic disease
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective inhibition concentration of chrysanthemin ester and both TrinexAN_SNacethyls different ratio mixture is determined by pilot study
Scope.
Toxicity test result
The chrysanthemin ester of table 13 compounds the toxicity test analysis of results table to tobacco mosaic disease with cycocel
As shown in Table 13, chrysanthemin ester compounds the proportioning for preventing and treating tobacco mosaic disease in 100 1~1 ︰ 100 of ︰ with TrinexAN_SNacethyl, increases
Effect ratio SR is all higher than 1.5, illustrates that both mixtures in the range of the ︰ 100 of 100 ︰ 1~1 show synergistic effect, chrysanthemin ester is with resisting
The proportioning of ester is 25: 1~1: 25, and synergistic effect is more prominent, synergy ratio more than 2.20, wherein chrysanthemin ester with it is anti-fall
Ester weight ratio is 2：Synergy ratio is maximum when 3, and synergistic effect is the most obvious.Tested through applicant and find chrysanthemin ester and TrinexAN_SNacethyl
Match as 25:1、20:1、15:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:
5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:16、1:17、1:18、1:19、1:20、1:25
When, to soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, head blight, mosaic disease, grey mold
The preventing and treating of disease or anthracnose has obvious synergistic effect, and synergy ratio is more than 1.50.
Application Example six：
For examination disease：Cotton wilt
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Effective inhibition concentration of chrysanthemin ester and both first piperazines different ratio mixture is determined by pilot study
Scope.
Toxicity test result
The chrysanthemin ester of table 14 compounds the toxicity test analysis of results table to cotton wilt with first piperazine
As shown in Table 14, the proportioning that chrysanthemin ester compounds preventing and treating cotton wilt with first piperazine increases in 100 1~1 ︰ 100 of ︰
Effect ratio SR is all higher than 1.5, illustrates that both show synergistic effect, chrysanthemin ester and first at the mixture in the range of the ︰ 100 of 100 ︰ 1~1
The proportioning of piperazine is 25: 1~1: 25, and synergistic effect is more prominent, and synergy ratio is more than 2.25, wherein chrysanthemin ester and first piperazine
Weight ratio is 1：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.Tested through applicant and find chrysanthemin ester and first piperazine
Match as 25:1、20:1、15:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:
5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:13、1:14、1:15、1:16、1:17、1:18、1:19、1:20、1:25
When, to soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot, phytophthora root rot, head blight, mosaic disease, grey mold
The preventing and treating of disease or anthracnose has obvious synergistic effect, and synergy ratio is more than 1.50.
Application Example seven：
For studying thing：Cucumber
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
Experimental design：Chrysanthemin ester and the regulation plant life of active component B both different ratio mixture are determined by pilot study
Long concentration range.
Regulation growth of the chrysanthemin ester of table 15 and active component B and its different proportion mixed liquid to cucumber
As shown in Table 15, after chrysanthemin ester and active component B are used in mixed way, can activated plant metabolic system and give birth to plant
Long quickening vigor enhancing, promotes plant cell to increase, root activity is strengthened, and reaches volume increase purpose, and chrysanthemin ester exists with active component B
During 100 1~1 ︰ 100 of ︰, there is stronger adjustment effect.
Find that chrysanthemin ester is compounded with amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine through applicant's experiment
Afterwards soft rot, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, corruption can be effectively prevented and treated in the range of the ︰ 100 of 100 ︰ 1~1
Rotten disease, phytophthora root rot, head blight, mosaic disease, gray mold or anthracnose, and can activated plant metabolic system and make plant growth
Quickening vigor strengthens, and promotes plant cell to increase, and root activity is strengthened, and reaches volume increase purpose, wherein most preferably weight ratio is 30:
1、25:1、20:1、15:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、
1:4、1:5、1:6、1:7、1:8、1:9、1:10、1:11、1:12、1:15、1:20、1:25、1:30。
Effect experiment part：Test medicine is researched and developed by Shaanxi Welch Crop Protection Co., Ltd., provided, comparison medicament
0.5% chrysanthemin ester wettable powder (autogamy), 2% amino-oligosaccharide aqua (autogamy), 30% humic acid copper wettable powder are (certainly
With), 50% cycocel aqua (autogamy), the anti-fall emulsifiable concentrates of 250g/L, 250g/L first piperazine aquas (autogamy).
The chrysanthemin ester of Application Example eight and active component B and its compounding preventing and treating tomato blight drug effect and regulation growth examination
Test
This experimental arrangement investigates the tomato blight state of an illness before Shaanxi Province Weinan City Dali County, medicine, in state of an illness first time at initial stage
Dispenser, every dispenser in 7 days once, is total to dispenser 2 times.3 days after second of dispenser, disease index is investigated respectively and calculates anti-within 7 days, 15 days
Effect, investigates the growth rate of crop after second of dispenser.Experimental result is as follows：
The chrysanthemin ester of table 16 and active component B and its compounding preventing and treating tomato blight drug effect and regulation growth experiment
As can be seen from Table 16, chrysanthemin ester after active component B and its compounding with can effectively prevent and treat tomato blight, while also may be used
To prevent and treat tomato virus disease, gray mold, anthracnose, prevention effect is superior to the preventive effect of single dose, and preventive effect phase is long, and can activated plant
Metabolic system and make plant growth accelerate vigor enhancing, strengthen root system growth.Simultaneously to target in experiment scope of medication
Crop has no adverse effects.
