CN104757007B - A kind of bactericidal composition containing Hexanaphthene flusulfamide - Google Patents
A kind of bactericidal composition containing Hexanaphthene flusulfamide Download PDFInfo
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- CN104757007B CN104757007B CN201510063623.8A CN201510063623A CN104757007B CN 104757007 B CN104757007 B CN 104757007B CN 201510063623 A CN201510063623 A CN 201510063623A CN 104757007 B CN104757007 B CN 104757007B
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- Prior art keywords
- hexanaphthene flusulfamide
- active component
- disease
- active
- flusulfamide
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- GNVDAZSPJWCIQZ-UHFFFAOYSA-N flusulfamide Chemical compound ClC1=CC([N+](=O)[O-])=CC=C1NS(=O)(=O)C1=CC=C(Cl)C(C(F)(F)F)=C1 GNVDAZSPJWCIQZ-UHFFFAOYSA-N 0.000 title claims abstract description 87
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 48
- 201000010099 disease Diseases 0.000 claims abstract description 46
- 230000000694 effects Effects 0.000 claims abstract description 23
- 229930182764 Polyoxin Natural products 0.000 claims abstract description 18
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 claims abstract description 18
- 239000000375 suspending agent Substances 0.000 claims description 18
- 206010039509 Scab Diseases 0.000 claims description 15
- 241000221785 Erysiphales Species 0.000 claims description 14
- 239000003094 microcapsule Substances 0.000 claims description 14
- 235000007164 Oryza sativa Nutrition 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 235000009566 rice Nutrition 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000004563 wettable powder Substances 0.000 claims description 8
- 239000004530 micro-emulsion Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 241001530056 Athelia rolfsii Species 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 241000918585 Pythium aphanidermatum Species 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 206010064458 Penicilliosis Diseases 0.000 claims description 4
- 241000233679 Peronosporaceae Species 0.000 claims description 4
- 230000035613 defoliation Effects 0.000 claims description 4
- 208000031968 Cadaver Diseases 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 25
- 230000002195 synergetic effect Effects 0.000 abstract description 24
- 239000005820 Prochloraz Substances 0.000 abstract description 23
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 abstract description 22
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 abstract description 20
- 239000006013 carbendazim Substances 0.000 abstract description 20
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 abstract description 20
- 150000003851 azoles Chemical class 0.000 abstract description 19
- 229910052731 fluorine Inorganic materials 0.000 abstract description 19
- 239000011737 fluorine Substances 0.000 abstract description 19
- 239000005842 Thiophanate-methyl Substances 0.000 abstract description 18
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 abstract description 18
- 150000003839 salts Chemical class 0.000 abstract description 17
- 150000001875 compounds Chemical class 0.000 abstract description 12
- 230000000855 fungicidal effect Effects 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 39
- 238000013329 compounding Methods 0.000 description 32
- 230000003449 preventive effect Effects 0.000 description 31
- 239000003814 drug Substances 0.000 description 29
- 239000000575 pesticide Substances 0.000 description 20
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000012071 phase Substances 0.000 description 14
- 239000013530 defoamer Substances 0.000 description 13
- 239000002270 dispersing agent Substances 0.000 description 13
- 240000008067 Cucumis sativus Species 0.000 description 12
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 12
- 241000209094 Oryza Species 0.000 description 11
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 231100000820 toxicity test Toxicity 0.000 description 10
- 235000013399 edible fruits Nutrition 0.000 description 9
- -1 prochloraz zinc salt Chemical class 0.000 description 9
- 206010067482 No adverse event Diseases 0.000 description 8
- 240000001987 Pyrus communis Species 0.000 description 8
- 235000014443 Pyrus communis Nutrition 0.000 description 8
- 230000002528 anti-freeze Effects 0.000 description 8
- 229940079593 drug Drugs 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 6
- 230000005764 inhibitory process Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 5
- 240000003768 Solanum lycopersicum Species 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 5
- 241000209140 Triticum Species 0.000 description 5
- 235000021307 Triticum Nutrition 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 5
- 238000013401 experimental design Methods 0.000 description 5
- 241000223600 Alternaria Species 0.000 description 4
- 241000207199 Citrus Species 0.000 description 4
- 206010011732 Cyst Diseases 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000011149 active material Substances 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 241000193738 Bacillus anthracis Species 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- QSLPNSWXUQHVLP-UHFFFAOYSA-N $l^{1}-sulfanylmethane Chemical compound [S]C QSLPNSWXUQHVLP-UHFFFAOYSA-N 0.000 description 1
- 229930182536 Antimycin Natural products 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 241000122123 Penicillium italicum Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 239000005858 Triflumizole Substances 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- CQIUKKVOEOPUDV-IYSWYEEDSA-N antimycin Chemical compound OC1=C(C(O)=O)C(=O)C(C)=C2[C@H](C)[C@@H](C)OC=C21 CQIUKKVOEOPUDV-IYSWYEEDSA-N 0.000 description 1
- 230000010165 autogamy Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 230000001965 increasing effect Effects 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical compound Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing Hexanaphthene flusulfamide, the bactericidal composition containing active components A Yu active component B, active components A is selected from Hexanaphthene flusulfamide, and active component B is selected from any one following compound：Fluorine bacterium azoles, polyoxin, Prochloraz or its salt, carbendazim, thiophanate-methyl, and active components A and active component B weight ratio are the ︰ 1 of 1 ︰ 60~80.The present composition has greater activity to the multiple diseases in various crop, and with obvious synergistic effect, expands fungicidal spectrum.And with dosage is small, resistance of rainwater washing against, the characteristics of synergy is obvious.
Description
The application is divisional application, and original application is a kind of patent application " sulphur containing hexamethylene of Shaanxi Meibang Pesticide Co., Ltd.
The bactericidal composition of bacterium amine ", the application Wei ︰ 201210301917.6 of original application, original application day is 2012.08.23.
Technical field
The invention belongs to technical field of pesticide, it is related to a kind of bactericidal composition containing Hexanaphthene flusulfamide in crop disease
Using.
Technical background
Hexanaphthene flusulfamide chemical name：N- (2- trifluoromethyl-4-chlorophenyls)-a- oxocyclohexyl sulfonamide.It has
Stronger prevention, treatment and osmotically active, and have higher lasting effect.Bright through table of field test results, Hexanaphthene flusulfamide can have
Prevent and treat gray mold, sclerotinia sclerotiorum, Cucumber Target Leaf Spot and scab to effect.
The salt of Prochloraz includes prochloraz-manganese chloride complex, prochloraz nantokite, prochloraz zinc salt.
In the real process of agricultural production, controlling disease is easiest to generate the problem that the generation of disease drug resistance.No
Compounded with kind composition, be to prevent and treat resistance disease very common method.Heterogeneity is compounded, and is imitated according to practical application
Really, come judge certain compounding be synergy, plus and or antagonism.In most cases, the compounding effect of agricultural chemicals is all to add
And effect, really have the compounding of synergistic effect seldom, especially synergistic effect clearly, synergy ratio very high compounding just more
It is few.Study, found Hexanaphthene flusulfamide and fluorine bacterium azoles, polyoxin, Prochloraz or its salt, carbendazim, first by inventor
Base thiophanate is mutually compounded, and has good synergistic effect within the specific limits, and about Hexanaphthene flusulfamide and fluorine bacterium azoles, many anti-mildews
Element, Prochloraz or its salt, carbendazim, the related compounding of thiophanate-methyl, at present at home and abroad there is not yet relevant report.
The content of the invention
There is synergistic function, the bacterium of sulphur containing hexamethylene that use cost is low, preventive effect is good the purpose of the present invention is to propose to a kind of
The bactericidal composition of amine.
The present invention is to be achieved through the following technical solutions：
A kind of bactericidal composition containing Hexanaphthene flusulfamide, it is characterised in that contain active components A and active component B, activity
Composition A is the ︰ 1 of 1 ︰ 60~80 with active component B weight ratio, and described active components A is selected from Hexanaphthene flusulfamide, active component B choosings
From any one following compound：Fluorine bacterium azoles, polyoxin, Prochloraz or its salt, carbendazim, thiophanate-methyl；Active components A
Preferred weight ratio with active component B is the ︰ 1 of 1 ︰ 40~60；More preferably the weight ratio of Hexanaphthene flusulfamide and fluorine bacterium azoles is 1 ︰ 10
The weight ratio of~35 ︰ 1, Hexanaphthene flusulfamide and polyoxin is the ︰ 1 of 1 ︰ 10~25, Hexanaphthene flusulfamide and Prochloraz or the weight of its salt
Ratio is measured for the ︰ 1 of 1 ︰ 10~25, the weight ratio of Hexanaphthene flusulfamide and carbendazim is 1：30~20：1, Hexanaphthene flusulfamide and methyl sulfur bacterium
The weight ratio of spirit is 1：20~20：1；Most preferably the weight ratio of Hexanaphthene flusulfamide and fluorine bacterium azoles is the ︰ 1 of 1 ︰ 5~20, hexamethylene sulphur bacterium
The weight ratio of amine and polyoxin is the ︰ 1 of 1 ︰ 5~15, and the weight ratio of Hexanaphthene flusulfamide and Prochloraz or its salt is the ︰ 1 of 1 ︰ 5~15,
Hexanaphthene flusulfamide and the weight of carbendazim ratio are 1：15~10：1, the weight ratio of Hexanaphthene flusulfamide and thiophanate-methyl is 1：10~
10：1.