The chrysanthemin ester of Application Example nine prevents and treats angular leaf spot of cucumber drug effect and regulation growth with active component B and its compounding
Experiment
This test arrangement investigates the angular leaf spot of cucumber state of an illness before Xian District, Shanxi Province suburban area, medicine, in state of an illness first time at initial stage
Dispenser, every dispenser in 7 days once, is total to dispenser 2 times.3 days after second of dispenser, disease index is investigated respectively and calculates anti-within 7 days, 15 days
Effect, investigates the growth rate of crop after second of dispenser.Experimental result is as follows：
The chrysanthemin ester of table 17 prevents and treats angular leaf spot of cucumber drug effect and regulation growth experiment with active component B and its compounding
As can be seen from Table 17, angular leaf spot of cucumber can be effectively prevented and treated after chrysanthemin ester and active component B and its compounding, can be with
Cucumber virosis, gray mold, droop, epidemic disease are prevented and treated, prevention effect is superior to the preventive effect of single dose, and preventive effect phase is long, and can activate
The metabolic system of plant and make plant growth accelerate vigor enhancing, strengthen root system growth.It is simultaneously right in experiment scope of medication
Target crop has no adverse effects.
The chrysanthemin ester of Application Example ten and active component B and its compounding preventing and treating watermelon blight drug effect and regulation growth
Experiment
This experimental arrangement investigates the watermelon blight state of an illness before Shaanxi Province Weinan City Dali County, medicine, state of an illness initial stage first
Secondary dispenser, every dispenser in 7 days once, is total to dispenser 2 times.7 days after second of dispenser, disease index is investigated respectively and is counted within 14 days, 30 days
Preventive effect is calculated, the growth rate of crop is investigated after second of dispenser.Experimental result is as follows：
The chrysanthemin ester of table 18 and active component B and its compounding preventing and treating watermelon blight drug effect and regulation growth experiment
As can be seen from Table 18, watermelon blight can be effectively prevented and treated after chrysanthemin ester and active component B and its compounding, can be with
Prevent and treat watermelon angular leaf spot, epidemic disease, prevention effect is superior to the preventive effect of single dose, and preventive effect phase is long, and can activated plant metabolic system
And plant growth is accelerated vigor enhancing, strengthen the growth of root system.Testing simultaneously in scope of medication to target crop without bad
Influence.
The chrysanthemin ester of Application Example 11 prevents and treats apple tree canker drug effect with active component B and its compounding and regulation grows
Experiment on Function
This experimental arrangement investigates the apple tree canker state of an illness before Shaanxi Province's Weinan City Baishui County, medicine, state of an illness initial stage
Dispenser, every dispenser in 7 days once, is total to dispenser 2 times.3 days after second of dispenser, disease index is investigated respectively and is counted within 7 days, 15 days
Preventive effect is calculated, the growth rate of crop is investigated after second of dispenser.Experimental result is as follows：
The chrysanthemin ester of table 19 prevents and treats apple tree canker drug effect and regulation growth experiment with active component B and its compounding
As can be seen from Table 19, chrysanthemin ester and energy effectively preventing and treating apple-tree rot after active component B and its compounding, may be used also
To prevent and treat apple tree anthracnose, prevention effect is superior to the preventive effect of single dose, and preventive effect phase is long, and can activated plant metabolic system and
Plant growth is accelerated vigor enhancing, strengthen the growth of root system.Testing simultaneously in scope of medication to target crop without bad shadow
Ring.
The chrysanthemin ester of Application Example 12 grows with active component B and its compounding preventing and treating mandarin tree anthracnose drug effect and regulation
Experiment on Function
This experimental arrangement investigates the mandarin tree anthracnose state of an illness before Shaanxi Province's Hanzhong City, medicine, is applied for the first time initial stage in the state of an illness
Medicine, every dispenser in 7 days once, is total to dispenser 2 times.7 days after second of dispenser, disease index is investigated respectively and calculates anti-within 14 days, 30 days
Effect, investigates the growth rate of crop after second of dispenser.Experimental result is as follows：
The chrysanthemin ester of table 20 and active component B and its compounding preventing and treating mandarin tree anthracnose drug effect and regulation growth experiment
As can be seen from Table 20, chrysanthemin ester is prevented and treated with can effectively prevent and treat mandarin tree anthracnose after active component B and its compounding
Effect is superior to the preventive effect of single dose, and preventive effect phase is long, and can activated plant metabolic system and make plant growth accelerate vigor enhancing,
Strengthen the growth of root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The chrysanthemin ester of Application Example 13 prevents and treats wheat scab drug effect with active component B and its compounding and regulation growth is made
With experiment
This experimental arrangement investigates the wheat scab state of an illness before Shaanxi Province Weinan City Pucheng County, medicine, state of an illness initial stage first
Secondary dispenser, every dispenser in 7 days once, is total to dispenser 2 times.3 days after second of dispenser, disease index is investigated respectively and is counted within 7 days, 15 days
Preventive effect is calculated, the growth rate of crop is investigated after second of dispenser.Experimental result is as follows：
The chrysanthemin ester of table 21 prevents and treats wheat scab drug effect and regulation growth experiment with active component B and its compounding
As can be seen from Table 21, chrysanthemin ester is with can effectively prevent and treat wheat scab, preventing and treating effect after active component B and its compounding
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long, and can activated plant metabolic system and plant growth is accelerated vigor enhancing, increase
The growth of strong root system.Target crop is had no adverse effects in experiment scope of medication simultaneously.