The described bactericidal composition containing Hexanaphthene flusulfamide is used for the disease for preventing and treating crops, and described crops include grain
Food crop, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root
Stem class crop, oil crops, flower crop, medicinal crop, crop, green manure pasture crop；Described disease includes grey mold
Disease, leaf mold, downy mildew, green mould, penicilliosis, head blight, sclerotiniose, brown spot, leaf spot, spot defoliation, scab,
Rust, powdery mildew, epidemic disease, damping-off, anthracnose, bakanae disease, rice blast, banded sclerotial blight, blossom-end rot, crown rot, seedling laying disease, wheel
Line disease.
The amount of application when content of active component depends on being used alone in the present composition, also depends on a kind of chemical combination
Thing and the mixed ratio and synergistic effect degree of another compound, while also relevant with target disease.In usual composition
The weight percentage of active component is the 1%~90% of gross weight, preferably 5%~80%.According to different preparation classes
Type, active component content scope is different.Generally, liquid preparation contains by weight 1%~60% active material, preferably
Ground is 5%~50%；Solid pharmaceutical preparation contains by weight 5%~80% active material, preferably 10%~80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, active component is in water during in favor of applying
It is scattered.Surface-active contents are the 2%~30% of total formulation weight, and surplus is solid or liquid diluent.
The present invention bactericidal composition can by user using it is preceding through dilute or directly use.Its preparation can be by usual
Processing method known in those skilled in the art prepare, i.e., after active material is mixed with liquid flux or solid carrier,
The one kind added in surfactant such as dispersant, stabilizer, wetting agent, binding agent, defoamer, disintegrant, antifreeze
Or it is several.
The bactericidal composition of the present invention, acceptable formulation on any agricultural chemicals can be processed on demand.Wherein preferred agent
Type is wettable powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-outstanding
Floating agent.Aqua can also be made.When active component B is the salt of Prochloraz, its formulation is wettable powder, water-dispersible grain
Agent.
Composition includes following component and content when wettable powder is made：Active components A 0.5%~80%, activity into
Divide B 0.5%~60%, dispersant 1%~12%, wetting agent 1%~8%, filler surplus.
Composition includes following component and content when water dispersible granules are made：Active components A 0.5%~80%, activity into
Point B 0.5%~60%, dispersant 1%~12%, wetting agent 1%~8%, disintegrant 1%~10%, binding agent 0~8%,
Filler surplus.
Composition includes following component and content when suspending agent is made：Active components A 0.5%~50%, active component B
0.5%~50%, dispersant 1%~10%, wetting agent 1%~10%, defoamer 0.01%~2%, thickener 0~2%, anti-
Freeze agent 0~8%, deionized water and add to 100%.
Composition includes following component and content when suspension emulsion is made：Active components A 0.5%~50%, active component B
0.5%~50%, emulsifying agent 1%~10%, dispersant 1%~10%, solvent 1%~20%, defoamer 0.01%~2%,
Thickener 0~2%, antifreeze 0~8%, deionized water add to 100%.
Composition includes following component and content when microemulsion is made：Active components A 0.5%~50%, active component B
0.5%~50%, emulsifying agent 3%~25%, solvent 1%~20%, antifreeze 0~8%, defoamer 0.01%~2%, go from
Sub- water adds to 100%.
Composition includes following component and content when aqueous emulsion is made：Active components A 0.5%~50%, active component B
0.5%~50%, solvent 1%~20%, emulsifying agent 1%~12%, antifreeze 0~8%, defoamer 0.01%~2%, thickening
Agent 0~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspending agent is made：Active components A 0.5%~50%, activity into
Divide B 0.5%~50%, macromolecule cyst material 1%~10%, dispersant 2%~10%, solvent 1%~10%, emulsifying agent
1%~7%, pH adjusting agent 0.01%~5%, defoamer 0.01%~2%, deionized water add to 100%.
Composition includes following component and content when microcapsule suspension-suspendinagent agent is made：Active components A 0.5%~50%,
Active component B 0.5%~50%, macromolecule cyst material 1%~12%, dispersant 1%~12%, wetting agent 1%~8%,
Solvent 1%~15%, emulsifying agent 1%~8%, defoamer 0.01%~2%, thickener 0~2%, pH adjusting agent 0.01%~
5%th, deionized water adds to 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：(1) present composition has good synergy and lasting effect within the specific limits, prevents
Effect is higher than single dose；(2) pesticide usage amount is reduced, residual quantity of the reduction agricultural chemicals on crop, mitigates environmental pollution；(3) expand
Multiple diseases are had greater activity by fungicidal spectrum.
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Application Example one
The wettable powder of embodiment 1~14
Hexanaphthene flusulfamide, active component B, dispersant, wetting agent, filler are mixed, are well mixed in mixed cylinder, through gas
Stream pulverizer remixes uniform after crushing, you can wettable powder product of the present invention is made.Specifically it is shown in Table 1.
The each component of 1 embodiment of table 1~14 and content
The water dispersible granules of embodiment 15~28
Hexanaphthene flusulfamide, active component B, dispersant, wetting agent, disintegrant, filler are needed through air-flow crushing together
The particle diameter wanted, adds other auxiliary agents such as binding agent (can add to be not added with), obtains materials of pelletizing.Item is quantified into feeding fluid bed
In granulating drier after granulation and drying, water dispersible granules product of the present invention is made.Specifically it is shown in Table 2.
The each component of 2 embodiment of table 15~28 and content
By table 1, into table 2, fluorine bacterium azoles, polyoxin, Prochloraz or its salt, carbendazim, thiophanate-methyl are exchanged, and can be made
Novel formulation.
The suspending agent of embodiment 29~42
By dispersant, wetting agent, thickener (can add to be not added with), defoamer, antifreeze (can add to be not added with) by a high speed
Shear-mixed is uniform, adds Hexanaphthene flusulfamide, active component B, supplies surplus with deionized water, ball milling 2~3 is small in ball mill
When, make diameter of particle all below 5 μm, suspending agent product of the present invention is made.Specifically it is shown in Table 3.
The each component of 3 embodiment of table 29~42 and content
Fluorine bacterium azoles, polyoxin, Prochloraz, carbendazim, thiophanate-methyl in table are exchanged, novel formulation can be made.
The suspension emulsion of embodiment 43~52
By dispersant, defoamer, thickener (can add to be not added with), antifreeze (can add to be not added with), deionized water through too high
Fast shear-mixed is uniform, adds Hexanaphthene flusulfamide, and ball milling 2~3 hours in ball mill make diameter of particle all below 5 μm,
Hexanaphthene flusulfamide suspending agent is made, it is then that active component B, solvent, emulsifying agent and various auxiliary agents is directly newborn with high speed agitator
Change into suspending agent, suspension emulsion product of the present invention is made.Specifically it is shown in Table 4,5.
The each component of 4 embodiment of table 43~47 and content
The each component of 5 embodiment of table 48~52 and content
By table 4, into table 5, fluorine bacterium azoles, Prochloraz, carbendazim, thiophanate-methyl are exchanged, and novel formulation can be made.
The aqueous emulsion of embodiment 53~58
Hexanaphthene flusulfamide, active component B, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；By deionization
Water, antifreeze (can add to be not added with), thickener (can add to be not added with), defoamer are mixed, into homogeneous aqueous phase.In high-speed stirring
Mix down, aqueous phase is added into oil phase, aqueous emulsion product of the present invention is made.Specifically it is shown in Table 6.
The each component of 6 embodiment of table 53~58 and content
Fluorine bacterium azoles, polyoxin, Prochloraz, carbendazim, thiophanate-methyl in table are exchanged, novel formulation can be made.
The microemulsion of embodiment 59~61
Hexanaphthene flusulfamide, active component B are dissolved in the homogenizer equipped with solvent, by emulsifying agent, antifreeze, (can add can
Be not added with), defoamer be added in the homogenizer equipped with above-mentioned solution, supplied with deionized water give after surplus strongly mixing and it is even
Change, finally obtain the transparent microemulsion product of the present invention of clear appearance.Specifically it is shown in Table 7.
The each component of 7 embodiment of table 59~61 and content
The microcapsule suspending agent of embodiment 62~64
Hexanaphthene flusulfamide, active component B, macromolecule cyst material, solvent are mixed, makes to be dissolved into homogeneous oil phase, is cutting
Under tangent condition, oil phase is added to containing in emulsifying agent, pH adjusting agent, dispersant, the aqueous phase solution of defoamer, deionized water is used
Surplus is supplied, two kinds of materials react in oil-water interfaces, form high score ascus wall, the present composition is made well dispersed
Microcapsule suspending agent product.Specifically it is shown in Table 8.
The each component of 8 embodiment of table 62~64 and content
The microcapsule suspension-suspendinagent agent of embodiment 65~67
Active component B, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, by oil phase in shearing condition
Under be added to containing in emulsifying agent, the aqueous phase solution of pH adjusting agent, well dispersed microcapsule suspending agent is made.By dispersant, wet
Profit agent, defoamer, thickener (can add to be not added with) are well mixed by high speed shear, Hexanaphthene flusulfamide are added, in ball mill
Ball milling 2~3 hours, makes diameter of particle all below 5 μm, and suspending agent is made, and suspending agent then is added into microcapsules suspends
In the aqueous phase solution of agent, deionized water supplies surplus, and the well dispersed microcapsule suspension-suspendinagent agent production of the present composition is made
Product.Specifically it is shown in Table 9.