The experiment by different places throughout the country is drawn afterwards, chrysanthemin ester and amino-oligosaccharide, humic acid copper, short strong
Element, TrinexAN_SNacethyl compounding after to the soft rot in various crop, virosis, epidemic disease, verticillium wilt, droop, angular leaf spot, rot,
The preventive effect of the Common Diseases such as phytophthora root rot, head blight, mosaic disease, gray mold or anthracnose 95% with excellent, it is anti-in single dose
Effect, synergistic effect is obvious.Simultaneously can activated plant metabolic system and make plant growth accelerate vigor enhancing, proline content
Increase and the reinforcement of cellulase, promote plant cell to increase, and root activity is strengthened, and reaches volume increase purpose.
Claims (8)
1. a kind of antibacterial volume increase composition of ester containing chrysanthemin, effective active composition is active components A and active component B, its feature
It is：Active components A and active component B weight ratio are 100:1~1:100, described active components A is chrysanthemin ester, activity
Composition B is selected from one of amino-oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine and planted.
2. the antibacterial volume increase composition of the ester according to claim 1 containing chrysanthemin, it is characterised in that：Active component in composition
A and active component B weight ratio is 60:1~1:60.
3. the antibacterial volume increase composition of the ester according to claim 2 containing chrysanthemin, it is characterised in that：
The weight ratio of chrysanthemin ester and amino-oligosaccharide is 30:1~1:30；
The weight ratio of chrysanthemin ester and humic acid copper is 10:1~1:35；
The weight ratio of chrysanthemin ester and cycocel is 25:1~1:25；
The weight ratio of chrysanthemin ester and TrinexAN_SNacethyl is 25:1~1:25；
The weight ratio of chrysanthemin ester and first piperazine is 25:1~1:25.
4. the antibacterial volume increase composition of the ester according to claim 1 containing chrysanthemin, it is characterised in that：Wherein effective active composition
Content accounts for the 0.05%~50% of gross weight.
5. the antibacterial volume increase composition of the ester according to claim 4 containing chrysanthemin, it is characterised in that：Wherein effective active composition
Content accounts for the 0.1%~30% of gross weight.
6. the antibacterial volume increase composition of the ester according to any one of claim 1 to 5 containing chrysanthemin, it is characterised in that：Combination
Wettable powder is made in thing, soluble granule, soluble powder, soluble liquid, water dispersible granules, aqua, thermal fog, super
Low capacity liquor or microcapsule suspending agent.
7. the antibacterial volume increase composition of the ester according to claim 1 containing chrysanthemin is used to prevent and treat crop disease and promotes plant life
Long purposes.
8. according to claim 7 use is characterized in that：Described disease be soft rot, virosis, epidemic disease, verticillium wilt,
Droop, angular leaf spot, rot, phytophthora root rot, head blight, mosaic disease, gray mold or anthracnose.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103392740A (en) * | 2013-07-26 | 2013-11-20 | 海南正业中农高科股份有限公司 | Kasugamycin-containing sterilization composition and application thereof |
| CN104276891A (en) * | 2014-09-29 | 2015-01-14 | 谢绪叶 | Foliage fertilizer containing amino oligosaccharins |
| CN104488924A (en) * | 2015-01-19 | 2015-04-08 | 陕西上格之路生物科学有限公司 | Compound composition used for increasing crop fertilization rate |
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2016
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103392740A (en) * | 2013-07-26 | 2013-11-20 | 海南正业中农高科股份有限公司 | Kasugamycin-containing sterilization composition and application thereof |
| CN104276891A (en) * | 2014-09-29 | 2015-01-14 | 谢绪叶 | Foliage fertilizer containing amino oligosaccharins |
| CN104488924A (en) * | 2015-01-19 | 2015-04-08 | 陕西上格之路生物科学有限公司 | Compound composition used for increasing crop fertilization rate |
Non-Patent Citations (1)
| Title |
|---|
| 黄艳刚等: "植物生长调节剂菊乙胺酯", 《现代化工》 * |
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