The each component of 9 embodiment of table 65~67 and content
Active component B includes fluorine bacterium azoles, Prochloraz, carbendazim, thiophanate-methyl in table.
The embodiment of the present invention is the method being combined using Toxicity Determination and field test.First pass through indoor virulence survey
Calmly, the synergy ratio (SR) after clear and definite two kinds of medicaments are compounded by a certain percentage, SR ＜ 0.5 are antagonism, 0.5≤SR≤1.5
For summation action, SR ＞ 1.5 are synergistic effect, on this basis, then carry out field test.
Test method：After determining the effective inhibition concentration scope of each medicament through prerun, medicament sets 5 respectively by active constituent content
Individual dosage processing, if clear water is compareed.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to crop germ.Colony diameter is measured with crossing method after 72h, the net growth of each processing is calculated
Amount, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter -5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum
Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to Wadley methods
Two medicament different ratio synergy ratios (SR) are calculated, SR ＜ 0.5 are antagonism, and 0.5≤SR≤1.5 are summation action,
SR ＞ 1.5 are synergistic effect.Calculation formula is as follows：
Wherein：A, b are respectively active components A and active component B ratio shared in combination；A is Hexanaphthene flusulfamide；B
Choosing to one of fluorine bacterium azoles, polyoxin, Prochloraz or its salt, carbendazim, thiophanate-methyl are planted.
Application Example two：
For examination disease：Powdery mildew of cucumber；Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.；Experimental design：Through
Cross pilot study and determine Hexanaphthene flusulfamide and fluorine bacterium azoles active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
The Hexanaphthene flusulfamide of table 10 compounds the toxicity test analysis of results table to powdery mildew of cucumber with fluorine bacterium azoles
As shown in Table 10, Hexanaphthene flusulfamide compounds the proportioning for preventing and treating powdery mildew of cucumber in 1 60~80 ︰ 1 of ︰ with fluorine bacterium azoles,
Synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 60~80, when hexamethylene sulphur bacterium
The proportioning of amine and fluorine bacterium azoles is in 1 10~35 ︰ 1 of ︰, and synergistic effect is more prominent, and synergy ratio is all higher than 2.20.Found through experiment
The optimum ratio of Hexanaphthene flusulfamide and fluorine bacterium azoles is 35：1、30：1、25：1、20：1、15：1、14：1、13：1、12：1、11：1、
10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：
10, especially when Hexanaphthene flusulfamide and fluorine bacterium azoles weight ratio are 7：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Application Example three：
For examination disease：Gray mold of cucumber；Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.；Experimental design：Through
Cross pilot study and determine Hexanaphthene flusulfamide and polyoxin active compound and effective inhibition concentration scope of the two different ratio mixture.
Toxicity test result
The Hexanaphthene flusulfamide of table 11 compounds the toxicity test analysis of results table to gray mold of cucumber with polyoxin
As shown in Table 11, Hexanaphthene flusulfamide compounds the proportioning of preventing and treating gray mold of cucumber in the ︰ 1 of 1 ︰ 60~80 with polyoxin
When, synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 60~80, works as hexamethylene
The proportioning of flusulfamide and polyoxin is in 1 10~25 ︰ 1 of ︰, and synergistic effect is more prominent, and synergy ratio is all higher than 2.25.Through examination
The optimum ratio for issuing after examination and approval existing Hexanaphthene flusulfamide and polyoxin is 25：1、20：1、15：1、10：1、9：1、8：1、7：1、6：1、5：
1、4：1、3：1、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10, especially when Hexanaphthene flusulfamide with it is many
Antimycin weight ratio is 5：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Application Example four：
For examination disease：Bakanae disease of rice；Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.；Experimental design：Through
Cross pilot study and determine Hexanaphthene flusulfamide and Prochloraz or effective inhibition concentration model of its salt active compound and the two different ratio mixture
Enclose.
Toxicity test result
The Hexanaphthene flusulfamide of table 12 compounds the toxicity test analysis of results table to bakanae disease of rice with Prochloraz or its salt
As shown in Table 12, Hexanaphthene flusulfamide and Prochloraz or its salt compounding prevent and treat the proportioning of bakanae disease of rice 1 ︰ 60~
During 80 ︰ 1, synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 60~80, when
Hexanaphthene flusulfamide and the proportioning of Prochloraz or its salt are in 1 10~25 ︰ 1 of ︰, and synergistic effect is more prominent, and synergy ratio is all higher than
2.25.The optimum ratio that Hexanaphthene flusulfamide and Prochloraz or its salt are found through experiment is 25：1、20：1、15：1、10：1、9：1、8：
1、7：1、6：1、5：1、4：1、3：1、5：2、2：1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10, especially
When Hexanaphthene flusulfamide and Prochloraz or its salt weight ratio are 5：Synergy ratio is maximum when 2, and synergistic effect is the most obvious.
Application Example five：
For examination disease：Ring rot of apple；Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.；Experimental design：Through
Cross pilot study and determine Hexanaphthene flusulfamide and effective inhibition concentration scope of carbendazim active compound and the two different ratio mixture.
Toxicity test result
The Hexanaphthene flusulfamide of table 13 compounds the toxicity test analysis of results table to ring rot of apple with carbendazim
As shown in Table 13, Hexanaphthene flusulfamide compounds the proportioning for preventing and treating ring rot of apple in 1 60~80 ︰ 1 of ︰ with carbendazim,
Synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 60~80, when hexamethylene sulphur bacterium
The proportioning of amine and carbendazim is in 1 30~20 ︰ 1 of ︰, and synergistic effect is more prominent, and synergy ratio is all higher than 2.20.Found through experiment
The optimum ratio of Hexanaphthene flusulfamide and carbendazim is 20：1、15：1、10：1、9：1、8：1、7：1、6：1、5：1、4：1、3：1、2：1、
1：1、2：3、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：15、1：20、1：25、1：30, especially work as hexamethylene
Flusulfamide is 2 with carbendazim weight ratio：Synergy ratio is maximum when 3, and synergistic effect is the most obvious.
Application Example six：
For examination disease：Pear scab；Test medicine is provided by Shaanxi Meibang Pesticide Co., Ltd.；Experimental design：Through
Cross pilot study and determine Hexanaphthene flusulfamide and effective inhibition concentration scope of thiophanate methyl raw pesticide and the two different ratio mixture.
Toxicity test result
The Hexanaphthene flusulfamide of table 14 compounds the toxicity test analysis of results table to pear scab with thiophanate-methyl
As shown in Table 14, Hexanaphthene flusulfamide compounds the proportioning of preventing and treating pear scab in the ︰ 1 of 1 ︰ 60~80 with thiophanate-methyl
When, synergy ratio SR is all higher than 1.5, illustrates that both show synergistic effect at the mixture in the range of the ︰ 1 of 1 ︰ 60~80, works as hexamethylene
The proportioning of flusulfamide and thiophanate-methyl is in 1 20~20 ︰ 1 of ︰, and synergistic effect is more prominent, and synergy ratio is all higher than 2.20.Through
Experiment finds that the optimum ratio of Hexanaphthene flusulfamide and thiophanate-methyl is 20：1、15：1、10：1、9：1、8：1、7：1、6：1、5：1、
4：1、3：1、2：1、1：1、1：2、2：5、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：15、1：20, especially work as ring
Own flusulfamide is 1 with thiophanate-methyl weight ratio：Synergy ratio is maximum when 1, and synergistic effect is the most obvious.
Found through experiment：After Hexanaphthene flusulfamide and active component B compounding to gray mold, leaf mold, downy mildew, green mould,
It is penicilliosis, head blight, sclerotiniose, brown spot, leaf spot, spot defoliation, scab, rust, powdery mildew, epidemic disease, vertical withered
Disease, anthracnose, bakanae disease, rice blast, banded sclerotial blight, blossom-end rot, crown rot, seedling laying disease, the preventing and treating of ring spot have obvious increasing
Effect is acted on, and synergy ratio is more than 1.50.
Test of pesticide effectiveness part
Test medicine is researched and developed by Shaanxi Meibang Pesticide Co., Ltd., provided.Comparison medicament：50% Hexanaphthene flusulfamide is wettable
Property pulvis (autogamy), 30% triflumizole wettable powder (purchased in market), 10% Wettable polyoxin powder (purchased in market), 20% miaow are fresh
Amine microemulsion (purchased in market), 40% carbendazim suspending agent (purchased in market), 10% thiophanate-methyl suspending agent (purchased in market).
The Hexanaphthene flusulfamide of Application Example seven and active component B and its compounding preventing and treating graw mold of tomato test of pesticide effectiveness
This test arrangement investigates the graw mold of tomato state of an illness before Xian District, Shanxi Province suburban area, medicine, in state of an illness first time at initial stage
Dispenser, every dispenser in 7 days once, is total to dispenser 2 times.7 days after last dispenser, disease index is investigated respectively and calculates anti-within 15 days, 20 days
Effect.Experimental result is as follows：
The Hexanaphthene flusulfamide of table 15 and active component B and its compounding preventing and treating graw mold of tomato test of pesticide effectiveness
As can be seen from Table 15, Hexanaphthene flusulfamide is with can effectively prevent and treat graw mold of tomato, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And tomato rust, damping-off, anthracnose, epidemic disease can be prevented and treated, and it is anti-
Effect is more than 96%.Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example eight and active component B and its compounding preventing and treating alternaria leaf spot of apple test of pesticide effectiveness
This test arrangement investigates the alternaria leaf spot of apple state of an illness before Xianyang, Shanxi province city, medicine, in state of an illness first time at initial stage
Dispenser, every dispenser in 7 days once, is total to dispenser 2 times.7 days after last dispenser, disease index is investigated respectively and calculates anti-within 15 days, 30 days
Effect.Experimental result is as follows：
The Hexanaphthene flusulfamide of table 16 and active component B and its compounding preventing and treating alternaria leaf spot of apple test of pesticide effectiveness
As can be seen from Table 16, Hexanaphthene flusulfamide is prevented with can effectively prevent and treat alternaria leaf spot of apple after active component B compoundings
The preventive effect that effect is superior to single dose is controlled, and preventive effect phase is long.And apple mildew, brown spot, ring spot, anthrax can be prevented and treated
Disease, scab, and preventive effect is more than 96%.Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example nine and active component B and its compounding preventing and treating rice blast test of pesticide effectiveness
This test arrangement investigates the rice blast state of an illness before Shaanxi Province's Hanzhong City, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 2 times.7 days after last dispenser, disease index is investigated respectively and preventive effect is calculated within 15 days, 20 days.It is real
Test result as follows：
The Hexanaphthene flusulfamide of table 17 and active component B and its compounding preventing and treating rice blast test of pesticide effectiveness
As can be seen from Table 17, Hexanaphthene flusulfamide is with can effectively prevent and treat rice blast, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And bakanae disease of rice, banded sclerotial blight can be prevented and treated, and preventive effect is more than 96%.
Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example ten and active component B and its compounding preventing and treating wheat powdery mildew test of pesticide effectiveness
This test arrangement investigates the wheat powdery mildew state of an illness before Shaanxi Province's Weinan City, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 2 times.7 days after last dispenser, disease index is investigated respectively and preventive effect is calculated within 15 days, 30 days.It is real
Test result as follows：
The Hexanaphthene flusulfamide of table 18 and active component B and its compounding preventing and treating wheat powdery mildew test of pesticide effectiveness
As can be seen from Table 18, Hexanaphthene flusulfamide is with can effectively prevent and treat wheat powdery mildew, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And wheat scab, banded sclerotial blight can be prevented and treated, and preventive effect is more than 96%.
Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example 11 and active component B and its compounding preventing and treating pear scab test of pesticide effectiveness
This test arrangement investigates the pear scab state of an illness before Xianyang, Shanxi province city, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 2 times.10 days after last dispenser, disease index is investigated respectively and preventive effect is calculated within 30 days, 45 days.It is real
Test result as follows：
The Hexanaphthene flusulfamide of table 19 and active component B and its compounding preventing and treating pear scab test of pesticide effectiveness
As can be seen from Table 19, Hexanaphthene flusulfamide is with can effectively prevent and treat pear scab, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And pear tree powdery mildew, brown spot, ring spot, anthracnose can be prevented and treated, and
Preventive effect is more than 96%.Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example 12 and active component B and its compounding preventing and treating gray mold of cucumber test of pesticide effectiveness
This test arrangement investigates the gray mold of cucumber state of an illness before Xian District, Shanxi Province suburban area, medicine, in state of an illness first time at initial stage
Dispenser, every dispenser in 7 days once, is total to dispenser 2 times.7 days after last dispenser, disease index is investigated respectively and calculates anti-within 15 days, 30 days
Effect.Experimental result is as follows：
The Hexanaphthene flusulfamide of table 20 and active component B and its compounding preventing and treating gray mold of cucumber test of pesticide effectiveness
As can be seen from Table 20, Hexanaphthene flusulfamide is with can effectively prevent and treat gray mold of cucumber, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And powdery mildew of cucumber, sclerotiniose, damping-off, anthracnose can be prevented and treated, and
Preventive effect is more than 96%.Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example 13 prevents and treats the sigatoka test of pesticide effectiveness with active component B and its compounding
This test arrangement investigates the sigatoka state of an illness before Nanning, medicine, in state of an illness first time at initial stage dispenser, often
Dispenser in 7 days once, is total to dispenser 2 times.7 days after last dispenser, disease index is investigated respectively and preventive effect is calculated within 15 days, 30 days.Experiment
As a result it is as follows：
The Hexanaphthene flusulfamide of table 21 prevents and treats the sigatoka test of pesticide effectiveness with active component B and its compounding
As can be seen from Table 21, Hexanaphthene flusulfamide is with can effectively prevent and treat sigatoka, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And banana crown rot, scab, anthracnose can be prevented and treated, and preventive effect exists
More than 96%.Target crop is had no adverse effects in experiment scope of medication.
The Hexanaphthene flusulfamide of Application Example 14 and active component B and its compounding preventing and treating citrus anthracnose test of pesticide effectiveness
This test arrangement investigates the citrus anthracnose state of an illness before Shaanxi Province's Hanzhong City, medicine, in state of an illness first time at initial stage dispenser,
Every dispenser in 7 days once, is total to dispenser 2 times.10 days after last dispenser, disease index is investigated respectively and preventive effect is calculated within 30 days, 45 days.It is real
Test result as follows：
The Hexanaphthene flusulfamide of table 22 and active component B and its compounding preventing and treating citrus anthracnose test of pesticide effectiveness
As can be seen from Table 22, Hexanaphthene flusulfamide is with can effectively prevent and treat citrus anthracnose, preventing and treating effect after active component B compoundings
Fruit is superior to the preventive effect of single dose, and preventive effect phase is long.And Penicillium italicum, green mould, powdery mildew can be prevented and treated, and preventive effect exists
More than 96%.Target crop is had no adverse effects in experiment scope of medication.
The experiment by different places in all parts of the country is drawn afterwards, Hexanaphthene flusulfamide and fluorine bacterium azoles, polyoxin, Prochloraz or
Its salt, carbendazim, thiophanate-methyl compounding after to the gray mold in various crop, leaf mold, downy mildew, green mould, penicilliosis,
Head blight, sclerotiniose, brown spot, leaf spot, spot defoliation, scab, rust, powdery mildew, epidemic disease, damping-off, anthrax
The preventive effect of the Common Diseases such as disease, bakanae disease, rice blast, banded sclerotial blight, blossom-end rot, crown rot, seedling laying disease, ring spot 95% with
On, better than single dose preventive effect, synergistic effect is obvious.
Claims (5)
1. a kind of bactericidal composition containing Hexanaphthene flusulfamide, it is characterised in that：Active ingredient is active components A and active component B,
Active components A is the ︰ 1 of 1 ︰ 60 ~ 80 with active component B weight ratio, and described active components A is Hexanaphthene flusulfamide, and active component B is
Wettable powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, microcapsule suspension is made in polyoxin, composition
Agent, microcapsule suspension-suspendinagent agent.
2. the bactericidal composition according to claim 1 containing Hexanaphthene flusulfamide, it is characterised in that：Active components A and activity
Composition B weight ratio is the ︰ 1 of 1 ︰ 40 ~ 60.
3. the bactericidal composition according to claim 2 containing Hexanaphthene flusulfamide, it is characterised in that：
Hexanaphthene flusulfamide and the weight of polyoxin ratio are the ︰ 1 of 1 ︰ 10 ~ 25.
4. the bactericidal composition according to claim 3 containing Hexanaphthene flusulfamide is used for the application for preventing and treating corps diseases.
5. application according to claim 4, it is characterised in that：Described disease include gray mold, leaf mold, downy mildew,
Green mould, penicilliosis, head blight, sclerotiniose, brown spot, leaf spot, spot defoliation, scab, rust, powdery mildew, epidemic disease
Disease, damping-off, anthracnose, bakanae disease, rice blast, banded sclerotial blight, blossom-end rot, crown rot, seedling laying disease, ring spot.
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| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| EP1980150A1 (en) * | 2007-04-13 | 2008-10-15 | Basf Se | Fungicidal mixtures based on triazolopyrimidine compounds |
| CN102067873A (en) * | 2011-02-19 | 2011-05-25 | 陕西美邦农药有限公司 | Bactericidal composition containing polyoxin and triazole compound |
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| CN101720764A (en) * | 2008-10-13 | 2010-06-09 | 中国农业大学 | New application of N-(2-trifluoromethyl-4-chlorphenyl)-alpha-oxocyclohexyl sulfamide as sterilizing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1900059A (en) * | 2005-07-20 | 2007-01-24 | 中国农业大学 | 2-keto naphthene sulfamide, its preparing method and use as germicide |
| EP1980150A1 (en) * | 2007-04-13 | 2008-10-15 | Basf Se | Fungicidal mixtures based on triazolopyrimidine compounds |
| CN102067873A (en) * | 2011-02-19 | 2011-05-25 | 陕西美邦农药有限公司 | Bactericidal composition containing polyoxin and triazole compound |
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| Title |
|---|
| 新颖杀菌剂-环己磺菌胺;中国农业大学 等;《世界农药》;20120625;第34卷(第3期);第56页第2栏第1-2段 * |
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